#------------------------------------------------------------------------------
#$Date: 2016-03-26 00:25:53 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180078 $
#$URL: svn://www.crystallography.net/cod/cif/7/05/24/7052402.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7052402
loop_
_publ_author_name
'Sumby, Christopher J.'
'Steel, Peter J.'
_publ_section_title
;
 An investigation of the coordination chemistry of the hexadentate
 ligand di-2-pyridylketone azine; the formation of a discrete
 tetranuclear complex with silver nitrate
;
_journal_issue                   8
_journal_name_full               'New Journal of Chemistry'
_journal_page_first              1077
_journal_paper_doi               10.1039/b400879k
_journal_volume                  29
_journal_year                    2005
_chemical_formula_moiety         '2(C44 H32 Ag4 N16 O12), 11(H2 O)'
_chemical_formula_sum            'C88 H86 Ag8 N32 O35'
_chemical_formula_weight         3014.85
_chemical_name_common            'Complex 4'
_chemical_name_systematic
;
?
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 95.5590(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   13.5851(12)
_cell_length_b                   16.1634(15)
_cell_length_c                   48.468(5)
_cell_measurement_reflns_used    7475
_cell_measurement_temperature    163(2)
_cell_measurement_theta_max      25.39
_cell_measurement_theta_min      2.26
_cell_volume                     10592.6(17)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      163(2)
_diffrn_measured_fraction_theta_full 0.991
_diffrn_measured_fraction_theta_max 0.991
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0887
_diffrn_reflns_av_sigmaI/netI    0.0942
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_k_min       -20
_diffrn_reflns_limit_l_max       60
_diffrn_reflns_limit_l_min       -60
_diffrn_reflns_number            131824
_diffrn_reflns_theta_full        26.35
_diffrn_reflns_theta_max         26.35
_diffrn_reflns_theta_min         1.52
_exptl_absorpt_coefficient_mu    1.545
_exptl_absorpt_correction_T_max  0.8484
_exptl_absorpt_correction_T_min  0.4380
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'Blessing, Acta Cryst. (1995) A51 33-38'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.890
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             5976
_exptl_crystal_size_max          0.64
_exptl_crystal_size_mid          0.35
_exptl_crystal_size_min          0.11
_refine_diff_density_max         1.217
_refine_diff_density_min         -0.701
_refine_diff_density_rms         0.110
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.023
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1509
_refine_ls_number_reflns         21434
_refine_ls_number_restraints     180
_refine_ls_restrained_S_all      1.039
_refine_ls_R_factor_all          0.1086
_refine_ls_R_factor_gt           0.0487
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0390P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0881
_refine_ls_wR_factor_ref         0.0990
_reflns_number_gt                12461
_reflns_number_total             21434
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b400879k.txt
_cod_data_source_block           pp
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_sg_symbol_H-M      P2(1)/c
_cod_database_code               7052402
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.31976(3) 0.24517(3) 0.196715(9) 0.03203(12) Uani 1 1 d . . .
Ag2 Ag 0.08318(4) 0.15946(3) 0.116561(9) 0.03447(13) Uani 1 1 d . . .
Ag3 Ag 0.25239(3) 0.44008(3) 0.139648(11) 0.03782(14) Uani 1 1 d . . .
Ag4 Ag 0.07934(4) 0.41153(3) 0.054732(10) 0.04247(14) Uani 1 1 d . . .
C1' C 0.3474(4) 0.2543(3) 0.13120(11) 0.0235(13) Uani 1 1 d . . .
C1 C 0.0939(4) 0.2710(3) 0.17246(12) 0.0246(14) Uani 1 1 d . . .
N2' N 0.2902(3) 0.2906(3) 0.11193(9) 0.0231(11) Uani 1 1 d . . .
N2 N 0.0744(3) 0.2880(3) 0.14663(9) 0.0246(11) Uani 1 1 d . . .
N3' N 0.2156(3) 0.2414(3) 0.09849(9) 0.0243(11) Uani 1 1 d . . .
N3 N 0.0859(3) 0.3719(3) 0.14002(9) 0.0238(11) Uani 1 1 d . . .
C4 C 0.0284(4) 0.3991(3) 0.11931(12) 0.0234(13) Uani 1 1 d . A .
C4' C 0.2011(4) 0.2503(3) 0.07206(12) 0.0248(13) Uani 1 1 d . A .
N11' N 0.3450(3) 0.1462(3) 0.16550(9) 0.0247(11) Uani 1 1 d . . .
N11 N 0.2062(3) 0.3333(3) 0.20801(9) 0.0279(12) Uani 1 1 d . . .
C12 C 0.1142(4) 0.3348(3) 0.19458(11) 0.0239(13) Uani 1 1 d . . .
C12' C 0.3463(4) 0.1640(3) 0.13825(11) 0.0210(13) Uani 1 1 d . . .
C13' C 0.3480(4) 0.1035(3) 0.11819(13) 0.0307(15) Uani 1 1 d . . .
H13A H 0.3487 0.1177 0.0992 0.037 Uiso 1 1 calc R . .
C13 C 0.0427(4) 0.3916(4) 0.20058(13) 0.0356(16) Uani 1 1 d . . .
H13B H -0.0204 0.3918 0.1903 0.043 Uiso 1 1 calc R . .
C14' C 0.3486(4) 0.0212(4) 0.12653(13) 0.0333(15) Uani 1 1 d . . .
H14A H 0.3497 -0.0219 0.1132 0.040 Uiso 1 1 calc R . .
C14 C 0.0646(5) 0.4479(4) 0.22173(13) 0.0354(16) Uani 1 1 d . . .
H14B H 0.0162 0.4862 0.2267 0.043 Uiso 1 1 calc R . .
C15' C 0.3476(4) 0.0028(4) 0.15411(13) 0.0341(16) Uani 1 1 d . . .
H15A H 0.3483 -0.0532 0.1602 0.041 Uiso 1 1 calc R . .
C15 C 0.1586(5) 0.4473(4) 0.23556(12) 0.0374(17) Uani 1 1 d . . .
H15B H 0.1759 0.4863 0.2499 0.045 Uiso 1 1 calc R . .
C16 C 0.2271(4) 0.3902(4) 0.22857(12) 0.0321(15) Uani 1 1 d . . .
H16A H 0.2912 0.3904 0.2384 0.039 Uiso 1 1 calc R . .
C16' C 0.3455(4) 0.0660(3) 0.17283(12) 0.0275(14) Uani 1 1 d . . .
H16B H 0.3443 0.0526 0.1919 0.033 Uiso 1 1 calc R . .
N21 N 0.0938(3) 0.1235(3) 0.16052(9) 0.0246(11) Uani 1 1 d . . .
N21' N 0.3964(3) 0.3838(3) 0.15461(9) 0.0274(12) Uani 1 1 d . . .
C22' C 0.4215(4) 0.3061(3) 0.14817(11) 0.0235(13) Uani 1 1 d . . .
C22 C 0.0949(4) 0.1820(3) 0.18064(12) 0.0237(14) Uani 1 1 d . . .
C23 C 0.0960(4) 0.1590(4) 0.20837(12) 0.0315(15) Uani 1 1 d . . .
H23A H 0.0940 0.2001 0.2223 0.038 Uiso 1 1 calc R . .
C23' C 0.5146(4) 0.2744(3) 0.15667(12) 0.0307(15) Uani 1 1 d . . .
H23B H 0.5309 0.2193 0.1520 0.037 Uiso 1 1 calc R . .
C24 C 0.1000(4) 0.0767(4) 0.21544(13) 0.0363(16) Uani 1 1 d . . .
H24A H 0.1011 0.0606 0.2343 0.044 Uiso 1 1 calc R . .
C24' C 0.5830(4) 0.3226(4) 0.17184(12) 0.0344(16) Uani 1 1 d . . .
H24B H 0.6470 0.3016 0.1777 0.041 Uiso 1 1 calc R . .
C25' C 0.5572(4) 0.4022(4) 0.17852(13) 0.0345(16) Uani 1 1 d . . .
H25A H 0.6032 0.4370 0.1890 0.041 Uiso 1 1 calc R . .
C25 C 0.1024(4) 0.0179(4) 0.19510(14) 0.0395(17) Uani 1 1 d . . .
H25B H 0.1070 -0.0392 0.1996 0.047 Uiso 1 1 calc R . .
C26 C 0.0981(4) 0.0445(4) 0.16780(13) 0.0332(16) Uani 1 1 d . . .
H26A H 0.0982 0.0040 0.1536 0.040 Uiso 1 1 calc R . .
C26' C 0.4641(4) 0.4304(4) 0.16988(13) 0.0360(16) Uani 1 1 d . . .
H26B H 0.4464 0.4849 0.1748 0.043 Uiso 1 1 calc R . .
N31' N 0.2354(3) 0.3755(3) 0.04736(10) 0.0290(12) Uani 1 1 d . A .
N31 N 0.1379(3) 0.5182(3) 0.11554(10) 0.0303(12) Uani 1 1 d . . .
C32' C 0.2688(4) 0.2995(3) 0.05587(11) 0.0222(13) Uani 1 1 d . . .
C32 C 0.0438(4) 0.4875(3) 0.11115(11) 0.0237(14) Uani 1 1 d . . .
C33 C -0.0362(4) 0.5374(3) 0.10235(11) 0.0273(14) Uani 1 1 d . . .
H33A H -0.1010 0.5148 0.0999 0.033 Uiso 1 1 calc R . .
C33' C 0.3602(4) 0.2683(4) 0.05103(11) 0.0275(14) Uani 1 1 d . A .
H33B H 0.3810 0.2152 0.0576 0.033 Uiso 1 1 calc R . .
C34 C -0.0208(5) 0.6203(4) 0.09711(12) 0.0360(16) Uani 1 1 d . . .
H34A H -0.0748 0.6553 0.0910 0.043 Uiso 1 1 calc R . .
C34' C 0.4209(4) 0.3176(4) 0.03613(12) 0.0337(15) Uani 1 1 d . . .
H34B H 0.4835 0.2978 0.0319 0.040 Uiso 1 1 calc R A .
C35 C 0.0736(5) 0.6510(4) 0.10087(13) 0.0367(16) Uani 1 1 d . . .
H35A H 0.0863 0.7076 0.0973 0.044 Uiso 1 1 calc R . .
C35' C 0.3895(5) 0.3944(4) 0.02767(12) 0.0352(16) Uani 1 1 d . A .
H35B H 0.4305 0.4290 0.0178 0.042 Uiso 1 1 calc R . .
C36' C 0.2968(5) 0.4214(4) 0.03360(12) 0.0367(16) Uani 1 1 d . . .
H36A H 0.2759 0.4750 0.0276 0.044 Uiso 1 1 calc R A .
C36 C 0.1495(5) 0.5989(4) 0.10988(13) 0.0362(16) Uani 1 1 d . . .
H36B H 0.2145 0.6211 0.1123 0.043 Uiso 1 1 calc R . .
N41' N 0.0575(3) 0.1588(3) 0.07107(9) 0.0281(12) Uani 1 1 d . A .
N41 N -0.0513(3) 0.3603(3) 0.07498(10) 0.0301(12) Uani 1 1 d . A .
C42 C -0.0519(4) 0.3527(3) 0.10280(12) 0.0288(15) Uani 1 1 d . . .
C42' C 0.1178(4) 0.2057(3) 0.05617(11) 0.0229(13) Uani 1 1 d . . .
C43 C -0.1236(4) 0.3099(3) 0.11521(13) 0.0311(15) Uani 1 1 d . A .
H43A H -0.1199 0.3047 0.1348 0.037 Uiso 1 1 calc R . .
C43' C 0.1034(4) 0.2106(4) 0.02780(12) 0.0311(15) Uani 1 1 d . A .
H43B H 0.1449 0.2446 0.0179 0.037 Uiso 1 1 calc R . .
C44' C 0.0281(4) 0.1658(4) 0.01374(13) 0.0407(17) Uani 1 1 d . . .
H44A H 0.0171 0.1690 -0.0059 0.049 Uiso 1 1 calc R A .
C44 C -0.2011(5) 0.2746(4) 0.09859(14) 0.0398(17) Uani 1 1 d . . .
H44B H -0.2525 0.2462 0.1066 0.048 Uiso 1 1 calc R A .
C45' C -0.0304(5) 0.1167(4) 0.02819(13) 0.0398(17) Uani 1 1 d . A .
H45A H -0.0811 0.0839 0.0188 0.048 Uiso 1 1 calc R . .
C45 C -0.2023(5) 0.2816(4) 0.07027(15) 0.0460(19) Uani 1 1 d . A .
H45B H -0.2547 0.2580 0.0584 0.055 Uiso 1 1 calc R . .
C46 C -0.1260(5) 0.3233(4) 0.05922(13) 0.0409(17) Uani 1 1 d . . .
H46A H -0.1264 0.3259 0.0396 0.049 Uiso 1 1 calc R A .
C46' C -0.0146(4) 0.1156(4) 0.05670(13) 0.0326(15) Uani 1 1 d . . .
H46B H -0.0568 0.0825 0.0667 0.039 Uiso 1 1 calc R A .
N100 N 0.5069(4) 0.2700(3) 0.23432(11) 0.0424(14) Uani 1 1 d D . .
O101 O 0.4831(3) 0.2057(3) 0.22102(9) 0.0496(13) Uani 1 1 d D . .
O102 O 0.4472(3) 0.3296(3) 0.23496(10) 0.0653(15) Uani 1 1 d D . .
O103 O 0.5915(3) 0.2748(3) 0.24709(11) 0.0710(16) Uani 1 1 d D . .
N105 N 0.2940(3) 0.6003(3) 0.17615(10) 0.0339(13) Uani 1 1 d D . .
O106 O 0.2498(3) 0.5381(2) 0.18342(9) 0.0510(13) Uani 1 1 d D . .
O107 O 0.3418(3) 0.5983(3) 0.15510(9) 0.0459(12) Uani 1 1 d D . .
O108 O 0.2898(3) 0.6654(2) 0.19031(9) 0.0492(12) Uani 1 1 d D . .
Ag5 Ag 0.81821(3) 0.83198(3) 0.191431(9) 0.03301(12) Uani 1 1 d . . .
Ag6 Ag 0.59099(4) 0.91506(3) 0.110310(9) 0.03345(12) Uani 1 1 d . . .
Ag7 Ag 0.73871(3) 0.63584(3) 0.136943(10) 0.03522(13) Uani 1 1 d . . .
Ag8 Ag 0.50673(4) 0.66810(3) 0.052466(10) 0.04019(14) Uani 1 1 d . . .
C51' C 0.8418(4) 0.8155(3) 0.12507(11) 0.0229(14) Uani 1 1 d . . .
C51 C 0.5895(4) 0.8109(3) 0.16811(12) 0.0254(14) Uani 1 1 d . . .
N52' N 0.7877(3) 0.7756(3) 0.10613(9) 0.0237(11) Uani 1 1 d . . .
N52 N 0.5692(3) 0.7903(3) 0.14232(9) 0.0214(11) Uani 1 1 d . . .
N53 N 0.5763(3) 0.7073(3) 0.13616(9) 0.0245(11) Uani 1 1 d . . .
N53' N 0.7148(3) 0.8237(3) 0.09096(9) 0.0243(11) Uani 1 1 d . . .
C54 C 0.5083(4) 0.6761(3) 0.11865(11) 0.0238(13) Uani 1 1 d . . .
C54' C 0.6851(4) 0.7970(3) 0.06639(11) 0.0216(13) Uani 1 1 d . . .
N61' N 0.8436(3) 0.9266(3) 0.15831(9) 0.0243(11) Uani 1 1 d . . .
N61 N 0.5973(3) 0.9550(3) 0.15430(9) 0.0249(11) Uani 1 1 d . . .
C62 C 0.5925(4) 0.9002(3) 0.17533(11) 0.0215(13) Uani 1 1 d . . .
C62' C 0.8383(4) 0.9061(3) 0.13089(11) 0.0218(13) Uani 1 1 d . . .
C63' C 0.8336(4) 0.9659(3) 0.11014(12) 0.0301(15) Uani 1 1 d . . .
H63A H 0.8297 0.9506 0.0911 0.036 Uiso 1 1 calc R . .
C63 C 0.5884(4) 0.9246(4) 0.20245(12) 0.0306(15) Uani 1 1 d . . .
H63B H 0.5825 0.8846 0.2166 0.037 Uiso 1 1 calc R . .
C64 C 0.5929(4) 1.0088(4) 0.20891(13) 0.0351(16) Uani 1 1 d . . .
H64A H 0.5913 1.0269 0.2275 0.042 Uiso 1 1 calc R . .
C64' C 0.8347(4) 1.0489(4) 0.11802(13) 0.0330(16) Uani 1 1 d . . .
H64B H 0.8313 1.0909 0.1043 0.040 Uiso 1 1 calc R . .
C65' C 0.8407(4) 1.0701(4) 0.14525(13) 0.0333(16) Uani 1 1 d . . .
H65A H 0.8416 1.1266 0.1507 0.040 Uiso 1 1 calc R . .
C65 C 0.5998(4) 1.0651(4) 0.18790(12) 0.0326(15) Uani 1 1 d . . .
H65B H 0.6034 1.1228 0.1917 0.039 Uiso 1 1 calc R . .
C66 C 0.6013(4) 1.0354(3) 0.16066(13) 0.0291(15) Uani 1 1 d . . .
H66A H 0.6054 1.0744 0.1461 0.035 Uiso 1 1 calc R . .
C66' C 0.8455(4) 1.0075(4) 0.16491(13) 0.0317(15) Uani 1 1 d . . .
H66B H 0.8502 1.0225 0.1840 0.038 Uiso 1 1 calc R . .
N71 N 0.7010(3) 0.7477(3) 0.20404(10) 0.0296(12) Uani 1 1 d . . .
N71' N 0.8873(3) 0.6902(3) 0.15110(10) 0.0280(12) Uani 1 1 d . . .
C72 C 0.6090(4) 0.7480(3) 0.19046(11) 0.0216(13) Uani 1 1 d . . .
C72' C 0.9146(4) 0.7664(3) 0.14288(11) 0.0242(14) Uani 1 1 d . . .
C73 C 0.5375(4) 0.6921(4) 0.19683(12) 0.0321(15) Uani 1 1 d . . .
H73A H 0.4734 0.6931 0.1871 0.038 Uiso 1 1 calc R . .
C73' C 1.0090(4) 0.7979(4) 0.15084(12) 0.0303(15) Uani 1 1 d . . .
H73B H 1.0267 0.8516 0.1451 0.036 Uiso 1 1 calc R . .
C74' C 1.0759(4) 0.7507(4) 0.16705(13) 0.0353(16) Uani 1 1 d . . .
H74A H 1.1408 0.7707 0.1723 0.042 Uiso 1 1 calc R . .
C74 C 0.5609(5) 0.6347(4) 0.21761(13) 0.0373(16) Uani 1 1 d . . .
H74B H 0.5129 0.5957 0.2222 0.045 Uiso 1 1 calc R . .
C75' C 1.0474(4) 0.6733(4) 0.17568(12) 0.0356(16) Uani 1 1 d . . .
H75A H 1.0920 0.6395 0.1870 0.043 Uiso 1 1 calc R . .
C75 C 0.6534(5) 0.6344(4) 0.23148(12) 0.0370(16) Uani 1 1 d . . .
H75B H 0.6699 0.5960 0.2460 0.044 Uiso 1 1 calc R . .
C76' C 0.9528(4) 0.6464(4) 0.16742(13) 0.0339(16) Uani 1 1 d . . .
H76A H 0.9332 0.5937 0.1737 0.041 Uiso 1 1 calc R . .
C76 C 0.7221(5) 0.6904(4) 0.22403(12) 0.0347(16) Uani 1 1 d . . .
H76B H 0.7870 0.6888 0.2333 0.042 Uiso 1 1 calc R . .
N81' N 0.5482(3) 0.8951(3) 0.06523(9) 0.0247(11) Uani 1 1 d . . .
N81 N 0.3990(4) 0.7219(3) 0.07967(10) 0.0317(12) Uani 1 1 d . . .
C82' C 0.6026(4) 0.8424(3) 0.05067(11) 0.0225(13) Uani 1 1 d . . .
C82 C 0.4191(4) 0.7228(3) 0.10741(12) 0.0247(14) Uani 1 1 d . . .
C83' C 0.5845(4) 0.8334(3) 0.02235(12) 0.0291(14) Uani 1 1 d . . .
H83A H 0.6246 0.7973 0.0128 0.035 Uiso 1 1 calc R . .
C83 C 0.3603(4) 0.7664(3) 0.12450(12) 0.0273(14) Uani 1 1 d . . .
H83B H 0.3755 0.7667 0.1441 0.033 Uiso 1 1 calc R . .
C84 C 0.2794(5) 0.8093(4) 0.11226(14) 0.0371(16) Uani 1 1 d . . .
H84A H 0.2382 0.8397 0.1234 0.045 Uiso 1 1 calc R . .
C84' C 0.5082(4) 0.8765(4) 0.00769(13) 0.0354(16) Uani 1 1 d . . .
H84B H 0.4946 0.8704 -0.0118 0.043 Uiso 1 1 calc R . .
C85' C 0.4529(4) 0.9288(4) 0.02253(13) 0.0364(16) Uani 1 1 d . . .
H85A H 0.3995 0.9590 0.0133 0.044 Uiso 1 1 calc R . .
C85 C 0.2588(5) 0.8075(4) 0.08362(14) 0.0420(18) Uani 1 1 d . . .
H85B H 0.2030 0.8359 0.0749 0.050 Uiso 1 1 calc R . .
C86' C 0.4750(4) 0.9371(4) 0.05081(12) 0.0328(15) Uani 1 1 d . . .
H86A H 0.4365 0.9742 0.0605 0.039 Uiso 1 1 calc R . .
C86 C 0.3210(4) 0.7636(4) 0.06807(13) 0.0381(16) Uani 1 1 d . . .
H86B H 0.3078 0.7631 0.0485 0.046 Uiso 1 1 calc R . .
N91' N 0.6678(4) 0.6577(3) 0.04934(10) 0.0320(12) Uani 1 1 d . . .
N91 N 0.6169(3) 0.5584(3) 0.11355(10) 0.0277(12) Uani 1 1 d . . .
C92 C 0.5224(4) 0.5881(3) 0.11026(11) 0.0257(14) Uani 1 1 d . . .
C92' C 0.7291(4) 0.7228(3) 0.05326(11) 0.0271(14) Uani 1 1 d . . .
C93 C 0.4434(4) 0.5385(3) 0.10075(12) 0.0296(15) Uani 1 1 d . . .
H93A H 0.3785 0.5611 0.0985 0.035 Uiso 1 1 calc R . .
C93' C 0.8239(5) 0.7223(4) 0.04616(12) 0.0380(17) Uani 1 1 d . . .
H93B H 0.8637 0.7706 0.0485 0.046 Uiso 1 1 calc R . .
C94' C 0.8613(5) 0.6506(5) 0.03560(13) 0.0485(19) Uani 1 1 d . . .
H94A H 0.9270 0.6492 0.0304 0.058 Uiso 1 1 calc R . .
C95' C 0.8020(6) 0.5812(4) 0.03266(14) 0.051(2) Uani 1 1 d . . .
H95A H 0.8267 0.5305 0.0262 0.061 Uiso 1 1 calc R . .
C96' C 0.7057(5) 0.5874(4) 0.03935(13) 0.0469(19) Uani 1 1 d . . .
H96A H 0.6642 0.5402 0.0368 0.056 Uiso 1 1 calc R . .
C94 C 0.4584(5) 0.4564(4) 0.09453(12) 0.0339(16) Uani 1 1 d . . .
H94B H 0.4044 0.4215 0.0884 0.041 Uiso 1 1 calc R . .
C95 C 0.5538(5) 0.4265(4) 0.09750(12) 0.0397(17) Uani 1 1 d . . .
H95B H 0.5671 0.3705 0.0932 0.048 Uiso 1 1 calc R . .
C96 C 0.6300(5) 0.4792(4) 0.10686(13) 0.0376(16) Uani 1 1 d . . .
H96B H 0.6955 0.4578 0.1086 0.045 Uiso 1 1 calc R . .
N110 N 0.3816(4) 0.6295(4) 0.00134(13) 0.0492(15) Uani 1 1 d . . .
O111 O 0.3270(5) 0.6095(3) -0.01941(13) 0.097(2) Uani 1 1 d . . .
O112 O 0.3948(3) 0.7044(3) 0.00737(9) 0.0482(12) Uani 1 1 d . . .
O113 O 0.4262(4) 0.5766(3) 0.01656(10) 0.0603(14) Uani 1 1 d . . .
N115 N 1.0007(5) 0.8024(4) 0.23067(12) 0.0468(15) Uani 1 1 d . . .
O116 O 0.9789(3) 0.8667(3) 0.21703(9) 0.0515(13) Uani 1 1 d . . .
O117 O 1.0829(4) 0.7964(3) 0.24429(12) 0.0771(18) Uani 1 1 d . . .
O118 O 0.9416(4) 0.7441(3) 0.22983(10) 0.0678(16) Uani 1 1 d . . .
N120 N 0.7939(4) 0.4731(3) 0.17136(11) 0.0326(13) Uani 1 1 d . . .
O121 O 0.7497(3) 0.5354(2) 0.17946(9) 0.0452(12) Uani 1 1 d . . .
O122 O 0.7992(3) 0.4092(3) 0.18647(9) 0.0449(12) Uani 1 1 d . . .
O123 O 0.8326(3) 0.4743(3) 0.14936(10) 0.0503(13) Uani 1 1 d . . .
N125 N 0.5701(4) 0.1481(4) 0.08584(12) 0.0403(14) Uani 1 1 d . . .
O126 O 0.6111(5) 0.0872(4) 0.09529(13) 0.102(2) Uani 1 1 d . . .
O127 O 0.5423(4) 0.2033(4) 0.10015(13) 0.092(2) Uani 1 1 d . . .
O128 O 0.5591(5) 0.1550(4) 0.06128(12) 0.114(2) Uani 1 1 d U . .
N130 N 0.2235(5) 0.0167(4) 0.04121(13) 0.0504(16) Uani 1 1 d . . .
O131 O 0.2379(4) 0.0170(3) 0.06655(10) 0.0641(15) Uani 1 1 d . . .
O132 O 0.1642(5) -0.0364(4) 0.03012(12) 0.106(2) Uani 1 1 d . . .
O133 O 0.2661(4) 0.0640(3) 0.02641(12) 0.0722(17) Uani 1 1 d . . .
N135 N 0.0949(11) 0.5996(7) 0.0136(3) 0.138(4) Uani 0.627(6) 1 d PDU A 1
O13 O 0.1076(10) 0.5601(8) 0.0361(2) 0.113(5) Uani 0.627(6) 1 d PDU A 1
O14 O 0.0324(6) 0.5754(6) -0.00665(18) 0.097(3) Uani 0.627(6) 1 d PDU . 1
O15 O 0.1137(12) 0.6769(7) 0.0172(3) 0.154(5) Uani 0.627(6) 1 d PDU A 1
N140 N 0.1500(10) 0.6082(9) 0.0393(3) 0.068(4) Uani 0.373(6) 1 d PDU A 2
O13' O 0.0798(10) 0.5606(9) 0.0434(3) 0.055(4) Uani 0.373(6) 1 d PDU A 2
O14' O 0.1304(12) 0.6827(9) 0.0312(4) 0.088(5) Uani 0.373(6) 1 d PDU A 2
O15' O 0.2276(9) 0.5947(8) 0.0555(3) 0.091(5) Uani 0.373(6) 1 d PDU A 2
O140 O 0.1976(3) 0.9415(3) 0.25643(9) 0.0593(14) Uani 1 1 d . B 3
H14C H 0.1962 0.9292 0.2724 0.089 Uiso 1 1 d R B 3
H14D H 0.1710 0.9008 0.2498 0.089 Uiso 1 1 d R B 3
O142 O 0.3007(3) 0.6264(3) 0.24709(9) 0.0585(14) Uani 1 1 d . C 3
H14E H 0.2942 0.6321 0.2306 0.088 Uiso 1 1 d R C 3
H14F H 0.3210 0.6694 0.2533 0.088 Uiso 1 1 d R C 3
O144 O 0.0979(4) -0.0374(3) 0.10574(10) 0.0540(14) Uani 1 1 d . D 3
H14G H 0.1388 -0.0192 0.0966 0.081 Uiso 1 1 d R D 3
H14H H 0.059(5) -0.063(4) 0.0945(14) 0.06(3) Uiso 1 1 d . . .
O146 O 0.8146(3) 0.9267(3) 0.03120(9) 0.0536(13) Uani 1 1 d . E 3
H14I H 0.8417 0.8929 0.0411 0.080 Uiso 1 1 d R E 3
H14J H 0.8062 0.9387 0.0151 0.080 Uiso 1 1 d R E 3
O148 O 0.1305(4) 0.6384(3) 0.27250(10) 0.0717(16) Uani 1 1 d . F 3
H14K H 0.0851 0.6594 0.2633 0.108 Uiso 1 1 d R F 3
H14L H 0.1824 0.6302 0.2664 0.108 Uiso 1 1 d R F 3
O150 O 0.8425(4) 0.2379(3) 0.17990(10) 0.0767(17) Uani 1 1 d . G 3
H15C H 0.8314 0.2865 0.1812 0.115 Uiso 1 1 d R G 3
H15D H 0.8483 0.2147 0.1947 0.115 Uiso 1 1 d R G 3
O152 O 0.3246(4) 0.8373(3) 0.18748(10) 0.089(2) Uani 1 1 d . H 3
H15E H 0.3282 0.8650 0.2013 0.133 Uiso 1 1 d R H 3
H15F H 0.3270 0.7928 0.1946 0.133 Uiso 1 1 d R H 3
O154 O 0.3712(4) 0.9474(3) 0.23327(10) 0.0704(16) Uani 1 1 d . I 3
H15G H 0.3877 0.9020 0.2382 0.106 Uiso 1 1 d R I 3
H15H H 0.4097 0.9723 0.2436 0.106 Uiso 1 1 d R I 3
O156 O 0.9997(4) 0.8950(3) 0.05737(10) 0.0831(18) Uani 1 1 d . J 3
H15I H 0.9956 0.8592 0.0689 0.125 Uiso 1 1 d R J 3
H15J H 0.9493 0.9139 0.0501 0.125 Uiso 1 1 d R J 3
O158 O 0.7415(4) 0.0656(3) 0.04994(11) 0.0805(18) Uani 1 1 d . K 3
H15K H 0.7380 0.0959 0.0369 0.121 Uiso 1 1 d R K 3
H15L H 0.6867 0.0633 0.0546 0.121 Uiso 1 1 d R K 3
O160 O 0.7524(4) 0.1800(4) 0.00802(11) 0.096(2) Uani 1 1 d . L 3
H16C H 0.7914 0.2034 -0.0007 0.144 Uiso 1 1 d R L 3
H16D H 0.7095 0.2143 0.0058 0.144 Uiso 1 1 d R L 3
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N11 Ag1 N11' 141.35(16) . . ?
N11 Ag1 O101 131.25(15) . . ?
N11' Ag1 O101 87.10(15) . . ?
N41' Ag2 N21 163.57(17) . . ?
N41' Ag2 N3' 72.33(16) . . ?
N21 Ag2 N3' 120.35(15) . . ?
N41' Ag2 N2 124.46(16) . . ?
N21 Ag2 N2 70.36(16) . . ?
N3' Ag2 N2 80.86(14) . . ?
N21' Ag3 N31 161.47(17) . . ?
N21' Ag3 N3 125.70(16) . . ?
N31 Ag3 N3 70.82(16) . . ?
N31' Ag4 N41 139.49(17) . . ?
N31' Ag4 O13' 101.2(3) . . ?
N41 Ag4 O13' 118.1(3) . . ?
N31' Ag4 O14 110.2(2) . 3_565 ?
N41 Ag4 O14 90.2(2) . 3_565 ?
O13' Ag4 O14 75.0(4) . 3_565 ?
N2' C1' C22' 117.9(5) . . ?
N2' C1' C12' 125.9(5) . . ?
C22' C1' C12' 116.2(5) . . ?
N2 C1 C22 117.5(5) . . ?
N2 C1 C12 123.9(5) . . ?
C22 C1 C12 118.6(5) . . ?
C1' N2' N3' 115.8(4) . . ?
C1 N2 N3 114.3(5) . . ?
C1 N2 Ag2 111.5(4) . . ?
N3 N2 Ag2 130.1(3) . . ?
C4' N3' N2' 115.8(5) . . ?
C4' N3' Ag2 111.6(4) . . ?
N2' N3' Ag2 131.4(3) . . ?
C4 N3 N2 115.8(5) . . ?
C4 N3 Ag3 108.8(4) . . ?
N2 N3 Ag3 122.9(3) . . ?
N3 C4 C42 127.1(5) . . ?
N3 C4 C32 116.2(5) . . ?
C42 C4 C32 116.7(5) . . ?
N3' C4' C42' 119.7(5) . . ?
N3' C4' C32' 122.7(5) . . ?
C42' C4' C32' 117.4(5) . . ?
C16' N11' C12' 117.6(5) . . ?
C16' N11' Ag1 120.3(4) . . ?
C12' N11' Ag1 121.4(4) . . ?
C12 N11 C16 117.2(5) . . ?
C12 N11 Ag1 121.8(4) . . ?
C16 N11 Ag1 120.9(4) . . ?
N11 C12 C13 122.9(5) . . ?
N11 C12 C1 115.6(5) . . ?
C13 C12 C1 121.5(5) . . ?
N11' C12' C13' 122.6(5) . . ?
N11' C12' C1' 115.6(5) . . ?
C13' C12' C1' 121.9(5) . . ?
C12' C13' C14' 118.3(6) . . ?
C12' C13' H13A 120.9 . . ?
C14' C13' H13A 120.9 . . ?
C14 C13 C12 119.2(6) . . ?
C14 C13 H13B 120.4 . . ?
C12 C13 H13B 120.4 . . ?
C15' C14' C13' 119.4(6) . . ?
C15' C14' H14A 120.3 . . ?
C13' C14' H14A 120.3 . . ?
C13 C14 C15 118.4(6) . . ?
C13 C14 H14B 120.8 . . ?
C15 C14 H14B 120.8 . . ?
C16' C15' C14' 119.1(6) . . ?
C16' C15' H15A 120.4 . . ?
C14' C15' H15A 120.4 . . ?
C16 C15 C14 120.0(6) . . ?
C16 C15 H15B 120.0 . . ?
C14 C15 H15B 120.0 . . ?
N11 C16 C15 122.2(6) . . ?
N11 C16 H16A 118.9 . . ?
C15 C16 H16A 118.9 . . ?
N11' C16' C15' 123.0(5) . . ?
N11' C16' H16B 118.5 . . ?
C15' C16' H16B 118.5 . . ?
C26 N21 C22 118.9(5) . . ?
C26 N21 Ag2 120.7(4) . . ?
C22 N21 Ag2 120.4(4) . . ?
C22' N21' C26' 118.2(5) . . ?
C22' N21' Ag3 122.9(4) . . ?
C26' N21' Ag3 118.8(4) . . ?
N21' C22' C23' 121.2(5) . . ?
N21' C22' C1' 118.7(5) . . ?
C23' C22' C1' 120.1(5) . . ?
N21 C22 C23 120.4(5) . . ?
N21 C22 C1 118.8(5) . . ?
C23 C22 C1 120.8(5) . . ?
C24 C23 C22 119.7(6) . . ?
C24 C23 H23A 120.2 . . ?
C22 C23 H23A 120.2 . . ?
C24' C23' C22' 120.0(6) . . ?
C24' C23' H23B 120.0 . . ?
C22' C23' H23B 120.0 . . ?
C25 C24 C23 119.7(6) . . ?
C25 C24 H24A 120.2 . . ?
C23 C24 H24A 120.2 . . ?
C23' C24' C25' 118.7(6) . . ?
C23' C24' H24B 120.6 . . ?
C25' C24' H24B 120.6 . . ?
C26' C25' C24' 119.1(5) . . ?
C26' C25' H25A 120.4 . . ?
C24' C25' H25A 120.4 . . ?
C24 C25 C26 118.0(6) . . ?
C24 C25 H25B 121.0 . . ?
C26 C25 H25B 121.0 . . ?
N21 C26 C25 123.3(6) . . ?
N21 C26 H26A 118.4 . . ?
C25 C26 H26A 118.4 . . ?
N21' C26' C25' 122.7(5) . . ?
N21' C26' H26B 118.7 . . ?
C25' C26' H26B 118.7 . . ?
C36' N31' C32' 116.4(5) . . ?
C36' N31' Ag4 125.1(4) . . ?
C32' N31' Ag4 118.4(4) . . ?
C36 N31 C32 116.5(5) . . ?
C36 N31 Ag3 124.2(4) . . ?
C32 N31 Ag3 117.9(4) . . ?
N31' C32' C33' 123.9(5) . . ?
N31' C32' C4' 115.8(5) . . ?
C33' C32' C4' 120.3(5) . . ?
N31 C32 C33 122.0(5) . . ?
N31 C32 C4 117.0(5) . . ?
C33 C32 C4 120.6(5) . . ?
C34 C33 C32 119.5(6) . . ?
C34 C33 H33A 120.3 . . ?
C32 C33 H33A 120.3 . . ?
C32' C33' C34' 117.7(5) . . ?
C32' C33' H33B 121.1 . . ?
C34' C33' H33B 121.1 . . ?
C35 C34 C33 118.8(6) . . ?
C35 C34 H34A 120.6 . . ?
C33 C34 H34A 120.6 . . ?
C35' C34' C33' 119.5(5) . . ?
C35' C34' H34B 120.3 . . ?
C33' C34' H34B 120.3 . . ?
C34 C35 C36 119.0(6) . . ?
C34 C35 H35A 120.5 . . ?
C36 C35 H35A 120.5 . . ?
C34' C35' C36' 119.2(5) . . ?
C34' C35' H35B 120.4 . . ?
C36' C35' H35B 120.4 . . ?
N31' C36' C35' 123.4(6) . . ?
N31' C36' H36A 118.3 . . ?
C35' C36' H36A 118.3 . . ?
N31 C36 C35 124.2(6) . . ?
N31 C36 H36B 117.9 . . ?
C35 C36 H36B 117.9 . . ?
C46' N41' C42' 117.2(5) . . ?
C46' N41' Ag2 124.1(4) . . ?
C42' N41' Ag2 118.7(4) . . ?
C46 N41 C42 116.6(5) . . ?
C46 N41 Ag4 119.6(4) . . ?
C42 N41 Ag4 122.9(4) . . ?
N41 C42 C43 123.5(5) . . ?
N41 C42 C4 114.5(5) . . ?
C43 C42 C4 121.9(5) . . ?
N41' C42' C43' 121.6(5) . . ?
N41' C42' C4' 117.2(5) . . ?
C43' C42' C4' 121.2(5) . . ?
C42 C43 C44 118.8(6) . . ?
C42 C43 H43A 120.6 . . ?
C44 C43 H43A 120.6 . . ?
C42' C43' C44' 119.5(6) . . ?
C42' C43' H43B 120.2 . . ?
C44' C43' H43B 120.2 . . ?
C45' C44' C43' 119.5(6) . . ?
C45' C44' H44A 120.2 . . ?
C43' C44' H44A 120.2 . . ?
C45 C44 C43 118.8(6) . . ?
C45 C44 H44B 120.6 . . ?
C43 C44 H44B 120.6 . . ?
C44' C45' C46' 118.8(6) . . ?
C44' C45' H45A 120.6 . . ?
C46' C45' H45A 120.6 . . ?
C44 C45 C46 119.2(6) . . ?
C44 C45 H45B 120.4 . . ?
C46 C45 H45B 120.4 . . ?
N41 C46 C45 123.1(6) . . ?
N41 C46 H46A 118.5 . . ?
C45 C46 H46A 118.5 . . ?
N41' C46' C45' 123.3(6) . . ?
N41' C46' H46B 118.4 . . ?
C45' C46' H46B 118.4 . . ?
O102 N100 O103 120.1(5) . . ?
O102 N100 O101 120.9(5) . . ?
O103 N100 O101 119.0(5) . . ?
N100 O101 Ag1 101.8(3) . . ?
O106 N105 O107 120.7(5) . . ?
O106 N105 O108 118.2(5) . . ?
O107 N105 O108 121.0(5) . . ?
N71 Ag5 N61' 140.29(16) . . ?
N71 Ag5 O116 128.49(16) . . ?
N61' Ag5 O116 90.84(16) . . ?
N61 Ag6 N81' 164.75(16) . . ?
N61 Ag6 N53' 124.72(16) . . ?
N81' Ag6 N53' 70.53(15) . . ?
N61 Ag6 N52 69.27(15) . . ?
N81' Ag6 N52 116.27(15) . . ?
N53' Ag6 N52 83.34(14) . . ?
N71' Ag7 N91 162.04(17) . . ?
N71' Ag7 N53 126.31(16) . . ?
N91 Ag7 N53 69.39(16) . . ?
N91' Ag8 N81 140.96(17) . . ?
N91' Ag8 O113 106.30(17) . . ?
N81 Ag8 O113 112.27(17) . . ?
N52' C51' C72' 116.7(5) . . ?
N52' C51' C62' 126.7(5) . . ?
C72' C51' C62' 116.6(5) . . ?
N52 C51 C62 118.4(5) . . ?
N52 C51 C72 122.1(5) . . ?
C62 C51 C72 119.5(5) . . ?
C51' N52' N53' 114.7(4) . . ?
C51 N52 N53 116.5(5) . . ?
C51 N52 Ag6 110.7(4) . . ?
N53 N52 Ag6 128.0(3) . . ?
C54 N53 N52 117.4(5) . . ?
C54 N53 Ag7 113.9(4) . . ?
N52 N53 Ag7 121.9(3) . . ?
C54' N53' N52' 115.9(4) . . ?
C54' N53' Ag6 112.5(3) . . ?
N52' N53' Ag6 126.7(3) . . ?
N53 C54 C82 123.3(5) . . ?
N53 C54 C92 116.5(5) . . ?
C82 C54 C92 120.2(5) . . ?
N53' C54' C82' 117.3(5) . . ?
N53' C54' C92' 123.5(5) . . ?
C82' C54' C92' 119.1(5) . . ?
C66' N61' C62' 117.7(5) . . ?
C66' N61' Ag5 119.2(4) . . ?
C62' N61' Ag5 121.9(4) . . ?
C66 N61 C62 117.8(5) . . ?
C66 N61 Ag6 120.1(4) . . ?
C62 N61 Ag6 122.0(4) . . ?
N61 C62 C63 122.5(5) . . ?
N61 C62 C51 117.4(5) . . ?
C63 C62 C51 120.0(5) . . ?
N61' C62' C63' 122.0(5) . . ?
N61' C62' C51' 115.0(5) . . ?
C63' C62' C51' 123.0(5) . . ?
C62' C63' C64' 118.1(6) . . ?
C62' C63' H63A 120.9 . . ?
C64' C63' H63A 120.9 . . ?
C62 C63 C64 119.2(6) . . ?
C62 C63 H63B 120.4 . . ?
C64 C63 H63B 120.4 . . ?
C65 C64 C63 118.9(6) . . ?
C65 C64 H64A 120.5 . . ?
C63 C64 H64A 120.5 . . ?
C65' C64' C63' 120.5(6) . . ?
C65' C64' H64B 119.8 . . ?
C63' C64' H64B 119.8 . . ?
C64' C65' C66' 118.5(6) . . ?
C64' C65' H65A 120.7 . . ?
C66' C65' H65A 120.7 . . ?
C64 C65 C66 118.5(5) . . ?
C64 C65 H65B 120.8 . . ?
C66 C65 H65B 120.8 . . ?
N61 C66 C65 123.0(6) . . ?
N61 C66 H66A 118.5 . . ?
C65 C66 H66A 118.5 . . ?
N61' C66' C65' 123.2(6) . . ?
N61' C66' H66B 118.4 . . ?
C65' C66' H66B 118.4 . . ?
C76 N71 C72 118.3(5) . . ?
C76 N71 Ag5 120.6(4) . . ?
C72 N71 Ag5 121.0(4) . . ?
C76' N71' C72' 118.0(5) . . ?
C76' N71' Ag7 120.1(4) . . ?
C72' N71' Ag7 121.9(4) . . ?
N71 C72 C73 121.5(5) . . ?
N71 C72 C51 116.6(5) . . ?
C73 C72 C51 121.9(5) . . ?
N71' C72' C73' 121.3(5) . . ?
N71' C72' C51' 118.2(5) . . ?
C73' C72' C51' 120.5(5) . . ?
C74 C73 C72 118.9(6) . . ?
C74 C73 H73A 120.5 . . ?
C72 C73 H73A 120.5 . . ?
C74' C73' C72' 119.5(6) . . ?
C74' C73' H73B 120.2 . . ?
C72' C73' H73B 120.2 . . ?
C73' C74' C75' 119.0(6) . . ?
C73' C74' H74A 120.5 . . ?
C75' C74' H74A 120.5 . . ?
C75 C74 C73 119.8(6) . . ?
C75 C74 H74B 120.1 . . ?
C73 C74 H74B 120.1 . . ?
C76' C75' C74' 118.5(6) . . ?
C76' C75' H75A 120.7 . . ?
C74' C75' H75A 120.7 . . ?
C74 C75 C76 118.9(6) . . ?
C74 C75 H75B 120.5 . . ?
C76 C75 H75B 120.5 . . ?
N71' C76' C75' 123.6(6) . . ?
N71' C76' H76A 118.2 . . ?
C75' C76' H76A 118.2 . . ?
N71 C76 C75 122.5(6) . . ?
N71 C76 H76B 118.7 . . ?
C75 C76 H76B 118.7 . . ?
C86' N81' C82' 117.1(5) . . ?
C86' N81' Ag6 123.2(4) . . ?
C82' N81' Ag6 119.5(4) . . ?
C86 N81 C82 119.5(5) . . ?
C86 N81 Ag8 119.1(4) . . ?
C82 N81 Ag8 120.8(4) . . ?
N81' C82' C83' 121.8(5) . . ?
N81' C82' C54' 117.5(5) . . ?
C83' C82' C54' 120.7(5) . . ?
N81 C82 C83 121.7(5) . . ?
N81 C82 C54 116.1(5) . . ?
C83 C82 C54 122.2(5) . . ?
C82' C83' C84' 120.6(5) . . ?
C82' C83' H83A 119.7 . . ?
C84' C83' H83A 119.7 . . ?
C84 C83 C82 118.4(6) . . ?
C84 C83 H83B 120.8 . . ?
C82 C83 H83B 120.8 . . ?
C83 C84 C85 119.5(6) . . ?
C83 C84 H84A 120.2 . . ?
C85 C84 H84A 120.2 . . ?
C85' C84' C83' 117.3(6) . . ?
C85' C84' H84B 121.4 . . ?
C83' C84' H84B 121.4 . . ?
C84' C85' C86' 120.0(6) . . ?
C84' C85' H85A 120.0 . . ?
C86' C85' H85A 120.0 . . ?
C86 C85 C84 118.7(6) . . ?
C86 C85 H85B 120.6 . . ?
C84 C85 H85B 120.6 . . ?
N81' C86' C85' 123.1(6) . . ?
N81' C86' H86A 118.4 . . ?
C85' C86' H86A 118.4 . . ?
N81 C86 C85 122.2(6) . . ?
N81 C86 H86B 118.9 . . ?
C85 C86 H86B 118.9 . . ?
C92' N91' C96' 117.0(5) . . ?
C92' N91' Ag8 122.3(4) . . ?
C96' N91' Ag8 120.0(4) . . ?
C96 N91 C92 117.0(5) . . ?
C96 N91 Ag7 122.5(4) . . ?
C92 N91 Ag7 119.5(4) . . ?
N91 C92 C93 121.8(5) . . ?
N91 C92 C54 116.5(5) . . ?
C93 C92 C54 121.7(5) . . ?
N91' C92' C93' 123.2(5) . . ?
N91' C92' C54' 114.6(5) . . ?
C93' C92' C54' 122.2(5) . . ?
C94 C93 C92 120.2(6) . . ?
C94 C93 H93A 119.9 . . ?
C92 C93 H93A 119.9 . . ?
C92' C93' C94' 119.2(6) . . ?
C92' C93' H93B 120.4 . . ?
C94' C93' H93B 120.4 . . ?
C95' C94' C93' 119.1(7) . . ?
C95' C94' H94A 120.4 . . ?
C93' C94' H94A 120.4 . . ?
C96' C95' C94' 118.2(6) . . ?
C96' C95' H95A 120.9 . . ?
C94' C95' H95A 120.9 . . ?
N91' C96' C95' 123.1(6) . . ?
N91' C96' H96A 118.4 . . ?
C95' C96' H96A 118.4 . . ?
C93 C94 C95 118.1(6) . . ?
C93 C94 H94B 120.9 . . ?
C95 C94 H94B 120.9 . . ?
C94 C95 C96 119.1(6) . . ?
C94 C95 H95B 120.5 . . ?
C96 C95 H95B 120.5 . . ?
N91 C96 C95 123.7(6) . . ?
N91 C96 H96B 118.1 . . ?
C95 C96 H96B 118.1 . . ?
O111 N110 O113 121.4(6) . . ?
O111 N110 O112 120.2(6) . . ?
O113 N110 O112 118.3(6) . . ?
N110 O113 Ag8 99.4(4) . . ?
O118 N115 O117 120.3(7) . . ?
O118 N115 O116 119.7(6) . . ?
O117 N115 O116 119.9(6) . . ?
N115 O116 Ag5 103.2(4) . . ?
O123 N120 O121 121.0(5) . . ?
O123 N120 O122 120.5(5) . . ?
O121 N120 O122 118.5(5) . . ?
O128 N125 O126 117.9(7) . . ?
O128 N125 O127 119.1(7) . . ?
O126 N125 O127 123.0(7) . . ?
O131 N130 O133 123.0(7) . . ?
O131 N130 O132 117.6(7) . . ?
O133 N130 O132 119.4(7) . . ?
O15 N135 O14 120.3(9) . . ?
O15 N135 O13 111.5(9) . . ?
O14 N135 O13 121.8(10) . . ?
N135 O14 Ag4 156.3(7) . 3_565 ?
O15' N140 O13' 113.3(10) . . ?
O15' N140 O14' 118.9(10) . . ?
O13' N140 O14' 119.0(10) . . ?
N140 O13' Ag4 130.6(9) . . ?
H14C O140 H14D 97.5 . . ?
H14E O142 H14F 105.9 . . ?
H14G O144 H14H 104.2 . . ?
H14I O146 H14J 140.3 . . ?
H14K O148 H14L 121.8 . . ?
H15C O150 H15D 113.0 . . ?
H15E O152 H15F 98.2 . . ?
H15G O154 H15H 97.3 . . ?
H15I O156 H15J 117.6 . . ?
H15K O158 H15L 105.4 . . ?
H16C O160 H16D 96.3 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 N11 2.208(4) . ?
Ag1 N11' 2.251(4) . ?
Ag1 O101 2.492(4) . ?
Ag2 N41' 2.199(4) . ?
Ag2 N21 2.200(4) . ?
Ag2 N3' 2.462(4) . ?
Ag2 N2 2.547(4) . ?
Ag3 N21' 2.215(4) . ?
Ag3 N31 2.242(5) . ?
Ag3 N3 2.518(4) . ?
Ag4 N31' 2.260(5) . ?
Ag4 N41 2.267(5) . ?
Ag4 O13' 2.472(14) . ?
Ag4 O14 2.664(9) 3_565 ?
C1' N2' 1.297(7) . ?
C1' C22' 1.494(7) . ?
C1' C12' 1.498(7) . ?
C1 N2 1.284(6) . ?
C1 C22 1.491(7) . ?
C1 C12 1.494(7) . ?
N2' N3' 1.398(6) . ?
N2 N3 1.406(6) . ?
N3' C4' 1.285(7) . ?
N3 C4 1.287(7) . ?
C4 C42 1.491(8) . ?
C4 C32 1.503(7) . ?
C4' C42' 1.491(7) . ?
C4' C32' 1.495(7) . ?
N11' C16' 1.344(7) . ?
N11' C12' 1.354(6) . ?
N11 C12 1.352(7) . ?
N11 C16 1.365(7) . ?
C12 C13 1.388(7) . ?
C12' C13' 1.381(7) . ?
C13' C14' 1.390(8) . ?
C13' H13A 0.9500 . ?
C13 C14 1.381(8) . ?
C13 H13B 0.9500 . ?
C14' C15' 1.371(8) . ?
C14' H14A 0.9500 . ?
C14 C15 1.384(8) . ?
C14 H14B 0.9500 . ?
C15' C16' 1.369(8) . ?
C15' H15A 0.9500 . ?
C15 C16 1.376(8) . ?
C15 H15B 0.9500 . ?
C16 H16A 0.9500 . ?
C16' H16B 0.9500 . ?
N21 C26 1.324(7) . ?
N21 C22 1.358(7) . ?
N21' C22' 1.345(6) . ?
N21' C26' 1.352(7) . ?
C22' C23' 1.391(7) . ?
C22 C23 1.393(7) . ?
C23 C24 1.374(8) . ?
C23 H23A 0.9500 . ?
C23' C24' 1.371(7) . ?
C23' H23B 0.9500 . ?
C24 C25 1.371(8) . ?
C24 H24A 0.9500 . ?
C24' C25' 1.380(8) . ?
C24' H24B 0.9500 . ?
C25' C26' 1.371(8) . ?
C25' H25A 0.9500 . ?
C25 C26 1.387(8) . ?
C25 H25B 0.9500 . ?
C26 H26A 0.9500 . ?
C26' H26B 0.9500 . ?
N31' C36' 1.342(7) . ?
N31' C32' 1.360(7) . ?
N31 C36 1.346(7) . ?
N31 C32 1.369(7) . ?
C32' C33' 1.380(7) . ?
C32 C33 1.386(7) . ?
C33 C34 1.384(8) . ?
C33 H33A 0.9500 . ?
C33' C34' 1.397(7) . ?
C33' H33B 0.9500 . ?
C34 C35 1.372(8) . ?
C34 H34A 0.9500 . ?
C34' C35' 1.362(8) . ?
C34' H34B 0.9500 . ?
C35 C36 1.370(8) . ?
C35 H35A 0.9500 . ?
C35' C36' 1.388(8) . ?
C35' H35B 0.9500 . ?
C36' H36A 0.9500 . ?
C36 H36B 0.9500 . ?
N41' C46' 1.341(7) . ?
N41' C42' 1.372(7) . ?
N41 C46 1.349(7) . ?
N41 C42 1.355(7) . ?
C42 C43 1.380(8) . ?
C42' C43' 1.373(7) . ?
C43 C44 1.385(8) . ?
C43 H43A 0.9500 . ?
C43' C44' 1.378(8) . ?
C43' H43B 0.9500 . ?
C44' C45' 1.363(8) . ?
C44' H44A 0.9500 . ?
C44 C45 1.376(9) . ?
C44 H44B 0.9500 . ?
C45' C46' 1.378(8) . ?
C45' H45A 0.9500 . ?
C45 C46 1.386(9) . ?
C45 H45B 0.9500 . ?
C46 H46A 0.9500 . ?
C46' H46B 0.9500 . ?
N100 O102 1.261(5) . ?
N100 O103 1.254(5) . ?
N100 O101 1.248(5) . ?
N105 O106 1.239(5) . ?
N105 O107 1.262(5) . ?
N105 O108 1.260(5) . ?
Ag5 N71 2.226(5) . ?
Ag5 N61' 2.268(4) . ?
Ag5 O116 2.469(4) . ?
Ag6 N61 2.222(5) . ?
Ag6 N81' 2.229(4) . ?
Ag6 N53' 2.489(4) . ?
Ag6 N52 2.579(4) . ?
Ag7 N71' 2.247(5) . ?
Ag7 N91 2.286(5) . ?
Ag7 N53 2.487(4) . ?
Ag8 N91' 2.214(5) . ?
Ag8 N81 2.239(5) . ?
Ag8 O113 2.459(5) . ?
C51' N52' 1.291(6) . ?
C51' C72' 1.479(7) . ?
C51' C62' 1.493(7) . ?
C51 N52 1.297(7) . ?
C51 C62 1.485(7) . ?
C51 C72 1.490(7) . ?
N52' N53' 1.409(6) . ?
N52 N53 1.380(6) . ?
N53 C54 1.294(7) . ?
N53' C54' 1.294(6) . ?
C54 C82 1.485(7) . ?
C54 C92 1.497(7) . ?
C54' C82' 1.487(7) . ?
C54' C92' 1.508(7) . ?
N61' C66' 1.346(7) . ?
N61' C62' 1.365(6) . ?
N61 C66 1.336(6) . ?
N61 C62 1.357(7) . ?
C62 C63 1.379(7) . ?
C62' C63' 1.391(7) . ?
C63' C64' 1.395(8) . ?
C63' H63A 0.9500 . ?
C63 C64 1.397(8) . ?
C63 H63B 0.9500 . ?
C64 C65 1.376(8) . ?
C64 H64A 0.9500 . ?
C64' C65' 1.358(8) . ?
C64' H64B 0.9500 . ?
C65' C66' 1.387(8) . ?
C65' H65A 0.9500 . ?
C65 C66 1.407(8) . ?
C65 H65B 0.9500 . ?
C66 H66A 0.9500 . ?
C66' H66B 0.9500 . ?
N71 C76 1.351(7) . ?
N71 C72 1.354(6) . ?
N71' C76' 1.336(7) . ?
N71' C72' 1.357(7) . ?
C72 C73 1.383(7) . ?
C72' C73' 1.399(7) . ?
C73 C74 1.384(8) . ?
C73 H73A 0.9500 . ?
C73' C74' 1.374(8) . ?
C73' H73B 0.9500 . ?
C74' C75' 1.387(8) . ?
C74' H74A 0.9500 . ?
C74 C75 1.366(8) . ?
C74 H74B 0.9500 . ?
C75' C76' 1.378(8) . ?
C75' H75A 0.9500 . ?
C75 C76 1.374(8) . ?
C75 H75B 0.9500 . ?
C76' H76A 0.9500 . ?
C76 H76B 0.9500 . ?
N81' C86' 1.342(7) . ?
N81' C82' 1.368(6) . ?
N81 C86 1.333(7) . ?
N81 C82 1.346(7) . ?
C82' C83' 1.378(7) . ?
C82 C83 1.396(7) . ?
C83' C84' 1.386(8) . ?
C83' H83A 0.9500 . ?
C83 C84 1.384(8) . ?
C83 H83B 0.9500 . ?
C84 C85 1.389(8) . ?
C84 H84A 0.9500 . ?
C84' C85' 1.378(8) . ?
C84' H84B 0.9500 . ?
C85' C86' 1.381(8) . ?
C85' H85A 0.9500 . ?
C85 C86 1.382(8) . ?
C85 H85B 0.9500 . ?
C86' H86A 0.9500 . ?
C86 H86B 0.9500 . ?
N91' C92' 1.343(7) . ?
N91' C96' 1.356(7) . ?
N91 C96 1.338(7) . ?
N91 C92 1.365(7) . ?
C92 C93 1.383(7) . ?
C92' C93' 1.366(8) . ?
C93 C94 1.381(7) . ?
C93 H93A 0.9500 . ?
C93' C94' 1.383(8) . ?
C93' H93B 0.9500 . ?
C94' C95' 1.381(9) . ?
C94' H94A 0.9500 . ?
C95' C96' 1.381(9) . ?
C95' H95A 0.9500 . ?
C96' H96A 0.9500 . ?
C94 C95 1.379(8) . ?
C94 H94B 0.9500 . ?
C95 C96 1.382(8) . ?
C95 H95B 0.9500 . ?
C96 H96B 0.9500 . ?
N110 O111 1.234(7) . ?
N110 O113 1.248(7) . ?
N110 O112 1.255(6) . ?
N115 O118 1.236(7) . ?
N115 O117 1.245(7) . ?
N115 O116 1.252(7) . ?
N120 O123 1.234(6) . ?
N120 O121 1.255(6) . ?
N120 O122 1.264(6) . ?
N125 O128 1.190(7) . ?
N125 O126 1.200(7) . ?
N125 O127 1.213(7) . ?
N130 O131 1.225(7) . ?
N130 O133 1.231(7) . ?
N130 O132 1.261(7) . ?
N135 O15 1.283(8) . ?
N135 O14 1.294(8) . ?
N135 O13 1.261(8) . ?
O14 Ag4 2.664(9) 3_565 ?
N140 O15' 1.271(9) . ?
N140 O13' 1.255(9) . ?
N140 O14' 1.286(9) . ?
O140 H14C 0.8001 . ?
O140 H14D 0.8026 . ?
O142 H14E 0.8005 . ?
O142 H14F 0.7966 . ?
O144 H14G 0.8000 . ?
O144 H14H 0.83(6) . ?
O146 H14I 0.7948 . ?
O146 H14J 0.8019 . ?
O148 H14K 0.7986 . ?
O148 H14L 0.8015 . ?
O150 H15C 0.8039 . ?
O150 H15D 0.8052 . ?
O152 H15E 0.8040 . ?
O152 H15F 0.7973 . ?
O154 H15G 0.7972 . ?
O154 H15H 0.7979 . ?
O156 H15I 0.8086 . ?
O156 H15J 0.7992 . ?
O158 H15K 0.7980 . ?
O158 H15L 0.7995 . ?
O160 H16C 0.8036 . ?
O160 H16D 0.8040 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C22' C1' N2' N3' -173.8(4) . . . . ?
C12' C1' N2' N3' 6.1(8) . . . . ?
C22 C1 N2 N3 -173.0(4) . . . . ?
C12 C1 N2 N3 7.7(8) . . . . ?
C22 C1 N2 Ag2 -13.3(6) . . . . ?
C12 C1 N2 Ag2 167.4(4) . . . . ?
N41' Ag2 N2 C1 -179.1(3) . . . . ?
N21 Ag2 N2 C1 8.9(4) . . . . ?
N3' Ag2 N2 C1 -118.0(4) . . . . ?
N41' Ag2 N2 N3 -23.5(5) . . . . ?
N21 Ag2 N2 N3 164.5(4) . . . . ?
N3' Ag2 N2 N3 37.6(4) . . . . ?
C1' N2' N3' C4' -138.0(5) . . . . ?
C1' N2' N3' Ag2 55.7(6) . . . . ?
N41' Ag2 N3' C4' 5.8(4) . . . . ?
N21 Ag2 N3' C4' 174.3(4) . . . . ?
N2 Ag2 N3' C4' -125.0(4) . . . . ?
N41' Ag2 N3' N2' 172.4(5) . . . . ?
N21 Ag2 N3' N2' -19.1(5) . . . . ?
N2 Ag2 N3' N2' 41.7(4) . . . . ?
C1 N2 N3 C4 -149.4(5) . . . . ?
Ag2 N2 N3 C4 55.6(6) . . . . ?
C1 N2 N3 Ag3 73.0(5) . . . . ?
Ag2 N2 N3 Ag3 -82.0(5) . . . . ?
N21' Ag3 N3 C4 -148.7(3) . . . . ?
N31 Ag3 N3 C4 21.8(4) . . . . ?
N21' Ag3 N3 N2 -8.6(4) . . . . ?
N31 Ag3 N3 N2 161.9(4) . . . . ?
N2 N3 C4 C42 3.7(8) . . . . ?
Ag3 N3 C4 C42 147.0(5) . . . . ?
N2 N3 C4 C32 -176.9(4) . . . . ?
Ag3 N3 C4 C32 -33.6(5) . . . . ?
N2' N3' C4' C42' -175.0(4) . . . . ?
Ag2 N3' C4' C42' -6.1(6) . . . . ?
N2' N3' C4' C32' 9.3(8) . . . . ?
Ag2 N3' C4' C32' 178.2(4) . . . . ?
N11 Ag1 N11' C16' -106.0(4) . . . . ?
O101 Ag1 N11' C16' 67.7(4) . . . . ?
N11 Ag1 N11' C12' 64.8(5) . . . . ?
O101 Ag1 N11' C12' -121.6(4) . . . . ?
N11' Ag1 N11 C12 4.2(6) . . . . ?
O101 Ag1 N11 C12 -167.4(4) . . . . ?
N11' Ag1 N11 C16 -174.3(4) . . . . ?
O101 Ag1 N11 C16 14.2(5) . . . . ?
C16 N11 C12 C13 1.0(8) . . . . ?
Ag1 N11 C12 C13 -177.5(4) . . . . ?
C16 N11 C12 C1 -179.3(5) . . . . ?
Ag1 N11 C12 C1 2.2(6) . . . . ?
N2 C1 C12 N11 -115.8(6) . . . . ?
C22 C1 C12 N11 64.9(7) . . . . ?
N2 C1 C12 C13 63.9(8) . . . . ?
C22 C1 C12 C13 -115.4(6) . . . . ?
C16' N11' C12' C13' 0.1(8) . . . . ?
Ag1 N11' C12' C13' -170.9(4) . . . . ?
C16' N11' C12' C1' -179.0(5) . . . . ?
Ag1 N11' C12' C1' 10.0(6) . . . . ?
N2' C1' C12' N11' -131.3(6) . . . . ?
C22' C1' C12' N11' 48.6(7) . . . . ?
N2' C1' C12' C13' 49.5(8) . . . . ?
C22' C1' C12' C13' -130.6(5) . . . . ?
N11' C12' C13' C14' -0.2(8) . . . . ?
C1' C12' C13' C14' 178.9(5) . . . . ?
N11 C12 C13 C14 -2.0(9) . . . . ?
C1 C12 C13 C14 178.3(5) . . . . ?
C12' C13' C14' C15' 0.0(9) . . . . ?
C12 C13 C14 C15 2.2(9) . . . . ?
C13' C14' C15' C16' 0.3(9) . . . . ?
C13 C14 C15 C16 -1.5(9) . . . . ?
C12 N11 C16 C15 -0.2(8) . . . . ?
Ag1 N11 C16 C15 178.3(4) . . . . ?
C14 C15 C16 N11 0.5(9) . . . . ?
C12' N11' C16' C15' 0.2(8) . . . . ?
Ag1 N11' C16' C15' 171.3(4) . . . . ?
C14' C15' C16' N11' -0.4(9) . . . . ?
N41' Ag2 N21 C26 20.5(9) . . . . ?
N3' Ag2 N21 C26 -117.3(4) . . . . ?
N2 Ag2 N21 C26 176.5(5) . . . . ?
N41' Ag2 N21 C22 -158.7(5) . . . . ?
N3' Ag2 N21 C22 63.4(4) . . . . ?
N2 Ag2 N21 C22 -2.7(4) . . . . ?
N31 Ag3 N21' C22' -104.8(6) . . . . ?
N3 Ag3 N21' C22' 45.8(5) . . . . ?
N31 Ag3 N21' C26' 72.2(7) . . . . ?
N3 Ag3 N21' C26' -137.2(4) . . . . ?
C26' N21' C22' C23' -0.6(8) . . . . ?
Ag3 N21' C22' C23' 176.4(4) . . . . ?
C26' N21' C22' C1' -179.8(5) . . . . ?
Ag3 N21' C22' C1' -2.7(7) . . . . ?
N2' C1' C22' N21' 36.1(7) . . . . ?
C12' C1' C22' N21' -143.8(5) . . . . ?
N2' C1' C22' C23' -143.0(5) . . . . ?
C12' C1' C22' C23' 37.1(7) . . . . ?
C26 N21 C22 C23 -2.9(8) . . . . ?
Ag2 N21 C22 C23 176.4(4) . . . . ?
C26 N21 C22 C1 177.8(5) . . . . ?
Ag2 N21 C22 C1 -3.0(7) . . . . ?
N2 C1 C22 N21 12.0(8) . . . . ?
C12 C1 C22 N21 -168.6(5) . . . . ?
N2 C1 C22 C23 -167.3(5) . . . . ?
C12 C1 C22 C23 12.0(8) . . . . ?
N21 C22 C23 C24 2.6(9) . . . . ?
C1 C22 C23 C24 -178.0(5) . . . . ?
N21' C22' C23' C24' -0.2(9) . . . . ?
C1' C22' C23' C24' 178.9(5) . . . . ?
C22 C23 C24 C25 -0.3(9) . . . . ?
C22' C23' C24' C25' 0.4(9) . . . . ?
C23' C24' C25' C26' 0.2(9) . . . . ?
C23 C24 C25 C26 -1.7(9) . . . . ?
C22 N21 C26 C25 0.8(9) . . . . ?
Ag2 N21 C26 C25 -178.4(4) . . . . ?
C24 C25 C26 N21 1.5(9) . . . . ?
C22' N21' C26' C25' 1.3(9) . . . . ?
Ag3 N21' C26' C25' -175.8(5) . . . . ?
C24' C25' C26' N21' -1.1(10) . . . . ?
N41 Ag4 N31' C36' 179.0(4) . . . . ?
O13' Ag4 N31' C36' -14.9(6) . . . . ?
O14 Ag4 N31' C36' 63.0(5) 3_565 . . . ?
N41 Ag4 N31' C32' 3.3(5) . . . . ?
O13' Ag4 N31' C32' 169.4(5) . . . . ?
O14 Ag4 N31' C32' -112.7(4) 3_565 . . . ?
N21' Ag3 N31 C36 -44.9(8) . . . . ?
N3 Ag3 N31 C36 160.1(5) . . . . ?
N21' Ag3 N31 C32 149.0(5) . . . . ?
N3 Ag3 N31 C32 -6.0(4) . . . . ?
C36' N31' C32' C33' -0.3(8) . . . . ?
Ag4 N31' C32' C33' 175.8(4) . . . . ?
C36' N31' C32' C4' 177.9(5) . . . . ?
Ag4 N31' C32' C4' -6.0(6) . . . . ?
N3' C4' C32' N31' -104.0(6) . . . . ?
C42' C4' C32' N31' 80.3(6) . . . . ?
N3' C4' C32' C33' 74.3(7) . . . . ?
C42' C4' C32' C33' -101.5(6) . . . . ?
C36 N31 C32 C33 -2.4(8) . . . . ?
Ag3 N31 C32 C33 164.8(4) . . . . ?
C36 N31 C32 C4 -175.7(5) . . . . ?
Ag3 N31 C32 C4 -8.6(6) . . . . ?
N3 C4 C32 N31 31.1(7) . . . . ?
C42 C4 C32 N31 -149.4(5) . . . . ?
N3 C4 C32 C33 -142.3(5) . . . . ?
C42 C4 C32 C33 37.2(7) . . . . ?
N31 C32 C33 C34 1.7(8) . . . . ?
C4 C32 C33 C34 174.8(5) . . . . ?
N31' C32' C33' C34' -1.0(8) . . . . ?
C4' C32' C33' C34' -179.1(5) . . . . ?
C32 C33 C34 C35 -0.2(9) . . . . ?
C32' C33' C34' C35' 1.7(9) . . . . ?
C33 C34 C35 C36 -0.5(9) . . . . ?
C33' C34' C35' C36' -1.2(9) . . . . ?
C32' N31' C36' C35' 0.8(9) . . . . ?
Ag4 N31' C36' C35' -174.9(4) . . . . ?
C34' C35' C36' N31' -0.1(9) . . . . ?
C32 N31 C36 C35 1.7(9) . . . . ?
Ag3 N31 C36 C35 -164.5(5) . . . . ?
C34 C35 C36 N31 -0.3(10) . . . . ?
N21 Ag2 N41' C46' 33.2(9) . . . . ?
N3' Ag2 N41' C46' 175.7(5) . . . . ?
N2 Ag2 N41' C46' -119.2(4) . . . . ?
N21 Ag2 N41' C42' -147.3(5) . . . . ?
N3' Ag2 N41' C42' -4.7(4) . . . . ?
N2 Ag2 N41' C42' 60.4(4) . . . . ?
N31' Ag4 N41 C46 -98.7(5) . . . . ?
O13' Ag4 N41 C46 96.8(6) . . . . ?
O14 Ag4 N41 C46 23.8(5) 3_565 . . . ?
N31' Ag4 N41 C42 70.2(5) . . . . ?
O13' Ag4 N41 C42 -94.2(6) . . . . ?
O14 Ag4 N41 C42 -167.3(5) 3_565 . . . ?
C46 N41 C42 C43 0.0(8) . . . . ?
Ag4 N41 C42 C43 -169.3(4) . . . . ?
C46 N41 C42 C4 -176.3(5) . . . . ?
Ag4 N41 C42 C4 14.4(6) . . . . ?
N3 C4 C42 N41 -133.1(6) . . . . ?
C32 C4 C42 N41 47.5(7) . . . . ?
N3 C4 C42 C43 50.6(8) . . . . ?
C32 C4 C42 C43 -128.8(6) . . . . ?
C46' N41' C42' C43' 2.1(8) . . . . ?
Ag2 N41' C42' C43' -177.4(4) . . . . ?
C46' N41' C42' C4' -176.9(5) . . . . ?
Ag2 N41' C42' C4' 3.5(6) . . . . ?
N3' C4' C42' N41' 2.4(8) . . . . ?
C32' C4' C42' N41' 178.3(5) . . . . ?
N3' C4' C42' C43' -176.7(5) . . . . ?
C32' C4' C42' C43' -0.8(8) . . . . ?
N41 C42 C43 C44 -1.9(9) . . . . ?
C4 C42 C43 C44 174.1(5) . . . . ?
N41' C42' C43' C44' -1.7(9) . . . . ?
C4' C42' C43' C44' 177.3(5) . . . . ?
C42' C43' C44' C45' -0.5(9) . . . . ?
C42 C43 C44 C45 1.8(9) . . . . ?
C43' C44' C45' C46' 2.2(10) . . . . ?
C43 C44 C45 C46 0.2(9) . . . . ?
C42 N41 C46 C45 2.1(9) . . . . ?
Ag4 N41 C46 C45 171.8(5) . . . . ?
C44 C45 C46 N41 -2.3(10) . . . . ?
C42' N41' C46' C45' -0.4(9) . . . . ?
Ag2 N41' C46' C45' 179.2(4) . . . . ?
C44' C45' C46' N41' -1.8(10) . . . . ?
O102 N100 O101 Ag1 6.8(6) . . . . ?
O103 N100 O101 Ag1 -173.0(5) . . . . ?
N11 Ag1 O101 N100 -28.2(4) . . . . ?
N11' Ag1 O101 N100 157.1(4) . . . . ?
C72' C51' N52' N53' 175.8(4) . . . . ?
C62' C51' N52' N53' -4.1(8) . . . . ?
C62 C51 N52 N53 174.1(4) . . . . ?
C72 C51 N52 N53 -6.3(7) . . . . ?
C62 C51 N52 Ag6 16.8(6) . . . . ?
C72 C51 N52 Ag6 -163.6(4) . . . . ?
N61 Ag6 N52 C51 -10.9(3) . . . . ?
N81' Ag6 N52 C51 -175.3(3) . . . . ?
N53' Ag6 N52 C51 120.2(4) . . . . ?
N61 Ag6 N52 N53 -164.9(4) . . . . ?
N81' Ag6 N52 N53 30.7(4) . . . . ?
N53' Ag6 N52 N53 -33.8(4) . . . . ?
C51 N52 N53 C54 138.8(5) . . . . ?
Ag6 N52 N53 C54 -68.4(6) . . . . ?
C51 N52 N53 Ag7 -71.9(5) . . . . ?
Ag6 N52 N53 Ag7 80.9(4) . . . . ?
N71' Ag7 N53 C54 156.5(4) . . . . ?
N91 Ag7 N53 C54 -13.6(4) . . . . ?
N71' Ag7 N53 N52 6.2(4) . . . . ?
N91 Ag7 N53 N52 -163.8(4) . . . . ?
C51' N52' N53' C54' 155.5(5) . . . . ?
C51' N52' N53' Ag6 -51.3(6) . . . . ?
N61 Ag6 N53' C54' 167.6(3) . . . . ?
N81' Ag6 N53' C54' -12.3(4) . . . . ?
N52 Ag6 N53' C54' 108.6(4) . . . . ?
N61 Ag6 N53' N52' 13.8(5) . . . . ?
N81' Ag6 N53' N52' -166.2(4) . . . . ?
N52 Ag6 N53' N52' -45.3(4) . . . . ?
N52 N53 C54 C82 -6.6(8) . . . . ?
Ag7 N53 C54 C82 -158.3(4) . . . . ?
N52 N53 C54 C92 174.5(4) . . . . ?
Ag7 N53 C54 C92 22.8(6) . . . . ?
N52' N53' C54' C82' 175.3(4) . . . . ?
Ag6 N53' C54' C82' 18.4(6) . . . . ?
N52' N53' C54' C92' -4.4(7) . . . . ?
Ag6 N53' C54' C92' -161.3(4) . . . . ?
N71 Ag5 N61' C66' 105.8(4) . . . . ?
O116 Ag5 N61' C66' -66.9(4) . . . . ?
N71 Ag5 N61' C62' -61.4(5) . . . . ?
O116 Ag5 N61' C62' 125.9(4) . . . . ?
N81' Ag6 N61 C66 -59.3(8) . . . . ?
N53' Ag6 N61 C66 120.8(4) . . . . ?
N52 Ag6 N61 C66 -173.6(5) . . . . ?
N81' Ag6 N61 C62 117.5(6) . . . . ?
N53' Ag6 N61 C62 -62.3(4) . . . . ?
N52 Ag6 N61 C62 3.3(4) . . . . ?
C66 N61 C62 C63 2.2(8) . . . . ?
Ag6 N61 C62 C63 -174.7(4) . . . . ?
C66 N61 C62 C51 -179.1(5) . . . . ?
Ag6 N61 C62 C51 3.9(6) . . . . ?
N52 C51 C62 N61 -15.3(7) . . . . ?
C72 C51 C62 N61 165.1(5) . . . . ?
N52 C51 C62 C63 163.4(5) . . . . ?
C72 C51 C62 C63 -16.2(8) . . . . ?
C66' N61' C62' C63' -0.8(8) . . . . ?
Ag5 N61' C62' C63' 166.6(4) . . . . ?
C66' N61' C62' C51' 177.0(5) . . . . ?
Ag5 N61' C62' C51' -15.6(6) . . . . ?
N52' C51' C62' N61' 137.3(5) . . . . ?
C72' C51' C62' N61' -42.6(7) . . . . ?
N52' C51' C62' C63' -45.0(8) . . . . ?
C72' C51' C62' C63' 135.2(5) . . . . ?
N61' C62' C63' C64' 0.2(8) . . . . ?
C51' C62' C63' C64' -177.4(5) . . . . ?
N61 C62 C63 C64 -2.5(9) . . . . ?
C51 C62 C63 C64 179.0(5) . . . . ?
C62 C63 C64 C65 1.1(9) . . . . ?
C62' C63' C64' C65' 0.3(9) . . . . ?
C63' C64' C65' C66' -0.1(9) . . . . ?
C63 C64 C65 C66 0.4(9) . . . . ?
C62 N61 C66 C65 -0.7(8) . . . . ?
Ag6 N61 C66 C65 176.3(4) . . . . ?
C64 C65 C66 N61 -0.6(9) . . . . ?
C62' N61' C66' C65' 1.0(8) . . . . ?
Ag5 N61' C66' C65' -166.7(4) . . . . ?
C64' C65' C66' N61' -0.5(9) . . . . ?
N61' Ag5 N71 C76 170.4(4) . . . . ?
O116 Ag5 N71 C76 -18.9(5) . . . . ?
N61' Ag5 N71 C72 -4.4(5) . . . . ?
O116 Ag5 N71 C72 166.3(4) . . . . ?
N91 Ag7 N71' C76' -76.1(7) . . . . ?
N53 Ag7 N71' C76' 135.6(4) . . . . ?
N91 Ag7 N71' C72' 101.8(6) . . . . ?
N53 Ag7 N71' C72' -46.5(5) . . . . ?
C76 N71 C72 C73 0.6(8) . . . . ?
Ag5 N71 C72 C73 175.5(4) . . . . ?
C76 N71 C72 C51 -178.6(5) . . . . ?
Ag5 N71 C72 C51 -3.7(6) . . . . ?
N52 C51 C72 N71 115.8(6) . . . . ?
C62 C51 C72 N71 -64.7(7) . . . . ?
N52 C51 C72 C73 -63.4(8) . . . . ?
C62 C51 C72 C73 116.2(6) . . . . ?
C76' N71' C72' C73' 0.9(8) . . . . ?
Ag7 N71' C72' C73' -177.0(4) . . . . ?
C76' N71' C72' C51' -179.3(5) . . . . ?
Ag7 N71' C72' C51' 2.7(7) . . . . ?
N52' C51' C72' N71' -39.4(7) . . . . ?
C62' C51' C72' N71' 140.5(5) . . . . ?
N52' C51' C72' C73' 140.4(5) . . . . ?
C62' C51' C72' C73' -39.7(7) . . . . ?
N71 C72 C73 C74 0.1(9) . . . . ?
C51 C72 C73 C74 179.2(5) . . . . ?
N71' C72' C73' C74' 0.7(8) . . . . ?
C51' C72' C73' C74' -179.0(5) . . . . ?
C72' C73' C74' C75' -1.5(9) . . . . ?
C72 C73 C74 C75 0.3(9) . . . . ?
C73' C74' C75' C76' 0.6(9) . . . . ?
C73 C74 C75 C76 -1.3(9) . . . . ?
C72' N71' C76' C75' -1.9(9) . . . . ?
Ag7 N71' C76' C75' 176.1(5) . . . . ?
C74' C75' C76' N71' 1.2(9) . . . . ?
C72 N71 C76 C75 -1.7(9) . . . . ?
Ag5 N71 C76 C75 -176.6(4) . . . . ?
C74 C75 C76 N71 2.0(9) . . . . ?
N61 Ag6 N81' C86' 9.2(9) . . . . ?
N53' Ag6 N81' C86' -170.9(5) . . . . ?
N52 Ag6 N81' C86' 117.2(4) . . . . ?
N61 Ag6 N81' C82' -175.8(5) . . . . ?
N53' Ag6 N81' C82' 4.1(4) . . . . ?
N52 Ag6 N81' C82' -67.7(4) . . . . ?
N91' Ag8 N81 C86 133.9(4) . . . . ?
O113 Ag8 N81 C86 -55.4(5) . . . . ?
N91' Ag8 N81 C82 -36.6(6) . . . . ?
O113 Ag8 N81 C82 134.1(4) . . . . ?
C86' N81' C82' C83' 1.0(8) . . . . ?
Ag6 N81' C82' C83' -174.3(4) . . . . ?
C86' N81' C82' C54' 178.9(5) . . . . ?
Ag6 N81' C82' C54' 3.5(6) . . . . ?
N53' C54' C82' N81' -15.8(7) . . . . ?
C92' C54' C82' N81' 163.9(5) . . . . ?
N53' C54' C82' C83' 162.1(5) . . . . ?
C92' C54' C82' C83' -18.3(8) . . . . ?
C86 N81 C82 C83 0.0(8) . . . . ?
Ag8 N81 C82 C83 170.5(4) . . . . ?
C86 N81 C82 C54 -178.8(5) . . . . ?
Ag8 N81 C82 C54 -8.3(7) . . . . ?
N53 C54 C82 N81 129.8(6) . . . . ?
C92 C54 C82 N81 -51.3(7) . . . . ?
N53 C54 C82 C83 -49.0(8) . . . . ?
C92 C54 C82 C83 129.9(6) . . . . ?
N81' C82' C83' C84' -1.5(9) . . . . ?
C54' C82' C83' C84' -179.3(5) . . . . ?
N81 C82 C83 C84 0.2(8) . . . . ?
C54 C82 C83 C84 179.0(5) . . . . ?
C82 C83 C84 C85 0.2(8) . . . . ?
C82' C83' C84' C85' 0.6(9) . . . . ?
C83' C84' C85' C86' 0.6(9) . . . . ?
C83 C84 C85 C86 -0.9(9) . . . . ?
C82' N81' C86' C85' 0.3(8) . . . . ?
Ag6 N81' C86' C85' 175.5(4) . . . . ?
C84' C85' C86' N81' -1.1(9) . . . . ?
C82 N81 C86 C85 -0.7(9) . . . . ?
Ag8 N81 C86 C85 -171.3(5) . . . . ?
C84 C85 C86 N81 1.1(10) . . . . ?
N81 Ag8 N91' C92' -46.0(6) . . . . ?
O113 Ag8 N91' C92' 143.0(4) . . . . ?
N81 Ag8 N91' C96' 143.7(4) . . . . ?
O113 Ag8 N91' C96' -27.2(5) . . . . ?
N71' Ag7 N91 C96 40.0(8) . . . . ?
N53 Ag7 N91 C96 -166.9(5) . . . . ?
N71' Ag7 N91 C92 -151.5(5) . . . . ?
N53 Ag7 N91 C92 1.6(4) . . . . ?
C96 N91 C92 C93 0.7(8) . . . . ?
Ag7 N91 C92 C93 -168.4(4) . . . . ?
C96 N91 C92 C54 178.2(5) . . . . ?
Ag7 N91 C92 C54 9.1(6) . . . . ?
N53 C54 C92 N91 -22.2(7) . . . . ?
C82 C54 C92 N91 158.9(5) . . . . ?
N53 C54 C92 C93 155.3(5) . . . . ?
C82 C54 C92 C93 -23.6(8) . . . . ?
C96' N91' C92' C93' 4.0(9) . . . . ?
Ag8 N91' C92' C93' -166.6(4) . . . . ?
C96' N91' C92' C54' -175.6(5) . . . . ?
Ag8 N91' C92' C54' 13.8(7) . . . . ?
N53' C54' C92' N91' 113.0(6) . . . . ?
C82' C54' C92' N91' -66.7(7) . . . . ?
N53' C54' C92' C93' -66.6(8) . . . . ?
C82' C54' C92' C93' 113.7(6) . . . . ?
N91 C92 C93 C94 0.6(9) . . . . ?
C54 C92 C93 C94 -176.7(5) . . . . ?
N91' C92' C93' C94' -3.1(9) . . . . ?
C54' C92' C93' C94' 176.5(5) . . . . ?
C92' C93' C94' C95' -0.4(10) . . . . ?
C93' C94' C95' C96' 2.7(10) . . . . ?
C92' N91' C96' C95' -1.5(9) . . . . ?
Ag8 N91' C96' C95' 169.3(5) . . . . ?
C94' C95' C96' N91' -1.8(10) . . . . ?
C92 C93 C94 C95 -1.4(9) . . . . ?
C93 C94 C95 C96 0.8(9) . . . . ?
C92 N91 C96 C95 -1.4(9) . . . . ?
Ag7 N91 C96 C95 167.4(5) . . . . ?
C94 C95 C96 N91 0.6(10) . . . . ?
O111 N110 O113 Ag8 -177.2(6) . . . . ?
O112 N110 O113 Ag8 3.8(6) . . . . ?
N91' Ag8 O113 N110 -114.5(4) . . . . ?
N81 Ag8 O113 N110 71.7(4) . . . . ?
O118 N115 O116 Ag5 -3.9(7) . . . . ?
O117 N115 O116 Ag5 173.8(5) . . . . ?
N71 Ag5 O116 N115 30.4(5) . . . . ?
N61' Ag5 O116 N115 -155.5(4) . . . . ?
O15 N135 O14 Ag4 17(3) . . . 3_565 ?
O13 N135 O14 Ag4 166.9(14) . . . 3_565 ?
O15' N140 O13' Ag4 -39(2) . . . . ?
O14' N140 O13' Ag4 173.9(14) . . . . ?
N31' Ag4 O13' N140 -11.2(16) . . . . ?
N41 Ag4 O13' N140 158.6(14) . . . . ?
O14 Ag4 O13' N140 -119.4(16) 3_565 . . . ?
