#------------------------------------------------------------------------------
#$Date: 2016-02-16 03:10:39 +0200 (Tue, 16 Feb 2016) $
#$Revision: 176453 $
#$URL: svn://www.crystallography.net/cod/cif/7/05/00/7050088.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7050088
loop_
_publ_author_name
'Kennedy, Alan R.'
'Brown, Karen G.'
'Graham, Duncan'
'Kirkhouse, Jennifer B.'
'Kittner, Madeleine'
'Major, Claire'
'McHugh, Callum J.'
'Murdoch, Paul'
'Smith, W. Ewen'
_publ_section_title
;
 Chromophore containing bipyridyl ligands. Part 1: supramolecular
 solid-state structure of Ag(i) complexes
;
_journal_issue                   6
_journal_name_full               'New Journal of Chemistry'
_journal_page_first              826
_journal_paper_doi               10.1039/b500698h
_journal_volume                  29
_journal_year                    2005
_chemical_formula_sum            'C14 H16.5 Ag F6 N5 O1.75 Sb'
_chemical_formula_weight         626.44
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                97.956(13)
_cell_angle_beta                 110.611(9)
_cell_angle_gamma                92.935(13)
_cell_formula_units_Z            2
_cell_length_a                   10.4959(15)
_cell_length_b                   11.9036(16)
_cell_length_c                   8.6632(12)
_cell_measurement_reflns_used    25
_cell_measurement_temperature    123(2)
_cell_measurement_theta_max      18.62
_cell_measurement_theta_min      11.66
_cell_volume                     997.5(3)
_computing_cell_refinement       ' " '
_computing_data_collection
;
MSC/Rigaku diffractometer control software
;
_computing_data_reduction        texsan
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      123(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'Rigaku AFC7S Diffractometer'
_diffrn_measurement_method       omega/2theta
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71069
_diffrn_reflns_av_R_equivalents  0.0370
_diffrn_reflns_av_sigmaI/netI    0.0445
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       10
_diffrn_reflns_limit_l_min       -11
_diffrn_reflns_number            4841
_diffrn_reflns_theta_full        27.50
_diffrn_reflns_theta_max         27.50
_diffrn_reflns_theta_min         2.55
_diffrn_standards_decay_%        1.825
_diffrn_standards_interval_count 150
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    2.409
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  0.658
_exptl_absorpt_correction_type   psi-scan
_exptl_absorpt_process_details   'North et al'
_exptl_crystal_colour            'pale yellow'
_exptl_crystal_density_diffrn    2.086
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       fragment
_exptl_crystal_F_000             603
_exptl_crystal_size_max          0.35
_exptl_crystal_size_mid          0.25
_exptl_crystal_size_min          0.15
_refine_diff_density_max         0.633
_refine_diff_density_min         -1.017
_refine_diff_density_rms         0.116
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.037
_refine_ls_hydrogen_treatment    noref
_refine_ls_matrix_type           full
_refine_ls_number_parameters     285
_refine_ls_number_reflns         4589
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.037
_refine_ls_R_factor_all          0.0352
_refine_ls_R_factor_gt           0.0307
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0215P)²+1.6811P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0788
_refine_ls_wR_factor_ref         0.0804
_reflns_number_gt                4185
_reflns_number_total             4589
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b500698h.txt
_cod_data_source_block           agsb
_cod_depositor_comments
;
The following automatic conversions were performed:

'_refine_ls_weighting_scheme' value 'calc
w=1/[\s^2^(Fo^2^)+(0.0215P)^2^+1.6811P] where P=(Fo^2^+2Fc^2^)/3' was
changed to 'calc'. New tag '_refine_ls_weighting_details' was
created. The value of the new tag was set to
'w=1/[\s^2^(Fo^2^)+(0.0215P)^2^+1.6811P] where P=(Fo^2^+2Fc^2^)/3'.

Automatic conversion script
Id: cif_fix_values 3143 2015-03-26 13:38:13Z robertas 
;
_cod_original_cell_volume        997.5(2)
_cod_original_sg_symbol_H-M      P-1
_cod_original_formula_sum        'C14 H16.50 Ag F6 N5 O1.75 Sb'
_cod_database_code               7050088
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Sb1 Sb 1.44115(4) 0.78282(11) -0.31706(17) 0.02444(19) Uani 0.873(5) d P . .
Sb2 Sb 1.4366(3) 0.7572(4) -0.3591(6) 0.0186(7) Uiso 0.127(5) d P . .
Ag1 Ag 1.05609(3) 1.208291(19) -0.40913(3) 0.02468(8) Uani 1 d . . .
F1 F 1.4972(4) 0.6651(3) -0.4361(7) 0.0681(12) Uani 0.873(5) d P . .
F2 F 1.6106(3) 0.8012(4) -0.1419(4) 0.0556(10) Uani 0.873(5) d P . .
F3 F 1.3846(3) 0.9016(4) -0.2003(4) 0.0520(8) Uani 0.873(5) d P . .
F4 F 1.2682(2) 0.7659(2) -0.4919(3) 0.0466(6) Uani 1 d . . .
F5 F 1.3723(3) 0.6794(3) -0.2143(5) 0.0550(11) Uani 0.873(5) d P . .
F6 F 1.5058(3) 0.8891(2) -0.4178(3) 0.0444(6) Uani 1 d . . .
F7 F 1.3737(15) 0.6267(13) -0.2988(19) 0.021(3) Uiso 0.127(5) d P . .
F8 F 1.615(2) 0.7488(17) -0.218(3) 0.037(5) Uiso 0.127(5) d P . .
F9 F 1.467(2) 0.6697(19) -0.530(3) 0.040(5) Uiso 0.127(5) d P . .
F10 F 1.396(3) 0.850(2) -0.187(3) 0.047(6) Uiso 0.127(5) d P . .
N1 N 1.0083(3) 1.0598(2) -0.3120(3) 0.0209(5) Uani 1 d . . .
N2 N 1.0433(3) 0.7453(2) 0.0276(3) 0.0202(5) Uani 1 d . . .
N3 N 1.0039(3) 0.6619(2) 0.1085(3) 0.0217(5) Uani 1 d . . .
N4 N 1.0683(3) 0.3409(2) 0.4455(3) 0.0193(5) Uani 1 d . . .
N5 N 1.3184(4) 1.2023(4) -0.2917(6) 0.0544(11) Uani 1 d . . .
C1 C 0.8820(3) 1.0230(3) -0.3232(4) 0.0226(6) Uani 1 d . . .
H1 H 0.8071 1.0596 -0.3859 0.027 Uiso 1 calc R . .
C2 C 0.8557(3) 0.9339(3) -0.2473(4) 0.0223(6) Uani 1 d . . .
H2 H 0.7645 0.9100 -0.2590 0.027 Uiso 1 calc R . .
C3 C 0.9642(3) 0.8800(2) -0.1540(4) 0.0179(5) Uani 1 d . . .
C4 C 1.0949(3) 0.9158(3) -0.1467(4) 0.0224(6) Uani 1 d . . .
H4 H 1.1710 0.8788 -0.0880 0.027 Uiso 1 calc R . .
C5 C 1.1134(3) 1.0054(3) -0.2253(4) 0.0237(6) Uani 1 d . . .
H5 H 1.2033 1.0296 -0.2182 0.028 Uiso 1 calc R . .
C6 C 0.9400(3) 0.7900(2) -0.0640(4) 0.0199(6) Uani 1 d . . .
H6 H 0.8497 0.7653 -0.0733 0.024 Uiso 1 calc R . .
C7 C 1.1046(3) 0.6079(2) 0.1790(4) 0.0201(6) Uani 1 d . . .
H7 H 1.1914 0.6281 0.1733 0.024 Uiso 1 calc R . .
C8 C 1.0891(3) 0.5153(2) 0.2688(4) 0.0182(5) Uani 1 d . . .
C9 C 0.9620(3) 0.4698(2) 0.2625(4) 0.0188(5) Uani 1 d . . .
H9 H 0.8804 0.4977 0.1974 0.023 Uiso 1 calc R . .
C10 C 0.9562(3) 0.3833(2) 0.3524(4) 0.0202(6) Uani 1 d . . .
H10 H 0.8693 0.3528 0.3479 0.024 Uiso 1 calc R . .
C11 C 1.1907(3) 0.3834(2) 0.4504(4) 0.0216(6) Uani 1 d . . .
H11 H 1.2705 0.3534 0.5160 0.026 Uiso 1 calc R . .
C12 C 1.2052(3) 0.4697(3) 0.3630(4) 0.0224(6) Uani 1 d . . .
H12 H 1.2932 0.4972 0.3675 0.027 Uiso 1 calc R . .
C13 C 1.4270(4) 1.1800(4) -0.2466(5) 0.0373(8) Uani 1 d . . .
C14 C 1.5666(4) 1.1511(4) -0.1857(5) 0.0431(9) Uani 1 d . . .
H14A H 1.6291 1.2206 -0.1291 0.065 Uiso 1 calc R . .
H14B H 1.5896 1.1154 -0.2802 0.065 Uiso 1 calc R . .
H14C H 1.5755 1.0978 -0.1068 0.065 Uiso 1 calc R . .
O1S O 0.5533(7) 0.4554(5) 0.8515(9) 0.0437(10) Uiso 0.50 d P . .
O2S O 0.6059(8) 0.4811(7) 0.9286(10) 0.0437(10) Uiso 0.50 d P . .
O3S O 0.6312(11) 0.5369(10) 0.9761(13) 0.0437(10) Uiso 0.301(9) d P . .
O4S O 0.5439(12) 0.4881(10) 0.9705(15) 0.0437(10) Uiso 0.306(9) d P . .
O5S O 0.455(3) 0.467(2) 0.959(3) 0.0437(10) Uiso 0.141(8) d P . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Sb Sb -0.5866 1.5461 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
F10 Sb1 F8 109.4(11) . . ?
F10 Sb1 F6 106.7(10) . . ?
F8 Sb1 F6 89.6(6) . . ?
F10 Sb1 F2 83.6(10) . . ?
F8 Sb1 F2 26.8(6) . . ?
F6 Sb1 F2 90.31(13) . . ?
F10 Sb1 F1 161.9(10) . . ?
F8 Sb1 F1 64.0(7) . . ?
F6 Sb1 F1 90.42(16) . . ?
F2 Sb1 F1 90.77(19) . . ?
F10 Sb1 F3 18.8(9) . . ?
F8 Sb1 F3 116.4(7) . . ?
F6 Sb1 F3 88.96(14) . . ?
F2 Sb1 F3 89.64(17) . . ?
F1 Sb1 F3 179.27(19) . . ?
F10 Sb1 F5 71.6(10) . . ?
F8 Sb1 F5 91.8(6) . . ?
F6 Sb1 F5 178.10(14) . . ?
F2 Sb1 F5 90.38(13) . . ?
F1 Sb1 F5 91.34(19) . . ?
F3 Sb1 F5 89.27(17) . . ?
F10 Sb1 F4 95.4(10) . . ?
F8 Sb1 F4 154.2(6) . . ?
F6 Sb1 F4 89.91(11) . . ?
F2 Sb1 F4 178.96(15) . . ?
F1 Sb1 F4 90.25(17) . . ?
F3 Sb1 F4 89.35(14) . . ?
F5 Sb1 F4 89.37(12) . . ?
F10 Sb1 F7 97.6(10) . . ?
F8 Sb1 F7 88.4(8) . . ?
F6 Sb1 F7 154.8(4) . . ?
F2 Sb1 F7 99.0(4) . . ?
F1 Sb1 F7 66.2(5) . . ?
F3 Sb1 F7 114.3(4) . . ?
F5 Sb1 F7 26.6(4) . . ?
F4 Sb1 F7 81.2(4) . . ?
F10 Sb1 F9 169.2(11) . . ?
F8 Sb1 F9 79.5(8) . . ?
F6 Sb1 F9 78.9(6) . . ?
F2 Sb1 F9 105.9(6) . . ?
F1 Sb1 F9 19.1(5) . . ?
F3 Sb1 F9 160.2(6) . . ?
F5 Sb1 F9 102.6(6) . . ?
F4 Sb1 F9 75.2(6) . . ?
F7 Sb1 F9 76.1(7) . . ?
F1 Sb2 F4 110.0(3) . . ?
F1 Sb2 F9 24.4(7) . . ?
F4 Sb2 F9 90.0(7) . . ?
F1 Sb2 F8 70.3(6) . . ?
F4 Sb2 F8 179.7(7) . . ?
F9 Sb2 F8 90.3(9) . . ?
F1 Sb2 F7 77.3(5) . . ?
F4 Sb2 F7 88.8(5) . . ?
F9 Sb2 F7 90.3(8) . . ?
F8 Sb2 F7 91.3(8) . . ?
F1 Sb2 F6 101.8(2) . . ?
F4 Sb2 F6 92.79(17) . . ?
F9 Sb2 F6 89.3(7) . . ?
F8 Sb2 F6 87.1(6) . . ?
F7 Sb2 F6 178.4(5) . . ?
F1 Sb2 F10 157.9(8) . . ?
F4 Sb2 F10 87.2(8) . . ?
F9 Sb2 F10 177.2(10) . . ?
F8 Sb2 F10 92.5(10) . . ?
F7 Sb2 F10 89.7(9) . . ?
F6 Sb2 F10 90.8(7) . . ?
F1 Sb2 F5 101.8(3) . . ?
F4 Sb2 F5 91.45(17) . . ?
F9 Sb2 F5 117.5(8) . . ?
F8 Sb2 F5 88.5(6) . . ?
F7 Sb2 F5 27.3(4) . . ?
F6 Sb2 F5 152.9(3) . . ?
F10 Sb2 F5 62.7(8) . . ?
F1 Sb2 F2 94.4(2) . . ?
F4 Sb2 F2 155.5(3) . . ?
F9 Sb2 F2 113.9(7) . . ?
F8 Sb2 F2 24.1(6) . . ?
F7 Sb2 F2 96.0(5) . . ?
F6 Sb2 F2 82.78(18) . . ?
F10 Sb2 F2 68.9(8) . . ?
F5 Sb2 F2 82.35(18) . . ?
F1 Sb2 F3 168.8(3) . . ?
F4 Sb2 F3 81.2(2) . . ?
F9 Sb2 F3 163.4(7) . . ?
F8 Sb2 F3 98.4(6) . . ?
F7 Sb2 F3 103.5(5) . . ?
F6 Sb2 F3 77.17(19) . . ?
F10 Sb2 F3 15.2(7) . . ?
F5 Sb2 F3 77.1(2) . . ?
F2 Sb2 F3 74.4(2) . . ?
N1 Ag1 N4 167.86(10) . 1_564 ?
N1 Ag1 N5 95.42(11) . . ?
N4 Ag1 N5 93.31(11) 1_564 . ?
C1 N1 C5 117.8(3) . . ?
C1 N1 Ag1 124.1(2) . . ?
C5 N1 Ag1 117.9(2) . . ?
C6 N2 N3 112.2(3) . . ?
C7 N3 N2 110.9(3) . . ?
C10 N4 C11 118.5(3) . . ?
C10 N4 Ag1 121.7(2) . 1_546 ?
C11 N4 Ag1 119.8(2) . 1_546 ?
C13 N5 Ag1 168.2(4) . . ?
N1 C1 C2 123.0(3) . . ?
N1 C1 H1 118.5 . . ?
C2 C1 H1 118.5 . . ?
C1 C2 C3 119.3(3) . . ?
C1 C2 H2 120.4 . . ?
C3 C2 H2 120.4 . . ?
C2 C3 C4 117.8(3) . . ?
C2 C3 C6 120.3(3) . . ?
C4 C3 C6 121.9(3) . . ?
C5 C4 C3 119.6(3) . . ?
C5 C4 H4 120.2 . . ?
C3 C4 H4 120.2 . . ?
N1 C5 C4 122.4(3) . . ?
N1 C5 H5 118.8 . . ?
C4 C5 H5 118.8 . . ?
N2 C6 C3 118.9(3) . . ?
N2 C6 H6 120.6 . . ?
C3 C6 H6 120.6 . . ?
N3 C7 C8 121.3(3) . . ?
N3 C7 H7 119.3 . . ?
C8 C7 H7 119.3 . . ?
C12 C8 C9 118.2(3) . . ?
C12 C8 C7 119.2(3) . . ?
C9 C8 C7 122.6(3) . . ?
C10 C9 C8 119.1(3) . . ?
C10 C9 H9 120.5 . . ?
C8 C9 H9 120.5 . . ?
N4 C10 C9 122.7(3) . . ?
N4 C10 H10 118.7 . . ?
C9 C10 H10 118.7 . . ?
N4 C11 C12 122.4(3) . . ?
N4 C11 H11 118.8 . . ?
C12 C11 H11 118.8 . . ?
C11 C12 C8 119.1(3) . . ?
C11 C12 H12 120.4 . . ?
C8 C12 H12 120.4 . . ?
N5 C13 C14 179.0(4) . . ?
C13 C14 H14A 109.5 . . ?
C13 C14 H14B 109.5 . . ?
H14A C14 H14B 109.5 . . ?
C13 C14 H14C 109.5 . . ?
H14A C14 H14C 109.5 . . ?
H14B C14 H14C 109.5 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Sb1 F10 1.52(3) . ?
Sb1 F8 1.81(2) . ?
Sb1 F6 1.859(2) . ?
Sb1 F2 1.866(3) . ?
Sb1 F1 1.866(3) . ?
Sb1 F3 1.868(3) . ?
Sb1 F5 1.870(3) . ?
Sb1 F4 1.890(2) . ?
Sb1 F7 2.001(15) . ?
Sb1 F9 2.23(2) . ?
Sb2 F1 1.490(6) . ?
Sb2 F4 1.754(4) . ?
Sb2 F9 1.82(2) . ?
Sb2 F8 1.86(2) . ?
Sb2 F7 1.867(15) . ?
Sb2 F6 1.901(4) . ?
Sb2 F10 1.91(2) . ?
Sb2 F5 1.934(4) . ?
Sb2 F2 2.088(5) . ?
Sb2 F3 2.261(6) . ?
Ag1 N1 2.168(3) . ?
Ag1 N4 2.177(2) 1_564 ?
Ag1 N5 2.586(4) . ?
N1 C1 1.341(4) . ?
N1 C5 1.351(4) . ?
N2 C6 1.288(4) . ?
N2 N3 1.415(3) . ?
N3 C7 1.275(4) . ?
N4 C10 1.339(4) . ?
N4 C11 1.341(4) . ?
N4 Ag1 2.177(2) 1_546 ?
N5 C13 1.126(5) . ?
C1 C2 1.387(4) . ?
C1 H1 0.9500 . ?
C2 C3 1.390(4) . ?
C2 H2 0.9500 . ?
C3 C4 1.393(4) . ?
C3 C6 1.471(4) . ?
C4 C5 1.384(4) . ?
C4 H4 0.9500 . ?
C5 H5 0.9500 . ?
C6 H6 0.9500 . ?
C7 C8 1.469(4) . ?
C7 H7 0.9500 . ?
C8 C12 1.391(4) . ?
C8 C9 1.394(4) . ?
C9 C10 1.385(4) . ?
C9 H9 0.9500 . ?
C10 H10 0.9500 . ?
C11 C12 1.390(4) . ?
C11 H11 0.9500 . ?
C12 H12 0.9500 . ?
C13 C14 1.449(5) . ?
C14 H14A 0.9800 . ?
C14 H14B 0.9800 . ?
C14 H14C 0.9800 . ?
O1S O2S 0.715(8) . ?
O1S O4S 1.091(14) . ?
O1S O3S 1.335(12) . ?
O1S O5S 1.61(3) . ?
O1S O5S 1.81(3) 2_667 ?
O2S O3S 0.714(10) . ?
O2S O4S 0.852(12) . ?
O2S O5S 1.44(3) 2_667 ?
O2S O5S 1.70(3) . ?
O3S O4S 1.042(15) . ?
O3S O5S 1.23(3) 2_667 ?
O4S O5S 0.75(2) 2_667 ?
O4S O5S 0.92(2) . ?
O4S O4S 1.23(3) 2_667 ?
O5S O4S 0.75(2) 2_667 ?
O5S O5S 1.15(5) 2_667 ?
O5S O3S 1.23(3) 2_667 ?
O5S O2S 1.44(3) 2_667 ?
O5S O1S 1.81(3) 2_667 ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N4 Ag1 N1 C1 -49.2(6) 1_564 . . . ?
N5 Ag1 N1 C1 175.0(3) . . . . ?
N4 Ag1 N1 C5 135.3(4) 1_564 . . . ?
N5 Ag1 N1 C5 -0.6(3) . . . . ?
C6 N2 N3 C7 170.9(3) . . . . ?
N1 Ag1 N5 C13 35.7(18) . . . . ?
N4 Ag1 N5 C13 -135.9(18) 1_564 . . . ?
C5 N1 C1 C2 1.4(5) . . . . ?
Ag1 N1 C1 C2 -174.2(2) . . . . ?
N1 C1 C2 C3 0.5(5) . . . . ?
C1 C2 C3 C4 -2.5(4) . . . . ?
C1 C2 C3 C6 176.3(3) . . . . ?
C2 C3 C4 C5 2.6(4) . . . . ?
C6 C3 C4 C5 -176.1(3) . . . . ?
C1 N1 C5 C4 -1.2(5) . . . . ?
Ag1 N1 C5 C4 174.6(2) . . . . ?
C3 C4 C5 N1 -0.8(5) . . . . ?
N3 N2 C6 C3 178.8(2) . . . . ?
C2 C3 C6 N2 -176.8(3) . . . . ?
C4 C3 C6 N2 1.9(4) . . . . ?
N2 N3 C7 C8 -178.8(2) . . . . ?
N3 C7 C8 C12 -171.2(3) . . . . ?
N3 C7 C8 C9 9.5(4) . . . . ?
C12 C8 C9 C10 1.4(4) . . . . ?
C7 C8 C9 C10 -179.3(3) . . . . ?
C11 N4 C10 C9 -0.6(4) . . . . ?
Ag1 N4 C10 C9 178.2(2) 1_546 . . . ?
C8 C9 C10 N4 -0.2(4) . . . . ?
C10 N4 C11 C12 0.2(4) . . . . ?
Ag1 N4 C11 C12 -178.7(2) 1_546 . . . ?
N4 C11 C12 C8 1.0(5) . . . . ?
C9 C8 C12 C11 -1.8(4) . . . . ?
C7 C8 C12 C11 178.8(3) . . . . ?
Ag1 N5 C13 C14 -84(28) . . . . ?
