#------------------------------------------------------------------------------
#$Date: 2016-03-26 00:12:50 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180065 $
#$URL: svn://www.crystallography.net/cod/cif/7/05/11/7051163.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7051163
loop_
_publ_author_name
'Marek Necas'
'Mark R. St J. Foreman'
'Jaromír Marek'
'J. Derek Woollins'
'Josef Novosad'
_publ_section_title
;
 New mixed-donor unsymmetrical P--N--P ligands and their palladium(II)
 complexes
;
_journal_issue                   10
_journal_name_full               'New J. Chem.'
_journal_page_first              1256
_journal_page_last               1263
_journal_paper_doi               10.1039/b103501k
_journal_volume                  25
_journal_year                    2001
_chemical_formula_moiety         '[iPr2P(S)-N-P(O)(OPh)2]2Pd'
_chemical_formula_sum            'C36 H48 N2 O6 P4 Pd S2'
_chemical_formula_weight         899.16
_chemical_name_systematic
; 
? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                110.77(3)
_cell_angle_beta                 91.19(3)
_cell_angle_gamma                106.59(3)
_cell_formula_units_Z            2
_cell_length_a                   11.605(2)
_cell_length_b                   12.181(2)
_cell_length_c                   15.930(3)
_cell_measurement_temperature    130(2)
_cell_volume                     1999.1(9)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.947
_diffrn_measured_fraction_theta_max 0.947
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0564
_diffrn_reflns_av_sigmaI/netI    0.1221
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       0
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            7026
_diffrn_reflns_theta_full        25.05
_diffrn_reflns_theta_max         25.05
_diffrn_reflns_theta_min         3.64
_exptl_absorpt_coefficient_mu    0.775
_exptl_crystal_density_diffrn    1.494
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             928
_exptl_crystal_size_max          0.25
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.15
_refine_diff_density_max         0.751
_refine_diff_density_min         -1.226
_refine_diff_density_rms         0.118
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.982
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     463
_refine_ls_number_reflns         6705
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.982
_refine_ls_R_factor_all          0.1212
_refine_ls_R_factor_gt           0.0422
_refine_ls_shift/su_max          0.007
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0633P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1030
_refine_ls_wR_factor_ref         0.1220
_reflns_number_gt                3988
_reflns_number_total             6705
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b103501k.txt
_cod_data_source_block           12.cif
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 

The following automatic conversions were performed:

'_refine_ls_weighting_scheme' value 'calc
w=1/[\s^2^(Fo^2^)+(0.0633P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3' was
changed to 'calc'. New tag '_refine_ls_weighting_details' was
created. The value of the new tag was set to
'w=1/[\s^2^(Fo^2^)+(0.0633P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'.

Automatic conversion script
Id: cif_fix_values 3143 2015-03-26 13:38:13Z robertas 
;
_cod_original_cell_volume        1999.1(6)
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7051163
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pd1 Pd 0.5000 0.5000 0.5000 0.01501(15) Uani 1 d S . .
P2 P 0.21776(12) 0.32172(12) 0.46173(9) 0.0182(3) Uani 1 d . . .
S1 S 0.52613(11) 0.30793(11) 0.41628(9) 0.0212(3) Uani 1 d . . .
P1 P 0.31249(11) 0.57857(12) 0.59026(8) 0.0167(3) Uani 1 d . . .
O1 O 0.0951(3) 0.3157(3) 0.4831(2) 0.0244(8) Uani 1 d . . .
O2 O 0.2596(3) 0.2095(3) 0.4645(2) 0.0196(8) Uani 1 d . . .
N1 N 0.3233(4) 0.4467(4) 0.5216(3) 0.0167(9) Uani 1 d . . .
O3 O 0.2379(3) 0.3089(3) 0.3611(2) 0.0219(8) Uani 1 d . . .
C7 C 0.1867(4) 0.2043(4) 0.2833(3) 0.0174(11) Uani 1 d . . .
C2 C 0.3662(5) 0.1978(5) 0.5890(4) 0.0296(13) Uani 1 d . . .
C17 C 0.1809(6) 0.6115(6) 0.4607(4) 0.0336(14) Uani 1 d . . .
C1 C 0.2579(5) 0.1820(5) 0.5431(3) 0.0205(11) Uani 1 d . . .
C13 C 0.3029(5) 0.5808(5) 0.7044(3) 0.0227(12) Uani 1 d . . .
C11 C 0.2069(5) 0.0891(5) 0.1312(4) 0.0281(13) Uani 1 d . . .
C12 C 0.2570(5) 0.1882(5) 0.2138(3) 0.0235(12) Uani 1 d . . .
C8 C 0.0726(5) 0.1238(5) 0.2743(4) 0.0274(13) Uani 1 d . . .
C16 C 0.1851(5) 0.6191(5) 0.5574(3) 0.0210(11) Uani 1 d . . .
C14 C 0.4050(5) 0.5422(5) 0.7335(4) 0.0272(12) Uani 1 d . . .
C5 C 0.1502(6) 0.1042(6) 0.6446(5) 0.0443(17) Uani 1 d . . .
C3 C 0.3646(6) 0.1642(6) 0.6632(4) 0.0354(14) Uani 1 d . . .
C10 C 0.0941(5) 0.0094(5) 0.1210(3) 0.0263(13) Uani 1 d . . .
C18 C 0.1899(6) 0.7482(6) 0.6238(4) 0.0401(16) Uani 1 d . . .
C9 C 0.0271(5) 0.0250(5) 0.1930(4) 0.0313(14) Uani 1 d . . .
C6 C 0.1491(5) 0.1336(5) 0.5686(4) 0.0297(13) Uani 1 d . . .
C4 C 0.2573(6) 0.1180(6) 0.6913(4) 0.0423(16) Uani 1 d . . .
C15 C 0.1798(5) 0.5010(6) 0.7138(4) 0.0388(16) Uani 1 d . . .
Pd2 Pd 0.0000 0.5000 0.0000 0.01377(14) Uani 1 d S . .
P4 P 0.20142(11) 0.44496(12) 0.05606(8) 0.0151(3) Uani 1 d . . .
S2 S 0.04629(11) 0.31825(11) -0.01816(9) 0.0188(3) Uani 1 d . . .
P3 P 0.27558(11) 0.69742(12) 0.05903(9) 0.0162(3) Uani 1 d . . .
O6 O 0.2467(3) 0.6964(3) -0.0391(2) 0.0204(8) Uani 1 d . . .
O5 O 0.2288(3) 0.8084(3) 0.1170(2) 0.0200(8) Uani 1 d . . .
N2 N 0.1784(3) 0.5713(4) 0.0563(3) 0.0158(9) Uani 1 d . . .
C34 C 0.3316(4) 0.4132(5) 0.0035(3) 0.0183(11) Uani 1 d . . .
C24 C 0.1331(5) 0.7847(5) 0.2451(4) 0.0237(12) Uani 1 d . . .
C19 C 0.2339(5) 0.8381(5) 0.2115(3) 0.0196(11) Uani 1 d . . .
C26 C 0.4173(5) 0.8268(5) -0.0787(4) 0.0241(12) Uani 1 d . . .
C25 C 0.2974(5) 0.7952(4) -0.0671(3) 0.0171(11) Uani 1 d . . .
C29 C 0.2648(5) 0.9427(6) -0.1206(4) 0.0301(13) Uani 1 d . . .
C36 C 0.3252(5) 0.4133(6) -0.0907(4) 0.0321(14) Uani 1 d . . .
C28 C 0.3855(5) 0.9780(5) -0.1323(4) 0.0312(13) Uani 1 d . . .
C21 C 0.3406(6) 0.9504(6) 0.3602(4) 0.0380(15) Uani 1 d . . .
C23 C 0.1386(5) 0.8140(5) 0.3367(4) 0.0300(13) Uani 1 d . . .
C31 C 0.2175(5) 0.4454(5) 0.1691(3) 0.0229(12) Uani 1 d . . .
C35 C 0.3421(6) 0.2924(6) 0.0040(4) 0.0369(15) Uani 1 d . . .
C22 C 0.2406(6) 0.8949(5) 0.3946(4) 0.0305(13) Uani 1 d . . .
C33 C 0.1000(5) 0.4502(5) 0.2123(4) 0.0260(12) Uani 1 d . . .
C32 C 0.3268(5) 0.5491(6) 0.2300(4) 0.0312(14) Uani 1 d . . .
C30 C 0.2205(5) 0.8498(5) -0.0879(4) 0.0266(12) Uani 1 d . . .
C27 C 0.4612(5) 0.9192(5) -0.1120(4) 0.0291(13) Uani 1 d . . .
C20 C 0.3375(5) 0.9209(5) 0.2682(4) 0.0315(14) Uani 1 d . . .
O4 O 0.4014(3) 0.7142(3) 0.0870(2) 0.0204(8) Uani 1 d . . .
H15B H 0.1594 0.4239 0.6847 0.050 Uiso 1 d . . .
H35C H 0.2773 0.2376 -0.0163 0.050 Uiso 1 d . . .
H9 H -0.0570 -0.0420 0.1857 0.050 Uiso 1 d . . .
H35B H 0.3605 0.3053 0.0554 0.050 Uiso 1 d . . .
H26 H 0.4678 0.7785 -0.0571 0.050 Uiso 1 d . . .
H15A H 0.1417 0.5355 0.7154 0.050 Uiso 1 d . . .
H17B H 0.1824 0.5335 0.4182 0.050 Uiso 1 d . . .
H34 H 0.3918 0.4800 0.0307 0.050 Uiso 1 d . . .
H36B H 0.2540 0.3529 -0.1254 0.050 Uiso 1 d . . .
H36A H 0.3252 0.4759 -0.0949 0.050 Uiso 1 d . . .
H31 H 0.1984 0.3700 0.1593 0.050 Uiso 1 d . . .
H17A H 0.2411 0.6656 0.4619 0.050 Uiso 1 d . . .
H24 H 0.0712 0.7403 0.2025 0.050 Uiso 1 d . . .
H6 H 0.0936 0.1359 0.5414 0.050 Uiso 1 d . . .
H27 H 0.5542 0.9598 -0.1154 0.050 Uiso 1 d . . .
H35A H 0.4129 0.2680 -0.0352 0.050 Uiso 1 d . . .
H18A H 0.2369 0.7979 0.6208 0.050 Uiso 1 d . . .
H33C H 0.0257 0.3832 0.1755 0.050 Uiso 1 d . . .
H33B H 0.1005 0.5411 0.2288 0.050 Uiso 1 d . . .
H8 H 0.0255 0.1285 0.3253 0.050 Uiso 1 d . . .
H32B H 0.3392 0.5411 0.2965 0.050 Uiso 1 d . . .
H12 H 0.3327 0.2552 0.2324 0.050 Uiso 1 d . . .
H28 H 0.4271 1.0405 -0.1531 0.050 Uiso 1 d . . .
H32A H 0.3078 0.6369 0.2486 0.050 Uiso 1 d . . .
H33A H 0.1068 0.4391 0.2733 0.050 Uiso 1 d . . .
H3 H 0.4373 0.1873 0.7002 0.050 Uiso 1 d . . .
H15C H 0.1832 0.4950 0.7745 0.050 Uiso 1 d . . .
H36C H 0.3838 0.3827 -0.1244 0.050 Uiso 1 d . . .
H22 H 0.2429 0.9045 0.4686 0.050 Uiso 1 d . . .
H21 H 0.4206 1.0162 0.4025 0.050 Uiso 1 d . . .
H30 H 0.1343 0.8332 -0.0811 0.050 Uiso 1 d . . .
H4 H 0.2680 0.1133 0.7543 0.050 Uiso 1 d . . .
H20 H 0.3816 0.9653 0.2441 0.050 Uiso 1 d . . .
H10 H 0.0664 -0.0758 0.0531 0.050 Uiso 1 d . . .
H23 H 0.0457 0.7625 0.3530 0.050 Uiso 1 d . . .
H2 H 0.4362 0.2337 0.5608 0.050 Uiso 1 d . . .
H18C H 0.1216 0.7866 0.5900 0.050 Uiso 1 d . . .
H17C H 0.1120 0.6401 0.4438 0.050 Uiso 1 d . . .
H29 H 0.1867 0.9585 -0.1503 0.050 Uiso 1 d . . .
H13 H 0.3026 0.6582 0.7350 0.050 Uiso 1 d . . .
H14C H 0.4803 0.5907 0.7317 0.050 Uiso 1 d . . .
H14B H 0.4186 0.5615 0.7965 0.050 Uiso 1 d . . .
H14A H 0.3983 0.4565 0.7082 0.050 Uiso 1 d . . .
H16 H 0.1110 0.5584 0.5598 0.050 Uiso 1 d . . .
H5 H 0.0787 0.0810 0.6706 0.050 Uiso 1 d . . .
H32C H 0.3935 0.5632 0.1989 0.050 Uiso 1 d . . .
H18B H 0.2429 0.7965 0.7024 0.050 Uiso 1 d . . .
H11 H 0.2597 0.0846 0.0843 0.050 Uiso 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pd Pd -0.9988 1.0072 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 Pd1 N1 180.0 2_666 . ?
N1 Pd1 S1 101.46(12) 2_666 2_666 ?
N1 Pd1 S1 78.54(12) . 2_666 ?
N1 Pd1 S1 78.54(12) 2_666 . ?
N1 Pd1 S1 101.46(12) . . ?
S1 Pd1 S1 180.0 2_666 . ?
N1 Pd1 P1 34.43(11) 2_666 2_666 ?
N1 Pd1 P1 145.57(11) . 2_666 ?
S1 Pd1 P1 135.56(5) 2_666 2_666 ?
S1 Pd1 P1 44.44(5) . 2_666 ?
N1 Pd1 P1 145.57(11) 2_666 . ?
N1 Pd1 P1 34.43(11) . . ?
S1 Pd1 P1 44.44(5) 2_666 . ?
S1 Pd1 P1 135.56(5) . . ?
P1 Pd1 P1 180.0 2_666 . ?
O1 P2 O3 115.6(2) . . ?
O1 P2 O2 114.4(2) . . ?
O3 P2 O2 98.92(19) . . ?
O1 P2 N1 115.9(2) . . ?
O3 P2 N1 103.0(2) . . ?
O2 P2 N1 107.0(2) . . ?
P1 S1 Pd1 80.59(6) 2_666 . ?
N1 P1 C16 114.8(2) . . ?
N1 P1 C13 110.9(2) . . ?
C16 P1 C13 107.8(2) . . ?
N1 P1 S1 99.49(16) . 2_666 ?
C16 P1 S1 112.93(19) . 2_666 ?
C13 P1 S1 110.70(19) . 2_666 ?
N1 P1 Pd1 45.00(14) . . ?
C16 P1 Pd1 134.41(17) . . ?
C13 P1 Pd1 117.56(18) . . ?
S1 P1 Pd1 54.96(5) 2_666 . ?
C1 O2 P2 120.7(3) . . ?
P2 N1 P1 129.5(3) . . ?
P2 N1 Pd1 127.3(2) . . ?
P1 N1 Pd1 100.6(2) . . ?
C7 O3 P2 126.2(3) . . ?
C8 C7 C12 121.8(5) . . ?
C8 C7 O3 122.8(4) . . ?
C12 C7 O3 115.4(4) . . ?
C1 C2 C3 118.6(5) . . ?
C6 C1 C2 121.9(5) . . ?
C6 C1 O2 119.6(5) . . ?
C2 C1 O2 118.4(5) . . ?
C14 C13 C15 111.2(5) . . ?
C14 C13 P1 109.8(4) . . ?
C15 C13 P1 112.7(4) . . ?
C10 C11 C12 120.9(5) . . ?
C7 C12 C11 118.0(5) . . ?
C7 C8 C9 118.8(5) . . ?
C17 C16 C18 111.7(5) . . ?
C17 C16 P1 111.6(4) . . ?
C18 C16 P1 109.7(4) . . ?
C4 C5 C6 120.9(6) . . ?
C4 C3 C2 120.8(6) . . ?
C11 C10 C9 119.9(5) . . ?
C8 C9 C10 120.6(5) . . ?
C1 C6 C5 118.3(6) . . ?
C3 C4 C5 119.4(6) . . ?
N2 Pd2 N2 180.0 2_565 . ?
N2 Pd2 S2 79.16(12) 2_565 2_565 ?
N2 Pd2 S2 100.84(12) . 2_565 ?
N2 Pd2 S2 100.84(12) 2_565 . ?
N2 Pd2 S2 79.16(12) . . ?
S2 Pd2 S2 180.0 2_565 . ?
N2 Pd2 P4 34.88(11) 2_565 2_565 ?
N2 Pd2 P4 145.12(11) . 2_565 ?
S2 Pd2 P4 44.73(5) 2_565 2_565 ?
S2 Pd2 P4 135.27(5) . 2_565 ?
N2 Pd2 P4 145.12(11) 2_565 . ?
N2 Pd2 P4 34.88(11) . . ?
S2 Pd2 P4 135.27(5) 2_565 . ?
S2 Pd2 P4 44.73(5) . . ?
P4 Pd2 P4 180.0 2_565 . ?
N2 P4 C31 111.7(2) . . ?
N2 P4 C34 114.8(2) . . ?
C31 P4 C34 108.0(2) . . ?
N2 P4 S2 100.25(15) . . ?
C31 P4 S2 111.46(18) . . ?
C34 P4 S2 110.52(17) . . ?
N2 P4 Pd2 45.78(14) . . ?
C31 P4 Pd2 118.29(17) . . ?
C34 P4 Pd2 133.62(17) . . ?
S2 P4 Pd2 55.11(5) . . ?
P4 S2 Pd2 80.16(6) . . ?
O4 P3 O6 115.6(2) . . ?
O4 P3 O5 114.0(2) . . ?
O6 P3 O5 99.32(19) . . ?
O4 P3 N2 115.7(2) . . ?
O6 P3 N2 103.0(2) . . ?
O5 P3 N2 107.3(2) . . ?
C25 O6 P3 125.1(3) . . ?
C19 O5 P3 118.0(3) . . ?
P3 N2 P4 129.1(2) . . ?
P3 N2 Pd2 127.2(2) . . ?
P4 N2 Pd2 99.35(19) . . ?
C36 C34 C35 111.5(5) . . ?
C36 C34 P4 111.0(4) . . ?
C35 C34 P4 110.5(4) . . ?
C23 C24 C19 118.6(5) . . ?
C20 C19 C24 121.5(5) . . ?
C20 C19 O5 119.6(5) . . ?
C24 C19 O5 118.9(5) . . ?
C25 C26 C27 118.3(5) . . ?
C30 C25 C26 122.6(5) . . ?
C30 C25 O6 116.8(5) . . ?
C26 C25 O6 120.4(4) . . ?
C28 C29 C30 120.2(5) . . ?
C27 C28 C29 119.5(5) . . ?
C20 C21 C22 120.0(5) . . ?
C22 C23 C24 121.3(5) . . ?
C32 C31 C33 110.8(4) . . ?
C32 C31 P4 112.8(4) . . ?
C33 C31 P4 110.8(4) . . ?
C23 C22 C21 119.6(5) . . ?
C25 C30 C29 118.9(5) . . ?
C28 C27 C26 120.5(5) . . ?
C21 C20 C19 119.0(5) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pd1 N1 2.042(4) 2_666 ?
Pd1 N1 2.042(4) . ?
Pd1 S1 2.3565(14) 2_666 ?
Pd1 S1 2.3565(14) . ?
Pd1 P1 2.8393(14) 2_666 ?
Pd1 P1 2.8393(14) . ?
P2 O1 1.458(4) . ?
P2 O3 1.583(3) . ?
P2 O2 1.590(4) . ?
P2 N1 1.608(4) . ?
S1 P1 2.0153(19) 2_666 ?
P1 N1 1.633(4) . ?
P1 C16 1.809(5) . ?
P1 C13 1.815(5) . ?
P1 S1 2.0153(19) 2_666 ?
O2 C1 1.406(6) . ?
O3 C7 1.390(6) . ?
C7 C8 1.373(7) . ?
C7 C12 1.380(7) . ?
C2 C1 1.369(8) . ?
C2 C3 1.380(8) . ?
C17 C16 1.509(8) . ?
C1 C6 1.368(7) . ?
C13 C14 1.513(7) . ?
C13 C15 1.525(7) . ?
C11 C10 1.355(8) . ?
C11 C12 1.402(7) . ?
C8 C9 1.381(8) . ?
C16 C18 1.537(7) . ?
C5 C4 1.371(10) . ?
C5 C6 1.380(8) . ?
C3 C4 1.367(9) . ?
C10 C9 1.387(7) . ?
Pd2 N2 2.047(4) 2_565 ?
Pd2 N2 2.047(4) . ?
Pd2 S2 2.3463(13) 2_565 ?
Pd2 S2 2.3463(13) . ?
Pd2 P4 2.8184(14) 2_565 ?
Pd2 P4 2.8184(14) . ?
P4 N2 1.633(4) . ?
P4 C31 1.805(5) . ?
P4 C34 1.813(5) . ?
P4 S2 2.013(2) . ?
P3 O4 1.453(4) . ?
P3 O6 1.587(4) . ?
P3 O5 1.590(3) . ?
P3 N2 1.611(4) . ?
O6 C25 1.408(6) . ?
O5 C19 1.414(6) . ?
C34 C36 1.501(8) . ?
C34 C35 1.514(8) . ?
C24 C23 1.369(8) . ?
C24 C19 1.384(7) . ?
C19 C20 1.376(8) . ?
C26 C25 1.368(7) . ?
C26 C27 1.384(8) . ?
C25 C30 1.354(7) . ?
C29 C28 1.381(8) . ?
C29 C30 1.383(8) . ?
C28 C27 1.379(8) . ?
C21 C20 1.376(8) . ?
C21 C22 1.394(8) . ?
C23 C22 1.366(8) . ?
C31 C32 1.520(8) . ?
C31 C33 1.547(7) . ?
