#------------------------------------------------------------------------------
#$Date: 2017-04-05 12:39:35 +0300 (Wed, 05 Apr 2017) $
#$Revision: 195050 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/04/20/7042080.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7042080
loop_
_publ_author_name
'Pop, Alexandra'
'Bellini, Clément'
'Şuteu, Răzvan'
'Dorcet, Vincent'
'Roisnel, Thierry'
'Carpentier, Jean-François'
'Silvestru, Anca'
'Sarazin, Yann'
_publ_section_title
;
 Cadmium complexes bearing (Me2)NEO(-) (E = S, Se)
 organochalcogenoalkoxides and their zinc and mercury analogues.
;
_journal_issue                   10
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              3179
_journal_page_last               3191
_journal_paper_doi               10.1039/c7dt00279c
_journal_volume                  46
_journal_year                    2017
_chemical_compound_source        'synthesis as described'
_chemical_formula_moiety         'C19 H38 N2 O Se Si2 Zn'
_chemical_formula_sum            'C19 H38 N2 O Se Si2 Zn'
_chemical_formula_weight         511.02
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_conform_dict_location     ftp://ftp.iucr.org/pub/cif_core.dic
_audit_conform_dict_name         cif_core.dic
_audit_conform_dict_version      2.4
_audit_creation_date             2015-06-01T11:25:43-00:00
_audit_creation_method           'WinGX routine CIF_UPDATE'
_audit_update_record
;
2016-11-22 deposited with the CCDC.
2017-02-13 downloaded from the CCDC.
;
_cell_angle_alpha                96.460(4)
_cell_angle_beta                 109.961(3)
_cell_angle_gamma                111.277(3)
_cell_formula_units_Z            2
_cell_length_a                   9.1925(6)
_cell_length_b                   12.6472(8)
_cell_length_c                   12.9189(10)
_cell_measurement_reflns_used    5514
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      27.55
_cell_measurement_theta_min      2.45
_cell_measurement_wavelength     0.71073
_cell_volume                     1266.67(16)
_computing_cell_refinement       'Bruker APEX2 (Bruker, 2006)'
_computing_data_collection       'Bruker APEX2 (Bruker, 2006)'
_computing_data_reduction        'Bruker APEX2 (Bruker, 2006)'
_computing_molecular_graphics    'Ortep-3 for Windows (Farrugia, 1997)'
_computing_publication_material
;
          WinGX publication routines (Farrugia, 2012),
          CRYSCALc (T. Roisnel, local program, 2014)
;
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SIR97 (Altomare et al., 1999)'
_diffrn_ambient_temperature      150(2)
_diffrn_detector                 'CCD plate'
_diffrn_measured_fraction_theta_full 0.985
_diffrn_measured_fraction_theta_max 0.985
_diffrn_measurement_device_type  'APEXII, Bruker-AXS'
_diffrn_measurement_method       'CCD rotation images, thin slices'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0281
_diffrn_reflns_av_unetI/netI     0.0408
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -14
_diffrn_reflns_number            13325
_diffrn_reflns_theta_full        27.48
_diffrn_reflns_theta_max         27.48
_diffrn_reflns_theta_min         3.33
_exptl_absorpt_coefficient_mu    2.511
_exptl_absorpt_correction_T_max  0.285
_exptl_absorpt_correction_T_min  0.175
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
  [Sheldrick, G.M. (2002). SADABS Bruker AXS Inc., Madison, Wisconsin, USA]
;
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.34
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             532
_exptl_crystal_size_max          0.6
_exptl_crystal_size_mid          0.59
_exptl_crystal_size_min          0.5
_refine_diff_density_max         1.418
_refine_diff_density_min         -0.551
_refine_diff_density_rms         0.082
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.039
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     245
_refine_ls_number_reflns         5722
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.039
_refine_ls_R_factor_all          0.0465
_refine_ls_R_factor_gt           0.0336
_refine_ls_shift/su_max          0.043
_refine_ls_shift/su_mean         0.002
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0452P)²+0.5925P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0838
_refine_ls_wR_factor_ref         0.0897
_reflns_number_gt                4660
_reflns_number_total             5722
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c7dt00279c2.cif
_cod_data_source_block           ALE284
_cod_depositor_comments
'Adding full bibliography for 7042078--7042085.cif.'
_cod_original_cell_volume        1266.67(15)
_cod_database_code               7042080
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Zn1 Zn 0.93839(3) 0.39449(2) 0.40579(3) 0.02073(9) Uani 1 1 d .
Se1 Se 0.99570(3) 0.53263(2) 0.26715(2) 0.02263(8) Uani 1 1 d .
O1 O 0.8490(2) 0.50468(15) 0.45510(15) 0.0218(4) Uani 1 1 d .
N1 N 0.8353(3) 0.22736(18) 0.3448(2) 0.0267(5) Uani 1 1 d .
Si1 Si 0.64278(10) 0.14656(7) 0.35036(8) 0.0358(2) Uani 1 1 d .
Si2 Si 0.93476(10) 0.16349(7) 0.28511(7) 0.03025(18) Uani 1 1 d .
C1 C 0.8365(3) 0.4530(2) 0.1100(2) 0.0216(5) Uani 1 1 d .
C2 C 0.7375(3) 0.3316(2) 0.0800(2) 0.0256(6) Uani 1 1 d .
H2 H 0.7431 0.291 0.1378 0.031 Uiso 1 1 calc R
C3 C 0.6310(3) 0.2699(3) -0.0334(3) 0.0314(6) Uani 1 1 d .
H3 H 0.5645 0.1871 -0.0536 0.038 Uiso 1 1 calc R
C4 C 0.6221(4) 0.3297(3) -0.1169(3) 0.0351(7) Uani 1 1 d .
H4 H 0.548 0.2882 -0.1946 0.042 Uiso 1 1 calc R
C5 C 0.7208(4) 0.4495(3) -0.0876(3) 0.0314(6) Uani 1 1 d .
H5 H 0.713 0.4892 -0.146 0.038 Uiso 1 1 calc R
C6 C 0.8314(3) 0.5139(2) 0.0250(2) 0.0245(6) Uani 1 1 d .
C7 C 0.9473(4) 0.6424(3) 0.0508(3) 0.0320(7) Uani 1 1 d .
H7A H 1.0654 0.657 0.1011 0.038 Uiso 1 1 calc R
H7B H 0.9487 0.6602 -0.0217 0.038 Uiso 1 1 calc R
N8 N 0.9007(3) 0.7207(2) 0.1036(3) 0.0398(6) Uani 1 1 d .
C9 C 0.7413(4) 0.7211(3) 0.0301(3) 0.0481(9) Uani 1 1 d .
H9A H 0.7519 0.7445 -0.0377 0.072 Uiso 1 1 calc R
H9B H 0.7164 0.7771 0.0718 0.072 Uiso 1 1 calc R
H9C H 0.6479 0.642 0.0064 0.072 Uiso 1 1 calc R
C10 C 1.0399(5) 0.8389(3) 0.1455(4) 0.0614(11) Uani 1 1 d .
H10A H 1.1472 0.8365 0.1924 0.092 Uiso 1 1 calc R
H10B H 1.0149 0.8911 0.1917 0.092 Uiso 1 1 calc R
H10C H 1.051 0.8687 0.0804 0.092 Uiso 1 1 calc R
C11 C 0.8789(4) 0.6171(2) 0.3183(3) 0.0295(6) Uani 1 1 d .
H11A H 0.9666 0.6915 0.377 0.035 Uiso 1 1 calc R
H11B H 0.8122 0.6381 0.2526 0.035 Uiso 1 1 calc R
C12 C 0.7582(3) 0.5463(2) 0.3683(2) 0.0270(6) Uani 1 1 d .
C13 C 0.6992(4) 0.6283(3) 0.4206(3) 0.0425(8) Uani 1 1 d .
H13A H 0.623 0.5853 0.4543 0.064 Uiso 1 1 calc R
H13B H 0.6375 0.657 0.361 0.064 Uiso 1 1 calc R
H13C H 0.7992 0.6954 0.4802 0.064 Uiso 1 1 calc R
C14 C 0.6032(3) 0.4414(3) 0.2769(3) 0.0358(7) Uani 1 1 d .
H14A H 0.6407 0.3863 0.2469 0.054 Uiso 1 1 calc R
H14B H 0.5444 0.4688 0.2146 0.054 Uiso 1 1 calc R
H14C H 0.5245 0.4016 0.3102 0.054 Uiso 1 1 calc R
C21 C 0.4535(4) 0.1128(3) 0.2133(3) 0.0488(9) Uani 1 1 d .
H21A H 0.457 0.1865 0.1949 0.073 Uiso 1 1 calc R
H21B H 0.3473 0.0712 0.2223 0.073 Uiso 1 1 calc R
H21C H 0.4574 0.063 0.1514 0.073 Uiso 1 1 calc R
C22 C 0.6240(5) -0.0005(3) 0.3768(4) 0.0614(12) Uani 1 1 d .
H22A H 0.6343 -0.0463 0.3155 0.092 Uiso 1 1 calc R
H22B H 0.5124 -0.0436 0.3784 0.092 Uiso 1 1 calc R
H22C H 0.7156 0.0119 0.4504 0.092 Uiso 1 1 calc R
C23 C 0.6167(4) 0.2265(3) 0.4686(3) 0.0482(9) Uani 1 1 d .
H23A H 0.6944 0.2258 0.5424 0.072 Uiso 1 1 calc R
H23B H 0.4981 0.1876 0.4602 0.072 Uiso 1 1 calc R
H23C H 0.6439 0.3082 0.4653 0.072 Uiso 1 1 calc R
C24 C 1.0263(5) 0.0743(3) 0.3711(3) 0.0500(9) Uani 1 1 d .
H24A H 1.0701 0.1118 0.4529 0.075 Uiso 1 1 calc R
H24B H 1.1199 0.0701 0.3535 0.075 Uiso 1 1 calc R
H24C H 0.9364 -0.0055 0.3519 0.075 Uiso 1 1 calc R
C25 C 0.7855(5) 0.0584(3) 0.1391(3) 0.0509(9) Uani 1 1 d .
H25A H 0.6991 -0.0103 0.1462 0.076 Uiso 1 1 calc R
H25B H 0.8512 0.0326 0.1048 0.076 Uiso 1 1 calc R
H25C H 0.7287 0.0982 0.0903 0.076 Uiso 1 1 calc R
C26 C 1.1133(4) 0.2778(3) 0.2647(3) 0.0349(7) Uani 1 1 d .
H26A H 1.0664 0.3176 0.2105 0.052 Uiso 1 1 calc R
H26B H 1.172 0.2399 0.2347 0.052 Uiso 1 1 calc R
H26C H 1.1949 0.3357 0.3383 0.052 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0 0 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.006 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Zn Zn 0.2839 1.4301 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Se Se -0.0929 2.2259 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N1 Zn1 O1 128.79(8) . 2_766
N1 Zn1 O1 132.01(8) . .
O1 Zn1 O1 84.02(7) 2_766 .
N1 Zn1 Se1 118.95(7) . .
O1 Zn1 Se1 97.19(5) 2_766 .
O1 Zn1 Se1 83.01(5) . .
N1 Zn1 Zn1 150.70(7) . 2_766
O1 Zn1 Zn1 42.20(5) 2_766 2_766
O1 Zn1 Zn1 41.82(5) . 2_766
Se1 Zn1 Zn1 90.102(15) . 2_766
C1 Se1 C11 101.64(11) . .
C1 Se1 Zn1 111.41(8) . .
C11 Se1 Zn1 88.96(8) . .
C12 O1 Zn1 125.42(16) . 2_766
C12 O1 Zn1 116.77(16) . .
Zn1 O1 Zn1 95.98(7) 2_766 .
Si2 N1 Si1 122.60(13) . .
Si2 N1 Zn1 119.41(12) . .
Si1 N1 Zn1 117.98(13) . .
N1 Si1 C23 111.06(13) . .
N1 Si1 C21 112.54(14) . .
C23 Si1 C21 107.90(17) . .
N1 Si1 C22 112.37(15) . .
C23 Si1 C22 106.79(19) . .
C21 Si1 C22 105.83(18) . .
N1 Si2 C26 110.96(12) . .
N1 Si2 C24 114.08(16) . .
C26 Si2 C24 107.70(16) . .
N1 Si2 C25 112.75(15) . .
C26 Si2 C25 105.83(17) . .
C24 Si2 C25 104.98(16) . .
C2 C1 C6 120.3(3) . .
C2 C1 Se1 118.8(2) . .
C6 C1 Se1 120.62(19) . .
C3 C2 C1 120.5(3) . .
C3 C2 H2 119.8 . .
C1 C2 H2 119.8 . .
C4 C3 C2 119.5(3) . .
C4 C3 H3 120.3 . .
C2 C3 H3 120.3 . .
C5 C4 C3 120.1(3) . .
C5 C4 H4 120 . .
C3 C4 H4 120 . .
C4 C5 C6 122.0(3) . .
C4 C5 H5 119 . .
C6 C5 H5 119 . .
C5 C6 C1 117.6(2) . .
C5 C6 C7 119.7(3) . .
C1 C6 C7 122.6(3) . .
N8 C7 C6 114.7(2) . .
N8 C7 H7A 108.6 . .
C6 C7 H7A 108.6 . .
N8 C7 H7B 108.6 . .
C6 C7 H7B 108.6 . .
H7A C7 H7B 107.6 . .
C7 N8 C9 113.6(3) . .
C7 N8 C10 109.4(3) . .
C9 N8 C10 110.5(3) . .
N8 C9 H9A 109.5 . .
N8 C9 H9B 109.5 . .
H9A C9 H9B 109.5 . .
N8 C9 H9C 109.5 . .
H9A C9 H9C 109.5 . .
H9B C9 H9C 109.5 . .
N8 C10 H10A 109.5 . .
N8 C10 H10B 109.5 . .
H10A C10 H10B 109.5 . .
N8 C10 H10C 109.5 . .
H10A C10 H10C 109.5 . .
H10B C10 H10C 109.5 . .
C12 C11 Se1 113.79(17) . .
C12 C11 H11A 108.8 . .
Se1 C11 H11A 108.8 . .
C12 C11 H11B 108.8 . .
Se1 C11 H11B 108.8 . .
H11A C11 H11B 107.7 . .
O1 C12 C14 108.9(2) . .
O1 C12 C13 109.7(2) . .
C14 C12 C13 109.6(2) . .
O1 C12 C11 109.2(2) . .
C14 C12 C11 111.5(2) . .
C13 C12 C11 107.9(2) . .
C12 C13 H13A 109.5 . .
C12 C13 H13B 109.5 . .
H13A C13 H13B 109.5 . .
C12 C13 H13C 109.5 . .
H13A C13 H13C 109.5 . .
H13B C13 H13C 109.5 . .
C12 C14 H14A 109.5 . .
C12 C14 H14B 109.5 . .
H14A C14 H14B 109.5 . .
C12 C14 H14C 109.5 . .
H14A C14 H14C 109.5 . .
H14B C14 H14C 109.5 . .
Si1 C21 H21A 109.5 . .
Si1 C21 H21B 109.5 . .
H21A C21 H21B 109.5 . .
Si1 C21 H21C 109.5 . .
H21A C21 H21C 109.5 . .
H21B C21 H21C 109.5 . .
Si1 C22 H22A 109.5 . .
Si1 C22 H22B 109.5 . .
H22A C22 H22B 109.5 . .
Si1 C22 H22C 109.5 . .
H22A C22 H22C 109.5 . .
H22B C22 H22C 109.5 . .
Si1 C23 H23A 109.5 . .
Si1 C23 H23B 109.5 . .
H23A C23 H23B 109.5 . .
Si1 C23 H23C 109.5 . .
H23A C23 H23C 109.5 . .
H23B C23 H23C 109.5 . .
Si2 C24 H24A 109.5 . .
Si2 C24 H24B 109.5 . .
H24A C24 H24B 109.5 . .
Si2 C24 H24C 109.5 . .
H24A C24 H24C 109.5 . .
H24B C24 H24C 109.5 . .
Si2 C25 H25A 109.5 . .
Si2 C25 H25B 109.5 . .
H25A C25 H25B 109.5 . .
Si2 C25 H25C 109.5 . .
H25A C25 H25C 109.5 . .
H25B C25 H25C 109.5 . .
Si2 C26 H26A 109.5 . .
Si2 C26 H26B 109.5 . .
H26A C26 H26B 109.5 . .
Si2 C26 H26C 109.5 . .
H26A C26 H26C 109.5 . .
H26B C26 H26C 109.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Zn1 N1 1.910(2) .
Zn1 O1 1.9881(18) 2_766
Zn1 O1 2.0027(17) .
Zn1 Se1 2.6868(4) .
Zn1 Zn1 2.9652(6) 2_766
Se1 C1 1.929(3) .
Se1 C11 1.972(3) .
O1 C12 1.431(3) .
O1 Zn1 1.9881(17) 2_766
N1 Si2 1.720(3) .
N1 Si1 1.724(2) .
Si1 C23 1.869(4) .
Si1 C21 1.879(3) .
Si1 C22 1.886(3) .
Si2 C26 1.874(3) .
Si2 C24 1.884(3) .
Si2 C25 1.885(3) .
C1 C2 1.395(4) .
C1 C6 1.408(4) .
C2 C3 1.387(4) .
C2 H2 0.95 .
C3 C4 1.382(4) .
C3 H3 0.95 .
C4 C5 1.379(4) .
C4 H4 0.95 .
C5 C6 1.391(4) .
C5 H5 0.95 .
C6 C7 1.505(4) .
C7 N8 1.409(4) .
C7 H7A 0.99 .
C7 H7B 0.99 .
N8 C9 1.452(4) .
N8 C10 1.457(4) .
C9 H9A 0.98 .
C9 H9B 0.98 .
C9 H9C 0.98 .
C10 H10A 0.98 .
C10 H10B 0.98 .
C10 H10C 0.98 .
C11 C12 1.532(4) .
C11 H11A 0.99 .
C11 H11B 0.99 .
C12 C14 1.520(4) .
C12 C13 1.525(4) .
C13 H13A 0.98 .
C13 H13B 0.98 .
C13 H13C 0.98 .
C14 H14A 0.98 .
C14 H14B 0.98 .
C14 H14C 0.98 .
C21 H21A 0.98 .
C21 H21B 0.98 .
C21 H21C 0.98 .
C22 H22A 0.98 .
C22 H22B 0.98 .
C22 H22C 0.98 .
C23 H23A 0.98 .
C23 H23B 0.98 .
C23 H23C 0.98 .
C24 H24A 0.98 .
C24 H24B 0.98 .
C24 H24C 0.98 .
C25 H25A 0.98 .
C25 H25B 0.98 .
C25 H25C 0.98 .
C26 H26A 0.98 .
C26 H26B 0.98 .
C26 H26C 0.98 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
N1 Zn1 Se1 C1 26.91(11) . .
O1 Zn1 Se1 C1 169.22(9) 2_766 .
O1 Zn1 Se1 C1 -107.74(9) . .
Zn1 Zn1 Se1 C1 -149.06(8) 2_766 .
N1 Zn1 Se1 C11 129.01(12) . .
O1 Zn1 Se1 C11 -88.68(10) 2_766 .
O1 Zn1 Se1 C11 -5.64(10) . .
Zn1 Zn1 Se1 C11 -46.96(9) 2_766 .
N1 Zn1 O1 C12 -86.24(19) . .
O1 Zn1 O1 C12 134.86(19) 2_766 .
Se1 Zn1 O1 C12 36.84(16) . .
Zn1 Zn1 O1 C12 134.87(19) 2_766 .
N1 Zn1 O1 Zn1 138.89(10) . 2_766
O1 Zn1 O1 Zn1 0 2_766 2_766
Se1 Zn1 O1 Zn1 -98.03(6) . 2_766
O1 Zn1 N1 Si2 -69.83(18) 2_766 .
O1 Zn1 N1 Si2 167.21(10) . .
Se1 Zn1 N1 Si2 59.08(15) . .
Zn1 Zn1 N1 Si2 -129.18(12) 2_766 .
O1 Zn1 N1 Si1 111.03(13) 2_766 .
O1 Zn1 N1 Si1 -11.9(2) . .
Se1 Zn1 N1 Si1 -120.06(12) . .
Zn1 Zn1 N1 Si1 51.7(2) 2_766 .
Si2 N1 Si1 C23 156.08(17) . .
Zn1 N1 Si1 C23 -24.81(19) . .
Si2 N1 Si1 C21 -82.8(2) . .
Zn1 N1 Si1 C21 96.29(18) . .
Si2 N1 Si1 C22 36.5(2) . .
Zn1 N1 Si1 C22 -144.36(19) . .
Si1 N1 Si2 C26 167.64(16) . .
Zn1 N1 Si2 C26 -11.46(19) . .
Si1 N1 Si2 C24 -70.5(2) . .
Zn1 N1 Si2 C24 110.40(17) . .
Si1 N1 Si2 C25 49.1(2) . .
Zn1 N1 Si2 C25 -129.97(16) . .
C11 Se1 C1 C2 -106.6(2) . .
Zn1 Se1 C1 C2 -13.1(2) . .
C11 Se1 C1 C6 79.3(2) . .
Zn1 Se1 C1 C6 172.80(17) . .
C6 C1 C2 C3 -1.1(4) . .
Se1 C1 C2 C3 -175.2(2) . .
C1 C2 C3 C4 -0.6(4) . .
C2 C3 C4 C5 1.0(4) . .
C3 C4 C5 C6 0.1(4) . .
C4 C5 C6 C1 -1.7(4) . .
C4 C5 C6 C7 174.7(2) . .
C2 C1 C6 C5 2.2(4) . .
Se1 C1 C6 C5 176.23(19) . .
C2 C1 C6 C7 -174.1(2) . .
Se1 C1 C6 C7 -0.1(3) . .
C5 C6 C7 N8 107.7(3) . .
C1 C6 C7 N8 -76.1(3) . .
C6 C7 N8 C9 -67.8(3) . .
C6 C7 N8 C10 168.2(3) . .
C1 Se1 C11 C12 90.0(2) . .
Zn1 Se1 C11 C12 -21.61(19) . .
Zn1 O1 C12 C14 179.96(17) 2_766 .
Zn1 O1 C12 C14 59.8(2) . .
Zn1 O1 C12 C13 -60.1(3) 2_766 .
Zn1 O1 C12 C13 179.78(19) . .
Zn1 O1 C12 C11 58.0(3) 2_766 .
Zn1 O1 C12 C11 -62.2(2) . .
Se1 C11 C12 O1 52.2(3) . .
Se1 C11 C12 C14 -68.2(3) . .
Se1 C11 C12 C13 171.36(19) . .
