#------------------------------------------------------------------------------
#$Date: 2016-03-26 00:22:36 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180075 $
#$URL: svn://www.crystallography.net/cod/cif/7/05/21/7052173.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7052173
loop_
_publ_author_name
'Seneclauze, Julie Batcha'
'Retailleau, Pascal'
'Ziessel, Raymond'
_publ_section_title
;
 Design and preparation of neutral substituted fluorene- and
 carbazole-based platinum(ii)--acetylide complexes
;
_journal_issue                   8
_journal_name_full               'New Journal of Chemistry'
_journal_page_first              1412
_journal_paper_doi               10.1039/b702374j
_journal_volume                  31
_journal_year                    2007
_chemical_formula_moiety         'C33 H24 N2 Pt'
_chemical_formula_sum            'C33 H24 N2 Pt'
_chemical_formula_weight         643.63
_chemical_name_systematic
;
?
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   difmap
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 96.684(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   7.2707(6)
_cell_length_b                   12.3313(10)
_cell_length_c                   28.699(2)
_cell_measurement_temperature    100(2)
_cell_volume                     2555.6(3)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'PLATON (Spek, 2004)'
_computing_publication_material  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'Bruker SHELXTL'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full .987
_diffrn_measured_fraction_theta_max .987
_diffrn_measurement_device_type  'APEX II CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0215
_diffrn_reflns_av_sigmaI/netI    0.0181
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -9
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       41
_diffrn_reflns_limit_l_min       -41
_diffrn_reflns_number            31394
_diffrn_reflns_theta_full        31.00
_diffrn_reflns_theta_max         31.00
_diffrn_reflns_theta_min         1.43
_exptl_absorpt_coefficient_mu    5.515
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    1.673
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             1256
_exptl_crystal_size_max          0.15
_exptl_crystal_size_mid          0.12
_exptl_crystal_size_min          0.10
_refine_diff_density_max         2.223
_refine_diff_density_min         -2.334
_refine_diff_density_rms         .274
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.581
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     327
_refine_ls_number_reflns         8052
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.581
_refine_ls_R_factor_all          0.0423
_refine_ls_R_factor_gt           0.0399
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0254P)²+9.6112P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1001
_refine_ls_wR_factor_ref         0.1008
_reflns_number_gt                7626
_reflns_number_total             8052
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b702374J.txt
_cod_data_source_block           jbs3942a
_cod_original_sg_symbol_H-M      P21/c
_cod_database_code               7052173
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.75566(2) 0.814337(13) 0.037160(6) 0.01715(5) Uani 1 1 d . . .
N2 N 0.7619(5) 0.9500(3) 0.00020(13) 0.0163(7) Uani 1 1 d . . .
N1 N 0.6693(6) 0.9208(3) 0.08461(14) 0.0220(8) Uani 1 1 d . . .
C1 C 0.8449(6) 0.7542(4) -0.02364(15) 0.0189(8) Uani 1 1 d . . .
C16 C 0.7160(6) 1.0434(4) 0.02054(17) 0.0196(8) Uani 1 1 d . . .
C12 C 0.8157(6) 0.9447(4) -0.04322(16) 0.0210(9) Uani 1 1 d . . .
C7 C 0.6624(6) 1.0280(4) 0.06806(16) 0.0184(8) Uani 1 1 d . . .
C13 C 0.8211(7) 1.0391(4) -0.06927(17) 0.0246(10) Uani 1 1 d . . .
H7 H 0.8555 1.0371 -0.0995 0.030 Uiso 1 1 calc R . .
C10 C 0.5578(7) 0.9832(4) 0.15557(17) 0.0246(9) Uani 1 1 d . . .
H14 H 0.5221 0.9677 0.1849 0.030 Uiso 1 1 calc R . .
C3 C 0.9293(7) 0.8079(5) -0.09929(17) 0.0296(11) Uani 1 1 d . . .
H4 H 0.9395 0.8617 -0.1216 0.036 Uiso 1 1 calc R . .
C2 C 0.8629(7) 0.8339(4) -0.05672(17) 0.0223(9) Uani 1 1 d . . .
C11 C 0.6152(6) 0.9000(4) 0.12815(16) 0.0208(8) Uani 1 1 d . . .
H15 H 0.6172 0.8292 0.1393 0.025 Uiso 1 1 calc R . .
C8 C 0.6060(7) 1.1119(4) 0.09581(18) 0.0239(9) Uani 1 1 d . . .
H12 H 0.6039 1.1830 0.0849 0.029 Uiso 1 1 calc R . .
C9 C 0.5533(8) 1.0892(4) 0.13961(18) 0.0272(10) Uani 1 1 d . . .
H13 H 0.5151 1.1448 0.1582 0.033 Uiso 1 1 calc R . .
C15 C 0.7193(7) 1.1396(4) -0.00474(18) 0.0243(9) Uani 1 1 d . . .
H9 H 0.6852 1.2049 0.0081 0.029 Uiso 1 1 calc R . .
C14 C 0.7748(7) 1.1362(5) -0.04965(19) 0.0283(11) Uani 1 1 d . . .
H8 H 0.7806 1.2001 -0.0666 0.034 Uiso 1 1 calc R . .
C6 C 0.8951(7) 0.6506(5) -0.03299(19) 0.0288(10) Uani 1 1 d . . .
H2 H 0.8855 0.5968 -0.0107 0.035 Uiso 1 1 calc R . .
C5 C 0.9608(8) 0.6235(5) -0.0754(2) 0.0334(12) Uani 1 1 d . . .
H3 H 0.9919 0.5521 -0.0815 0.040 Uiso 1 1 calc R . .
C18 C 0.8426(6) 0.5160(4) 0.17560(16) 0.0188(8) Uani 1 1 d . . .
H29 H 0.9453 0.5614 0.1794 0.023 Uiso 1 1 calc R . .
C24 C 0.8269(7) 0.3302(4) 0.27663(16) 0.0200(8) Uani 1 1 d . . .
C22 C 0.5594(6) 0.4543(4) 0.13031(16) 0.0198(8) Uani 1 1 d . . .
H27 H 0.4753 0.4585 0.1034 0.024 Uiso 1 1 calc R . .
C23 C 0.9375(7) 0.4179(4) 0.25550(16) 0.0193(8) Uani 1 1 d . . .
C29 C 0.6676(7) 0.3028(3) 0.24659(16) 0.0190(8) Uani 1 1 d . . .
C19 C 0.8157(6) 0.4402(4) 0.20975(15) 0.0165(7) Uani 1 1 d . . .
C20 C 0.6595(6) 0.3722(3) 0.20467(15) 0.0168(8) Uani 1 1 d . . .
C21 C 0.5298(6) 0.3793(4) 0.16490(16) 0.0184(8) Uani 1 1 d . . .
H26 H 0.4257 0.3348 0.1616 0.022 Uiso 1 1 calc R . .
C17 C 0.7144(7) 0.5240(4) 0.13525(16) 0.0186(8) Uani 1 1 d . . .
C26 C 0.7459(9) 0.1957(5) 0.3311(2) 0.0342(13) Uani 1 1 d . . .
H21 H 0.7705 0.1597 0.3596 0.041 Uiso 1 1 calc R . .
C28 C 0.5485(7) 0.2223(4) 0.25837(19) 0.0254(10) Uani 1 1 d . . .
H23 H 0.4431 0.2047 0.2382 0.031 Uiso 1 1 calc R . .
C27 C 0.5895(9) 0.1682(4) 0.3009(2) 0.0327(13) Uani 1 1 d . . .
H22 H 0.5117 0.1134 0.3092 0.039 Uiso 1 1 calc R . .
C25 C 0.8665(8) 0.2762(4) 0.31932(17) 0.0276(10) Uani 1 1 d . . .
H20 H 0.9716 0.2936 0.3396 0.033 Uiso 1 1 calc R . .
C30 C 0.9611(8) 0.5197(4) 0.28661(18) 0.0274(10) Uani 1 1 d . . .
H16A H 0.8417 0.5450 0.2930 0.041 Uiso 1 1 calc R . .
H16B H 1.0217 0.5754 0.2707 0.041 Uiso 1 1 calc R . .
H16C H 1.0346 0.5023 0.3156 0.041 Uiso 1 1 calc R . .
C31 C 1.1275(7) 0.3744(4) 0.24582(18) 0.0259(10) Uani 1 1 d . . .
H17A H 1.1940 0.4304 0.2317 0.039 Uiso 1 1 calc R . .
H17B H 1.1106 0.3135 0.2249 0.039 Uiso 1 1 calc R . .
H17C H 1.1965 0.3522 0.2748 0.039 Uiso 1 1 calc R . .
C4 C 0.9790(8) 0.7034(6) -0.10819(18) 0.0345(13) Uani 1 1 d . . .
H31 H 1.0249 0.6864 -0.1362 0.041 Uiso 1 1 calc R . .
C2" C 0.7357(7) 0.6078(4) 0.10170(16) 0.0210(9) Uani 1 1 d . . .
C1" C 0.7488(6) 0.6837(4) 0.07556(16) 0.0202(8) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C .0033 .0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H .0000 .0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N .0061 .0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C1" Pt1 N2 178.00(17) . . ?
C1" Pt1 N1 97.11(17) . . ?
N2 Pt1 N1 80.95(16) . . ?
C1" Pt1 C1 102.20(19) . . ?
N2 Pt1 C1 79.74(17) . . ?
N1 Pt1 C1 160.69(18) . . ?
C12 N2 C16 123.5(4) . . ?
C12 N2 Pt1 118.7(3) . . ?
C16 N2 Pt1 117.8(3) . . ?
C11 N1 C7 118.7(4) . . ?
C11 N1 Pt1 128.9(3) . . ?
C7 N1 Pt1 112.4(3) . . ?
C6 C1 C2 118.8(4) . . ?
C6 C1 Pt1 128.2(4) . . ?
C2 C1 Pt1 112.9(3) . . ?
N2 C16 C15 118.8(4) . . ?
N2 C16 C7 113.3(4) . . ?
C15 C16 C7 127.9(5) . . ?
N2 C12 C13 119.1(5) . . ?
N2 C12 C2 112.9(4) . . ?
C13 C12 C2 128.0(4) . . ?
C8 C7 N1 120.4(4) . . ?
C8 C7 C16 124.0(4) . . ?
N1 C7 C16 115.6(4) . . ?
C14 C13 C12 118.9(5) . . ?
C14 C13 H7 120.5 . . ?
C12 C13 H7 120.5 . . ?
C9 C10 C11 120.6(5) . . ?
C9 C10 H14 119.7 . . ?
C11 C10 H14 119.7 . . ?
C4 C3 C2 120.2(5) . . ?
C4 C3 H4 119.9 . . ?
C2 C3 H4 119.9 . . ?
C1 C2 C3 120.3(5) . . ?
C1 C2 C12 115.8(4) . . ?
C3 C2 C12 123.8(5) . . ?
N1 C11 C10 120.9(5) . . ?
N1 C11 H15 119.5 . . ?
C10 C11 H15 119.5 . . ?
C9 C8 C7 120.0(5) . . ?
C9 C8 H12 120.0 . . ?
C7 C8 H12 120.0 . . ?
C10 C9 C8 119.5(5) . . ?
C10 C9 H13 120.2 . . ?
C8 C9 H13 120.2 . . ?
C16 C15 C14 118.7(5) . . ?
C16 C15 H9 120.7 . . ?
C14 C15 H9 120.7 . . ?
C13 C14 C15 120.9(5) . . ?
C13 C14 H8 119.5 . . ?
C15 C14 H8 119.5 . . ?
C1 C6 C5 121.4(5) . . ?
C1 C6 H2 119.3 . . ?
C5 C6 H2 119.3 . . ?
C4 C5 C6 119.5(6) . . ?
C4 C5 H3 120.3 . . ?
C6 C5 H3 120.3 . . ?
C19 C18 C17 119.7(4) . . ?
C19 C18 H29 120.1 . . ?
C17 C18 H29 120.1 . . ?
C25 C24 C29 119.7(5) . . ?
C25 C24 C23 128.9(5) . . ?
C29 C24 C23 111.4(4) . . ?
C21 C22 C17 121.4(4) . . ?
C21 C22 H27 119.3 . . ?
C17 C22 H27 119.3 . . ?
C24 C23 C19 101.1(4) . . ?
C24 C23 C31 110.7(4) . . ?
C19 C23 C31 110.6(4) . . ?
C24 C23 C30 112.2(4) . . ?
C19 C23 C30 111.5(4) . . ?
C31 C23 C30 110.3(4) . . ?
C28 C29 C24 121.2(4) . . ?
C28 C29 C20 130.5(5) . . ?
C24 C29 C20 108.3(4) . . ?
C18 C19 C20 120.6(4) . . ?
C18 C19 C23 128.1(4) . . ?
C20 C19 C23 111.3(4) . . ?
C21 C20 C19 120.6(4) . . ?
C21 C20 C29 131.5(4) . . ?
C19 C20 C29 107.9(4) . . ?
C22 C21 C20 118.6(4) . . ?
C22 C21 H26 120.7 . . ?
C20 C21 H26 120.7 . . ?
C18 C17 C22 119.1(4) . . ?
C18 C17 C2" 119.4(4) . . ?
C22 C17 C2" 121.3(4) . . ?
C27 C26 C25 121.1(5) . . ?
C27 C26 H21 119.4 . . ?
C25 C26 H21 119.4 . . ?
C29 C28 C27 118.7(5) . . ?
C29 C28 H23 120.6 . . ?
C27 C28 H23 120.6 . . ?
C26 C27 C28 120.4(5) . . ?
C26 C27 H22 119.8 . . ?
C28 C27 H22 119.8 . . ?
C26 C25 C24 118.8(5) . . ?
C26 C25 H20 120.6 . . ?
C24 C25 H20 120.6 . . ?
C23 C30 H16A 109.5 . . ?
C23 C30 H16B 109.5 . . ?
H16A C30 H16B 109.5 . . ?
C23 C30 H16C 109.5 . . ?
H16A C30 H16C 109.5 . . ?
H16B C30 H16C 109.5 . . ?
C23 C31 H17A 109.5 . . ?
C23 C31 H17B 109.5 . . ?
H17A C31 H17B 109.5 . . ?
C23 C31 H17C 109.5 . . ?
H17A C31 H17C 109.5 . . ?
H17B C31 H17C 109.5 . . ?
C3 C4 C5 119.8(5) . . ?
C3 C4 H31 120.1 . . ?
C5 C4 H31 120.1 . . ?
C1" C2" C17 175.4(5) . . ?
C2" C1" Pt1 174.5(4) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 C1" 1.956(5) . ?
Pt1 N2 1.984(4) . ?
Pt1 N1 2.042(4) . ?
Pt1 C1 2.068(4) . ?
N2 C12 1.350(6) . ?
N2 C16 1.352(6) . ?
N1 C11 1.377(6) . ?
N1 C7 1.404(6) . ?
C1 C6 1.364(7) . ?
C1 C2 1.383(7) . ?
C16 C15 1.392(6) . ?
C16 C7 1.473(6) . ?
C12 C13 1.387(6) . ?
C12 C2 1.472(7) . ?
C7 C8 1.396(7) . ?
C13 C14 1.381(8) . ?
C13 H7 0.9300 . ?
C10 C9 1.384(8) . ?
C10 C11 1.387(7) . ?
C10 H14 0.9300 . ?
C3 C4 1.370(9) . ?
C3 C2 1.402(7) . ?
C3 H4 0.9300 . ?
C11 H15 0.9300 . ?
C8 C9 1.385(7) . ?
C8 H12 0.9300 . ?
C9 H13 0.9300 . ?
C15 C14 1.395(8) . ?
C15 H9 0.9300 . ?
C14 H8 0.9300 . ?
C6 C5 1.399(7) . ?
C6 H2 0.9300 . ?
C5 C4 1.379(9) . ?
C5 H3 0.9300 . ?
C18 C19 1.385(6) . ?
C18 C17 1.403(7) . ?
C18 H29 0.9300 . ?
C24 C25 1.395(6) . ?
C24 C29 1.402(7) . ?
C24 C23 1.515(7) . ?
C22 C21 1.392(6) . ?
C22 C17 1.411(6) . ?
C22 H27 0.9300 . ?
C23 C19 1.521(6) . ?
C23 C31 1.537(7) . ?
C23 C30 1.539(7) . ?
C29 C28 1.385(7) . ?
C29 C20 1.472(6) . ?
C19 C20 1.405(6) . ?
C20 C21 1.397(6) . ?
C21 H26 0.9300 . ?
C17 C2" 1.434(6) . ?
C26 C27 1.388(10) . ?
C26 C25 1.391(8) . ?
C26 H21 0.9300 . ?
C28 C27 1.394(7) . ?
C28 H23 0.9300 . ?
C27 H22 0.9300 . ?
C25 H20 0.9300 . ?
C30 H16A 0.9600 . ?
C30 H16B 0.9600 . ?
C30 H16C 0.9600 . ?
C31 H17A 0.9600 . ?
C31 H17B 0.9600 . ?
C31 H17C 0.9600 . ?
C4 H31 0.9300 . ?
C2" C1" 1.210(6) . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C1" Pt1 N2 C12 166(5) . . . . ?
N1 Pt1 N2 C12 179.8(3) . . . . ?
C1 Pt1 N2 C12 -0.2(3) . . . . ?
C1" Pt1 N2 C16 -12(5) . . . . ?
N1 Pt1 N2 C16 1.4(3) . . . . ?
C1 Pt1 N2 C16 -178.6(3) . . . . ?
C1" Pt1 N1 C11 -3.3(4) . . . . ?
N2 Pt1 N1 C11 177.2(4) . . . . ?
C1 Pt1 N1 C11 177.1(5) . . . . ?
C1" Pt1 N1 C7 178.6(3) . . . . ?
N2 Pt1 N1 C7 -0.9(3) . . . . ?
C1 Pt1 N1 C7 -1.0(7) . . . . ?
C1" Pt1 C1 C6 -3.1(5) . . . . ?
N2 Pt1 C1 C6 176.4(5) . . . . ?
N1 Pt1 C1 C6 176.4(5) . . . . ?
C1" Pt1 C1 C2 -179.3(3) . . . . ?
N2 Pt1 C1 C2 0.2(3) . . . . ?
N1 Pt1 C1 C2 0.3(7) . . . . ?
C12 N2 C16 C15 1.7(7) . . . . ?
Pt1 N2 C16 C15 -180.0(3) . . . . ?
C12 N2 C16 C7 -179.9(4) . . . . ?
Pt1 N2 C16 C7 -1.5(5) . . . . ?
C16 N2 C12 C13 -1.4(7) . . . . ?
Pt1 N2 C12 C13 -179.8(3) . . . . ?
C16 N2 C12 C2 178.4(4) . . . . ?
Pt1 N2 C12 C2 0.1(5) . . . . ?
C11 N1 C7 C8 1.6(6) . . . . ?
Pt1 N1 C7 C8 179.9(3) . . . . ?
C11 N1 C7 C16 -177.9(4) . . . . ?
Pt1 N1 C7 C16 0.4(5) . . . . ?
N2 C16 C7 C8 -178.8(4) . . . . ?
C15 C16 C7 C8 -0.5(7) . . . . ?
N2 C16 C7 N1 0.7(6) . . . . ?
C15 C16 C7 N1 178.9(4) . . . . ?
N2 C12 C13 C14 1.2(7) . . . . ?
C2 C12 C13 C14 -178.6(5) . . . . ?
C6 C1 C2 C3 0.9(7) . . . . ?
Pt1 C1 C2 C3 177.4(4) . . . . ?
C6 C1 C2 C12 -176.8(4) . . . . ?
Pt1 C1 C2 C12 -0.3(5) . . . . ?
C4 C3 C2 C1 -0.8(8) . . . . ?
C4 C3 C2 C12 176.7(5) . . . . ?
N2 C12 C2 C1 0.2(6) . . . . ?
C13 C12 C2 C1 180.0(5) . . . . ?
N2 C12 C2 C3 -177.5(4) . . . . ?
C13 C12 C2 C3 2.4(8) . . . . ?
C7 N1 C11 C10 -1.1(7) . . . . ?
Pt1 N1 C11 C10 -179.1(4) . . . . ?
C9 C10 C11 N1 0.2(7) . . . . ?
N1 C7 C8 C9 -1.2(7) . . . . ?
C16 C7 C8 C9 178.2(4) . . . . ?
C11 C10 C9 C8 0.2(8) . . . . ?
C7 C8 C9 C10 0.3(7) . . . . ?
N2 C16 C15 C14 -1.7(7) . . . . ?
C7 C16 C15 C14 -179.9(4) . . . . ?
C12 C13 C14 C15 -1.4(7) . . . . ?
C16 C15 C14 C13 1.6(7) . . . . ?
C2 C1 C6 C5 -1.1(8) . . . . ?
Pt1 C1 C6 C5 -177.1(4) . . . . ?
C1 C6 C5 C4 1.4(9) . . . . ?
C25 C24 C23 C19 -179.5(4) . . . . ?
C29 C24 C23 C19 2.0(5) . . . . ?
C25 C24 C23 C31 63.2(6) . . . . ?
C29 C24 C23 C31 -115.2(4) . . . . ?
C25 C24 C23 C30 -60.5(6) . . . . ?
C29 C24 C23 C30 121.0(4) . . . . ?
C25 C24 C29 C28 -0.3(7) . . . . ?
C23 C24 C29 C28 178.3(4) . . . . ?
C25 C24 C29 C20 179.7(4) . . . . ?
C23 C24 C29 C20 -1.7(5) . . . . ?
C17 C18 C19 C20 -0.9(6) . . . . ?
C17 C18 C19 C23 179.5(4) . . . . ?
C24 C23 C19 C18 178.0(4) . . . . ?
C31 C23 C19 C18 -64.7(6) . . . . ?
C30 C23 C19 C18 58.5(6) . . . . ?
C24 C23 C19 C20 -1.7(5) . . . . ?
C31 C23 C19 C20 115.7(4) . . . . ?
C30 C23 C19 C20 -121.1(4) . . . . ?
C18 C19 C20 C21 0.6(6) . . . . ?
C23 C19 C20 C21 -179.8(4) . . . . ?
C18 C19 C20 C29 -178.9(4) . . . . ?
C23 C19 C20 C29 0.8(5) . . . . ?
C28 C29 C20 C21 1.2(8) . . . . ?
C24 C29 C20 C21 -178.8(4) . . . . ?
C28 C29 C20 C19 -179.5(5) . . . . ?
C24 C29 C20 C19 0.6(5) . . . . ?
C17 C22 C21 C20 -1.4(7) . . . . ?
C19 C20 C21 C22 0.6(6) . . . . ?
C29 C20 C21 C22 179.9(4) . . . . ?
C19 C18 C17 C22 0.1(6) . . . . ?
C19 C18 C17 C2" 175.4(4) . . . . ?
C21 C22 C17 C18 1.1(7) . . . . ?
C21 C22 C17 C2" -174.1(4) . . . . ?
C24 C29 C28 C27 -0.1(7) . . . . ?
C20 C29 C28 C27 179.9(4) . . . . ?
C25 C26 C27 C28 -1.1(8) . . . . ?
C29 C28 C27 C26 0.8(7) . . . . ?
C27 C26 C25 C24 0.7(8) . . . . ?
C29 C24 C25 C26 0.0(7) . . . . ?
C23 C24 C25 C26 -178.3(4) . . . . ?
C2 C3 C4 C5 1.1(8) . . . . ?
C6 C5 C4 C3 -1.3(9) . . . . ?
C18 C17 C2" C1" -76(7) . . . . ?
C22 C17 C2" C1" 99(7) . . . . ?
C17 C2" C1" Pt1 -12(11) . . . . ?
N2 Pt1 C1" C2" 29(8) . . . . ?
N1 Pt1 C1" C2" 15(5) . . . . ?
C1 Pt1 C1" C2" -165(5) . . . . ?
