#------------------------------------------------------------------------------
#$Date: 2017-09-15 05:39:13 +0300 (Fri, 15 Sep 2017) $
#$Revision: 200917 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/04/42/7044236.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7044236
loop_
_publ_author_name
'Ferrer, Montserrat'
'Giménez, Leticia'
'Gutiérrez, Albert'
'Lima, J. C. Carlos'
'Rodriguez, Laura'
'Martinez, Manuel'
'Martín, Avelino'
'Puttreddy, Rakesh'
'Rissanen, Kari'
_publ_section_title
;
 Polypyridyl-functionalizated alkynyl gold(I) metallaligands supported by
 tri- and tetradentate phosphanes
;
_journal_name_full               'Dalton Trans.'
_journal_paper_doi               10.1039/C7DT02732J
_journal_year                    2017
_chemical_formula_moiety         'C102 H70 Au4 N8 P4'
_chemical_formula_sum            'C102 H70 Au4 N8 P4'
_chemical_formula_weight         2319.4
_chemical_properties_physical    ', Air-sensitive,Light-sensitive'
_space_group_IT_number           60
_symmetry_cell_setting           orthorhombic
_symmetry_Int_Tables_number      60
_symmetry_space_group_name_Hall  '-P 2n 2ab'
_symmetry_space_group_name_H-M   'P b c n'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_conform_dict_location     ftp://ftp.iucr.org/pub/cif_core.dic
_audit_conform_dict_name         cif_core.dic
_audit_conform_dict_version      2.4.3
_audit_creation_date             2017-05-31T16:01:26-00:00
_audit_creation_method           'WinGX routine CIF_UPDATE'
_audit_update_record
;
2017-06-29 deposited with the CCDC.
2017-09-13 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   18.968(6)
_cell_length_b                   26.452(8)
_cell_length_c                   20.5749(13)
_cell_measurement_reflns_used    95
_cell_measurement_temperature    200(2)
_cell_measurement_theta_max      20
_cell_measurement_theta_min      3
_cell_measurement_wavelength     0.71073
_cell_volume                     10323(5)
_computing_cell_refinement
'Dirax/lsq (Duisenberg & Schreurs, 1989-2000)'
_computing_data_collection       'Collect (Bruker AXS BV, 1997-2004)'
_computing_data_reduction        'EvalCCD (Duisenberg & Schreurs 1990-2000)'
_computing_molecular_graphics    'DIAMOND (Brandenburg, 2006)'
_computing_publication_material  'WinGX publication routines (Farrugia, 2012)'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_structure_solution    'SHELXS-2013 (Sheldrick, 2008)'
_diffrn_ambient_temperature      200(2)
_diffrn_detector                 'CCD plate'
_diffrn_detector_area_resol_mean 9
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device       '95mm CCD camera on κ-goniostat'
_diffrn_measurement_device_type  KappaCCD
_diffrn_measurement_method       'CCD rotation images, thick slices'
_diffrn_orient_matrix_UB_11      0.01
_diffrn_orient_matrix_UB_12      0
_diffrn_orient_matrix_UB_13      0
_diffrn_orient_matrix_UB_21      0
_diffrn_orient_matrix_UB_22      0.01
_diffrn_orient_matrix_UB_23      0
_diffrn_orient_matrix_UB_31      0
_diffrn_orient_matrix_UB_32      0
_diffrn_orient_matrix_UB_33      0.01
_diffrn_radiation_monochromator  'horizonally mounted graphite crystal'
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.1839
_diffrn_reflns_av_unetI/netI     0.0599
_diffrn_reflns_Laue_measured_fraction_full 0.997
_diffrn_reflns_Laue_measured_fraction_max 0.997
_diffrn_reflns_limit_h_max       20
_diffrn_reflns_limit_h_min       -20
_diffrn_reflns_limit_k_max       29
_diffrn_reflns_limit_k_min       -28
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_number            89602
_diffrn_reflns_point_group_measured_fraction_full 0.997
_diffrn_reflns_point_group_measured_fraction_max 0.997
_diffrn_reflns_theta_full        23.009
_diffrn_reflns_theta_max         23.009
_diffrn_reflns_theta_min         3.021
_diffrn_source                   'Enraf Nonius FR590'
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    5.774
_exptl_absorpt_correction_T_max  0.633
_exptl_absorpt_correction_T_min  0.277
_exptl_absorpt_correction_type   analytical
_exptl_absorpt_process_details
;
(see. N.W. Alcock (1970). Cryst. Computing, p271)
;
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.492
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             4456
_exptl_crystal_preparation       ', Luminescent'
_exptl_crystal_size_max          0.3
_exptl_crystal_size_mid          0.17
_exptl_crystal_size_min          0.13
_refine_diff_density_max         3.139
_refine_diff_density_min         -1.577
_refine_diff_density_rms         0.217
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.13
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_constraints    0
_refine_ls_number_parameters     196
_refine_ls_number_reflns         7185
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.13
_refine_ls_R_factor_all          0.1264
_refine_ls_R_factor_gt           0.0916
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0750P)²+322.2655P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2216
_refine_ls_wR_factor_ref         0.2476
_reflns_Friedel_coverage         0
_reflns_number_gt                5183
_reflns_number_total             7185
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c7dt02732j2.cif
_cod_data_source_block           shelx
_cod_database_code               7044236
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, -y+1/2, z+1/2'
'x+1/2, -y+1/2, -z'
'-x, y, -z+1/2'
'-x, -y, -z'
'x-1/2, y-1/2, -z-1/2'
'-x-1/2, y-1/2, z'
'x, -y, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
C1 C 0.9466(11) 0.3921(7) 0.7039(9) 0.060(6) Uani 1 1 d . .
H1 H 0.911 0.392 0.6714 0.073 Uiso 1 1 calc R U
C2 C 0.9708(11) 0.3457(7) 0.7276(10) 0.064(6) Uani 1 1 d . .
C3 C 0.9725(11) 0.4397(7) 0.7260(10) 0.061(5) Uani 1 1 d . .
C4 C 0.9091(11) 0.1602(8) 0.8275(12) 0.070(6) Uani 1 1 d . .
C5 C 0.9066(13) 0.1296(9) 0.8654(14) 0.084(8) Uani 1 1 d . .
C6 C 0.9032(11) 0.0916(5) 0.9173(8) 0.107(4) Uani 1 1 d G .
C7 C 0.8832(11) 0.1080(4) 0.9788(9) 0.107(4) Uani 1 1 d G .
H7 H 0.8723 0.1426 0.9859 0.128 Uiso 1 1 calc R U
C8 C 0.8793(11) 0.0738(6) 1.0299(7) 0.107(4) Uani 1 1 d G .
H8 H 0.8657 0.085 1.072 0.128 Uiso 1 1 calc R U
C9 C 0.8953(10) 0.0231(5) 1.0195(7) 0.107(4) Uani 1 1 d G .
N1 N 0.9153(10) 0.0067(4) 0.9580(9) 0.107(4) Uani 1 1 d G .
C10 C 0.9192(10) 0.0410(6) 0.9069(7) 0.107(4) Uani 1 1 d G .
H10 H 0.9329 0.0298 0.8649 0.128 Uiso 1 1 calc R U
C11 C 0.8986(13) -0.0092(10) 1.0758(12) 0.194(9) Uani 1 1 d G .
C12 C 0.8927(14) 0.0078(8) 1.1395(14) 0.194(9) Uani 1 1 d G .
H12 H 0.8887 0.0429 1.1482 0.233 Uiso 1 1 calc R U
C13 C 0.8925(14) -0.0267(11) 1.1905(10) 0.194(9) Uani 1 1 d G .
H13 H 0.8884 -0.0151 1.2341 0.233 Uiso 1 1 calc R U
C14 C 0.8982(14) -0.0782(10) 1.1778(11) 0.194(9) Uani 1 1 d G .
H14 H 0.8981 -0.1017 1.2126 0.233 Uiso 1 1 calc R U
C15 C 0.9041(14) -0.0951(8) 1.1141(13) 0.194(9) Uani 1 1 d G .
H15 H 0.908 -0.1303 1.1054 0.233 Uiso 1 1 calc R U
N2 N 0.9043(13) -0.0607(10) 1.0631(10) 0.194(9) Uani 1 1 d G .
C21 C 1.0730(14) 0.6244(8) 0.6532(11) 0.074(7) Uani 1 1 d . .
C22 C 1.1140(14) 0.6572(9) 0.6416(11) 0.077(7) Uani 1 1 d . .
C23 C 1.1580(9) 0.7013(6) 0.6222(13) 0.143(6) Uani 1 1 d G .
C24 C 1.2308(9) 0.7037(6) 0.6298(12) 0.143(6) Uani 1 1 d G .
H24 H 1.2557 0.6756 0.6469 0.172 Uiso 1 1 calc R U
N3 N 1.2670(7) 0.7473(6) 0.6122(12) 0.143(6) Uani 1 1 d G .
C25 C 1.2306(9) 0.7884(6) 0.5870(13) 0.143(6) Uani 1 1 d G .
C26 C 1.1578(9) 0.7860(6) 0.5795(13) 0.143(6) Uani 1 1 d G .
H26 H 1.1329 0.8142 0.5623 0.172 Uiso 1 1 calc R U
C27 C 1.1216(7) 0.7425(7) 0.5971(13) 0.143(6) Uani 1 1 d G .
H27 H 1.0718 0.7408 0.592 0.172 Uiso 1 1 calc R U
C28 C 1.2605(11) 0.8351(7) 0.5638(13) 0.155(6) Uani 1 1 d G .
C29 C 1.2335(10) 0.8654(8) 0.5145(12) 0.155(6) Uani 1 1 d G .
H29 H 1.1909 0.8562 0.4933 0.186 Uiso 1 1 calc R U
C30 C 1.2689(12) 0.9091(8) 0.4962(11) 0.155(6) Uani 1 1 d G .
H30 H 1.2505 0.9298 0.4625 0.186 Uiso 1 1 calc R U
C31 C 1.3313(11) 0.9226(7) 0.5272(13) 0.155(6) Uani 1 1 d G .
H31 H 1.3555 0.9525 0.5147 0.186 Uiso 1 1 calc R U
C32 C 1.3582(10) 0.8923(8) 0.5765(12) 0.155(6) Uani 1 1 d G .
H32 H 1.4008 0.9015 0.5977 0.186 Uiso 1 1 calc R U
N4 N 1.3228(11) 0.8485(7) 0.5948(11) 0.155(6) Uani 1 1 d G .
C101 C 0.9664(15) 0.2742(10) 0.6200(9) 0.162(7) Uani 1 1 d G .
C102 C 0.9550(15) 0.2254(9) 0.5972(10) 0.162(7) Uani 1 1 d G .
H102 H 0.9265 0.2026 0.6214 0.194 Uiso 1 1 calc R U
C103 C 0.9852(15) 0.2099(8) 0.5389(10) 0.162(7) Uani 1 1 d G .
H103 H 0.9773 0.1766 0.5233 0.194 Uiso 1 1 calc R U
C104 C 1.0268(14) 0.2432(10) 0.5034(9) 0.162(7) Uani 1 1 d G .
H104 H 1.0474 0.2327 0.4636 0.194 Uiso 1 1 calc R U
C105 C 1.0382(14) 0.2920(9) 0.5262(10) 0.162(7) Uani 1 1 d G .
H105 H 1.0667 0.3148 0.502 0.194 Uiso 1 1 calc R U
C106 C 1.0081(15) 0.3075(8) 0.5845(11) 0.162(7) Uani 1 1 d G .
H106 H 1.0159 0.3408 0.6001 0.194 Uiso 1 1 calc R U
C111 C 0.8390(8) 0.3123(7) 0.6775(15) 0.151(7) Uani 1 1 d G .
C112 C 0.7963(12) 0.3269(8) 0.7291(12) 0.151(7) Uani 1 1 d G .
H112 H 0.8137 0.3254 0.7723 0.181 Uiso 1 1 calc R U
C113 C 0.7280(11) 0.3436(8) 0.7174(13) 0.151(7) Uani 1 1 d G .
H113 H 0.6988 0.3536 0.7527 0.181 Uiso 1 1 calc R U
C114 C 0.7024(8) 0.3458(7) 0.6542(14) 0.151(7) Uani 1 1 d G .
H114 H 0.6557 0.3572 0.6462 0.181 Uiso 1 1 calc R U
C115 C 0.7451(12) 0.3312(8) 0.6026(11) 0.151(7) Uani 1 1 d G .
H115 H 0.7277 0.3326 0.5593 0.181 Uiso 1 1 calc R U
C116 C 0.8134(11) 0.3144(7) 0.6143(13) 0.151(7) Uani 1 1 d G .
H116 H 0.8426 0.3044 0.579 0.181 Uiso 1 1 calc R U
C201 C 0.8584(10) 0.5143(9) 0.7379(11) 0.140(6) Uani 1 1 d G .
C202 C 0.8321(12) 0.4829(8) 0.7863(11) 0.140(6) Uani 1 1 d G .
H202 H 0.8532 0.4509 0.794 0.168 Uiso 1 1 calc R U
C203 C 0.7747(12) 0.4983(9) 0.8233(10) 0.140(6) Uani 1 1 d G .
H203 H 0.7566 0.4769 0.8564 0.168 Uiso 1 1 calc R U
C204 C 0.7437(10) 0.5451(9) 0.8120(10) 0.140(6) Uani 1 1 d G .
H204 H 0.7045 0.5557 0.8374 0.168 Uiso 1 1 calc R U
C205 C 0.7701(12) 0.5765(8) 0.7636(11) 0.140(6) Uani 1 1 d G .
H205 H 0.7489 0.6085 0.7559 0.168 Uiso 1 1 calc R U
C206 C 0.8275(12) 0.5611(9) 0.7265(10) 0.140(6) Uani 1 1 d G .
H206 H 0.8455 0.5826 0.6935 0.168 Uiso 1 1 calc R U
C211 C 0.9007(8) 0.4731(5) 0.6108(6) 0.081(3) Uani 1 1 d G .
C212 C 0.9495(6) 0.4610(6) 0.5628(8) 0.081(3) Uani 1 1 d G .
H212 H 0.9984 0.466 0.5704 0.097 Uiso 1 1 calc R U
C213 C 0.9267(7) 0.4415(5) 0.5037(7) 0.081(3) Uani 1 1 d G .
H213 H 0.96 0.4332 0.4709 0.097 Uiso 1 1 calc R U
C214 C 0.8551(8) 0.4342(5) 0.4925(6) 0.081(3) Uani 1 1 d G .
H214 H 0.8396 0.4208 0.4521 0.097 Uiso 1 1 calc R U
C215 C 0.8064(6) 0.4463(6) 0.5405(7) 0.081(3) Uani 1 1 d G .
H215 H 0.7575 0.4413 0.5328 0.097 Uiso 1 1 calc R U
C216 C 0.8292(8) 0.4658(6) 0.5996(6) 0.081(3) Uani 1 1 d G .
H216 H 0.7958 0.4741 0.6324 0.097 Uiso 1 1 calc R U
Au1 Au 0.92044(5) 0.22068(3) 0.76451(4) 0.0635(3) Uani 1 1 d . .
Au2 Au 1.01057(5) 0.56446(3) 0.67487(5) 0.0721(4) Uani 1 1 d . .
P1 P 0.9267(3) 0.2886(2) 0.6957(3) 0.0671(16) Uani 1 1 d . .
P2 P 0.9351(3) 0.4976(2) 0.6893(3) 0.0685(16) Uani 1 1 d . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0 0 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_exptl_crystal_face_index_h
_exptl_crystal_face_index_k
_exptl_crystal_face_index_l
_exptl_crystal_face_perp_dist
-1 0 0 0.096
15 -2 1 0.025
-1 -5 0 0.239
-2 12 -1 0.201
0 1 -14 0.066
0 0 1 0.016
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C2 C1 C3 123(2) . .
C2 C1 H1 118.3 . .
C3 C1 H1 118.3 . .
C1 C2 C2 118.4(13) . 4_756
C1 C2 P1 116.4(17) . .
C2 C2 P1 125.1(7) 4_756 .
C1 C3 C3 118.1(12) . 4_756
C1 C3 P2 117.9(16) . .
C3 C3 P2 124.0(7) 4_756 .
C5 C4 Au1 174(2) . .
C4 C5 C6 177(3) . .
C7 C6 C10 120 . .
C7 C6 C5 117.5(15) . .
C10 C6 C5 122.5(15) . .
C8 C7 C6 120 . .
C8 C7 H7 120 . .
C6 C7 H7 120 . .
C9 C8 C7 120 . .
C9 C8 H8 120 . .
C7 C8 H8 120 . .
C8 C9 N1 120 . .
C8 C9 C11 117.2(17) . .
N1 C9 C11 122.3(16) . .
C10 N1 C9 120 . .
N1 C10 C6 120 . .
N1 C10 H10 120 . .
C6 C10 H10 120 . .
C12 C11 N2 120 . .
C12 C11 C9 124(2) . .
N2 C11 C9 116(2) . .
C11 C12 C13 120 . .
C11 C12 H12 120 . .
C13 C12 H12 120 . .
C14 C13 C12 120 . .
C14 C13 H13 120 . .
C12 C13 H13 120 . .
C15 C14 C13 120 . .
C15 C14 H14 120 . .
C13 C14 H14 120 . .
N2 C15 C14 120 . .
N2 C15 H15 120 . .
C14 C15 H15 120 . .
C15 N2 C11 120 . .
C22 C21 Au2 175(2) . .
C21 C22 C23 173(3) . .
C24 C23 C27 120 . .
C24 C23 C22 124.3(14) . .
C27 C23 C22 115.7(14) . .
C23 C24 N3 120 . .
C23 C24 H24 120 . .
N3 C24 H24 120 . .
C25 N3 C24 120 . .
N3 C25 C26 120 . .
N3 C25 C28 126.8(14) . .
C26 C25 C28 113.1(14) . .
C25 C26 C27 120 . .
C25 C26 H26 120 . .
C27 C26 H26 120 . .
C26 C27 C23 120 . .
C26 C27 H27 120 . .
C23 C27 H27 120 . .
C29 C28 N4 120 . .
C29 C28 C25 126.3(15) . .
N4 C28 C25 113.7(15) . .
C30 C29 C28 120 . .
C30 C29 H29 120 . .
C28 C29 H29 120 . .
C31 C30 C29 120 . .
C31 C30 H30 120 . .
C29 C30 H30 120 . .
C32 C31 C30 120 . .
C32 C31 H31 120 . .
C30 C31 H31 120 . .
C31 C32 N4 120 . .
C31 C32 H32 120 . .
N4 C32 H32 120 . .
C32 N4 C28 120 . .
C102 C101 C106 120 . .
C102 C101 P1 115.4(15) . .
C106 C101 P1 124.5(15) . .
C103 C102 C101 120 . .
C103 C102 H102 120 . .
C101 C102 H102 120 . .
C102 C103 C104 120 . .
C102 C103 H103 120 . .
C104 C103 H103 120 . .
C103 C104 C105 120 . .
C103 C104 H104 120 . .
C105 C104 H104 120 . .
C106 C105 C104 120 . .
C106 C105 H105 120 . .
C104 C105 H105 120 . .
C105 C106 C101 120 . .
C105 C106 H106 120 . .
C101 C106 H106 120 . .
C112 C111 C116 120 . .
C112 C111 P1 118.2(16) . .
C116 C111 P1 121.7(16) . .
C113 C112 C111 120 . .
C113 C112 H112 120 . .
C111 C112 H112 120 . .
C112 C113 C114 120 . .
C112 C113 H113 120 . .
C114 C113 H113 120 . .
C115 C114 C113 120 . .
C115 C114 H114 120 . .
C113 C114 H114 120 . .
C114 C115 C116 120 . .
C114 C115 H115 120 . .
C116 C115 H115 120 . .
C115 C116 C111 120 . .
C115 C116 H116 120 . .
C111 C116 H116 120 . .
C202 C201 C206 120 . .
C202 C201 P2 122.4(14) . .
C206 C201 P2 117.5(14) . .
C203 C202 C201 120 . .
C203 C202 H202 120 . .
C201 C202 H202 120 . .
C204 C203 C202 120 . .
C204 C203 H203 120 . .
C202 C203 H203 120 . .
C203 C204 C205 120 . .
C203 C204 H204 120 . .
C205 C204 H204 120 . .
C206 C205 C204 120 . .
C206 C205 H205 120 . .
C204 C205 H205 120 . .
C205 C206 C201 120 . .
C205 C206 H206 120 . .
C201 C206 H206 120 . .
C212 C211 C216 120 . .
C212 C211 P2 117.6(9) . .
C216 C211 P2 122.4(9) . .
C211 C212 C213 120 . .
C211 C212 H212 120 . .
C213 C212 H212 120 . .
C214 C213 C212 120 . .
C214 C213 H213 120 . .
C212 C213 H213 120 . .
C213 C214 C215 120 . .
C213 C214 H214 120 . .
C215 C214 H214 120 . .
C216 C215 C214 120 . .
C216 C215 H215 120 . .
C214 C215 H215 120 . .
C215 C216 C211 120 . .
C215 C216 H216 120 . .
C211 C216 H216 120 . .
C4 Au1 P1 176.9(6) . .
C4 Au1 Au1 102.9(6) . 4_756
P1 Au1 Au1 80.18(16) . 4_756
C21 Au2 P2 174.3(7) . .
C21 Au2 Au2 107.1(7) . 4_756
P2 Au2 Au2 77.99(15) . 4_756
C101 P1 C111 106.5(14) . .
C101 P1 C2 107.2(11) . .
C111 P1 C2 101.9(10) . .
C101 P1 Au1 113.4(9) . .
C111 P1 Au1 110.5(8) . .
C2 P1 Au1 116.4(7) . .
C201 P2 C3 106.4(11) . .
C201 P2 C211 106.3(10) . .
C3 P2 C211 101.6(8) . .
C201 P2 Au2 112.5(8) . .
C3 P2 Au2 116.9(7) . .
C211 P2 Au2 112.0(5) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C1 C2 1.40(3) .
C1 C3 1.42(3) .
C1 H1 0.95 .
C2 C2 1.44(4) 4_756
C2 P1 1.85(2) .
C3 C3 1.44(4) 4_756
C3 P2 1.850(19) .
C4 C5 1.13(3) .
C4 Au1 2.07(2) .
C5 C6 1.47(3) .
C6 C7 1.39 .
C6 C10 1.39 .
C7 C8 1.39 .
C7 H7 0.95 .
C8 C9 1.39 .
C8 H8 0.95 .
C9 N1 1.39 .
C9 C11 1.441(19) .
N1 C10 1.39 .
C10 H10 0.95 .
C11 C12 1.39 .
C11 N2 1.39 .
C12 C13 1.39 .
C12 H12 0.95 .
C13 C14 1.39 .
C13 H13 0.95 .
C14 C15 1.39 .
C14 H14 0.95 .
C15 N2 1.39 .
C15 H15 0.95 .
C21 C22 1.19(3) .
C21 Au2 2.03(2) .
C22 C23 1.49(3) .
C23 C24 1.39 .
C23 C27 1.39 .
C24 N3 1.39 .
C24 H24 0.95 .
N3 C25 1.39 .
C25 C26 1.39 .
C25 C28 1.439(16) .
C26 C27 1.39 .
C26 H26 0.95 .
C27 H27 0.95 .
C28 C29 1.39 .
C28 N4 1.39 .
C29 C30 1.39 .
C29 H29 0.95 .
C30 C31 1.39 .
C30 H30 0.95 .
C31 C32 1.39 .
C31 H31 0.95 .
C32 N4 1.39 .
C32 H32 0.95 .
C101 C102 1.39 .
C101 C106 1.39 .
C101 P1 1.772(16) .
C102 C103 1.39 .
C102 H102 0.95 .
C103 C104 1.39 .
C103 H103 0.95 .
C104 C105 1.39 .
C104 H104 0.95 .
C105 C106 1.39 .
C105 H105 0.95 .
C106 H106 0.95 .
C111 C112 1.39 .
C111 C116 1.39 .
C111 P1 1.816(16) .
C112 C113 1.39 .
C112 H112 0.95 .
C113 C114 1.39 .
C113 H113 0.95 .
C114 C115 1.39 .
C114 H114 0.95 .
C115 C116 1.39 .
C115 H115 0.95 .
C116 H116 0.95 .
C201 C202 1.39 .
C201 C206 1.39 .
C201 P2 1.820(14) .
C202 C203 1.39 .
C202 H202 0.95 .
C203 C204 1.39 .
C203 H203 0.95 .
C204 C205 1.39 .
C204 H204 0.95 .
C205 C206 1.39 .
C205 H205 0.95 .
C206 H206 0.95 .
C211 C212 1.39 .
C211 C216 1.39 .
C211 P2 1.858(13) .
C212 C213 1.39 .
C212 H212 0.95 .
C213 C214 1.39 .
C213 H213 0.95 .
C214 C215 1.39 .
C214 H214 0.95 .
C215 C216 1.39 .
C215 H215 0.95 .
C216 H216 0.95 .
Au1 P1 2.290(6) .
Au1 Au1 3.077(2) 4_756
Au2 P2 2.294(6) .
Au2 Au2 3.1175(19) 4_756
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
C3 C1 C2 C2 -6(4) . 4_756
C3 C1 C2 P1 176.7(15) . .
C2 C1 C3 C3 1(3) . 4_756
C2 C1 C3 P2 179.7(15) . .
C10 C6 C7 C8 0 . .
C5 C6 C7 C8 -180(2) . .
C6 C7 C8 C9 0 . .
C7 C8 C9 N1 0 . .
C7 C8 C9 C11 173(2) . .
C8 C9 N1 C10 0 . .
C11 C9 N1 C10 -172(2) . .
C9 N1 C10 C6 0 . .
C7 C6 C10 N1 0 . .
C5 C6 C10 N1 180(2) . .
C8 C9 C11 C12 -6(2) . .
N1 C9 C11 C12 166.8(14) . .
C8 C9 C11 N2 170.8(12) . .
N1 C9 C11 N2 -17(2) . .
N2 C11 C12 C13 0 . .
C9 C11 C12 C13 176(2) . .
C11 C12 C13 C14 0 . .
C12 C13 C14 C15 0 . .
C13 C14 C15 N2 0 . .
C14 C15 N2 C11 0 . .
C12 C11 N2 C15 0 . .
C9 C11 N2 C15 -177(2) . .
C27 C23 C24 N3 0 . .
C22 C23 C24 N3 -178(3) . .
C23 C24 N3 C25 0 . .
C24 N3 C25 C26 0 . .
C24 N3 C25 C28 -177(3) . .
N3 C25 C26 C27 0 . .
C28 C25 C26 C27 177(3) . .
C25 C26 C27 C23 0 . .
C24 C23 C27 C26 0 . .
C22 C23 C27 C26 178(2) . .
N3 C25 C28 C29 148.7(16) . .
C26 C25 C28 C29 -28(3) . .
N3 C25 C28 N4 -30(3) . .
C26 C25 C28 N4 152.9(15) . .
N4 C28 C29 C30 0 . .
C25 C28 C29 C30 -179(3) . .
C28 C29 C30 C31 0 . .
C29 C30 C31 C32 0 . .
C30 C31 C32 N4 0 . .
C31 C32 N4 C28 0 . .
C29 C28 N4 C32 0 . .
C25 C28 N4 C32 179(3) . .
C106 C101 C102 C103 0 . .
P1 C101 C102 C103 -179(2) . .
C101 C102 C103 C104 0 . .
C102 C103 C104 C105 0 . .
C103 C104 C105 C106 0 . .
C104 C105 C106 C101 0 . .
C102 C101 C106 C105 0 . .
P1 C101 C106 C105 178(2) . .
C116 C111 C112 C113 0 . .
P1 C111 C112 C113 -177.9(14) . .
C111 C112 C113 C114 0 . .
C112 C113 C114 C115 0 . .
C113 C114 C115 C116 0 . .
C114 C115 C116 C111 0 . .
C112 C111 C116 C115 0 . .
P1 C111 C116 C115 177.8(15) . .
C206 C201 C202 C203 0 . .
P2 C201 C202 C203 177.9(18) . .
C201 C202 C203 C204 0 . .
C202 C203 C204 C205 0 . .
C203 C204 C205 C206 0 . .
C204 C205 C206 C201 0 . .
C202 C201 C206 C205 0 . .
P2 C201 C206 C205 -178.0(17) . .
C216 C211 C212 C213 0 . .
P2 C211 C212 C213 178.6(10) . .
C211 C212 C213 C214 0 . .
C212 C213 C214 C215 0 . .
C213 C214 C215 C216 0 . .
C214 C215 C216 C211 0 . .
C212 C211 C216 C215 0 . .
P2 C211 C216 C215 -178.5(11) . .
C102 C101 P1 C111 -89.1(15) . .
C106 C101 P1 C111 92.4(18) . .
C102 C101 P1 C2 162.5(13) . .
C106 C101 P1 C2 -16(2) . .
C102 C101 P1 Au1 32.7(16) . .
C106 C101 P1 Au1 -145.9(14) . .
C112 C111 P1 C101 -179.5(13) . .
C116 C111 P1 C101 2.7(16) . .
C112 C111 P1 C2 -67.4(12) . .
C116 C111 P1 C2 114.8(13) . .
C112 C111 P1 Au1 57.0(11) . .
C116 C111 P1 Au1 -120.9(11) . .
C1 C2 P1 C101 82.7(19) . .
C2 C2 P1 C101 -95(3) 4_756 .
C1 C2 P1 C111 -28.9(19) . .
C2 C2 P1 C111 154(3) 4_756 .
C1 C2 P1 Au1 -149.2(13) . .
C2 C2 P1 Au1 33(3) 4_756 .
C202 C201 P2 C3 -8.0(16) . .
C206 C201 P2 C3 169.9(12) . .
C202 C201 P2 C211 99.7(14) . .
C206 C201 P2 C211 -82.3(13) . .
C202 C201 P2 Au2 -137.3(11) . .
C206 C201 P2 Au2 40.7(14) . .
C1 C3 P2 C201 88.7(17) . .
C3 C3 P2 C201 -93(2) 4_756 .
C1 C3 P2 C211 -22.4(17) . .
C3 C3 P2 C211 156(2) 4_756 .
C1 C3 P2 Au2 -144.7(13) . .
C3 C3 P2 Au2 33(3) 4_756 .
C212 C211 P2 C201 175.5(11) . .
C216 C211 P2 C201 -5.9(13) . .
C212 C211 P2 C3 -73.3(10) . .
C216 C211 P2 C3 105.3(10) . .
C212 C211 P2 Au2 52.3(8) . .
C216 C211 P2 Au2 -129.1(7) . .
