#------------------------------------------------------------------------------
#$Date: 2016-02-16 03:10:39 +0200 (Tue, 16 Feb 2016) $
#$Revision: 176453 $
#$URL: svn://www.crystallography.net/cod/cif/7/05/15/7051553.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7051553
loop_
_publ_author_name
'Berenguer, Jesús R.'
'Chaouche, Naima'
'Forniés, Juan'
'Fortuño, Consuelo'
'Martín, Antonio'
_publ_section_title
;
 Coordination of a monomeric diphosphido platinum complex as a bridging
 ligand
;
_journal_issue                   3
_journal_name_full               'New Journal of Chemistry'
_journal_page_first              473
_journal_paper_doi               10.1039/b517726j
_journal_volume                  30
_journal_year                    2006
_chemical_formula_sum            'C73.5 H53 Au2 Cl3 F10 P4 Pt'
_chemical_formula_weight         1945.41
_chemical_name_systematic
;
?
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 110.9598(8)
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   30.4401(14)
_cell_length_b                   21.4415(10)
_cell_length_c                   22.4453(11)
_cell_measurement_temperature    100(2)
_cell_volume                     13680.3(11)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0331
_diffrn_reflns_av_sigmaI/netI    0.0530
_diffrn_reflns_limit_h_max       36
_diffrn_reflns_limit_h_min       -35
_diffrn_reflns_limit_k_max       25
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       26
_diffrn_reflns_limit_l_min       -26
_diffrn_reflns_number            74456
_diffrn_reflns_theta_full        25.02
_diffrn_reflns_theta_max         25.02
_diffrn_reflns_theta_min         1.69
_exptl_absorpt_coefficient_mu    6.600
_exptl_absorpt_correction_T_max  0.3669
_exptl_absorpt_correction_T_min  0.1828
_exptl_absorpt_correction_type   none
_exptl_crystal_density_diffrn    1.889
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             7448
_exptl_crystal_size_max          0.39
_exptl_crystal_size_mid          0.32
_exptl_crystal_size_min          0.19
_refine_diff_density_max         3.575
_refine_diff_density_min         -2.835
_refine_diff_density_rms         0.122
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.018
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           fullcycle
_refine_ls_number_parameters     1690
_refine_ls_number_reflns         24104
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.018
_refine_ls_R_factor_all          0.0502
_refine_ls_R_factor_gt           0.0320
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0170P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0578
_refine_ls_wR_factor_ref         0.0603
_reflns_number_gt                17343
_reflns_number_total             24104
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b517726j.txt
_cod_data_source_block           1
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_sg_symbol_H-M      P2(1)/c
_cod_original_formula_sum        'C73.50 H53 Au2 Cl3 F10 P4 Pt'
_cod_database_code               7051553
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.508305(8) 0.679960(11) 0.254158(11) 0.02126(6) Uani 1 1 d . . .
Au1 Au 0.377641(8) 0.649402(12) 0.192343(11) 0.02530(6) Uani 1 1 d . . .
Au2 Au 0.396885(8) 0.763768(12) 0.280460(12) 0.02888(7) Uani 1 1 d . . .
P1 P 0.43924(5) 0.69529(7) 0.16975(7) 0.0209(4) Uani 1 1 d . . .
P2 P 0.47238(5) 0.72091(8) 0.31992(8) 0.0264(4) Uani 1 1 d . . .
P3 P 0.32513(6) 0.58033(8) 0.20898(8) 0.0301(4) Uani 1 1 d . . .
P4 P 0.32700(5) 0.81582(8) 0.26321(8) 0.0287(4) Uani 1 1 d . . .
F1 F 0.58661(11) 0.72552(14) 0.19546(15) 0.0310(9) Uani 1 1 d . . .
F2 F 0.62762(11) 0.66677(16) 0.12396(15) 0.0349(9) Uani 1 1 d . . .
F3 F 0.60648(13) 0.54574(17) 0.08968(16) 0.0458(11) Uani 1 1 d . . .
F4 F 0.54194(14) 0.48527(16) 0.12630(18) 0.0503(11) Uani 1 1 d . . .
F5 F 0.49901(12) 0.54282(15) 0.19564(16) 0.0355(9) Uani 1 1 d . . .
F6 F 0.59340(11) 0.77353(15) 0.32505(15) 0.0313(9) Uani 1 1 d . . .
F7 F 0.67867(11) 0.75564(16) 0.41389(16) 0.0406(10) Uani 1 1 d . . .
F8 F 0.70761(11) 0.64070(17) 0.46067(16) 0.0426(10) Uani 1 1 d . . .
F9 F 0.64543(12) 0.54367(16) 0.42695(17) 0.0448(10) Uani 1 1 d . . .
F10 F 0.55836(12) 0.56109(15) 0.34163(16) 0.0372(9) Uani 1 1 d . . .
C1 C 0.5405(2) 0.6369(3) 0.1986(3) 0.0230(14) Uani 1 1 d . . .
C2 C 0.5737(2) 0.6653(3) 0.1788(3) 0.0229(14) Uani 1 1 d . . .
C3 C 0.59527(19) 0.6364(3) 0.1420(3) 0.0242(15) Uani 1 1 d . . .
C4 C 0.5845(2) 0.5757(3) 0.1241(3) 0.0313(17) Uani 1 1 d . . .
C5 C 0.5520(2) 0.5456(3) 0.1419(3) 0.0317(16) Uani 1 1 d . . .
C6 C 0.5314(2) 0.5765(3) 0.1788(3) 0.0251(15) Uani 1 1 d . . .
C7 C 0.5713(2) 0.6675(3) 0.3279(3) 0.0216(14) Uani 1 1 d . . .
C8 C 0.6043(2) 0.7145(3) 0.3492(3) 0.0259(15) Uani 1 1 d . . .
C9 C 0.6489(2) 0.7067(3) 0.3942(3) 0.0283(16) Uani 1 1 d . . .
C10 C 0.6630(2) 0.6492(3) 0.4191(3) 0.0303(16) Uani 1 1 d . . .
C11 C 0.6315(2) 0.6007(3) 0.4017(3) 0.0312(16) Uani 1 1 d . . .
C12 C 0.5876(2) 0.6108(3) 0.3570(3) 0.0277(16) Uani 1 1 d . . .
C13 C 0.43992(19) 0.6606(3) 0.0954(3) 0.0214(14) Uani 1 1 d . . .
C14 C 0.46496(19) 0.6893(3) 0.0618(3) 0.0236(14) Uani 1 1 d . . .
H14 H 0.4784 0.7294 0.0745 0.028 Uiso 1 1 calc R . .
C15 C 0.4705(2) 0.6600(3) 0.0100(3) 0.0278(16) Uani 1 1 d . . .
H15 H 0.4875 0.6800 -0.0128 0.033 Uiso 1 1 calc R . .
C16 C 0.4514(2) 0.6020(3) -0.0084(3) 0.0314(16) Uani 1 1 d . . .
H16 H 0.4556 0.5818 -0.0436 0.038 Uiso 1 1 calc R . .
C17 C 0.4263(2) 0.5731(3) 0.0236(3) 0.0310(16) Uani 1 1 d . . .
H17 H 0.4131 0.5330 0.0107 0.037 Uiso 1 1 calc R . .
C18 C 0.4202(2) 0.6028(3) 0.0749(3) 0.0255(15) Uani 1 1 d . . .
H18 H 0.4022 0.5830 0.0964 0.031 Uiso 1 1 calc R . .
C19 C 0.4293(2) 0.7782(3) 0.1487(3) 0.0232(14) Uani 1 1 d . . .
C20 C 0.3860(2) 0.7993(3) 0.1071(3) 0.0315(16) Uani 1 1 d . . .
H20 H 0.3603 0.7711 0.0916 0.038 Uiso 1 1 calc R . .
C21 C 0.3801(2) 0.8614(3) 0.0882(3) 0.0383(18) Uani 1 1 d . . .
H21 H 0.3506 0.8754 0.0593 0.046 Uiso 1 1 calc R . .
C22 C 0.4166(3) 0.9026(3) 0.1107(3) 0.0416(19) Uani 1 1 d . . .
H22 H 0.4122 0.9450 0.0979 0.050 Uiso 1 1 calc R . .
C23 C 0.4602(3) 0.8824(3) 0.1525(3) 0.0388(18) Uani 1 1 d . . .
H23 H 0.4857 0.9108 0.1678 0.047 Uiso 1 1 calc R . .
C24 C 0.4661(2) 0.8211(3) 0.1715(3) 0.0331(16) Uani 1 1 d . . .
H24 H 0.4957 0.8077 0.2006 0.040 Uiso 1 1 calc R . .
C25 C 0.5100(2) 0.7772(3) 0.3769(3) 0.0264(16) Uani 1 1 d . . .
C26 C 0.5066(2) 0.8399(3) 0.3641(3) 0.0296(16) Uani 1 1 d . . .
H26 H 0.4824 0.8549 0.3269 0.035 Uiso 1 1 calc R . .
C27 C 0.5378(2) 0.8815(3) 0.4045(3) 0.0353(17) Uani 1 1 d . . .
H27 H 0.5350 0.9248 0.3950 0.042 Uiso 1 1 calc R . .
C28 C 0.5726(2) 0.8605(3) 0.4580(3) 0.0354(18) Uani 1 1 d . . .
H28 H 0.5942 0.8893 0.4854 0.042 Uiso 1 1 calc R . .
C29 C 0.5768(2) 0.7991(3) 0.4723(3) 0.0319(17) Uani 1 1 d . . .
H29 H 0.6011 0.7852 0.5100 0.038 Uiso 1 1 calc R . .
C30 C 0.5461(2) 0.7561(3) 0.4327(3) 0.0306(16) Uani 1 1 d . . .
H30 H 0.5492 0.7129 0.4430 0.037 Uiso 1 1 calc R . .
C31 C 0.4618(2) 0.6601(3) 0.3696(3) 0.0338(17) Uani 1 1 d . . .
C32 C 0.4513(2) 0.6747(3) 0.4240(3) 0.0408(19) Uani 1 1 d . . .
H32 H 0.4540 0.7166 0.4387 0.049 Uiso 1 1 calc R . .
C33 C 0.4373(3) 0.6289(4) 0.4563(4) 0.063(3) Uani 1 1 d . . .
H33 H 0.4302 0.6390 0.4931 0.075 Uiso 1 1 calc R . .
C34 C 0.4334(3) 0.5673(4) 0.4345(4) 0.065(3) Uani 1 1 d . . .
H34 H 0.4235 0.5357 0.4565 0.078 Uiso 1 1 calc R . .
C35 C 0.4440(3) 0.5519(4) 0.3813(4) 0.059(2) Uani 1 1 d . . .
H35 H 0.4413 0.5099 0.3669 0.071 Uiso 1 1 calc R . .
C36 C 0.4583(2) 0.5978(3) 0.3490(3) 0.0414(19) Uani 1 1 d . . .
H36 H 0.4659 0.5872 0.3127 0.050 Uiso 1 1 calc R . .
C37 C 0.3524(2) 0.5047(3) 0.2329(3) 0.0303(16) Uani 1 1 d . . .
C38 C 0.3414(2) 0.4661(3) 0.2740(3) 0.0374(18) Uani 1 1 d . . .
H38 H 0.3196 0.4793 0.2929 0.045 Uiso 1 1 calc R . .
C39 C 0.3622(2) 0.4074(3) 0.2883(3) 0.0385(18) Uani 1 1 d . . .
H39 H 0.3544 0.3808 0.3169 0.046 Uiso 1 1 calc R . .
C40 C 0.3938(2) 0.3876(3) 0.2613(3) 0.0433(19) Uani 1 1 d . . .
H40 H 0.4069 0.3470 0.2702 0.052 Uiso 1 1 calc R . .
C41 C 0.4065(3) 0.4265(3) 0.2214(3) 0.045(2) Uani 1 1 d . . .
H41 H 0.4290 0.4134 0.2035 0.054 Uiso 1 1 calc R . .
C42 C 0.3862(2) 0.4842(3) 0.2080(3) 0.0416(19) Uani 1 1 d . . .
H42 H 0.3953 0.5113 0.1810 0.050 Uiso 1 1 calc R . .
C43 C 0.2761(2) 0.5655(3) 0.1359(3) 0.0335(17) Uani 1 1 d . . .
C44 C 0.2561(2) 0.6150(4) 0.0954(3) 0.048(2) Uani 1 1 d . . .
H44 H 0.2684 0.6558 0.1069 0.057 Uiso 1 1 calc R . .
C45 C 0.2189(3) 0.6063(4) 0.0392(4) 0.061(2) Uani 1 1 d . . .
H45 H 0.2054 0.6408 0.0123 0.073 Uiso 1 1 calc R . .
C46 C 0.2010(3) 0.5464(4) 0.0219(4) 0.056(2) Uani 1 1 d . . .
H46 H 0.1754 0.5399 -0.0170 0.067 Uiso 1 1 calc R . .
C47 C 0.2206(2) 0.4966(4) 0.0613(4) 0.048(2) Uani 1 1 d . . .
H47 H 0.2083 0.4559 0.0495 0.057 Uiso 1 1 calc R . .
C48 C 0.2582(2) 0.5055(3) 0.1180(3) 0.0393(18) Uani 1 1 d . . .
H48 H 0.2717 0.4709 0.1447 0.047 Uiso 1 1 calc R . .
C49 C 0.2999(2) 0.6005(3) 0.2685(3) 0.0324(17) Uani 1 1 d . . .
C50 C 0.2544(2) 0.5847(3) 0.2622(3) 0.0425(19) Uani 1 1 d . . .
H50 H 0.2351 0.5626 0.2255 0.051 Uiso 1 1 calc R . .
C51 C 0.2367(2) 0.6009(4) 0.3093(4) 0.054(2) Uani 1 1 d . . .
H51 H 0.2052 0.5909 0.3040 0.064 Uiso 1 1 calc R . .
C52 C 0.2650(3) 0.6314(4) 0.3638(4) 0.060(2) Uani 1 1 d . . .
H52 H 0.2531 0.6421 0.3962 0.072 Uiso 1 1 calc R . .
C53 C 0.3102(2) 0.6461(4) 0.3708(3) 0.055(2) Uani 1 1 d . . .
H53 H 0.3300 0.6662 0.4085 0.066 Uiso 1 1 calc R . .
C54 C 0.3272(2) 0.6317(3) 0.3229(3) 0.043(2) Uani 1 1 d . . .
H54 H 0.3584 0.6436 0.3276 0.052 Uiso 1 1 calc R . .
C55 C 0.3126(2) 0.8156(3) 0.3353(3) 0.0292(16) Uani 1 1 d . . .
C56 C 0.2671(2) 0.8284(3) 0.3350(3) 0.0350(17) Uani 1 1 d . . .
H56 H 0.2421 0.8368 0.2960 0.042 Uiso 1 1 calc R . .
C57 C 0.2590(2) 0.8285(3) 0.3918(3) 0.0407(19) Uani 1 1 d . . .
H57 H 0.2283 0.8367 0.3918 0.049 Uiso 1 1 calc R . .
C58 C 0.2950(2) 0.8171(3) 0.4480(3) 0.0427(19) Uani 1 1 d . . .
H58 H 0.2891 0.8173 0.4867 0.051 Uiso 1 1 calc R . .
C59 C 0.3395(2) 0.8051(3) 0.4493(3) 0.0434(19) Uani 1 1 d . . .
H59 H 0.3643 0.7973 0.4887 0.052 Uiso 1 1 calc R . .
C60 C 0.3481(2) 0.8045(3) 0.3928(3) 0.0408(19) Uani 1 1 d . . .
H60 H 0.3790 0.7964 0.3937 0.049 Uiso 1 1 calc R . .
C61 C 0.3344(2) 0.8974(3) 0.2466(3) 0.0304(16) Uani 1 1 d . . .
C62 C 0.3740(2) 0.9172(3) 0.2353(3) 0.0359(18) Uani 1 1 d . . .
H62 H 0.3972 0.8874 0.2358 0.043 Uiso 1 1 calc R . .
C63 C 0.3806(2) 0.9783(3) 0.2235(3) 0.0409(19) Uani 1 1 d . . .
H63 H 0.4080 0.9906 0.2155 0.049 Uiso 1 1 calc R . .
C64 C 0.3471(2) 1.0223(3) 0.2231(3) 0.0377(18) Uani 1 1 d . . .
H64 H 0.3514 1.0652 0.2160 0.045 Uiso 1 1 calc R . .
C65 C 0.3078(3) 1.0024(3) 0.2333(4) 0.055(2) Uani 1 1 d . . .
H65 H 0.2844 1.0321 0.2325 0.066 Uiso 1 1 calc R . .
C66 C 0.3011(2) 0.9415(3) 0.2446(4) 0.049(2) Uani 1 1 d . . .
H66 H 0.2731 0.9293 0.2511 0.059 Uiso 1 1 calc R . .
C67 C 0.2739(2) 0.7916(3) 0.1996(3) 0.0318(16) Uani 1 1 d . . .
C68 C 0.2634(3) 0.8185(4) 0.1393(3) 0.053(2) Uani 1 1 d . . .
H68 H 0.2841 0.8482 0.1319 0.064 Uiso 1 1 calc R . .
C69 C 0.2224(3) 0.8012(4) 0.0906(4) 0.078(3) Uani 1 1 d . . .
H69 H 0.2147 0.8196 0.0496 0.093 Uiso 1 1 calc R . .
C70 C 0.1925(3) 0.7574(4) 0.1008(4) 0.079(3) Uani 1 1 d . . .
H70 H 0.1643 0.7462 0.0671 0.095 Uiso 1 1 calc R . .
C71 C 0.2036(3) 0.7303(4) 0.1593(4) 0.060(2) Uani 1 1 d . . .
H71 H 0.1833 0.6999 0.1661 0.072 Uiso 1 1 calc R . .
C72 C 0.2441(2) 0.7468(3) 0.2086(3) 0.0424(19) Uani 1 1 d . . .
H72 H 0.2517 0.7274 0.2490 0.051 Uiso 1 1 calc R . .
Pt2 Pt 0.014993(8) 0.316654(11) -0.215219(11) 0.01795(6) Uani 1 1 d . . .
Au3 Au 0.123692(8) 0.234156(11) -0.250707(11) 0.02224(6) Uani 1 1 d . . .
Au4 Au 0.144372(8) 0.350901(11) -0.159238(11) 0.02172(6) Uani 1 1 d . . .
P5 P 0.04971(5) 0.28112(7) -0.28480(7) 0.0210(4) Uani 1 1 d . . .
P6 P 0.08562(5) 0.30270(7) -0.13294(7) 0.0194(4) Uani 1 1 d . . .
P7 P 0.18496(5) 0.16845(7) -0.24471(8) 0.0227(4) Uani 1 1 d . . .
P8 P 0.19635(6) 0.41591(8) -0.18230(8) 0.0237(4) Uani 1 1 d . . .
F11 F -0.04187(12) 0.42876(15) -0.31172(15) 0.0333(9) Uani 1 1 d . . .
F12 F -0.12772(13) 0.43133(18) -0.40369(17) 0.0554(12) Uani 1 1 d . . .
F13 F -0.18282(12) 0.3277(2) -0.43122(17) 0.0598(13) Uani 1 1 d . . .
F14 F -0.15051(12) 0.22037(18) -0.36528(17) 0.0528(11) Uani 1 1 d . . .
F15 F -0.06541(11) 0.21629(15) -0.27332(16) 0.0341(9) Uani 1 1 d . . .
F16 F -0.06531(12) 0.27164(15) -0.15832(15) 0.0353(9) Uani 1 1 d . . .
F17 F -0.10339(12) 0.32945(17) -0.08297(15) 0.0398(10) Uani 1 1 d . . .
F18 F -0.07476(12) 0.44539(16) -0.03763(15) 0.0379(10) Uani 1 1 d . . .
F19 F -0.00682(12) 0.50385(15) -0.06939(15) 0.0353(9) Uani 1 1 d . . .
F20 F 0.02984(11) 0.44913(14) -0.14825(15) 0.0279(8) Uani 1 1 d . . .
C73 C -0.04961(19) 0.3222(3) -0.2879(3) 0.0200(14) Uani 1 1 d . . .
C74 C -0.0683(2) 0.3752(3) -0.3232(3) 0.0273(15) Uani 1 1 d . . .
C75 C -0.1125(2) 0.3779(3) -0.3712(3) 0.0389(18) Uani 1 1 d . . .
C76 C -0.1397(2) 0.3259(4) -0.3845(3) 0.0397(19) Uani 1 1 d . . .
C77 C -0.1238(2) 0.2722(3) -0.3512(3) 0.0346(17) Uani 1 1 d . . .
C78 C -0.0797(2) 0.2711(3) -0.3037(3) 0.0253(15) Uani 1 1 d . . .
C79 C -0.01552(18) 0.3573(3) -0.1565(2) 0.0179(13) Uani 1 1 d . . .
C80 C -0.04951(19) 0.3298(3) -0.1378(3) 0.0216(14) Uani 1 1 d . . .
C81 C -0.06937(19) 0.3583(3) -0.0984(3) 0.0252(15) Uani 1 1 d . . .
C82 C -0.0548(2) 0.4168(3) -0.0747(3) 0.0260(15) Uani 1 1 d . . .
C83 C -0.0211(2) 0.4465(3) -0.0913(3) 0.0241(15) Uani 1 1 d . . .
C84 C -0.00299(19) 0.4163(3) -0.1321(3) 0.0227(14) Uani 1 1 d . . .
C85 C 0.0116(2) 0.2232(3) -0.3400(3) 0.0320(17) Uani 1 1 d . . .
C86 C -0.0254(2) 0.2424(4) -0.3945(3) 0.0412(19) Uani 1 1 d . . .
H86 H -0.0290 0.2851 -0.4067 0.049 Uiso 1 1 calc R . .
C87 C -0.0571(3) 0.1975(5) -0.4308(4) 0.066(3) Uani 1 1 d . . .
H87 H -0.0820 0.2096 -0.4686 0.079 Uiso 1 1 calc R . .
C88 C -0.0524(3) 0.1363(5) -0.4124(5) 0.079(4) Uani 1 1 d . . .
H88 H -0.0746 0.1065 -0.4369 0.095 Uiso 1 1 calc R . .
C89 C -0.0168(3) 0.1181(4) -0.3600(4) 0.064(3) Uani 1 1 d . . .
H89 H -0.0138 0.0754 -0.3481 0.077 Uiso 1 1 calc R . .
C90 C 0.0160(2) 0.1612(3) -0.3227(3) 0.0425(19) Uani 1 1 d . . .
H90 H 0.0412 0.1478 -0.2857 0.051 Uiso 1 1 calc R . .
C91 C 0.05655(19) 0.3433(3) -0.3362(3) 0.0223(14) Uani 1 1 d . . .
C92 C 0.0660(2) 0.3299(3) -0.3915(3) 0.0366(18) Uani 1 1 d . . .
H92 H 0.0664 0.2877 -0.4041 0.044 Uiso 1 1 calc R . .
C93 C 0.0748(2) 0.3767(4) -0.4282(3) 0.045(2) Uani 1 1 d . . .
H93 H 0.0805 0.3666 -0.4659 0.054 Uiso 1 1 calc R . .
C94 C 0.0752(2) 0.4375(4) -0.4100(4) 0.052(2) Uani 1 1 d . . .
H94 H 0.0821 0.4696 -0.4345 0.062 Uiso 1 1 calc R . .
C95 C 0.0657(2) 0.4524(3) -0.3557(3) 0.0429(19) Uani 1 1 d . . .
H95 H 0.0653 0.4948 -0.3436 0.051 Uiso 1 1 calc R . .
C96 C 0.05680(19) 0.4049(3) -0.3190(3) 0.0295(16) Uani 1 1 d . . .
H96 H 0.0508 0.4153 -0.2815 0.035 Uiso 1 1 calc R . .
C97 C 0.08596(19) 0.3337(3) -0.0566(3) 0.0204(14) Uani 1 1 d . . .
C98 C 0.05872(19) 0.3057(3) -0.0252(3) 0.0212(14) Uani 1 1 d . . .
H98 H 0.0433 0.2672 -0.0404 0.025 Uiso 1 1 calc R . .
C99 C 0.0542(2) 0.3335(3) 0.0275(3) 0.0246(15) Uani 1 1 d . . .
H99 H 0.0353 0.3143 0.0481 0.030 Uiso 1 1 calc R . .
C100 C 0.0768(2) 0.3891(3) 0.0508(3) 0.0258(15) Uani 1 1 d . . .
H100 H 0.0733 0.4081 0.0871 0.031 Uiso 1 1 calc R . .
C101 C 0.1043(2) 0.4166(3) 0.0213(3) 0.0277(15) Uani 1 1 d . . .
H101 H 0.1203 0.4544 0.0377 0.033 Uiso 1 1 calc R . .
C102 C 0.10871(19) 0.3896(3) -0.0325(3) 0.0244(15) Uani 1 1 d . . .
H102 H 0.1274 0.4094 -0.0530 0.029 Uiso 1 1 calc R . .
C103 C 0.0983(2) 0.2200(3) -0.1133(3) 0.0274(15) Uani 1 1 d . . .
C104 C 0.0629(2) 0.1759(3) -0.1297(3) 0.0369(17) Uani 1 1 d . . .
H104 H 0.0316 0.1879 -0.1545 0.044 Uiso 1 1 calc R . .
C105 C 0.0721(3) 0.1145(3) -0.1104(3) 0.046(2) Uani 1 1 d . . .
H105 H 0.0474 0.0846 -0.1221 0.055 Uiso 1 1 calc R . .
C106 C 0.1169(3) 0.0970(4) -0.0746(4) 0.057(2) Uani 1 1 d . . .
H106 H 0.1231 0.0551 -0.0605 0.068 Uiso 1 1 calc R . .
C107 C 0.1531(3) 0.1397(4) -0.0587(3) 0.057(2) Uani 1 1 d . . .
H107 H 0.1843 0.1270 -0.0344 0.068 Uiso 1 1 calc R . .
C108 C 0.1439(2) 0.2008(3) -0.0780(3) 0.0382(18) Uani 1 1 d . . .
H108 H 0.1689 0.2302 -0.0672 0.046 Uiso 1 1 calc R . .
C109 C 0.16117(19) 0.0908(3) -0.2565(3) 0.0227(14) Uani 1 1 d . . .
C110 C 0.1339(2) 0.0724(3) -0.2216(3) 0.0303(16) Uani 1 1 d . . .
H110 H 0.1299 0.1003 -0.1912 0.036 Uiso 1 1 calc R . .
C111 C 0.1126(2) 0.0151(3) -0.2297(3) 0.0352(17) Uani 1 1 d . . .
H111 H 0.0942 0.0037 -0.2050 0.042 Uiso 1 1 calc R . .
C112 C 0.1180(2) -0.0260(3) -0.2740(3) 0.0313(16) Uani 1 1 d . . .
H112 H 0.1036 -0.0660 -0.2796 0.038 Uiso 1 1 calc R . .
C113 C 0.1439(2) -0.0088(3) -0.3095(3) 0.0283(15) Uani 1 1 d . . .
H113 H 0.1471 -0.0367 -0.3406 0.034 Uiso 1 1 calc R . .
C114 C 0.1659(2) 0.0489(3) -0.3011(3) 0.0259(15) Uani 1 1 d . . .
H114 H 0.1842 0.0599 -0.3260 0.031 Uiso 1 1 calc R . .
C115 C 0.20545(19) 0.1796(3) -0.3102(3) 0.0208(14) Uani 1 1 d . . .
C116 C 0.2498(2) 0.1612(3) -0.3069(3) 0.0291(16) Uani 1 1 d . . .
H116 H 0.2719 0.1456 -0.2681 0.035 Uiso 1 1 calc R . .
C117 C 0.2618(2) 0.1657(3) -0.3610(3) 0.0345(17) Uani 1 1 d . . .
H117 H 0.2923 0.1533 -0.3589 0.041 Uiso 1 1 calc R . .
C118 C 0.2302(2) 0.1877(3) -0.4172(3) 0.0329(17) Uani 1 1 d . . .
H118 H 0.2386 0.1898 -0.4541 0.039 Uiso 1 1 calc R . .
C119 C 0.1861(2) 0.2068(3) -0.4206(3) 0.0281(15) Uani 1 1 d . . .
H119 H 0.1644 0.2227 -0.4594 0.034 Uiso 1 1 calc R . .
C120 C 0.1736(2) 0.2028(3) -0.3671(3) 0.0256(15) Uani 1 1 d . . .
H120 H 0.1432 0.2158 -0.3693 0.031 Uiso 1 1 calc R . .
C121 C 0.2372(2) 0.1648(3) -0.1739(3) 0.0257(15) Uani 1 1 d . . .
C122 C 0.2596(2) 0.1095(3) -0.1482(3) 0.0383(18) Uani 1 1 d . . .
H122 H 0.2459 0.0708 -0.1660 0.046 Uiso 1 1 calc R . .
C123 C 0.3020(2) 0.1103(4) -0.0965(3) 0.047(2) Uani 1 1 d . . .
H123 H 0.3166 0.0722 -0.0783 0.056 Uiso 1 1 calc R . .
C124 C 0.3225(2) 0.1658(4) -0.0720(3) 0.046(2) Uani 1 1 d . . .
H124 H 0.3522 0.1660 -0.0380 0.055 Uiso 1 1 calc R . .
C125 C 0.3005(3) 0.2219(4) -0.0961(3) 0.052(2) Uani 1 1 d . . .
H125 H 0.3144 0.2604 -0.0782 0.063 Uiso 1 1 calc R . .
C126 C 0.2578(2) 0.2208(3) -0.1471(3) 0.047(2) Uani 1 1 d . . .
H126 H 0.2424 0.2590 -0.1637 0.057 Uiso 1 1 calc R . .
C127 C 0.2210(2) 0.3843(3) -0.2375(3) 0.0219(14) Uani 1 1 d . . .
C128 C 0.1918(2) 0.3780(3) -0.3021(3) 0.0294(16) Uani 1 1 d . . .
H128 H 0.1600 0.3916 -0.3155 0.035 Uiso 1 1 calc R . .
C129 C 0.2083(2) 0.3528(3) -0.3458(3) 0.0301(16) Uani 1 1 d . . .
H129 H 0.1885 0.3504 -0.3894 0.036 Uiso 1 1 calc R . .
C130 C 0.2547(2) 0.3303(3) -0.3262(3) 0.0300(16) Uani 1 1 d . . .
H130 H 0.2661 0.3121 -0.3565 0.036 Uiso 1 1 calc R . .
C131 C 0.2839(2) 0.3345(3) -0.2627(3) 0.0321(17) Uani 1 1 d . . .
H131 H 0.3152 0.3189 -0.2493 0.038 Uiso 1 1 calc R . .
C132 C 0.2671(2) 0.3618(3) -0.2189(3) 0.0274(15) Uani 1 1 d . . .
H132 H 0.2873 0.3653 -0.1755 0.033 Uiso 1 1 calc R . .
C133 C 0.2456(2) 0.4355(3) -0.1104(3) 0.0249(15) Uani 1 1 d . . .
C134 C 0.2674(2) 0.4936(3) -0.1007(3) 0.0356(17) Uani 1 1 d . . .
H134 H 0.2569 0.5248 -0.1328 0.043 Uiso 1 1 calc R . .
C135 C 0.3040(2) 0.5062(3) -0.0447(3) 0.0423(19) Uani 1 1 d . . .
H135 H 0.3186 0.5460 -0.0387 0.051 Uiso 1 1 calc R . .
C136 C 0.3198(2) 0.4621(3) 0.0023(3) 0.0353(17) Uani 1 1 d . . .
H136 H 0.3448 0.4716 0.0410 0.042 Uiso 1 1 calc R . .
C137 C 0.2992(2) 0.4040(3) -0.0068(3) 0.0370(17) Uani 1 1 d . . .
H137 H 0.3105 0.3730 0.0253 0.044 Uiso 1 1 calc R . .
C138 C 0.2624(2) 0.3907(3) -0.0620(3) 0.0319(16) Uani 1 1 d . . .
H138 H 0.2481 0.3507 -0.0675 0.038 Uiso 1 1 calc R . .
C139 C 0.1702(2) 0.4903(3) -0.2144(3) 0.0247(15) Uani 1 1 d . . .
C140 C 0.1384(2) 0.5174(3) -0.1908(3) 0.0372(18) Uani 1 1 d . . .
H140 H 0.1296 0.4956 -0.1599 0.045 Uiso 1 1 calc R . .
C141 C 0.1192(2) 0.5748(3) -0.2111(3) 0.0433(19) Uani 1 1 d . . .
H141 H 0.0980 0.5929 -0.1938 0.052 Uiso 1 1 calc R . .
C142 C 0.1309(2) 0.6063(3) -0.2568(3) 0.0438(19) Uani 1 1 d . . .
H142 H 0.1176 0.6462 -0.2710 0.053 Uiso 1 1 calc R . .
C143 C 0.1615(2) 0.5804(3) -0.2817(3) 0.0369(17) Uani 1 1 d . . .
H143 H 0.1690 0.6018 -0.3138 0.044 Uiso 1 1 calc R . .
C144 C 0.1814(2) 0.5230(3) -0.2604(3) 0.0335(17) Uani 1 1 d . . .
H144 H 0.2031 0.5056 -0.2775 0.040 Uiso 1 1 calc R . .
C145 C 0.5488(3) 0.6014(4) 0.5601(4) 0.078(3) Uani 1 1 d . . .
H1 H 0.5691 0.5765 0.5967 0.093 Uiso 1 1 calc R . .
H2 H 0.5157 0.5895 0.5515 0.093 Uiso 1 1 calc R . .
Cl1 Cl 0.55645(8) 0.68237(10) 0.57952(10) 0.0695(6) Uani 1 1 d . . .
Cl2 Cl 0.56362(8) 0.58505(10) 0.49187(11) 0.0783(7) Uani 1 1 d . . .
C146 C 0.2518(3) -0.0015(4) 0.0637(4) 0.084(3) Uani 1 1 d . . .
Cl3 Cl 0.19800(9) -0.01589(12) 0.07378(12) 0.0918(8) Uani 1 1 d . A .
Cl4 Cl 0.25661(19) -0.0446(2) -0.0025(3) 0.0928(16) Uani 0.70 1 d P A 1
Cl4' Cl 0.2435(5) -0.0149(6) -0.0138(9) 0.0928(16) Uani 0.30 1 d P A 2
C147 C -0.0616(6) 0.1719(9) -0.0478(9) 0.089(5) Uani 0.55 1 d P B 1
Cl5 Cl -0.03335(17) 0.1180(2) -0.0844(2) 0.0937(10) Uani 0.55 1 d P B 1
Cl6 Cl -0.09660(19) 0.1353(2) -0.0172(3) 0.0937(10) Uani 0.55 1 d P B 1
C148 C -0.0377(7) 0.1027(9) -0.0196(11) 0.089(5) Uani 0.45 1 d P C 2
Cl7 Cl -0.0428(2) 0.1690(3) -0.0650(3) 0.0937(10) Uani 0.45 1 d P C 2
Cl8 Cl -0.0909(2) 0.0912(3) -0.0103(3) 0.0937(10) Uani 0.45 1 d P C 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C7 Pt1 C1 85.4(2) . . ?
C7 Pt1 P1 178.08(16) . . ?
C1 Pt1 P1 93.34(16) . . ?
C7 Pt1 P2 93.08(15) . . ?
C1 Pt1 P2 175.65(17) . . ?
P1 Pt1 P2 88.26(6) . . ?
P3 Au1 P1 164.96(6) . . ?
P3 Au1 Au2 113.08(4) . . ?
P1 Au1 Au2 79.63(4) . . ?
P4 Au2 P2 167.52(6) . . ?
P4 Au2 Au1 109.01(4) . . ?
P2 Au2 Au1 82.25(4) . . ?
C13 P1 C19 102.3(3) . . ?
C13 P1 Pt1 112.82(18) . . ?
C19 P1 Pt1 111.7(2) . . ?
C13 P1 Au1 107.39(19) . . ?
C19 P1 Au1 113.17(19) . . ?
Pt1 P1 Au1 109.32(6) . . ?
C31 P2 C25 104.3(3) . . ?
C31 P2 Pt1 110.4(2) . . ?
C25 P2 Pt1 112.14(18) . . ?
C31 P2 Au2 98.6(2) . . ?
C25 P2 Au2 106.9(2) . . ?
Pt1 P2 Au2 122.38(7) . . ?
C43 P3 C37 104.7(3) . . ?
C43 P3 C49 106.3(3) . . ?
C37 P3 C49 105.4(3) . . ?
C43 P3 Au1 111.2(2) . . ?
C37 P3 Au1 110.6(2) . . ?
C49 P3 Au1 117.8(2) . . ?
C67 P4 C61 104.8(3) . . ?
C67 P4 C55 105.7(3) . . ?
C61 P4 C55 105.7(3) . . ?
C67 P4 Au2 120.2(2) . . ?
C61 P4 Au2 109.0(2) . . ?
C55 P4 Au2 110.5(2) . . ?
C6 C1 C2 113.8(5) . . ?
C6 C1 Pt1 122.4(4) . . ?
C2 C1 Pt1 123.8(4) . . ?
F1 C2 C3 116.0(5) . . ?
F1 C2 C1 120.2(5) . . ?
C3 C2 C1 123.7(5) . . ?
F2 C3 C4 119.5(5) . . ?
F2 C3 C2 121.1(5) . . ?
C4 C3 C2 119.4(5) . . ?
F3 C4 C5 120.3(6) . . ?
F3 C4 C3 120.4(5) . . ?
C5 C4 C3 119.3(5) . . ?
F4 C5 C4 120.1(5) . . ?
F4 C5 C6 120.6(5) . . ?
C4 C5 C6 119.1(6) . . ?
C1 C6 C5 124.7(6) . . ?
C1 C6 F5 119.4(5) . . ?
C5 C6 F5 115.9(5) . . ?
C8 C7 C12 112.7(6) . . ?
C8 C7 Pt1 122.5(4) . . ?
C12 C7 Pt1 124.5(5) . . ?
F6 C8 C7 119.7(5) . . ?
F6 C8 C9 115.8(5) . . ?
C7 C8 C9 124.5(6) . . ?
F7 C9 C10 119.6(5) . . ?
F7 C9 C8 120.9(6) . . ?
C10 C9 C8 119.5(6) . . ?
F8 C10 C9 119.7(6) . . ?
F8 C10 C11 121.2(6) . . ?
C9 C10 C11 119.0(6) . . ?
F9 C11 C12 121.8(6) . . ?
F9 C11 C10 119.0(6) . . ?
C12 C11 C10 119.1(6) . . ?
F10 C12 C11 116.3(6) . . ?
F10 C12 C7 118.7(5) . . ?
C11 C12 C7 125.0(6) . . ?
C18 C13 C14 118.2(5) . . ?
C18 C13 P1 121.5(4) . . ?
C14 C13 P1 120.0(4) . . ?
C15 C14 C13 120.6(5) . . ?
C16 C15 C14 119.9(6) . . ?
C17 C16 C15 120.6(6) . . ?
C16 C17 C18 119.6(6) . . ?
C13 C18 C17 121.2(5) . . ?
C20 C19 C24 118.3(6) . . ?
C20 C19 P1 121.2(5) . . ?
C24 C19 P1 120.5(5) . . ?
C19 C20 C21 120.3(6) . . ?
C22 C21 C20 120.4(7) . . ?
C21 C22 C23 120.1(7) . . ?
C24 C23 C22 119.6(7) . . ?
C23 C24 C19 121.2(6) . . ?
C26 C25 C30 118.6(6) . . ?
C26 C25 P2 121.2(5) . . ?
C30 C25 P2 120.1(5) . . ?
C25 C26 C27 120.9(6) . . ?
C28 C27 C26 120.0(7) . . ?
C29 C28 C27 120.7(6) . . ?
C28 C29 C30 120.8(6) . . ?
C29 C30 C25 119.1(6) . . ?
C32 C31 C36 119.0(6) . . ?
C32 C31 P2 121.2(5) . . ?
C36 C31 P2 119.3(5) . . ?
C33 C32 C31 120.5(7) . . ?
C32 C33 C34 119.5(7) . . ?
C35 C34 C33 120.8(7) . . ?
C36 C35 C34 119.8(7) . . ?
C35 C36 C31 120.3(6) . . ?
C38 C37 C42 117.9(6) . . ?
C38 C37 P3 123.0(5) . . ?
C42 C37 P3 119.1(5) . . ?
C37 C38 C39 120.1(6) . . ?
C40 C39 C38 120.5(6) . . ?
C39 C40 C41 120.4(7) . . ?
C42 C41 C40 118.7(6) . . ?
C41 C42 C37 122.3(6) . . ?
C44 C43 C48 118.7(7) . . ?
C44 C43 P3 119.1(5) . . ?
C48 C43 P3 122.2(6) . . ?
C45 C44 C43 121.5(7) . . ?
C44 C45 C46 119.4(8) . . ?
C47 C46 C45 119.9(7) . . ?
C46 C47 C48 120.6(7) . . ?
C47 C48 C43 119.9(7) . . ?
C54 C49 C50 118.3(6) . . ?
C54 C49 P3 119.1(5) . . ?
C50 C49 P3 122.6(5) . . ?
C49 C50 C51 120.4(6) . . ?
C52 C51 C50 120.2(6) . . ?
C53 C52 C51 119.5(7) . . ?
C52 C53 C54 120.2(7) . . ?
C49 C54 C53 121.2(6) . . ?
C60 C55 C56 118.6(6) . . ?
C60 C55 P4 118.4(5) . . ?
C56 C55 P4 123.0(5) . . ?
C57 C56 C55 119.6(6) . . ?
C58 C57 C56 120.2(6) . . ?
C57 C58 C59 121.0(6) . . ?
C58 C59 C60 119.5(7) . . ?
C55 C60 C59 121.0(6) . . ?
C66 C61 C62 117.7(6) . . ?
C66 C61 P4 121.6(5) . . ?
C62 C61 P4 120.7(5) . . ?
C63 C62 C61 121.8(6) . . ?
C62 C63 C64 119.6(6) . . ?
C65 C64 C63 118.3(7) . . ?
C66 C65 C64 122.0(7) . . ?
C65 C66 C61 120.6(6) . . ?
C72 C67 C68 119.5(6) . . ?
C72 C67 P4 122.0(5) . . ?
C68 C67 P4 118.5(5) . . ?
C69 C68 C67 118.9(7) . . ?
C70 C69 C68 120.8(8) . . ?
C71 C70 C69 119.8(8) . . ?
C70 C71 C72 120.5(7) . . ?
C71 C72 C67 120.4(7) . . ?
C79 Pt2 C73 87.8(2) . . ?
C79 Pt2 P6 92.73(15) . . ?
C73 Pt2 P6 175.60(17) . . ?
C79 Pt2 P5 174.18(16) . . ?
C73 Pt2 P5 91.22(15) . . ?
P6 Pt2 P5 88.71(5) . . ?
P7 Au3 P5 161.87(6) . . ?
P7 Au3 Au4 118.59(4) . . ?
P5 Au3 Au4 79.36(4) . . ?
P8 Au4 P6 169.23(6) . . ?
P8 Au4 Au3 109.10(4) . . ?
P6 Au4 Au3 79.59(4) . . ?
C91 P5 C85 104.8(3) . . ?
C91 P5 Pt2 111.8(2) . . ?
C85 P5 Pt2 110.29(18) . . ?
C91 P5 Au3 102.00(18) . . ?
C85 P5 Au3 103.4(2) . . ?
Pt2 P5 Au3 122.90(7) . . ?
C97 P6 C103 101.3(3) . . ?
C97 P6 Pt2 113.24(18) . . ?
C103 P6 Pt2 112.0(2) . . ?
C97 P6 Au4 109.23(19) . . ?
C103 P6 Au4 112.1(2) . . ?
Pt2 P6 Au4 108.82(6) . . ?
C109 P7 C121 105.8(3) . . ?
C109 P7 C115 104.0(3) . . ?
C121 P7 C115 105.7(3) . . ?
C109 P7 Au3 106.44(19) . . ?
C121 P7 Au3 121.2(2) . . ?
C115 P7 Au3 112.3(2) . . ?
C127 P8 C139 106.9(3) . . ?
C127 P8 C133 106.6(3) . . ?
C139 P8 C133 104.8(3) . . ?
C127 P8 Au4 114.63(19) . . ?
C139 P8 Au4 112.5(2) . . ?
C133 P8 Au4 110.82(19) . . ?
C74 C73 C78 113.7(5) . . ?
C74 C73 Pt2 125.5(4) . . ?
C78 C73 Pt2 120.8(4) . . ?
F11 C74 C73 119.0(5) . . ?
F11 C74 C75 116.7(5) . . ?
C73 C74 C75 124.3(6) . . ?
F12 C75 C76 121.0(6) . . ?
F12 C75 C74 120.4(6) . . ?
C76 C75 C74 118.7(6) . . ?
F13 C76 C75 119.5(7) . . ?
F13 C76 C77 120.2(6) . . ?
C75 C76 C77 120.3(6) . . ?
F14 C77 C76 120.2(6) . . ?
F14 C77 C78 120.3(6) . . ?
C76 C77 C78 119.4(6) . . ?
F15 C78 C77 116.8(5) . . ?
F15 C78 C73 119.6(5) . . ?
C77 C78 C73 123.6(6) . . ?
C84 C79 C80 113.7(5) . . ?
C84 C79 Pt2 121.3(4) . . ?
C80 C79 Pt2 125.0(4) . . ?
F16 C80 C81 116.2(5) . . ?
F16 C80 C79 120.2(5) . . ?
C81 C80 C79 123.6(5) . . ?
F17 C81 C82 119.3(5) . . ?
F17 C81 C80 120.8(5) . . ?
C82 C81 C80 119.9(5) . . ?
F18 C82 C83 120.5(5) . . ?
F18 C82 C81 120.2(5) . . ?
C83 C82 C81 119.2(5) . . ?
F19 C83 C82 120.2(5) . . ?
F19 C83 C84 121.2(5) . . ?
C82 C83 C84 118.6(5) . . ?
F20 C84 C79 119.3(5) . . ?
F20 C84 C83 115.8(5) . . ?
C79 C84 C83 124.9(5) . . ?
C90 C85 C86 119.9(7) . . ?
C90 C85 P5 119.1(5) . . ?
C86 C85 P5 120.5(5) . . ?
C85 C86 C87 118.6(8) . . ?
C88 C87 C86 120.6(9) . . ?
C89 C88 C87 120.6(8) . . ?
C88 C89 C90 120.9(9) . . ?
C85 C90 C89 119.5(8) . . ?
C96 C91 C92 117.6(6) . . ?
C96 C91 P5 121.1(5) . . ?
C92 C91 P5 121.1(5) . . ?
C93 C92 C91 121.6(7) . . ?
C94 C93 C92 119.9(7) . . ?
C93 C94 C95 120.0(7) . . ?
C94 C95 C96 119.7(7) . . ?
C91 C96 C95 121.2(6) . . ?
C102 C97 C98 118.3(5) . . ?
C102 C97 P6 120.7(4) . . ?
C98 C97 P6 120.6(4) . . ?
C99 C98 C97 120.5(5) . . ?
C98 C99 C100 120.7(5) . . ?
C101 C100 C99 119.6(5) . . ?
C100 C101 C102 120.4(6) . . ?
C101 C102 C97 120.5(5) . . ?
C104 C103 C108 118.3(6) . . ?
C104 C103 P6 121.3(5) . . ?
C108 C103 P6 120.3(5) . . ?
C105 C104 C103 121.1(7) . . ?
C106 C105 C104 119.6(7) . . ?
C105 C106 C107 120.6(7) . . ?
C106 C107 C108 119.8(8) . . ?
C107 C108 C103 120.6(7) . . ?
C110 C109 C114 117.4(6) . . ?
C110 C109 P7 118.2(5) . . ?
C114 C109 P7 124.3(4) . . ?
C111 C110 C109 122.1(6) . . ?
C110 C111 C112 119.6(6) . . ?
C113 C112 C111 119.5(6) . . ?
C112 C113 C114 121.0(6) . . ?
C113 C114 C109 120.3(6) . . ?
C116 C115 C120 119.8(5) . . ?
C116 C115 P7 122.3(5) . . ?
C120 C115 P7 117.7(4) . . ?
C115 C116 C117 119.3(6) . . ?
C118 C117 C116 120.8(6) . . ?
C117 C118 C119 120.1(6) . . ?
C118 C119 C120 119.9(6) . . ?
C119 C120 C115 120.1(5) . . ?
C126 C121 C122 118.8(6) . . ?
C126 C121 P7 117.7(5) . . ?
C122 C121 P7 123.4(5) . . ?
C121 C122 C123 120.4(7) . . ?
C124 C123 C122 120.2(7) . . ?
C123 C124 C125 120.6(7) . . ?
C124 C125 C126 119.0(7) . . ?
C121 C126 C125 121.0(7) . . ?
C132 C127 C128 118.0(5) . . ?
C132 C127 P8 123.1(5) . . ?
C128 C127 P8 118.8(4) . . ?
C129 C128 C127 121.3(6) . . ?
C128 C129 C130 119.9(6) . . ?
C131 C130 C129 120.1(6) . . ?
C130 C131 C132 119.5(6) . . ?
C131 C132 C127 121.2(6) . . ?
C134 C133 C138 118.0(6) . . ?
C134 C133 P8 122.8(5) . . ?
C138 C133 P8 119.2(5) . . ?
C135 C134 C133 120.3(6) . . ?
C136 C135 C134 121.0(6) . . ?
C135 C136 C137 119.5(6) . . ?
C138 C137 C136 120.4(6) . . ?
C137 C138 C133 120.8(6) . . ?
C144 C139 C140 117.6(6) . . ?
C144 C139 P8 123.4(5) . . ?
C140 C139 P8 119.0(5) . . ?
C141 C140 C139 121.4(6) . . ?
C140 C141 C142 119.9(6) . . ?
C143 C142 C141 120.0(6) . . ?
C142 C143 C144 120.1(6) . . ?
C143 C144 C139 121.0(6) . . ?
Cl2 C145 Cl1 110.6(4) . . ?
Cl4' C146 Cl3 107.3(7) . . ?
Cl4' C146 Cl4 24.5(4) . . ?
Cl3 C146 Cl4 111.7(5) . . ?
Cl6 C147 Cl5 111.5(10) . . ?
Cl8 C148 Cl7 107.4(12) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 C7 2.054(6) . ?
Pt1 C1 2.061(6) . ?
Pt1 P1 2.2952(16) . ?
Pt1 P2 2.3023(15) . ?
Au1 P3 2.3054(16) . ?
Au1 P1 2.3284(15) . ?
Au1 Au2 3.0723(4) . ?
Au2 P4 2.3091(16) . ?
Au2 P2 2.3353(16) . ?
P1 C13 1.833(6) . ?
P1 C19 1.836(6) . ?
P2 C31 1.818(7) . ?
P2 C25 1.833(6) . ?
P3 C43 1.808(7) . ?
P3 C37 1.813(7) . ?
P3 C49 1.815(6) . ?
P4 C67 1.808(6) . ?
P4 C61 1.820(7) . ?
P4 C55 1.822(6) . ?
F1 C2 1.362(6) . ?
F2 C3 1.358(5) . ?
F3 C4 1.350(5) . ?
F4 C5 1.346(6) . ?
F5 C6 1.378(6) . ?
F6 C8 1.369(6) . ?
F7 C9 1.352(6) . ?
F8 C10 1.357(6) . ?
F9 C11 1.350(6) . ?
F10 C12 1.351(6) . ?
C1 C6 1.364(7) . ?
C1 C2 1.381(7) . ?
C2 C3 1.375(7) . ?
C3 C4 1.366(8) . ?
C4 C5 1.358(8) . ?
C5 C6 1.376(7) . ?
C7 C8 1.381(8) . ?
C7 C12 1.386(8) . ?
C8 C9 1.383(8) . ?
C9 C10 1.359(8) . ?
C10 C11 1.373(8) . ?
C11 C12 1.372(8) . ?
C13 C18 1.383(7) . ?
C13 C14 1.394(7) . ?
C14 C15 1.383(7) . ?
C15 C16 1.372(8) . ?
C16 C17 1.369(7) . ?
C17 C18 1.384(7) . ?
C19 C20 1.390(8) . ?
C19 C24 1.399(8) . ?
C20 C21 1.391(8) . ?
C21 C22 1.365(9) . ?
C22 C23 1.392(9) . ?
C23 C24 1.373(8) . ?
C25 C26 1.370(8) . ?
C25 C30 1.413(8) . ?
C26 C27 1.381(8) . ?
C27 C28 1.362(8) . ?
C28 C29 1.351(8) . ?
C29 C30 1.386(8) . ?
C31 C32 1.404(8) . ?
C31 C36 1.405(9) . ?
C32 C33 1.378(9) . ?
C33 C34 1.398(10) . ?
C34 C35 1.383(9) . ?
C35 C36 1.382(9) . ?
C37 C38 1.368(8) . ?
C37 C42 1.406(8) . ?
C38 C39 1.394(9) . ?
C39 C40 1.374(8) . ?
C40 C41 1.376(8) . ?
C41 C42 1.368(9) . ?
C43 C44 1.388(9) . ?
C43 C48 1.398(8) . ?
C44 C45 1.374(9) . ?
C45 C46 1.395(10) . ?
C46 C47 1.379(10) . ?
C47 C48 1.387(9) . ?
C49 C54 1.381(8) . ?
C49 C50 1.382(8) . ?
C50 C51 1.390(8) . ?
C51 C52 1.383(9) . ?
C52 C53 1.363(9) . ?
C53 C54 1.385(8) . ?
C55 C60 1.376(8) . ?
C55 C56 1.410(8) . ?
C56 C57 1.382(8) . ?
C57 C58 1.364(9) . ?
C58 C59 1.370(8) . ?
C59 C60 1.383(8) . ?
C61 C66 1.374(8) . ?
C61 C62 1.384(8) . ?
C62 C63 1.367(8) . ?
C63 C64 1.387(8) . ?
C64 C65 1.364(8) . ?
C65 C66 1.361(9) . ?
C67 C72 1.385(8) . ?
C67 C68 1.397(9) . ?
C68 C69 1.384(9) . ?
C69 C70 1.382(10) . ?
C70 C71 1.362(10) . ?
C71 C72 1.376(8) . ?
Pt2 C79 2.057(5) . ?
Pt2 C73 2.061(5) . ?
Pt2 P6 2.2982(16) . ?
Pt2 P5 2.3059(15) . ?
Au3 P7 2.3025(15) . ?
Au3 P5 2.3320(15) . ?
Au3 Au4 3.1548(4) . ?
Au4 P8 2.3022(15) . ?
Au4 P6 2.3173(15) . ?
P5 C91 1.823(6) . ?
P5 C85 1.843(6) . ?
P6 C97 1.834(6) . ?
P6 C103 1.835(6) . ?
P7 C109 1.798(6) . ?
P7 C121 1.803(6) . ?
P7 C115 1.806(5) . ?
P8 C127 1.795(6) . ?
P8 C139 1.813(6) . ?
P8 C133 1.815(6) . ?
F11 C74 1.374(6) . ?
F12 C75 1.348(7) . ?
F13 C76 1.357(6) . ?
F14 C77 1.346(6) . ?
F15 C78 1.351(6) . ?
F16 C80 1.356(5) . ?
F17 C81 1.354(5) . ?
F18 C82 1.341(5) . ?
F19 C83 1.339(6) . ?
F20 C84 1.373(5) . ?
C73 C74 1.385(8) . ?
C73 C78 1.389(8) . ?
C74 C75 1.391(8) . ?
C75 C76 1.358(9) . ?
C76 C77 1.363(9) . ?
C77 C78 1.385(8) . ?
C79 C84 1.378(7) . ?
C79 C80 1.381(7) . ?
C80 C81 1.379(7) . ?
C81 C82 1.374(8) . ?
C82 C83 1.367(8) . ?
C83 C84 1.385(7) . ?
C85 C90 1.378(9) . ?
C85 C86 1.397(8) . ?
C86 C87 1.399(9) . ?
C87 C88 1.367(12) . ?
C88 C89 1.342(12) . ?
C89 C90 1.396(9) . ?
C91 C96 1.374(8) . ?
C91 C92 1.400(7) . ?
C92 C93 1.385(8) . ?
C93 C94 1.363(9) . ?
C94 C95 1.387(9) . ?
C95 C96 1.397(8) . ?
C97 C102 1.394(7) . ?
C97 C98 1.402(7) . ?
C98 C99 1.374(7) . ?
C99 C100 1.382(8) . ?
C100 C101 1.374(7) . ?
C101 C102 1.388(7) . ?
C103 C104 1.383(8) . ?
C103 C108 1.391(8) . ?
C104 C105 1.382(8) . ?
C105 C106 1.364(10) . ?
C106 C107 1.377(10) . ?
C107 C108 1.379(9) . ?
C109 C110 1.384(7) . ?
C109 C114 1.390(7) . ?
C110 C111 1.371(8) . ?
C111 C112 1.381(8) . ?
C112 C113 1.360(8) . ?
C113 C114 1.387(8) . ?
C115 C116 1.384(7) . ?
C115 C120 1.390(8) . ?
C116 C117 1.389(8) . ?
C117 C118 1.369(8) . ?
C118 C119 1.379(8) . ?
C119 C120 1.386(7) . ?
C121 C126 1.387(8) . ?
C121 C122 1.388(8) . ?
C122 C123 1.393(8) . ?
C123 C124 1.365(9) . ?
C124 C125 1.390(9) . ?
C125 C126 1.391(9) . ?
C127 C132 1.400(7) . ?
C127 C128 1.410(8) . ?
C128 C129 1.363(7) . ?
C129 C130 1.406(8) . ?
C130 C131 1.387(8) . ?
C131 C132 1.390(7) . ?
C133 C134 1.393(8) . ?
C133 C138 1.402(8) . ?
C134 C135 1.375(8) . ?
C135 C136 1.370(9) . ?
C136 C137 1.377(8) . ?
C137 C138 1.370(8) . ?
C139 C144 1.388(7) . ?
C139 C140 1.388(8) . ?
C140 C141 1.368(8) . ?
C141 C142 1.376(8) . ?
C142 C143 1.365(8) . ?
C143 C144 1.379(8) . ?
C145 Cl2 1.779(7) . ?
C145 Cl1 1.785(8) . ?
C146 Cl4' 1.69(2) . ?
C146 Cl3 1.760(8) . ?
C146 Cl4 1.799(10) . ?
C147 Cl6 1.658(16) . ?
C147 Cl5 1.804(17) . ?
C148 Cl8 1.723(18) . ?
C148 Cl7 1.72(2) . ?
