#------------------------------------------------------------------------------
#$Date: 2019-11-17 12:14:53 +0200 (Sun, 17 Nov 2019) $
#$Revision: 229815 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/04/67/7046729.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7046729
loop_
_publ_author_name
'Pousaneh, Elaheh'
'Korb, Marcus'
'Dzhagan, Volodymyr'
'Weber, Marcus'
'Noll, Julian'
'Mehring, Michael'
'Zahn, Dietrich R. T.'
'Schulz, Stefan E.'
'Lang, Heinrich'
_publ_section_title
;
 β-Ketoiminato-based copper(ii) complexes as CVD precursors for copper
 and copper oxide layer formation.
;
_journal_issue                   30
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              10002
_journal_page_last               10016
_journal_paper_doi               10.1039/c8dt01647j
_journal_volume                  47
_journal_year                    2018
_chemical_formula_moiety         '2(C13 H24 Cu N2 O3), H2 O'
_chemical_formula_sum            'C26 H50 Cu2 N4 O7'
_chemical_formula_weight         657.78
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_Hall           '-C 2yc'
_space_group_name_H-M_alt        'C 1 2/c 1'
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   mixed
_audit_creation_method           SHELXL-2013
_audit_update_record
;
2017-06-12 deposited with the CCDC.
2018-05-28 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 94.524(7)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   22.4102(19)
_cell_length_b                   12.7485(9)
_cell_length_c                   11.2535(8)
_cell_measurement_reflns_used    2097
_cell_measurement_temperature    116(1)
_cell_measurement_theta_max      26.1740
_cell_measurement_theta_min      3.6560
_cell_volume                     3205.1(4)
_computing_cell_refinement       'CrysAlisPro 1.171.38.41l (Rigaku OD, 2015)'
_computing_data_collection       'CrysAlisPro 1.171.38.41l (Rigaku OD, 2015)'
_computing_data_reduction        'CrysAlisPro 1.171.38.41l (Rigaku OD, 2015)'
_computing_structure_refinement  'SHELXL-2013 (Sheldrick, 2013)'
_computing_structure_solution    'SHELXS-2013 (Sheldrick, 2013)'
_diffrn_ambient_temperature      116(1)
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'Xcalibur, Sapphire3, Gemini'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0750
_diffrn_reflns_av_unetI/netI     0.0763
_diffrn_reflns_Laue_measured_fraction_full 0.996
_diffrn_reflns_Laue_measured_fraction_max 0.996
_diffrn_reflns_limit_h_max       26
_diffrn_reflns_limit_h_min       -26
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       13
_diffrn_reflns_limit_l_min       -13
_diffrn_reflns_number            10414
_diffrn_reflns_point_group_measured_fraction_full 0.996
_diffrn_reflns_point_group_measured_fraction_max 0.996
_diffrn_reflns_theta_full        25.000
_diffrn_reflns_theta_max         24.996
_diffrn_reflns_theta_min         3.168
_diffrn_source                   'fine-focus sealed X-ray tube'
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 50
_diffrn_standards_interval_time  10
_diffrn_standards_number         2
_exptl_absorpt_coefficient_mu    1.372
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.40287
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlisPro 1.171.38.41l (Rigaku Oxford Diffraction, 2015)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            plate
_exptl_crystal_density_diffrn    1.363
_exptl_crystal_description       blue
_exptl_crystal_F_000             1392
_exptl_crystal_size_max          0.40
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.02
_refine_diff_density_max         0.581
_refine_diff_density_min         -0.379
_refine_diff_density_rms         0.083
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.957
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     236
_refine_ls_number_reflns         2816
_refine_ls_number_restraints     2
_refine_ls_restrained_S_all      0.957
_refine_ls_R_factor_all          0.0708
_refine_ls_R_factor_gt           0.0452
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0462P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0943
_refine_ls_wR_factor_ref         0.1033
_reflns_Friedel_coverage         0.000
_reflns_number_gt                2074
_reflns_number_total             2816
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c8dt01647j2.cif
_cod_data_source_block           Ela-17
_cod_depositor_comments
'Adding full bibliography for 7046726--7046729.cif.'
_cod_database_code               7046729
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelxl_version_number           2013-4
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.29636(16) 0.0430(3) 0.8799(3) 0.0318(9) Uani 1 1 d . . . . .
H1A H 0.3250 0.0951 0.8606 0.048 Uiso 1 1 calc R U . . .
H1B H 0.3154 -0.0245 0.8857 0.048 Uiso 1 1 calc R U . . .
H1C H 0.2810 0.0602 0.9548 0.048 Uiso 1 1 calc R U . . .
C2 C 0.24574(16) 0.0402(3) 0.7841(3) 0.0241(8) Uani 1 1 d . . . . .
C3 C 0.23403(16) -0.0499(3) 0.7195(3) 0.0246(8) Uani 1 1 d . . . . .
H3 H 0.2582 -0.1076 0.7397 0.029 Uiso 1 1 calc R U . . .
C4 C 0.18913(16) -0.0640(3) 0.6257(3) 0.0236(8) Uani 1 1 d . . . . .
C5 C 0.18413(17) -0.1723(3) 0.5696(3) 0.0307(9) Uani 1 1 d . . . . .
H5A H 0.1446 -0.1996 0.5766 0.046 Uiso 1 1 calc R U . . .
H5B H 0.2131 -0.2182 0.6097 0.046 Uiso 1 1 calc R U . . .
H5C H 0.1915 -0.1675 0.4868 0.046 Uiso 1 1 calc R U . . .
C6 C 0.10905(17) -0.0062(3) 0.4858(3) 0.0325(9) Uani 1 1 d . . . . .
H6A H 0.0901 -0.0739 0.4940 0.039 Uiso 0.55 1 calc R U P A 1
H6B H 0.1289 -0.0064 0.4123 0.039 Uiso 0.55 1 calc R U P A 1
H6C H 0.0698 -0.0190 0.5135 0.039 Uiso 0.45 1 calc R U P B 2
H6D H 0.1203 -0.0662 0.4395 0.039 Uiso 0.45 1 calc R U P B 2
C7 C 0.0626(3) 0.0783(5) 0.4811(6) 0.0318(17) Uani 0.55 1 d . . P C 1
H7A H 0.0365 0.0698 0.5453 0.038 Uiso 0.55 1 calc R U P C 1
H7B H 0.0385 0.0764 0.4057 0.038 Uiso 0.55 1 calc R U P C 1
C7' C 0.1086(4) 0.0988(6) 0.4070(6) 0.0251(19) Uani 0.45 1 d . . P C 2
H7'1 H 0.1465 0.1083 0.3723 0.030 Uiso 0.45 1 calc R U P C 2
H7'2 H 0.0767 0.0969 0.3435 0.030 Uiso 0.45 1 calc R U P C 2
C8 C 0.1312(3) 0.2047(6) 0.4021(6) 0.0321(17) Uani 0.55 1 d . . P C 1
H8A H 0.1050 0.2068 0.3294 0.038 Uiso 0.55 1 calc R U P C 1
H8B H 0.1593 0.1475 0.3950 0.038 Uiso 0.55 1 calc R U P C 1
C9 C 0.1653(5) 0.3057(10) 0.4143(11) 0.033(3) Uani 0.55 1 d . . P C 1
H9A H 0.1377 0.3634 0.4121 0.049 Uiso 0.55 1 calc R U P C 1
H9B H 0.1907 0.3122 0.3498 0.049 Uiso 0.55 1 calc R U P C 1
H9C H 0.1894 0.3063 0.4887 0.049 Uiso 0.55 1 calc R U P C 1
C10 C 0.0493(4) 0.2654(7) 0.5170(7) 0.032(2) Uani 0.55 1 d . . P C 1
H10A H 0.0263 0.2395 0.5805 0.038 Uiso 0.55 1 calc R U P C 1
H10B H 0.0682 0.3304 0.5442 0.038 Uiso 0.55 1 calc R U P C 1
C11 C 0.0066(5) 0.2885(8) 0.4086(8) 0.039(2) Uani 0.55 1 d . . P C 1
H11A H 0.0286 0.3161 0.3459 0.059 Uiso 0.55 1 calc R U P C 1
H11B H -0.0226 0.3390 0.4294 0.059 Uiso 0.55 1 calc R U P C 1
H11C H -0.0133 0.2250 0.3821 0.059 Uiso 0.55 1 calc R U P C 1
C8' C 0.1249(4) 0.2887(7) 0.4321(7) 0.0229(19) Uani 0.45 1 d . . P C 2
H8'1 H 0.1089 0.2905 0.3495 0.027 Uiso 0.45 1 calc R U P C 2
H8'2 H 0.1104 0.3506 0.4709 0.027 Uiso 0.45 1 calc R U P C 2
C9' C 0.1935(5) 0.2949(13) 0.4356(14) 0.035(3) Uani 0.45 1 d . . P C 2
H9'1 H 0.2100 0.2961 0.5169 0.052 Uiso 0.45 1 calc R U P C 2
H9'2 H 0.2049 0.3576 0.3959 0.052 Uiso 0.45 1 calc R U P C 2
H9'3 H 0.2085 0.2348 0.3960 0.052 Uiso 0.45 1 calc R U P C 2
C10' C 0.0396(4) 0.2045(8) 0.5164(8) 0.023(2) Uani 0.45 1 d . . P C 2
H10C H 0.0397 0.2624 0.5723 0.027 Uiso 0.45 1 calc R U P C 2
H10D H 0.0253 0.1434 0.5570 0.027 Uiso 0.45 1 calc R U P C 2
C11' C -0.0068(5) 0.2299(9) 0.4144(10) 0.034(3) Uani 0.45 1 d . . P C 2
H11D H 0.0049 0.2922 0.3744 0.051 Uiso 0.45 1 calc R U P C 2
H11E H -0.0450 0.2410 0.4454 0.051 Uiso 0.45 1 calc R U P C 2
H11F H -0.0096 0.1725 0.3590 0.051 Uiso 0.45 1 calc R U P C 2
C12 C 0.10727(17) 0.2959(3) 0.7897(3) 0.0253(8) Uani 1 1 d . . . . .
C13 C 0.09700(19) 0.4035(3) 0.8422(3) 0.0417(11) Uani 1 1 d . . . . .
H13A H 0.0685 0.4414 0.7905 0.063 Uiso 1 1 calc R U . . .
H13B H 0.1341 0.4414 0.8500 0.063 Uiso 1 1 calc R U . . .
H13C H 0.0819 0.3957 0.9192 0.063 Uiso 1 1 calc R U . . .
N1 N 0.15317(13) 0.0115(2) 0.5869(2) 0.0247(7) Uani 1 1 d . . . . .
N2 N 0.09819(14) 0.1853(2) 0.4951(2) 0.0286(8) Uani 1 1 d . . . . .
O1 O 0.21563(11) 0.12740(18) 0.7705(2) 0.0245(6) Uani 1 1 d . . . . .
O2 O 0.14379(11) 0.29281(18) 0.70844(19) 0.0249(6) Uani 1 1 d . . . . .
O3 O 0.07954(11) 0.2191(2) 0.8240(2) 0.0336(7) Uani 1 1 d D . . . .
O4 O 0.0000 0.0542(3) 0.7500 0.0363(9) Uani 1 2 d DS T P . .
Cu1 Cu 0.15273(2) 0.15187(3) 0.64788(3) 0.02319(17) Uani 1 1 d . . . . .
H1O4 H 0.0270(13) 0.098(2) 0.769(3) 0.024(10) Uiso 1 1 d D . . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
C2 C1 H1A 109.5
C2 C1 H1B 109.5
H1A C1 H1B 109.5
C2 C1 H1C 109.5
H1A C1 H1C 109.5
H1B C1 H1C 109.5
O1 C2 C3 125.2(3)
O1 C2 C1 114.7(3)
C3 C2 C1 120.1(3)
C2 C3 C4 126.7(3)
C2 C3 H3 116.6
C4 C3 H3 116.6
N1 C4 C3 122.7(3)
N1 C4 C5 120.5(3)
C3 C4 C5 116.9(3)
C4 C5 H5A 109.5
C4 C5 H5B 109.5
H5A C5 H5B 109.5
C4 C5 H5C 109.5
H5A C5 H5C 109.5
H5B C5 H5C 109.5
N1 C6 C7 110.0(4)
N1 C6 C7' 106.0(4)
N1 C6 H6A 109.7
C7 C6 H6A 109.7
N1 C6 H6B 109.7
C7 C6 H6B 109.7
H6A C6 H6B 108.2
N1 C6 H6C 110.5
C7' C6 H6C 110.5
N1 C6 H6D 110.5
C7' C6 H6D 110.5
H6C C6 H6D 108.7
C6 C7 N2 105.9(5)
C6 C7 H7A 110.6
N2 C7 H7A 110.6
C6 C7 H7B 110.6
N2 C7 H7B 110.6
H7A C7 H7B 108.7
N2 C7' C6 103.9(4)
N2 C7' H7'1 111.0
C6 C7' H7'1 111.0
N2 C7' H7'2 111.0
C6 C7' H7'2 111.0
H7'1 C7' H7'2 109.0
N2 C8 C9 113.1(7)
N2 C8 H8A 108.9
C9 C8 H8A 108.9
N2 C8 H8B 108.9
C9 C8 H8B 108.9
H8A C8 H8B 107.8
C8 C9 H9A 109.5
C8 C9 H9B 109.5
H9A C9 H9B 109.5
C8 C9 H9C 109.5
H9A C9 H9C 109.5
H9B C9 H9C 109.5
C11 C10 N2 114.4(6)
C11 C10 H10A 108.7
N2 C10 H10A 108.7
C11 C10 H10B 108.7
N2 C10 H10B 108.7
H10A C10 H10B 107.6
C10 C11 H11A 109.5
C10 C11 H11B 109.5
H11A C11 H11B 109.5
C10 C11 H11C 109.5
H11A C11 H11C 109.5
H11B C11 H11C 109.5
C9' C8' N2 115.5(8)
C9' C8' H8'1 108.4
N2 C8' H8'1 108.4
C9' C8' H8'2 108.4
N2 C8' H8'2 108.4
H8'1 C8' H8'2 107.5
C8' C9' H9'1 109.5
C8' C9' H9'2 109.5
H9'1 C9' H9'2 109.5
C8' C9' H9'3 109.5
H9'1 C9' H9'3 109.5
H9'2 C9' H9'3 109.5
N2 C10' C11' 120.8(7)
N2 C10' H10C 107.1
C11' C10' H10C 107.1
N2 C10' H10D 107.1
C11' C10' H10D 107.1
H10C C10' H10D 106.8
C10' C11' H11D 109.5
C10' C11' H11E 109.5
H11D C11' H11E 109.5
C10' C11' H11F 109.5
H11D C11' H11F 109.5
H11E C11' H11F 109.5
O3 C12 O2 124.4(3)
O3 C12 C13 119.9(3)
O2 C12 C13 115.7(3)
C12 C13 H13A 109.5
C12 C13 H13B 109.5
H13A C13 H13B 109.5
C12 C13 H13C 109.5
H13A C13 H13C 109.5
H13B C13 H13C 109.5
C4 N1 C6 120.4(3)
C4 N1 Cu1 126.0(2)
C6 N1 Cu1 113.5(2)
C10' N2 C7' 116.2(6)
C8 N2 C10 116.4(5)
C8 N2 C7 112.6(4)
C10 N2 C7 103.2(5)
C10' N2 C8' 108.6(5)
C7' N2 C8' 102.9(4)
C8 N2 Cu1 110.9(4)
C10' N2 Cu1 113.6(4)
C7' N2 Cu1 106.4(3)
C10 N2 Cu1 112.7(3)
C7 N2 Cu1 99.5(3)
C8' N2 Cu1 108.3(4)
C2 O1 Cu1 124.6(2)
C12 O2 Cu1 111.8(2)
N1 Cu1 O1 94.67(11)
N1 Cu1 O2 174.37(11)
O1 Cu1 O2 89.33(10)
N1 Cu1 N2 85.08(12)
O1 Cu1 N2 168.88(11)
O2 Cu1 N2 91.75(11)
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
C1 C2 1.503(5)
C1 H1A 0.9600
C1 H1B 0.9600
C1 H1C 0.9600
C2 O1 1.303(4)
C2 C3 1.374(5)
C3 C4 1.412(5)
C3 H3 0.9300
C4 N1 1.308(4)
C4 C5 1.518(5)
C5 H5A 0.9600
C5 H5B 0.9600
C5 H5C 0.9600
C6 N1 1.464(4)
C6 C7 1.496(8)
C6 C7' 1.605(8)
C6 H6A 0.9700
C6 H6B 0.9700
C6 H6C 0.9700
C6 H6D 0.9700
C7 N2 1.581(7)
C7 H7A 0.9700
C7 H7B 0.9700
C7' N2 1.513(8)
C7' H7'1 0.9700
C7' H7'2 0.9700
C8 N2 1.352(7)
C8 C9 1.498(14)
C8 H8A 0.9700
C8 H8B 0.9700
C9 H9A 0.9600
C9 H9B 0.9600
C9 H9C 0.9600
C10 C11 1.519(13)
C10 N2 1.532(8)
C10 H10A 0.9700
C10 H10B 0.9700
C11 H11A 0.9600
C11 H11B 0.9600
C11 H11C 0.9600
C8' C9' 1.538(13)
C8' N2 1.632(9)
C8' H8'1 0.9700
C8' H8'2 0.9700
C9' H9'1 0.9600
C9' H9'2 0.9600
C9' H9'3 0.9600
C10' N2 1.376(10)
C10' C11' 1.522(15)
C10' H10C 0.9700
C10' H10D 0.9700
C11' H11D 0.9600
C11' H11E 0.9600
C11' H11F 0.9600
C12 O3 1.238(4)
C12 O2 1.275(4)
C12 C13 1.518(5)
C13 H13A 0.9600
C13 H13B 0.9600
C13 H13C 0.9600
N1 Cu1 1.917(3)
N2 Cu1 2.074(3)
O1 Cu1 1.919(2)
O2 Cu1 1.938(2)
O4 H1O4 0.840(14)
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
O1 C2 C3 C4 1.9(5)
C1 C2 C3 C4 -178.6(3)
C2 C3 C4 N1 1.6(5)
C2 C3 C4 C5 -178.7(3)
N1 C6 C7 N2 47.8(5)
C7' C6 C7 N2 -47.8(4)
N1 C6 C7' N2 -53.3(5)
C7 C6 C7' N2 50.0(5)
C3 C4 N1 C6 177.4(3)
C5 C4 N1 C6 -2.3(5)
C3 C4 N1 Cu1 -0.9(5)
C5 C4 N1 Cu1 179.4(2)
C7 C6 N1 C4 163.6(4)
C7' C6 N1 C4 -140.0(4)
C7 C6 N1 Cu1 -18.0(4)
C7' C6 N1 Cu1 38.4(4)
C9 C8 N2 C10' 94.0(9)
C9 C8 N2 C7' -166.9(9)
C9 C8 N2 C10 61.2(8)
C9 C8 N2 C7 -179.9(7)
C9 C8 N2 C8' 25.5(6)
C9 C8 N2 Cu1 -69.4(7)
C11' C10' N2 C8 17.2(13)
C11' C10' N2 C7' -55.7(10)
C11' C10' N2 C10 85.0(13)
C11' C10' N2 C7 -87.0(9)
C11' C10' N2 C8' 59.7(10)
C11' C10' N2 Cu1 -179.7(7)
C6 C7' N2 C8 148.6(6)
C6 C7' N2 C10' -84.1(6)
C6 C7' N2 C10 -113.7(7)
C6 C7' N2 C7 -46.3(4)
C6 C7' N2 C8' 157.3(5)
C6 C7' N2 Cu1 43.5(5)
C11 C10 N2 C8 52.8(9)
C11 C10 N2 C10' -78.8(12)
C11 C10 N2 C7' -21.1(12)
C11 C10 N2 C7 -71.0(8)
C11 C10 N2 C8' 76.9(8)
C11 C10 N2 Cu1 -177.4(6)
C6 C7 N2 C8 65.5(6)
C6 C7 N2 C10' -163.8(6)
C6 C7 N2 C7' 51.5(5)
C6 C7 N2 C10 -168.1(4)
C6 C7 N2 C8' 99.9(9)
C6 C7 N2 Cu1 -51.9(4)
C9' C8' N2 C8 -62.6(9)
C9' C8' N2 C10' 162.6(9)
C9' C8' N2 C7' -73.7(10)
C9' C8' N2 C10 149.4(10)
C9' C8' N2 C7 -111.8(11)
C9' C8' N2 Cu1 38.7(9)
C3 C2 O1 Cu1 -5.6(5)
C1 C2 O1 Cu1 174.9(2)
O3 C12 O2 Cu1 -1.8(4)
C13 C12 O2 Cu1 -179.6(2)
