#------------------------------------------------------------------------------
#$Date: 2016-03-26 00:18:19 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180071 $
#$URL: svn://www.crystallography.net/cod/cif/7/05/17/7051785.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7051785
loop_
_publ_author_name
'Strasser, Christoph E.'
'Gabrielli, William F.'
'Esterhuysen, Catharine'
'Schuster, Oliver B.'
'Nogai, Stefan D.'
'Cronje, Stephanie'
'Raubenheimer, Helgard G.'
_publ_section_title
;
 Preparation of tris(azolyl)phosphine gold(i) complexes: digold(i)
 coordination and variation in solid state intermolecular interactions
;
_journal_issue                   1
_journal_name_full               'New Journal of Chemistry'
_journal_page_first              138
_journal_paper_doi               10.1039/b709896k
_journal_volume                  32
_journal_year                    2008
_chemical_formula_moiety         'C9 H6 Au Cl N3 P S3, 0.5(C H2 Cl2)'
_chemical_formula_sum            'C9.5 H7 Au Cl2 N3 P S3'
_chemical_formula_weight         558.22
_chemical_name_common
'tris(thiazol-2-yl)phosphinegold(I) chloride dichloromethane hemisolvate'
_chemical_name_systematic
'chlorido[tris(thiazol-2-yl)phosphane]gold(I) dichloromethane hemisolvate'
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      14
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 96.018(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   7.9518(9)
_cell_length_b                   20.261(2)
_cell_length_c                   19.413(2)
_cell_measurement_reflns_used    1857
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      25.909
_cell_measurement_theta_min      2.271
_cell_volume                     3110.4(6)
_computing_cell_refinement       'SAINT (Bruker, 2003)'
_computing_data_collection       'SMART (Bruker, 2002)'
_computing_data_reduction        SAINT
_computing_molecular_graphics    'X-Seed (Barbour, 2001)'
_computing_publication_material  X-Seed
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS (Sheldrick, 1990)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.991
_diffrn_measured_fraction_theta_max 0.991
_diffrn_measurement_device_type  'Bruker APEX CCD area detector'
_diffrn_measurement_method       ω-scans
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0675
_diffrn_reflns_av_sigmaI/netI    0.0880
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_h_min       -9
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -25
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_number            17633
_diffrn_reflns_theta_full        26.44
_diffrn_reflns_theta_max         26.44
_diffrn_reflns_theta_min         2.01
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    10.296
_exptl_absorpt_correction_T_max  0.596
_exptl_absorpt_correction_T_min  0.117
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS (Bruker, 2002)'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    2.384
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       needle
_exptl_crystal_F_000             2088
_exptl_crystal_size_max          0.34
_exptl_crystal_size_mid          0.08
_exptl_crystal_size_min          0.05
_refine_diff_density_max         1.663
_refine_diff_density_min         -2.172
_refine_diff_density_rms         0.258
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.991
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     352
_refine_ls_number_reflns         6344
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.991
_refine_ls_R_factor_all          0.0739
_refine_ls_R_factor_gt           0.0481
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0288P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0833
_refine_ls_wR_factor_ref         0.0909
_reflns_number_gt                4748
_reflns_number_total             6344
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b709896k.txt
_cod_data_source_block           Compound2bDCM
_cod_original_cell_volume        3110.6(6)
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               7051785
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Au1 Au 0.57237(4) 0.160161(19) 0.768351(17) 0.01391(10) Uani 1 1 d . . .
Au2 Au 0.34624(4) 0.24949(2) 0.858981(17) 0.01349(10) Uani 1 1 d . . .
Cl1 Cl 0.3984(3) 0.18516(13) 0.67062(12) 0.0254(6) Uani 1 1 d . . .
Cl2 Cl 0.4665(3) 0.19366(12) 0.95326(11) 0.0182(5) Uani 1 1 d . . .
Cl3 Cl -0.0369(4) 0.07639(15) 0.54725(13) 0.0376(7) Uani 1 1 d . . .
Cl4 Cl 0.2472(4) 0.08250(16) 0.46457(17) 0.0502(9) Uani 1 1 d . . .
S11 S 0.8804(3) 0.26079(12) 0.90239(12) 0.0213(6) Uani 1 1 d . . .
S21 S 1.1465(3) 0.08536(13) 0.84480(12) 0.0199(6) Uani 1 1 d . . .
S31 S 0.7836(3) 0.01714(13) 0.96995(11) 0.0166(5) Uani 1 1 d . . .
S41 S 0.5971(3) 0.34913(13) 0.75309(12) 0.0212(6) Uani 1 1 d . . .
S51 S 0.2013(3) 0.41838(14) 0.88540(12) 0.0263(6) Uani 1 1 d . . .
S61 S 0.0452(3) 0.29823(12) 0.62514(11) 0.0168(5) Uani 1 1 d . . .
P1 P 0.7651(3) 0.12313(12) 0.84979(12) 0.0124(5) Uani 1 1 d . . .
P2 P 0.2297(3) 0.31300(13) 0.77436(12) 0.0137(5) Uani 1 1 d . . .
N11 N 0.9412(9) 0.1558(4) 0.9743(4) 0.0212(19) Uani 1 1 d . . .
N21 N 0.9062(8) 0.0568(4) 0.7496(4) 0.0138(17) Uani 1 1 d . . .
N31 N 0.5525(8) 0.0235(4) 0.8683(4) 0.0167(18) Uani 1 1 d . . .
N41 N 0.3442(8) 0.3843(4) 0.6682(4) 0.0146(17) Uani 1 1 d . . .
N51 N -0.0069(9) 0.4145(4) 0.7739(4) 0.0185(19) Uani 1 1 d . . .
N61 N -0.0159(9) 0.2266(4) 0.7291(4) 0.0209(19) Uani 1 1 d . . .
C1 C 0.1212(13) 0.1277(5) 0.5188(5) 0.035(3) Uani 1 1 d . . .
H1A H 0.1937 0.1451 0.5593 0.042 Uiso 1 1 calc R . .
H1B H 0.0679 0.1657 0.4928 0.042 Uiso 1 1 calc R . .
C11 C 0.8688(11) 0.1764(5) 0.9130(4) 0.015(2) Uani 1 1 d . . .
C12 C 0.9815(12) 0.2669(5) 0.9840(5) 0.022(2) Uani 1 1 d . . .
H12 H 1.0172 0.3072 1.0057 0.026 Uiso 1 1 calc R . .
C13 C 1.0043(12) 0.2071(5) 1.0137(5) 0.025(2) Uani 1 1 d . . .
H13 H 1.0605 0.2012 1.0589 0.031 Uiso 1 1 calc R . .
C21 C 0.9369(11) 0.0866(5) 0.8093(4) 0.014(2) Uani 1 1 d . . .
C22 C 1.1956(11) 0.0424(5) 0.7737(5) 0.019(2) Uani 1 1 d . . .
H22 H 1.3061 0.0281 0.7665 0.023 Uiso 1 1 calc R . .
C23 C 1.0572(11) 0.0315(5) 0.7298(5) 0.017(2) Uani 1 1 d . . .
H23 H 1.0615 0.0081 0.6876 0.020 Uiso 1 1 calc R . .
C31 C 0.6854(10) 0.0545(5) 0.8967(5) 0.015(2) Uani 1 1 d . . .
C32 C 0.6369(10) -0.0444(5) 0.9602(4) 0.015(2) Uani 1 1 d . . .
H32 H 0.6350 -0.0819 0.9895 0.019 Uiso 1 1 calc R . .
C33 C 0.5231(11) -0.0321(5) 0.9046(5) 0.016(2) Uani 1 1 d . . .
H33 H 0.4296 -0.0604 0.8918 0.019 Uiso 1 1 calc R . .
C41 C 0.3828(9) 0.3519(4) 0.7257(4) 0.0103(19) Uani 1 1 d . . .
C42 C 0.6334(11) 0.3938(5) 0.6831(4) 0.019(2) Uani 1 1 d . . .
H42 H 0.7423 0.4070 0.6723 0.023 Uiso 1 1 calc R . .
C43 C 0.4863(10) 0.4086(5) 0.6442(5) 0.017(2) Uani 1 1 d . . .
H43 H 0.4829 0.4341 0.6031 0.020 Uiso 1 1 calc R . .
C51 C 0.1221(11) 0.3838(5) 0.8072(4) 0.017(2) Uani 1 1 d . . .
C52 C 0.0528(12) 0.4801(5) 0.8704(5) 0.027(3) Uani 1 1 d . . .
H52 H 0.0419 0.5167 0.9001 0.033 Uiso 1 1 calc R . .
C53 C -0.0448(11) 0.4693(5) 0.8114(5) 0.022(2) Uani 1 1 d . . .
H53 H -0.1357 0.4978 0.7960 0.027 Uiso 1 1 calc R . .
C61 C 0.0742(10) 0.2765(5) 0.7108(4) 0.014(2) Uani 1 1 d . . .
C62 C -0.1000(10) 0.2372(5) 0.6117(5) 0.021(2) Uani 1 1 d . . .
H62 H -0.1625 0.2272 0.5686 0.026 Uiso 1 1 calc R . .
C63 C -0.1133(11) 0.2046(5) 0.6722(5) 0.023(2) Uani 1 1 d . . .
H63 H -0.1876 0.1682 0.6745 0.028 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P1 Au1 Cl1 168.97(9) . . ?
P1 Au1 Au2 100.70(6) . . ?
Cl1 Au1 Au2 90.29(6) . . ?
P2 Au2 Cl2 174.00(9) . . ?
P2 Au2 Au1 97.84(6) . . ?
Cl2 Au2 Au1 87.03(6) . . ?
Au2 Cl2 S61 143.08(10) . 4_666 ?
C12 S11 C11 89.2(5) . . ?
C22 S21 C21 88.7(4) . . ?
C32 S31 C31 89.1(4) . . ?
C42 S41 C41 88.9(4) . . ?
C52 S51 C51 88.0(5) . . ?
C62 S61 C61 89.0(4) . . ?
C11 P1 C21 103.5(4) . . ?
C11 P1 C31 106.3(4) . . ?
C21 P1 C31 103.0(4) . . ?
C11 P1 Au1 121.7(3) . . ?
C21 P1 Au1 109.1(3) . . ?
C31 P1 Au1 111.5(3) . . ?
C41 P2 C61 105.8(4) . . ?
C41 P2 C51 102.0(4) . . ?
C61 P2 C51 104.4(4) . . ?
C41 P2 Au2 113.0(3) . . ?
C61 P2 Au2 118.1(3) . . ?
C51 P2 Au2 112.0(3) . . ?
C11 N11 C13 111.3(8) . . ?
C21 N21 C23 109.1(7) . . ?
C31 N31 C33 110.9(8) . . ?
C41 N41 C43 110.3(7) . . ?
C51 N51 C53 108.9(8) . . ?
C61 N61 C63 108.3(8) . . ?
Cl3 C1 Cl4 110.2(6) . . ?
Cl3 C1 H1A 109.6 . . ?
Cl4 C1 H1A 109.6 . . ?
Cl3 C1 H1B 109.6 . . ?
Cl4 C1 H1B 109.6 . . ?
H1A C1 H1B 108.1 . . ?
N11 C11 S11 113.2(7) . . ?
N11 C11 P1 123.6(7) . . ?
S11 C11 P1 123.2(5) . . ?
C13 C12 S11 111.3(8) . . ?
C13 C12 H12 124.4 . . ?
S11 C12 H12 124.4 . . ?
C12 C13 N11 115.0(9) . . ?
C12 C13 H13 122.5 . . ?
N11 C13 H13 122.5 . . ?
N21 C21 S21 115.3(6) . . ?
N21 C21 P1 119.8(6) . . ?
S21 C21 P1 124.9(5) . . ?
C23 C22 S21 110.9(7) . . ?
C23 C22 H22 124.6 . . ?
S21 C22 H22 124.6 . . ?
C22 C23 N21 116.0(8) . . ?
C22 C23 H23 122.0 . . ?
N21 C23 H23 122.0 . . ?
N31 C31 S31 114.5(7) . . ?
N31 C31 P1 117.9(7) . . ?
S31 C31 P1 126.8(5) . . ?
C33 C32 S31 110.3(7) . . ?
C33 C32 H32 124.9 . . ?
S31 C32 H32 124.9 . . ?
C32 C33 N31 115.2(8) . . ?
C32 C33 H33 122.4 . . ?
N31 C33 H33 122.4 . . ?
N41 C41 S41 114.5(6) . . ?
N41 C41 P2 124.0(6) . . ?
S41 C41 P2 121.6(5) . . ?
C43 C42 S41 110.9(7) . . ?
C43 C42 H42 124.5 . . ?
S41 C42 H42 124.5 . . ?
C42 C43 N41 115.4(8) . . ?
C42 C43 H43 122.3 . . ?
N41 C43 H43 122.3 . . ?
N51 C51 S51 115.7(7) . . ?
N51 C51 P2 125.0(7) . . ?
S51 C51 P2 119.1(5) . . ?
C53 C52 S51 110.6(8) . . ?
C53 C52 H52 124.7 . . ?
S51 C52 H52 124.7 . . ?
C52 C53 N51 116.6(9) . . ?
C52 C53 H53 121.7 . . ?
N51 C53 H53 121.7 . . ?
N61 C61 S61 116.1(7) . . ?
N61 C61 P2 118.9(7) . . ?
S61 C61 P2 124.7(5) . . ?
C63 C62 S61 109.6(7) . . ?
C63 C62 H62 125.2 . . ?
S61 C62 H62 125.2 . . ?
N61 C63 C62 117.0(9) . . ?
N61 C63 H63 121.5 . . ?
C62 C63 H63 121.5 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au1 P1 2.214(2) . ?
Au1 Cl1 2.285(2) . ?
Au1 Au2 3.2044(5) . ?
Au2 P2 2.212(2) . ?
Au2 Cl2 2.275(2) . ?
Cl2 S61 3.334(3) 4_666 ?
Cl3 C1 1.765(10) . ?
Cl4 C1 1.781(10) . ?
S11 C12 1.704(9) . ?
S11 C11 1.726(9) . ?
S21 C22 1.711(9) . ?
S21 C21 1.736(9) . ?
S31 C32 1.704(9) . ?
S31 C31 1.723(9) . ?
S41 C42 1.682(9) . ?
S41 C41 1.732(8) . ?
S51 C52 1.724(11) . ?
S51 C51 1.729(9) . ?
S61 C62 1.693(10) . ?
S61 C61 1.712(9) . ?
P1 C11 1.772(9) . ?
P1 C21 1.805(9) . ?
P1 C31 1.813(9) . ?
P2 C41 1.799(8) . ?
P2 C61 1.811(9) . ?
P2 C51 1.819(10) . ?
N11 C11 1.333(10) . ?
N11 C13 1.354(12) . ?
N21 C21 1.307(10) . ?
N21 C23 1.396(10) . ?
N31 C31 1.301(10) . ?
N31 C33 1.363(11) . ?
N41 C41 1.304(10) . ?
N41 C43 1.359(10) . ?
N51 C51 1.312(11) . ?
N51 C53 1.377(12) . ?
N61 C61 1.311(11) . ?
N61 C63 1.356(11) . ?
C1 H1A 0.9900 . ?
C1 H1B 0.9900 . ?
C12 C13 1.346(13) . ?
C12 H12 0.9500 . ?
C13 H13 0.9500 . ?
C22 C23 1.338(11) . ?
C22 H22 0.9500 . ?
C23 H23 0.9500 . ?
C32 C33 1.357(12) . ?
C32 H32 0.9500 . ?
C33 H33 0.9500 . ?
C42 C43 1.358(11) . ?
C42 H42 0.9500 . ?
C43 H43 0.9500 . ?
C52 C53 1.332(12) . ?
C52 H52 0.9500 . ?
C53 H53 0.9500 . ?
C62 C63 1.361(12) . ?
C62 H62 0.9500 . ?
C63 H63 0.9500 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
P1 Au1 Au2 P2 158.66(9) . . . . ?
Cl1 Au1 Au2 P2 -22.32(9) . . . . ?
P1 Au1 Au2 Cl2 -17.81(9) . . . . ?
Cl1 Au1 Au2 Cl2 161.21(9) . . . . ?
Au1 Au2 Cl2 S61 159.46(16) . . . 4_666 ?
Cl1 Au1 P1 C11 138.6(5) . . . . ?
Au2 Au1 P1 C11 -46.6(3) . . . . ?
Cl1 Au1 P1 C21 18.4(6) . . . . ?
Au2 Au1 P1 C21 -166.8(3) . . . . ?
Cl1 Au1 P1 C31 -94.7(6) . . . . ?
Au2 Au1 P1 C31 80.1(3) . . . . ?
Au1 Au2 P2 C41 -53.4(3) . . . . ?
Au1 Au2 P2 C61 70.8(3) . . . . ?
Au1 Au2 P2 C51 -167.9(3) . . . . ?
C13 N11 C11 S11 0.9(10) . . . . ?
C13 N11 C11 P1 -177.2(7) . . . . ?
C12 S11 C11 N11 -1.3(7) . . . . ?
C12 S11 C11 P1 176.8(6) . . . . ?
C21 P1 C11 N11 -79.7(8) . . . . ?
C31 P1 C11 N11 28.4(9) . . . . ?
Au1 P1 C11 N11 157.4(6) . . . . ?
C21 P1 C11 S11 102.3(6) . . . . ?
C31 P1 C11 S11 -149.5(5) . . . . ?
Au1 P1 C11 S11 -20.5(7) . . . . ?
C11 S11 C12 C13 1.4(8) . . . . ?
S11 C12 C13 N11 -1.2(11) . . . . ?
C11 N11 C13 C12 0.2(12) . . . . ?
C23 N21 C21 S21 -0.5(10) . . . . ?
C23 N21 C21 P1 -178.7(6) . . . . ?
C22 S21 C21 N21 0.6(7) . . . . ?
C22 S21 C21 P1 178.6(6) . . . . ?
C11 P1 C21 N21 -163.7(7) . . . . ?
C31 P1 C21 N21 85.7(8) . . . . ?
Au1 P1 C21 N21 -32.9(8) . . . . ?
C11 P1 C21 S21 18.3(7) . . . . ?
C31 P1 C21 S21 -92.3(6) . . . . ?
Au1 P1 C21 S21 149.2(5) . . . . ?
C21 S21 C22 C23 -0.5(8) . . . . ?
S21 C22 C23 N21 0.3(11) . . . . ?
C21 N21 C23 C22 0.1(11) . . . . ?
C33 N31 C31 S31 0.1(10) . . . . ?
C33 N31 C31 P1 171.1(6) . . . . ?
C32 S31 C31 N31 0.9(7) . . . . ?
C32 S31 C31 P1 -169.1(6) . . . . ?
C11 P1 C31 N31 152.8(7) . . . . ?
C21 P1 C31 N31 -98.7(7) . . . . ?
Au1 P1 C31 N31 18.1(8) . . . . ?
C11 P1 C31 S31 -37.5(7) . . . . ?
C21 P1 C31 S31 71.0(7) . . . . ?
Au1 P1 C31 S31 -172.2(5) . . . . ?
C31 S31 C32 C33 -1.6(7) . . . . ?
S31 C32 C33 N31 2.0(10) . . . . ?
C31 N31 C33 C32 -1.4(11) . . . . ?
C43 N41 C41 S41 -0.5(10) . . . . ?
C43 N41 C41 P2 179.3(7) . . . . ?
C42 S41 C41 N41 0.0(7) . . . . ?
C42 S41 C41 P2 -179.8(6) . . . . ?
C61 P2 C41 N41 39.8(9) . . . . ?
C51 P2 C41 N41 -69.1(8) . . . . ?
Au2 P2 C41 N41 170.5(7) . . . . ?
C61 P2 C41 S41 -140.5(6) . . . . ?
C51 P2 C41 S41 110.6(6) . . . . ?
Au2 P2 C41 S41 -9.7(6) . . . . ?
C41 S41 C42 C43 0.5(8) . . . . ?
S41 C42 C43 N41 -0.9(11) . . . . ?
C41 N41 C43 C42 0.9(12) . . . . ?
C53 N51 C51 S51 1.0(10) . . . . ?
C53 N51 C51 P2 -174.2(7) . . . . ?
C52 S51 C51 N51 -1.8(8) . . . . ?
C52 S51 C51 P2 173.8(6) . . . . ?
C41 P2 C51 N51 86.6(9) . . . . ?
C61 P2 C51 N51 -23.4(9) . . . . ?
Au2 P2 C51 N51 -152.4(7) . . . . ?
C41 P2 C51 S51 -88.5(6) . . . . ?
C61 P2 C51 S51 161.5(5) . . . . ?
Au2 P2 C51 S51 32.6(6) . . . . ?
C51 S51 C52 C53 2.0(8) . . . . ?
S51 C52 C53 N51 -2.0(11) . . . . ?
C51 N51 C53 C52 0.7(12) . . . . ?
C63 N61 C61 S61 -0.2(10) . . . . ?
C63 N61 C61 P2 -175.5(7) . . . . ?
C62 S61 C61 N61 0.7(8) . . . . ?
C62 S61 C61 P2 175.7(6) . . . . ?
C41 P2 C61 N61 155.9(7) . . . . ?
C51 P2 C61 N61 -96.9(8) . . . . ?
Au2 P2 C61 N61 28.2(9) . . . . ?
C41 P2 C61 S61 -18.9(7) . . . . ?
C51 P2 C61 S61 88.2(6) . . . . ?
Au2 P2 C61 S61 -146.7(5) . . . . ?
C61 S61 C62 C63 -1.0(7) . . . . ?
C61 N61 C63 C62 -0.6(12) . . . . ?
S61 C62 C63 N61 1.2(11) . . . . ?
