#------------------------------------------------------------------------------
#$Date: 2016-03-26 00:20:33 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180073 $
#$URL: svn://www.crystallography.net/cod/cif/7/05/19/7051942.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7051942
loop_
_publ_author_name
'Degtyarenko, Anna S.'
'Solntsev, Pavlo V.'
'Krautscheid, Harald'
'Rusanov, Eduard B.'
'Chernega, Alexander N.'
'Domasevitch, Konstantin V.'
_publ_section_title
;
 Copper(i) and silver(i) coordination frameworks involving extended
 bipyridazine bridges
;
_journal_issue                   11
_journal_name_full               'New Journal of Chemistry'
_journal_page_first              1910
_journal_paper_doi               10.1039/b801231h
_journal_volume                  32
_journal_year                    2008
_chemical_formula_sum            'C52 H33 Ag4 F12 N13 O8'
_chemical_formula_weight         1627.39
_chemical_name_systematic
;
Silver(I) Trifluoroacetate 4:3 complex with 1,4-bi(pyridazin-4-yl)benzene,
Acetonitrile solvate
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                92.620(11)
_cell_angle_beta                 108.916(11)
_cell_angle_gamma                117.522(10)
_cell_formula_units_Z            1
_cell_length_a                   10.9059(10)
_cell_length_b                   11.1531(11)
_cell_length_c                   13.8012(13)
_cell_measurement_reflns_used    8000
_cell_measurement_temperature    223(2)
_cell_measurement_theta_max      28.15
_cell_measurement_theta_min      3.20
_cell_volume                     1369.6(3)
_computing_cell_refinement       'IPDS Software (Stoe & Cie, 2000)'
_computing_data_collection       'IPDS Software (Stoe & Cie, 2000)'
_computing_data_reduction        'IPDS Software (Stoe & Cie, 2000)'
_computing_molecular_graphics    'Diamond 2.1e (Brandenburg, 1999)'
_computing_publication_material  'WinGX 1.700.00 (Farrugia, 1999)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      223(2)
_diffrn_measured_fraction_theta_full 0.980
_diffrn_measured_fraction_theta_max 0.980
_diffrn_measurement_device_type  'Stoe Imaging plate diffraction system'
_diffrn_measurement_method       'φ oscillation scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0345
_diffrn_reflns_av_sigmaI/netI    0.0434
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            12755
_diffrn_reflns_theta_full        28.15
_diffrn_reflns_theta_max         28.15
_diffrn_reflns_theta_min         3.20
_diffrn_standards_decay_%        0
_exptl_absorpt_coefficient_mu    1.518
_exptl_absorpt_correction_T_max  0.7212
_exptl_absorpt_correction_T_min  0.6747
_exptl_absorpt_correction_type   refdelf
_exptl_absorpt_process_details   'DIFABS, (Walker & Stuart, 1983)'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.973
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             796
_exptl_crystal_size_max          0.27
_exptl_crystal_size_mid          0.22
_exptl_crystal_size_min          0.22
_refine_diff_density_max         0.761
_refine_diff_density_min         -0.615
_refine_diff_density_rms         0.086
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.889
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     469
_refine_ls_number_reflns         6582
_refine_ls_number_restraints     41
_refine_ls_restrained_S_all      0.897
_refine_ls_R_factor_all          0.0402
_refine_ls_R_factor_gt           0.0300
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0498P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0744
_refine_ls_wR_factor_ref         0.0762
_reflns_number_gt                4636
_reflns_number_total             6582
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b801231h.txt
_cod_data_source_block           (4)
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7051942
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 1.23609(2) 0.50174(3) 0.226222(17) 0.04091(8) Uani 1 1 d . . .
Ag2 Ag 0.89125(2) 0.38419(2) 0.208836(15) 0.03484(8) Uani 1 1 d . . .
N1 N 1.0600(2) 0.3940(3) 0.05819(17) 0.0295(5) Uani 1 1 d . . .
N2 N 0.9166(2) 0.3361(3) 0.05138(17) 0.0286(5) Uani 1 1 d . . .
N3 N 0.0710(2) -0.4210(3) -0.65784(17) 0.0333(6) Uani 1 1 d . . .
N4 N 0.2128(2) -0.3674(3) -0.65296(17) 0.0308(5) Uani 1 1 d . . .
N5 N 0.6362(3) 0.2814(3) 0.15334(19) 0.0370(6) Uani 1 1 d . . .
N6 N 0.5527(3) 0.1705(3) 0.07073(19) 0.0353(6) Uani 1 1 d . . .
O1 O 1.1836(3) 0.3062(3) 0.3156(2) 0.0582(7) Uani 1 1 d . . .
O2 O 0.9478(3) 0.2314(4) 0.3032(2) 0.0647(8) Uani 1 1 d . . .
O3 O 1.4983(4) 0.5845(4) 0.2720(3) 0.0852(11) Uani 1 1 d . . .
O4 O 1.4193(3) 0.6231(4) 0.1155(3) 0.0869(11) Uani 1 1 d . . .
F1 F 1.2230(4) 0.1797(6) 0.4702(4) 0.0697(18) Uani 0.60 1 d PD . .
F2 F 1.0305(8) 0.0123(4) 0.3499(4) 0.0667(17) Uani 0.60 1 d PD . .
F3 F 1.0064(8) 0.1216(8) 0.4670(5) 0.101(3) Uani 0.60 1 d PD . .
F1A F 1.2105(9) 0.1954(10) 0.4900(6) 0.158(8) Uani 0.40 1 d PD . .
F2A F 1.0725(14) 0.0277(7) 0.3541(7) 0.123(7) Uani 0.40 1 d PD . .
F3A F 0.9720(11) 0.0875(12) 0.4409(9) 0.112(5) Uani 0.40 1 d PD . .
F4 F 1.6851(9) 0.6474(11) 0.1177(7) 0.145(7) Uani 0.50 1 d PD . .
F5 F 1.7166(8) 0.8379(6) 0.1919(10) 0.126(6) Uani 0.50 1 d PD . .
F6 F 1.7775(6) 0.7105(12) 0.2847(6) 0.120(5) Uani 0.50 1 d PD . .
F6A F 1.7698(6) 0.6786(10) 0.2651(7) 0.090(3) Uani 0.50 1 d PD . .
F4A F 1.6769(9) 0.6815(12) 0.1042(5) 0.121(5) Uani 0.50 1 d PD . .
F5A F 1.7307(8) 0.8452(4) 0.2252(10) 0.104(4) Uani 0.50 1 d PD . .
C1 C 1.0842(3) 0.3651(3) -0.0256(2) 0.0317(6) Uani 1 1 d . . .
H1 H 1.1836 0.4081 -0.0211 0.038 Uiso 1 1 calc R . .
C2 C 0.9697(3) 0.2742(3) -0.1200(2) 0.0304(6) Uani 1 1 d . . .
H2 H 0.9916 0.2554 -0.1775 0.037 Uiso 1 1 calc R . .
C3 C 0.8237(3) 0.2124(3) -0.12726(19) 0.0257(5) Uani 1 1 d . . .
C4 C 0.8047(3) 0.2514(3) -0.0373(2) 0.0277(6) Uani 1 1 d . . .
H4 H 0.7063 0.2149 -0.0405 0.033 Uiso 1 1 calc R . .
C5 C 0.6930(3) 0.1072(3) -0.22081(19) 0.0253(5) Uani 1 1 d . . .
C6 C 0.7111(3) 0.0292(3) -0.2910(2) 0.0318(6) Uani 1 1 d . . .
H6 H 0.8079 0.0463 -0.2804 0.038 Uiso 1 1 calc R . .
C7 C 0.5889(3) -0.0730(3) -0.3760(2) 0.0327(7) Uani 1 1 d . . .
H7 H 0.6039 -0.1250 -0.4217 0.039 Uiso 1 1 calc R . .
C8 C 0.4438(3) -0.1004(3) -0.39507(19) 0.0271(6) Uani 1 1 d . . .
C9 C 0.4251(3) -0.0219(3) -0.3251(2) 0.0350(7) Uani 1 1 d . . .
H9 H 0.3284 -0.0383 -0.3362 0.042 Uiso 1 1 calc R . .
C10 C 0.5477(3) 0.0800(3) -0.2394(2) 0.0322(6) Uani 1 1 d . . .
H10 H 0.5328 0.1316 -0.1932 0.039 Uiso 1 1 calc R . .
C11 C 0.0515(3) -0.3715(4) -0.5786(2) 0.0391(8) Uani 1 1 d . . .
H11 H -0.0472 -0.4083 -0.5824 0.047 Uiso 1 1 calc R . .
C12 C 0.1672(3) -0.2686(3) -0.4902(2) 0.0373(7) Uani 1 1 d . . .
H12 H 0.1472 -0.2388 -0.4353 0.045 Uiso 1 1 calc R . .
C13 C 0.3123(3) -0.2113(3) -0.48530(19) 0.0279(6) Uani 1 1 d . . .
C14 C 0.3268(3) -0.2670(3) -0.5714(2) 0.0301(6) Uani 1 1 d . . .
H14 H 0.4236 -0.2308 -0.5713 0.036 Uiso 1 1 calc R . .
C15 C 0.5670(3) 0.3241(4) 0.1959(3) 0.0466(9) Uani 1 1 d . . .
H15 H 0.6266 0.4019 0.2532 0.056 Uiso 1 1 calc R . .
C16 C 0.4132(3) 0.2628(4) 0.1623(3) 0.0432(8) Uani 1 1 d . . .
H16 H 0.3699 0.2977 0.1959 0.052 Uiso 1 1 calc R . .
C17 C 0.3247(3) 0.1491(3) 0.0781(2) 0.0280(6) Uani 1 1 d . . .
C18 C 0.4043(3) 0.1077(3) 0.0359(2) 0.0328(6) Uani 1 1 d . . .
H18 H 0.3481 0.0298 -0.0211 0.039 Uiso 1 1 calc R . .
C19 C 0.0854(3) 0.0871(3) 0.0993(2) 0.0300(6) Uani 1 1 d . . .
H19 H 0.1430 0.1462 0.1671 0.036 Uiso 1 1 calc R . .
C20 C 0.1581(3) 0.0723(3) 0.0369(2) 0.0257(5) Uani 1 1 d . . .
C21 C 0.0698(3) -0.0167(3) -0.0635(2) 0.0298(6) Uani 1 1 d . . .
H21 H 0.1161 -0.0289 -0.1069 0.036 Uiso 1 1 calc R . .
C22 C 1.0717(4) 0.2393(3) 0.3351(2) 0.0428(8) Uani 1 1 d D . .
C23 C 1.0822(3) 0.1380(3) 0.4062(2) 0.0551(10) Uani 1 1 d D . .
C24 C 1.5139(3) 0.6272(3) 0.1968(3) 0.0487(9) Uani 1 1 d D . .
C25 C 1.6749(3) 0.7074(4) 0.1983(3) 0.0671(13) Uani 1 1 d D . .
N7 N 1.7258(8) 0.5114(7) 0.4420(5) 0.0513(15) Uani 0.50 1 d PD . .
C26 C 1.6288(9) 0.5013(9) 0.4594(6) 0.069(3) Uani 0.50 1 d PD . .
C27 C 1.506(4) 0.504(7) 0.483(2) 0.105(7) Uani 0.50 1 d PD . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 Ag1 N4 122.97(8) . 1_666 ?
N1 Ag1 O3 122.88(10) . . ?
N4 Ag1 O3 108.36(11) 1_666 . ?
N1 Ag1 O1 102.42(9) . . ?
N4 Ag1 O1 93.55(9) 1_666 . ?
O3 Ag1 O1 97.33(12) . . ?
N1 Ag1 Ag2 66.65(6) . . ?
N4 Ag1 Ag2 65.48(6) 1_666 . ?
O3 Ag1 Ag2 169.47(8) . . ?
O1 Ag1 Ag2 75.13(7) . . ?
N5 Ag2 N3 127.43(8) . 1_666 ?
N5 Ag2 N2 101.36(8) . . ?
N3 Ag2 N2 122.90(8) 1_666 . ?
N5 Ag2 O2 103.71(11) . . ?
N3 Ag2 O2 93.71(11) 1_666 . ?
N2 Ag2 O2 102.41(9) . . ?
N5 Ag2 Ag1 165.59(6) . . ?
N3 Ag2 Ag1 65.20(6) 1_666 . ?
N2 Ag2 Ag1 64.24(5) . . ?
O2 Ag2 Ag1 80.47(7) . . ?
C1 N1 N2 118.8(2) . . ?
C1 N1 Ag1 126.55(17) . . ?
N2 N1 Ag1 113.72(15) . . ?
C4 N2 N1 119.8(2) . . ?
C4 N2 Ag2 124.92(17) . . ?
N1 N2 Ag2 115.06(15) . . ?
C11 N3 N4 117.9(2) . . ?
C11 N3 Ag2 125.87(19) . 1_444 ?
N4 N3 Ag2 115.43(15) . 1_444 ?
C14 N4 N3 120.1(2) . . ?
C14 N4 Ag1 124.69(18) . 1_444 ?
N3 N4 Ag1 113.74(16) . 1_444 ?
C15 N5 N6 118.6(2) . . ?
C15 N5 Ag2 124.50(19) . . ?
N6 N5 Ag2 116.88(17) . . ?
C18 N6 N5 118.9(2) . . ?
C22 O1 Ag1 127.1(2) . . ?
C22 O2 Ag2 124.6(2) . . ?
C24 O3 Ag1 100.6(2) . . ?
N1 C1 C2 123.3(2) . . ?
N1 C1 H1 118.3 . . ?
C2 C1 H1 118.3 . . ?
C3 C2 C1 118.5(2) . . ?
C3 C2 H2 120.8 . . ?
C1 C2 H2 120.8 . . ?
C2 C3 C4 115.6(2) . . ?
C2 C3 C5 123.6(2) . . ?
C4 C3 C5 120.7(2) . . ?
N2 C4 C3 124.0(2) . . ?
N2 C4 H4 118.0 . . ?
C3 C4 H4 118.0 . . ?
C6 C5 C10 118.0(2) . . ?
C6 C5 C3 120.7(2) . . ?
C10 C5 C3 121.2(2) . . ?
C7 C6 C5 121.0(2) . . ?
C7 C6 H6 119.5 . . ?
C5 C6 H6 119.5 . . ?
C6 C7 C8 121.2(2) . . ?
C6 C7 H7 119.4 . . ?
C8 C7 H7 119.4 . . ?
C7 C8 C9 118.0(2) . . ?
C7 C8 C13 121.3(2) . . ?
C9 C8 C13 120.7(2) . . ?
C10 C9 C8 120.8(2) . . ?
C10 C9 H9 119.6 . . ?
C8 C9 H9 119.6 . . ?
C9 C10 C5 121.0(2) . . ?
C9 C10 H10 119.5 . . ?
C5 C10 H10 119.5 . . ?
N3 C11 C12 124.4(3) . . ?
N3 C11 H11 117.8 . . ?
C12 C11 H11 117.8 . . ?
C13 C12 C11 118.2(2) . . ?
C13 C12 H12 120.9 . . ?
C11 C12 H12 120.9 . . ?
C12 C13 C14 115.1(2) . . ?
C12 C13 C8 122.6(2) . . ?
C14 C13 C8 122.2(2) . . ?
N4 C14 C13 124.3(2) . . ?
N4 C14 H14 117.9 . . ?
C13 C14 H14 117.9 . . ?
N5 C15 C16 124.6(3) . . ?
N5 C15 H15 117.7 . . ?
C16 C15 H15 117.7 . . ?
C17 C16 C15 118.2(3) . . ?
C17 C16 H16 120.9 . . ?
C15 C16 H16 120.9 . . ?
C16 C17 C18 114.8(2) . . ?
C16 C17 C20 122.9(2) . . ?
C18 C17 C20 122.2(2) . . ?
N6 C18 C17 124.9(3) . . ?
N6 C18 H18 117.6 . . ?
C17 C18 H18 117.6 . . ?
C21 C19 C20 121.4(2) 2 . ?
C21 C19 H19 119.3 2 . ?
C20 C19 H19 119.3 . . ?
C19 C20 C21 118.2(2) . . ?
C19 C20 C17 119.9(2) . . ?
C21 C20 C17 121.9(2) . . ?
C19 C21 C20 120.4(2) 2 . ?
C19 C21 H21 119.8 2 . ?
C20 C21 H21 119.8 . . ?
O1 C22 O2 131.8(3) . . ?
O1 C22 C23 114.7(3) . . ?
O2 C22 C23 113.3(3) . . ?
F1A C23 F3A 107.2(4) . . ?
F3 C23 F2 107.2(4) . . ?
F3 C23 F1 106.4(4) . . ?
F2 C23 F1 105.2(3) . . ?
F1A C23 F2A 105.9(4) . . ?
F3A C23 F2A 106.1(4) . . ?
F3 C23 C22 113.0(3) . . ?
F1A C23 C22 113.2(4) . . ?
F3A C23 C22 112.5(4) . . ?
F2 C23 C22 111.8(3) . . ?
F1 C23 C22 112.7(3) . . ?
F2A C23 C22 111.5(4) . . ?
O3 C24 O4 129.5(3) . . ?
O3 C24 C25 118.3(3) . . ?
O4 C24 C25 112.1(3) . . ?
F6A C25 F4A 107.3(4) . . ?
F5 C25 F6 107.4(4) . . ?
F5 C25 F4 107.1(4) . . ?
F6 C25 F4 105.9(4) . . ?
F6A C25 F5A 107.4(4) . . ?
F4A C25 F5A 106.2(4) . . ?
F6A C25 C24 113.4(4) . . ?
F5 C25 C24 112.2(4) . . ?
F4A C25 C24 112.0(4) . . ?
F6 C25 C24 112.6(4) . . ?
F4 C25 C24 111.2(4) . . ?
F5A C25 C24 110.2(3) . . ?
N7 C26 C27 174(3) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 N1 2.288(2) . ?
Ag1 N4 2.317(2) 1_666 ?
Ag1 O3 2.401(3) . ?
Ag1 O1 2.481(3) . ?
Ag1 Ag2 3.2786(5) . ?
Ag2 N5 2.287(2) . ?
Ag2 N3 2.304(2) 1_666 ?
Ag2 N2 2.347(2) . ?
Ag2 O2 2.374(3) . ?
N1 C1 1.323(3) . ?
N1 N2 1.356(3) . ?
N2 C4 1.319(3) . ?
N3 C11 1.322(3) . ?
N3 N4 1.352(3) . ?
N3 Ag2 2.304(2) 1_444 ?
N4 C14 1.325(3) . ?
N4 Ag1 2.317(2) 1_444 ?
N5 C15 1.318(4) . ?
N5 N6 1.348(3) . ?
N6 C18 1.327(3) . ?
O1 C22 1.228(4) . ?
O2 C22 1.237(4) . ?
O3 C24 1.190(5) . ?
O4 C24 1.235(5) . ?
F1 C23 1.334(4) . ?
F2 C23 1.332(4) . ?
F3 C23 1.321(4) . ?
F1A C23 1.327(4) . ?
F2A C23 1.339(4) . ?
F3A C23 1.327(4) . ?
F4 C25 1.333(4) . ?
F5 C25 1.326(4) . ?
F6 C25 1.330(4) . ?
F6A C25 1.319(4) . ?
F4A C25 1.327(4) . ?
F5A C25 1.345(4) . ?
C1 C2 1.393(4) . ?
C1 H1 0.9400 . ?
C2 C3 1.378(4) . ?
C2 H2 0.9400 . ?
C3 C4 1.405(3) . ?
C3 C5 1.482(3) . ?
C4 H4 0.9400 . ?
C5 C6 1.393(3) . ?
C5 C10 1.398(4) . ?
C6 C7 1.383(4) . ?
C6 H6 0.9400 . ?
C7 C8 1.394(4) . ?
C7 H7 0.9400 . ?
C8 C9 1.399(3) . ?
C8 C13 1.483(3) . ?
C9 C10 1.388(4) . ?
C9 H9 0.9400 . ?
C10 H10 0.9400 . ?
C11 C12 1.390(4) . ?
C11 H11 0.9400 . ?
C12 C13 1.382(4) . ?
C12 H12 0.9400 . ?
C13 C14 1.403(3) . ?
C14 H14 0.9400 . ?
C15 C16 1.379(4) . ?
C15 H15 0.9400 . ?
C16 C17 1.378(4) . ?
C16 H16 0.9400 . ?
C17 C18 1.406(4) . ?
C17 C20 1.486(3) . ?
C18 H18 0.9400 . ?
C19 C21 1.386(4) 2 ?
C19 C20 1.395(3) . ?
C19 H19 0.9400 . ?
C20 C21 1.399(4) . ?
C21 C19 1.386(4) 2 ?
C21 H21 0.9400 . ?
C22 C23 1.550(3) . ?
C24 C25 1.552(3) . ?
N7 C26 1.116(4) . ?
C26 C27 1.493(4) . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N1 Ag1 Ag2 N5 3.3(3) . . . . ?
N4 Ag1 Ag2 N5 151.4(3) 1_666 . . . ?
O3 Ag1 Ag2 N5 -152.7(6) . . . . ?
O1 Ag1 Ag2 N5 -107.6(3) . . . . ?
N1 Ag1 Ag2 N3 -149.84(11) . . . 1_666 ?
N4 Ag1 Ag2 N3 -1.79(11) 1_666 . . 1_666 ?
O3 Ag1 Ag2 N3 54.1(6) . . . 1_666 ?
O1 Ag1 Ag2 N3 99.25(10) . . . 1_666 ?
N1 Ag1 Ag2 N2 2.70(10) . . . . ?
N4 Ag1 Ag2 N2 150.75(10) 1_666 . . . ?
O3 Ag1 Ag2 N2 -153.3(6) . . . . ?
O1 Ag1 Ag2 N2 -108.21(10) . . . . ?
N1 Ag1 Ag2 O2 111.54(11) . . . . ?
N4 Ag1 Ag2 O2 -100.41(11) 1_666 . . . ?
O3 Ag1 Ag2 O2 -44.5(6) . . . . ?
O1 Ag1 Ag2 O2 0.63(10) . . . . ?
N4 Ag1 N1 C1 151.9(2) 1_666 . . . ?
O3 Ag1 N1 C1 1.8(3) . . . . ?
O1 Ag1 N1 C1 -105.5(3) . . . . ?
Ag2 Ag1 N1 C1 -173.1(3) . . . . ?
N4 Ag1 N1 N2 -39.6(2) 1_666 . . . ?
O3 Ag1 N1 N2 170.3(2) . . . . ?
O1 Ag1 N1 N2 63.0(2) . . . . ?
Ag2 Ag1 N1 N2 -4.60(17) . . . . ?
C1 N1 N2 C4 0.9(4) . . . . ?
Ag1 N1 N2 C4 -168.6(2) . . . . ?
C1 N1 N2 Ag2 176.0(2) . . . . ?
Ag1 N1 N2 Ag2 6.5(2) . . . . ?
N5 Ag2 N2 C4 -9.6(3) . . . . ?
N3 Ag2 N2 C4 -159.9(2) 1_666 . . . ?
O2 Ag2 N2 C4 97.4(2) . . . . ?
Ag1 Ag2 N2 C4 170.2(3) . . . . ?
N5 Ag2 N2 N1 175.5(2) . . . . ?
N3 Ag2 N2 N1 25.3(2) 1_666 . . . ?
O2 Ag2 N2 N1 -77.5(2) . . . . ?
Ag1 Ag2 N2 N1 -4.62(17) . . . . ?
C11 N3 N4 C14 -1.0(4) . . . . ?
Ag2 N3 N4 C14 -171.1(2) 1_444 . . . ?
C11 N3 N4 Ag1 165.8(2) . . . 1_444 ?
Ag2 N3 N4 Ag1 -4.3(3) 1_444 . . 1_444 ?
N3 Ag2 N5 C15 -1.8(4) 1_666 . . . ?
N2 Ag2 N5 C15 -150.1(3) . . . . ?
O2 Ag2 N5 C15 103.9(3) . . . . ?
Ag1 Ag2 N5 C15 -150.7(3) . . . . ?
N3 Ag2 N5 N6 177.6(2) 1_666 . . . ?
N2 Ag2 N5 N6 29.3(2) . . . . ?
O2 Ag2 N5 N6 -76.7(2) . . . . ?
Ag1 Ag2 N5 N6 28.7(5) . . . . ?
C15 N5 N6 C18 -0.6(5) . . . . ?
Ag2 N5 N6 C18 -180.0(2) . . . . ?
N1 Ag1 O1 C22 -67.8(3) . . . . ?
N4 Ag1 O1 C22 57.1(3) 1_666 . . . ?
O3 Ag1 O1 C22 166.1(3) . . . . ?
Ag2 Ag1 O1 C22 -6.4(3) . . . . ?
N5 Ag2 O2 C22 170.3(3) . . . . ?
N3 Ag2 O2 C22 -59.7(3) 1_666 . . . ?
N2 Ag2 O2 C22 65.1(3) . . . . ?
Ag1 Ag2 O2 C22 4.4(3) . . . . ?
N1 Ag1 O3 C24 37.9(3) . . . . ?
N4 Ag1 O3 C24 -115.9(3) 1_666 . . . ?
O1 Ag1 O3 C24 147.9(3) . . . . ?
Ag2 Ag1 O3 C24 -168.4(4) . . . . ?
N2 N1 C1 C2 -2.2(5) . . . . ?
Ag1 N1 C1 C2 165.8(2) . . . . ?
N1 C1 C2 C3 0.8(5) . . . . ?
C1 C2 C3 C4 1.7(4) . . . . ?
C1 C2 C3 C5 -176.0(3) . . . . ?
N1 N2 C4 C3 1.8(5) . . . . ?
Ag2 N2 C4 C3 -172.8(2) . . . . ?
C2 C3 C4 N2 -3.0(4) . . . . ?
C5 C3 C4 N2 174.7(3) . . . . ?
C2 C3 C5 C6 22.6(5) . . . . ?
C4 C3 C5 C6 -154.9(3) . . . . ?
C2 C3 C5 C10 -159.6(3) . . . . ?
C4 C3 C5 C10 22.9(4) . . . . ?
C10 C5 C6 C7 -0.6(5) . . . . ?
C3 C5 C6 C7 177.3(3) . . . . ?
C5 C6 C7 C8 0.7(5) . . . . ?
C6 C7 C8 C9 -0.4(5) . . . . ?
C6 C7 C8 C13 -179.1(3) . . . . ?
C7 C8 C9 C10 0.0(5) . . . . ?
C13 C8 C9 C10 178.7(3) . . . . ?
C8 C9 C10 C5 0.1(5) . . . . ?
C6 C5 C10 C9 0.1(5) . . . . ?
C3 C5 C10 C9 -177.7(3) . . . . ?
N4 N3 C11 C12 -0.5(5) . . . . ?
Ag2 N3 C11 C12 168.5(3) 1_444 . . . ?
N3 C11 C12 C13 1.6(6) . . . . ?
C11 C12 C13 C14 -1.2(5) . . . . ?
C11 C12 C13 C8 179.6(3) . . . . ?
C7 C8 C13 C12 160.8(3) . . . . ?
C9 C8 C13 C12 -17.8(5) . . . . ?
C7 C8 C13 C14 -18.4(5) . . . . ?
C9 C8 C13 C14 163.0(3) . . . . ?
N3 N4 C14 C13 1.3(5) . . . . ?
Ag1 N4 C14 C13 -163.9(2) 1_444 . . . ?
C12 C13 C14 N4 -0.2(5) . . . . ?
C8 C13 C14 N4 179.0(3) . . . . ?
N6 N5 C15 C16 0.3(6) . . . . ?
Ag2 N5 C15 C16 179.7(3) . . . . ?
N5 C15 C16 C17 -0.2(6) . . . . ?
C15 C16 C17 C18 0.4(5) . . . . ?
C15 C16 C17 C20 178.3(3) . . . . ?
N5 N6 C18 C17 0.8(5) . . . . ?
C16 C17 C18 N6 -0.7(5) . . . . ?
C20 C17 C18 N6 -178.6(3) . . . . ?
C21 C19 C20 C21 -0.3(5) 2 . . . ?
C21 C19 C20 C17 -179.8(3) 2 . . . ?
C16 C17 C20 C19 -18.2(5) . . . . ?
C18 C17 C20 C19 159.5(3) . . . . ?
C16 C17 C20 C21 162.3(3) . . . . ?
C18 C17 C20 C21 -20.0(5) . . . . ?
C19 C20 C21 C19 0.3(5) . . . 2 ?
C17 C20 C21 C19 179.8(3) . . . 2 ?
Ag1 O1 C22 O2 13.7(5) . . . . ?
Ag1 O1 C22 C23 -171.35(18) . . . . ?
Ag2 O2 C22 O1 -12.3(5) . . . . ?
Ag2 O2 C22 C23 172.71(19) . . . . ?
O1 C22 C23 F3 148.2(5) . . . . ?
O2 C22 C23 F3 -35.9(6) . . . . ?
O1 C22 C23 F2 -90.8(5) . . . . ?
O2 C22 C23 F2 85.2(4) . . . . ?
O1 C22 C23 F1 27.5(4) . . . . ?
O2 C22 C23 F1 -156.6(4) . . . . ?
Ag1 O3 C24 O4 -3.3(5) . . . . ?
Ag1 O3 C24 C25 173.1(2) . . . . ?
O3 C24 C25 F5 -117.4(7) . . . . ?
O4 C24 C25 F5 59.6(6) . . . . ?
O3 C24 C25 F6 4.0(7) . . . . ?
O4 C24 C25 F6 -179.0(6) . . . . ?
O3 C24 C25 F4 122.6(7) . . . . ?
O4 C24 C25 F4 -60.4(7) . . . . ?
