#------------------------------------------------------------------------------
#$Date: 2016-03-26 00:20:33 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180073 $
#$URL: svn://www.crystallography.net/cod/cif/7/05/19/7051944.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7051944
loop_
_publ_author_name
'Degtyarenko, Anna S.'
'Solntsev, Pavlo V.'
'Krautscheid, Harald'
'Rusanov, Eduard B.'
'Chernega, Alexander N.'
'Domasevitch, Konstantin V.'
_publ_section_title
;
 Copper(i) and silver(i) coordination frameworks involving extended
 bipyridazine bridges
;
_journal_issue                   11
_journal_name_full               'New Journal of Chemistry'
_journal_page_first              1910
_journal_paper_doi               10.1039/b801231h
_journal_volume                  32
_journal_year                    2008
_chemical_formula_sum            'C48 H44 Ag4 Cl6 N12 O12 S4'
_chemical_formula_weight         1753.37
_chemical_name_systematic
;
Silver(I) Methanesulfonate 4:3 complex with
1,4-bi(pyridazin-4-yl)benzene, solvate with 2 Chloroform
;
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      14
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 99.346(5)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   19.3101(19)
_cell_length_b                   17.3714(15)
_cell_length_c                   18.1903(15)
_cell_measurement_reflns_used    10705
_cell_measurement_temperature    213(2)
_cell_measurement_theta_max      25.35
_cell_measurement_theta_min      3.81
_cell_volume                     6020.8(9)
_computing_cell_refinement       'SMART-NT (Bruker, 1998)'
_computing_data_collection       'SMART-NT (Bruker, 1998)'
_computing_data_reduction        'SMART-NT (Bruker, 1998)'
_computing_molecular_graphics    'Diamond 2.1e (Brandenburg, 1999)'
_computing_publication_material  'WinGX 1.700.00 (Farrugia, 1999)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      213(2)
_diffrn_measured_fraction_theta_full 0.972
_diffrn_measured_fraction_theta_max 0.972
_diffrn_measurement_device_type
'Siemens SMART CCD area-detector diffractometer'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0680
_diffrn_reflns_av_sigmaI/netI    0.1031
_diffrn_reflns_limit_h_max       19
_diffrn_reflns_limit_h_min       -23
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -20
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_number            25245
_diffrn_reflns_theta_full        25.35
_diffrn_reflns_theta_max         25.35
_diffrn_reflns_theta_min         3.81
_diffrn_standards_decay_%        20
_exptl_absorpt_coefficient_mu    1.757
_exptl_absorpt_correction_T_max  0.7202
_exptl_absorpt_correction_T_min  0.6484
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   'SADABS (Sheldrick, 1996)'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.934
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             3464
_exptl_crystal_size_max          0.27
_exptl_crystal_size_mid          0.21
_exptl_crystal_size_min          0.20
_refine_diff_density_max         0.982
_refine_diff_density_min         -1.874
_refine_diff_density_rms         0.144
_refine_ls_extinction_coef       0.0011(2)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.088
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     713
_refine_ls_number_reflns         10705
_refine_ls_number_restraints     14
_refine_ls_restrained_S_all      1.088
_refine_ls_R_factor_all          0.1191
_refine_ls_R_factor_gt           0.0932
_refine_ls_shift/su_max          0.004
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0850P)²+40.2604P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2418
_refine_ls_wR_factor_ref         0.2555
_reflns_number_gt                7019
_reflns_number_total             10705
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b801231h.txt
_cod_data_source_block           (6)
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               7051944
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.25729(4) 0.13552(5) 0.25530(4) 0.0495(3) Uani 1 1 d . . .
Ag2 Ag 0.38938(4) 0.02106(7) 0.34088(5) 0.0630(3) Uani 1 1 d . . .
Ag3 Ag 0.23864(5) -0.07180(6) 0.24021(5) 0.0585(3) Uani 1 1 d . . .
Ag4 Ag 0.10674(4) 0.05295(7) 0.15644(5) 0.0637(3) Uani 1 1 d . . .
S1 S 0.3638(2) 0.2431(2) 0.4052(3) 0.0899(13) Uani 1 1 d . . .
S2 S 0.4034(2) -0.1597(2) 0.2584(2) 0.0867(13) Uani 1 1 d . . .
S3 S 0.0663(2) -0.1335(3) 0.2119(3) 0.1028(17) Uani 1 1 d . . .
N1 N 0.3449(4) 0.1168(4) 0.1935(4) 0.0382(17) Uani 1 1 d . . .
N2 N 0.3944(4) 0.0690(5) 0.2236(4) 0.0393(18) Uani 1 1 d . . .
N3 N 0.8043(5) -0.0224(6) -0.0959(5) 0.058(2) Uani 1 1 d . . .
N4 N 0.7558(4) 0.0291(5) -0.1243(4) 0.044(2) Uani 1 1 d . . .
N5 N 0.2955(4) -0.0021(5) 0.3956(4) 0.0408(18) Uani 1 1 d . . .
N6 N 0.2390(4) -0.0412(4) 0.3607(4) 0.0403(19) Uani 1 1 d . . .
N7 N -0.1661(4) -0.1255(5) 0.6857(4) 0.0425(19) Uani 1 1 d . . .
N8 N -0.1101(4) -0.0878(5) 0.7205(4) 0.0388(18) Uani 1 1 d . . .
N9 N 0.4955(5) 0.0714(8) 0.4022(6) 0.075(3) Uani 1 1 d . . .
N10 N 0.5055(7) 0.0948(8) 0.4712(7) 0.093(4) Uani 1 1 d . . .
N11 N 0.9984(5) 0.3930(7) 0.6060(6) 0.073(3) Uani 1 1 d . . .
N12 N 0.9692(10) 0.4027(11) 0.5354(9) 0.138(7) Uani 1 1 d . . .
C1 C 0.3525(5) 0.1505(6) 0.1329(5) 0.047(2) Uani 1 1 d . . .
H1 H 0.3176 0.1858 0.1128 0.056 Uiso 1 1 calc R . .
C2 C 0.4086(5) 0.1392(6) 0.0939(6) 0.049(3) Uani 1 1 d . . .
H2 H 0.4105 0.1650 0.0489 0.058 Uiso 1 1 calc R . .
C3 C 0.4600(5) 0.0899(6) 0.1234(5) 0.039(2) Uani 1 1 d . . .
C4 C 0.4502(4) 0.0547(6) 0.1895(5) 0.039(2) Uani 1 1 d . . .
H4 H 0.4841 0.0193 0.2115 0.047 Uiso 1 1 calc R . .
C5 C 0.7995(6) -0.0554(12) -0.0307(6) 0.100(6) Uani 1 1 d . . .
H5 H 0.8333 -0.0920 -0.0109 0.120 Uiso 1 1 calc R . .
C6 C 0.7455(6) -0.0369(10) 0.0087(6) 0.080(5) Uani 1 1 d . . .
H6 H 0.7440 -0.0597 0.0553 0.096 Uiso 1 1 calc R . .
C7 C 0.6948(5) 0.0145(7) -0.0206(5) 0.045(2) Uani 1 1 d . . .
C8 C 0.7032(5) 0.0449(6) -0.0888(5) 0.040(2) Uani 1 1 d . . .
H8 H 0.6688 0.0794 -0.1116 0.048 Uiso 1 1 calc R . .
C9 C 0.5203(5) 0.0723(6) 0.0877(5) 0.039(2) Uani 1 1 d . . .
C10 C 0.5529(5) 0.0017(6) 0.0983(5) 0.041(2) Uani 1 1 d . . .
H10 H 0.5363 -0.0349 0.1294 0.049 Uiso 1 1 calc R . .
C11 C 0.6103(5) -0.0162(6) 0.0636(6) 0.045(2) Uani 1 1 d . . .
H11 H 0.6327 -0.0641 0.0727 0.054 Uiso 1 1 calc R . .
C12 C 0.6342(5) 0.0347(6) 0.0167(5) 0.036(2) Uani 1 1 d . . .
C13 C 0.5993(6) 0.1054(6) 0.0039(7) 0.060(3) Uani 1 1 d . . .
H13 H 0.6144 0.1412 -0.0289 0.072 Uiso 1 1 calc R . .
C14 C 0.5446(6) 0.1225(6) 0.0381(7) 0.059(3) Uani 1 1 d . . .
H14 H 0.5219 0.1702 0.0281 0.070 Uiso 1 1 calc R . .
C15 C 0.2966(5) 0.0179(7) 0.4663(5) 0.049(3) Uani 1 1 d . . .
H15 H 0.3370 0.0423 0.4916 0.059 Uiso 1 1 calc R . .
C16 C 0.2419(5) 0.0048(7) 0.5042(5) 0.053(3) Uani 1 1 d . . .
H16 H 0.2439 0.0224 0.5534 0.064 Uiso 1 1 calc R . .
C17 C 0.1841(5) -0.0346(5) 0.4690(5) 0.039(2) Uani 1 1 d . . .
C18 C 0.1853(5) -0.0553(6) 0.3953(6) 0.045(2) Uani 1 1 d . . .
H18 H 0.1459 -0.0805 0.3688 0.054 Uiso 1 1 calc R . .
C19 C -0.1651(5) -0.1536(6) 0.6204(6) 0.049(3) Uani 1 1 d . . .
H19 H -0.2040 -0.1824 0.5978 0.059 Uiso 1 1 calc R . .
C20 C -0.1088(6) -0.1435(7) 0.5809(6) 0.055(3) Uani 1 1 d . . .
H20 H -0.1106 -0.1638 0.5327 0.066 Uiso 1 1 calc R . .
C21 C -0.0522(5) -0.1040(6) 0.6141(5) 0.045(2) Uani 1 1 d . . .
C22 C -0.0550(5) -0.0772(6) 0.6867(5) 0.044(2) Uani 1 1 d . . .
H22 H -0.0160 -0.0506 0.7123 0.053 Uiso 1 1 calc R . .
C23 C 0.1226(4) -0.0514(5) 0.5070(5) 0.035(2) Uani 1 1 d . . .
C24 C 0.1061(5) -0.0043(6) 0.5616(5) 0.046(2) Uani 1 1 d . . .
H24 H 0.1337 0.0395 0.5755 0.055 Uiso 1 1 calc R . .
C25 C 0.0493(5) -0.0202(6) 0.5968(5) 0.042(2) Uani 1 1 d . . .
H25 H 0.0373 0.0137 0.6329 0.051 Uiso 1 1 calc R . .
C26 C 0.0095(5) -0.0874(6) 0.5782(5) 0.044(2) Uani 1 1 d . . .
C27 C 0.0240(5) -0.1344(6) 0.5207(6) 0.050(3) Uani 1 1 d . . .
H27 H -0.0041 -0.1777 0.5060 0.060 Uiso 1 1 calc R . .
C28 C 0.0811(5) -0.1164(6) 0.4852(6) 0.045(2) Uani 1 1 d . . .
H28 H 0.0916 -0.1479 0.4465 0.054 Uiso 1 1 calc R . .
C29 C 0.5457(6) 0.0743(13) 0.3635(7) 0.116(8) Uani 1 1 d . . .
H29 H 0.5435 0.0457 0.3193 0.139 Uiso 1 1 calc R . .
C30 C 0.6006(8) 0.1188(17) 0.3879(10) 0.154(11) Uani 1 1 d . . .
H30 H 0.6331 0.1262 0.3553 0.185 Uiso 1 1 calc R . .
C31 C 0.6147(6) 0.1554(8) 0.4566(6) 0.062(3) Uani 1 1 d . . .
C32 C 0.5660(7) 0.1379(8) 0.4997(7) 0.066(3) Uani 1 1 d . . .
H32 H 0.5725 0.1547 0.5494 0.079 Uiso 1 1 calc R . .
C33 C 0.9696(7) 0.3451(11) 0.6510(7) 0.087(5) Uani 1 1 d . . .
H33 H 0.9927 0.3356 0.6997 0.104 Uiso 1 1 calc R . .
C34 C 0.9104(7) 0.3124(12) 0.6269(8) 0.102(6) Uani 1 1 d . . .
H34 H 0.8901 0.2819 0.6604 0.123 Uiso 1 1 calc R . .
C35 C 0.8741(6) 0.3197(7) 0.5533(7) 0.059(3) Uani 1 1 d . . .
C36 C 0.9073(8) 0.3649(9) 0.5081(8) 0.086(5) Uani 1 1 d . . .
H36 H 0.8877 0.3704 0.4576 0.103 Uiso 1 1 calc R . .
C37 C 0.6806(6) 0.1988(7) 0.4815(6) 0.057(3) Uani 1 1 d . . .
C38 C 0.7060(6) 0.2078(7) 0.5560(7) 0.064(3) Uani 1 1 d . . .
H38 H 0.6809 0.1867 0.5914 0.077 Uiso 1 1 calc R . .
C39 C 0.7678(6) 0.2474(7) 0.5802(6) 0.061(3) Uani 1 1 d . . .
H39 H 0.7843 0.2525 0.6316 0.073 Uiso 1 1 calc R . .
C40 C 0.8058(6) 0.2798(7) 0.5288(7) 0.059(3) Uani 1 1 d . . .
C41 C 0.7793(7) 0.2702(8) 0.4550(7) 0.071(3) Uani 1 1 d . . .
H41 H 0.8036 0.2923 0.4195 0.085 Uiso 1 1 calc R . .
C42 C 0.7189(6) 0.2299(9) 0.4300(7) 0.073(4) Uani 1 1 d . . .
H42 H 0.7035 0.2233 0.3786 0.087 Uiso 1 1 calc R . .
C43 C 0.4127(13) 0.2709(12) 0.3377(13) 0.145(9) Uani 1 1 d . . .
H43A H 0.4458 0.2305 0.3308 0.218 Uiso 1 1 calc R . .
H43B H 0.4382 0.3178 0.3534 0.218 Uiso 1 1 calc R . .
H43C H 0.3816 0.2800 0.2910 0.218 Uiso 1 1 calc R . .
C44 C 0.4414(14) -0.2489(11) 0.2887(14) 0.171(12) Uani 1 1 d . . .
H44A H 0.4228 -0.2659 0.3324 0.257 Uiso 1 1 calc R . .
H44B H 0.4919 -0.2431 0.3010 0.257 Uiso 1 1 calc R . .
H44C H 0.4303 -0.2866 0.2493 0.257 Uiso 1 1 calc R . .
C45 C 0.0177(13) -0.2155(12) 0.1755(12) 0.150(10) Uani 1 1 d . . .
H45A H 0.0342 -0.2325 0.1305 0.226 Uiso 1 1 calc R . .
H45B H -0.0317 -0.2023 0.1638 0.226 Uiso 1 1 calc R . .
H45C H 0.0240 -0.2566 0.2121 0.226 Uiso 1 1 calc R . .
O1 O 0.3329(6) 0.1696(6) 0.3828(6) 0.098(3) Uani 1 1 d . . .
O2 O 0.4158(7) 0.2357(9) 0.4735(8) 0.141(5) Uani 1 1 d . . .
O3 O 0.3168(7) 0.3012(7) 0.4161(9) 0.132(5) Uani 1 1 d . . .
O4 O 0.4128(11) -0.1142(9) 0.3224(7) 0.165(7) Uani 1 1 d . . .
O5 O 0.3260(7) -0.1702(8) 0.2340(10) 0.142(5) Uani 1 1 d . . .
O6 O 0.4309(7) -0.1363(7) 0.1949(7) 0.117(4) Uani 1 1 d . . .
O7 O 0.1351(9) -0.1569(9) 0.2221(13) 0.175(8) Uani 1 1 d . . .
O8 O 0.0620(13) -0.0770(10) 0.1533(10) 0.194(9) Uani 1 1 d . . .
O9 O 0.0428(9) -0.1099(11) 0.2760(8) 0.180(8) Uani 1 1 d . . .
S4 S 0.1485(8) 0.2588(9) 0.1060(10) 0.155(9) Uani 0.50 1 d PD . .
C46 C 0.102(2) 0.295(2) 0.1748(16) 0.093(4) Uani 0.50 1 d PD . .
O10 O 0.1863(10) 0.1914(10) 0.1347(11) 0.093(4) Uani 0.50 1 d PD . .
O11 O 0.0924(9) 0.2409(11) 0.0447(11) 0.093(4) Uani 0.50 1 d PD . .
O12 O 0.1918(10) 0.3212(9) 0.0876(13) 0.093(4) Uani 0.50 1 d PD . .
S4A S 0.1655(5) 0.2744(6) 0.1267(6) 0.071(3) Uani 0.50 1 d PD . .
C46A C 0.116(3) 0.291(3) 0.1988(19) 0.131(6) Uani 0.50 1 d PD . .
O10A O 0.2268(9) 0.2381(12) 0.1677(12) 0.131(6) Uani 0.50 1 d PD . .
O11A O 0.1234(12) 0.2237(11) 0.0748(14) 0.131(6) Uani 0.50 1 d PD . .
O12A O 0.1810(11) 0.3466(9) 0.0933(15) 0.131(6) Uani 0.50 1 d PD . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 Ag1 N7 166.8(3) . 3_556 ?
N1 Ag1 O10A 84.1(5) . . ?
N7 Ag1 O10A 104.6(5) 3_556 . ?
N1 Ag1 O10 88.1(5) . . ?
N7 Ag1 O10 95.0(5) 3_556 . ?
O10A Ag1 O10 28.0(6) . . ?
N5 Ag2 N2 129.4(3) . . ?
N5 Ag2 N9 124.4(3) . . ?
N2 Ag2 N9 98.1(3) . . ?
N5 Ag2 O4 94.0(5) . . ?
N2 Ag2 O4 100.7(4) . . ?
N9 Ag2 O4 105.1(6) . . ?
N4 Ag3 N6 147.0(3) 3_655 . ?
N4 Ag3 O5 92.8(5) 3_655 . ?
N6 Ag3 O5 108.7(5) . . ?
N4 Ag3 O7 103.4(6) 3_655 . ?
N6 Ag3 O7 98.4(5) . . ?
O5 Ag3 O7 97.3(5) . . ?
N3 Ag4 N8 129.3(3) 3_655 3_556 ?
N3 Ag4 N11 127.4(4) 3_655 4_465 ?
N8 Ag4 N11 99.1(4) 3_556 4_465 ?
N3 Ag4 O8 93.8(7) 3_655 . ?
N8 Ag4 O8 102.8(5) 3_556 . ?
N11 Ag4 O8 94.1(7) 4_465 . ?
O3 S1 O1 115.7(8) . . ?
O3 S1 O2 108.3(9) . . ?
O1 S1 O2 110.9(9) . . ?
O3 S1 C43 109.9(11) . . ?
O1 S1 C43 107.2(8) . . ?
O2 S1 C43 104.2(12) . . ?
O4 S2 O6 120.5(11) . . ?
O4 S2 O5 107.7(11) . . ?
O6 S2 O5 106.4(9) . . ?
O4 S2 C44 104.3(11) . . ?
O6 S2 C44 108.4(8) . . ?
O5 S2 C44 109.2(12) . . ?
O7 S3 O9 114.7(13) . . ?
O7 S3 O8 103.8(13) . . ?
O9 S3 O8 115.8(13) . . ?
O7 S3 C45 104.8(11) . . ?
O9 S3 C45 109.1(9) . . ?
O8 S3 C45 107.9(11) . . ?
C1 N1 N2 118.1(7) . . ?
C1 N1 Ag1 125.3(6) . . ?
N2 N1 Ag1 116.6(5) . . ?
N1 N2 C4 120.2(7) . . ?
N1 N2 Ag2 118.4(5) . . ?
C4 N2 Ag2 121.0(6) . . ?
C5 N3 N4 119.1(9) . . ?
C5 N3 Ag4 120.2(8) . 3_655 ?
N4 N3 Ag4 120.7(6) . 3_655 ?
C8 N4 N3 119.8(8) . . ?
C8 N4 Ag3 123.2(7) . 3_655 ?
N3 N4 Ag3 116.4(6) . 3_655 ?
C15 N5 N6 118.0(8) . . ?
C15 N5 Ag2 119.7(7) . . ?
N6 N5 Ag2 122.1(5) . . ?
C18 N6 N5 120.4(8) . . ?
C18 N6 Ag3 122.8(7) . . ?
N5 N6 Ag3 116.7(5) . . ?
C19 N7 N8 119.4(8) . . ?
C19 N7 Ag1 123.4(7) . 3_556 ?
N8 N7 Ag1 117.2(5) . 3_556 ?
C22 N8 N7 119.9(8) . . ?
C22 N8 Ag4 121.0(6) . 3_556 ?
N7 N8 Ag4 118.8(5) . 3_556 ?
C29 N9 N10 120.5(11) . . ?
C29 N9 Ag2 115.7(8) . . ?
N10 N9 Ag2 123.9(8) . . ?
N9 N10 C32 120.2(12) . . ?
N12 N11 C33 121.0(12) . . ?
N12 N11 Ag4 122.7(11) . 4_666 ?
C33 N11 Ag4 116.0(8) . 4_666 ?
N11 N12 C36 119.6(15) . . ?
N1 C1 C2 125.3(9) . . ?
N1 C1 H1 117.4 . . ?
C2 C1 H1 117.4 . . ?
C3 C2 C1 117.8(9) . . ?
C3 C2 H2 121.1 . . ?
C1 C2 H2 121.1 . . ?
C2 C3 C4 115.3(8) . . ?
C2 C3 C9 123.0(8) . . ?
C4 C3 C9 121.6(9) . . ?
N2 C4 C3 123.2(9) . . ?
N2 C4 H4 118.4 . . ?
C3 C4 H4 118.4 . . ?
N3 C5 C6 121.6(12) . . ?
N3 C5 H5 119.2 . . ?
C6 C5 H5 119.2 . . ?
C7 C6 C5 119.8(11) . . ?
C7 C6 H6 120.1 . . ?
C5 C6 H6 120.1 . . ?
C6 C7 C8 114.7(9) . . ?
C6 C7 C12 122.8(9) . . ?
C8 C7 C12 122.4(9) . . ?
N4 C8 C7 125.0(10) . . ?
N4 C8 H8 117.5 . . ?
C7 C8 H8 117.5 . . ?
C10 C9 C14 117.1(8) . . ?
C10 C9 C3 120.4(8) . . ?
C14 C9 C3 122.4(9) . . ?
C9 C10 C11 120.9(9) . . ?
C9 C10 H10 119.6 . . ?
C11 C10 H10 119.6 . . ?
C12 C11 C10 120.9(9) . . ?
C12 C11 H11 119.6 . . ?
C10 C11 H11 119.6 . . ?
C11 C12 C13 118.1(8) . . ?
C11 C12 C7 120.3(9) . . ?
C13 C12 C7 121.5(8) . . ?
C14 C13 C12 120.6(10) . . ?
C14 C13 H13 119.7 . . ?
C12 C13 H13 119.7 . . ?
C13 C14 C9 122.3(10) . . ?
C13 C14 H14 118.8 . . ?
C9 C14 H14 118.8 . . ?
N5 C15 C16 123.5(10) . . ?
N5 C15 H15 118.3 . . ?
C16 C15 H15 118.3 . . ?
C15 C16 C17 118.7(9) . . ?
C15 C16 H16 120.7 . . ?
C17 C16 H16 120.7 . . ?
C16 C17 C18 116.0(8) . . ?
C16 C17 C23 121.7(8) . . ?
C18 C17 C23 122.2(9) . . ?
N6 C18 C17 123.2(10) . . ?
N6 C18 H18 118.4 . . ?
C17 C18 H18 118.4 . . ?
N7 C19 C20 123.5(11) . . ?
N7 C19 H19 118.2 . . ?
C20 C19 H19 118.2 . . ?
C21 C20 C19 118.2(10) . . ?
C21 C20 H20 120.9 . . ?
C19 C20 H20 120.9 . . ?
C20 C21 C22 115.9(8) . . ?
C20 C21 C26 123.8(9) . . ?
C22 C21 C26 120.3(9) . . ?
N8 C22 C21 123.0(9) . . ?
N8 C22 H22 118.5 . . ?
C21 C22 H22 118.5 . . ?
C24 C23 C28 119.8(8) . . ?
C24 C23 C17 121.1(9) . . ?
C28 C23 C17 119.1(8) . . ?
C23 C24 C25 120.8(10) . . ?
C23 C24 H24 119.6 . . ?
C25 C24 H24 119.6 . . ?
C24 C25 C26 119.8(9) . . ?
C24 C25 H25 120.1 . . ?
C26 C25 H25 120.1 . . ?
C27 C26 C25 119.9(8) . . ?
C27 C26 C21 119.5(10) . . ?
C25 C26 C21 120.3(9) . . ?
C26 C27 C28 119.0(10) . . ?
C26 C27 H27 120.5 . . ?
C28 C27 H27 120.5 . . ?
C27 C28 C23 120.4(9) . . ?
C27 C28 H28 119.8 . . ?
C23 C28 H28 119.8 . . ?
N9 C29 C30 118.1(13) . . ?
N9 C29 H29 121.0 . . ?
C30 C29 H29 121.0 . . ?
C29 C30 C31 126.6(15) . . ?
C29 C30 H30 116.7 . . ?
C31 C30 H30 116.7 . . ?
C32 C31 C30 111.4(12) . . ?
C32 C31 C37 125.4(10) . . ?
C30 C31 C37 122.7(12) . . ?
C31 C32 N10 121.2(11) . . ?
C31 C32 H32 119.4 . . ?
N10 C32 H32 119.4 . . ?
C34 C33 N11 119.7(13) . . ?
C34 C33 H33 120.2 . . ?
N11 C33 H33 120.2 . . ?
C33 C34 C35 124.0(15) . . ?
C33 C34 H34 118.0 . . ?
C35 C34 H34 118.0 . . ?
C36 C35 C34 114.3(11) . . ?
C36 C35 C40 124.4(11) . . ?
C34 C35 C40 121.3(12) . . ?
C35 C36 N12 121.2(13) . . ?
C35 C36 H36 119.4 . . ?
N12 C36 H36 119.4 . . ?
C38 C37 C42 118.5(11) . . ?
C38 C37 C31 120.6(11) . . ?
C42 C37 C31 120.9(10) . . ?
C37 C38 C39 121.4(12) . . ?
C37 C38 H38 119.3 . . ?
C39 C38 H38 119.3 . . ?
C38 C39 C40 120.4(11) . . ?
C38 C39 H39 119.8 . . ?
C40 C39 H39 119.8 . . ?
C41 C40 C39 117.0(11) . . ?
C41 C40 C35 121.4(12) . . ?
C39 C40 C35 121.5(11) . . ?
C40 C41 C42 123.4(12) . . ?
C40 C41 H41 118.3 . . ?
C42 C41 H41 118.3 . . ?
C41 C42 C37 119.3(11) . . ?
C41 C42 H42 120.3 . . ?
C37 C42 H42 120.3 . . ?
S1 C43 H43A 109.5 . . ?
S1 C43 H43B 109.5 . . ?
H43A C43 H43B 109.5 . . ?
S1 C43 H43C 109.5 . . ?
H43A C43 H43C 109.5 . . ?
H43B C43 H43C 109.5 . . ?
S2 C44 H44A 109.5 . . ?
S2 C44 H44B 109.5 . . ?
H44A C44 H44B 109.5 . . ?
S2 C44 H44C 109.5 . . ?
H44A C44 H44C 109.5 . . ?
H44B C44 H44C 109.5 . . ?
S3 C45 H45A 109.5 . . ?
S3 C45 H45B 109.5 . . ?
H45A C45 H45B 109.5 . . ?
S3 C45 H45C 109.5 . . ?
H45A C45 H45C 109.5 . . ?
H45B C45 H45C 109.5 . . ?
S2 O4 Ag2 131.5(8) . . ?
S2 O5 Ag3 124.7(8) . . ?
S3 O7 Ag3 126.0(9) . . ?
S3 O8 Ag4 129.9(9) . . ?
O10 S4 O12 114.7(10) . . ?
O10 S4 O11 112.1(10) . . ?
O12 S4 O11 111.7(9) . . ?
O10 S4 C46 108.7(17) . . ?
O12 S4 C46 106(2) . . ?
O11 S4 C46 102.6(18) . . ?
S4 O10 Ag1 141.8(13) . . ?
O10A S4A O11A 113.6(9) . . ?
O10A S4A O12A 112.9(8) . . ?
O11A S4A O12A 112.9(9) . . ?
O10A S4A C46A 100.7(17) . . ?
O11A S4A C46A 106(3) . . ?
O12A S4A C46A 110(2) . . ?
S4A O10A Ag1 139.7(12) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 N1 2.202(7) . ?
Ag1 N7 2.213(7) 3_556 ?
Ag1 O10A 2.399(15) . ?
Ag1 O10 2.581(15) . ?
Ag2 N5 2.242(7) . ?
Ag2 N2 2.306(7) . ?
Ag2 N9 2.338(9) . ?
Ag2 O4 2.425(15) . ?
Ag3 N4 2.254(8) 3_655 ?
Ag3 N6 2.255(8) . ?
Ag3 O5 2.416(12) . ?
Ag3 O7 2.466(13) . ?
Ag4 N3 2.250(8) 3_655 ?
Ag4 N8 2.310(7) 3_556 ?
Ag4 N11 2.341(10) 4_465 ?
Ag4 O8 2.415(14) . ?
S1 O3 1.394(13) . ?
S1 O1 1.439(9) . ?
S1 O2 1.471(14) . ?
S1 C43 1.736(17) . ?
S2 O4 1.395(14) . ?
S2 O6 1.407(10) . ?
S2 O5 1.500(14) . ?
S2 C44 1.764(13) . ?
S3 O7 1.371(17) . ?
S3 O9 1.381(12) . ?
S3 O8 1.442(18) . ?
S3 C45 1.774(14) . ?
N1 C1 1.278(12) . ?
N1 N2 1.317(10) . ?
N2 C4 1.352(11) . ?
N3 C5 1.334(15) . ?
N3 N4 1.337(12) . ?
N3 Ag4 2.250(8) 3_655 ?
N4 C8 1.317(11) . ?
N4 Ag3 2.254(8) 3_655 ?
N5 C15 1.329(12) . ?
N5 N6 1.352(11) . ?
N6 C18 1.319(11) . ?
N7 C19 1.287(13) . ?
N7 N8 1.333(11) . ?
N7 Ag1 2.213(7) 3_556 ?
N8 C22 1.325(11) . ?
N8 Ag4 2.310(7) 3_556 ?
N9 C29 1.287(15) . ?
N9 N10 1.303(15) . ?
N10 C32 1.413(17) . ?
N11 N12 1.325(16) . ?
N11 C33 1.348(17) . ?
N11 Ag4 2.341(10) 4_666 ?
N12 C36 1.384(19) . ?
C1 C2 1.402(13) . ?
C1 H1 0.9400 . ?
C2 C3 1.353(14) . ?
C2 H2 0.9400 . ?
C3 C4 1.388(12) . ?
C3 C9 1.455(12) . ?
C4 H4 0.9400 . ?
C5 C6 1.396(15) . ?
C5 H5 0.9400 . ?
C6 C7 1.368(16) . ?
C6 H6 0.9400 . ?
C7 C8 1.382(13) . ?
C7 C12 1.487(12) . ?
C8 H8 0.9400 . ?
C9 C10 1.378(13) . ?
C9 C14 1.390(13) . ?
C10 C11 1.397(13) . ?
C10 H10 0.9400 . ?
C11 C12 1.360(13) . ?
C11 H11 0.9400 . ?
C12 C13 1.401(15) . ?
C13 C14 1.345(13) . ?
C13 H13 0.9400 . ?
C14 H14 0.9400 . ?
C15 C16 1.370(13) . ?
C15 H15 0.9400 . ?
C16 C17 1.376(14) . ?
C16 H16 0.9400 . ?
C17 C18 1.391(13) . ?
C17 C23 1.497(11) . ?
C18 H18 0.9400 . ?
C19 C20 1.407(13) . ?
C19 H19 0.9400 . ?
C20 C21 1.346(16) . ?
C20 H20 0.9400 . ?
C21 C22 1.410(13) . ?
C21 C26 1.477(12) . ?
C22 H22 0.9400 . ?
C23 C24 1.364(13) . ?
C23 C28 1.404(13) . ?
C24 C25 1.386(13) . ?
C24 H24 0.9400 . ?
C25 C26 1.407(14) . ?
C25 H25 0.9400 . ?
C26 C27 1.391(13) . ?
C27 C28 1.401(13) . ?
C27 H27 0.9400 . ?
C28 H28 0.9400 . ?
C29 C30 1.33(2) . ?
C29 H29 0.9400 . ?
C30 C31 1.390(19) . ?
C30 H30 0.9400 . ?
C31 C32 1.353(17) . ?
C31 C37 1.486(16) . ?
C32 H32 0.9400 . ?
C33 C34 1.288(17) . ?
C33 H33 0.9400 . ?
C34 C35 1.413(17) . ?
C34 H34 0.9400 . ?
C35 C36 1.369(19) . ?
C35 C40 1.492(16) . ?
C36 H36 0.9400 . ?
C37 C38 1.374(15) . ?
C37 C42 1.393(17) . ?
C38 C39 1.386(16) . ?
C38 H38 0.9400 . ?
C39 C40 1.398(17) . ?
C39 H39 0.9400 . ?
C40 C41 1.368(16) . ?
C41 C42 1.373(17) . ?
C41 H41 0.9400 . ?
C42 H42 0.9400 . ?
C43 H43A 0.9700 . ?
C43 H43B 0.9700 . ?
C43 H43C 0.9700 . ?
C44 H44A 0.9700 . ?
C44 H44B 0.9700 . ?
C44 H44C 0.9700 . ?
C45 H45A 0.9700 . ?
C45 H45B 0.9700 . ?
C45 H45C 0.9700 . ?
S4 O10 1.433(9) . ?
S4 O12 1.442(9) . ?
S4 O11 1.456(10) . ?
S4 C46 1.770(10) . ?
S4A O10A 1.439(9) . ?
S4A O11A 1.441(9) . ?
S4A O12A 1.446(9) . ?
S4A C46A 1.766(10) . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N7 Ag1 N1 C1 124.0(13) 3_556 . . . ?
O10A Ag1 N1 C1 -8.0(10) . . . . ?
O10 Ag1 N1 C1 19.7(9) . . . . ?
N7 Ag1 N1 N2 -58.8(15) 3_556 . . . ?
O10A Ag1 N1 N2 169.2(9) . . . . ?
O10 Ag1 N1 N2 -163.1(8) . . . . ?
C1 N1 N2 C4 -2.2(13) . . . . ?
Ag1 N1 N2 C4 -179.6(7) . . . . ?
C1 N1 N2 Ag2 171.5(7) . . . . ?
Ag1 N1 N2 Ag2 -5.9(8) . . . . ?
N5 Ag2 N2 N1 30.0(8) . . . . ?
N9 Ag2 N2 N1 -118.6(7) . . . . ?
O4 Ag2 N2 N1 134.3(8) . . . . ?
N5 Ag2 N2 C4 -156.4(7) . . . . ?
N9 Ag2 N2 C4 55.0(8) . . . . ?
O4 Ag2 N2 C4 -52.1(9) . . . . ?
C5 N3 N4 C8 -1.9(17) . . . . ?
Ag4 N3 N4 C8 178.4(7) 3_655 . . . ?
C5 N3 N4 Ag3 -173.4(11) . . . 3_655 ?
Ag4 N3 N4 Ag3 6.9(10) 3_655 . . 3_655 ?
N2 Ag2 N5 C15 -136.8(7) . . . . ?
N9 Ag2 N5 C15 4.6(10) . . . . ?
O4 Ag2 N5 C15 115.9(8) . . . . ?
N2 Ag2 N5 N6 48.1(8) . . . . ?
N9 Ag2 N5 N6 -170.5(7) . . . . ?
O4 Ag2 N5 N6 -59.2(7) . . . . ?
C15 N5 N6 C18 3.3(13) . . . . ?
Ag2 N5 N6 C18 178.4(7) . . . . ?
C15 N5 N6 Ag3 178.9(7) . . . . ?
Ag2 N5 N6 Ag3 -6.0(9) . . . . ?
N4 Ag3 N6 C18 117.8(8) 3_655 . . . ?
O5 Ag3 N6 C18 -114.1(8) . . . . ?
O7 Ag3 N6 C18 -13.4(9) . . . . ?
N4 Ag3 N6 N5 -57.7(9) 3_655 . . . ?
O5 Ag3 N6 N5 70.4(7) . . . . ?
O7 Ag3 N6 N5 171.1(7) . . . . ?
C19 N7 N8 C22 2.5(13) . . . . ?
Ag1 N7 N8 C22 -177.3(7) 3_556 . . . ?
C19 N7 N8 Ag4 -171.4(7) . . . 3_556 ?
Ag1 N7 N8 Ag4 8.8(8) 3_556 . . 3_556 ?
N5 Ag2 N9 C29 173.9(13) . . . . ?
N2 Ag2 N9 C29 -35.3(14) . . . . ?
O4 Ag2 N9 C29 68.1(15) . . . . ?
N5 Ag2 N9 N10 -5.3(14) . . . . ?
N2 Ag2 N9 N10 145.6(12) . . . . ?
O4 Ag2 N9 N10 -111.0(12) . . . . ?
C29 N9 N10 C32 13(2) . . . . ?
Ag2 N9 N10 C32 -167.7(10) . . . . ?
C33 N11 N12 C36 2(3) . . . . ?
Ag4 N11 N12 C36 175.7(13) 4_666 . . . ?
N2 N1 C1 C2 2.2(16) . . . . ?
Ag1 N1 C1 C2 179.3(8) . . . . ?
N1 C1 C2 C3 -1.6(17) . . . . ?
C1 C2 C3 C4 1.0(15) . . . . ?
C1 C2 C3 C9 178.9(10) . . . . ?
N1 N2 C4 C3 1.9(14) . . . . ?
Ag2 N2 C4 C3 -171.7(7) . . . . ?
C2 C3 C4 N2 -1.2(15) . . . . ?
C9 C3 C4 N2 -179.1(9) . . . . ?
N4 N3 C5 C6 -1(2) . . . . ?
Ag4 N3 C5 C6 179.1(13) 3_655 . . . ?
N3 C5 C6 C7 2(3) . . . . ?
C5 C6 C7 C8 -1(2) . . . . ?
C5 C6 C7 C12 177.5(13) . . . . ?
N3 N4 C8 C7 3.2(15) . . . . ?
Ag3 N4 C8 C7 174.0(8) 3_655 . . . ?
C6 C7 C8 N4 -1.7(16) . . . . ?
C12 C7 C8 N4 179.9(9) . . . . ?
C2 C3 C9 C10 -150.9(10) . . . . ?
C4 C3 C9 C10 26.8(14) . . . . ?
C2 C3 C9 C14 24.7(16) . . . . ?
C4 C3 C9 C14 -157.6(10) . . . . ?
C14 C9 C10 C11 3.4(15) . . . . ?
C3 C9 C10 C11 179.2(9) . . . . ?
C9 C10 C11 C12 -1.9(16) . . . . ?
C10 C11 C12 C13 -0.3(15) . . . . ?
C10 C11 C12 C7 -179.3(9) . . . . ?
C6 C7 C12 C11 -26.5(16) . . . . ?
C8 C7 C12 C11 151.8(10) . . . . ?
C6 C7 C12 C13 154.6(12) . . . . ?
C8 C7 C12 C13 -27.1(15) . . . . ?
C11 C12 C13 C14 1.0(17) . . . . ?
C7 C12 C13 C14 179.9(11) . . . . ?
C12 C13 C14 C9 0.6(19) . . . . ?
C10 C9 C14 C13 -2.8(17) . . . . ?
C3 C9 C14 C13 -178.5(11) . . . . ?
N6 N5 C15 C16 -3.8(16) . . . . ?
Ag2 N5 C15 C16 -179.0(9) . . . . ?
N5 C15 C16 C17 3.5(18) . . . . ?
C15 C16 C17 C18 -2.6(15) . . . . ?
C15 C16 C17 C23 179.7(10) . . . . ?
N5 N6 C18 C17 -2.8(14) . . . . ?
Ag3 N6 C18 C17 -178.1(7) . . . . ?
C16 C17 C18 N6 2.4(15) . . . . ?
C23 C17 C18 N6 -179.9(9) . . . . ?
N8 N7 C19 C20 -3.5(15) . . . . ?
Ag1 N7 C19 C20 176.2(8) 3_556 . . . ?
N7 C19 C20 C21 1.8(16) . . . . ?
C19 C20 C21 C22 0.8(15) . . . . ?
C19 C20 C21 C26 -178.2(9) . . . . ?
N7 N8 C22 C21 0.2(15) . . . . ?
Ag4 N8 C22 C21 173.9(7) 3_556 . . . ?
C20 C21 C22 N8 -1.7(15) . . . . ?
C26 C21 C22 N8 177.3(9) . . . . ?
C16 C17 C23 C24 28.2(14) . . . . ?
C18 C17 C23 C24 -149.4(10) . . . . ?
C16 C17 C23 C28 -152.4(10) . . . . ?
C18 C17 C23 C28 30.0(14) . . . . ?
C28 C23 C24 C25 0.9(15) . . . . ?
C17 C23 C24 C25 -179.8(9) . . . . ?
C23 C24 C25 C26 2.5(15) . . . . ?
C24 C25 C26 C27 -4.9(15) . . . . ?
C24 C25 C26 C21 -178.6(9) . . . . ?
C20 C21 C26 C27 -23.8(15) . . . . ?
C22 C21 C26 C27 157.2(10) . . . . ?
C20 C21 C26 C25 149.8(11) . . . . ?
C22 C21 C26 C25 -29.1(14) . . . . ?
C25 C26 C27 C28 3.8(15) . . . . ?
C21 C26 C27 C28 177.6(9) . . . . ?
C26 C27 C28 C23 -0.5(16) . . . . ?
C24 C23 C28 C27 -1.9(15) . . . . ?
C17 C23 C28 C27 178.7(9) . . . . ?
N10 N9 C29 C30 -17(3) . . . . ?
Ag2 N9 C29 C30 163.6(18) . . . . ?
N9 C29 C30 C31 9(4) . . . . ?
C29 C30 C31 C32 3(3) . . . . ?
C29 C30 C31 C37 175(2) . . . . ?
C30 C31 C32 N10 -7(2) . . . . ?
C37 C31 C32 N10 -178.6(12) . . . . ?
N9 N10 C32 C31 0(2) . . . . ?
N12 N11 C33 C34 -5(3) . . . . ?
Ag4 N11 C33 C34 -179.2(14) 4_666 . . . ?
N11 C33 C34 C35 4(3) . . . . ?
C33 C34 C35 C36 0(2) . . . . ?
C33 C34 C35 C40 179.6(16) . . . . ?
C34 C35 C36 N12 -3(2) . . . . ?
C40 C35 C36 N12 177.3(15) . . . . ?
N11 N12 C36 C35 2(3) . . . . ?
C32 C31 C37 C38 16.9(19) . . . . ?
C30 C31 C37 C38 -154.1(18) . . . . ?
C32 C31 C37 C42 -164.4(14) . . . . ?
C30 C31 C37 C42 25(2) . . . . ?
C42 C37 C38 C39 0.6(19) . . . . ?
C31 C37 C38 C39 179.3(11) . . . . ?
C37 C38 C39 C40 0.4(18) . . . . ?
C38 C39 C40 C41 -0.1(18) . . . . ?
C38 C39 C40 C35 -177.3(11) . . . . ?
C36 C35 C40 C41 16.1(19) . . . . ?
C34 C35 C40 C41 -163.3(14) . . . . ?
C36 C35 C40 C39 -166.9(13) . . . . ?
C34 C35 C40 C39 13.6(18) . . . . ?
C39 C40 C41 C42 -1(2) . . . . ?
C35 C40 C41 C42 175.9(13) . . . . ?
C40 C41 C42 C37 2(2) . . . . ?
C38 C37 C42 C41 -2(2) . . . . ?
C31 C37 C42 C41 179.5(12) . . . . ?
O6 S2 O4 Ag2 52.0(19) . . . . ?
O5 S2 O4 Ag2 -70.2(18) . . . . ?
C44 S2 O4 Ag2 173.8(15) . . . . ?
N5 Ag2 O4 S2 107.0(17) . . . . ?
N2 Ag2 O4 S2 -24.3(18) . . . . ?
N9 Ag2 O4 S2 -125.8(16) . . . . ?
O4 S2 O5 Ag3 38.1(13) . . . . ?
O6 S2 O5 Ag3 -92.4(11) . . . . ?
C44 S2 O5 Ag3 150.7(11) . . . . ?
N4 Ag3 O5 S2 90.9(11) 3_655 . . . ?
N6 Ag3 O5 S2 -63.7(12) . . . . ?
O7 Ag3 O5 S2 -165.2(12) . . . . ?
O9 S3 O7 Ag3 -77.0(18) . . . . ?
O8 S3 O7 Ag3 50.3(16) . . . . ?
C45 S3 O7 Ag3 163.4(13) . . . . ?
N4 Ag3 O7 S3 -77.7(16) 3_655 . . . ?
N6 Ag3 O7 S3 77.4(16) . . . . ?
O5 Ag3 O7 S3 -172.4(15) . . . . ?
O7 S3 O8 Ag4 -73.2(19) . . . . ?
O9 S3 O8 Ag4 53(2) . . . . ?
C45 S3 O8 Ag4 176.0(16) . . . . ?
N3 Ag4 O8 S3 105.3(19) 3_655 . . . ?
N8 Ag4 O8 S3 -26(2) 3_556 . . . ?
N11 Ag4 O8 S3 -126.7(19) 4_465 . . . ?
O12 S4 O10 Ag1 80(2) . . . . ?
O11 S4 O10 Ag1 -151.1(16) . . . . ?
C46 S4 O10 Ag1 -38(3) . . . . ?
N1 Ag1 O10 S4 -124.4(18) . . . . ?
N7 Ag1 O10 S4 68.4(18) 3_556 . . . ?
O11A S4A O10A Ag1 -62(3) . . . . ?
O12A S4A O10A Ag1 167(2) . . . . ?
C46A S4A O10A Ag1 50(3) . . . . ?
