#------------------------------------------------------------------------------
#$Date: 2019-11-07 22:39:31 +0200 (Thu, 07 Nov 2019) $
#$Revision: 223832 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/04/98/7049831.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7049831
loop_
_publ_author_name
'Afrin, Unjila'
'Iguchi, Hiroaki'
'Mian, Mohammad Rasel'
'Takaishi, Shinya'
'Yamakawa, Hiromichi'
'Terashige, Tsubasa'
'Miyamoto, Tatsuya'
'Okamoto, Hiroshi'
'Yamashita, Masahiro'
_publ_section_title
;
 MX-type single chain complexes with an aromatic in-plane ligand:
 incorporation of aromatic interactions for stabilizing the chain
 structure.
;
_journal_issue                   22
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              7828
_journal_page_last               7834
_journal_paper_doi               10.1039/c9dt00784a
_journal_volume                  48
_journal_year                    2019
_chemical_formula_moiety
'C24 H32 Br2 N8 Pt2 4+, C12 H16 Br2 N4 Pt 2+, 2(H O4 S 1-), 2(O4 S 2-), 13(H2 O)'
_chemical_formula_sum            'C36 H76 Br4 N12 O29 Pt3 S4'
_chemical_formula_weight         2174.23
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-2018/3
_audit_update_record
;
2019-04-19 deposited with the CCDC.    2019-04-24 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 108.8236(10)
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   11.1877(5)
_cell_length_b                   18.4105(7)
_cell_length_c                   16.9085(7)
_cell_measurement_reflns_used    9948
_cell_measurement_temperature    298(2)
_cell_measurement_theta_max      34.02
_cell_measurement_theta_min      2.22
_cell_volume                     3296.4(2)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Ortep for Windows (Farrugia, 2012)'
_computing_publication_material  'SHELXL-2018/3 (Sheldrick, 2018)'
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018)'
_computing_structure_solution    'SHELXT-2014/5 (Sheldrick, 2015)'
_diffrn_ambient_temperature      298(2)
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.927
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0391
_diffrn_reflns_av_unetI/netI     0.0537
_diffrn_reflns_Laue_measured_fraction_full 0.997
_diffrn_reflns_Laue_measured_fraction_max 0.927
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_h_min       -8
_diffrn_reflns_limit_k_max       28
_diffrn_reflns_limit_k_min       -29
_diffrn_reflns_limit_l_max       26
_diffrn_reflns_limit_l_min       -27
_diffrn_reflns_number            36384
_diffrn_reflns_point_group_measured_fraction_full 0.997
_diffrn_reflns_point_group_measured_fraction_max 0.927
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         34.879
_diffrn_reflns_theta_min         1.686
_diffrn_source                   'fine-focus sealed tube'
_exptl_absorpt_coefficient_mu    8.990
_exptl_absorpt_correction_T_max  0.533
_exptl_absorpt_correction_T_min  0.299
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS-2014/5
_exptl_crystal_colour            brown
_exptl_crystal_density_diffrn    2.191
_exptl_crystal_description       plate
_exptl_crystal_F_000             2092
_exptl_crystal_recrystallization_method
'Re-crystallisation from solvent: water'
_exptl_crystal_size_max          0.310
_exptl_crystal_size_mid          0.110
_exptl_crystal_size_min          0.080
_refine_diff_density_max         2.584
_refine_diff_density_min         -1.769
_refine_diff_density_rms         0.165
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.024
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     430
_refine_ls_number_reflns         13325
_refine_ls_number_restraints     10
_refine_ls_restrained_S_all      1.024
_refine_ls_R_factor_all          0.0967
_refine_ls_R_factor_gt           0.0435
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0336P)²+3.9335P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0765
_refine_ls_wR_factor_ref         0.0915
_reflns_Friedel_coverage         0.000
_reflns_number_gt                7876
_reflns_number_total             13325
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c9dt00784a2.cif
_cod_data_source_block           20180810ptampbrso4_0m
_cod_depositor_comments
'Adding full bibliography for 7049828--7049831.cif.'
_cod_database_code               7049831
_shelx_shelxl_version_number     2018/3
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.167
_shelx_estimated_absorpt_t_max   0.533
_exptl_absorpt_special_details
;
SADABS-2014/5 - Bruker AXS area detector scaling and absorption correction.
wR2(int) was 0.1254 before and 0.0432 after correction.
;
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
Pt1 Pt 0.000000 0.500000 0.500000 0.01795(4) Uani 1 2 d S . P
Br1 Br 0.21569(4) 0.47719(2) 0.49684(3) 0.02793(9) Uani 1 1 d . . .
Pt2 Pt 0.500000 0.500000 0.500000 0.04227(7) Uani 1 2 d S . P
Pt3 Pt 0.000000 0.500000 0.000000 0.02185(5) Uani 1 2 d S . P
Br2 Br 0.21466(5) 0.52983(3) 0.00201(3) 0.03430(10) Uani 1 1 d . . .
N1 N 0.0774(3) 0.53157(18) 0.62083(19) 0.0232(7) Uani 1 1 d . . .
C1 C 0.1200(4) 0.4853(2) 0.6862(3) 0.0315(10) Uani 1 1 d . . .
H1 H 0.112526 0.435462 0.676854 0.038 Uiso 1 1 calc R U .
C2 C 0.1741(5) 0.5111(3) 0.7662(3) 0.0397(12) Uani 1 1 d . . .
H2 H 0.203897 0.479141 0.810840 0.048 Uiso 1 1 calc R U .
C3 C 0.1835(5) 0.5849(3) 0.7791(3) 0.0437(12) Uani 1 1 d . . .
H3 H 0.218663 0.603157 0.832954 0.052 Uiso 1 1 calc R U .
C4 C 0.1416(5) 0.6312(3) 0.7137(3) 0.0408(12) Uani 1 1 d . . .
H4 H 0.149041 0.681065 0.722558 0.049 Uiso 1 1 calc R U .
C5 C 0.0875(4) 0.6041(2) 0.6335(3) 0.0282(9) Uani 1 1 d . . .
C6 C 0.0339(5) 0.6508(2) 0.5580(3) 0.0377(11) Uani 1 1 d . . .
H5 H -0.047119 0.669990 0.557450 0.045 Uiso 1 1 calc R U .
H6 H 0.090005 0.691563 0.560368 0.045 Uiso 1 1 calc R U .
N2 N 0.0175(3) 0.60885(17) 0.4803(2) 0.0255(7) Uani 1 1 d . . .
H2A H 0.083858 0.616103 0.463120 0.031 Uiso 1 1 calc R U .
H2B H -0.051055 0.624405 0.440423 0.031 Uiso 1 1 calc R U .
N3 N 0.4836(4) 0.5010(3) 0.3773(3) 0.0546(12) Uani 1 1 d . . .
C7 C 0.4623(6) 0.5622(4) 0.3309(4) 0.0675(19) Uani 1 1 d . . .
H7 H 0.450121 0.606496 0.353562 0.081 Uiso 1 1 calc R U .
C8 C 0.4590(9) 0.5571(6) 0.2485(5) 0.101(3) Uani 1 1 d . . .
H8 H 0.443635 0.598402 0.215070 0.121 Uiso 1 1 calc R U .
C9 C 0.4780(9) 0.4918(6) 0.2157(6) 0.100(3) Uani 1 1 d . . .
H9 H 0.476816 0.489276 0.160568 0.120 Uiso 1 1 calc R U .
C10 C 0.4981(7) 0.4323(6) 0.2621(5) 0.093(3) Uani 1 1 d . . .
H10 H 0.509027 0.387608 0.239762 0.112 Uiso 1 1 calc R U .
C11 C 0.5027(6) 0.4382(4) 0.3463(5) 0.0679(18) Uani 1 1 d . . .
C12 C 0.5232(8) 0.3736(4) 0.3993(5) 0.083(2) Uani 1 1 d . . .
H11 H 0.598581 0.348598 0.397511 0.099 Uiso 1 1 calc R U .
H12 H 0.452190 0.340784 0.378158 0.099 Uiso 1 1 calc R U .
N4 N 0.5379(5) 0.3937(3) 0.4889(3) 0.0623(14) Uani 1 1 d . . .
H4A H 0.616484 0.384083 0.521093 0.075 Uiso 1 1 calc R U .
H4B H 0.485746 0.366619 0.506696 0.075 Uiso 1 1 calc R U .
N5 N 0.0716(3) 0.46764(18) 0.1209(2) 0.0255(7) Uani 1 1 d . . .
C13 C 0.1053(4) 0.5140(2) 0.1870(3) 0.0313(10) Uani 1 1 d . . .
H13 H 0.094196 0.563684 0.177831 0.038 Uiso 1 1 calc R U .
C14 C 0.1557(5) 0.4882(2) 0.2670(3) 0.0331(10) Uani 1 1 d . . .
H14 H 0.178347 0.520164 0.312040 0.040 Uiso 1 1 calc R U .
C15 C 0.1722(5) 0.4147(3) 0.2800(3) 0.0373(11) Uani 1 1 d . . .
H15 H 0.205101 0.396517 0.334027 0.045 Uiso 1 1 calc R U .
C16 C 0.1399(5) 0.3682(3) 0.2129(3) 0.0371(11) Uani 1 1 d . . .
H16 H 0.152917 0.318492 0.221200 0.045 Uiso 1 1 calc R U .
C17 C 0.0881(4) 0.3955(2) 0.1331(3) 0.0286(9) Uani 1 1 d . . .
C18 C 0.0432(5) 0.3488(2) 0.0571(3) 0.0394(11) Uani 1 1 d . . .
H17 H 0.103144 0.309799 0.061014 0.047 Uiso 1 1 calc R U .
H18 H -0.037416 0.327299 0.053673 0.047 Uiso 1 1 calc R U .
N6 N 0.0293(4) 0.39237(18) -0.0196(2) 0.0264(7) Uani 1 1 d . . .
H6A H -0.035566 0.375499 -0.061429 0.032 Uiso 1 1 calc R U .
H6B H 0.098744 0.387862 -0.034042 0.032 Uiso 1 1 calc R U .
S1 S 0.20008(13) 0.30724(7) 0.85501(8) 0.0411(3) Uani 1 1 d . . .
O1 O 0.0604(4) 0.3267(4) 0.8135(3) 0.129(3) Uani 1 1 d . . .
H19 H 0.029427 0.299645 0.773583 0.194 Uiso 1 1 calc R U .
O2 O 0.2397(4) 0.3581(2) 0.9233(2) 0.0549(10) Uani 1 1 d . . .
O3 O 0.2076(7) 0.2349(3) 0.8827(3) 0.108(2) Uani 1 1 d . . .
O4 O 0.2617(5) 0.3179(3) 0.7941(3) 0.0848(16) Uani 1 1 d . . .
S2 S 0.18575(11) 0.70516(7) 0.36208(7) 0.0360(3) Uani 1 1 d . . .
O5 O 0.0479(4) 0.7127(3) 0.3259(3) 0.0915(18) Uani 1 1 d . . .
O6 O 0.2132(4) 0.6455(2) 0.4198(3) 0.0675(13) Uani 1 1 d . . .
O7 O 0.2446(4) 0.6945(3) 0.2989(3) 0.0835(16) Uani 1 1 d . . .
O8 O 0.2315(6) 0.7723(3) 0.4046(4) 0.115(2) Uani 1 1 d . . .
O9 O 0.4811(5) 0.4217(4) 0.9894(6) 0.118(3) Uani 1 1 d D . .
O10 O 0.4660(5) 0.6901(4) 0.8748(4) 0.126(3) Uani 1 1 d . . .
O11 O 0.1952(4) 0.3162(2) 0.6207(3) 0.0538(10) Uani 1 1 d D . .
O12 O 0.3751(4) 0.2952(2) 0.5389(3) 0.0662(12) Uani 1 1 d . . .
O13 O 0.1767(4) 0.6849(2) 0.1268(3) 0.0541(10) Uani 1 1 d D . .
O14 O 0.3852(5) 0.6938(3) 0.0671(4) 0.1013(18) Uani 1 1 d . . .
H20 H 0.486(8) 0.4513(11) 1.028(2) 0.17(6) Uiso 1 1 d D . .
H21 H 0.404(3) 0.417(5) 0.963(5) 0.12(3) Uiso 1 1 d D . .
H22 H 0.226(6) 0.317(4) 0.6728(12) 0.09(3) Uiso 1 1 d D . .
H23 H 0.262(4) 0.315(4) 0.608(4) 0.10(3) Uiso 1 1 d D . .
H24 H 0.247(3) 0.679(3) 0.120(3) 0.050(18) Uiso 1 1 d D . .
H25 H 0.193(5) 0.681(3) 0.1785(14) 0.057(19) Uiso 1 1 d D . .
O15 O 0.4771(11) 0.2450(6) 0.2756(8) 0.100(4) Uani 0.5 1 d . . P
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Br Br -0.2901 2.4595 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N1 Pt1 N1 180.0 . 3_566
N1 Pt1 N2 98.54(13) . 3_566
N1 Pt1 N2 81.46(13) 3_566 3_566
N1 Pt1 N2 81.45(13) . .
N1 Pt1 N2 98.54(13) 3_566 .
N2 Pt1 N2 180.00(19) 3_566 .
N1 Pt1 Br1 91.85(10) . 3_566
N1 Pt1 Br1 88.15(10) 3_566 3_566
N2 Pt1 Br1 90.99(10) 3_566 3_566
N2 Pt1 Br1 89.01(10) . 3_566
N1 Pt1 Br1 88.15(10) . .
N1 Pt1 Br1 91.85(10) 3_566 .
N2 Pt1 Br1 89.01(10) 3_566 .
N2 Pt1 Br1 90.99(10) . .
Br1 Pt1 Br1 180.0 3_566 .
N3 Pt2 N3 180.0 3_666 .
N3 Pt2 N4 97.7(2) 3_666 .
N3 Pt2 N4 82.3(2) . .
N3 Pt2 N4 82.3(2) 3_666 3_666
N3 Pt2 N4 97.7(2) . 3_666
N4 Pt2 N4 180.0 . 3_666
N5 Pt3 N5 180.0 . 3_565
N5 Pt3 N6 98.77(13) . 3_565
N5 Pt3 N6 81.23(13) 3_565 3_565
N5 Pt3 N6 81.23(13) . .
N5 Pt3 N6 98.77(13) 3_565 .
N6 Pt3 N6 180.0 3_565 .
N5 Pt3 Br2 90.84(10) . 3_565
N5 Pt3 Br2 89.16(10) 3_565 3_565
N6 Pt3 Br2 90.67(11) 3_565 3_565
N6 Pt3 Br2 89.33(11) . 3_565
N5 Pt3 Br2 89.16(10) . .
N5 Pt3 Br2 90.84(10) 3_565 .
N6 Pt3 Br2 89.33(11) 3_565 .
N6 Pt3 Br2 90.67(11) . .
Br2 Pt3 Br2 180.0 3_565 .
C5 N1 C1 120.2(3) . .
C5 N1 Pt1 115.4(3) . .
C1 N1 Pt1 124.4(3) . .
N1 C1 C2 120.8(4) . .
C3 C2 C1 119.0(4) . .
C4 C3 C2 120.2(4) . .
C3 C4 C5 120.0(4) . .
N1 C5 C4 119.8(4) . .
N1 C5 C6 116.3(3) . .
C4 C5 C6 123.8(4) . .
N2 C6 C5 110.9(3) . .
C6 N2 Pt1 110.9(3) . .
C11 N3 C7 121.6(6) . .
C11 N3 Pt2 115.3(4) . .
C7 N3 Pt2 123.0(5) . .
N3 C7 C8 118.1(8) . .
C9 C8 C7 120.6(8) . .
C10 C9 C8 120.4(9) . .
C9 C10 C11 118.5(10) . .
N3 C11 C10 120.7(7) . .
N3 C11 C12 119.0(7) . .
C10 C11 C12 120.2(8) . .
C11 C12 N4 111.0(6) . .
C12 N4 Pt2 111.7(4) . .
C17 N5 C13 120.3(3) . .
C17 N5 Pt3 115.7(3) . .
C13 N5 Pt3 124.0(3) . .
N5 C13 C14 120.7(4) . .
C13 C14 C15 119.3(4) . .
C14 C15 C16 119.7(4) . .
C15 C16 C17 119.8(4) . .
N5 C17 C16 120.1(4) . .
N5 C17 C18 116.4(3) . .
C16 C17 C18 123.4(4) . .
N6 C18 C17 110.6(4) . .
C18 N6 Pt3 110.9(3) . .
O3 S1 O4 112.3(4) . .
O3 S1 O2 112.3(3) . .
O4 S1 O2 113.2(3) . .
O3 S1 O1 108.4(4) . .
O4 S1 O1 107.2(3) . .
O2 S1 O1 102.7(3) . .
O6 S2 O7 110.6(3) . .
O6 S2 O8 110.7(4) . .
O7 S2 O8 108.3(4) . .
O6 S2 O5 108.7(3) . .
O7 S2 O5 112.0(3) . .
O8 S2 O5 106.4(4) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Pt1 N1 2.030(3) .
Pt1 N1 2.030(3) 3_566
Pt1 N2 2.051(3) 3_566
Pt1 N2 2.051(3) .
Pt1 Br1 2.4668(4) 3_566
Pt1 Br1 2.4668(4) .
Pt2 N3 2.024(5) 3_666
Pt2 N3 2.024(5) .
Pt2 N4 2.024(5) .
Pt2 N4 2.024(5) 3_666
Pt3 N5 2.029(3) .
Pt3 N5 2.029(3) 3_565
Pt3 N6 2.053(3) 3_565
Pt3 N6 2.053(3) .
Pt3 Br2 2.4531(5) 3_565
Pt3 Br2 2.4531(5) .
N1 C5 1.352(5) .
N1 C1 1.354(5) .
C1 C2 1.377(6) .
C2 C3 1.375(7) .
C3 C4 1.354(7) .
C4 C5 1.387(6) .
C5 C6 1.495(6) .
C6 N2 1.483(5) .
N3 C11 1.314(8) .
N3 C7 1.349(7) .
C7 C8 1.385(10) .
C8 C9 1.367(12) .
C9 C10 1.324(12) .
C10 C11 1.412(9) .
C11 C12 1.462(9) .
C12 N4 1.515(8) .
N5 C17 1.348(5) .
N5 C13 1.359(5) .
C13 C14 1.372(6) .
C14 C15 1.374(6) .
C15 C16 1.374(6) .
C16 C17 1.380(6) .
C17 C18 1.491(6) .
C18 N6 1.489(5) .
S1 O3 1.405(5) .
S1 O4 1.426(4) .
S1 O2 1.440(4) .
S1 O1 1.534(5) .
S2 O6 1.435(4) .
S2 O7 1.438(4) .
S2 O8 1.438(6) .
S2 O5 1.471(4) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
C5 N1 C1 C2 -0.1(7)
Pt1 N1 C1 C2 178.4(4)
N1 C1 C2 C3 0.6(8)
C1 C2 C3 C4 -1.0(8)
C2 C3 C4 C5 0.8(8)
C1 N1 C5 C4 0.0(6)
Pt1 N1 C5 C4 -178.7(3)
C1 N1 C5 C6 -178.0(4)
Pt1 N1 C5 C6 3.4(5)
C3 C4 C5 N1 -0.3(7)
C3 C4 C5 C6 177.4(5)
N1 C5 C6 N2 -18.6(6)
C4 C5 C6 N2 163.6(4)
C5 C6 N2 Pt1 24.4(5)
C11 N3 C7 C8 1.0(9)
Pt2 N3 C7 C8 176.9(5)
N3 C7 C8 C9 -0.6(12)
C7 C8 C9 C10 1.0(15)
C8 C9 C10 C11 -1.6(14)
C7 N3 C11 C10 -1.7(10)
Pt2 N3 C11 C10 -177.9(5)
C7 N3 C11 C12 -179.0(6)
Pt2 N3 C11 C12 4.8(8)
C9 C10 C11 N3 2.0(12)
C9 C10 C11 C12 179.3(8)
N3 C11 C12 N4 -8.5(9)
C10 C11 C12 N4 174.2(6)
C11 C12 N4 Pt2 7.9(7)
C17 N5 C13 C14 -0.5(7)
Pt3 N5 C13 C14 -178.6(3)
N5 C13 C14 C15 0.2(7)
C13 C14 C15 C16 0.9(8)
C14 C15 C16 C17 -1.7(8)
C13 N5 C17 C16 -0.2(7)
Pt3 N5 C17 C16 178.0(4)
C13 N5 C17 C18 177.5(4)
Pt3 N5 C17 C18 -4.3(5)
C15 C16 C17 N5 1.3(7)
C15 C16 C17 C18 -176.2(5)
N5 C17 C18 N6 19.5(6)
C16 C17 C18 N6 -162.9(4)
C17 C18 N6 Pt3 -24.9(5)
