#------------------------------------------------------------------------------
#$Date: 2017-09-05 05:39:27 +0300 (Tue, 05 Sep 2017) $
#$Revision: 200164 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/04/41/7044110.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7044110
loop_
_publ_author_name
'CANAC, Yves'
'Lugan, Noël'
'Benaissa, Idir'
'Taakili, Rachid'
_publ_section_title
;
 A Convenient Access to N-Phosphonio-Substituted NHC Metal Complexes [M =
 Ag(I), Rh(I), Pd(II)]
;
_journal_name_full               'Dalton Trans.'
_journal_paper_doi               10.1039/C7DT02759A
_journal_year                    2017
_chemical_formula_moiety         'C66 H68 Ag4 Br6 N4 P2, 2(C2 H3 N)'
_chemical_formula_sum            'C70 H74 Ag4 Br6 N6 P2'
_chemical_formula_weight         1972.17
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_audit_creation_date             2016-06-20T12:56:48-00:00
_audit_creation_method           'WinGX routine CIF_UPDATE'
_audit_update_record
;
2017-06-26 deposited with the CCDC.
2017-09-04 downloaded from the CCDC.
;
_cell_angle_alpha                92.2450(10)
_cell_angle_beta                 93.8830(10)
_cell_angle_gamma                102.0020(10)
_cell_formula_units_Z            1
_cell_length_a                   9.7558(4)
_cell_length_b                   12.6715(5)
_cell_length_c                   15.0828(6)
_cell_measurement_reflns_used    9999
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      36.29
_cell_measurement_theta_min      2.41
_cell_measurement_wavelength     0.71073
_cell_volume                     1816.89(13)
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Bruker APEX II'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_probe          x-ray
_diffrn_radiation_source         'Incoatec I\mS Microsource '
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0381
_diffrn_reflns_av_unetI/netI     0.0188
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.999
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            69328
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.999
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         26.37
_diffrn_reflns_theta_min         2.409
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    4.449
_exptl_absorpt_correction_T_max  0.7462
_exptl_absorpt_correction_T_min  0.6579
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
'SADABS, Sheldrick, Bruker, 2000'
;
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.803
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             964
_exptl_crystal_size_max          0.15
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.08
_refine_diff_density_max         1.086
_refine_diff_density_min         -0.624
_refine_diff_density_rms         0.07
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.045
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     401
_refine_ls_number_reflns         7411
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.045
_refine_ls_R_factor_all          0.0247
_refine_ls_R_factor_gt           0.0199
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0162P)²+2.2451P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0444
_refine_ls_wR_factor_ref         0.0461
_reflns_Friedel_coverage         0
_reflns_number_gt                6712
_reflns_number_total             7411
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c7dt02759a2.cif
_cod_data_source_block           7
_cod_database_code               7044110
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
C1 C 0.1208(2) 0.14819(16) 0.22372(14) 0.0130(4) Uani 1 1 d . .
C2 C -0.0468(2) 0.19443(18) 0.13059(16) 0.0182(5) Uani 1 1 d . .
H2 H -0.0893 0.2199 0.0811 0.022 Uiso 1 1 calc R U
C3 C -0.1094(2) 0.15603(18) 0.20277(16) 0.0183(5) Uani 1 1 d . .
H3 H -0.2038 0.149 0.2129 0.022 Uiso 1 1 calc R U
C4 C -0.0322(2) 0.07365(17) 0.34142(14) 0.0151(4) Uani 1 1 d . .
H4A H -0.0927 0.1083 0.3758 0.018 Uiso 1 1 calc R U
H4B H 0.0558 0.0781 0.3769 0.018 Uiso 1 1 calc R U
C5 C -0.1026(2) -0.04483(17) 0.31918(14) 0.0151(4) Uani 1 1 d . .
H5A H -0.0572 -0.0733 0.2711 0.018 Uiso 1 1 calc R U
H5B H -0.2006 -0.0501 0.2993 0.018 Uiso 1 1 calc R U
C6 C -0.0930(2) -0.11216(16) 0.40079(14) 0.0123(4) Uani 1 1 d . .
H6A H -0.1554 -0.0932 0.4432 0.015 Uiso 1 1 calc R U
H6B H 0.002 -0.0921 0.4287 0.015 Uiso 1 1 calc R U
C7 C 0.5774(3) 0.3055(3) 0.1712(2) 0.0460(8) Uani 1 1 d . .
H7A H 0.5018 0.3435 0.1686 0.069 Uiso 1 1 calc R U
H7B H 0.6237 0.3151 0.23 0.069 Uiso 1 1 calc R U
H7C H 0.5405 0.23 0.1569 0.069 Uiso 1 1 calc R U
C8 C 0.6781(3) 0.34825(19) 0.10705(15) 0.0199(5) Uani 1 1 d . .
C11 C 0.1953(2) 0.21818(18) 0.07932(14) 0.0161(4) Uani 1 1 d . .
C12 C 0.2403(2) 0.32668(19) 0.06323(15) 0.0191(5) Uani 1 1 d . .
C13 C 0.3346(3) 0.3528(2) -0.00206(16) 0.0232(5) Uani 1 1 d . .
H13 H 0.3664 0.4249 -0.0136 0.028 Uiso 1 1 calc R U
C14 C 0.3824(3) 0.2738(2) -0.05031(15) 0.0252(5) Uani 1 1 d . .
C15 C 0.3351(3) 0.1664(2) -0.03191(16) 0.0261(5) Uani 1 1 d . .
H15 H 0.3673 0.1131 -0.0636 0.031 Uiso 1 1 calc R U
C16 C 0.2407(2) 0.1358(2) 0.03261(15) 0.0213(5) Uani 1 1 d . .
C17 C 0.1914(3) 0.4147(2) 0.11469(18) 0.0288(6) Uani 1 1 d . .
H17A H 0.0924 0.4083 0.1011 0.043 Uiso 1 1 calc R U
H17B H 0.2411 0.484 0.0984 0.043 Uiso 1 1 calc R U
H17C H 0.2098 0.4078 0.1773 0.043 Uiso 1 1 calc R U
C18 C 0.4836(3) 0.3042(3) -0.12080(17) 0.0348(7) Uani 1 1 d . .
H18A H 0.4564 0.3601 -0.1546 0.052 Uiso 1 1 calc R U
H18B H 0.4822 0.242 -0.1596 0.052 Uiso 1 1 calc R U
H18C H 0.5768 0.3298 -0.093 0.052 Uiso 1 1 calc R U
C19 C 0.1932(3) 0.0182(2) 0.05034(18) 0.0287(6) Uani 1 1 d . .
H19A H 0.1995 -0.0253 -0.0021 0.043 Uiso 1 1 calc R U
H19B H 0.0975 0.0049 0.066 0.043 Uiso 1 1 calc R U
H19C H 0.2521 0.0002 0.0985 0.043 Uiso 1 1 calc R U
C21 C -0.3225(2) -0.30385(17) 0.36417(14) 0.0122(4) Uani 1 1 d . .
C22 C -0.3808(2) -0.41458(18) 0.35772(16) 0.0179(5) Uani 1 1 d . .
H22 H -0.3228 -0.4642 0.3604 0.022 Uiso 1 1 calc R U
C23 C -0.5256(2) -0.45003(18) 0.34732(16) 0.0211(5) Uani 1 1 d . .
H23 H -0.5648 -0.5236 0.3418 0.025 Uiso 1 1 calc R U
C24 C -0.6118(2) -0.37580(19) 0.34508(15) 0.0189(5) Uani 1 1 d . .
H24 H -0.7088 -0.4 0.3376 0.023 Uiso 1 1 calc R U
C25 C -0.5549(2) -0.26617(18) 0.35387(14) 0.0157(4) Uani 1 1 d . .
H25 H -0.6136 -0.2169 0.3532 0.019 Uiso 1 1 calc R U
C26 C -0.4103(2) -0.22974(17) 0.36360(14) 0.0133(4) Uani 1 1 d . .
H26 H -0.3718 -0.156 0.3697 0.016 Uiso 1 1 calc R U
C31 C -0.0485(2) -0.28582(17) 0.28286(14) 0.0141(4) Uani 1 1 d . .
C32 C -0.1133(2) -0.36247(18) 0.21593(15) 0.0187(5) Uani 1 1 d . .
H32 H -0.2037 -0.4021 0.2209 0.022 Uiso 1 1 calc R U
C33 C -0.0419(3) -0.3793(2) 0.14174(16) 0.0236(5) Uani 1 1 d . .
H33 H -0.0846 -0.4307 0.0972 0.028 Uiso 1 1 calc R U
C34 C 0.0920(3) -0.3201(2) 0.13375(16) 0.0223(5) Uani 1 1 d . .
H34 H 0.1389 -0.3318 0.0838 0.027 Uiso 1 1 calc R U
C35 C 0.1570(2) -0.24336(19) 0.19994(15) 0.0201(5) Uani 1 1 d . .
H35 H 0.2471 -0.2033 0.1942 0.024 Uiso 1 1 calc R U
C36 C 0.0877(2) -0.22660(18) 0.27428(15) 0.0166(5) Uani 1 1 d . .
H36 H 0.1317 -0.1757 0.3189 0.02 Uiso 1 1 calc R U
C41 C -0.0705(2) -0.31585(16) 0.47503(14) 0.0132(4) Uani 1 1 d . .
C42 C -0.1549(2) -0.33624(18) 0.54614(15) 0.0179(5) Uani 1 1 d . .
H42 H -0.2462 -0.3248 0.5417 0.022 Uiso 1 1 calc R U
C43 C -0.1014(3) -0.37361(19) 0.62344(16) 0.0226(5) Uani 1 1 d . .
H43 H -0.1571 -0.3871 0.6711 0.027 Uiso 1 1 calc R U
C44 C 0.0339(3) -0.39094(19) 0.63018(17) 0.0253(5) Uani 1 1 d . .
H44 H 0.0689 -0.4161 0.6823 0.03 Uiso 1 1 calc R U
C45 C 0.1176(3) -0.3710(2) 0.55986(17) 0.0254(5) Uani 1 1 d . .
H45 H 0.2086 -0.383 0.5646 0.03 Uiso 1 1 calc R U
C46 C 0.0660(2) -0.33321(18) 0.48218(16) 0.0200(5) Uani 1 1 d . .
H46 H 0.1224 -0.3195 0.4349 0.024 Uiso 1 1 calc R U
N1 N 0.09383(19) 0.18880(14) 0.14417(12) 0.0142(4) Uani 1 1 d . .
N2 N -0.00548(19) 0.12894(14) 0.25914(12) 0.0142(4) Uani 1 1 d . .
N3 N 0.7554(2) 0.38075(19) 0.05811(15) 0.0313(5) Uani 1 1 d . .
P1 P -0.13591(5) -0.25624(4) 0.37914(4) 0.01086(11) Uani 1 1 d . .
Br1 Br 0.49390(2) 0.27597(2) 0.39564(2) 0.01967(5) Uani 1 1 d . .
Br2 Br 0.50732(2) 0.00894(2) 0.23650(2) 0.01912(5) Uani 1 1 d . .
Ag2 Ag 0.53679(2) 0.07615(2) 0.41038(2) 0.02398(5) Uani 1 1 d . .
Br3 Br 0.71659(2) 0.03939(2) 0.53544(2) 0.01715(5) Uani 1 1 d . .
Ag1 Ag 0.31900(2) 0.12878(2) 0.28058(2) 0.02321(5) Uani 1 1 d . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0 0 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Br Br -0.2901 2.4595 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N1 C1 N2 103.77(18) . .
N1 C1 Ag1 127.16(15) . .
N2 C1 Ag1 128.99(15) . .
C3 C2 N1 106.70(19) . .
C3 C2 H2 126.7 . .
N1 C2 H2 126.7 . .
C2 C3 N2 106.34(19) . .
C2 C3 H3 126.8 . .
N2 C3 H3 126.8 . .
N2 C4 C5 109.58(17) . .
N2 C4 H4A 109.8 . .
C5 C4 H4A 109.8 . .
N2 C4 H4B 109.8 . .
C5 C4 H4B 109.8 . .
H4A C4 H4B 108.2 . .
C4 C5 C6 110.76(17) . .
C4 C5 H5A 109.5 . .
C6 C5 H5A 109.5 . .
C4 C5 H5B 109.5 . .
C6 C5 H5B 109.5 . .
H5A C5 H5B 108.1 . .
C5 C6 P1 115.61(15) . .
C5 C6 H6A 108.4 . .
P1 C6 H6A 108.4 . .
C5 C6 H6B 108.4 . .
P1 C6 H6B 108.4 . .
H6A C6 H6B 107.4 . .
C8 C7 H7A 109.5 . .
C8 C7 H7B 109.5 . .
H7A C7 H7B 109.5 . .
C8 C7 H7C 109.5 . .
H7A C7 H7C 109.5 . .
H7B C7 H7C 109.5 . .
N3 C8 C7 179.8(3) . .
C12 C11 C16 122.5(2) . .
C12 C11 N1 118.9(2) . .
C16 C11 N1 118.6(2) . .
C11 C12 C13 117.8(2) . .
C11 C12 C17 121.9(2) . .
C13 C12 C17 120.3(2) . .
C14 C13 C12 121.8(2) . .
C14 C13 H13 119.1 . .
C12 C13 H13 119.1 . .
C15 C14 C13 118.5(2) . .
C15 C14 C18 120.8(2) . .
C13 C14 C18 120.7(2) . .
C14 C15 C16 122.0(2) . .
C14 C15 H15 119 . .
C16 C15 H15 119 . .
C15 C16 C11 117.4(2) . .
C15 C16 C19 120.0(2) . .
C11 C16 C19 122.7(2) . .
C12 C17 H17A 109.5 . .
C12 C17 H17B 109.5 . .
H17A C17 H17B 109.5 . .
C12 C17 H17C 109.5 . .
H17A C17 H17C 109.5 . .
H17B C17 H17C 109.5 . .
C14 C18 H18A 109.5 . .
C14 C18 H18B 109.5 . .
H18A C18 H18B 109.5 . .
C14 C18 H18C 109.5 . .
H18A C18 H18C 109.5 . .
H18B C18 H18C 109.5 . .
C16 C19 H19A 109.5 . .
C16 C19 H19B 109.5 . .
H19A C19 H19B 109.5 . .
C16 C19 H19C 109.5 . .
H19A C19 H19C 109.5 . .
H19B C19 H19C 109.5 . .
C26 C21 C22 119.88(19) . .
C26 C21 P1 119.64(16) . .
C22 C21 P1 120.39(16) . .
C23 C22 C21 119.6(2) . .
C23 C22 H22 120.2 . .
C21 C22 H22 120.2 . .
C22 C23 C24 120.0(2) . .
C22 C23 H23 120 . .
C24 C23 H23 120 . .
C25 C24 C23 120.6(2) . .
C25 C24 H24 119.7 . .
C23 C24 H24 119.7 . .
C24 C25 C26 119.9(2) . .
C24 C25 H25 120.1 . .
C26 C25 H25 120.1 . .
C25 C26 C21 119.9(2) . .
C25 C26 H26 120 . .
C21 C26 H26 120 . .
C32 C31 C36 119.5(2) . .
C32 C31 P1 122.30(17) . .
C36 C31 P1 118.18(16) . .
C33 C32 C31 119.6(2) . .
C33 C32 H32 120.2 . .
C31 C32 H32 120.2 . .
C34 C33 C32 120.4(2) . .
C34 C33 H33 119.8 . .
C32 C33 H33 119.8 . .
C33 C34 C35 120.3(2) . .
C33 C34 H34 119.8 . .
C35 C34 H34 119.8 . .
C36 C35 C34 119.8(2) . .
C36 C35 H35 120.1 . .
C34 C35 H35 120.1 . .
C35 C36 C31 120.3(2) . .
C35 C36 H36 119.8 . .
C31 C36 H36 119.8 . .
C46 C41 C42 119.9(2) . .
C46 C41 P1 121.05(17) . .
C42 C41 P1 118.78(16) . .
C43 C42 C41 119.4(2) . .
C43 C42 H42 120.3 . .
C41 C42 H42 120.3 . .
C44 C43 C42 120.4(2) . .
C44 C43 H43 119.8 . .
C42 C43 H43 119.8 . .
C43 C44 C45 120.3(2) . .
C43 C44 H44 119.9 . .
C45 C44 H44 119.9 . .
C44 C45 C46 120.0(2) . .
C44 C45 H45 120 . .
C46 C45 H45 120 . .
C45 C46 C41 119.9(2) . .
C45 C46 H46 120.1 . .
C41 C46 H46 120.1 . .
C1 N1 C2 111.37(18) . .
C1 N1 C11 124.94(18) . .
C2 N1 C11 123.64(18) . .
C1 N2 C3 111.82(18) . .
C1 N2 C4 123.80(18) . .
C3 N2 C4 123.95(18) . .
C21 P1 C41 108.53(10) . .
C21 P1 C6 110.43(10) . .
C41 P1 C6 107.37(10) . .
C21 P1 C31 112.61(10) . .
C41 P1 C31 110.49(10) . .
C6 P1 C31 107.29(10) . .
Ag2 Br1 Ag1 67.280(8) . .
Ag2 Br2 Ag1 66.904(8) . .
Br3 Ag2 Br1 119.324(10) . .
Br3 Ag2 Br2 128.671(10) . .
Br1 Ag2 Br2 99.600(9) . .
Br3 Ag2 Br3 101.695(9) . 2_656
Br1 Ag2 Br3 103.911(9) . 2_656
Br2 Ag2 Br3 99.596(9) . 2_656
Br3 Ag2 Ag1 174.582(10) . .
Br1 Ag2 Ag1 57.296(7) . .
Br2 Ag2 Ag1 56.734(7) . .
Br3 Ag2 Ag1 75.915(8) 2_656 .
Ag2 Br3 Ag2 78.305(9) . 2_656
C1 Ag1 Br2 135.02(6) . .
C1 Ag1 Br1 124.64(6) . .
Br2 Ag1 Br1 97.867(9) . .
C1 Ag1 Ag2 160.53(6) . .
Br2 Ag1 Ag2 56.362(7) . .
Br1 Ag1 Ag2 55.424(7) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C1 N1 1.355(3) .
C1 N2 1.355(3) .
C1 Ag1 2.127(2) .
C2 C3 1.343(3) .
C2 N1 1.390(3) .
C2 H2 0.93 .
C3 N2 1.386(3) .
C3 H3 0.93 .
C4 N2 1.461(3) .
C4 C5 1.529(3) .
C4 H4A 0.97 .
C4 H4B 0.97 .
C5 C6 1.534(3) .
C5 H5A 0.97 .
C5 H5B 0.97 .
C6 P1 1.798(2) .
C6 H6A 0.97 .
C6 H6B 0.97 .
C7 C8 1.464(4) .
C7 H7A 0.96 .
C7 H7B 0.96 .
C7 H7C 0.96 .
C8 N3 1.120(3) .
C11 C12 1.390(3) .
C11 C16 1.399(3) .
C11 N1 1.443(3) .
C12 C13 1.396(3) .
C12 C17 1.509(3) .
C13 C14 1.390(4) .
C13 H13 0.93 .
C14 C15 1.388(4) .
C14 C18 1.506(3) .
C15 C16 1.396(4) .
C15 H15 0.93 .
C16 C19 1.506(4) .
C17 H17A 0.96 .
C17 H17B 0.96 .
C17 H17C 0.96 .
C18 H18A 0.96 .
C18 H18B 0.96 .
C18 H18C 0.96 .
C19 H19A 0.96 .
C19 H19B 0.96 .
C19 H19C 0.96 .
C21 C26 1.396(3) .
C21 C22 1.397(3) .
C21 P1 1.791(2) .
C22 C23 1.386(3) .
C22 H22 0.93 .
C23 C24 1.386(3) .
C23 H23 0.93 .
C24 C25 1.382(3) .
C24 H24 0.93 .
C25 C26 1.386(3) .
C25 H25 0.93 .
C26 H26 0.93 .
C31 C32 1.394(3) .
C31 C36 1.401(3) .
C31 P1 1.799(2) .
C32 C33 1.390(3) .
C32 H32 0.93 .
C33 C34 1.379(4) .
C33 H33 0.93 .
C34 C35 1.388(3) .
C34 H34 0.93 .
C35 C36 1.379(3) .
C35 H35 0.93 .
C36 H36 0.93 .
C41 C46 1.392(3) .
C41 C42 1.395(3) .
C41 P1 1.797(2) .
C42 C43 1.385(3) .
C42 H42 0.93 .
C43 C44 1.381(4) .
C43 H43 0.93 .
C44 C45 1.381(4) .
C44 H44 0.93 .
C45 C46 1.386(3) .
C45 H45 0.93 .
C46 H46 0.93 .
Br1 Ag2 2.6660(3) .
Br1 Ag1 2.7246(3) .
Br2 Ag2 2.7032(3) .
Br2 Ag1 2.7148(3) .
Ag2 Br3 2.6101(3) .
Ag2 Br3 2.7900(3) 2_656
Ag2 Ag1 2.9866(3) .
Br3 Ag2 2.7900(3) 2_656
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
N1 C2 C3 N2 0.6(2)
N2 C4 C5 C6 163.34(17)
C4 C5 C6 P1 -166.85(15)
C16 C11 C12 C13 -0.2(3)
N1 C11 C12 C13 -177.8(2)
C16 C11 C12 C17 -179.4(2)
N1 C11 C12 C17 3.0(3)
C11 C12 C13 C14 0.3(3)
C17 C12 C13 C14 179.6(2)
C12 C13 C14 C15 -0.5(4)
C12 C13 C14 C18 179.6(2)
C13 C14 C15 C16 0.6(4)
C18 C14 C15 C16 -179.6(2)
C14 C15 C16 C11 -0.4(3)
C14 C15 C16 C19 -179.7(2)
C12 C11 C16 C15 0.2(3)
N1 C11 C16 C15 177.8(2)
C12 C11 C16 C19 179.5(2)
N1 C11 C16 C19 -3.0(3)
C26 C21 C22 C23 2.5(3)
P1 C21 C22 C23 179.15(18)
C21 C22 C23 C24 -1.2(4)
C22 C23 C24 C25 -0.5(4)
C23 C24 C25 C26 1.0(3)
C24 C25 C26 C21 0.2(3)
C22 C21 C26 C25 -2.0(3)
P1 C21 C26 C25 -178.68(16)
C36 C31 C32 C33 0.1(3)
P1 C31 C32 C33 177.92(18)
C31 C32 C33 C34 -0.4(4)
C32 C33 C34 C35 0.2(4)
C33 C34 C35 C36 0.4(4)
C34 C35 C36 C31 -0.7(3)
C32 C31 C36 C35 0.4(3)
P1 C31 C36 C35 -177.46(17)
C46 C41 C42 C43 0.1(3)
P1 C41 C42 C43 -174.59(17)
C41 C42 C43 C44 -0.2(3)
C42 C43 C44 C45 0.1(4)
C43 C44 C45 C46 0.2(4)
C44 C45 C46 C41 -0.3(4)
C42 C41 C46 C45 0.2(3)
P1 C41 C46 C45 174.72(18)
N2 C1 N1 C2 -0.1(2)
Ag1 C1 N1 C2 -177.00(15)
N2 C1 N1 C11 -177.40(19)
Ag1 C1 N1 C11 5.7(3)
C3 C2 N1 C1 -0.4(3)
C3 C2 N1 C11 177.0(2)
C12 C11 N1 C1 -111.3(2)
C16 C11 N1 C1 71.0(3)
C12 C11 N1 C2 71.7(3)
C16 C11 N1 C2 -106.0(2)
N1 C1 N2 C3 0.5(2)
Ag1 C1 N2 C3 177.33(15)
N1 C1 N2 C4 173.20(18)
Ag1 C1 N2 C4 -9.9(3)
C2 C3 N2 C1 -0.7(3)
C2 C3 N2 C4 -173.42(19)
C5 C4 N2 C1 -99.0(2)
C5 C4 N2 C3 72.9(3)
C26 C21 P1 C41 122.20(17)
C22 C21 P1 C41 -54.5(2)
C26 C21 P1 C6 4.8(2)
C22 C21 P1 C6 -171.91(17)
C26 C21 P1 C31 -115.15(18)
C22 C21 P1 C31 68.2(2)
C46 C41 P1 C21 152.12(18)
C42 C41 P1 C21 -33.3(2)
C46 C41 P1 C6 -88.51(19)
C42 C41 P1 C6 86.08(19)
C46 C41 P1 C31 28.2(2)
C42 C41 P1 C31 -157.22(17)
C5 C6 P1 C21 -77.92(18)
C5 C6 P1 C41 163.92(16)
C5 C6 P1 C31 45.14(18)
C32 C31 P1 C21 -16.9(2)
C36 C31 P1 C21 160.91(17)
C32 C31 P1 C41 104.62(19)
C36 C31 P1 C41 -77.55(19)
C32 C31 P1 C6 -138.62(18)
C36 C31 P1 C6 39.20(19)
