#------------------------------------------------------------------------------
#$Date: 2017-09-27 05:48:10 +0300 (Wed, 27 Sep 2017) $
#$Revision: 201332 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/04/43/7044336.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7044336
loop_
_publ_author_name
'Cui, Xiaobing'
'Lv, Ying'
'xiao, lina'
'hao, xiangrong'
'Xu, Ji-Qing'
_publ_section_title
;
 A series of organic-inorganic hybrid compounds formed by [P2W18O62]6- and
 several types of transition metal complexes
;
_journal_name_full               'Dalton Trans.'
_journal_paper_doi               10.1039/C7DT02814H
_journal_year                    2017
_chemical_formula_sum            'C70 H60 Ag6 N14 O64 P2 W18'
_chemical_formula_weight         6139.78
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2017-07-26 deposited with the CCDC.
2017-09-25 downloaded from the CCDC.
;
_cell_angle_alpha                96.4460(10)
_cell_angle_beta                 93.0220(10)
_cell_angle_gamma                108.8120(10)
_cell_formula_units_Z            2
_cell_length_a                   17.4100(8)
_cell_length_b                   18.1484(9)
_cell_length_c                   18.3892(8)
_cell_measurement_reflns_used    9740
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      28.32
_cell_measurement_theta_min      3.07
_cell_volume                     5440.7(4)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_publication_material  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_structure_solution    'SHELXL-2014/7 (Sheldrick, 2014)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.985
_diffrn_measured_fraction_theta_max 0.924
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0330
_diffrn_reflns_av_unetI/netI     0.0547
_diffrn_reflns_Laue_measured_fraction_full 0.985
_diffrn_reflns_Laue_measured_fraction_max 0.924
_diffrn_reflns_limit_h_max       23
_diffrn_reflns_limit_h_min       -23
_diffrn_reflns_limit_k_max       24
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_number            43884
_diffrn_reflns_point_group_measured_fraction_full 0.985
_diffrn_reflns_point_group_measured_fraction_max 0.924
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         28.321
_diffrn_reflns_theta_min         2.822
_exptl_absorpt_coefficient_mu    20.122
_exptl_absorpt_correction_T_max  0.041
_exptl_absorpt_correction_T_min  0.036
_exptl_absorpt_correction_type   empirical
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    3.748
_exptl_crystal_description       block
_exptl_crystal_F_000             5468
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.18
_refine_diff_density_max         4.639
_refine_diff_density_min         -4.751
_refine_diff_density_rms         0.454
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.015
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1567
_refine_ls_number_reflns         25076
_refine_ls_number_restraints     46
_refine_ls_restrained_S_all      1.014
_refine_ls_R_factor_all          0.0697
_refine_ls_R_factor_gt           0.0517
_refine_ls_shift/su_max          0.014
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0666P)²+225.0361P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1303
_refine_ls_wR_factor_ref         0.1482
_reflns_Friedel_coverage         0.000
_reflns_number_gt                19889
_reflns_number_total             25076
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c7dt02814h2.cif
_cod_data_source_block           4
_cod_database_code               7044336
_shelx_shelxl_version_number     2014/7
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
W1 W 0.43354(3) 0.34441(3) 0.12107(3) 0.01834(11) Uani 1 1 d . .
W2 W 0.65576(3) 0.42193(3) 0.09326(3) 0.01753(11) Uani 1 1 d . .
W3 W 0.73532(3) 0.19190(3) 0.35288(3) 0.01770(11) Uani 1 1 d . .
W4 W 0.51284(3) 0.11228(3) 0.37840(3) 0.01870(11) Uani 1 1 d . .
W5 W 0.69586(3) 0.50160(3) 0.28891(3) 0.01644(10) Uani 1 1 d . .
W6 W 0.47479(3) 0.42172(3) 0.31710(3) 0.01802(11) Uani 1 1 d . .
W7 W 0.47642(3) 0.04074(3) 0.19865(3) 0.01704(11) Uani 1 1 d . .
W8 W 0.69904(3) 0.11981(3) 0.17389(3) 0.01725(11) Uani 1 1 d . .
W9 W 0.64937(3) 0.23680(3) 0.04010(3) 0.01671(10) Uani 1 1 d . .
W10 W 0.42719(3) 0.15919(3) 0.06636(3) 0.01750(11) Uani 1 1 d . .
W12 W 0.28089(3) 0.26535(3) 0.25035(3) 0.02352(12) Uani 1 1 d . .
W13 W 0.52022(3) 0.31390(3) 0.43987(3) 0.01861(11) Uani 1 1 d . .
W14 W 0.74120(3) 0.39439(3) 0.41136(3) 0.01777(11) Uani 1 1 d . .
W18 W 0.86415(3) 0.47500(3) 0.18544(3) 0.02257(12) Uani 1 1 d . .
W19 W 0.90332(3) 0.35955(3) 0.30483(3) 0.02344(12) Uani 1 1 d . .
W20 W 0.32250(3) 0.15954(3) 0.37799(3) 0.02366(12) Uani 1 1 d . .
W25 W 0.86109(3) 0.29161(3) 0.12435(3) 0.02248(12) Uani 1 1 d . .
W26 W 0.28013(3) 0.07973(3) 0.19954(3) 0.02202(12) Uani 1 1 d . .
Ag2 Ag 0.56397(13) -0.11937(10) 0.13527(8) 0.0571(5) Uani 1 1 d . .
Ag3 Ag 0.37317(14) -0.21550(13) 0.16232(9) 0.0739(6) Uani 1 1 d . .
Ag1 Ag 0.78708(17) -0.00167(19) 0.02382(15) 0.1044(10) Uani 1 1 d . .
N1 N 0.8508(16) -0.0928(16) 0.0158(14) 0.082(7) Uani 1 1 d . .
N2 N 0.9090(15) 0.0425(17) 0.0997(16) 0.092(9) Uani 1 1 d . U
C1 C 0.819(2) -0.161(2) -0.0329(17) 0.085(9) Uani 1 1 d . .
H1A H 0.7668 -0.1737 -0.0568 0.102 Uiso 1 1 calc R U
C2 C 0.863(2) -0.209(3) -0.0459(18) 0.112(14) Uani 1 1 d . .
H2A H 0.8414 -0.2551 -0.0793 0.134 Uiso 1 1 calc R U
C3 C 0.9413(17) -0.193(2) -0.0105(18) 0.096(11) Uani 1 1 d . .
H3A H 0.9726 -0.2249 -0.0213 0.116 Uiso 1 1 calc R U
C4 C 0.970(2) -0.126(2) 0.0419(19) 0.093(9) Uani 1 1 d . U
H4A H 1.0194 -0.1145 0.0700 0.112 Uiso 1 1 calc R U
C5 C 0.9250(17) -0.076(2) 0.0519(16) 0.089(11) Uani 1 1 d . .
C6 C 0.9541(15) -0.0030(15) 0.1046(13) 0.060(5) Uani 1 1 d . U
C7 C 1.0218(14) 0.012(2) 0.158(2) 0.098(12) Uani 1 1 d . .
H7A H 1.0471 -0.0248 0.1634 0.118 Uiso 1 1 calc R U
C8 C 1.0477(19) 0.083(2) 0.199(3) 0.14(2) Uani 1 1 d . .
H8A H 1.0962 0.0987 0.2295 0.166 Uiso 1 1 calc R U
C9 C 1.005(2) 0.131(2) 0.197(3) 0.122(16) Uani 1 1 d . .
H9A H 1.0215 0.1780 0.2283 0.146 Uiso 1 1 calc R U
C10 C 0.939(3) 0.114(2) 0.152(3) 0.125(14) Uani 1 1 d . U
H10A H 0.9099 0.1489 0.1538 0.150 Uiso 1 1 calc R U
P1 P 0.70180(16) 0.31235(16) 0.22599(14) 0.0071(5) Uani 1 1 d . U
P2 P 0.46905(16) 0.22939(16) 0.25330(14) 0.0073(5) Uani 1 1 d . .
O1 O 0.2717(7) 0.1278(7) 0.4516(6) 0.038(3) Uani 1 1 d . .
O013 O 0.7249(6) 0.2845(5) 0.4003(5) 0.0206(19) Uani 1 1 d . .
O2 O 0.6491(7) 0.1911(7) -0.0482(6) 0.032(2) Uani 1 1 d . .
O012 O 0.5907(5) 0.4646(5) 0.3172(5) 0.0198(18) Uani 1 1 d . .
O3 O 0.9202(7) 0.2612(7) 0.0656(6) 0.035(3) Uani 1 1 d . .
O4 O 0.6555(7) 0.4918(6) 0.0394(6) 0.029(2) Uani 1 1 d . .
O5 O 0.3961(7) 0.4017(7) 0.0722(6) 0.036(3) Uani 1 1 d . .
O6 O 0.9908(7) 0.3768(7) 0.3597(7) 0.037(3) Uani 1 1 d . .
O6W O 0.7154(11) 0.0610(9) -0.0357(8) 0.064(4) Uani 1 1 d . .
O7 O 0.3930(6) 0.1055(7) -0.0193(5) 0.029(2) Uani 1 1 d . .
O10 O 0.7763(7) 0.1571(6) 0.4229(6) 0.032(2) Uani 1 1 d . .
O11 O 0.4547(7) -0.0550(6) 0.1592(6) 0.029(2) Uani 1 1 d . .
O12 O 0.5061(6) 0.3027(6) 0.3085(5) 0.0216(19) Uani 1 1 d . .
O15 O 0.4025(6) 0.1088(6) 0.3786(6) 0.026(2) Uani 1 1 d . .
O16 O 0.3324(6) 0.1202(6) 0.1144(5) 0.024(2) Uani 1 1 d . .
O17 O 0.4573(7) 0.5085(6) 0.3353(6) 0.031(2) Uani 1 1 d . .
O18 O 0.3749(6) 0.1949(6) 0.2651(5) 0.0223(19) Uani 1 1 d . .
O19 O 0.6861(5) 0.3679(5) 0.2874(5) 0.0180(18) Uani 1 1 d . .
O20 O 0.2621(6) 0.2199(6) 0.3407(6) 0.025(2) Uani 1 1 d . .
O22 O 0.7817(6) 0.4230(6) 0.5010(5) 0.028(2) Uani 1 1 d . .
O25 O 0.6869(6) 0.2292(6) 0.2452(5) 0.0211(19) Uani 1 1 d . .
O26 O 0.7126(6) 0.0364(6) 0.1323(5) 0.028(2) Uani 1 1 d . .
O29 O 0.7709(6) 0.4505(6) 0.1163(5) 0.025(2) Uani 1 1 d . .
O30 O 0.4860(6) 0.0286(6) 0.2995(5) 0.026(2) Uani 1 1 d . .
O32 O 0.2624(6) 0.0753(6) 0.2992(6) 0.025(2) Uani 1 1 d . .
O34 O 0.4732(6) 0.2462(5) 0.1735(5) 0.0191(18) Uani 1 1 d . .
O36 O 0.5251(7) 0.3302(6) 0.5330(5) 0.028(2) Uani 1 1 d . .
O37 O 0.4694(6) 0.0926(5) 0.1168(5) 0.0186(18) Uani 1 1 d . .
O39 O 0.5164(7) 0.0633(6) 0.4516(6) 0.029(2) Uani 1 1 d . .
O40 O 0.9293(6) 0.3116(6) 0.2156(6) 0.028(2) Uani 1 1 d . .
O41 O 0.7121(6) 0.5998(5) 0.3005(5) 0.026(2) Uani 1 1 d . .
O42 O 0.4698(6) 0.4057(5) 0.2130(5) 0.0196(18) Uani 1 1 d . .
O44 O 0.3343(5) 0.2940(6) 0.1670(5) 0.0223(19) Uani 1 1 d . .
O46 O 0.2311(5) 0.1601(6) 0.2012(6) 0.024(2) Uani 1 1 d . .
O49 O 0.9300(6) 0.4563(6) 0.2617(6) 0.027(2) Uani 1 1 d . .
O52 O 0.3645(5) 0.0367(6) 0.2087(5) 0.0212(19) Uani 1 1 d . .
O55 O 0.5045(5) 0.1641(5) 0.2662(5) 0.0154(16) Uani 1 1 d . U
O57 O 0.6560(5) 0.3117(5) 0.1535(5) 0.0176(17) Uani 1 1 d . .
O60 O 0.7952(5) 0.3455(6) 0.2151(5) 0.0176(18) Uani 1 1 d . .
O61 O 0.6548(6) 0.4718(5) 0.1896(5) 0.0215(19) Uani 1 1 d . .
O62 O 0.6525(6) 0.1573(5) 0.0951(5) 0.0213(19) Uani 1 1 d . .
O65 O 0.8381(6) 0.2608(6) 0.3251(5) 0.023(2) Uani 1 1 d . .
O66 O 0.6559(6) 0.3396(6) 0.0198(5) 0.023(2) Uani 1 1 d . .
O67 O 0.6287(6) 0.3683(5) 0.4270(5) 0.0214(19) Uani 1 1 d . .
O72 O 0.8392(6) 0.4021(6) 0.3681(5) 0.023(2) Uani 1 1 d . .
O78 O 0.7669(6) 0.2765(6) 0.0629(5) 0.0226(19) Uani 1 1 d . .
O79 O 0.6256(6) 0.1375(6) 0.3586(5) 0.023(2) Uani 1 1 d . .
O81 O 0.5416(6) 0.2184(5) 0.4235(5) 0.0210(19) Uani 1 1 d . .
O83 O 0.4024(6) 0.2505(6) 0.0504(5) 0.025(2) Uani 1 1 d . .
O88 O 0.4061(6) 0.2484(6) 0.4221(5) 0.0228(19) Uani 1 1 d . .
O89 O 0.5403(6) 0.3733(6) 0.0933(5) 0.023(2) Uani 1 1 d . .
O90 O 0.3659(6) 0.3514(6) 0.3053(5) 0.024(2) Uani 1 1 d . .
O94 O 0.5378(6) 0.2102(6) 0.0442(5) 0.0196(18) Uani 1 1 d . .
O95 O 0.8009(5) 0.5072(5) 0.2537(5) 0.0180(18) Uani 1 1 d . .
O96 O 0.7992(6) 0.1936(6) 0.1577(6) 0.024(2) Uani 1 1 d . .
O98 O 0.7381(6) 0.1183(5) 0.2710(5) 0.0199(18) Uani 1 1 d . .
O99 O 0.5906(5) 0.0729(5) 0.1978(5) 0.0177(17) Uani 1 1 d . .
O105 O 0.4893(6) 0.3994(5) 0.4140(5) 0.024(2) Uani 1 1 d . .
O108 O 0.7413(5) 0.4915(5) 0.3828(5) 0.0162(17) Uani 1 1 d . .
O110 O 0.2024(6) 0.3019(6) 0.2435(7) 0.033(2) Uani 1 1 d . .
O111 O 0.8967(6) 0.4005(6) 0.1211(6) 0.027(2) Uani 1 1 d . .
O130 O 0.9252(7) 0.5620(7) 0.1628(7) 0.038(3) Uani 1 1 d . .
O131 O 0.2017(7) 0.0013(7) 0.1589(6) 0.036(3) Uani 1 1 d . .
N3 N 0.5233(8) -0.2583(8) 0.1466(7) 0.031(3) Uani 1 1 d . .
N4 N 0.5872(8) -0.1298(8) 0.2583(7) 0.030(3) Uani 1 1 d . .
N5 N 0.3306(10) -0.3437(11) 0.1904(9) 0.048(4) Uani 1 1 d . .
N6 N 0.3574(10) -0.2087(10) 0.2819(8) 0.045(4) Uani 1 1 d . .
C11 C 0.5065(10) -0.3155(10) 0.0918(9) 0.034(3) Uani 1 1 d . .
H11A H 0.4892 -0.3069 0.0457 0.041 Uiso 1 1 calc R U
C12 C 0.5135(11) -0.3879(10) 0.0996(10) 0.038(4) Uani 1 1 d . .
H12A H 0.5029 -0.4270 0.0594 0.046 Uiso 1 1 calc R U
C13 C 0.5368(12) -0.4010(13) 0.1696(10) 0.048(5) Uani 1 1 d . .
H13A H 0.5404 -0.4495 0.1775 0.057 Uiso 1 1 calc R U
C14 C 0.5542(13) -0.3411(10) 0.2255(10) 0.043(4) Uani 1 1 d . .
H14A H 0.5721 -0.3478 0.2721 0.051 Uiso 1 1 calc R U
C15 C 0.5456(9) -0.2718(9) 0.2142(8) 0.028(3) Uani 1 1 d . .
C16 C 0.5623(9) -0.2039(9) 0.2757(8) 0.024(3) Uani 1 1 d . .
C17 C 0.5530(11) -0.2167(11) 0.3477(9) 0.038(4) Uani 1 1 d . .
H17A H 0.5384 -0.2679 0.3589 0.045 Uiso 1 1 calc R U
C18 C 0.5650(12) -0.1560(12) 0.4034(9) 0.042(4) Uani 1 1 d . .
H18A H 0.5551 -0.1650 0.4514 0.051 Uiso 1 1 calc R U
C19 C 0.5923(13) -0.0807(12) 0.3848(10) 0.048(5) Uani 1 1 d . .
H19A H 0.6049 -0.0373 0.4208 0.058 Uiso 1 1 calc R U
C20 C 0.6008(11) -0.0709(12) 0.3112(9) 0.041(4) Uani 1 1 d . .
H20A H 0.6169 -0.0202 0.2990 0.049 Uiso 1 1 calc R U
C21 C 0.3185(15) -0.4101(18) 0.1467(15) 0.071(7) Uani 1 1 d . .
H21A H 0.3200 -0.4062 0.0967 0.085 Uiso 1 1 calc R U
C22 C 0.3041(14) -0.4839(15) 0.1653(17) 0.068(7) Uani 1 1 d . .
H22A H 0.2966 -0.5284 0.1316 0.082 Uiso 1 1 calc R U
C23 C 0.3021(16) -0.4847(15) 0.2408(16) 0.069(7) Uani 1 1 d . .
H23A H 0.2942 -0.5322 0.2587 0.083 Uiso 1 1 calc R U
C24 C 0.3110(17) -0.4201(14) 0.2897(13) 0.064(6) Uani 1 1 d . .
H24A H 0.3072 -0.4232 0.3396 0.077 Uiso 1 1 calc R U
C25 C 0.3258(9) -0.3506(11) 0.2625(9) 0.035(4) Uani 1 1 d . .
C26 C 0.3349(10) -0.2769(11) 0.3125(9) 0.037(4) Uani 1 1 d . .
C27 C 0.3224(14) -0.2770(16) 0.3866(11) 0.060(6) Uani 1 1 d . .
H27A H 0.3055 -0.3242 0.4060 0.072 Uiso 1 1 calc R U
C28 C 0.3351(15) -0.2078(18) 0.4307(12) 0.067(7) Uani 1 1 d . .
H28A H 0.3283 -0.2071 0.4806 0.080 Uiso 1 1 calc R U
C29 C 0.3584(16) -0.1375(14) 0.3998(13) 0.071(7) Uani 1 1 d . .
H29A H 0.3676 -0.0892 0.4281 0.085 Uiso 1 1 calc R U
C30 C 0.3668(15) -0.1430(16) 0.3280(12) 0.064(6) Uani 1 1 d . .
H30A H 0.3807 -0.0963 0.3077 0.077 Uiso 1 1 calc R U
Ag5 Ag 0.11169(9) 0.25948(10) 0.69143(9) 0.0508(4) Uani 1 1 d . .
Ag4 Ag 0.24980(10) 0.24876(11) 0.61124(9) 0.0553(4) Uani 1 1 d . .
N8 N 0.1402(10) 0.2022(10) 0.5069(10) 0.049(4) Uani 1 1 d . .
N7 N 0.2801(9) 0.3304(7) 0.5311(7) 0.031(3) Uani 1 1 d . .
N12 N -0.0100(11) 0.1600(10) 0.6473(12) 0.063(6) Uani 1 1 d . .
N11 N 0.0413(8) 0.3112(8) 0.6185(7) 0.031(3) Uani 1 1 d . .
N10 N 0.1966(9) 0.2633(9) 0.7829(8) 0.038(3) Uani 1 1 d . .
N9 N 0.2207(9) 0.1444(9) 0.6675(8) 0.039(3) Uani 1 1 d . .
C40 C 0.0746(15) 0.1379(15) 0.4930(17) 0.074(7) Uani 1 1 d . .
H40A H 0.0721 0.0974 0.5205 0.089 Uiso 1 1 calc R U
C39 C 0.0126(14) 0.127(2) 0.4433(15) 0.083(9) Uani 1 1 d . .
H39A H -0.0308 0.0797 0.4353 0.099 Uiso 1 1 calc R U
C38 C 0.0146(16) 0.186(2) 0.4050(18) 0.088(9) Uani 1 1 d . .
H38A H -0.0284 0.1820 0.3709 0.106 Uiso 1 1 calc R U
C37 C 0.0837(16) 0.2545(19) 0.4177(16) 0.086(9) Uani 1 1 d . .
H37A H 0.0851 0.2968 0.3928 0.103 Uiso 1 1 calc R U
C36 C 0.1471(11) 0.2600(11) 0.4646(9) 0.036(4) Uani 1 1 d . .
C35 C 0.2214(10) 0.3282(10) 0.4769(8) 0.031(3) Uani 1 1 d . .
C34 C 0.2366(14) 0.3868(12) 0.4324(10) 0.048(5) Uani 1 1 d . .
H34A H 0.1975 0.3862 0.3956 0.058 Uiso 1 1 calc R U
C33 C 0.3125(16) 0.4475(11) 0.4437(13) 0.059(7) Uani 1 1 d . .
H33A H 0.3247 0.4858 0.4125 0.071 Uiso 1 1 calc R U
C32 C 0.3661(18) 0.4505(11) 0.4978(14) 0.061(7) Uani 1 1 d . .
H32A H 0.4142 0.4931 0.5075 0.073 Uiso 1 1 calc R U
C31 C 0.3511(11) 0.3912(11) 0.5393(9) 0.039(4) Uani 1 1 d . .
H31A H 0.3913 0.3922 0.5751 0.047 Uiso 1 1 calc R U
C60 C -0.0363(14) 0.0837(12) 0.6626(15) 0.065(7) Uani 1 1 d . .
H60A H -0.0029 0.0691 0.6951 0.078 Uiso 1 1 calc R U
C59 C -0.1080(13) 0.0282(11) 0.6333(15) 0.060(6) Uani 1 1 d . .
H59A H -0.1216 -0.0235 0.6427 0.072 Uiso 1 1 calc R U
C58 C -0.1569(15) 0.0511(12) 0.5915(16) 0.071(8) Uani 1 1 d . .
H58A H -0.2067 0.0144 0.5719 0.085 Uiso 1 1 calc R U
C57 C -0.1380(10) 0.1263(12) 0.5751(10) 0.047(5) Uani 1 1 d . .
H57A H -0.1744 0.1409 0.5458 0.056 Uiso 1 1 calc R U
C56 C -0.0611(11) 0.1814(10) 0.6044(9) 0.035(3) Uani 1 1 d . .
C55 C -0.0313(9) 0.2638(10) 0.5882(8) 0.031(3) Uani 1 1 d . .
C54 C -0.0812(10) 0.2904(12) 0.5424(10) 0.044(4) Uani 1 1 d . .
H54A H -0.1330 0.2582 0.5229 0.053 Uiso 1 1 calc R U
C53 C -0.0485(11) 0.3681(11) 0.5278(10) 0.044(4) Uani 1 1 d . .
H53A H -0.0784 0.3871 0.4959 0.053 Uiso 1 1 calc R U
C52 C 0.0264(12) 0.4168(10) 0.5594(11) 0.050(5) Uani 1 1 d . .
H52A H 0.0477 0.4688 0.5509 0.060 Uiso 1 1 calc R U
C51 C 0.0669(11) 0.3847(10) 0.6033(11) 0.047(5) Uani 1 1 d . .
H51A H 0.1178 0.4170 0.6253 0.056 Uiso 1 1 calc R U
C50 C 0.2101(15) 0.3233(11) 0.8339(12) 0.056(6) Uani 1 1 d . .
H50A H 0.1897 0.3633 0.8251 0.067 Uiso 1 1 calc R U
C49 C 0.2534(14) 0.3294(13) 0.8997(11) 0.063(7) Uani 1 1 d . .
H49A H 0.2616 0.3729 0.9349 0.076 Uiso 1 1 calc R U
C48 C 0.2849(13) 0.2717(16) 0.9145(11) 0.066(7) Uani 1 1 d . .
H48A H 0.3147 0.2753 0.9591 0.080 Uiso 1 1 calc R U
C47 C 0.2704(12) 0.2063(15) 0.8591(10) 0.052(5) Uani 1 1 d . .
H47A H 0.2907 0.1659 0.8660 0.062 Uiso 1 1 calc R U
C46 C 0.2251(9) 0.2047(10) 0.7948(9) 0.032(3) Uani 1 1 d . .
C45 C 0.2097(9) 0.1333(10) 0.7389(9) 0.033(4) Uani 1 1 d . .
C44 C 0.1840(11) 0.0602(11) 0.7593(11) 0.042(4) Uani 1 1 d . .
H44A H 0.1745 0.0542 0.8079 0.051 Uiso 1 1 calc R U
C43 C 0.1724(15) -0.0036(14) 0.7093(16) 0.065(7) Uani 1 1 d . .
H43A H 0.1553 -0.0536 0.7234 0.078 Uiso 1 1 calc R U
C42 C 0.1863(12) 0.0059(12) 0.6357(14) 0.054(5) Uani 1 1 d . .
H42A H 0.1792 -0.0368 0.6000 0.065 Uiso 1 1 calc R U
C41 C 0.2108(13) 0.0817(11) 0.6192(12) 0.048(5) Uani 1 1 d . .
H41A H 0.2210 0.0892 0.5709 0.057 Uiso 1 1 calc R U
Ag6 Ag 0.1073(2) 0.56782(19) 0.28518(13) 0.1037(9) Uani 1 1 d . .
N13 N 0.1007(11) 0.5208(17) 0.1674(12) 0.073(6) Uani 1 1 d . .
C61 C 0.0883(15) 0.443(2) 0.1394(19) 0.093(10) Uani 1 1 d . .
H61A H 0.0758 0.4054 0.1713 0.111 Uiso 1 1 calc R U
C62 C 0.093(2) 0.420(2) 0.070(2) 0.105(10) Uani 1 1 d . U
H62A H 0.0840 0.3677 0.0535 0.126 Uiso 1 1 calc R U
C63 C 0.112(3) 0.473(3) 0.025(3) 0.152(15) Uani 1 1 d . U
H63A H 0.1177 0.4555 -0.0233 0.182 Uiso 1 1 calc R U
C64 C 0.123(3) 0.550(3) 0.0413(15) 0.121(11) Uani 1 1 d D U
H64A H 0.1334 0.5854 0.0075 0.145 Uiso 1 1 calc R U
C65 C 0.1171(15) 0.569(2) 0.1183(14) 0.079(7) Uani 1 1 d D U
C66 C 0.1311(15) 0.6524(18) 0.1496(11) 0.067(6) Uani 1 1 d . U
C67 C 0.1469(18) 0.715(3) 0.1065(16) 0.094(11) Uani 1 1 d . .
H67A H 0.1481 0.7053 0.0559 0.113 Uiso 1 1 calc R U
C68 C 0.161(2) 0.791(2) 0.140(3) 0.114(15) Uani 1 1 d . .
H68A H 0.1662 0.8312 0.1109 0.136 Uiso 1 1 calc R U
C69 C 0.166(3) 0.808(2) 0.213(3) 0.123(15) Uani 1 1 d . .
H69A H 0.1787 0.8594 0.2358 0.147 Uiso 1 1 calc R U
C70 C 0.152(2) 0.748(2) 0.2496(18) 0.086(9) Uani 1 1 d . .
H70A H 0.1536 0.7591 0.3004 0.103 Uiso 1 1 calc R U
N14 N 0.1355(14) 0.6730(14) 0.2224(11) 0.069(6) Uani 1 1 d . .
O1W O 0.1280(11) 0.5025(10) 0.3710(9) 0.073(5) Uani 1 1 d . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
W W -0.8490 6.8722 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O5 W1 O42 103.5(5) . .
O5 W1 O89 99.7(5) . .
O42 W1 O89 91.0(4) . .
O5 W1 O83 99.1(5) . .
O42 W1 O83 156.7(4) . .
O89 W1 O83 90.5(4) . .
O5 W1 O44 97.6(5) . .
O42 W1 O44 85.0(4) . .
O89 W1 O44 162.7(4) . .
O83 W1 O44 86.6(4) . .
O5 W1 O34 170.2(5) . .
O42 W1 O34 85.9(3) . .
O89 W1 O34 82.6(4) . .
O83 W1 O34 71.3(3) . .
O44 W1 O34 80.3(4) . .
O4 W2 O66 99.5(5) . .
O4 W2 O61 103.4(5) . .
O66 W2 O61 157.0(4) . .
O4 W2 O29 98.6(5) . .
O66 W2 O29 91.3(4) . .
O61 W2 O29 85.7(4) . .
O4 W2 O89 98.8(5) . .
O66 W2 O89 88.9(4) . .
O61 W2 O89 87.1(4) . .
O29 W2 O89 162.3(4) . .
O4 W2 O57 171.9(4) . .
O66 W2 O57 72.4(3) . .
O61 W2 O57 84.6(3) . .
O29 W2 O57 81.9(4) . .
O89 W2 O57 81.4(4) . .
O10 W3 O79 98.9(5) . .
O10 W3 O013 102.5(5) . .
O79 W3 O013 91.3(4) . .
O10 W3 O98 100.6(5) . .
O79 W3 O98 90.7(4) . .
O013 W3 O98 156.2(4) . .
O10 W3 O65 97.1(5) . .
O79 W3 O65 164.1(4) . .
O013 W3 O65 85.0(4) . .
O98 W3 O65 86.7(4) . .
O10 W3 O25 171.9(4) . .
O79 W3 O25 84.0(4) . .
O013 W3 O25 84.9(4) . .
O98 W3 O25 71.7(3) . .
O65 W3 O25 80.3(4) . .
O39 W4 O30 100.9(5) . .
O39 W4 O15 98.2(5) . .
O30 W4 O15 91.9(4) . .
O39 W4 O81 102.6(4) . .
O30 W4 O81 156.4(4) . .
O15 W4 O81 86.6(4) . .
O39 W4 O79 98.1(5) . .
O30 W4 O79 88.5(4) . .
O15 W4 O79 163.3(4) . .
O81 W4 O79 86.4(4) . .
O39 W4 O55 172.3(4) . .
O30 W4 O55 71.4(3) . .
O15 W4 O55 82.8(4) . .
O81 W4 O55 85.1(3) . .
O79 W4 O55 81.5(3) . .
O41 W5 O012 100.3(5) . .
O41 W5 O61 102.3(4) . .
O012 W5 O61 90.3(4) . .
O41 W5 O108 99.7(4) . .
O012 W5 O108 91.2(4) . .
O61 W5 O108 157.3(4) . .
O41 W5 O95 96.7(4) . .
O012 W5 O95 163.0(4) . .
O61 W5 O95 85.4(4) . .
O108 W5 O95 86.6(4) . .
O41 W5 O19 172.1(4) . .
O012 W5 O19 82.2(4) . .
O61 W5 O19 85.1(4) . .
O108 W5 O19 72.6(3) . .
O95 W5 O19 81.1(3) . .
O17 W6 O105 100.1(5) . .
O17 W6 O42 103.2(5) . .
O105 W6 O42 156.7(4) . .
O17 W6 O90 99.9(5) . .
O105 W6 O90 91.1(4) . .
O42 W6 O90 85.8(4) . .
O17 W6 O012 97.1(5) . .
O105 W6 O012 89.2(4) . .
O42 W6 O012 87.2(4) . .
O90 W6 O012 162.7(4) . .
O17 W6 O12 172.3(4) . .
O105 W6 O12 72.5(3) . .
O42 W6 O12 84.2(4) . .
O90 W6 O12 82.6(4) . .
O012 W6 O12 80.9(4) . .
O11 W7 O37 102.6(4) . .
O11 W7 O99 98.0(4) . .
O37 W7 O99 89.9(4) . .
O11 W7 O30 100.1(5) . .
O37 W7 O30 157.1(4) . .
O99 W7 O30 90.6(4) . .
O11 W7 O52 97.1(5) . .
O37 W7 O52 85.4(4) . .
O99 W7 O52 164.9(4) . .
O30 W7 O52 88.3(4) . .
O11 W7 O55 172.7(4) . .
O37 W7 O55 84.6(3) . .
O99 W7 O55 83.1(3) . .
O30 W7 O55 72.7(4) . .
O52 W7 O55 82.1(4) . .
O26 W8 O98 99.3(4) . .
O26 W8 O96 98.9(5) . .
O98 W8 O96 91.4(4) . .
O26 W8 O99 97.6(5) . .
O98 W8 O99 89.5(4) . .
O96 W8 O99 163.1(4) . .
O26 W8 O62 103.5(4) . .
O98 W8 O62 157.2(4) . .
O96 W8 O62 85.9(4) . .
O99 W8 O62 86.7(4) . .
O26 W8 O25 172.3(4) . .
O98 W8 O25 73.0(3) . .
O96 W8 O25 81.9(4) . .
O99 W8 O25 82.2(3) . .
O62 W8 O25 84.2(3) . .
O2 W9 O94 98.6(5) . .
O2 W9 O62 100.6(5) . .
O94 W9 O62 91.0(4) . .
O2 W9 O66 100.3(4) . .
O94 W9 O66 90.6(4) . .
O62 W9 O66 158.6(4) . .
O2 W9 O78 96.7(5) . .
O94 W9 O78 164.7(4) . .
O62 W9 O78 85.1(4) . .
O66 W9 O78 87.8(4) . .
O2 W9 O57 173.5(4) . .
O94 W9 O57 83.9(3) . .
O62 W9 O57 85.3(4) . .
O66 W9 O57 73.6(3) . .
O78 W9 O57 81.0(4) . .
O7 W10 O16 99.1(5) . .
O7 W10 O83 98.8(5) . .
O16 W10 O83 92.1(4) . .
O7 W10 O37 103.1(5) . .
O16 W10 O37 86.4(4) . .
O83 W10 O37 158.0(4) . .
O7 W10 O94 96.1(4) . .
O16 W10 O94 164.3(4) . .
O83 W10 O94 89.2(4) . .
O37 W10 O94 86.6(4) . .
O7 W10 O34 172.1(4) . .
O16 W10 O34 83.9(4) . .
O83 W10 O34 73.7(4) . .
O37 W10 O34 84.3(3) . .
O94 W10 O34 81.4(3) . .
O110 W12 O44 102.4(5) . .
O110 W12 O90 102.7(5) . .
O44 W12 O90 86.7(4) . .
O110 W12 O46 101.6(5) . .
O44 W12 O46 90.0(4) . .
O90 W12 O46 155.7(4) . .
O110 W12 O20 100.8(5) . .
O44 W12 O20 156.8(4) . .
O90 W12 O20 87.6(4) . .
O46 W12 O20 86.0(4) . .
O110 W12 O18 170.5(4) . .
O44 W12 O18 84.5(4) . .
O90 W12 O18 84.0(4) . .
O46 W12 O18 71.7(4) . .
O20 W12 O18 72.5(4) . .
O36 W13 O67 99.3(5) . .
O36 W13 O81 102.1(5) . .
O67 W13 O81 89.7(4) . .
O36 W13 O105 101.2(5) . .
O67 W13 O105 90.2(4) . .
O81 W13 O105 156.4(4) . .
O36 W13 O88 97.6(5) . .
O67 W13 O88 163.0(4) . .
O81 W13 O88 85.0(4) . .
O105 W13 O88 88.4(4) . .
O36 W13 O12 173.3(4) . .
O67 W13 O12 82.2(3) . .
O81 W13 O12 84.4(4) . .
O105 W13 O12 72.2(4) . .
O88 W13 O12 81.3(4) . .
O22 W14 O72 98.0(5) . .
O22 W14 O108 101.1(4) . .
O72 W14 O108 91.4(4) . .
O22 W14 O67 98.6(4) . .
O72 W14 O67 162.7(4) . .
O108 W14 O67 90.2(4) . .
O22 W14 O013 101.6(5) . .
O72 W14 O013 84.6(4) . .
O108 W14 O013 157.2(4) . .
O67 W14 O013 87.2(4) . .
O22 W14 O19 174.4(4) . .
O72 W14 O19 82.6(4) . .
O108 W14 O19 73.2(3) . .
O67 W14 O19 81.4(3) . .
O013 W14 O19 84.0(3) . .
O130 W18 O95 102.6(5) . .
O130 W18 O49 102.2(5) . .
O95 W18 O49 91.2(4) . .
O130 W18 O29 102.1(5) . .
O95 W18 O29 85.9(4) . .
O49 W18 O29 155.6(4) . .
O130 W18 O111 101.2(5) . .
O95 W18 O111 156.0(4) . .
O49 W18 O111 86.7(4) . .
O29 W18 O111 86.2(4) . .
O130 W18 O60 171.4(4) . .
O95 W18 O60 84.5(3) . .
O49 W18 O60 72.5(4) . .
O29 W18 O60 83.1(4) . .
O111 W18 O60 72.1(4) . .
O6 W19 O65 102.6(5) . .
O6 W19 O40 100.5(5) . .
O65 W19 O40 90.4(4) . .
O6 W19 O72 102.7(5) . .
O65 W19 O72 86.1(4) . .
O40 W19 O72 156.8(4) . .
O6 W19 O49 100.2(5) . .
O65 W19 O49 157.0(4) . .
O40 W19 O49 87.5(5) . .
O72 W19 O49 87.0(4) . .
O6 W19 O60 171.0(5) . .
O65 W19 O60 84.6(4) . .
O40 W19 O60 73.9(4) . .
O72 W19 O60 83.0(4) . .
O49 W19 O60 72.8(3) . .
O1 W20 O88 101.8(5) . .
O1 W20 O20 102.1(5) . .
O88 W20 O20 92.7(4) . .
O1 W20 O15 101.5(5) . .
O88 W20 O15 85.4(4) . .
O20 W20 O15 156.2(4) . .
O1 W20 O32 101.0(5) . .
O88 W20 O32 156.8(4) . .
O20 W20 O32 86.7(4) . .
O15 W20 O32 85.9(4) . .
O1 W20 O18 171.7(5) . .
O88 W20 O18 85.6(4) . .
O20 W20 O18 73.5(4) . .
O15 W20 O18 82.7(4) . .
O32 W20 O18 72.0(4) . .
O3 W25 O78 101.9(5) . .
O3 W25 O111 101.9(5) . .
O78 W25 O111 91.8(4) . .
O3 W25 O40 100.1(5) . .
O78 W25 O40 157.5(4) . .
O111 W25 O40 88.4(5) . .
O3 W25 O96 101.6(5) . .
O78 W25 O96 85.1(4) . .
O111 W25 O96 156.4(4) . .
O40 W25 O96 85.8(4) . .
O3 W25 O60 172.3(5) . .
O78 W25 O60 84.9(4) . .
O111 W25 O60 73.9(4) . .
O40 W25 O60 73.5(3) . .
O96 W25 O60 82.5(4) . .
O131 W26 O32 101.0(5) . .
O131 W26 O52 102.0(5) . .
O32 W26 O52 91.6(4) . .
O131 W26 O46 100.5(5) . .
O32 W26 O46 88.2(4) . .
O52 W26 O46 157.2(4) . .
O131 W26 O16 101.2(5) . .
O32 W26 O16 157.7(4) . .
O52 W26 O16 84.7(4) . .
O46 W26 O16 86.9(4) . .
O131 W26 O18 171.6(5) . .
O32 W26 O18 73.9(4) . .
O52 W26 O18 85.1(4) . .
O46 W26 O18 72.9(4) . .
O16 W26 O18 83.9(4) . .
O7 Ag2 N4 151.6(4) 2_655 .
O7 Ag2 N3 107.0(4) 2_655 .
N4 Ag2 N3 72.7(5) . .
O7 Ag2 O11 111.4(4) 2_655 .
N4 Ag2 O11 93.2(4) . .
N3 Ag2 O11 115.2(4) . .
O7 Ag2 Ag3 122.6(3) 2_655 .
N4 Ag2 Ag3 82.7(3) . .
N3 Ag2 Ag3 60.2(3) . .
O11 Ag2 Ag3 55.3(2) . .
N6 Ag3 O2 154.0(6) . 2_655
N6 Ag3 N5 72.8(6) . .
O2 Ag3 N5 120.7(5) 2_655 .
N6 Ag3 Ag2 110.6(4) . .
O2 Ag3 Ag2 81.7(3) 2_655 .
N5 Ag3 Ag2 123.1(4) . .
O6W Ag1 N1 147.3(8) . .
O6W Ag1 N2 132.9(7) . .
N1 Ag1 N2 69.2(10) . .
O6W Ag1 O26 81.5(4) . .
N1 Ag1 O26 127.5(6) . .
N2 Ag1 O26 89.7(7) . .
C5 N1 C1 120(2) . .
C5 N1 Ag1 119(2) . .
C1 N1 Ag1 120.1(19) . .
C6 N2 C10 112(3) . .
C6 N2 Ag1 120(2) . .
C10 N2 Ag1 126.8(19) . .
C2 C1 N1 120(3) . .
C2 C1 H1A 120.1 . .
N1 C1 H1A 120.1 . .
C1 C2 C3 122(4) . .
C1 C2 H2A 119.0 . .
C3 C2 H2A 119.0 . .
C2 C3 C4 117(3) . .
C2 C3 H3A 121.6 . .
C4 C3 H3A 121.6 . .
C5 C4 C3 120(3) . .
C5 C4 H4A 120.0 . .
C3 C4 H4A 120.0 . .
N1 C5 C4 121(3) . .
N1 C5 C6 117(2) . .
C4 C5 C6 122(3) . .
N2 C6 C7 125(3) . .
N2 C6 C5 113(2) . .
C7 C6 C5 122(2) . .
C8 C7 C6 117(3) . .
C8 C7 H7A 121.4 . .
C6 C7 H7A 121.4 . .
C9 C8 C7 120(4) . .
C9 C8 H8A 120.0 . .
C7 C8 H8A 120.0 . .
C10 C9 C8 122(5) . .
C10 C9 H9A 118.8 . .
C8 C9 H9A 118.8 . .
C9 C10 N2 123(3) . .
C9 C10 H10A 118.7 . .
N2 C10 H10A 118.7 . .
O57 P1 O19 111.8(5) . .
O57 P1 O25 111.9(5) . .
O19 P1 O25 113.4(5) . .
O57 P1 O60 106.6(5) . .
O19 P1 O60 106.8(5) . .
O25 P1 O60 105.6(5) . .
O12 P2 O34 112.9(5) . .
O12 P2 O55 112.7(5) . .
O34 P2 O55 111.3(5) . .
O12 P2 O18 107.3(5) . .
O34 P2 O18 106.4(5) . .
O55 P2 O18 105.7(5) . .
W3 O013 W14 153.6(5) . .
W9 O2 Ag3 136.0(6) . 2_655
W5 O012 W6 163.9(5) . .
W10 O7 Ag2 133.8(6) . 2_655
W7 O11 Ag2 123.6(5) . .
P2 O12 W6 128.0(5) . .
P2 O12 W13 128.5(5) . .
W6 O12 W13 89.7(3) . .
W4 O15 W20 150.9(6) . .
W10 O16 W26 150.2(6) . .
P2 O18 W26 125.8(5) . .
P2 O18 W20 125.0(5) . .
W26 O18 W20 90.9(3) . .
P2 O18 W12 123.6(5) . .
W26 O18 W12 90.9(3) . .
W20 O18 W12 90.0(3) . .
P1 O19 W14 127.3(5) . .
P1 O19 W5 128.9(5) . .
W14 O19 W5 90.3(3) . .
W20 O20 W12 123.9(5) . .
P1 O25 W8 129.1(5) . .
P1 O25 W3 128.1(5) . .
W8 O25 W3 91.1(3) . .
W8 O26 Ag1 137.2(6) . .
W18 O29 W2 151.2(6) . .
W7 O30 W4 124.6(5) . .
W26 O32 W20 123.0(5) . .
P2 O34 W10 128.8(5) . .
P2 O34 W1 127.2(5) . .
W10 O34 W1 91.5(3) . .
W7 O37 W10 151.1(5) . .
W19 O40 W25 122.0(5) . .
W1 O42 W6 152.7(6) . .
W12 O44 W1 150.7(5) . .
W26 O46 W12 124.5(5) . .
W18 O49 W19 124.3(5) . .
W26 O52 W7 151.2(5) . .
P2 O55 W7 129.2(5) . .
P2 O55 W4 126.4(5) . .
W7 O55 W4 91.3(3) . .
P1 O57 W9 129.2(5) . .
P1 O57 W2 127.8(5) . .
W9 O57 W2 90.4(3) . .
P1 O60 W19 125.4(5) . .
P1 O60 W25 125.2(5) . .
W19 O60 W25 90.5(3) . .
P1 O60 W18 124.7(5) . .
W19 O60 W18 90.4(3) . .
W25 O60 W18 89.8(3) . .
W5 O61 W2 151.9(5) . .
W9 O62 W8 151.6(6) . .
W19 O65 W3 150.4(5) . .
W2 O66 W9 123.4(4) . .
W13 O67 W14 163.7(6) . .
W14 O72 W19 151.7(6) . .
W25 O78 W9 152.0(5) . .
W3 O79 W4 162.5(6) . .
W13 O81 W4 151.0(5) . .
W10 O83 W1 123.4(5) . .
W20 O88 W13 152.5(5) . .
W1 O89 W2 162.7(6) . .
W6 O90 W12 150.5(6) . .
W9 O94 W10 162.4(5) . .
W18 O95 W5 151.3(5) . .
W8 O96 W25 150.8(5) . .
W8 O98 W3 124.0(5) . .
W7 O99 W8 163.4(5) . .
W6 O105 W13 125.5(5) . .
W14 O108 W5 123.6(4) . .
W25 O111 W18 124.2(5) . .
C11 N3 C15 118.6(14) . .
C11 N3 Ag2 125.4(11) . .
C15 N3 Ag2 112.6(10) . .
C20 N4 C16 118.5(14) . .
C20 N4 Ag2 123.4(11) . .
C16 N4 Ag2 115.4(10) . .
C21 N5 C25 115(2) . .
C21 N5 Ag3 128.9(16) . .
C25 N5 Ag3 115.5(13) . .
C30 N6 C26 115.5(16) . .
C30 N6 Ag3 126.0(14) . .
C26 N6 Ag3 118.4(12) . .
N3 C11 C12 122.7(15) . .
N3 C11 H11A 118.7 . .
C12 C11 H11A 118.7 . .
C11 C12 C13 118.1(17) . .
C11 C12 H12A 120.9 . .
C13 C12 H12A 120.9 . .
C14 C13 C12 118.3(17) . .
C14 C13 H13A 120.8 . .
C12 C13 H13A 120.8 . .
C15 C14 C13 120.5(16) . .
C15 C14 H14A 119.8 . .
C13 C14 H14A 119.8 . .
C14 C15 N3 121.7(15) . .
C14 C15 C16 122.3(14) . .
N3 C15 C16 116.0(13) . .
N4 C16 C17 120.4(14) . .
N4 C16 C15 118.3(13) . .
C17 C16 C15 121.3(14) . .
C18 C17 C16 121.8(16) . .
C18 C17 H17A 119.1 . .
C16 C17 H17A 119.1 . .
C17 C18 C19 116.8(16) . .
C17 C18 H18A 121.6 . .
C19 C18 H18A 121.6 . .
C18 C19 C20 119.0(17) . .
C18 C19 H19A 120.5 . .
C20 C19 H19A 120.5 . .
N4 C20 C19 123.3(19) . .
N4 C20 H20A 118.3 . .
C19 C20 H20A 118.3 . .
N5 C21 C22 128(3) . .
N5 C21 H21A 115.8 . .
C22 C21 H21A 115.8 . .
C21 C22 C23 112(2) . .
C21 C22 H22A 123.9 . .
C23 C22 H22A 123.9 . .
C24 C23 C22 124(2) . .
C24 C23 H23A 118.1 . .
C22 C23 H23A 118.1 . .
C23 C24 C25 117(2) . .
C23 C24 H24A 121.5 . .
C25 C24 H24A 121.5 . .
N5 C25 C24 123.4(19) . .
N5 C25 C26 116.2(16) . .
C24 C25 C26 120.4(16) . .
N6 C26 C27 121.4(19) . .
N6 C26 C25 116.4(15) . .
C27 C26 C25 122.2(18) . .
C28 C27 C26 120(2) . .
C28 C27 H27A 120.0 . .
C26 C27 H27A 120.0 . .
C27 C28 C29 119(2) . .
C27 C28 H28A 120.5 . .
C29 C28 H28A 120.5 . .
C30 C29 C28 117(2) . .
C30 C29 H29A 121.5 . .
C28 C29 H29A 121.5 . .
C29 C30 N6 127(2) . .
C29 C30 H30A 116.5 . .
N6 C30 H30A 116.5 . .
N10 Ag5 N11 154.6(5) . .
N10 Ag5 N12 128.2(6) . .
N11 Ag5 N12 73.0(5) . .
N10 Ag5 Ag4 80.5(4) . .
N11 Ag5 Ag4 105.4(4) . .
N12 Ag5 Ag4 112.9(6) . .
N7 Ag4 N9 164.9(5) . .
N7 Ag4 N8 71.6(5) . .
N9 Ag4 N8 100.3(6) . .
N7 Ag4 Ag5 112.9(4) . .
N9 Ag4 Ag5 77.4(4) . .
N8 Ag4 Ag5 81.0(4) . .
C40 N8 C36 118(2) . .
C40 N8 Ag4 131.6(17) . .
C36 N8 Ag4 109.7(12) . .
C31 N7 C35 118.3(14) . .
C31 N7 Ag4 121.4(11) . .
C35 N7 Ag4 119.4(11) . .
C56 N12 C60 116.9(18) . .
C56 N12 Ag5 115.1(12) . .
C60 N12 Ag5 127.9(14) . .
C55 N11 C51 118.4(13) . .
C55 N11 Ag5 116.5(10) . .
C51 N11 Ag5 125.1(10) . .
C50 N10 C46 119.8(16) . .
C50 N10 Ag5 114.5(13) . .
C46 N10 Ag5 124.9(12) . .
C41 N9 C45 117.7(16) . .
C41 N9 Ag4 109.4(12) . .
C45 N9 Ag4 132.9(13) . .
C39 C40 N8 126(3) . .
C39 C40 H40A 117.2 . .
N8 C40 H40A 117.2 . .
C40 C39 C38 117(3) . .
C40 C39 H39A 121.3 . .
C38 C39 H39A 121.3 . .
C39 C38 C37 118(3) . .
C39 C38 H38A 120.8 . .
C37 C38 H38A 120.8 . .
C36 C37 C38 121(3) . .
C36 C37 H37A 119.3 . .
C38 C37 H37A 119.3 . .
C37 C36 N8 119(2) . .
C37 C36 C35 123(2) . .
N8 C36 C35 117.9(15) . .
N7 C35 C34 119.6(17) . .
N7 C35 C36 118.4(14) . .
C34 C35 C36 121.8(16) . .
C35 C34 C33 119(2) . .
C35 C34 H34A 120.6 . .
C33 C34 H34A 120.6 . .
C32 C33 C34 120.7(19) . .
C32 C33 H33A 119.7 . .
C34 C33 H33A 119.7 . .
C33 C32 C31 120(2) . .
C33 C32 H32A 120.2 . .
C31 C32 H32A 120.2 . .
N7 C31 C32 123(2) . .
N7 C31 H31A 118.5 . .
C32 C31 H31A 118.5 . .
C59 C60 N12 124(2) . .
C59 C60 H60A 117.8 . .
N12 C60 H60A 117.8 . .
C58 C59 C60 117.0(19) . .
C58 C59 H59A 121.5 . .
C60 C59 H59A 121.5 . .
C59 C58 C57 123.1(19) . .
C59 C58 H58A 118.5 . .
C57 C58 H58A 118.5 . .
C58 C57 C56 117.8(19) . .
C58 C57 H57A 121.1 . .
C56 C57 H57A 121.1 . .
N12 C56 C57 120.5(17) . .
N12 C56 C55 116.0(15) . .
C57 C56 C55 123.5(15) . .
N11 C55 C54 121.3(15) . .
N11 C55 C56 119.3(13) . .
C54 C55 C56 119.4(15) . .
C53 C54 C55 116.5(15) . .
C53 C54 H54A 121.8 . .
C55 C54 H54A 121.8 . .
C52 C53 C54 121.8(15) . .
C52 C53 H53A 119.1 . .
C54 C53 H53A 119.1 . .
C51 C52 C53 115.7(17) . .
C51 C52 H52A 122.2 . .
C53 C52 H52A 122.2 . .
N11 C51 C52 126.3(15) . .
N11 C51 H51A 116.9 . .
C52 C51 H51A 116.9 . .
N10 C50 C49 122(2) . .
N10 C50 H50A 118.9 . .
C49 C50 H50A 118.9 . .
C50 C49 C48 121(2) . .
C50 C49 H49A 119.7 . .
C48 C49 H49A 119.7 . .
C49 C48 C47 117.4(16) . .
C49 C48 H48A 121.3 . .
C47 C48 H48A 121.3 . .
C46 C47 C48 117.9(19) . .
C46 C47 H47A 121.0 . .
C48 C47 H47A 121.0 . .
N10 C46 C47 122.1(18) . .
N10 C46 C45 122.2(13) . .
C47 C46 C45 115.7(16) . .
C44 C45 N9 121.6(18) . .
C44 C45 C46 120.5(15) . .
N9 C45 C46 117.9(14) . .
C43 C44 C45 120.3(19) . .
C43 C44 H44A 119.8 . .
C45 C44 H44A 119.8 . .
C44 C43 C42 119(2) . .
C44 C43 H43A 120.3 . .
C42 C43 H43A 120.3 . .
C41 C42 C43 117(2) . .
C41 C42 H42A 121.6 . .
C43 C42 H42A 121.6 . .
N9 C41 C42 124(2) . .
N9 C41 H41A 117.9 . .
C42 C41 H41A 117.9 . .
O1W Ag6 N13 121.1(9) . .
O1W Ag6 N14 155.2(8) . .
N13 Ag6 N14 73.6(9) . .
C65 N13 C61 114(3) . .
C65 N13 Ag6 120(2) . .
C61 N13 Ag6 126(2) . .
C62 C61 N13 123(3) . .
C62 C61 H61A 118.5 . .
N13 C61 H61A 118.5 . .
C61 C62 C63 119(5) . .
C61 C62 H62A 120.4 . .
C63 C62 H62A 120.4 . .
C62 C63 C64 126(5) . .
C62 C63 H63A 116.9 . .
C64 C63 H63A 116.8 . .
C63 C64 C65 111(4) . .
C63 C64 H64A 124.6 . .
C65 C64 H64A 124.6 . .
N13 C65 C64 127(4) . .
N13 C65 C66 113(2) . .
C64 C65 C66 120(3) . .
N14 C66 C67 116(3) . .
N14 C66 C65 121(2) . .
C67 C66 C65 123(2) . .
C68 C67 C66 120(3) . .
C68 C67 H67A 120.0 . .
C66 C67 H67A 120.0 . .
C69 C68 C67 121(3) . .
C69 C68 H68A 119.4 . .
C67 C68 H68A 119.4 . .
C70 C69 C68 116(4) . .
C70 C69 H69A 122.0 . .
C68 C69 H69A 122.1 . .
C69 C70 N14 127(3) . .
C69 C70 H70A 116.4 . .
N14 C70 H70A 116.4 . .
C70 N14 C66 120(2) . .
C70 N14 Ag6 127.6(19) . .
C66 N14 Ag6 112.6(19) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
W1 O5 1.702(10) .
W1 O42 1.872(9) .
W1 O89 1.877(9) .
W1 O83 1.928(10) .
W1 O44 1.961(10) .
W1 O34 2.386(9) .
W2 O4 1.694(10) .
W2 O66 1.899(10) .
W2 O61 1.900(9) .
W2 O29 1.913(10) .
W2 O89 1.917(9) .
W2 O57 2.394(9) .
W3 O10 1.715(9) .
W3 O79 1.861(10) .
W3 O013 1.871(10) .
W3 O98 1.911(9) .
W3 O65 1.956(10) .
W3 O25 2.362(9) .
W4 O39 1.703(9) .
W4 O30 1.899(10) .
W4 O15 1.901(10) .
W4 O81 1.904(9) .
W4 O79 1.931(10) .
W4 O55 2.378(8) .
W5 O41 1.698(9) .
W5 O012 1.860(9) .
W5 O61 1.879(9) .
W5 O108 1.914(8) .
W5 O95 1.947(8) .
W5 O19 2.374(9) .
W6 O17 1.698(10) .
W6 O105 1.892(10) .
W6 O42 1.897(9) .
W6 O90 1.898(10) .
W6 O012 1.915(9) .
W6 O12 2.384(9) .
W7 O11 1.719(10) .
W7 O37 1.881(9) .
W7 O99 1.885(9) .
W7 O30 1.897(9) .
W7 O52 1.945(9) .
W7 O55 2.325(9) .
W8 O26 1.709(10) .
W8 O98 1.884(9) .
W8 O96 1.887(10) .
W8 O99 1.901(9) .
W8 O62 1.917(9) .
W8 O25 2.329(9) .
W9 O2 1.737(10) .
W9 O94 1.852(9) .
W9 O62 1.864(9) .
W9 O66 1.913(10) .
W9 O78 1.942(9) .
W9 O57 2.335(9) .
W10 O7 1.723(10) .
W10 O16 1.883(10) .
W10 O83 1.891(9) .
W10 O37 1.901(8) .
W10 O94 1.937(10) .
W10 O34 2.310(9) .
W12 O110 1.706(10) .
W12 O44 1.871(10) .
W12 O90 1.910(10) .
W12 O46 1.917(10) .
W12 O20 1.933(11) .
W12 O18 2.402(9) .
W13 O36 1.698(9) .
W13 O67 1.869(10) .
W13 O81 1.882(9) .
W13 O105 1.898(9) .
W13 O88 1.946(10) .
W13 O12 2.394(9) .
W14 O22 1.712(9) .
W14 O72 1.891(10) .
W14 O108 1.894(9) .
W14 O67 1.907(10) .
W14 O013 1.907(9) .
W14 O19 2.362(9) .
W18 O130 1.704(10) .
W18 O95 1.878(9) .
W18 O49 1.893(10) .
W18 O29 1.907(10) .
W18 O111 1.937(10) .
W18 O60 2.409(9) .
W19 O6 1.701(10) .
W19 O65 1.876(10) .
W19 O40 1.914(10) .
W19 O72 1.921(9) .
W19 O49 1.938(10) .
W19 O60 2.366(9) .
W20 O1 1.708(11) .
W20 O88 1.857(10) .
W20 O20 1.901(10) .
W20 O15 1.902(10) .
W20 O32 1.960(10) .
W20 O18 2.382(9) .
W25 O3 1.697(10) .
W25 O78 1.868(10) .
W25 O111 1.880(11) .
W25 O40 1.932(10) .
W25 O96 1.944(10) .
W25 O60 2.370(9) .
W26 O131 1.688(11) .
W26 O32 1.881(10) .
W26 O52 1.882(9) .
W26 O46 1.912(9) .
W26 O16 1.948(10) .
W26 O18 2.355(10) .
Ag2 O7 2.311(10) 2_655
Ag2 N4 2.316(13) .
Ag2 N3 2.426(14) .
Ag2 O11 2.565(10) .
Ag2 Ag3 3.310(3) .
Ag3 N6 2.225(15) .
Ag3 O2 2.232(10) 2_655
Ag3 N5 2.329(18) .
Ag1 O6W 2.258(14) .
Ag1 N1 2.265(19) .
Ag1 N2 2.33(3) .
Ag1 O26 2.585(11) .
N1 C5 1.35(4) .
N1 C1 1.38(4) .
N2 C6 1.32(3) .
N2 C10 1.45(5) .
C1 C2 1.36(4) .
C1 H1A 0.9300 .
C2 C3 1.40(4) .
C2 H2A 0.9300 .
C3 C4 1.40(4) .
C3 H3A 0.9300 .
C4 C5 1.38(4) .
C4 H4A 0.9300 .
C5 C6 1.47(4) .
C6 C7 1.42(4) .
C7 C8 1.34(6) .
C7 H7A 0.9300 .
C8 C9 1.31(5) .
C8 H8A 0.9300 .
C9 C10 1.30(6) .
C9 H9A 0.9300 .
C10 H10A 0.9300 .
P1 O57 1.513(9) .
P1 O19 1.523(10) .
P1 O25 1.532(10) .
P1 O60 1.574(8) .
P2 O12 1.513(10) .
P2 O34 1.532(9) .
P2 O55 1.536(9) .
P2 O18 1.591(9) .
O2 Ag3 2.232(10) 2_655
O7 Ag2 2.311(10) 2_655
N3 C11 1.31(2) .
N3 C15 1.355(19) .
N4 C20 1.31(2) .
N4 C16 1.356(19) .
N5 C21 1.32(3) .
N5 C25 1.35(2) .
N6 C30 1.34(3) .
N6 C26 1.37(2) .
C11 C12 1.38(2) .
C11 H11A 0.9300 .
C12 C13 1.40(2) .
C12 H12A 0.9300 .
C13 C14 1.36(3) .
C13 H13A 0.9300 .
C14 C15 1.35(2) .
C14 H14A 0.9300 .
C15 C16 1.52(2) .
C16 C17 1.38(2) .
C17 C18 1.37(3) .
C17 H17A 0.9300 .
C18 C19 1.38(3) .
C18 H18A 0.9300 .
C19 C20 1.39(3) .
C19 H19A 0.9300 .
C20 H20A 0.9300 .
C21 C22 1.37(4) .
C21 H21A 0.9300 .
C22 C23 1.39(4) .
C22 H22A 0.9300 .
C23 C24 1.35(3) .
C23 H23A 0.9300 .
C24 C25 1.36(3) .
C24 H24A 0.9300 .
C25 C26 1.49(3) .
C26 C27 1.39(2) .
C27 C28 1.36(4) .
C27 H27A 0.9300 .
C28 C29 1.40(4) .
C28 H28A 0.9300 .
C29 C30 1.33(3) .
C29 H29A 0.9300 .
C30 H30A 0.9300 .
Ag5 N10 2.160(14) .
Ag5 N11 2.244(12) .
Ag5 N12 2.330(18) .
Ag5 Ag4 2.933(2) .
Ag4 N7 2.172(12) .
Ag4 N9 2.189(14) .
Ag4 N8 2.500(18) .
N8 C40 1.33(3) .
N8 C36 1.35(2) .
N7 C31 1.35(2) .
N7 C35 1.38(2) .
N12 C56 1.33(2) .
N12 C60 1.38(2) .
N11 C55 1.33(2) .
N11 C51 1.33(2) .
N10 C50 1.31(2) .
N10 C46 1.34(2) .
N9 C41 1.32(2) .
N9 C45 1.37(2) .
C40 C39 1.32(4) .
C40 H40A 0.9300 .
C39 C38 1.34(4) .
C39 H39A 0.9300 .
C38 C37 1.41(4) .
C38 H38A 0.9300 .
C37 C36 1.34(3) .
C37 H37A 0.9300 .
C36 C35 1.46(3) .
C35 C34 1.38(2) .
C34 C33 1.41(3) .
C34 H34A 0.9300 .
C33 C32 1.31(4) .
C33 H33A 0.9300 .
C32 C31 1.36(3) .
C32 H32A 0.9300 .
C31 H31A 0.9300 .
C60 C59 1.36(3) .
C60 H60A 0.9300 .
C59 C58 1.31(3) .
C59 H59A 0.9300 .
C58 C57 1.37(3) .
C58 H58A 0.9300 .
C57 C56 1.42(2) .
C57 H57A 0.9300 .
C56 C55 1.49(2) .
C55 C54 1.41(2) .
C54 C53 1.40(3) .
C54 H54A 0.9300 .
C53 C52 1.37(2) .
C53 H53A 0.9300 .
C52 C51 1.34(2) .
C52 H52A 0.9300 .
C51 H51A 0.9300 .
C50 C49 1.37(3) .
C50 H50A 0.9300 .
C49 C48 1.38(4) .
C49 H49A 0.9300 .
C48 C47 1.42(3) .
C48 H48A 0.9300 .
C47 C46 1.38(2) .
C47 H47A 0.9300 .
C46 C45 1.50(3) .
C45 C44 1.36(2) .
C44 C43 1.35(3) .
C44 H44A 0.9300 .
C43 C42 1.41(3) .
C43 H43A 0.9300 .
C42 C41 1.38(3) .
C42 H42A 0.9300 .
C41 H41A 0.9300 .
Ag6 O1W 2.159(16) .
Ag6 N13 2.22(2) .
Ag6 N14 2.274(19) .
N13 C65 1.31(3) .
N13 C61 1.39(4) .
C61 C62 1.31(5) .
C61 H61A 0.9300 .
C62 C63 1.31(6) .
C62 H62A 0.9300 .
C63 C64 1.34(6) .
C63 H63A 0.9300 .
C64 C65 1.438(10) .
C64 H64A 0.9300 .
C65 C66 1.49(4) .
C66 N14 1.34(3) .
C66 C67 1.42(4) .
C67 C68 1.38(5) .
C67 H67A 0.9300 .
C68 C69 1.33(6) .
C68 H68A 0.9300 .
C69 C70 1.31(4) .
C69 H69A 0.9300 .
C70 N14 1.33(4) .
C70 H70A 0.9300 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_4
C5 N1 C1 C2 -2(4) .
Ag1 N1 C1 C2 170(2) .
N1 C1 C2 C3 1(5) .
C1 C2 C3 C4 3(5) .
C2 C3 C4 C5 -6(5) .
C1 N1 C5 C4 -1(4) .
Ag1 N1 C5 C4 -172(2) .
C1 N1 C5 C6 -178(2) .
Ag1 N1 C5 C6 10(3) .
C3 C4 C5 N1 5(5) .
C3 C4 C5 C6 -178(3) .
C10 N2 C6 C7 4(4) .
Ag1 N2 C6 C7 -169(2) .
C10 N2 C6 C5 -180(2) .
Ag1 N2 C6 C5 7(3) .
N1 C5 C6 N2 -11(3) .
C4 C5 C6 N2 171(3) .
N1 C5 C6 C7 165(2) .
C4 C5 C6 C7 -12(4) .
N2 C6 C7 C8 -9(4) .
C5 C6 C7 C8 175(3) .
C6 C7 C8 C9 9(5) .
C7 C8 C9 C10 -4(6) .
C8 C9 C10 N2 -2(6) .
C6 N2 C10 C9 2(5) .
Ag1 N2 C10 C9 174(3) .
O10 W3 O013 W14 127.3(12) .
O79 W3 O013 W14 -133.3(12) .
O98 W3 O013 W14 -38.8(19) .
O65 W3 O013 W14 31.2(12) .
O25 W3 O013 W14 -49.5(12) .
O94 W9 O2 Ag3 75.5(9) 2_655
O62 W9 O2 Ag3 168.1(8) 2_655
O66 W9 O2 Ag3 -16.7(10) 2_655
O78 W9 O2 Ag3 -105.7(9) 2_655
O41 W5 O012 W6 98(2) .
O61 W5 O012 W6 -4(2) .
O108 W5 O012 W6 -162(2) .
O95 W5 O012 W6 -79(3) .
O19 W5 O012 W6 -90(2) .
O16 W10 O7 Ag2 161.1(7) 2_655
O83 W10 O7 Ag2 67.6(8) 2_655
O37 W10 O7 Ag2 -110.5(8) 2_655
O94 W10 O7 Ag2 -22.6(8) 2_655
O37 W7 O11 Ag2 100.5(6) .
O99 W7 O11 Ag2 8.8(6) .
O30 W7 O11 Ag2 -83.2(6) .
O52 W7 O11 Ag2 -172.7(5) .
O34 P2 O12 W6 53.6(8) .
O55 P2 O12 W6 -179.2(5) .
O18 P2 O12 W6 -63.3(7) .
O34 P2 O12 W13 -178.6(6) .
O55 P2 O12 W13 -51.5(8) .
O18 P2 O12 W13 64.5(7) .
O7 W10 O16 W26 134.7(11) .
O83 W10 O16 W26 -126.0(11) .
O37 W10 O16 W26 32.1(11) .
O94 W10 O16 W26 -31(2) .
O34 W10 O16 W26 -52.6(11) .
O12 P2 O18 W26 -178.7(6) .
O34 P2 O18 W26 60.2(7) .
O55 P2 O18 W26 -58.3(7) .
O12 P2 O18 W20 -56.7(7) .
O34 P2 O18 W20 -177.8(5) .
O55 P2 O18 W20 63.8(7) .
O12 P2 O18 W12 61.1(7) .
O34 P2 O18 W12 -60.0(7) .
O55 P2 O18 W12 -178.4(5) .
O57 P1 O19 W14 -179.4(5) .
O25 P1 O19 W14 52.9(7) .
O60 P1 O19 W14 -63.1(7) .
O57 P1 O19 W5 -50.8(8) .
O25 P1 O19 W5 -178.6(5) .
O60 P1 O19 W5 65.5(7) .
O57 P1 O25 W8 51.4(8) .
O19 P1 O25 W8 179.1(5) .
O60 P1 O25 W8 -64.2(7) .
O57 P1 O25 W3 -176.6(5) .
O19 P1 O25 W3 -48.9(8) .
O60 P1 O25 W3 67.8(7) .
O98 W8 O26 Ag1 -124.3(7) .
O96 W8 O26 Ag1 -31.4(8) .
O99 W8 O26 Ag1 144.9(7) .
O62 W8 O26 Ag1 56.5(8) .
O11 W7 O30 W4 178.3(7) .
O37 W7 O30 W4 -10.9(15) .
O99 W7 O30 W4 80.1(7) .
O52 W7 O30 W4 -84.9(7) .
O55 W7 O30 W4 -2.6(5) .
O39 W4 O30 W7 -177.0(7) .
O15 W4 O30 W7 84.2(7) .
O81 W4 O30 W7 -1.6(15) .
O79 W4 O30 W7 -79.0(7) .
O55 W4 O30 W7 2.5(5) .
O131 W26 O32 W20 -170.5(6) .
O52 W26 O32 W20 87.0(6) .
O46 W26 O32 W20 -70.1(6) .
O16 W26 O32 W20 7.3(15) .
O18 W26 O32 W20 2.6(5) .
O12 P2 O34 W10 -180.0(6) .
O55 P2 O34 W10 52.2(8) .
O18 P2 O34 W10 -62.5(7) .
O12 P2 O34 W1 -49.2(8) .
O55 P2 O34 W1 -177.0(6) .
O18 P2 O34 W1 68.3(7) .
O11 W7 O37 W10 126.8(11) .
O99 W7 O37 W10 -135.1(11) .
O30 W7 O37 W10 -44.0(18) .
O52 W7 O37 W10 30.6(11) .
O55 W7 O37 W10 -52.0(11) .
O5 W1 O42 W6 128.4(11) .
O89 W1 O42 W6 -131.3(11) .
O83 W1 O42 W6 -37.6(18) .
O44 W1 O42 W6 31.8(11) .
O34 W1 O42 W6 -48.8(11) .
O17 W6 O42 W1 -131.8(11) .
O105 W6 O42 W1 50.3(18) .
O90 W6 O42 W1 -32.6(11) .
O012 W6 O42 W1 131.6(11) .
O12 W6 O42 W1 50.4(11) .
O110 W12 O44 W1 127.0(11) .
O90 W12 O44 W1 24.7(11) .
O46 W12 O44 W1 -131.2(11) .
O20 W12 O44 W1 -51.5(18) .
O18 W12 O44 W1 -59.6(11) .
O130 W18 O49 W19 -171.8(7) .
O95 W18 O49 W19 85.0(7) .
O29 W18 O49 W19 2.3(15) .
O111 W18 O49 W19 -71.1(7) .
O60 W18 O49 W19 1.1(6) .
O131 W26 O52 W7 133.4(12) .
O32 W26 O52 W7 -125.0(12) .
O46 W26 O52 W7 -35.8(19) .
O16 W26 O52 W7 33.0(12) .
O18 W26 O52 W7 -51.2(12) .
O12 P2 O55 W7 -177.7(5) .
O34 P2 O55 W7 -49.7(8) .
O18 P2 O55 W7 65.4(7) .
O12 P2 O55 W4 52.8(7) .
O34 P2 O55 W4 -179.2(5) .
O18 P2 O55 W4 -64.1(7) .
O19 P1 O57 W9 -177.3(6) .
O25 P1 O57 W9 -48.8(8) .
O60 P1 O57 W9 66.2(7) .
O19 P1 O57 W2 52.3(7) .
O25 P1 O57 W2 -179.1(5) .
O60 P1 O57 W2 -64.1(7) .
O57 P1 O60 W19 -178.1(6) .
O19 P1 O60 W19 62.2(7) .
O25 P1 O60 W19 -58.9(7) .
O57 P1 O60 W25 -57.1(7) .
O19 P1 O60 W25 -176.8(5) .
O25 P1 O60 W25 62.1(6) .
O57 P1 O60 W18 61.8(7) .
O19 P1 O60 W18 -58.0(7) .
O25 P1 O60 W18 -179.0(5) .
O41 W5 O61 W2 127.5(12) .
O012 W5 O61 W2 -131.9(12) .
O108 W5 O61 W2 -38.0(19) .
O95 W5 O61 W2 31.7(12) .
O19 W5 O61 W2 -49.7(12) .
O4 W2 O61 W5 -129.4(12) .
O66 W2 O61 W5 51.8(18) .
O29 W2 O61 W5 -31.5(12) .
O89 W2 O61 W5 132.3(12) .
O57 W2 O61 W5 50.7(12) .
O2 W9 O62 W8 127.9(11) .
O94 W9 O62 W8 -133.2(11) .
O66 W9 O62 W8 -39.1(19) .
O78 W9 O62 W8 32.0(11) .
O57 W9 O62 W8 -49.4(11) .
O6 W19 O65 W3 128.4(12) .
O40 W19 O65 W3 -130.8(12) .
O72 W19 O65 W3 26.3(11) .
O49 W19 O65 W3 -46.4(19) .
O60 W19 O65 W3 -57.0(11) .
O4 W2 O66 W9 -176.0(6) .
O61 W2 O66 W9 2.8(14) .
O29 W2 O66 W9 85.0(6) .
O89 W2 O66 W9 -77.3(6) .
O57 W2 O66 W9 3.9(5) .
O36 W13 O67 W14 99.1(19) .
O81 W13 O67 W14 -3.1(19) .
O105 W13 O67 W14 -159.5(19) .
O88 W13 O67 W14 -74(2) .
O12 W13 O67 W14 -87.5(19) .
O22 W14 O72 W19 129.4(12) .
O108 W14 O72 W19 -129.1(11) .
O67 W14 O72 W19 -34(2) .
O013 W14 O72 W19 28.4(11) .
O19 W14 O72 W19 -56.2(11) .
O3 W25 O78 W9 130.8(12) .
O111 W25 O78 W9 -126.6(12) .
O40 W25 O78 W9 -37(2) .
O96 W25 O78 W9 30.0(12) .
O60 W25 O78 W9 -53.0(12) .
O10 W3 O79 W4 104.1(17) .
O013 W3 O79 W4 1.2(17) .
O98 W3 O79 W4 -155.1(17) .
O65 W3 O79 W4 -75(2) .
O25 W3 O79 W4 -83.6(17) .
O36 W13 O81 W4 125.5(11) .
O67 W13 O81 W4 -135.1(11) .
O105 W13 O81 W4 -45.4(18) .
O88 W13 O81 W4 28.8(11) .
O12 W13 O81 W4 -52.9(11) .
O7 W10 O83 W1 -173.7(7) .
O16 W10 O83 W1 86.7(7) .
O37 W10 O83 W1 1.3(16) .
O94 W10 O83 W1 -77.6(7) .
O34 W10 O83 W1 3.7(6) .
O1 W20 O88 W13 130.5(12) .
O20 W20 O88 W13 -126.6(12) .
O15 W20 O88 W13 29.6(12) .
O32 W20 O88 W13 -39(2) .
O18 W20 O88 W13 -53.4(12) .
O5 W1 O89 W2 100(2) .
O42 W1 O89 W2 -4(2) .
O83 W1 O89 W2 -160(2) .
O44 W1 O89 W2 -80(3) .
O34 W1 O89 W2 -89(2) .
O17 W6 O90 W12 130.1(11) .
O105 W6 O90 W12 -129.4(11) .
O42 W6 O90 W12 27.5(11) .
O012 W6 O90 W12 -39(2) .
O12 W6 O90 W12 -57.2(11) .
O2 W9 O94 W10 102.6(17) .
O62 W9 O94 W10 1.7(17) .
O66 W9 O94 W10 -156.9(17) .
O78 W9 O94 W10 -73(3) .
O57 W9 O94 W10 -83.5(17) .
O130 W18 O95 W5 128.3(11) .
O49 W18 O95 W5 -128.8(11) .
O29 W18 O95 W5 26.9(11) .
O111 W18 O95 W5 -44.1(17) .
O60 W18 O95 W5 -56.6(11) .
O26 W8 O96 W25 130.1(12) .
O98 W8 O96 W25 -130.2(12) .
O99 W8 O96 W25 -37(2) .
O62 W8 O96 W25 27.1(12) .
O25 W8 O96 W25 -57.6(12) .
O26 W8 O98 W3 -175.6(6) .
O96 W8 O98 W3 85.2(6) .
O99 W8 O98 W3 -78.0(6) .
O62 W8 O98 W3 2.5(15) .
O25 W8 O98 W3 4.0(5) .
O11 W7 O99 W8 104.6(18) .
O37 W7 O99 W8 1.9(18) .
O30 W7 O99 W8 -155.1(18) .
O52 W7 O99 W8 -70(3) .
O55 W7 O99 W8 -82.7(18) .
O17 W6 O105 W13 -174.7(7) .
O42 W6 O105 W13 3.2(15) .
O90 W6 O105 W13 85.0(7) .
O012 W6 O105 W13 -77.7(7) .
O12 W6 O105 W13 3.1(6) .
O36 W13 O105 W6 178.1(7) .
O67 W13 O105 W6 78.7(7) .
O81 W13 O105 W6 -10.9(15) .
O88 W13 O105 W6 -84.4(7) .
O12 W13 O105 W6 -3.1(6) .
O22 W14 O108 W5 -175.4(6) .
O72 W14 O108 W5 86.2(6) .
O67 W14 O108 W5 -76.6(6) .
O013 W14 O108 W5 6.7(13) .
O19 W14 O108 W5 4.3(5) .
O3 W25 O111 W18 -171.8(7) .
O78 W25 O111 W18 85.7(6) .
O40 W25 O111 W18 -71.8(6) .
O96 W25 O111 W18 3.7(15) .
O60 W25 O111 W18 1.5(5) .
C15 N3 C11 C12 -2(2) .
Ag2 N3 C11 C12 155.2(13) .
N3 C11 C12 C13 2(3) .
C11 C12 C13 C14 -2(3) .
C12 C13 C14 C15 3(3) .
C13 C14 C15 N3 -3(3) .
C13 C14 C15 C16 178.4(17) .
C11 N3 C15 C14 3(2) .
Ag2 N3 C15 C14 -157.5(15) .
C11 N3 C15 C16 -178.6(13) .
Ag2 N3 C15 C16 21.1(16) .
C20 N4 C16 C17 -1(2) .
Ag2 N4 C16 C17 -163.0(11) .
C20 N4 C16 C15 179.2(14) .
Ag2 N4 C16 C15 17.4(15) .
C14 C15 C16 N4 151.6(16) .
N3 C15 C16 N4 -27.0(19) .
C14 C15 C16 C17 -28(2) .
N3 C15 C16 C17 153.5(15) .
N4 C16 C17 C18 3(2) .
C15 C16 C17 C18 -177.5(16) .
C16 C17 C18 C19 -4(3) .
C17 C18 C19 C20 4(3) .
C16 N4 C20 C19 1(3) .
Ag2 N4 C20 C19 161.5(14) .
C18 C19 C20 N4 -3(3) .
C25 N5 C21 C22 -2(3) .
Ag3 N5 C21 C22 170.4(18) .
N5 C21 C22 C23 1(4) .
C21 C22 C23 C24 2(4) .
C22 C23 C24 C25 -3(4) .
C21 N5 C25 C24 1(3) .
Ag3 N5 C25 C24 -172.3(17) .
C21 N5 C25 C26 -177.0(17) .
Ag3 N5 C25 C26 9.6(18) .
C23 C24 C25 N5 1(3) .
C23 C24 C25 C26 179(2) .
C30 N6 C26 C27 1(3) .
Ag3 N6 C26 C27 -178.7(15) .
C30 N6 C26 C25 -178.8(17) .
Ag3 N6 C26 C25 2(2) .
N5 C25 C26 N6 -8(2) .
C24 C25 C26 N6 173.9(19) .
N5 C25 C26 C27 172.8(18) .
C24 C25 C26 C27 -5(3) .
N6 C26 C27 C28 -2(3) .
C25 C26 C27 C28 177.1(19) .
C26 C27 C28 C29 2(4) .
C27 C28 C29 C30 0(4) .
C28 C29 C30 N6 -2(4) .
C26 N6 C30 C29 2(4) .
Ag3 N6 C30 C29 -179(2) .
C36 N8 C40 C39 -4(4) .
Ag4 N8 C40 C39 166(2) .
N8 C40 C39 C38 -2(5) .
C40 C39 C38 C37 3(5) .
C39 C38 C37 C36 2(5) .
C38 C37 C36 N8 -8(4) .
C38 C37 C36 C35 177(3) .
C40 N8 C36 C37 9(3) .
Ag4 N8 C36 C37 -163.4(19) .
C40 N8 C36 C35 -176.2(19) .
Ag4 N8 C36 C35 11.8(18) .
C31 N7 C35 C34 1(2) .
Ag4 N7 C35 C34 170.9(12) .
C31 N7 C35 C36 175.8(14) .
Ag4 N7 C35 C36 -14.1(18) .
C37 C36 C35 N7 175(2) .
N8 C36 C35 N7 0(2) .
C37 C36 C35 C34 -10(3) .
N8 C36 C35 C34 174.5(16) .
N7 C35 C34 C33 0(2) .
C36 C35 C34 C33 -174.8(15) .
C35 C34 C33 C32 -3(3) .
C34 C33 C32 C31 5(3) .
C35 N7 C31 C32 1(2) .
Ag4 N7 C31 C32 -168.5(13) .
C33 C32 C31 N7 -5(3) .
C56 N12 C60 C59 4(4) .
Ag5 N12 C60 C59 -179(2) .
N12 C60 C59 C58 -4(4) .
C60 C59 C58 C57 2(4) .
C59 C58 C57 C56 1(4) .
C60 N12 C56 C57 -1(3) .
Ag5 N12 C56 C57 -178.9(14) .
C60 N12 C56 C55 -180(2) .
Ag5 N12 C56 C55 3(2) .
C58 C57 C56 N12 -1(3) .
C58 C57 C56 C55 177(2) .
C51 N11 C55 C54 -1(3) .
Ag5 N11 C55 C54 179.0(14) .
C51 N11 C55 C56 180.0(17) .
Ag5 N11 C55 C56 0(2) .
N12 C56 C55 N11 -2(3) .
C57 C56 C55 N11 179.6(17) .
N12 C56 C55 C54 179.1(19) .
C57 C56 C55 C54 1(3) .
N11 C55 C54 C53 3(3) .
C56 C55 C54 C53 -178.3(17) .
C55 C54 C53 C52 -3(3) .
C54 C53 C52 C51 2(3) .
C55 N11 C51 C52 0(3) .
Ag5 N11 C51 C52 179.4(18) .
C53 C52 C51 N11 0(4) .
C46 N10 C50 C49 0(3) .
Ag5 N10 C50 C49 171.1(18) .
N10 C50 C49 C48 0(4) .
C50 C49 C48 C47 0(3) .
C49 C48 C47 C46 -1(3) .
C50 N10 C46 C47 -1(3) .
Ag5 N10 C46 C47 -171.0(13) .
C50 N10 C46 C45 178.5(17) .
Ag5 N10 C46 C45 9(2) .
C48 C47 C46 N10 1(3) .
C48 C47 C46 C45 -178.4(17) .
C41 N9 C45 C44 -4(2) .
Ag4 N9 C45 C44 173.7(12) .
C41 N9 C45 C46 176.9(16) .
Ag4 N9 C45 C46 -5(2) .
N10 C46 C45 C44 -133.0(17) .
C47 C46 C45 C44 47(2) .
N10 C46 C45 N9 46(2) .
C47 C46 C45 N9 -134.4(16) .
N9 C45 C44 C43 3(3) .
C46 C45 C44 C43 -178.2(17) .
C45 C44 C43 C42 -1(3) .
C44 C43 C42 C41 -1(3) .
C45 N9 C41 C42 3(3) .
Ag4 N9 C41 C42 -175.2(17) .
C43 C42 C41 N9 -1(3) .
C65 N13 C61 C62 1(4) .
Ag6 N13 C61 C62 -173(3) .
N13 C61 C62 C63 1(6) .
C61 C62 C63 C64 -3(8) .
C62 C63 C64 C65 4(7) .
C61 N13 C65 C64 0(4) .
Ag6 N13 C65 C64 174(3) .
C61 N13 C65 C66 -179(2) .
Ag6 N13 C65 C66 -5(3) .
C63 C64 C65 N13 -2(5) .
C63 C64 C65 C66 177(3) .
N13 C65 C66 N14 7(4) .
C64 C65 C66 N14 -172(3) .
N13 C65 C66 C67 -178(2) .
C64 C65 C66 C67 3(4) .
N14 C66 C67 C68 -4(4) .
C65 C66 C67 C68 -179(3) .
C66 C67 C68 C69 6(5) .
C67 C68 C69 C70 -4(6) .
C68 C69 C70 N14 2(6) .
C69 C70 N14 C66 -1(5) .
C69 C70 N14 Ag6 -178(3) .
C67 C66 N14 C70 2(4) .
C65 C66 N14 C70 177(3) .
C67 C66 N14 Ag6 179.2(18) .
C65 C66 N14 Ag6 -6(3) .
