#------------------------------------------------------------------------------
#$Date: 2019-11-07 23:52:17 +0200 (Thu, 07 Nov 2019) $
#$Revision: 224123 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/04/83/7048374.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7048374
loop_
_publ_author_name
'Xiang, Jing'
'Cheng, Shun-Cheung'
'Jin, Xin-Xin'
'Su, Qian-Qian'
'Zhou, Xin'
'Chu, Wing-Kin'
'Leung, Chi-Fai'
'Ko, Chi-Chiu'
_publ_section_title
;
 Polynuclear Cu(i) and Ag(i) phosphine complexes containing multi-dentate
 polytopic ligands: syntheses, crystal structures and photoluminescence
 properties.
;
_journal_issue                   2
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              741
_journal_page_last               750
_journal_paper_doi               10.1039/c8dt03377c
_journal_volume                  48
_journal_year                    2019
_chemical_formula_sum            'C60 H47 Ag2 N10 P3'
_chemical_formula_weight         1216.72
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2018-10-15 deposited with the CCDC.
2018-12-03 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 103.460(3)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   15.6274(4)
_cell_length_b                   14.2329(5)
_cell_length_c                   25.1211(8)
_cell_measurement_reflns_used    5416
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      71.0780
_cell_measurement_theta_min      3.6040
_cell_volume                     5434.0(3)
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_diffrn_ambient_temperature      293(2)
_diffrn_detector_area_resol_mean 8.1281
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'Xcalibur, Eos, Gemini'
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54184
_diffrn_reflns_av_R_equivalents  0.0703
_diffrn_reflns_av_unetI/netI     0.1173
_diffrn_reflns_Laue_measured_fraction_full 0.997
_diffrn_reflns_Laue_measured_fraction_max 0.997
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       29
_diffrn_reflns_limit_l_min       -30
_diffrn_reflns_number            19833
_diffrn_reflns_point_group_measured_fraction_full 0.997
_diffrn_reflns_point_group_measured_fraction_max 0.997
_diffrn_reflns_theta_full        67.249
_diffrn_reflns_theta_max         67.249
_diffrn_reflns_theta_min         2.908
_diffrn_source                   'Enhance (Cu) X-ray Source'
_exptl_absorpt_coefficient_mu    7.007
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.66768
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            white
_exptl_crystal_density_diffrn    1.487
_exptl_crystal_description       block
_exptl_crystal_F_000             2464
_exptl_crystal_size_max          0.080
_exptl_crystal_size_mid          0.070
_exptl_crystal_size_min          0.070
_refine_diff_density_max         0.666
_refine_diff_density_min         -0.578
_refine_diff_density_rms         0.101
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.039
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     676
_refine_ls_number_reflns         9709
_refine_ls_number_restraints     1932
_refine_ls_restrained_S_all      0.995
_refine_ls_R_factor_all          0.1052
_refine_ls_R_factor_gt           0.0630
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0147P)²+11.1158P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1202
_refine_ls_wR_factor_ref         0.1331
_reflns_Friedel_coverage         0.000
_reflns_number_gt                6318
_reflns_number_total             9709
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c8dt03377c2.cif
_cod_data_source_block           exp_7353
_cod_depositor_comments
'Adding full bibliography for 7048372--7048377.cif.'
_cod_database_code               7048374
_shelx_shelxl_version_number     2014/7
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.604
_shelx_estimated_absorpt_t_max   0.640
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
Ag1 Ag 1.08536(3) 0.07404(4) 0.56953(2) 0.03848(15) Uani 1 1 d . U
Ag2 Ag 0.69664(3) 0.09161(4) 0.60487(2) 0.04192(16) Uani 1 1 d . U
P1 P 1.13049(12) 0.23462(14) 0.56505(7) 0.0347(4) Uani 1 1 d . U
P2 P 0.64336(12) 0.00180(15) 0.67363(8) 0.0404(5) Uani 1 1 d . U
P3 P 0.64978(13) 0.23726(15) 0.55466(8) 0.0440(5) Uani 1 1 d . U
C1 C 1.2419(5) 0.2626(6) 0.6028(3) 0.0404(16) Uani 1 1 d . U
C2 C 1.3011(5) 0.1898(6) 0.6112(3) 0.053(2) Uani 1 1 d . U
H2 H 1.2825 0.1296 0.5996 0.064 Uiso 1 1 calc R U
C3 C 1.3893(5) 0.2057(7) 0.6372(4) 0.063(2) Uani 1 1 d . U
H3 H 1.4291 0.1561 0.6428 0.076 Uiso 1 1 calc R U
C4 C 1.4169(6) 0.2944(7) 0.6543(4) 0.062(2) Uani 1 1 d . U
H4 H 1.4756 0.3056 0.6712 0.074 Uiso 1 1 calc R U
C5 C 1.3571(6) 0.3668(7) 0.6462(4) 0.064(2) Uani 1 1 d . U
H5 H 1.3759 0.4271 0.6573 0.077 Uiso 1 1 calc R U
C6 C 1.2688(5) 0.3513(6) 0.6217(3) 0.0514(19) Uani 1 1 d . U
H6 H 1.2284 0.4002 0.6180 0.062 Uiso 1 1 calc R U
C7 C 1.1315(5) 0.2717(5) 0.4952(3) 0.0372(15) Uani 1 1 d . U
C8 C 1.1928(5) 0.3332(6) 0.4832(3) 0.0500(19) Uani 1 1 d . U
H8 H 1.2364 0.3583 0.5113 0.060 Uiso 1 1 calc R U
C9 C 1.1893(6) 0.3574(6) 0.4291(4) 0.057(2) Uani 1 1 d . U
H9 H 1.2299 0.3997 0.4211 0.068 Uiso 1 1 calc R U
C10 C 1.1262(6) 0.3193(7) 0.3875(4) 0.062(2) Uani 1 1 d . U
H10 H 1.1238 0.3357 0.3513 0.074 Uiso 1 1 calc R U
C11 C 1.0673(6) 0.2576(7) 0.3994(4) 0.065(2) Uani 1 1 d . U
H11 H 1.0251 0.2313 0.3710 0.078 Uiso 1 1 calc R U
C12 C 1.0686(5) 0.2329(6) 0.4527(3) 0.0498(19) Uani 1 1 d . U
H12 H 1.0276 0.1904 0.4601 0.060 Uiso 1 1 calc R U
C13 C 1.0641(5) 0.3230(5) 0.5897(3) 0.0359(15) Uani 1 1 d . U
C14 C 1.0437(5) 0.4095(6) 0.5666(3) 0.0520(18) Uani 1 1 d . U
H14 H 1.0617 0.4254 0.5350 0.062 Uiso 1 1 calc R U
C15 C 0.9964(6) 0.4737(7) 0.5897(4) 0.060(2) Uani 1 1 d . U
H15 H 0.9822 0.5320 0.5733 0.072 Uiso 1 1 calc R U
C16 C 0.9703(6) 0.4513(6) 0.6370(3) 0.058(2) Uani 1 1 d . U
H16 H 0.9393 0.4947 0.6528 0.069 Uiso 1 1 calc R U
C17 C 0.9900(6) 0.3658(7) 0.6603(4) 0.064(2) Uani 1 1 d . U
H17 H 0.9729 0.3510 0.6924 0.077 Uiso 1 1 calc R U
C18 C 1.0355(6) 0.3003(6) 0.6367(3) 0.057(2) Uani 1 1 d . U
H18 H 1.0470 0.2410 0.6523 0.069 Uiso 1 1 calc R U
C19 C 1.0524(4) -0.0257(5) 0.6797(3) 0.0357(15) Uani 1 1 d . U
C20 C 0.8871(4) 0.0356(5) 0.5927(3) 0.0318(14) Uani 1 1 d . U
C21 C 0.9134(4) 0.0721(5) 0.6493(3) 0.0342(14) Uani 1 1 d . U
C22 C 0.9896(4) 0.0476(5) 0.6875(3) 0.0361(15) Uani 1 1 d . U
C23 C 0.9508(5) 0.1463(6) 0.7495(3) 0.052(2) Uani 1 1 d . U
H23 H 0.9632 0.1759 0.7835 0.062 Uiso 1 1 calc R U
C24 C 0.8724(5) 0.1666(6) 0.7126(3) 0.0460(18) Uani 1 1 d . U
H24 H 0.8319 0.2062 0.7231 0.055 Uiso 1 1 calc R U
C25 C 0.6961(5) -0.1084(6) 0.6983(3) 0.0471(17) Uani 1 1 d . U
C26 C 0.7850(5) -0.1184(7) 0.7008(3) 0.056(2) Uani 1 1 d . U
H26 H 0.8149 -0.0708 0.6874 0.067 Uiso 1 1 calc R U
C27 C 0.8299(6) -0.1984(7) 0.7228(4) 0.068(2) Uani 1 1 d . U
H27 H 0.8900 -0.2029 0.7251 0.082 Uiso 1 1 calc R U
C28 C 0.7875(7) -0.2697(7) 0.7409(4) 0.071(3) Uani 1 1 d . U
H28 H 0.8184 -0.3233 0.7553 0.085 Uiso 1 1 calc R U
C29 C 0.6989(6) -0.2633(7) 0.7381(4) 0.064(2) Uani 1 1 d . U
H29 H 0.6692 -0.3129 0.7500 0.077 Uiso 1 1 calc R U
C30 C 0.6538(6) -0.1816(6) 0.7173(3) 0.055(2) Uani 1 1 d . U
H30 H 0.5941 -0.1765 0.7162 0.066 Uiso 1 1 calc R U
C31 C 0.5254(5) -0.0216(5) 0.6561(3) 0.0432(17) Uani 1 1 d . U
C32 C 0.4751(5) -0.0295(6) 0.6944(4) 0.058(2) Uani 1 1 d . U
H32 H 0.5007 -0.0240 0.7316 0.070 Uiso 1 1 calc R U
C33 C 0.3840(6) -0.0460(7) 0.6760(4) 0.067(2) Uani 1 1 d . U
H33 H 0.3490 -0.0505 0.7011 0.081 Uiso 1 1 calc R U
C34 C 0.3470(6) -0.0552(7) 0.6215(4) 0.069(3) Uani 1 1 d . U
H34 H 0.2870 -0.0672 0.6101 0.083 Uiso 1 1 calc R U
C35 C 0.3958(6) -0.0473(6) 0.5832(4) 0.065(2) Uani 1 1 d . U
H35 H 0.3694 -0.0522 0.5461 0.078 Uiso 1 1 calc R U
C36 C 0.4857(5) -0.0319(6) 0.6010(3) 0.0514(19) Uani 1 1 d . U
H36 H 0.5199 -0.0284 0.5753 0.062 Uiso 1 1 calc R U
C37 C 0.6607(5) 0.0724(6) 0.7354(4) 0.0546(19) Uani 1 1 d . U
C38 C 0.7232(7) 0.0512(8) 0.7815(4) 0.078(2) Uani 1 1 d . U
H38 H 0.7553 -0.0042 0.7834 0.093 Uiso 1 1 calc R U
C39 C 0.7389(8) 0.1131(9) 0.8260(5) 0.101(3) Uani 1 1 d . U
H39 H 0.7827 0.0994 0.8569 0.121 Uiso 1 1 calc R U
C40 C 0.6910(9) 0.1921(9) 0.8245(5) 0.106(3) Uani 1 1 d . U
H40 H 0.6978 0.2292 0.8556 0.128 Uiso 1 1 calc R U
C41 C 0.6340(9) 0.2174(9) 0.7785(5) 0.120(4) Uani 1 1 d . U
H41 H 0.6037 0.2740 0.7768 0.145 Uiso 1 1 calc R U
C42 C 0.6201(7) 0.1579(8) 0.7324(5) 0.095(3) Uani 1 1 d . U
H42 H 0.5829 0.1770 0.6997 0.114 Uiso 1 1 calc R U
C43 C 0.7282(5) 0.2806(6) 0.5172(3) 0.0509(18) Uani 1 1 d . U
C44 C 0.7717(5) 0.2167(7) 0.4922(3) 0.0554(19) Uani 1 1 d . U
H44 H 0.7592 0.1531 0.4944 0.066 Uiso 1 1 calc R U
C45 C 0.8335(6) 0.2438(7) 0.4641(4) 0.066(2) Uani 1 1 d . U
H45 H 0.8621 0.1992 0.4474 0.079 Uiso 1 1 calc R U
C46 C 0.8522(6) 0.3365(8) 0.4609(4) 0.072(2) Uani 1 1 d . U
H46 H 0.8942 0.3556 0.4424 0.087 Uiso 1 1 calc R U
C47 C 0.8096(7) 0.4018(8) 0.4849(4) 0.080(3) Uani 1 1 d . U
H47 H 0.8225 0.4652 0.4823 0.096 Uiso 1 1 calc R U
C48 C 0.7473(6) 0.3748(7) 0.5131(4) 0.071(2) Uani 1 1 d . U
H48 H 0.7185 0.4199 0.5292 0.085 Uiso 1 1 calc R U
C49 C 0.5450(5) 0.2322(6) 0.5056(4) 0.0520(19) Uani 1 1 d . U
C50 C 0.5300(6) 0.2757(7) 0.4547(4) 0.071(2) Uani 1 1 d . U
H50 H 0.5749 0.3086 0.4443 0.085 Uiso 1 1 calc R U
C51 C 0.4458(7) 0.2693(8) 0.4190(4) 0.084(3) Uani 1 1 d . U
H51 H 0.4349 0.2988 0.3851 0.101 Uiso 1 1 calc R U
C52 C 0.3810(7) 0.2206(8) 0.4339(5) 0.081(3) Uani 1 1 d . U
H52 H 0.3259 0.2165 0.4100 0.097 Uiso 1 1 calc R U
C53 C 0.3955(6) 0.1779(8) 0.4832(4) 0.075(3) Uani 1 1 d . U
H53 H 0.3504 0.1451 0.4935 0.090 Uiso 1 1 calc R U
C54 C 0.4780(6) 0.1834(7) 0.5184(4) 0.067(2) Uani 1 1 d . U
H54 H 0.4878 0.1526 0.5519 0.080 Uiso 1 1 calc R U
C55 C 0.6393(6) 0.3360(7) 0.5991(4) 0.059(2) Uani 1 1 d . U
C56 C 0.7087(8) 0.3537(8) 0.6428(4) 0.095(3) Uani 1 1 d . U
H56 H 0.7562 0.3125 0.6500 0.114 Uiso 1 1 calc R U
C57 C 0.7098(9) 0.4317(9) 0.6766(5) 0.110(4) Uani 1 1 d . U
H57 H 0.7582 0.4446 0.7051 0.132 Uiso 1 1 calc R U
C58 C 0.6376(9) 0.4880(9) 0.6666(5) 0.103(3) Uani 1 1 d . U
H58 H 0.6356 0.5379 0.6902 0.124 Uiso 1 1 calc R U
C59 C 0.5687(8) 0.4744(8) 0.6235(5) 0.096(3) Uani 1 1 d . U
H59 H 0.5207 0.5149 0.6173 0.115 Uiso 1 1 calc R U
C60 C 0.5707(7) 0.3985(7) 0.5883(4) 0.075(2) Uani 1 1 d . U
H60 H 0.5251 0.3904 0.5575 0.090 Uiso 1 1 calc R U
N1 N 1.1002(4) -0.0253(5) 0.6422(2) 0.0419(14) Uani 1 1 d . U
N2 N 1.1484(4) -0.1051(5) 0.6516(3) 0.0497(16) Uani 1 1 d . U
N3 N 1.1283(5) -0.1503(5) 0.6925(3) 0.0584(19) Uani 1 1 d . U
N4 N 1.0672(4) -0.1018(5) 0.7110(3) 0.0521(17) Uani 1 1 d . U
N5 N 1.0086(4) 0.0866(5) 0.7381(2) 0.0473(15) Uani 1 1 d . U
N6 N 0.8540(4) 0.1304(5) 0.6627(2) 0.0417(14) Uani 1 1 d . U
N7 N 0.8023(4) 0.0117(5) 0.5710(2) 0.0375(14) Uani 1 1 d . U
N8 N 0.8024(4) -0.0152(5) 0.5193(2) 0.0392(14) Uani 1 1 d . U
N9 N 0.8810(4) -0.0058(4) 0.5107(2) 0.0375(14) Uani 1 1 d . U
N10 N 0.9365(4) 0.0257(4) 0.5565(2) 0.0353(13) Uani 1 1 d . U
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag 0.1306 4.2820 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.2955 0.4335 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_3
N1 Ag1 N10 81.0(2) .
N1 Ag1 P1 130.69(17) .
N10 Ag1 P1 123.95(15) .
N1 Ag1 N9 114.8(2) 3_756
N10 Ag1 N9 99.55(18) 3_756
P1 Ag1 N9 102.78(15) 3_756
N7 Ag2 P2 113.00(16) .
N7 Ag2 P3 112.25(16) .
P2 Ag2 P3 134.12(7) .
N7 Ag2 N6 69.5(2) .
P2 Ag2 N6 98.56(14) .
P3 Ag2 N6 103.77(15) .
C1 P1 C13 102.8(3) .
C1 P1 C7 102.5(3) .
C13 P1 C7 105.0(3) .
C1 P1 Ag1 116.0(3) .
C13 P1 Ag1 116.3(2) .
C7 P1 Ag1 112.7(3) .
C25 P2 C37 102.8(4) .
C25 P2 C31 106.2(4) .
C37 P2 C31 104.4(4) .
C25 P2 Ag2 119.4(3) .
C37 P2 Ag2 107.8(3) .
C31 P2 Ag2 114.6(3) .
C49 P3 C43 105.9(4) .
C49 P3 C55 104.6(4) .
C43 P3 C55 102.9(4) .
C49 P3 Ag2 115.6(3) .
C43 P3 Ag2 113.4(3) .
C55 P3 Ag2 113.3(3) .
C2 C1 C6 119.8(7) .
C2 C1 P1 116.4(6) .
C6 C1 P1 123.8(6) .
C1 C2 C3 120.4(8) .
C4 C3 C2 119.9(8) .
C3 C4 C5 119.3(8) .
C4 C5 C6 121.2(9) .
C1 C6 C5 119.2(8) .
C8 C7 C12 119.2(7) .
C8 C7 P1 123.4(6) .
C12 C7 P1 117.4(6) .
C7 C8 C9 119.8(8) .
C10 C9 C8 120.3(9) .
C11 C10 C9 119.6(8) .
C10 C11 C12 121.5(9) .
C11 C12 C7 119.5(8) .
C14 C13 C18 118.6(7) .
C14 C13 P1 124.8(6) .
C18 C13 P1 116.5(6) .
C13 C14 C15 120.8(8) .
C16 C15 C14 120.0(9) .
C17 C16 C15 119.9(8) .
C16 C17 C18 120.4(8) .
C17 C18 C13 120.3(8) .
N4 C19 N1 112.0(7) .
N4 C19 C22 121.8(6) .
N1 C19 C22 126.2(7) .
N10 C20 N7 111.6(6) .
N10 C20 C21 128.2(6) .
N7 C20 C21 120.1(6) .
N6 C21 C22 120.8(6) .
N6 C21 C20 113.8(6) .
C22 C21 C20 125.3(6) .
N5 C22 C21 120.7(7) .
N5 C22 C19 114.0(6) .
C21 C22 C19 125.1(7) .
N5 C23 C24 122.2(7) .
N6 C24 C23 121.1(7) .
C30 C25 C26 117.7(8) .
C30 C25 P2 123.7(6) .
C26 C25 P2 118.5(7) .
C25 C26 C27 121.0(9) .
C28 C27 C26 120.7(9) .
C27 C28 C29 120.2(10) .
C28 C29 C30 119.2(9) .
C25 C30 C29 121.2(9) .
C32 C31 C36 119.4(8) .
C32 C31 P2 123.6(7) .
C36 C31 P2 116.9(6) .
C31 C32 C33 118.7(9) .
C34 C33 C32 120.3(9) .
C35 C34 C33 121.6(9) .
C34 C35 C36 118.5(9) .
C31 C36 C35 121.4(8) .
C38 C37 C42 118.4(9) .
C38 C37 P2 122.6(7) .
C42 C37 P2 118.1(8) .
C37 C38 C39 119.8(10) .
C40 C39 C38 120.7(12) .
C41 C40 C39 120.4(12) .
C40 C41 C42 119.5(12) .
C37 C42 C41 120.5(11) .
C44 C43 C48 118.1(9) .
C44 C43 P3 118.5(7) .
C48 C43 P3 123.5(7) .
C43 C44 C45 122.0(9) .
C46 C45 C44 119.1(10) .
C45 C46 C47 120.3(10) .
C46 C47 C48 120.8(10) .
C43 C48 C47 119.8(10) .
C54 C49 C50 118.2(9) .
C54 C49 P3 119.1(7) .
C50 C49 P3 122.8(7) .
C49 C50 C51 119.1(10) .
C52 C51 C50 120.4(11) .
C51 C52 C53 120.6(10) .
C52 C53 C54 119.5(11) .
C49 C54 C53 122.2(10) .
C60 C55 C56 118.4(10) .
C60 C55 P3 123.8(8) .
C56 C55 P3 117.6(8) .
C55 C56 C57 121.8(11) .
C58 C57 C56 117.6(12) .
C59 C58 C57 122.5(12) .
C58 C59 C60 119.0(12) .
C55 C60 C59 120.4(10) .
C19 N1 N2 104.7(6) .
C19 N1 Ag1 126.9(5) .
N2 N1 Ag1 127.5(5) .
N3 N2 N1 108.9(6) .
N2 N3 N4 109.7(7) .
C19 N4 N3 104.7(6) .
C23 N5 C22 117.1(7) .
C24 N6 C21 117.8(6) .
C24 N6 Ag2 125.4(5) .
C21 N6 Ag2 110.3(5) .
C20 N7 N8 103.7(5) .
C20 N7 Ag2 116.3(5) .
N8 N7 Ag2 130.4(4) .
N9 N8 N7 109.9(5) .
N8 N9 N10 109.8(5) .
N8 N9 Ag1 119.7(4) 3_756
N10 N9 Ag1 128.9(4) 3_756
C20 N10 N9 104.9(5) .
C20 N10 Ag1 125.5(5) .
N9 N10 Ag1 129.1(4) .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 N1 2.278(6) .
Ag1 N10 2.374(5) .
Ag1 P1 2.402(2) .
Ag1 N9 2.405(6) 3_756
Ag2 N7 2.323(6) .
Ag2 P2 2.446(2) .
Ag2 P3 2.448(2) .
Ag2 N6 2.608(6) .
P1 C1 1.823(7) .
P1 C13 1.828(7) .
P1 C7 1.837(7) .
P2 C25 1.812(8) .
P2 C37 1.816(9) .
P2 C31 1.823(7) .
P3 C49 1.807(8) .
P3 C43 1.819(8) .
P3 C55 1.826(9) .
C1 C2 1.372(10) .
C1 C6 1.380(11) .
C2 C3 1.399(11) .
C3 C4 1.372(12) .
C4 C5 1.374(11) .
C5 C6 1.391(10) .
C7 C8 1.382(10) .
C7 C12 1.385(10) .
C8 C9 1.391(10) .
C9 C10 1.371(12) .
C10 C11 1.354(12) .
C11 C12 1.380(10) .
C13 C14 1.367(10) .
C13 C18 1.394(9) .
C14 C15 1.385(11) .
C15 C16 1.380(10) .
C16 C17 1.354(11) .
C17 C18 1.387(11) .
C19 N4 1.327(9) .
C19 N1 1.330(8) .
C19 C22 1.477(10) .
C20 N10 1.329(8) .
C20 N7 1.354(8) .
C20 C21 1.481(9) .
C21 N6 1.346(9) .
C21 C22 1.388(9) .
C22 N5 1.355(8) .
C23 N5 1.318(9) .
C23 C24 1.384(10) .
C24 N6 1.323(8) .
C25 C30 1.378(11) .
C25 C26 1.382(10) .
C26 C27 1.383(11) .
C27 C28 1.347(13) .
C28 C29 1.374(12) .
C29 C30 1.398(11) .
C31 C32 1.381(10) .
C31 C36 1.387(10) .
C32 C33 1.410(11) .
C33 C34 1.362(12) .
C34 C35 1.363(12) .
C35 C36 1.389(11) .
C37 C38 1.364(11) .
C37 C42 1.366(13) .
C38 C39 1.398(13) .
C39 C40 1.346(15) .
C40 C41 1.334(14) .
C41 C42 1.410(13) .
C43 C44 1.372(11) .
C43 C48 1.383(12) .
C44 C45 1.379(11) .
C45 C46 1.358(13) .
C46 C47 1.362(13) .
C47 C48 1.384(12) .
C49 C54 1.356(12) .
C49 C50 1.391(11) .
C50 C51 1.412(12) .
C51 C52 1.349(14) .
C52 C53 1.351(13) .
C53 C54 1.386(11) .
C55 C60 1.370(12) .
C55 C56 1.374(13) .
C56 C57 1.397(14) .
C57 C58 1.359(15) .
C58 C59 1.350(14) .
C59 C60 1.402(13) .
N1 N2 1.353(8) .
N2 N3 1.310(8) .
N3 N4 1.345(9) .
N7 N8 1.355(7) .
N8 N9 1.302(7) .
N9 N10 1.346(7) .
N9 Ag1 2.405(6) 3_756
