#------------------------------------------------------------------------------
#$Date: 2017-11-21 06:07:45 +0200 (Tue, 21 Nov 2017) $
#$Revision: 203405 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/04/48/7044821.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7044821
loop_
_publ_author_name
'Wang, Xiuli'
'Zhang, Shan'
'Wang, Xiang'
'Liu, Guo Cheng'
'Lin, Hongyan'
'Zhang, Huixiu'
_publ_section_title
;
 Various Polyoxomolybdate-based Hybrids Induced by pH and Solvents:
 Structures, Adsorption Activities for Dyes and Bifunctional
 Electrocatalytic Properties
;
_journal_name_full               'Dalton Transactions'
_journal_paper_doi               10.1039/C7DT03618C
_journal_year                    2017
_chemical_formula_sum            'C58 H36 Co2 Mo8 N22 O40'
_chemical_formula_weight         2566.47
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_Hall           '-C 2yc'
_space_group_name_H-M_alt        'C 1 2/c 1'
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2017-08-30 deposited with the CCDC.
2017-11-08 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 98.740(2)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   18.1219(11)
_cell_length_b                   17.2253(11)
_cell_length_c                   27.7704(16)
_cell_measurement_reflns_used    2050
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      25.147
_cell_measurement_theta_min      1.484
_cell_volume                     8568.0(9)
_computing_cell_refinement       'SMART (Bruker, 2001)'
_computing_data_collection       'SMART (Bruker, 2001)'
_computing_data_reduction        'SAINT+ (Bruker, 1999)'
_computing_molecular_graphics    'SHELXS-97 (Sheldrick, 2008)'
_computing_publication_material  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0803
_diffrn_reflns_av_unetI/netI     0.0866
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.999
_diffrn_reflns_limit_h_max       21
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       29
_diffrn_reflns_limit_l_min       -33
_diffrn_reflns_number            24662
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.999
_diffrn_reflns_theta_full        25.147
_diffrn_reflns_theta_max         25.147
_diffrn_reflns_theta_min         1.484
_diffrn_source                   'fine-focus sealed tube'
_exptl_absorpt_coefficient_mu    1.608
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            pink
_exptl_crystal_density_diffrn    1.990
_exptl_crystal_description       block
_exptl_crystal_F_000             4992
_exptl_crystal_size_max          0.25
_exptl_crystal_size_mid          0.23
_exptl_crystal_size_min          0.2
_exptl_transmission_factor_max   0.725
_exptl_transmission_factor_min   0.676
_refine_diff_density_max         0.717
_refine_diff_density_min         -0.711
_refine_diff_density_rms         0.150
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.009
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     587
_refine_ls_number_reflns         7644
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.009
_refine_ls_R_factor_all          0.0866
_refine_ls_R_factor_gt           0.0454
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0468P)²+8.2968P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0977
_refine_ls_wR_factor_ref         0.1127
_reflns_Friedel_coverage         0.000
_reflns_number_gt                5098
_reflns_number_total             7644
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c7dt03618c2.cif
_cod_data_source_block           4
_cod_database_code               7044821
_shelx_shelxl_version_number     2014/7
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
Mo1 Mo -0.37101(3) 0.64651(4) 0.45417(2) 0.02051(16) Uani 1 1 d . . .
Co1 Co -0.16230(5) 0.46229(6) 0.68526(3) 0.0196(2) Uani 1 1 d . . .
C1 C -0.2242(4) 0.4128(5) 0.5755(3) 0.0309(19) Uani 1 1 d . . .
H1A H -0.2511 0.4572 0.5650 0.037 Uiso 1 1 calc R U .
O1 O -0.0717(2) 0.5317(3) 0.66614(17) 0.0242(12) Uani 1 1 d . . .
N1 N -0.2179(3) 0.5620(3) 0.6555(2) 0.0221(14) Uani 1 1 d . . .
O1W O 0.5263(3) 0.3915(4) 0.81517(19) 0.0435(16) Uani 1 1 d . . .
Mo2 Mo -0.46793(3) 0.45660(4) 0.55476(2) 0.01453(15) Uani 1 1 d . . .
O2 O -0.1006(3) 0.3558(3) 0.69938(16) 0.0254(12) Uani 1 1 d . . .
N2 N -0.1838(3) 0.4042(4) 0.6183(2) 0.0249(15) Uani 1 1 d . . .
C2 C -0.1075(8) 0.5863(8) 0.4438(9) 0.162(11) Uani 1 1 d . . .
Mo3 Mo -0.50212(3) 0.65340(4) 0.54505(2) 0.01833(16) Uani 1 1 d . . .
N3 N -0.2211(3) 0.3476(4) 0.5486(2) 0.0296(16) Uani 1 1 d . . .
H3D H -0.2436 0.3407 0.5193 0.035 Uiso 1 1 calc R U .
C3 C -0.1425(8) 0.5818(10) 0.5008(4) 0.109(6) Uani 1 1 d . . .
O3 O -0.1609(4) 0.5790(5) 0.4097(3) 0.069(2) Uani 1 1 d . . .
Mo4 Mo -0.36197(3) 0.45726(4) 0.43173(2) 0.01667(15) Uani 1 1 d . . .
N4 N 0.2047(3) 0.5318(4) 0.6774(2) 0.0248(15) Uani 1 1 d . . .
H4D H 0.2420 0.5186 0.6634 0.030 Uiso 1 1 calc R U .
C4 C -0.0275(7) 0.6035(8) 0.3944(5) 0.089(4) Uani 1 1 d . . .
O4 O -0.2882(3) 0.6441(3) 0.40623(19) 0.0415(15) Uani 1 1 d . . .
N5 N 0.2601(3) 0.4242(4) 0.7895(2) 0.0209(14) Uani 1 1 d . . .
C5 C 0.0069(7) 0.6054(8) 0.4930(6) 0.121(6) Uani 1 1 d . . .
O5 O -0.4514(2) 0.5462(3) 0.41099(15) 0.0186(11) Uani 1 1 d . . .
N6 N -0.0458(3) 0.6465(4) 0.6300(2) 0.0274(15) Uani 1 1 d . . .
H6B H -0.0666 0.6891 0.6190 0.033 Uiso 1 1 calc R U .
C6 C 0.0000 0.2431(6) 0.7500 0.022(2) Uani 1 2 d S T P
H6A H 0.0000 0.2971 0.7500 0.027 Uiso 1 2 calc R U P
O6 O -0.3310(3) 0.4704(3) 0.37711(17) 0.0260(12) Uani 1 1 d . . .
N7 N -0.0556(9) 0.5909(7) 0.4548(7) 0.182(10) Uani 1 1 d . . .
C7 C 0.3399(4) 0.4540(5) 0.7378(3) 0.0298(19) Uani 1 1 d . . .
H7A H 0.3598 0.4726 0.7111 0.036 Uiso 1 1 calc R U .
O7 O -0.4268(2) 0.5449(3) 0.57317(16) 0.0196(11) Uani 1 1 d . . .
O8 O 0.3349(3) 0.3013(4) 0.6817(2) 0.0468(16) Uani 1 1 d . . .
N8 N 0.3769(3) 0.4152(4) 0.7767(2) 0.0329(17) Uani 1 1 d . . .
H8B H 0.4236 0.4034 0.7813 0.039 Uiso 1 1 calc R U .
C8 C 0.1385(4) 0.6952(5) 0.5992(3) 0.047(3) Uani 1 1 d . . .
H8A H 0.1586 0.7320 0.5804 0.056 Uiso 1 1 calc R U .
O9 O -0.3031(2) 0.3895(3) 0.46132(16) 0.0243(12) Uani 1 1 d . . .
N9 N -0.0746(3) 0.2386(4) 0.66797(19) 0.0246(14) Uani 1 1 d . . .
H9B H -0.0778 0.2129 0.6412 0.029 Uiso 1 1 calc R U .
C9 C 0.0629(4) 0.6975(5) 0.6027(3) 0.045(2) Uani 1 1 d . . .
H9A H 0.0324 0.7359 0.5867 0.054 Uiso 1 1 calc R U .
C10 C -0.1542(4) 0.3308(4) 0.6184(2) 0.0208(17) Uani 1 1 d . . .
O10 O -0.4319(3) 0.7065(3) 0.57678(18) 0.0321(13) Uani 1 1 d . . .
N10 N 0.2453(4) 0.2483(5) 0.7179(3) 0.053(2) Uani 1 1 d . . .
O11 O 0.1448(3) 0.5041(3) 0.74204(16) 0.0240(12) Uani 1 1 d . . .
N11 N -0.2868(3) 0.6432(4) 0.6070(2) 0.0319(16) Uani 1 1 d . . .
H11D H -0.3257 0.6662 0.5919 0.038 Uiso 1 1 calc R U .
C11 C 0.1834(5) 0.2924(6) 0.6868(3) 0.052(3) Uani 1 1 d . . .
O12 O -0.4088(2) 0.3896(3) 0.58387(16) 0.0243(12) Uani 1 1 d . . .
C12 C 0.1834(4) 0.6395(5) 0.6230(3) 0.036(2) Uani 1 1 d . . .
H12A H 0.2338 0.6377 0.6201 0.043 Uiso 1 1 calc R U .
O13 O -0.4450(2) 0.4527(3) 0.48814(15) 0.0163(10) Uani 1 1 d . . .
C13 C 0.3153(6) 0.2571(5) 0.7133(3) 0.045(2) Uani 1 1 d . . .
O14 O -0.4120(3) 0.7068(3) 0.40880(19) 0.0338(14) Uani 1 1 d . . .
C14 C -0.0350(4) 0.2013(4) 0.7103(2) 0.0213(17) Uani 1 1 d . . .
O15 O -0.3218(3) 0.7040(3) 0.49604(19) 0.0359(14) Uani 1 1 d . . .
C15 C -0.1722(4) 0.6100(4) 0.6330(2) 0.0210(17) Uani 1 1 d . . .
O16 O -0.4420(2) 0.3824(3) 0.40720(15) 0.0207(11) Uani 1 1 d . . .
C16 C 0.2187(6) 0.1955(6) 0.7548(4) 0.067(3) Uani 1 1 d . . .
O17 O -0.3251(2) 0.5446(3) 0.46814(16) 0.0209(11) Uani 1 1 d . . .
C17 C 0.1534(4) 0.5855(5) 0.6518(2) 0.0235(17) Uani 1 1 d . . .
O18 O -0.4547(2) 0.6272(3) 0.48675(16) 0.0209(11) Uani 1 1 d . . .
C18 C 0.0000 0.0815(6) 0.7500 0.033(3) Uani 1 2 d S T P
H18A H 0.0000 0.0275 0.7500 0.040 Uiso 1 2 calc R U P
O19 O -0.5631(3) 0.7198(3) 0.51678(18) 0.0297(13) Uani 1 1 d . . .
C19 C 0.0778(4) 0.5847(4) 0.6553(2) 0.0219(17) Uani 1 1 d . . .
H19A H 0.0576 0.5474 0.6737 0.026 Uiso 1 1 calc R U .
C20 C 0.2013(4) 0.4995(4) 0.7208(2) 0.0191(16) Uani 1 1 d . . .
C21 C -0.0916(4) 0.5927(5) 0.6448(3) 0.0231(17) Uani 1 1 d . . .
C22 C -0.1070(4) 0.3087(5) 0.6649(2) 0.0213(17) Uani 1 1 d . . .
C23 C -0.1772(4) 0.2952(5) 0.5752(3) 0.0293(19) Uani 1 1 d . . .
H23A H -0.1652 0.2455 0.5659 0.035 Uiso 1 1 calc R U .
C24 C 0.3274(4) 0.3985(5) 0.8066(3) 0.0275(18) Uani 1 1 d . . .
H24A H 0.3393 0.3720 0.8360 0.033 Uiso 1 1 calc R U .
C25 C 0.2673(4) 0.4602(4) 0.7457(3) 0.0223(17) Uani 1 1 d . . .
C26 C -0.2861(4) 0.5847(5) 0.6390(3) 0.0272(18) Uani 1 1 d . . .
H26A H -0.3287 0.5630 0.6483 0.033 Uiso 1 1 calc R U .
C27 C 0.0338(4) 0.6415(5) 0.6304(3) 0.0300(19) Uani 1 1 d . . .
C28 C 0.3743(6) 0.2143(6) 0.7475(3) 0.057(3) Uani 1 1 d . . .
C29 C -0.2150(4) 0.6595(5) 0.6027(3) 0.0305(19) Uani 1 1 d . . .
H29A H -0.1984 0.6972 0.5829 0.037 Uiso 1 1 calc R U .
C30 C -0.0348(4) 0.1215(5) 0.7095(3) 0.0294(19) Uani 1 1 d . . .
H30A H -0.0577 0.0947 0.6822 0.035 Uiso 1 1 calc R U .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Co Co 0.3494 0.9721 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Mo Mo -1.6832 0.6857 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O15 Mo1 O14 106.1(3) . .
O15 Mo1 O18 98.7(2) . .
O14 Mo1 O18 99.6(2) . .
O15 Mo1 O17 103.1(2) . .
O14 Mo1 O17 144.5(2) . .
O18 Mo1 O17 95.38(19) . .
O15 Mo1 O4 95.3(2) . .
O14 Mo1 O4 79.7(2) . .
O18 Mo1 O4 165.5(2) . .
O17 Mo1 O4 77.9(2) . .
O15 Mo1 O5 165.6(2) . .
O14 Mo1 O5 84.7(2) . .
O18 Mo1 O5 69.72(17) . .
O17 Mo1 O5 70.60(17) . .
O4 Mo1 O5 95.85(19) . .
N2 Co1 N1 91.6(2) . .
N2 Co1 N5 95.4(2) . 2_556
N1 Co1 N5 90.5(2) . 2_556
N2 Co1 O11 170.9(2) . 2_556
N1 Co1 O11 95.2(2) . 2_556
N5 Co1 O11 78.5(2) 2_556 2_556
N2 Co1 O2 77.1(2) . .
N1 Co1 O2 167.1(2) . .
N5 Co1 O2 96.5(2) 2_556 .
O11 Co1 O2 96.77(18) 2_556 .
N2 Co1 O1 95.2(2) . .
N1 Co1 O1 77.7(2) . .
N5 Co1 O1 164.3(2) 2_556 .
O11 Co1 O1 92.11(19) 2_556 .
O2 Co1 O1 97.05(18) . .
N2 C1 N3 110.1(7) . .
C21 O1 Co1 114.3(4) . .
C26 N1 C15 105.1(6) . .
C26 N1 Co1 138.9(5) . .
C15 N1 Co1 112.6(4) . .
O12 Mo2 O7 104.1(2) . .
O12 Mo2 O5 103.1(2) . 5_466
O7 Mo2 O5 102.0(2) . 5_466
O12 Mo2 O13 102.6(2) . .
O7 Mo2 O13 99.5(2) . .
O5 Mo2 O13 141.02(18) 5_466 .
O12 Mo2 O18 96.3(2) . 5_466
O7 Mo2 O18 159.29(19) . 5_466
O5 Mo2 O18 76.38(18) 5_466 5_466
O13 Mo2 O18 72.13(17) . 5_466
O12 Mo2 O13 177.6(2) . 5_466
O7 Mo2 O13 78.25(18) . 5_466
O5 Mo2 O13 76.29(17) 5_466 5_466
O13 Mo2 O13 76.79(18) . 5_466
O18 Mo2 O13 81.35(16) 5_466 5_466
C22 O2 Co1 115.5(4) . .
C1 N2 C10 105.8(6) . .
C1 N2 Co1 139.1(6) . .
C10 N2 Co1 114.7(4) . .
N7 C2 O3 150(3) . .
N7 C2 C3 101(3) . .
O3 C2 C3 109.0(13) . .
O19 Mo3 O10 105.1(3) . .
O19 Mo3 O16 99.4(2) . 5_466
O10 Mo3 O16 104.5(2) . 5_466
O19 Mo3 O18 96.1(2) . .
O10 Mo3 O18 99.3(2) . .
O16 Mo3 O18 146.9(2) 5_466 .
O19 Mo3 O13 98.9(2) . 5_466
O10 Mo3 O13 155.2(2) . 5_466
O16 Mo3 O13 77.15(18) 5_466 5_466
O18 Mo3 O13 71.67(17) . 5_466
O19 Mo3 O7 169.5(2) . .
O10 Mo3 O7 84.6(2) . .
O16 Mo3 O7 81.69(18) 5_466 .
O18 Mo3 O7 77.99(17) . .
O13 Mo3 O7 71.11(15) 5_466 .
C23 N3 C1 108.8(6) . .
O9 Mo4 O6 104.6(2) . .
O9 Mo4 O17 98.3(2) . .
O6 Mo4 O17 103.5(2) . .
O9 Mo4 O16 95.3(2) . .
O6 Mo4 O16 95.9(2) . .
O17 Mo4 O16 152.62(18) . .
O9 Mo4 O5 165.15(18) . .
O6 Mo4 O5 90.19(19) . .
O17 Mo4 O5 76.96(18) . .
O16 Mo4 O5 83.93(18) . .
O9 Mo4 O13 94.20(19) . .
O6 Mo4 O13 158.77(19) . .
O17 Mo4 O13 83.02(17) . .
O16 Mo4 O13 72.29(16) . .
O5 Mo4 O13 71.39(15) . .
C20 N4 C17 127.2(6) . .
C24 N5 C25 105.2(6) . .
C24 N5 Co1 139.8(5) . 2_556
C25 N5 Co1 110.3(4) . 2_556
Mo2 O5 Mo4 116.4(2) 5_466 .
Mo2 O5 Mo1 102.86(19) 5_466 .
Mo4 O5 Mo1 90.21(15) . .
C21 N6 C27 128.1(6) . .
C14 C6 C14 117.5(10) 2_556 .
C2 N7 C5 151(3) . .
C2 N7 C4 97(2) . .
C5 N7 C4 110.7(15) . .
N8 C7 C25 106.4(6) . .
Mo2 O7 Mo3 113.1(2) . .
C24 N8 C7 107.5(6) . .
C12 C8 C9 120.7(8) . .
C22 N9 C14 128.0(6) . .
C27 C9 C8 118.8(8) . .
C23 C10 N2 110.3(6) . .
C23 C10 C22 135.4(7) . .
N2 C10 C22 114.3(6) . .
C13 N10 C16 123.7(9) . .
C13 N10 C11 122.3(8) . .
C16 N10 C11 114.0(8) . .
C20 O11 Co1 114.2(4) . 2_556
C26 N11 C29 107.6(6) . .
C8 C12 C17 119.5(7) . .
Mo2 O13 Mo3 106.47(19) . 5_466
Mo2 O13 Mo4 152.2(2) . .
Mo3 O13 Mo4 91.78(16) 5_466 .
Mo2 O13 Mo2 103.20(18) . 5_466
Mo3 O13 Mo2 96.97(15) 5_466 5_466
Mo4 O13 Mo2 94.98(15) . 5_466
O8 C13 N10 121.6(9) . .
O8 C13 C28 119.2(9) . .
N10 C13 C28 119.2(8) . .
C30 C14 C6 121.9(7) . .
C30 C14 N9 116.0(6) . .
C6 C14 N9 122.1(7) . .
C29 C15 N1 109.3(6) . .
C29 C15 C21 135.8(7) . .
N1 C15 C21 114.7(6) . .
Mo3 O16 Mo4 114.4(2) 5_466 .
Mo4 O17 Mo1 120.4(2) . .
C19 C17 C12 121.6(7) . .
C19 C17 N4 122.4(6) . .
C12 C17 N4 116.0(6) . .
Mo1 O18 Mo3 144.6(3) . .
Mo1 O18 Mo2 110.7(2) . 5_466
Mo3 O18 Mo2 104.71(18) . 5_466
C30 C18 C30 120.4(10) . 2_556
C27 C19 C17 117.4(7) . .
O11 C20 N4 123.3(6) . .
O11 C20 C25 118.2(6) . .
N4 C20 C25 118.4(6) . .
O1 C21 N6 125.6(6) . .
O1 C21 C15 119.1(6) . .
N6 C21 C15 115.2(7) . .
O2 C22 N9 123.4(6) . .
O2 C22 C10 118.3(7) . .
N9 C22 C10 118.4(6) . .
N3 C23 C10 105.0(7) . .
N5 C24 N8 111.9(7) . .
C7 C25 N5 109.0(6) . .
C7 C25 C20 134.4(7) . .
N5 C25 C20 116.5(6) . .
N1 C26 N11 111.6(6) . .
C19 C27 C9 122.1(7) . .
C19 C27 N6 123.2(7) . .
C9 C27 N6 114.7(7) . .
N11 C29 C15 106.3(7) . .
C14 C30 C18 119.1(8) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Mo1 O15 1.677(5) .
Mo1 O14 1.712(5) .
Mo1 O18 1.910(4) .
Mo1 O17 1.955(5) .
Mo1 O4 2.153(5) .
Mo1 O5 2.452(5) .
Co1 N2 2.096(6) .
Co1 N1 2.096(6) .
Co1 N5 2.107(6) 2_556
Co1 O11 2.122(5) 2_556
Co1 O2 2.152(5) .
Co1 O1 2.162(5) .
C1 N2 1.306(9) .
C1 N3 1.355(10) .
O1 C21 1.233(8) .
N1 C26 1.311(8) .
N1 C15 1.383(9) .
Mo2 O12 1.693(5) .
Mo2 O7 1.737(5) .
Mo2 O5 1.862(4) 5_466
Mo2 O13 1.958(4) .
Mo2 O18 2.210(5) 5_466
Mo2 O13 2.404(4) 5_466
O2 C22 1.247(8) .
N2 C10 1.372(9) .
C2 N7 0.946(15) .
C2 O3 1.255(17) .
C2 C3 1.79(3) .
Mo3 O19 1.697(5) .
Mo3 O10 1.700(5) .
Mo3 O16 1.890(4) 5_466
Mo3 O18 1.996(4) .
Mo3 O13 2.199(5) 5_466
Mo3 O7 2.375(5) .
N3 C23 1.347(9) .
Mo4 O9 1.705(5) .
Mo4 O6 1.710(5) .
Mo4 O17 1.879(5) .
Mo4 O16 1.982(5) .
Mo4 O5 2.241(4) .
Mo4 O13 2.333(4) .
N4 C20 1.335(8) .
N4 C17 1.423(9) .
C4 N7 1.84(2) .
N5 C24 1.317(9) .
N5 C25 1.388(9) .
N5 Co1 2.107(5) 2_556
C5 N7 1.451(15) .
O5 Mo2 1.863(4) 5_466
N6 C21 1.350(9) .
N6 C27 1.442(8) .
C6 C14 1.387(9) 2_556
C6 C14 1.387(9) .
C7 N8 1.357(9) .
C7 C25 1.371(9) .
O8 C13 1.253(10) .
N8 C24 1.344(9) .
C8 C12 1.363(11) .
C8 C9 1.388(10) .
N9 C22 1.340(9) .
N9 C14 1.432(8) .
C9 C27 1.387(11) .
C10 C23 1.356(10) .
C10 C22 1.487(9) .
N10 C13 1.304(11) .
N10 C16 1.503(11) .
N10 C11 1.512(11) .
O11 C20 1.259(7) .
O11 Co1 2.121(5) 2_556
N11 C26 1.343(9) .
N11 C29 1.353(9) .
C12 C17 1.391(10) .
O13 Mo3 2.199(5) 5_466
O13 Mo2 2.404(4) 5_466
C13 C28 1.509(13) .
C14 C30 1.375(10) .
C15 C29 1.356(10) .
C15 C21 1.479(9) .
O16 Mo3 1.890(4) 5_466
C17 C19 1.388(9) .
O18 Mo2 2.210(5) 5_466
C18 C30 1.385(9) .
C18 C30 1.385(9) 2_556
C19 C27 1.380(10) .
C20 C25 1.455(9) .
