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#$Date: 2025-01-15 11:55:26 +0200 (Wed, 15 Jan 2025) $
#$Revision: 297324 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/04/27/7042743.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7042743
loop_
_publ_author_name
'Parvin, Nasrina'
'Dasgupta, Rajarshi'
'Pal, Shiv'
'Sen, Sakya Singha'
'Khan, Shabana'
_publ_section_title
;
 Strikingly diverse reactivity of structurally identical silylene and stannylene
;
_journal_coden_ASTM              DTARAF
_journal_issue                   20
_journal_name_full               'Dalton Transactions'
_journal_page_first              6528
_journal_page_last               6532
_journal_paper_doi               10.1039/C7DT01055A
_journal_volume                  46
_journal_year                    2017
_chemical_formula_sum            'C42 H79.5 Ag F6 N6 Sb Si4 Sn2'
_chemical_formula_weight         1361.97
_chemical_properties_physical
', Air-sensitive,Moisture-sensitive,Oxygen-sensitive'
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_Hall           '-C 2yc'
_space_group_name_H-M_alt        'C 1 2/c 1'
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2017-03-03 deposited with the CCDC.
2017-04-20 downloaded from the CCDC.
;
_cell_angle_alpha                90.00(3)
_cell_angle_beta                 107.03(3)
_cell_angle_gamma                90.00(3)
_cell_formula_units_Z            4
_cell_length_a                   15.748(3)
_cell_length_b                   19.935(4)
_cell_length_c                   20.701(4)
_cell_measurement_reflns_used    9942
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      22.32
_cell_measurement_theta_min      2.30
_cell_volume                     6214(2)
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_diffrn_ambient_temperature      150(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.1741
_diffrn_reflns_av_unetI/netI     0.0618
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.999
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_k_max       23
_diffrn_reflns_limit_k_min       -23
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_number            95896
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.999
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         25.249
_diffrn_reflns_theta_min         2.288
_exptl_absorpt_coefficient_mu    1.661
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
'Sheldrick,G.M(2012)SADABS.BrukerAXS Inc.,Madison,Wisconsin,USA.'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.456
_exptl_crystal_description       block
_exptl_crystal_F_000             2726
_exptl_crystal_size_max          0.1
_exptl_crystal_size_mid          0.1
_exptl_crystal_size_min          0.1
_exptl_transmission_factor_max   0.7074
_exptl_transmission_factor_min   0.5589
_refine_diff_density_max         1.020
_refine_diff_density_min         -0.729
_refine_diff_density_rms         0.107
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.021
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     380
_refine_ls_number_reflns         5635
_refine_ls_number_restraints     48
_refine_ls_restrained_S_all      1.018
_refine_ls_R_factor_all          0.1040
_refine_ls_R_factor_gt           0.0519
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0573P)²+48.2216P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1157
_refine_ls_wR_factor_ref         0.1479
_reflns_Friedel_coverage         0.000
_reflns_number_gt                3519
_reflns_number_total             5635
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c7dt01055a2.cif
_cod_data_source_block           mo_NP_170_0m_a
_cod_original_formula_sum        'C42 H79.50 Ag F6 N6 Sb Si4 Sn2'
_cod_database_code               7042743
_shelx_shelxl_version_number     2014/7
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.7786(5) 0.6253(4) 0.3342(4) 0.055(2) Uani 1 1 d . . . A 1
C2 C 0.6973(5) 0.5134(4) 0.3209(4) 0.057(2) Uani 1 1 d . . . B 1
C3 C 0.8423(5) 0.6150(4) 0.4025(5) 0.069(2) Uani 1 1 d . . . A 1
C4 C 0.9265(5) 0.5891(5) 0.4088(5) 0.079(3) Uani 1 1 d . . . A 1
H4 H 0.9425 0.5776 0.3704 0.095 Uiso 1 1 calc R U . A 1
C5 C 0.8154(6) 0.7484(5) 0.3185(7) 0.099(4) Uani 1 1 d . . . C 1
C6 C 0.6381(7) 0.4811(5) 0.2566(6) 0.106(4) Uani 1 1 d . . . B 1
H6A H 0.6720 0.4733 0.2256 0.158 Uiso 1 1 calc R U . B 1
H6B H 0.5893 0.5105 0.2361 0.158 Uiso 1 1 calc R U . B 1
H6C H 0.6156 0.4392 0.2676 0.158 Uiso 1 1 calc R U . B 1
C7 C 0.8201(7) 0.6319(5) 0.4603(6) 0.093(3) Uani 1 1 d . . . A 1
H7 H 0.7647 0.6505 0.4565 0.112 Uiso 1 1 calc R U . A 1
C8 C 0.7748(7) 0.4682(5) 0.3494(6) 0.109(4) Uani 1 1 d . . . B 1
H8A H 0.8088 0.4845 0.3930 0.164 Uiso 1 1 calc R U . B 1
H8B H 0.8116 0.4674 0.3197 0.164 Uiso 1 1 calc R U . B 1
H8C H 0.7540 0.4237 0.3539 0.164 Uiso 1 1 calc R U . B 1
C9 C 0.9862(7) 0.5803(6) 0.4721(7) 0.101(4) Uani 1 1 d . . . A 1
H9 H 1.0426 0.5634 0.4761 0.121 Uiso 1 1 calc R U . A 1
C10 C 0.6424(8) 0.5210(5) 0.3694(6) 0.105(4) Uani 1 1 d . . . B 1
H10A H 0.5927 0.5498 0.3497 0.158 Uiso 1 1 calc R U . B 1
H10B H 0.6783 0.5403 0.4109 0.158 Uiso 1 1 calc R U . B 1
H10C H 0.6213 0.4778 0.3782 0.158 Uiso 1 1 calc R U . B 1
C11 C 0.9631(9) 0.5962(7) 0.5285(7) 0.116(4) Uani 1 1 d . . . A 1
H11 H 1.0041 0.5901 0.5707 0.139 Uiso 1 1 calc R U . A 1
C12 C 0.8475(13) 0.5788(10) 0.1907(10) 0.095(6) Uani 0.604(12) 1 d . U P D 1
H12A H 0.8795 0.6146 0.2184 0.143 Uiso 0.604(12) 1 calc R U P D 1
H12B H 0.8880 0.5517 0.1753 0.143 Uiso 0.604(12) 1 calc R U P D 1
H12C H 0.8191 0.5517 0.2167 0.143 Uiso 0.604(12) 1 calc R U P D 1
C16 C 0.7865(10) 0.7824(5) 0.3718(9) 0.169(8) Uani 1 1 d . . . . .
H16A H 0.8187 0.7644 0.4151 0.254 Uiso 1 1 calc R U . C 1
H16B H 0.7241 0.7752 0.3642 0.254 Uiso 1 1 calc R U . C 1
H16C H 0.7980 0.8296 0.3709 0.254 Uiso 1 1 calc R U . C 1
C17 C 0.7864(9) 0.7893(7) 0.2551(7) 0.137(5) Uani 1 1 d . U . . .
H17A H 0.7227 0.7909 0.2394 0.205 Uiso 1 1 calc R U . C 1
H17B H 0.8084 0.7692 0.2210 0.205 Uiso 1 1 calc R U . C 1
H17C H 0.8094 0.8340 0.2641 0.205 Uiso 1 1 calc R U . C 1
C19 C 0.7568(18) 0.5275(15) 0.0785(13) 0.151(13) Uani 0.604(12) 1 d . . P D 1
H19A H 0.8120 0.5045 0.0836 0.226 Uiso 0.604(12) 1 calc R U P D 1
H19B H 0.7303 0.5385 0.0318 0.226 Uiso 0.604(12) 1 calc R U P D 1
H19C H 0.7173 0.4990 0.0937 0.226 Uiso 0.604(12) 1 calc R U P D 1
Sn1 Sn 0.64800(3) 0.65279(3) 0.22640(3) 0.04990(19) Uani 1 1 d . . . . .
Ag1 Ag 0.5000 0.68950(4) 0.2500 0.0556(3) Uani 1 2 d S T P A .
Sb1 Sb 0.5000 0.88606(4) 0.2500 0.0890(3) Uani 1 2 d S T P . .
Si2 Si 0.7783(5) 0.6078(4) 0.1310(3) 0.075(2) Uani 0.604(12) 1 d . . P D 1
C13 C 0.8797(10) 0.6215(6) 0.5245(6) 0.113(4) Uani 1 1 d . . . . .
H13 H 0.8638 0.6312 0.5633 0.136 Uiso 1 1 calc R U . A 1
Si1 Si 0.5951(6) 0.6761(4) 0.0688(5) 0.078(3) Uani 0.604(12) 1 d . . P D 1
N1 N 0.7212(4) 0.5793(3) 0.2994(3) 0.0499(15) Uani 1 1 d . . . . .
N3 N 0.6686(5) 0.6349(4) 0.1353(4) 0.076(2) Uani 1 1 d . . . . .
F3 F 0.4866(6) 0.9516(4) 0.3098(4) 0.146(3) Uani 1 1 d . . . . .
F2 F 0.6181(7) 0.8965(7) 0.2938(6) 0.250(6) Uani 1 1 d . . . . .
C21 C 0.8301(15) 0.6719(11) 0.0873(12) 0.131(8) Uani 0.604(12) 1 d . U P D 1
H21A H 0.8453 0.7112 0.1151 0.197 Uiso 0.604(12) 1 calc R U P D 1
H21B H 0.7886 0.6837 0.0447 0.197 Uiso 0.604(12) 1 calc R U P D 1
H21C H 0.8827 0.6534 0.0798 0.197 Uiso 0.604(12) 1 calc R U P D 1
N2 N 0.7711(4) 0.6819(3) 0.2987(4) 0.0641(19) Uani 1 1 d . . . . .
C15 C 0.4881(19) 0.679(2) 0.0739(16) 0.168(17) Uani 0.604(12) 1 d . . P D 1
H15A H 0.4700 0.6342 0.0823 0.252 Uiso 0.604(12) 1 calc R U P D 1
H15B H 0.4492 0.6950 0.0321 0.252 Uiso 0.604(12) 1 calc R U P D 1
H15C H 0.4854 0.7078 0.1101 0.252 Uiso 0.604(12) 1 calc R U P D 1
C18 C 0.6200(17) 0.7685(10) 0.0677(12) 0.137(10) Uani 0.604(12) 1 d . . P D 1
H18A H 0.6017 0.7908 0.1025 0.205 Uiso 0.604(12) 1 calc R U P D 1
H18B H 0.5884 0.7870 0.0245 0.205 Uiso 0.604(12) 1 calc R U P D 1
H18C H 0.6826 0.7748 0.0755 0.205 Uiso 0.604(12) 1 calc R U P D 1
C20 C 0.6030(18) 0.6454(13) -0.0132(9) 0.144(11) Uani 0.604(12) 1 d . . P D 1
H20A H 0.6575 0.6608 -0.0200 0.216 Uiso 0.604(12) 1 calc R U P D 1
H20B H 0.5537 0.6622 -0.0487 0.216 Uiso 0.604(12) 1 calc R U P D 1
H20C H 0.6019 0.5973 -0.0135 0.216 Uiso 0.604(12) 1 calc R U P D 1
C14 C 0.9181(7) 0.7406(7) 0.3363(9) 0.165(7) Uani 1 1 d . . . . .
H14A H 0.9330 0.7205 0.2989 0.248 Uiso 1 1 calc R U . C 1
H14B H 0.9390 0.7125 0.3754 0.248 Uiso 1 1 calc R U . C 1
H14C H 0.9456 0.7839 0.3456 0.248 Uiso 1 1 calc R U . C 1
F1 F 0.5308(15) 0.8145(5) 0.3063(6) 0.152(7) Uani 0.604(12) 1 d . . P D 1
C21A C 0.770(2) 0.608(2) 0.0367(18) 0.144(14) Uani 0.396(12) 1 d . U P D 2
H21D H 0.7790 0.5706 0.0107 0.216 Uiso 0.396(12) 1 calc R U P D 2
H21E H 0.8240 0.6335 0.0522 0.216 Uiso 0.396(12) 1 calc R U P D 2
H21F H 0.7240 0.6365 0.0090 0.216 Uiso 0.396(12) 1 calc R U P D 2
C19A C 0.695(3) 0.4910(18) 0.093(3) 0.152(18) Uani 0.396(12) 1 d . . P D 2
H19D H 0.6777 0.4736 0.1302 0.227 Uiso 0.396(12) 1 calc R U P D 2
H19E H 0.7412 0.4636 0.0851 0.227 Uiso 0.396(12) 1 calc R U P D 2
H19F H 0.6446 0.4907 0.0529 0.227 Uiso 0.396(12) 1 calc R U P D 2
C12A C 0.8689(17) 0.5928(13) 0.2191(13) 0.065(7) Uani 0.396(12) 1 d . U P D 2
Si2A Si 0.7356(10) 0.5779(7) 0.1112(6) 0.087(3) Uani 0.396(12) 1 d . . P D 2
Si1A Si 0.5720(12) 0.6483(9) 0.0604(10) 0.115(6) Uani 0.396(12) 1 d . . P D 2
C20A C 0.520(3) 0.593(2) -0.004(2) 0.157(15) Uani 0.396(12) 1 d . U P D 2
H20D H 0.5550 0.5879 -0.0346 0.235 Uiso 0.396(12) 1 calc R U P D 2
H20E H 0.4623 0.6103 -0.0284 0.235 Uiso 0.396(12) 1 calc R U P D 2
H20F H 0.5128 0.5500 0.0148 0.235 Uiso 0.396(12) 1 calc R U P D 2
C15A C 0.468(3) 0.6863(18) 0.083(2) 0.071(9) Uani 0.396(12) 1 d . U P D 2
H15D H 0.4247 0.7004 0.0423 0.107 Uiso 0.396(12) 1 calc R U P D 2
H15E H 0.4870 0.7242 0.1124 0.107 Uiso 0.396(12) 1 calc R U P D 2
H15F H 0.4432 0.6529 0.1053 0.107 Uiso 0.396(12) 1 calc R U P D 2
C18A C 0.609(3) 0.724(2) 0.014(2) 0.163(16) Uani 0.396(12) 1 d . U P D 2
H18D H 0.5981 0.7140 -0.0330 0.245 Uiso 0.396(12) 1 calc R U P D 2
H18E H 0.6716 0.7326 0.0340 0.245 Uiso 0.396(12) 1 calc R U P D 2
H18F H 0.5763 0.7638 0.0187 0.245 Uiso 0.396(12) 1 calc R U P D 2
F1A F 0.444(2) 0.8344(11) 0.3076(10) 0.154(11) Uani 0.396(12) 1 d . . P D 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sb Sb -0.5866 1.5461 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sn Sn -0.6537 1.4246 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N2 C1 N1 110.2(7) . .
N2 C1 C3 124.5(7) . .
N1 C1 C3 125.3(7) . .
N2 C1 Sn1 55.3(4) . .
N1 C1 Sn1 56.3(4) . .
C3 C1 Sn1 169.5(6) . .
N1 C2 C8 114.0(7) . .
N1 C2 C10 111.0(7) . .
C8 C2 C10 111.0(8) . .
N1 C2 C6 104.9(6) . .
C8 C2 C6 108.1(8) . .
C10 C2 C6 107.4(8) . .
C7 C3 C4 119.0(9) . .
C7 C3 C1 121.2(8) . .
C4 C3 C1 119.8(9) . .
C9 C4 C3 120.0(10) . .
C9 C4 H4 120.0 . .
C3 C4 H4 120.0 . .
C16 C5 N2 112.9(9) . .
C16 C5 C17 108.9(11) . .
N2 C5 C17 104.1(10) . .
C16 C5 C14 113.2(12) . .
N2 C5 C14 110.1(9) . .
C17 C5 C14 106.9(11) . .
C2 C6 H6A 109.5 . .
C2 C6 H6B 109.5 . .
H6A C6 H6B 109.5 . .
C2 C6 H6C 109.5 . .
H6A C6 H6C 109.5 . .
H6B C6 H6C 109.5 . .
C3 C7 C13 121.1(10) . .
C3 C7 H7 119.5 . .
C13 C7 H7 119.5 . .
C2 C8 H8A 109.5 . .
C2 C8 H8B 109.5 . .
H8A C8 H8B 109.5 . .
C2 C8 H8C 109.5 . .
H8A C8 H8C 109.5 . .
H8B C8 H8C 109.5 . .
C11 C9 C4 120.4(11) . .
C11 C9 H9 119.8 . .
C4 C9 H9 119.8 . .
C2 C10 H10A 109.5 . .
C2 C10 H10B 109.5 . .
H10A C10 H10B 109.5 . .
C2 C10 H10C 109.5 . .
H10A C10 H10C 109.5 . .
H10B C10 H10C 109.5 . .
C9 C11 C13 121.5(12) . .
C9 C11 H11 119.3 . .
C13 C11 H11 119.3 . .
Si2 C12 H12A 109.5 . .
Si2 C12 H12B 109.5 . .
H12A C12 H12B 109.5 . .
Si2 C12 H12C 109.5 . .
H12A C12 H12C 109.5 . .
H12B C12 H12C 109.5 . .
C5 C16 H16A 109.5 . .
C5 C16 H16B 109.5 . .
H16A C16 H16B 109.5 . .
C5 C16 H16C 109.5 . .
H16A C16 H16C 109.5 . .
H16B C16 H16C 109.5 . .
C5 C17 H17A 109.5 . .
C5 C17 H17B 109.5 . .
H17A C17 H17B 109.5 . .
C5 C17 H17C 109.5 . .
H17A C17 H17C 109.5 . .
H17B C17 H17C 109.5 . .
Si2 C19 H19A 109.5 . .
Si2 C19 H19B 109.5 . .
H19A C19 H19B 109.5 . .
Si2 C19 H19C 109.5 . .
H19A C19 H19C 109.5 . .
H19B C19 H19C 109.5 . .
N3 Sn1 N2 109.7(3) . .
N3 Sn1 N1 109.2(2) . .
N2 Sn1 N1 60.9(2) . .
N3 Sn1 C1 117.1(3) . .
N2 Sn1 C1 30.6(2) . .
N1 Sn1 C1 30.9(2) . .
N3 Sn1 Ag1 127.8(2) . .
N2 Sn1 Ag1 117.60(19) . .
N1 Sn1 Ag1 112.17(15) . .
C1 Sn1 Ag1 114.83(17) . .
Sn1 Ag1 Sn1 147.57(4) . 2_655
F1 Sb1 F1 76.4(8) . 2_655
F1 Sb1 F2 74.3(8) . .
F1 Sb1 F2 116.7(9) 2_655 .
F1 Sb1 F2 116.7(9) . 2_655
F1 Sb1 F2 74.3(8) 2_655 2_655
F2 Sb1 F2 166.9(9) . 2_655
F1 Sb1 F3 157.1(8) . 2_655
F1 Sb1 F3 100.8(5) 2_655 2_655
F2 Sb1 F3 87.3(5) . 2_655
F2 Sb1 F3 83.5(5) 2_655 2_655
F1 Sb1 F3 100.8(5) . .
F1 Sb1 F3 157.1(8) 2_655 .
F2 Sb1 F3 83.5(5) . .
F2 Sb1 F3 87.3(5) 2_655 .
F3 Sb1 F3 90.3(5) 2_655 .
F2 Sb1 F1A 109.4(10) . .
F2 Sb1 F1A 77.7(10) 2_655 .
F3 Sb1 F1A 158.5(11) 2_655 .
F3 Sb1 F1A 78.8(8) . .
F2 Sb1 F1A 77.7(10) . 2_655
F2 Sb1 F1A 109.4(10) 2_655 2_655
F3 Sb1 F1A 78.7(8) 2_655 2_655
F3 Sb1 F1A 158.5(11) . 2_655
F1A Sb1 F1A 117.1(17) . 2_655
C12 Si2 N3 122.5(9) . .
C12 Si2 C21 110.2(12) . .
N3 Si2 C21 111.6(8) . .
C12 Si2 C19 96.4(12) . .
N3 Si2 C19 105.2(9) . .
C21 Si2 C19 109.0(13) . .
C11 C13 C7 118.1(12) . .
C11 C13 H13 120.9 . .
C7 C13 H13 120.9 . .
C15 Si1 N3 113.9(13) . .
C15 Si1 C20 113.4(15) . .
N3 Si1 C20 111.5(8) . .
C15 Si1 C18 100.6(16) . .
N3 Si1 C18 112.4(10) . .
C20 Si1 C18 104.1(12) . .
C1 N1 C2 129.8(7) . .
C1 N1 Sn1 92.8(4) . .
C2 N1 Sn1 133.0(5) . .
Si1 N3 Si2 121.5(5) . .
Si2A N3 Si1A 106.0(10) . .
Si2A N3 Sn1 131.4(5) . .
Si1 N3 Sn1 113.9(4) . .
Si2 N3 Sn1 120.2(4) . .
Si1A N3 Sn1 116.0(7) . .
Si2 C21 H21A 109.5 . .
Si2 C21 H21B 109.5 . .
H21A C21 H21B 109.5 . .
Si2 C21 H21C 109.5 . .
H21A C21 H21C 109.5 . .
H21B C21 H21C 109.5 . .
C1 N2 C5 129.7(8) . .
C1 N2 Sn1 94.1(5) . .
C5 N2 Sn1 132.9(5) . .
Si1 C15 H15A 109.5 . .
Si1 C15 H15B 109.5 . .
H15A C15 H15B 109.5 . .
Si1 C15 H15C 109.5 . .
H15A C15 H15C 109.5 . .
H15B C15 H15C 109.5 . .
Si1 C18 H18A 109.5 . .
Si1 C18 H18B 109.5 . .
H18A C18 H18B 109.5 . .
Si1 C18 H18C 109.5 . .
H18A C18 H18C 109.5 . .
H18B C18 H18C 109.5 . .
Si1 C20 H20A 109.5 . .
Si1 C20 H20B 109.5 . .
H20A C20 H20B 109.5 . .
Si1 C20 H20C 109.5 . .
H20A C20 H20C 109.5 . .
H20B C20 H20C 109.5 . .
C5 C14 H14A 109.5 . .
C5 C14 H14B 109.5 . .
H14A C14 H14B 109.5 . .
C5 C14 H14C 109.5 . .
H14A C14 H14C 109.5 . .
H14B C14 H14C 109.5 . .
Si2A C21A H21D 109.5 . .
Si2A C21A H21E 109.5 . .
H21D C21A H21E 109.5 . .
Si2A C21A H21F 109.5 . .
H21D C21A H21F 109.5 . .
H21E C21A H21F 109.5 . .
Si2A C19A H19D 109.5 . .
Si2A C19A H19E 109.5 . .
H19D C19A H19E 109.5 . .
Si2A C19A H19F 109.5 . .
H19D C19A H19F 109.5 . .
H19E C19A H19F 109.5 . .
N3 Si2A C19A 118.3(14) . .
N3 Si2A C21A 111.9(14) . .
C19A Si2A C21A 107(2) . .
C20A Si1A N3 129.9(18) . .
C20A Si1A C18A 105(2) . .
N3 Si1A C18A 103.3(15) . .
C20A Si1A C15A 101(2) . .
N3 Si1A C15A 113.0(16) . .
C18A Si1A C15A 102(2) . .
Si1A C20A H20D 109.5 . .
Si1A C20A H20E 109.5 . .
H20D C20A H20E 109.5 . .
Si1A C20A H20F 109.5 . .
H20D C20A H20F 109.5 . .
H20E C20A H20F 109.5 . .
Si1A C15A H15D 109.5 . .
Si1A C15A H15E 109.5 . .
H15D C15A H15E 109.5 . .
Si1A C15A H15F 109.5 . .
H15D C15A H15F 109.5 . .
H15E C15A H15F 109.5 . .
Si1A C18A H18D 109.5 . .
Si1A C18A H18E 109.5 . .
H18D C18A H18E 109.5 . .
Si1A C18A H18F 109.5 . .
H18D C18A H18F 109.5 . .
H18E C18A H18F 109.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C1 N2 1.333(9) .
C1 N1 1.342(9) .
C1 C3 1.488(12) .
C1 Sn1 2.613(8) .
C2 N1 1.471(9) .
C2 C8 1.492(11) .
C2 C10 1.512(12) .
C2 C6 1.527(12) .
C3 C7 1.383(13) .
C3 C4 1.394(11) .
C4 C9 1.383(14) .
C4 H4 0.9300 .
C5 C16 1.476(18) .
C5 N2 1.497(12) .
C5 C17 1.498(15) .
C5 C14 1.558(14) .
C6 H6A 0.9600 .
C6 H6B 0.9600 .
C6 H6C 0.9600 .
C7 C13 1.399(15) .
C7 H7 0.9300 .
C8 H8A 0.9600 .
C8 H8B 0.9600 .
C8 H8C 0.9600 .
C9 C11 1.358(16) .
C9 H9 0.9300 .
C10 H10A 0.9600 .
C10 H10B 0.9600 .
C10 H10C 0.9600 .
C11 C13 1.386(17) .
C11 H11 0.9300 .
C12 Si2 1.50(2) .
C12 H12A 0.9600 .
C12 H12B 0.9600 .
C12 H12C 0.9600 .
C16 H16A 0.9600 .
C16 H16B 0.9600 .
C16 H16C 0.9600 .
C17 H17A 0.9600 .
C17 H17B 0.9600 .
C17 H17C 0.9600 .
C19 Si2 1.91(2) .
C19 H19A 0.9600 .
C19 H19B 0.9600 .
C19 H19C 0.9600 .
Sn1 N3 2.036(7) .
Sn1 N2 2.153(7) .
Sn1 N1 2.176(6) .
Sn1 Ag1 2.6217(8) .
Ag1 Sn1 2.6217(8) 2_655
Sb1 F1 1.816(11) .
Sb1 F1 1.816(11) 2_655
Sb1 F2 1.827(10) .
Sb1 F2 1.827(10) 2_655
Sb1 F3 1.853(7) 2_655
Sb1 F3 1.853(7) .
Sb1 F1A 1.973(19) .
Sb1 F1A 1.973(19) 2_655
Si2 N3 1.838(9) .
Si2 C21 1.88(2) .
C13 H13 0.9300 .
Si1 C15 1.72(3) .
Si1 N3 1.725(11) .
Si1 C20 1.84(2) .
Si1 C18 1.88(2) .
N3 Si2A 1.722(12) .
N3 Si1A 1.85(2) .
C21 H21A 0.9600 .
C21 H21B 0.9600 .
C21 H21C 0.9600 .
C15 H15A 0.9600 .
C15 H15B 0.9600 .
C15 H15C 0.9600 .
C18 H18A 0.9600 .
C18 H18B 0.9600 .
C18 H18C 0.9600 .
C20 H20A 0.9600 .
C20 H20B 0.9600 .
C20 H20C 0.9600 .
C14 H14A 0.9600 .
C14 H14B 0.9600 .
C14 H14C 0.9600 .
C21A Si2A 1.88(4) .
C21A H21D 0.9600 .
C21A H21E 0.9600 .
C21A H21F 0.9600 .
C19A Si2A 1.85(4) .
C19A H19D 0.9600 .
C19A H19E 0.9600 .
C19A H19F 0.9600 .
Si1A C20A 1.74(4) .
Si1A C18A 1.98(4) .
Si1A C15A 1.98(4) .
C20A H20D 0.9600 .
C20A H20E 0.9600 .
C20A H20F 0.9600 .
C15A H15D 0.9600 .
C15A H15E 0.9600 .
C15A H15F 0.9600 .
C18A H18D 0.9600 .
C18A H18E 0.9600 .
C18A H18F 0.9600 .
