#------------------------------------------------------------------------------
#$Date: 2019-11-07 23:43:19 +0200 (Thu, 07 Nov 2019) $
#$Revision: 224089 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/04/83/7048389.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7048389
loop_
_publ_author_name
'Wu, Dong-Fang'
'Liu, Zhen'
'Ren, Peng'
'Liu, Xiao-He'
'Wang, Ning'
'Cui, Jian-Zhong'
'Gao, Hong-Ling'
_publ_section_title
;
 A new family of dinuclear lanthanide complexes constructed from an
 8-hydroxyquinoline Schiff base and β-diketone: magnetic properties and
 near-infrared luminescence.
;
_journal_issue                   4
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              1392
_journal_page_last               1403
_journal_paper_doi               10.1039/c8dt04384a
_journal_volume                  48
_journal_year                    2019
_chemical_formula_moiety         'C92 H64 Eu2 N6 O14'
_chemical_formula_sum            'C92 H64 Eu2 N6 O14'
_chemical_formula_weight         1781.41
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_audit_creation_date             2018-07-25
_audit_creation_method
;
Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_audit_update_record
;
2018-07-31 deposited with the CCDC.
2018-12-19 downloaded from the CCDC.
;
_cell_angle_alpha                95.6180(10)
_cell_angle_beta                 107.503(2)
_cell_angle_gamma                108.923(3)
_cell_formula_units_Z            1
_cell_length_a                   11.0252(17)
_cell_length_b                   13.768(2)
_cell_length_c                   14.157(2)
_cell_measurement_reflns_used    7185
_cell_measurement_temperature    133
_cell_measurement_theta_max      27.5
_cell_measurement_theta_min      3.1
_cell_volume                     1892.7(5)
_computing_cell_refinement
;
CrystalClear-SM Expert 2.1 b42 (Rigaku, 2015)
;
_computing_data_collection
;
CrystalClear-SM Expert 2.1 b42 (Rigaku, 2015)
;
_computing_data_reduction
;
CrystalClear-SM Expert 2.1 b42 (Rigaku, 2015)
;
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'ShelXS (Sheldrick, 2008)'
_diffrn_ambient_temperature      133.15
_diffrn_measured_fraction_theta_full 0.980
_diffrn_measured_fraction_theta_max 0.958
_diffrn_measurement_device_type  'Rigaku Xtalab P200'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0288
_diffrn_reflns_av_unetI/netI     0.0304
_diffrn_reflns_Laue_measured_fraction_full 0.980
_diffrn_reflns_Laue_measured_fraction_max 0.958
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            19519
_diffrn_reflns_point_group_measured_fraction_full 0.980
_diffrn_reflns_point_group_measured_fraction_max 0.958
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.595
_diffrn_reflns_theta_min         3.004
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    1.716
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  0.813
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'REQAB(Rigaku, 1998)'
_exptl_crystal_colour            Colorless
_exptl_crystal_density_diffrn    1.563
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Prism
_exptl_crystal_F_000             896
_exptl_crystal_size_max          0.2
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.14
_refine_diff_density_max         1.141
_refine_diff_density_min         -0.521
_refine_diff_density_rms         0.068
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.046
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     514
_refine_ls_number_reflns         8419
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.046
_refine_ls_R_factor_all          0.0224
_refine_ls_R_factor_gt           0.0208
_refine_ls_shift/su_max          0.004
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0330P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0546
_refine_ls_wR_factor_ref         0.0552
_reflns_Friedel_coverage         0.000
_reflns_number_gt                7926
_reflns_number_total             8419
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c8dt04384a2.cif
_cod_data_source_block           shelx_CCDC4
_cod_depositor_comments
'Adding full bibliography for 7048384--7048389.cif.'
_cod_database_code               7048389
_shelx_shelxl_version_number     2018/3
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_max   0.795
_shelx_estimated_absorpt_t_min   0.725
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
2.a Aromatic/amide H refined with riding coordinates:
 C3(H3), C4(H4), C5(H5), C7(H7), C8(H8), C10(H10), C12(H12), C13(H13),
 C15(H15), C16(H16), C17(H17), C18(H18), C19(H19), C20(H20), C21(H21), C24(H24),
  C27(H27), C28(H28), C29(H29), C30(H30), C31(H31), C32(H32), C33(H33),
 C34(H34), C35(H35), C36(H36), C39(H39), C42(H42), C43(H43), C44(H44), C45(H45),
  C46(H46)
;
_olex2_submission_special_instructions 'No special instructions were received'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
Eu1 Eu 0.67864(2) 0.55266(2) 0.10855(2) 0.01786(4) Uani 1 1 d .
O1 O 0.56076(13) 0.52278(10) -0.07330(9) 0.0208(3) Uani 1 1 d .
O2 O 1.09334(19) 0.70515(15) 0.68633(12) 0.0477(4) Uani 1 1 d .
O3 O 1.1976(2) 0.86335(14) 0.67286(13) 0.0528(5) Uani 1 1 d .
O4 O 0.67304(14) 0.39128(9) 0.03032(10) 0.0247(3) Uani 1 1 d .
O5 O 0.68111(14) 0.43791(10) 0.22274(10) 0.0261(3) Uani 1 1 d .
O6 O 0.70874(14) 0.66397(10) 0.25603(10) 0.0237(3) Uani 1 1 d .
O7 O 0.72420(14) 0.72452(10) 0.08150(10) 0.0247(3) Uani 1 1 d .
N1 N 0.83789(15) 0.58878(11) 0.00950(11) 0.0191(3) Uani 1 1 d .
N2 N 0.94966(17) 0.62879(12) 0.21372(12) 0.0247(3) Uani 1 1 d .
N3 N 1.1304(2) 0.76970(16) 0.63673(14) 0.0373(4) Uani 1 1 d .
C1 C 0.77865(19) 0.56638(13) -0.09297(13) 0.0193(3) Uani 1 1 d .
C2 C 0.63221(19) 0.53279(13) -0.13513(13) 0.0198(3) Uani 1 1 d .
C3 C 0.5727(2) 0.51081(14) -0.23996(14) 0.0241(4) Uani 1 1 d .
H3 H 0.476000 0.489074 -0.270343 0.029 Uiso 1 1 calc R
C4 C 0.6518(2) 0.51993(17) -0.30219(15) 0.0295(4) Uani 1 1 d .
H4 H 0.607088 0.503705 -0.373719 0.035 Uiso 1 1 calc R
C5 C 0.7921(2) 0.55159(16) -0.26299(15) 0.0295(4) Uani 1 1 d .
H5 H 0.843302 0.556555 -0.306791 0.035 Uiso 1 1 calc R
C6 C 0.8590(2) 0.57667(14) -0.15663(14) 0.0230(4) Uani 1 1 d .
C7 C 1.0024(2) 0.61170(15) -0.10874(16) 0.0266(4) Uani 1 1 d .
H7 H 1.059278 0.618539 -0.148420 0.032 Uiso 1 1 calc R
C8 C 1.0593(2) 0.63575(15) -0.00544(15) 0.0255(4) Uani 1 1 d .
H8 H 1.155975 0.660704 0.027324 0.031 Uiso 1 1 calc R
C9 C 0.97328(19) 0.62314(13) 0.05180(14) 0.0221(4) Uani 1 1 d .
C10 C 1.0299(2) 0.64877(14) 0.16302(14) 0.0243(4) Uani 1 1 d .
H10 H 1.126213 0.680262 0.197447 0.029 Uiso 1 1 calc R
C11 C 1.0063(2) 0.66442(15) 0.32113(14) 0.0255(4) Uani 1 1 d .
C12 C 1.0925(2) 0.76855(16) 0.36651(16) 0.0326(5) Uani 1 1 d .
H12 H 1.121832 0.815833 0.326137 0.039 Uiso 1 1 calc R
C13 C 1.1354(2) 0.80307(16) 0.47063(16) 0.0341(5) Uani 1 1 d .
H13 H 1.194003 0.873952 0.502399 0.041 Uiso 1 1 calc R
C14 C 1.0914(2) 0.73270(16) 0.52714(15) 0.0299(4) Uani 1 1 d .
C15 C 1.0085(2) 0.62895(17) 0.48410(16) 0.0324(5) Uani 1 1 d .
H15 H 0.981518 0.581654 0.525133 0.039 Uiso 1 1 calc R
C16 C 0.9652(2) 0.59465(16) 0.37994(15) 0.0311(4) Uani 1 1 d .
H16 H 0.907484 0.523440 0.348853 0.037 Uiso 1 1 calc R
C17 C 0.5774(2) 0.25360(16) -0.14972(16) 0.0306(4) Uani 1 1 d .
H17 H 0.610175 0.327111 -0.146864 0.037 Uiso 1 1 calc R
C18 C 0.5402(3) 0.18402(18) -0.24041(17) 0.0380(5) Uani 1 1 d .
H18 H 0.549872 0.209772 -0.298655 0.046 Uiso 1 1 calc R
C19 C 0.4892(3) 0.07719(18) -0.24557(17) 0.0411(5) Uani 1 1 d .
H19 H 0.463099 0.029161 -0.307621 0.049 Uiso 1 1 calc R
C20 C 0.4761(3) 0.04032(17) -0.16143(18) 0.0420(6) Uani 1 1 d .
H20 H 0.439669 -0.033305 -0.165575 0.050 Uiso 1 1 calc R
C21 C 0.5159(2) 0.11003(16) -0.06978(16) 0.0347(5) Uani 1 1 d .
H21 H 0.507680 0.083616 -0.011545 0.042 Uiso 1 1 calc R
C22 C 0.56744(19) 0.21763(14) -0.06283(14) 0.0241(4) Uani 1 1 d .
C23 C 0.60949(19) 0.29809(14) 0.03287(14) 0.0219(4) Uani 1 1 d .
C24 C 0.5781(2) 0.26828(15) 0.11730(15) 0.0270(4) Uani 1 1 d .
H24 H 0.527189 0.196279 0.111957 0.032 Uiso 1 1 calc R
C25 C 0.6178(2) 0.33875(15) 0.20856(14) 0.0244(4) Uani 1 1 d .
C26 C 0.5890(2) 0.29908(16) 0.29767(15) 0.0286(4) Uani 1 1 d .
C27 C 0.5023(3) 0.19784(18) 0.29051(18) 0.0394(5) Uani 1 1 d .
H27 H 0.458198 0.150177 0.226368 0.047 Uiso 1 1 calc R
C28 C 0.4782(3) 0.1644(2) 0.3745(2) 0.0508(7) Uani 1 1 d .
H28 H 0.417863 0.094674 0.367496 0.061 Uiso 1 1 calc R
C29 C 0.5416(3) 0.2322(2) 0.46821(19) 0.0511(7) Uani 1 1 d .
H29 H 0.525157 0.209401 0.525982 0.061 Uiso 1 1 calc R
C30 C 0.6290(3) 0.3332(2) 0.47763(17) 0.0475(6) Uani 1 1 d .
H30 H 0.673917 0.379877 0.542336 0.057 Uiso 1 1 calc R
C31 C 0.6519(2) 0.36739(18) 0.39291(16) 0.0357(5) Uani 1 1 d .
H31 H 0.710812 0.437683 0.399958 0.043 Uiso 1 1 calc R
C32 C 0.7498(2) 0.71465(16) 0.45639(15) 0.0317(5) Uani 1 1 d .
H32 H 0.710946 0.643173 0.421181 0.038 Uiso 1 1 calc R
C33 C 0.7756(3) 0.73829(18) 0.56003(16) 0.0387(5) Uani 1 1 d .
H33 H 0.753083 0.683190 0.594734 0.046 Uiso 1 1 calc R
C34 C 0.8333(3) 0.84099(19) 0.61209(16) 0.0395(5) Uani 1 1 d .
H34 H 0.854766 0.857281 0.683387 0.047 Uiso 1 1 calc R
C35 C 0.8601(3) 0.92090(19) 0.56007(17) 0.0484(7) Uani 1 1 d .
H35 H 0.897402 0.992237 0.595451 0.058 Uiso 1 1 calc R
C36 C 0.8326(3) 0.89712(17) 0.45652(17) 0.0411(6) Uani 1 1 d .
H36 H 0.850137 0.952426 0.421306 0.049 Uiso 1 1 calc R
C37 C 0.7798(2) 0.79327(15) 0.40366(14) 0.0245(4) Uani 1 1 d .
C38 C 0.75829(19) 0.76245(14) 0.29298(14) 0.0222(4) Uani 1 1 d .
C39 C 0.7939(2) 0.83943(14) 0.23872(14) 0.0260(4) Uani 1 1 d .
H39 H 0.835650 0.910931 0.274079 0.031 Uiso 1 1 calc R
C40 C 0.77134(19) 0.81708(14) 0.13430(14) 0.0226(4) Uani 1 1 d .
C41 C 0.8029(2) 0.90476(15) 0.07949(15) 0.0261(4) Uani 1 1 d .
C42 C 0.7941(2) 0.88088(17) -0.02069(16) 0.0332(5) Uani 1 1 d .
H42 H 0.770027 0.809861 -0.052453 0.040 Uiso 1 1 calc R
C43 C 0.8199(3) 0.95905(19) -0.07508(19) 0.0442(6) Uani 1 1 d .
H43 H 0.815305 0.941618 -0.143011 0.053 Uiso 1 1 calc R
C44 C 0.8522(3) 1.0620(2) -0.0303(2) 0.0484(6) Uani 1 1 d .
H44 H 0.868743 1.115517 -0.067595 0.058 Uiso 1 1 calc R
C45 C 0.8605(3) 1.08728(18) 0.0687(2) 0.0487(6) Uani 1 1 d .
H45 H 0.881966 1.158209 0.099217 0.058 Uiso 1 1 calc R
C46 C 0.8376(3) 1.00947(16) 0.12398(17) 0.0364(5) Uani 1 1 d .
H46 H 0.845571 1.027833 0.192644 0.044 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O1 Eu1 Eu1 36.28(3) 2_665 2_665
O1 Eu1 Eu1 35.21(3) . 2_665
O1 Eu1 O1 71.49(5) 2_665 .
O1 Eu1 N1 66.46(5) . .
O1 Eu1 N1 137.46(4) 2_665 .
O1 Eu1 N2 159.74(5) 2_665 .
O1 Eu1 N2 128.66(5) . .
O4 Eu1 Eu1 78.66(3) . 2_665
O4 Eu1 O1 71.54(4) . .
O4 Eu1 O1 90.09(4) . 2_665
O4 Eu1 O5 69.82(5) . .
O4 Eu1 N1 71.11(5) . .
O4 Eu1 N2 94.78(5) . .
O5 Eu1 Eu1 109.58(3) . 2_665
O5 Eu1 O1 81.88(5) . 2_665
O5 Eu1 O1 132.44(4) . .
O5 Eu1 N1 122.96(5) . .
O5 Eu1 N2 81.39(5) . .
O6 Eu1 Eu1 118.17(4) . 2_665
O6 Eu1 O1 90.95(4) . 2_665
O6 Eu1 O1 137.77(4) . .
O6 Eu1 O4 148.68(5) . .
O6 Eu1 O5 79.35(5) . .
O6 Eu1 O7 70.99(5) . .
O6 Eu1 N1 124.89(5) . .
O6 Eu1 N2 74.79(5) . .
O7 Eu1 Eu1 91.91(3) . 2_665
O7 Eu1 O1 77.43(4) . .
O7 Eu1 O1 106.16(5) . 2_665
O7 Eu1 O4 138.09(5) . .
O7 Eu1 O5 149.23(4) . .
O7 Eu1 N1 71.02(5) . .
O7 Eu1 N2 83.08(5) . .
N1 Eu1 Eu1 101.47(4) . 2_665
N1 Eu1 N2 62.33(5) . .
N2 Eu1 Eu1 163.80(3) . 2_665
Eu1 O1 Eu1 108.51(5) 2_665 .
C2 O1 Eu1 119.66(11) . .
C2 O1 Eu1 130.74(11) . 2_665
C23 O4 Eu1 131.41(12) . .
C25 O5 Eu1 131.16(12) . .
C38 O6 Eu1 137.32(12) . .
C40 O7 Eu1 137.85(12) . .
C1 N1 Eu1 116.68(12) . .
C9 N1 Eu1 123.72(12) . .
C9 N1 C1 119.51(16) . .
C10 N2 Eu1 117.30(12) . .
C10 N2 C11 118.78(17) . .
C11 N2 Eu1 122.97(12) . .
O2 N3 C14 118.22(18) . .
O3 N3 O2 124.12(19) . .
O3 N3 C14 117.7(2) . .
N1 C1 C2 117.50(16) . .
N1 C1 C6 121.31(17) . .
C6 C1 C2 121.19(16) . .
O1 C2 C1 119.39(16) . .
O1 C2 C3 123.52(17) . .
C3 C2 C1 117.08(17) . .
C2 C3 H3 119.2 . .
C2 C3 C4 121.52(19) . .
C4 C3 H3 119.2 . .
C3 C4 H4 119.0 . .
C5 C4 C3 122.09(18) . .
C5 C4 H4 119.0 . .
C4 C5 H5 120.5 . .
C4 C5 C6 119.07(18) . .
C6 C5 H5 120.5 . .
C5 C6 C1 119.05(18) . .
C7 C6 C1 117.41(17) . .
C7 C6 C5 123.54(18) . .
C6 C7 H7 120.0 . .
C8 C7 C6 120.01(18) . .
C8 C7 H7 120.0 . .
C7 C8 H8 120.4 . .
C7 C8 C9 119.11(18) . .
C9 C8 H8 120.4 . .
N1 C9 C8 122.63(17) . .
N1 C9 C10 116.29(17) . .
C8 C9 C10 121.08(18) . .
N2 C10 C9 120.09(18) . .
N2 C10 H10 120.0 . .
C9 C10 H10 120.0 . .
C12 C11 N2 121.38(18) . .
C16 C11 N2 118.19(17) . .
C16 C11 C12 120.25(18) . .
C11 C12 H12 120.1 . .
C13 C12 C11 119.9(2) . .
C13 C12 H12 120.1 . .
C12 C13 H13 120.6 . .
C14 C13 C12 118.73(19) . .
C14 C13 H13 120.6 . .
C13 C14 N3 119.17(18) . .
C13 C14 C15 122.32(19) . .
C15 C14 N3 118.5(2) . .
C14 C15 H15 120.6 . .
C14 C15 C16 118.9(2) . .
C16 C15 H15 120.6 . .
C11 C16 H16 120.0 . .
C15 C16 C11 119.90(19) . .
C15 C16 H16 120.0 . .
C18 C17 H17 119.4 . .
C18 C17 C22 121.1(2) . .
C22 C17 H17 119.4 . .
C17 C18 H18 120.2 . .
C19 C18 C17 119.6(2) . .
C19 C18 H18 120.2 . .
C18 C19 H19 120.0 . .
C20 C19 C18 120.07(19) . .
C20 C19 H19 120.0 . .
C19 C20 H20 119.8 . .
C19 C20 C21 120.4(2) . .
C21 C20 H20 119.8 . .
C20 C21 H21 119.7 . .
C22 C21 C20 120.5(2) . .
C22 C21 H21 119.7 . .
C17 C22 C23 118.06(17) . .
C21 C22 C17 118.23(18) . .
C21 C22 C23 123.69(18) . .
O4 C23 C22 115.16(17) . .
O4 C23 C24 123.84(16) . .
C24 C23 C22 121.00(17) . .
C23 C24 H24 118.3 . .
C25 C24 C23 123.43(18) . .
C25 C24 H24 118.3 . .
O5 C25 C24 123.63(18) . .
O5 C25 C26 116.39(16) . .
C24 C25 C26 119.97(18) . .
C27 C26 C25 123.39(18) . .
C27 C26 C31 117.9(2) . .
C31 C26 C25 118.74(19) . .
C26 C27 H27 119.2 . .
C28 C27 C26 121.6(2) . .
C28 C27 H27 119.2 . .
C27 C28 H28 120.0 . .
C29 C28 C27 120.1(3) . .
C29 C28 H28 120.0 . .
C28 C29 H29 120.2 . .
C28 C29 C30 119.5(2) . .
C30 C29 H29 120.2 . .
C29 C30 H30 119.8 . .
C29 C30 C31 120.4(2) . .
C31 C30 H30 119.8 . .
C26 C31 H31 119.8 . .
C30 C31 C26 120.5(2) . .
C30 C31 H31 119.8 . .
C33 C32 H32 119.4 . .
C37 C32 H32 119.4 . .
C37 C32 C33 121.23(19) . .
C32 C33 H33 120.0 . .
C34 C33 C32 120.0(2) . .
C34 C33 H33 120.0 . .
C33 C34 H34 120.2 . .
C33 C34 C35 119.6(2) . .
C35 C34 H34 120.2 . .
C34 C35 H35 119.9 . .
C34 C35 C36 120.2(2) . .
C36 C35 H35 119.9 . .
C35 C36 H36 119.6 . .
C35 C36 C37 120.7(2) . .
C37 C36 H36 119.6 . .
C32 C37 C36 118.10(18) . .
C32 C37 C38 118.60(16) . .
C36 C37 C38 123.26(18) . .
O6 C38 C37 115.33(16) . .
O6 C38 C39 124.43(17) . .
C39 C38 C37 120.24(16) . .
C38 C39 H39 118.2 . .
C38 C39 C40 123.56(16) . .
C40 C39 H39 118.2 . .
O7 C40 C39 123.27(17) . .
O7 C40 C41 116.34(17) . .
C39 C40 C41 120.39(16) . .
C42 C41 C40 119.04(17) . .
C42 C41 C46 118.22(19) . .
C46 C41 C40 122.72(18) . .
C41 C42 H42 119.4 . .
C43 C42 C41 121.1(2) . .
C43 C42 H42 119.4 . .
C42 C43 H43 120.1 . .
C44 C43 C42 119.8(2) . .
C44 C43 H43 120.1 . .
C43 C44 H44 120.0 . .
C45 C44 C43 120.0(2) . .
C45 C44 H44 120.0 . .
C44 C45 H45 119.9 . .
C44 C45 C46 120.3(2) . .
C46 C45 H45 119.9 . .
C41 C46 H46 119.7 . .
C45 C46 C41 120.5(2) . .
C45 C46 H46 119.7 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Eu1 Eu1 3.8994(5) 2_665
Eu1 O1 2.3711(13) 2_665
Eu1 O1 2.4331(13) .
Eu1 O4 2.3571(12) .
Eu1 O5 2.3689(14) .
Eu1 O6 2.3334(12) .
Eu1 O7 2.3494(13) .
Eu1 N1 2.5195(15) .
Eu1 N2 2.6891(16) .
O1 C2 1.332(2) .
O2 N3 1.229(3) .
O3 N3 1.223(2) .
O4 C23 1.257(2) .
O5 C25 1.279(2) .
O6 C38 1.272(2) .
O7 C40 1.266(2) .
N1 C1 1.356(2) .
N1 C9 1.326(2) .
N2 C10 1.279(3) .
N2 C11 1.424(2) .
N3 C14 1.467(3) .
C1 C2 1.435(3) .
C1 C6 1.428(3) .
C2 C3 1.386(3) .
C3 H3 0.9500 .
C3 C4 1.402(3) .
C4 H4 0.9500 .
C4 C5 1.374(3) .
C5 H5 0.9500 .
C5 C6 1.413(3) .
C6 C7 1.410(3) .
C7 H7 0.9500 .
C7 C8 1.364(3) .
C8 H8 0.9500 .
C8 C9 1.404(3) .
C9 C10 1.466(3) .
C10 H10 0.9500 .
C11 C12 1.393(3) .
C11 C16 1.386(3) .
C12 H12 0.9500 .
C12 C13 1.386(3) .
C13 H13 0.9500 .
C13 C14 1.376(3) .
C14 C15 1.377(3) .
C15 H15 0.9500 .
C15 C16 1.385(3) .
C16 H16 0.9500 .
C17 H17 0.9500 .
C17 C18 1.386(3) .
C17 C22 1.391(3) .
C18 H18 0.9500 .
C18 C19 1.379(3) .
C19 H19 0.9500 .
C19 C20 1.368(3) .
C20 H20 0.9500 .
C20 C21 1.392(3) .
C21 H21 0.9500 .
C21 C22 1.385(3) .
C22 C23 1.508(2) .
C23 C24 1.403(3) .
C24 H24 0.9500 .
C24 C25 1.393(3) .
C25 C26 1.501(3) .
C26 C27 1.385(3) .
C26 C31 1.396(3) .
C27 H27 0.9500 .
C27 C28 1.383(3) .
C28 H28 0.9500 .
C28 C29 1.377(4) .
C29 H29 0.9500 .
C29 C30 1.378(4) .
C30 H30 0.9500 .
C30 C31 1.393(3) .
C31 H31 0.9500 .
C32 H32 0.9500 .
C32 C33 1.391(3) .
C32 C37 1.383(3) .
C33 H33 0.9500 .
C33 C34 1.370(3) .
C34 H34 0.9500 .
C34 C35 1.385(4) .
C35 H35 0.9500 .
C35 C36 1.387(3) .
C36 H36 0.9500 .
C36 C37 1.390(3) .
C37 C38 1.508(2) .
C38 C39 1.392(3) .
C39 H39 0.9500 .
C39 C40 1.408(3) .
C40 C41 1.501(3) .
C41 C42 1.391(3) .
C41 C46 1.393(3) .
C42 H42 0.9500 .
C42 C43 1.388(3) .
C43 H43 0.9500 .
C43 C44 1.378(4) .
C44 H44 0.9500 .
C44 C45 1.378(4) .
C45 H45 0.9500 .
C45 C46 1.390(3) .
C46 H46 0.9500 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
Eu1 O1 C2 C1 -169.83(11) 2_665
Eu1 O1 C2 C1 -3.2(2) .
Eu1 O1 C2 C3 175.76(13) .
Eu1 O1 C2 C3 9.1(2) 2_665
Eu1 O4 C23 C22 147.77(13) .
Eu1 O4 C23 C24 -32.2(3) .
Eu1 O5 C25 C24 29.1(3) .
Eu1 O5 C25 C26 -152.16(13) .
Eu1 O6 C38 C37 -167.44(13) .
Eu1 O6 C38 C39 11.6(3) .
Eu1 O7 C40 C39 -10.5(3) .
Eu1 O7 C40 C41 169.61(13) .
Eu1 N1 C1 C2 5.08(19) .
Eu1 N1 C1 C6 -175.45(12) .
Eu1 N1 C9 C8 175.48(13) .
Eu1 N1 C9 C10 -5.1(2) .
Eu1 N2 C10 C9 -4.3(2) .
Eu1 N2 C11 C12 -117.70(19) .
Eu1 N2 C11 C16 57.4(2) .
O1 C2 C3 C4 -178.35(18) .
O2 N3 C14 C13 -178.0(2) .
O2 N3 C14 C15 3.8(3) .
O3 N3 C14 C13 2.2(3) .
O3 N3 C14 C15 -176.0(2) .
O4 C23 C24 C25 -1.9(3) .
O5 C25 C26 C27 168.7(2) .
O5 C25 C26 C31 -10.9(3) .
O6 C38 C39 C40 4.0(3) .
O7 C40 C41 C42 -7.2(3) .
O7 C40 C41 C46 171.1(2) .
N1 C1 C2 O1 -1.4(2) .
N1 C1 C2 C3 179.54(15) .
N1 C1 C6 C5 179.55(16) .
N1 C1 C6 C7 -0.4(2) .
N1 C9 C10 N2 6.2(3) .
N2 C11 C12 C13 173.9(2) .
N2 C11 C16 C15 -174.3(2) .
N3 C14 C15 C16 176.6(2) .
C1 N1 C9 C8 -1.2(3) .
C1 N1 C9 C10 178.16(15) .
C1 C2 C3 C4 0.6(3) .
C1 C6 C7 C8 -1.0(3) .
C2 C1 C6 C5 -1.0(3) .
C2 C1 C6 C7 179.05(16) .
C2 C3 C4 C5 -0.4(3) .
C3 C4 C5 C6 -0.6(3) .
C4 C5 C6 C1 1.2(3) .
C4 C5 C6 C7 -178.8(2) .
C5 C6 C7 C8 179.08(18) .
C6 C1 C2 O1 179.09(15) .
C6 C1 C2 C3 0.1(2) .
C6 C7 C8 C9 1.2(3) .
C7 C8 C9 N1 -0.1(3) .
C7 C8 C9 C10 -179.51(18) .
C8 C9 C10 N2 -174.35(18) .
C9 N1 C1 C2 -177.98(16) .
C9 N1 C1 C6 1.5(2) .
C10 N2 C11 C12 50.8(3) .
C10 N2 C11 C16 -134.1(2) .
C11 N2 C10 C9 -173.50(17) .
C11 C12 C13 C14 0.1(3) .
C12 C11 C16 C15 0.9(3) .
C12 C13 C14 N3 -176.9(2) .
C12 C13 C14 C15 1.2(3) .
C13 C14 C15 C16 -1.5(3) .
C14 C15 C16 C11 0.5(3) .
C16 C11 C12 C13 -1.2(3) .
C17 C18 C19 C20 -0.4(4) .
C17 C22 C23 O4 -12.2(3) .
C17 C22 C23 C24 167.72(19) .
C18 C17 C22 C21 -1.7(3) .
C18 C17 C22 C23 -179.9(2) .
C18 C19 C20 C21 -0.9(4) .
C19 C20 C21 C22 0.9(4) .
C20 C21 C22 C17 0.4(3) .
C20 C21 C22 C23 178.5(2) .
C21 C22 C23 O4 169.65(19) .
C21 C22 C23 C24 -10.4(3) .
C22 C17 C18 C19 1.7(4) .
C22 C23 C24 C25 178.11(19) .
C23 C24 C25 O5 3.3(3) .
C23 C24 C25 C26 -175.48(19) .
C24 C25 C26 C27 -12.4(3) .
C24 C25 C26 C31 167.9(2) .
C25 C26 C27 C28 -179.8(2) .
C25 C26 C31 C30 -179.3(2) .
C26 C27 C28 C29 -0.3(4) .
C27 C26 C31 C30 1.0(3) .
C27 C28 C29 C30 0.0(4) .
C28 C29 C30 C31 0.9(4) .
C29 C30 C31 C26 -1.4(4) .
C31 C26 C27 C28 -0.2(4) .
C32 C33 C34 C35 2.8(4) .
C32 C37 C38 O6 2.3(3) .
C32 C37 C38 C39 -176.7(2) .
C33 C32 C37 C36 -2.0(4) .
C33 C32 C37 C38 176.0(2) .
C33 C34 C35 C36 -2.0(4) .
C34 C35 C36 C37 -0.9(4) .
C35 C36 C37 C32 2.8(4) .
C35 C36 C37 C38 -175.0(2) .
C36 C37 C38 O6 -179.9(2) .
C36 C37 C38 C39 1.1(3) .
C37 C32 C33 C34 -0.9(4) .
C37 C38 C39 C40 -177.08(19) .
C38 C39 C40 O7 -4.4(3) .
C38 C39 C40 C41 175.41(18) .
C39 C40 C41 C42 172.9(2) .
C39 C40 C41 C46 -8.7(3) .
C40 C41 C42 C43 178.8(2) .
C40 C41 C46 C45 -177.4(2) .
C41 C42 C43 C44 -1.3(4) .
C42 C41 C46 C45 1.0(4) .
C42 C43 C44 C45 0.8(4) .
C43 C44 C45 C46 0.6(5) .
C44 C45 C46 C41 -1.5(4) .
C46 C41 C42 C43 0.4(3) .
