#------------------------------------------------------------------------------
#$Date: 2019-11-17 09:51:35 +0200 (Sun, 17 Nov 2019) $
#$Revision: 229197 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/04/68/7046815.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7046815
loop_
_publ_author_name
'de Bruin-Dickason, Caspar N'
'Boutland, Aaron J.'
'Dange, Deepak'
'Deacon, Glen B.'
'Jones, Cameron'
_publ_section_title
;
 Redox transmetallation approaches to the synthesis of extremely bulky
 amido-lanthanoid(ii) and -calcium(ii) complexes.
;
_journal_issue                   28
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              9512
_journal_page_last               9520
_journal_paper_doi               10.1039/c8dt02138d
_journal_volume                  47
_journal_year                    2018
_chemical_formula_sum            'C84 H96 Eu2 I2 N2 O2 Si2'
_chemical_formula_weight         1779.53
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_audit_update_record
;
2018-05-25 deposited with the CCDC.
2018-06-22 downloaded from the CCDC.
;
_cell_angle_alpha                90.368(4)
_cell_angle_beta                 106.621(4)
_cell_angle_gamma                91.770(4)
_cell_formula_units_Z            1
_cell_length_a                   9.7676(7)
_cell_length_b                   13.1133(10)
_cell_length_c                   14.9720(12)
_cell_measurement_reflns_used    7339
_cell_measurement_temperature    123(2)
_cell_measurement_theta_max      26.22
_cell_measurement_theta_min      2.69
_cell_volume                     1836.5(2)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick 2008)'
_diffrn_ambient_temperature      123(2)
_diffrn_measured_fraction_theta_full 0.995
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device_type  'Bruker Apex X8'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0829
_diffrn_reflns_av_sigmaI/netI    0.0524
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            59258
_diffrn_reflns_theta_full        26.22
_diffrn_reflns_theta_max         26.22
_diffrn_reflns_theta_min         2.69
_exptl_absorpt_coefficient_mu    2.614
_exptl_absorpt_correction_T_max  0.780
_exptl_absorpt_correction_T_min  0.694
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'Sortav (Blessing)'
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    1.609
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             890
_exptl_crystal_size_max          0.15
_exptl_crystal_size_mid          0.13
_exptl_crystal_size_min          0.10
_refine_diff_density_max         0.930
_refine_diff_density_min         -0.790
_refine_diff_density_rms         0.132
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.029
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     450
_refine_ls_number_reflns         7339
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.029
_refine_ls_R_factor_all          0.0488
_refine_ls_R_factor_gt           0.0321
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0107P)²+3.4073P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0557
_refine_ls_wR_factor_ref         0.0619
_reflns_number_gt                5853
_reflns_number_total             7339
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c8dt02138d2.cif
_cod_data_source_block           compound9
_cod_depositor_comments
'Adding full bibliography for 7046810--7046818.cif.'
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7046815
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.44389(2) 0.131158(15) 0.116853(14) 0.01334(6) Uani 1 1 d . . .
I1 I 0.67717(3) 0.08680(2) 0.005769(19) 0.02111(8) Uani 1 1 d . . .
Si1 Si 0.73864(11) 0.34818(8) 0.18278(8) 0.0140(2) Uani 1 1 d . . .
O1 O 0.2846(3) 0.0559(2) 0.2128(2) 0.0228(7) Uani 1 1 d . D .
N1 N 0.5967(3) 0.2780(2) 0.1951(2) 0.0099(7) Uani 1 1 d . . .
C1 C 0.7738(5) 0.4631(3) 0.2610(3) 0.0279(11) Uani 1 1 d . . .
H1A H 0.6892 0.5052 0.2457 0.042 Uiso 1 1 calc R . .
H1B H 0.8556 0.5029 0.2524 0.042 Uiso 1 1 calc R . .
H1C H 0.7950 0.4417 0.3260 0.042 Uiso 1 1 calc R . .
C2 C 0.7113(5) 0.3927(3) 0.0616(3) 0.0240(10) Uani 1 1 d . . .
H2A H 0.6791 0.3349 0.0180 0.036 Uiso 1 1 calc R . .
H2B H 0.8015 0.4217 0.0550 0.036 Uiso 1 1 calc R . .
H2C H 0.6388 0.4449 0.0478 0.036 Uiso 1 1 calc R . .
C42 C 0.5843(4) -0.1163(3) 0.2979(3) 0.0290(11) Uani 1 1 d . . .
H2AA H 0.5512 -0.1841 0.2790 0.035 Uiso 1 1 calc R . .
C3 C 0.9099(4) 0.2789(3) 0.2100(3) 0.0226(10) Uani 1 1 d . . .
H3A H 0.9310 0.2515 0.2731 0.034 Uiso 1 1 calc R . .
H3B H 0.9877 0.3261 0.2063 0.034 Uiso 1 1 calc R . .
H3C H 0.9007 0.2227 0.1650 0.034 Uiso 1 1 calc R . .
C4 C 0.5344(4) 0.2977(3) 0.2664(3) 0.0108(8) Uani 1 1 d . . .
C5 C 0.4134(4) 0.3578(3) 0.2488(3) 0.0122(8) Uani 1 1 d . . .
C6 C 0.3443(4) 0.3724(3) 0.3173(3) 0.0127(8) Uani 1 1 d . . .
H6 H 0.2625 0.4134 0.3038 0.015 Uiso 1 1 calc R . .
C7 C 0.3910(4) 0.3291(3) 0.4043(3) 0.0128(8) Uani 1 1 d . . .
C8 C 0.5144(4) 0.2724(3) 0.4220(3) 0.0135(8) Uani 1 1 d . . .
H8 H 0.5503 0.2431 0.4816 0.016 Uiso 1 1 calc R . .
C9 C 0.5861(4) 0.2574(3) 0.3564(3) 0.0113(8) Uani 1 1 d . . .
C10 C 0.3612(4) 0.4081(3) 0.1545(3) 0.0116(8) Uani 1 1 d . . .
H10 H 0.4490 0.4351 0.1397 0.014 Uiso 1 1 calc R . .
C11 C 0.2923(4) 0.3304(3) 0.0785(3) 0.0147(9) Uani 1 1 d . . .
C12 C 0.1850(4) 0.2626(3) 0.0871(3) 0.0164(9) Uani 1 1 d . . .
H12 H 0.1511 0.2668 0.1404 0.020 Uiso 1 1 calc R . .
C13 C 0.1265(4) 0.1888(3) 0.0189(3) 0.0227(10) Uani 1 1 d . . .
H13 H 0.0516 0.1439 0.0251 0.027 Uiso 1 1 calc R . .
C14 C 0.1767(4) 0.1804(3) -0.0577(3) 0.0248(11) Uani 1 1 d . . .
H14 H 0.1395 0.1283 -0.1034 0.030 Uiso 1 1 calc R . .
C15 C 0.2817(4) 0.2484(3) -0.0676(3) 0.0221(10) Uani 1 1 d . . .
H15 H 0.3152 0.2440 -0.1211 0.026 Uiso 1 1 calc R . .
C16 C 0.3386(4) 0.3227(3) -0.0004(3) 0.0177(9) Uani 1 1 d . . .
H16 H 0.4105 0.3693 -0.0084 0.021 Uiso 1 1 calc R . .
C17 C 0.2717(4) 0.5004(3) 0.1569(3) 0.0130(8) Uani 1 1 d . . .
C18 C 0.1266(4) 0.5020(3) 0.1188(3) 0.0162(9) Uani 1 1 d . . .
H18 H 0.0766 0.4430 0.0870 0.019 Uiso 1 1 calc R . .
C19 C 0.0510(4) 0.5882(3) 0.1259(3) 0.0204(10) Uani 1 1 d . . .
H19 H -0.0497 0.5880 0.0989 0.024 Uiso 1 1 calc R . .
C20 C 0.1217(5) 0.6729(3) 0.1716(3) 0.0264(11) Uani 1 1 d . . .
H20 H 0.0705 0.7320 0.1770 0.032 Uiso 1 1 calc R . .
C21 C 0.2670(5) 0.6725(3) 0.2097(3) 0.0334(12) Uani 1 1 d . . .
H21 H 0.3164 0.7317 0.2416 0.040 Uiso 1 1 calc R . .
C22 C 0.3416(4) 0.5879(3) 0.2022(3) 0.0238(10) Uani 1 1 d . . .
H22 H 0.4425 0.5892 0.2284 0.029 Uiso 1 1 calc R . .
C23 C 0.3153(4) 0.3408(3) 0.4782(3) 0.0187(9) Uani 1 1 d . . .
H23 H 0.2874 0.2704 0.4933 0.022 Uiso 1 1 calc R . .
C24 C 0.1787(5) 0.3991(4) 0.4470(3) 0.0359(13) Uani 1 1 d . . .
H24A H 0.2008 0.4687 0.4306 0.054 Uiso 1 1 calc R . .
H24B H 0.1339 0.4017 0.4978 0.054 Uiso 1 1 calc R . .
H24C H 0.1129 0.3646 0.3925 0.054 Uiso 1 1 calc R . .
C25 C 0.4111(5) 0.3870(4) 0.5673(3) 0.0422(14) Uani 1 1 d . . .
H25A H 0.4970 0.3469 0.5887 0.063 Uiso 1 1 calc R . .
H25B H 0.3601 0.3871 0.6149 0.063 Uiso 1 1 calc R . .
H25C H 0.4386 0.4573 0.5562 0.063 Uiso 1 1 calc R . .
C26 C 0.7191(4) 0.1942(3) 0.3763(3) 0.0125(8) Uani 1 1 d . . .
H26 H 0.7691 0.2165 0.3296 0.015 Uiso 1 1 calc R . .
C27 C 0.6755(4) 0.0830(3) 0.3523(3) 0.0140(9) Uani 1 1 d . . .
C28 C 0.6894(4) 0.0413(3) 0.2699(3) 0.0184(9) Uani 1 1 d . . .
H28 H 0.7321 0.0814 0.2318 0.022 Uiso 1 1 calc R . .
C29 C 0.6422(4) -0.0575(3) 0.2425(3) 0.0243(10) Uani 1 1 d . . .
H29 H 0.6501 -0.0843 0.1852 0.029 Uiso 1 1 calc R . .
C30 C 0.5735(5) -0.0779(3) 0.3814(4) 0.0306(12) Uani 1 1 d . . .
H30 H 0.5354 -0.1198 0.4206 0.037 Uiso 1 1 calc R . .
C31 C 0.6180(4) 0.0217(3) 0.4081(3) 0.0227(10) Uani 1 1 d . . .
H31 H 0.6089 0.0482 0.4653 0.027 Uiso 1 1 calc R . .
C32 C 0.8282(4) 0.2113(3) 0.4703(3) 0.0137(8) Uani 1 1 d . . .
C33 C 0.9337(4) 0.1403(3) 0.5017(3) 0.0199(9) Uani 1 1 d . . .
H33 H 0.9293 0.0784 0.4676 0.024 Uiso 1 1 calc R . .
C34 C 1.0443(4) 0.1584(3) 0.5814(3) 0.0251(10) Uani 1 1 d . . .
H34 H 1.1157 0.1092 0.6014 0.030 Uiso 1 1 calc R . .
C35 C 1.0524(4) 0.2469(3) 0.6322(3) 0.0247(10) Uani 1 1 d . . .
H35 H 1.1291 0.2593 0.6871 0.030 Uiso 1 1 calc R . .
C36 C 0.9489(4) 0.3175(3) 0.6030(3) 0.0239(10) Uani 1 1 d . . .
H36 H 0.9529 0.3784 0.6385 0.029 Uiso 1 1 calc R . .
C37 C 0.8392(4) 0.3004(3) 0.5224(3) 0.0208(10) Uani 1 1 d . . .
H37 H 0.7697 0.3508 0.5021 0.025 Uiso 1 1 calc R . .
C38 C 0.2602(5) 0.1065(3) 0.2922(4) 0.0337(12) Uani 1 1 d . D .
H38A H 0.2171 0.1733 0.2739 0.040 Uiso 1 1 calc R . .
H38B H 0.3518 0.1183 0.3414 0.040 Uiso 1 1 calc R . .
C39 C 0.1643(8) 0.0417(4) 0.3266(4) 0.0564(18) Uani 1 1 d . . .
H39C H 0.1027 0.0831 0.3537 0.068 Uiso 0.50 1 calc PR A 2
H39D H 0.2188 -0.0047 0.3748 0.068 Uiso 0.50 1 calc PR A 2
H39A H 0.116(12) 0.088(9) 0.263(8) 0.068 Uiso 0.50 1 d P B 1
H39B H 0.145(12) 0.047(9) 0.378(8) 0.068 Uiso 0.50 1 d P C 1
C40 C 0.0784(12) -0.0164(10) 0.2447(7) 0.044(3) Uani 0.50 1 d P D 2
H40A H -0.0006 0.0239 0.2063 0.053 Uiso 0.50 1 calc PR D 2
H40B H 0.0391 -0.0812 0.2624 0.053 Uiso 0.50 1 calc PR D 2
C40A C 0.1655(13) -0.0612(7) 0.2857(8) 0.036(3) Uani 0.50 1 d P D 1
H40C H 0.0723 -0.0982 0.2756 0.043 Uiso 0.50 1 calc PR D 1
H40D H 0.2421 -0.1024 0.3255 0.043 Uiso 0.50 1 calc PR D 1
C41 C 0.1949(7) -0.0354(4) 0.1935(4) 0.0510(17) Uani 1 1 d . . .
H41C H 0.2503 -0.0961 0.2184 0.061 Uiso 0.50 1 calc PR D 2
H41D H 0.1507 -0.0454 0.1256 0.061 Uiso 0.50 1 calc PR D 2
H41A H 0.250(11) -0.088(8) 0.175(8) 0.061 Uiso 0.50 1 d P E 1
H41B H 0.129(12) -0.009(9) 0.144(8) 0.061 Uiso 0.50 1 d P F 1
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
I I -0.4742 1.8119 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_3
N1 Eu1 O1 113.14(9) .
N1 Eu1 C11 67.57(10) .
O1 Eu1 C11 95.12(10) .
N1 Eu1 C12 89.06(10) .
O1 Eu1 C12 71.98(10) .
C11 Eu1 C12 26.53(10) .
N1 Eu1 C4 26.92(10) .
O1 Eu1 C4 86.77(9) .
C11 Eu1 C4 62.76(10) .
C12 Eu1 C4 75.13(10) .
N1 Eu1 C28 73.92(10) .
O1 Eu1 C28 84.22(10) .
C11 Eu1 C28 137.73(10) .
C12 Eu1 C28 142.53(11) .
C4 Eu1 C28 75.02(10) .
N1 Eu1 C16 72.62(10) .
O1 Eu1 C16 117.54(10) .
C11 Eu1 C16 26.07(10) .
C12 Eu1 C16 45.57(11) .
C4 Eu1 C16 79.37(10) .
C28 Eu1 C16 145.27(11) .
N1 Eu1 C13 113.22(10) .
O1 Eu1 C13 71.92(10) .
C11 Eu1 C13 46.09(10) .
C12 Eu1 C13 25.87(10) .
C4 Eu1 C13 100.97(10) .
C28 Eu1 C13 156.05(12) .
C16 Eu1 C13 52.31(11) .
N1 Eu1 C15 96.42(10) .
O1 Eu1 C15 115.92(10) .
C11 Eu1 C15 45.43(10) .
C12 Eu1 C15 52.28(11) .
C4 Eu1 C15 104.50(10) .
C28 Eu1 C15 159.86(12) .
C16 Eu1 C15 25.28(10) .
C13 Eu1 C15 44.04(12) .
N1 Eu1 C14 116.79(10) .
O1 Eu1 C14 93.42(11) .
C11 Eu1 C14 53.19(10) .
C12 Eu1 C14 45.03(11) .
C4 Eu1 C14 115.72(10) .
C28 Eu1 C14 168.92(10) .
C16 Eu1 C14 44.61(11) .
C13 Eu1 C14 25.00(11) .
C15 Eu1 C14 24.87(11) .
N1 Eu1 I1 88.60(7) .
O1 Eu1 I1 146.70(6) .
C11 Eu1 I1 117.01(8) .
C12 Eu1 I1 136.04(8) .
C4 Eu1 I1 114.69(7) .
C28 Eu1 I1 77.81(8) .
C16 Eu1 I1 92.31(8) .
C13 Eu1 I1 123.88(8) .
C15 Eu1 I1 84.44(8) .
C14 Eu1 I1 98.88(8) .
N1 Eu1 I1 163.25(7) 2_655
O1 Eu1 I1 79.87(6) 2_655
C11 Eu1 I1 123.61(7) 2_655
C12 Eu1 I1 105.53(7) 2_655
C4 Eu1 I1 165.54(7) 2_655
C28 Eu1 I1 97.98(7) 2_655
C16 Eu1 I1 111.70(7) 2_655
C13 Eu1 I1 80.19(7) 2_655
C15 Eu1 I1 86.45(7) 2_655
C14 Eu1 I1 70.94(7) 2_655
I1 Eu1 I1 75.218(10) 2_655
Eu1 I1 Eu1 104.781(10) 2_655
N1 Si1 C2 112.41(17) .
N1 Si1 C1 110.78(17) .
C2 Si1 C1 107.7(2) .
N1 Si1 C3 114.65(17) .
C2 Si1 C3 104.48(19) .
C1 Si1 C3 106.4(2) .
C41 O1 C38 107.7(3) .
C41 O1 Eu1 128.0(3) .
C38 O1 Eu1 124.0(2) .
C4 N1 Si1 122.1(2) .
C4 N1 Eu1 99.9(2) .
Si1 N1 Eu1 137.98(16) .
Si1 C1 H1A 109.5 .
Si1 C1 H1B 109.5 .
H1A C1 H1B 109.5 .
Si1 C1 H1C 109.5 .
H1A C1 H1C 109.5 .
H1B C1 H1C 109.5 .
Si1 C2 H2A 109.5 .
Si1 C2 H2B 109.5 .
H2A C2 H2B 109.5 .
Si1 C2 H2C 109.5 .
H2A C2 H2C 109.5 .
H2B C2 H2C 109.5 .
C29 C42 C30 120.2(4) .
C29 C42 H2AA 119.9 .
C30 C42 H2AA 119.9 .
Si1 C3 H3A 109.5 .
Si1 C3 H3B 109.5 .
H3A C3 H3B 109.5 .
Si1 C3 H3C 109.5 .
H3A C3 H3C 109.5 .
H3B C3 H3C 109.5 .
N1 C4 C5 119.8(3) .
N1 C4 C9 122.6(3) .
C5 C4 C9 117.5(3) .
N1 C4 Eu1 53.14(17) .
C5 C4 Eu1 103.0(2) .
C9 C4 Eu1 112.1(2) .
C6 C5 C4 120.5(3) .
C6 C5 C10 120.8(3) .
C4 C5 C10 118.6(3) .
C7 C6 C5 122.0(3) .
C7 C6 H6 119.0 .
C5 C6 H6 119.0 .
C6 C7 C8 116.8(3) .
C6 C7 C23 123.0(3) .
C8 C7 C23 120.1(3) .
C9 C8 C7 122.6(3) .
C9 C8 H8 118.7 .
C7 C8 H8 118.7 .
C8 C9 C4 120.4(3) .
C8 C9 C26 121.9(3) .
C4 C9 C26 117.7(3) .
C11 C10 C5 111.2(3) .
C11 C10 C17 114.5(3) .
C5 C10 C17 112.7(3) .
C11 C10 H10 105.8 .
C5 C10 H10 105.8 .
C17 C10 H10 105.8 .
C16 C11 C12 118.1(4) .
C16 C11 C10 120.6(4) .
C12 C11 C10 121.3(4) .
C16 C11 Eu1 80.3(2) .
C12 C11 Eu1 77.2(2) .
C10 C11 Eu1 110.2(2) .
C13 C12 C11 121.0(4) .
C13 C12 Eu1 81.6(2) .
C11 C12 Eu1 76.2(2) .
C13 C12 H12 119.5 .
C11 C12 H12 119.5 .
Eu1 C12 H12 113.0 .
C14 C13 C12 120.1(4) .
C14 C13 Eu1 80.0(2) .
C12 C13 Eu1 72.5(2) .
C14 C13 H13 119.9 .
C12 C13 H13 119.9 .
Eu1 C13 H13 118.3 .
C13 C14 C15 119.3(4) .
C13 C14 Eu1 75.0(2) .
C15 C14 Eu1 77.0(2) .
C13 C14 H14 120.3 .
C15 C14 H14 120.3 .
Eu1 C14 H14 118.6 .
C14 C15 C16 120.6(4) .
C14 C15 Eu1 78.1(2) .
C16 C15 Eu1 73.7(2) .
C14 C15 H15 119.7 .
C16 C15 H15 119.7 .
Eu1 C15 H15 119.4 .
C15 C16 C11 120.9(4) .
C15 C16 Eu1 81.0(2) .
C11 C16 Eu1 73.6(2) .
C15 C16 H16 119.5 .
C11 C16 H16 119.5 .
Eu1 C16 H16 116.4 .
C18 C17 C22 118.0(4) .
C18 C17 C10 124.3(3) .
C22 C17 C10 117.6(3) .
C17 C18 C19 121.2(4) .
C17 C18 H18 119.4 .
C19 C18 H18 119.4 .
C20 C19 C18 119.8(4) .
C20 C19 H19 120.1 .
C18 C19 H19 120.1 .
C19 C20 C21 119.6(4) .
C19 C20 H20 120.2 .
C21 C20 H20 120.2 .
C22 C21 C20 120.7(4) .
C22 C21 H21 119.7 .
C20 C21 H21 119.7 .
C21 C22 C17 120.7(4) .
C21 C22 H22 119.7 .
C17 C22 H22 119.7 .
C25 C23 C7 112.5(3) .
C25 C23 C24 109.9(4) .
C7 C23 C24 114.1(3) .
C25 C23 H23 106.6 .
C7 C23 H23 106.6 .
C24 C23 H23 106.6 .
C23 C24 H24A 109.5 .
C23 C24 H24B 109.5 .
H24A C24 H24B 109.5 .
C23 C24 H24C 109.5 .
H24A C24 H24C 109.5 .
H24B C24 H24C 109.5 .
C23 C25 H25A 109.5 .
C23 C25 H25B 109.5 .
H25A C25 H25B 109.5 .
C23 C25 H25C 109.5 .
H25A C25 H25C 109.5 .
H25B C25 H25C 109.5 .
C32 C26 C27 114.2(3) .
C32 C26 C9 116.6(3) .
C27 C26 C9 109.4(3) .
C32 C26 H26 105.2 .
C27 C26 H26 105.2 .
C9 C26 H26 105.2 .
C31 C27 C28 118.3(4) .
C31 C27 C26 122.4(4) .
C28 C27 C26 119.3(4) .
C29 C28 C27 121.1(4) .
C29 C28 Eu1 92.2(2) .
C27 C28 Eu1 104.3(2) .
C29 C28 H28 119.5 .
C27 C28 H28 119.5 .
Eu1 C28 H28 73.2 .
C42 C29 C28 119.8(4) .
C42 C29 H29 120.1 .
C28 C29 H29 120.1 .
C42 C30 C31 120.2(4) .
C42 C30 H30 119.9 .
C31 C30 H30 119.9 .
C27 C31 C30 120.4(4) .
C27 C31 H31 119.8 .
C30 C31 H31 119.8 .
C37 C32 C33 117.4(4) .
C37 C32 C26 123.0(3) .
C33 C32 C26 119.2(3) .
C34 C33 C32 121.1(4) .
C34 C33 H33 119.5 .
C32 C33 H33 119.5 .
C35 C34 C33 120.5(4) .
C35 C34 H34 119.8 .
C33 C34 H34 119.8 .
C36 C35 C34 119.5(4) .
C36 C35 H35 120.3 .
C34 C35 H35 120.3 .
C35 C36 C37 120.2(4) .
C35 C36 H36 119.9 .
C37 C36 H36 119.9 .
C36 C37 C32 121.4(4) .
C36 C37 H37 119.3 .
C32 C37 H37 119.3 .
O1 C38 C39 107.9(4) .
O1 C38 H38A 110.1 .
C39 C38 H38A 110.1 .
O1 C38 H38B 110.1 .
C39 C38 H38B 110.1 .
H38A C38 H38B 108.4 .
O1 C38 H39A 94(5) .
C39 C38 H39A 47(5) .
H38A C38 H39A 73.8 .
H38B C38 H39A 152.4 .
C38 C39 C40 105.0(6) .
C38 C39 C40A 106.8(6) .
C40 C39 C40A 43.3(6) .
C38 C39 H39C 110.7 .
C40 C39 H39C 110.7 .
C40A C39 H39C 139.6 .
C38 C39 H39D 110.7 .
C40 C39 H39D 110.7 .
C40A C39 H39D 70.0 .
H39C C39 H39D 108.8 .
C38 C39 H39A 63(6) .
C40 C39 H39A 65(6) .
C40A C39 H39A 102(6) .
H39C C39 H39A 82.7 .
H39D C39 H39A 168.4 .
C38 C39 H39B 128(8) .
C40 C39 H39B 125(8) .
C40A C39 H39B 119(8) .
H39C C39 H39B 42.0 .
H39D C39 H39B 66.8 .
H39A C39 H39B 125(10) .
C39 C40 C41 100.1(7) .
C39 C40 H39A 46(5) .
C41 C40 H39A 95(5) .
C39 C40 H40A 111.8 .
C41 C40 H40A 111.8 .
H39A C40 H40A 71.9 .
C39 C40 H40B 111.8 .
C41 C40 H40B 111.8 .
H39A C40 H40B 149.5 .
H40A C40 H40B 109.5 .
C39 C40A C41 101.4(6) .
C39 C40A H40C 111.5 .
C41 C40A H40C 111.5 .
C39 C40A H40D 111.5 .
C41 C40A H40D 111.5 .
H40C C40A H40D 109.3 .
O1 C41 C40A 105.1(5) .
O1 C41 C40 104.0(5) .
C40A C41 C40 41.2(5) .
O1 C41 H41C 111.0 .
C40A C41 H41C 72.6 .
C40 C41 H41C 111.0 .
O1 C41 H41D 111.0 .
C40A C41 H41D 139.9 .
C40 C41 H41D 111.0 .
H41C C41 H41D 109.0 .
O1 C41 H41A 107(6) .
C40A C41 H41A 112(6) .
C40 C41 H41A 144(6) .
H41C C41 H41A 39.7 .
H41D C41 H41A 74.7 .
O1 C41 H41B 94(7) .
C40A C41 H41B 124(8) .
C40 C41 H41B 83(7) .
H41C C41 H41B 145.6 .
H41D C41 H41B 37.8 .
H41A C41 H41B 112(10) .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Eu1 N1 2.470(3) .
Eu1 O1 2.581(3) .
Eu1 C11 3.020(3) .
Eu1 C12 3.033(4) .
Eu1 C4 3.041(4) .
Eu1 C28 3.075(4) .
Eu1 C16 3.104(4) .
Eu1 C13 3.145(4) .
Eu1 C15 3.194(4) .
Eu1 C14 3.207(4) .
Eu1 I1 3.2456(4) .
Eu1 I1 3.3793(4) 2_655
I1 Eu1 3.3794(4) 2_655
Si1 N1 1.695(3) .
Si1 C2 1.857(4) .
Si1 C1 1.865(4) .
Si1 C3 1.870(4) .
O1 C41 1.439(6) .
O1 C38 1.440(5) .
N1 C4 1.398(5) .
C1 H1A 0.9800 .
C1 H1B 0.9800 .
C1 H1C 0.9800 .
C2 H2A 0.9800 .
C2 H2B 0.9800 .
C2 H2C 0.9800 .
C42 C29 1.361(6) .
C42 C30 1.377(6) .
C42 H2AA 0.9500 .
C3 H3A 0.9800 .
C3 H3B 0.9800 .
C3 H3C 0.9800 .
C4 C5 1.404(5) .
C4 C9 1.410(5) .
C5 C6 1.395(5) .
C5 C10 1.520(5) .
C6 C7 1.383(5) .
C6 H6 0.9500 .
C7 C8 1.397(5) .
C7 C23 1.506(5) .
C8 C9 1.376(5) .
C8 H8 0.9500 .
C9 C26 1.520(5) .
C10 C11 1.514(5) .
C10 C17 1.521(5) .
C10 H10 1.0000 .
C11 C16 1.384(5) .
C11 C12 1.389(5) .
C12 C13 1.387(5) .
C12 H12 0.9500 .
C13 C14 1.376(6) .
C13 H13 0.9500 .
C14 C15 1.378(6) .
C14 H14 0.9500 .
C15 C16 1.381(5) .
C15 H15 0.9500 .
C16 H16 0.9500 .
C17 C18 1.369(5) .
C17 C22 1.386(5) .
C18 C19 1.389(5) .
C18 H18 0.9500 .
C19 C20 1.361(6) .
C19 H19 0.9500 .
C20 C21 1.370(6) .
C20 H20 0.9500 .
C21 C22 1.367(6) .
C21 H21 0.9500 .
C22 H22 0.9500 .
C23 C25 1.504(6) .
C23 C24 1.514(5) .
C23 H23 1.0000 .
C24 H24A 0.9800 .
C24 H24B 0.9800 .
C24 H24C 0.9800 .
C25 H25A 0.9800 .
C25 H25B 0.9800 .
C25 H25C 0.9800 .
C26 C32 1.513(5) .
C26 C27 1.518(5) .
C26 H26 1.0000 .
C27 C31 1.382(6) .
C27 C28 1.389(5) .
C28 C29 1.381(6) .
C28 H28 0.9500 .
C29 H29 0.9500 .
C30 C31 1.383(6) .
C30 H30 0.9500 .
C31 H31 0.9500 .
C32 C37 1.385(5) .
C32 C33 1.392(5) .
C33 C34 1.374(6) .
C33 H33 0.9500 .
C34 C35 1.371(6) .
C34 H34 0.9500 .
C35 C36 1.371(6) .
C35 H35 0.9500 .
C36 C37 1.378(6) .
C36 H36 0.9500 .
C37 H37 0.9500 .
C38 C39 1.448(7) .
C38 H38A 0.9900 .
C38 H38B 0.9900 .
C38 H39A 1.36(11) .
C39 C40 1.466(11) .
C39 C40A 1.480(11) .
C39 H39C 0.9900 .
C39 H39D 0.9900 .
C39 H39A 1.13(11) .
C39 H39B 0.85(12) .
C40 C41 1.568(12) .
C40 H39A 1.41(11) .
C40 H40A 0.9900 .
C40 H40B 0.9900 .
C40A C41 1.526(11) .
C40A H40C 0.9900 .
C40A H40D 0.9900 .
C41 H41C 0.9900 .
C41 H41D 0.9900 .
C41 H41A 0.97(11) .
C41 H41B 0.91(10) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
N1 Eu1 I1 Eu1 175.62(7) . 2_655
O1 Eu1 I1 Eu1 42.87(12) . 2_655
C11 Eu1 I1 Eu1 -120.54(8) . 2_655
C12 Eu1 I1 Eu1 -97.19(11) . 2_655
C4 Eu1 I1 Eu1 168.79(7) . 2_655
C28 Eu1 I1 Eu1 101.77(8) . 2_655
C16 Eu1 I1 Eu1 -111.84(7) . 2_655
C13 Eu1 I1 Eu1 -67.08(9) . 2_655
C15 Eu1 I1 Eu1 -87.79(8) . 2_655
C14 Eu1 I1 Eu1 -67.48(8) . 2_655
I1 Eu1 I1 Eu1 0.0 2_655 2_655
N1 Eu1 O1 C41 -172.8(4) . .
C11 Eu1 O1 C41 119.5(4) . .
C12 Eu1 O1 C41 106.3(4) . .
C4 Eu1 O1 C41 -178.3(4) . .
C28 Eu1 O1 C41 -103.0(4) . .
C16 Eu1 O1 C41 105.5(4) . .
C13 Eu1 O1 C41 79.1(4) . .
C15 Eu1 O1 C41 77.2(4) . .
C14 Eu1 O1 C41 66.1(4) . .
I1 Eu1 O1 C41 -45.7(5) . .
I1 Eu1 O1 C41 -3.8(4) 2_655 .
N1 Eu1 O1 C38 13.9(3) . .
C11 Eu1 O1 C38 -53.9(3) . .
C12 Eu1 O1 C38 -67.0(3) . .
C4 Eu1 O1 C38 8.4(3) . .
C28 Eu1 O1 C38 83.6(3) . .
C16 Eu1 O1 C38 -67.9(3) . .
C13 Eu1 O1 C38 -94.3(3) . .
C15 Eu1 O1 C38 -96.2(3) . .
C14 Eu1 O1 C38 -107.2(3) . .
I1 Eu1 O1 C38 140.9(3) . .
I1 Eu1 O1 C38 -177.2(3) 2_655 .
C2 Si1 N1 C4 -130.5(3) . .
C1 Si1 N1 C4 -10.0(3) . .
C3 Si1 N1 C4 110.4(3) . .
C2 Si1 N1 Eu1 49.9(3) . .
C1 Si1 N1 Eu1 170.4(2) . .
C3 Si1 N1 Eu1 -69.2(3) . .
O1 Eu1 N1 C4 -12.2(2) . .
C11 Eu1 N1 C4 73.7(2) . .
C12 Eu1 N1 C4 57.7(2) . .
C28 Eu1 N1 C4 -88.5(2) . .
C16 Eu1 N1 C4 100.9(2) . .
C13 Eu1 N1 C4 67.2(2) . .
C15 Eu1 N1 C4 109.6(2) . .
C14 Eu1 N1 C4 94.6(2) . .
I1 Eu1 N1 C4 -166.2(2) . .
I1 Eu1 N1 C4 -151.35(19) 2_655 .
O1 Eu1 N1 Si1 167.4(2) . .
C11 Eu1 N1 Si1 -106.6(2) . .
C12 Eu1 N1 Si1 -122.6(2) . .
C4 Eu1 N1 Si1 179.7(4) . .
C28 Eu1 N1 Si1 91.2(2) . .
C16 Eu1 N1 Si1 -79.4(2) . .
C13 Eu1 N1 Si1 -113.1(2) . .
C15 Eu1 N1 Si1 -70.8(2) . .
C14 Eu1 N1 Si1 -85.8(2) . .
I1 Eu1 N1 Si1 13.5(2) . .
I1 Eu1 N1 Si1 28.3(4) 2_655 .
Si1 N1 C4 C5 96.3(4) . .
Eu1 N1 C4 C5 -84.0(3) . .
Si1 N1 C4 C9 -85.2(4) . .
Eu1 N1 C4 C9 94.5(3) . .
Si1 N1 C4 Eu1 -179.7(3) . .
O1 Eu1 C4 N1 168.8(2) . .
C11 Eu1 C4 N1 -93.8(2) . .
C12 Eu1 C4 N1 -119.0(2) . .
C28 Eu1 C4 N1 83.9(2) . .
C16 Eu1 C4 N1 -72.4(2) . .
C13 Eu1 C4 N1 -120.4(2) . .
C15 Eu1 C4 N1 -75.3(2) . .
C14 Eu1 C4 N1 -99.0(2) . .
I1 Eu1 C4 N1 15.2(2) . .
I1 Eu1 C4 N1 146.4(2) 2_655 .
N1 Eu1 C4 C5 117.7(3) . .
O1 Eu1 C4 C5 -73.5(2) . .
C11 Eu1 C4 C5 23.9(2) . .
C12 Eu1 C4 C5 -1.3(2) . .
C28 Eu1 C4 C5 -158.4(3) . .
C16 Eu1 C4 C5 45.3(2) . .
C13 Eu1 C4 C5 -2.7(3) . .
C15 Eu1 C4 C5 42.4(3) . .
C14 Eu1 C4 C5 18.7(3) . .
I1 Eu1 C4 C5 132.9(2) . .
I1 Eu1 C4 C5 -95.9(3) 2_655 .
N1 Eu1 C4 C9 -115.0(3) . .
O1 Eu1 C4 C9 53.7(3) . .
C11 Eu1 C4 C9 151.2(3) . .
C12 Eu1 C4 C9 125.9(3) . .
C28 Eu1 C4 C9 -31.1(3) . .
C16 Eu1 C4 C9 172.5(3) . .
C13 Eu1 C4 C9 124.6(3) . .
C15 Eu1 C4 C9 169.7(2) . .
C14 Eu1 C4 C9 146.0(2) . .
I1 Eu1 C4 C9 -99.8(2) . .
I1 Eu1 C4 C9 31.4(5) 2_655 .
N1 C4 C5 C6 175.6(3) . .
C9 C4 C5 C6 -2.9(5) . .
Eu1 C4 C5 C6 120.9(3) . .
N1 C4 C5 C10 -5.5(5) . .
C9 C4 C5 C10 176.0(3) . .
Eu1 C4 C5 C10 -60.3(3) . .
C4 C5 C6 C7 0.0(6) . .
C10 C5 C6 C7 -178.8(3) . .
C5 C6 C7 C8 2.1(6) . .
C5 C6 C7 C23 -177.8(4) . .
C6 C7 C8 C9 -1.4(6) . .
C23 C7 C8 C9 178.5(4) . .
C7 C8 C9 C4 -1.4(6) . .
C7 C8 C9 C26 -179.1(3) . .
N1 C4 C9 C8 -174.9(3) . .
C5 C4 C9 C8 3.6(5) . .
Eu1 C4 C9 C8 -115.5(3) . .
N1 C4 C9 C26 2.9(5) . .
C5 C4 C9 C26 -178.6(3) . .
Eu1 C4 C9 C26 62.3(4) . .
C6 C5 C10 C11 -108.9(4) . .
C4 C5 C10 C11 72.2(4) . .
C6 C5 C10 C17 21.3(5) . .
C4 C5 C10 C17 -157.5(3) . .
C5 C10 C11 C16 -125.7(4) . .
C17 C10 C11 C16 105.0(4) . .
C5 C10 C11 C12 51.9(4) . .
C17 C10 C11 C12 -77.4(4) . .
C5 C10 C11 Eu1 -35.2(4) . .
C17 C10 C11 Eu1 -164.5(2) . .
N1 Eu1 C11 C16 96.2(2) . .
O1 Eu1 C11 C16 -150.8(2) . .
C12 Eu1 C11 C16 -121.9(4) . .
C4 Eu1 C11 C16 125.5(3) . .
C28 Eu1 C11 C16 122.1(2) . .
C13 Eu1 C11 C16 -92.1(3) . .
C15 Eu1 C11 C16 -29.0(2) . .
C14 Eu1 C11 C16 -60.4(2) . .
I1 Eu1 C11 C16 20.1(3) . .
I1 Eu1 C11 C16 -69.6(2) 2_655 .
N1 Eu1 C11 C12 -141.9(3) . .
O1 Eu1 C11 C12 -29.0(2) . .
C4 Eu1 C11 C12 -112.6(3) . .
C28 Eu1 C11 C12 -116.0(3) . .
C16 Eu1 C11 C12 121.9(4) . .
C13 Eu1 C11 C12 29.8(2) . .
C15 Eu1 C11 C12 92.9(3) . .
C14 Eu1 C11 C12 61.5(2) . .
I1 Eu1 C11 C12 142.0(2) . .
I1 Eu1 C11 C12 52.3(3) 2_655 .
N1 Eu1 C11 C10 -22.9(2) . .
O1 Eu1 C11 C10 90.0(3) . .
C12 Eu1 C11 C10 119.0(4) . .
C4 Eu1 C11 C10 6.3(2) . .
C28 Eu1 C11 C10 3.0(3) . .
C16 Eu1 C11 C10 -119.2(4) . .
C13 Eu1 C11 C10 148.8(3) . .
C15 Eu1 C11 C10 -148.1(3) . .
C14 Eu1 C11 C10 -179.6(3) . .
I1 Eu1 C11 C10 -99.1(2) . .
I1 Eu1 C11 C10 171.2(2) 2_655 .
C16 C11 C12 C13 0.4(5) . .
C10 C11 C12 C13 -177.3(3) . .
Eu1 C11 C12 C13 -71.2(3) . .
C16 C11 C12 Eu1 71.6(3) . .
C10 C11 C12 Eu1 -106.1(3) . .
N1 Eu1 C12 C13 159.7(3) . .
O1 Eu1 C12 C13 -85.6(3) . .
C11 Eu1 C12 C13 124.9(4) . .
C4 Eu1 C12 C13 -177.0(3) . .
C28 Eu1 C12 C13 -138.8(3) . .
C16 Eu1 C12 C13 93.4(3) . .
C15 Eu1 C12 C13 60.8(3) . .
C14 Eu1 C12 C13 28.8(2) . .
I1 Eu1 C12 C13 72.7(3) . .
I1 Eu1 C12 C13 -12.0(3) 2_655 .
N1 Eu1 C12 C11 34.8(2) . .
O1 Eu1 C12 C11 149.5(3) . .
C4 Eu1 C12 C11 58.1(2) . .
C28 Eu1 C12 C11 96.3(3) . .
C16 Eu1 C12 C11 -31.5(2) . .
C13 Eu1 C12 C11 -124.9(4) . .
C15 Eu1 C12 C11 -64.1(2) . .
C14 Eu1 C12 C11 -96.0(3) . .
I1 Eu1 C12 C11 -52.2(3) . .
I1 Eu1 C12 C11 -136.9(2) 2_655 .
C11 C12 C13 C14 1.5(6) . .
Eu1 C12 C13 C14 -66.9(3) . .
C11 C12 C13 Eu1 68.3(3) . .
N1 Eu1 C13 C14 103.9(3) . .
O1 Eu1 C13 C14 -148.0(3) . .
C11 Eu1 C13 C14 95.6(3) . .
C12 Eu1 C13 C14 126.1(4) . .
C4 Eu1 C13 C14 129.1(2) . .
C28 Eu1 C13 C14 -153.2(3) . .
C16 Eu1 C13 C14 61.8(3) . .
C15 Eu1 C13 C14 29.5(2) . .
I1 Eu1 C13 C14 -0.9(3) . .
I1 Eu1 C13 C14 -65.6(2) 2_655 .
N1 Eu1 C13 C12 -22.2(3) . .
O1 Eu1 C13 C12 85.8(3) . .
C11 Eu1 C13 C12 -30.6(2) . .
C4 Eu1 C13 C12 2.9(3) . .
C28 Eu1 C13 C12 80.7(4) . .
C16 Eu1 C13 C12 -64.3(3) . .
C15 Eu1 C13 C12 -96.6(3) . .
C14 Eu1 C13 C12 -126.1(4) . .
I1 Eu1 C13 C12 -127.1(2) . .
I1 Eu1 C13 C12 168.3(3) 2_655 .
C12 C13 C14 C15 -2.4(6) . .
Eu1 C13 C14 C15 -65.4(3) . .
C12 C13 C14 Eu1 63.0(3) . .
N1 Eu1 C14 C13 -87.8(3) . .
O1 Eu1 C14 C13 30.3(3) . .
C11 Eu1 C14 C13 -63.6(2) . .
C12 Eu1 C14 C13 -29.9(2) . .
C4 Eu1 C14 C13 -57.8(3) . .
C28 Eu1 C14 C13 107.5(6) . .
C16 Eu1 C14 C13 -96.5(3) . .
C15 Eu1 C14 C13 -125.6(4) . .
I1 Eu1 C14 C13 179.2(2) . .
I1 Eu1 C14 C13 108.3(3) 2_655 .
N1 Eu1 C14 C15 37.7(3) . .
O1 Eu1 C14 C15 155.8(2) . .
C11 Eu1 C14 C15 62.0(2) . .
C12 Eu1 C14 C15 95.7(3) . .
C4 Eu1 C14 C15 67.8(3) . .
C28 Eu1 C14 C15 -126.9(6) . .
C16 Eu1 C14 C15 29.0(2) . .
C13 Eu1 C14 C15 125.6(4) . .
I1 Eu1 C14 C15 -55.2(2) . .
I1 Eu1 C14 C15 -126.1(3) 2_655 .
C13 C14 C15 C16 1.5(6) . .
Eu1 C14 C15 C16 -62.8(3) . .
C13 C14 C15 Eu1 64.3(3) . .
N1 Eu1 C15 C14 -146.7(2) . .
O1 Eu1 C15 C14 -27.0(3) . .
C11 Eu1 C15 C14 -97.2(3) . .
C12 Eu1 C15 C14 -62.9(2) . .
C4 Eu1 C15 C14 -120.5(2) . .
C28 Eu1 C15 C14 153.5(3) . .
C16 Eu1 C15 C14 -127.1(4) . .
C13 Eu1 C15 C14 -29.6(2) . .
I1 Eu1 C15 C14 125.4(2) . .
I1 Eu1 C15 C14 49.9(2) 2_655 .
N1 Eu1 C15 C16 -19.6(3) . .
O1 Eu1 C15 C16 100.1(3) . .
C11 Eu1 C15 C16 29.9(2) . .
C12 Eu1 C15 C16 64.2(3) . .
C4 Eu1 C15 C16 6.6(3) . .
C28 Eu1 C15 C16 -79.4(4) . .
C13 Eu1 C15 C16 97.5(3) . .
C14 Eu1 C15 C16 127.1(4) . .
I1 Eu1 C15 C16 -107.5(3) . .
I1 Eu1 C15 C16 177.0(3) 2_655 .
C14 C15 C16 C11 0.3(6) . .
Eu1 C15 C16 C11 -64.7(3) . .
C14 C15 C16 Eu1 65.0(3) . .
C12 C11 C16 C15 -1.3(5) . .
C10 C11 C16 C15 176.4(3) . .
Eu1 C11 C16 C15 68.5(3) . .
C12 C11 C16 Eu1 -69.8(3) . .
C10 C11 C16 Eu1 107.9(3) . .
N1 Eu1 C16 C15 159.6(3) . .
O1 Eu1 C16 C15 -92.9(3) . .
C11 Eu1 C16 C15 -126.1(4) . .
C12 Eu1 C16 C15 -94.0(3) . .
C4 Eu1 C16 C15 -173.5(3) . .
C28 Eu1 C16 C15 143.6(3) . .
C13 Eu1 C16 C15 -60.6(3) . .
C14 Eu1 C16 C15 -28.5(2) . .
I1 Eu1 C16 C15 71.8(3) . .
I1 Eu1 C16 C15 -3.2(3) 2_655 .
N1 Eu1 C16 C11 -74.3(2) . .
O1 Eu1 C16 C11 33.2(3) . .
C12 Eu1 C16 C11 32.1(2) . .
C4 Eu1 C16 C11 -47.5(2) . .
C28 Eu1 C16 C11 -90.4(3) . .
C13 Eu1 C16 C11 65.5(2) . .
C15 Eu1 C16 C11 126.1(4) . .
C14 Eu1 C16 C11 97.5(3) . .
I1 Eu1 C16 C11 -162.2(2) . .
I1 Eu1 C16 C11 122.8(2) 2_655 .
C11 C10 C17 C18 21.6(5) . .
C5 C10 C17 C18 -107.0(4) . .
C11 C10 C17 C22 -159.8(4) . .
C5 C10 C17 C22 71.7(5) . .
C22 C17 C18 C19 -0.5(6) . .
C10 C17 C18 C19 178.2(4) . .
C17 C18 C19 C20 -0.2(6) . .
C18 C19 C20 C21 0.4(7) . .
C19 C20 C21 C22 0.1(7) . .
C20 C21 C22 C17 -0.8(7) . .
C18 C17 C22 C21 1.0(6) . .
C10 C17 C22 C21 -177.8(4) . .
C6 C7 C23 C25 -122.7(4) . .
C8 C7 C23 C25 57.3(5) . .
C6 C7 C23 C24 3.3(6) . .
C8 C7 C23 C24 -176.7(4) . .
C8 C9 C26 C32 -43.2(5) . .
C4 C9 C26 C32 139.0(4) . .
C8 C9 C26 C27 88.2(4) . .
C4 C9 C26 C27 -89.5(4) . .
C32 C26 C27 C31 57.5(5) . .
C9 C26 C27 C31 -75.2(4) . .
C32 C26 C27 C28 -124.4(4) . .
C9 C26 C27 C28 102.8(4) . .
C31 C27 C28 C29 2.4(5) . .
C26 C27 C28 C29 -175.7(3) . .
C31 C27 C28 Eu1 103.9(3) . .
C26 C27 C28 Eu1 -74.2(3) . .
N1 Eu1 C28 C29 -176.0(3) . .
O1 Eu1 C28 C29 67.9(3) . .
C11 Eu1 C28 C29 159.1(3) . .
C12 Eu1 C28 C29 117.8(3) . .
C4 Eu1 C28 C29 156.1(3) . .
C16 Eu1 C28 C29 -160.1(3) . .
C13 Eu1 C28 C29 72.8(4) . .
C15 Eu1 C28 C29 -112.6(4) . .
C14 Eu1 C28 C29 -10.3(8) . .
I1 Eu1 C28 C29 -83.9(3) . .
I1 Eu1 C28 C29 -11.0(3) 2_655 .
N1 Eu1 C28 C27 61.1(3) . .
O1 Eu1 C28 C27 -55.0(3) . .
C11 Eu1 C28 C27 36.3(4) . .
C12 Eu1 C28 C27 -5.0(4) . .
C4 Eu1 C28 C27 33.2(3) . .
C16 Eu1 C28 C27 77.1(3) . .
C13 Eu1 C28 C27 -50.1(4) . .
C15 Eu1 C28 C27 124.5(3) . .
C14 Eu1 C28 C27 -133.1(6) . .
I1 Eu1 C28 C27 153.2(3) . .
I1 Eu1 C28 C27 -133.9(3) 2_655 .
C30 C42 C29 C28 -0.4(6) . .
C27 C28 C29 C42 -1.7(6) . .
Eu1 C28 C29 C42 -109.8(4) . .
C29 C42 C30 C31 1.7(6) . .
C28 C27 C31 C30 -1.1(6) . .
C26 C27 C31 C30 177.0(4) . .
C42 C30 C31 C27 -0.9(6) . .
C27 C26 C32 C37 -152.4(4) . .
C9 C26 C32 C37 -23.2(5) . .
C27 C26 C32 C33 35.5(5) . .
C9 C26 C32 C33 164.7(3) . .
C37 C32 C33 C34 -0.1(6) . .
C26 C32 C33 C34 172.5(4) . .
C32 C33 C34 C35 0.5(7) . .
C33 C34 C35 C36 0.1(7) . .
C34 C35 C36 C37 -1.2(7) . .
C35 C36 C37 C32 1.7(7) . .
C33 C32 C37 C36 -1.0(6) . .
C26 C32 C37 C36 -173.3(4) . .
C41 O1 C38 C39 4.8(6) . .
Eu1 O1 C38 C39 179.3(4) . .
O1 C38 C39 C40 -28.3(8) . .
O1 C38 C39 C40A 16.8(8) . .
C38 C39 C40 C41 37.8(9) . .
C40A C39 C40 C41 -60.8(8) . .
C38 C39 C40A C41 -30.0(10) . .
C40 C39 C40A C41 64.3(8) . .
C38 O1 C41 C40A -23.7(7) . .
Eu1 O1 C41 C40A 162.1(5) . .
C38 O1 C41 C40 18.9(7) . .
Eu1 O1 C41 C40 -155.3(5) . .
C39 C40A C41 O1 32.7(9) . .
C39 C40A C41 C40 -61.5(8) . .
C39 C40 C41 O1 -34.9(9) . .
C39 C40 C41 C40A 62.1(8) . .
