#------------------------------------------------------------------------------
#$Date: 2016-03-26 00:35:06 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180086 $
#$URL: svn://www.crystallography.net/cod/cif/7/05/32/7053207.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7053207
loop_
_publ_author_name
'Mei, Xuelan'
'Wang, Xiufeng'
'Wang, Juanjuan'
'Ma, Yue'
'Li, Licun'
'Liao, Daizheng'
_publ_section_title
;
 Dinuclear lanthanide complexes bridged by nitronyl nitroxide radical
 ligands with 2-phenolate groups: structure and magnetic properties
;
_journal_issue                   11
_journal_name_full               'New Journal of Chemistry'
_journal_page_first              3620
_journal_paper_doi               10.1039/c3nj00739a
_journal_volume                  37
_journal_year                    2013
_chemical_formula_sum            'C46 H60 Eu2 N4 O14'
_chemical_formula_weight         1196.90
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                103.788(4)
_cell_angle_beta                 98.622(4)
_cell_angle_gamma                114.832(3)
_cell_formula_units_Z            1
_cell_length_a                   10.509(4)
_cell_length_b                   11.349(5)
_cell_length_c                   11.813(4)
_cell_measurement_reflns_used    4184
_cell_measurement_temperature    113(2)
_cell_measurement_theta_max      27.9
_cell_measurement_theta_min      1.9
_cell_volume                     1190.8(8)
_computing_cell_refinement       'CrystalClear (Rigaku/MSC Inc., 2005)'
_computing_data_collection       'CrystalClear (Rigaku/MSC Inc., 2005)'
_computing_data_reduction        'CrystalClear (Rigaku/MSC Inc., 2005)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      113(2)
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'profile data from ω-scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0418
_diffrn_reflns_av_sigmaI/netI    0.0711
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       10
_diffrn_reflns_limit_l_min       -14
_diffrn_reflns_number            9098
_diffrn_reflns_theta_full        25.01
_diffrn_reflns_theta_max         25.01
_diffrn_reflns_theta_min         1.85
_exptl_absorpt_coefficient_mu    2.679
_exptl_absorpt_correction_T_max  0.8558
_exptl_absorpt_correction_T_min  0.6164
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   CrystalClear
_exptl_crystal_colour            blue
_exptl_crystal_density_diffrn    1.669
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Prism
_exptl_crystal_F_000             602
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.16
_exptl_crystal_size_min          0.06
_refine_diff_density_max         0.883
_refine_diff_density_min         -1.048
_refine_diff_density_rms         0.130
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.059
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     306
_refine_ls_number_reflns         4182
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.059
_refine_ls_R_factor_all          0.0492
_refine_ls_R_factor_gt           0.0402
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0303P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0737
_refine_ls_wR_factor_ref         0.0769
_reflns_number_gt                3715
_reflns_number_total             4182
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c3nj00739a.txt
_cod_data_source_block           Eu
_cod_depositor_comments
;
The following automatic conversions were performed:

'_exptl_absorpt_correction_type' value 'Multi-scan' changed to
'multi-scan' according to
/home/saulius/struct/CIF-dictionaries/cif_core.dic dictionary named
'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 1891 2012-01-12 08:04:46Z andrius 
;
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7053207
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Eu1 Eu 0.84325(3) 0.34171(3) 0.35963(2) 0.02098(10) Uani 1 1 d .
C1 C 0.6736(6) 0.5714(6) 0.1534(5) 0.0316(13) Uani 1 1 d .
H1A H 0.7032 0.6467 0.2269 0.047 Uiso 1 1 calc R
H1B H 0.5795 0.5493 0.1049 0.047 Uiso 1 1 calc R
H1C H 0.7438 0.5973 0.1085 0.047 Uiso 1 1 calc R
C2 C 0.6647(5) 0.4482(5) 0.1844(4) 0.0194(11) Uani 1 1 d .
C3 C 0.5400(6) 0.3211(5) 0.1274(5) 0.0239(12) Uani 1 1 d .
H3 H 0.4648 0.3174 0.0715 0.029 Uiso 1 1 calc R
C4 C 0.5189(6) 0.1991(6) 0.1473(5) 0.0237(12) Uani 1 1 d .
C5 C 0.3763(6) 0.0703(6) 0.0799(5) 0.0418(16) Uani 1 1 d .
H5A H 0.3953 -0.0045 0.0466 0.063 Uiso 1 1 calc R
H5B H 0.3243 0.0849 0.0153 0.063 Uiso 1 1 calc R
H5C H 0.3185 0.0481 0.1348 0.063 Uiso 1 1 calc R
C6 C 1.0381(7) 0.2242(7) 0.0434(5) 0.0440(17) Uani 1 1 d .
H6A H 0.9640 0.1570 -0.0299 0.066 Uiso 1 1 calc R
H6B H 1.1211 0.2081 0.0527 0.066 Uiso 1 1 calc R
H6C H 1.0673 0.3149 0.0389 0.066 Uiso 1 1 calc R
C7 C 0.9779(6) 0.2126(6) 0.1513(5) 0.0321(14) Uani 1 1 d .
C8 C 0.9650(6) 0.1040(6) 0.1918(5) 0.0317(14) Uani 1 1 d .
H8 H 0.9959 0.0448 0.1508 0.038 Uiso 1 1 calc R
C9 C 0.9111(6) 0.0752(6) 0.2868(5) 0.0327(14) Uani 1 1 d .
C10 C 0.9099(7) -0.0451(6) 0.3228(7) 0.056(2) Uani 1 1 d .
H10A H 0.9984 -0.0132 0.3851 0.083 Uiso 1 1 calc R
H10B H 0.9033 -0.1138 0.2531 0.083 Uiso 1 1 calc R
H10C H 0.8273 -0.0843 0.3529 0.083 Uiso 1 1 calc R
C11 C 0.8043(5) 0.5804(5) 0.5500(4) 0.0190(11) Uani 1 1 d .
C12 C 0.7962(5) 0.6804(5) 0.5045(4) 0.0225(12) Uani 1 1 d .
H12 H 0.8544 0.7118 0.4551 0.027 Uiso 1 1 calc R
C13 C 0.7037(6) 0.7340(5) 0.5312(4) 0.0240(12) Uani 1 1 d .
H13 H 0.7010 0.8013 0.5003 0.029 Uiso 1 1 calc R
C14 C 0.6151(6) 0.6884(6) 0.6035(5) 0.0263(13) Uani 1 1 d .
H14 H 0.5553 0.7266 0.6236 0.032 Uiso 1 1 calc R
C15 C 0.6164(6) 0.5862(6) 0.6454(5) 0.0272(13) Uani 1 1 d .
H15 H 0.5553 0.5539 0.6927 0.033 Uiso 1 1 calc R
C16 C 0.7083(5) 0.5292(5) 0.6183(4) 0.0209(12) Uani 1 1 d .
C17 C 0.7060(5) 0.4198(5) 0.6629(4) 0.0216(12) Uani 1 1 d .
C18 C 0.6818(6) 0.2809(6) 0.7893(5) 0.0271(13) Uani 1 1 d .
C19 C 0.5196(6) 0.1842(6) 0.7669(5) 0.0348(14) Uani 1 1 d .
H19A H 0.4819 0.2273 0.8229 0.052 Uiso 1 1 calc R
H19B H 0.5079 0.0998 0.7786 0.052 Uiso 1 1 calc R
H19C H 0.4672 0.1649 0.6852 0.052 Uiso 1 1 calc R
C20 C 0.7686(6) 0.3116(6) 0.9170(5) 0.0360(15) Uani 1 1 d .
H20A H 0.8663 0.3839 0.9336 0.054 Uiso 1 1 calc R
H20B H 0.7716 0.2302 0.9238 0.054 Uiso 1 1 calc R
H20C H 0.7227 0.3403 0.9743 0.054 Uiso 1 1 calc R
C21 C 0.7450(6) 0.2361(6) 0.6867(5) 0.0275(13) Uani 1 1 d .
C22 C 0.6763(7) 0.0813(6) 0.6216(5) 0.0400(16) Uani 1 1 d .
H22A H 0.5720 0.0429 0.5942 0.060 Uiso 1 1 calc R
H22B H 0.7008 0.0389 0.6766 0.060 Uiso 1 1 calc R
H22C H 0.7130 0.0646 0.5531 0.060 Uiso 1 1 calc R
C23 C 0.9103(6) 0.3006(6) 0.7253(5) 0.0340(14) Uani 1 1 d .
H23A H 0.9443 0.2874 0.6546 0.051 Uiso 1 1 calc R
H23B H 0.9397 0.2578 0.7774 0.051 Uiso 1 1 calc R
H23C H 0.9517 0.3975 0.7682 0.051 Uiso 1 1 calc R
N1 N 0.7102(5) 0.3059(4) 0.6025(4) 0.0242(10) Uani 1 1 d .
N2 N 0.6931(5) 0.4116(4) 0.7741(4) 0.0259(11) Uani 1 1 d .
O1 O 0.7758(4) 0.4676(3) 0.2612(3) 0.0241(8) Uani 1 1 d .
O2 O 0.6108(4) 0.1874(4) 0.2204(3) 0.0270(8) Uani 1 1 d .
O3 O 0.9434(4) 0.3041(4) 0.1983(3) 0.0311(9) Uani 1 1 d .
O4 O 0.8634(4) 0.1448(4) 0.3526(3) 0.0295(9) Uani 1 1 d .
O5 O 0.9042(4) 0.5378(3) 0.5315(3) 0.0196(8) Uani 1 1 d .
O6 O 0.7016(4) 0.2643(4) 0.4884(3) 0.0278(9) Uani 1 1 d .
O7 O 0.6808(4) 0.4992(4) 0.8564(3) 0.0332(10) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O1 Eu1 O4 149.77(13) . .
O1 Eu1 O3 83.50(12) . .
O4 Eu1 O3 74.95(12) . .
O1 Eu1 O6 113.99(12) . .
O4 Eu1 O6 80.15(12) . .
O3 Eu1 O6 152.17(13) . .
O1 Eu1 O2 73.28(13) . .
O4 Eu1 O2 84.67(13) . .
O3 Eu1 O2 87.46(13) . .
O6 Eu1 O2 77.96(13) . .
O1 Eu1 O5 112.21(12) . 2_766
O4 Eu1 O5 85.09(12) . 2_766
O3 Eu1 O5 80.32(12) . 2_766
O6 Eu1 O5 109.95(12) . 2_766
O2 Eu1 O5 165.74(10) . 2_766
O1 Eu1 O5 80.65(12) . .
O4 Eu1 O5 129.57(12) . .
O3 Eu1 O5 134.37(12) . .
O6 Eu1 O5 72.07(12) . .
O2 Eu1 O5 127.27(11) . .
O5 Eu1 O5 66.98(11) 2_766 .
O1 Eu1 Eu1 97.35(9) . 2_766
O4 Eu1 Eu1 109.40(10) . 2_766
O3 Eu1 Eu1 108.69(10) . 2_766
O6 Eu1 Eu1 91.06(9) . 2_766
O2 Eu1 Eu1 160.62(8) . 2_766
O5 Eu1 Eu1 33.64(7) 2_766 2_766
O5 Eu1 Eu1 33.35(8) . 2_766
C2 C1 H1A 109.5 . .
C2 C1 H1B 109.5 . .
H1A C1 H1B 109.5 . .
C2 C1 H1C 109.5 . .
H1A C1 H1C 109.5 . .
H1B C1 H1C 109.5 . .
O1 C2 C3 124.0(5) . .
O1 C2 C1 116.3(5) . .
C3 C2 C1 119.7(5) . .
C4 C3 C2 125.2(5) . .
C4 C3 H3 117.4 . .
C2 C3 H3 117.4 . .
O2 C4 C3 124.9(5) . .
O2 C4 C5 116.3(5) . .
C3 C4 C5 118.8(5) . .
C4 C5 H5A 109.5 . .
C4 C5 H5B 109.5 . .
H5A C5 H5B 109.5 . .
C4 C5 H5C 109.5 . .
H5A C5 H5C 109.5 . .
H5B C5 H5C 109.5 . .
C7 C6 H6A 109.5 . .
C7 C6 H6B 109.5 . .
H6A C6 H6B 109.5 . .
C7 C6 H6C 109.5 . .
H6A C6 H6C 109.5 . .
H6B C6 H6C 109.5 . .
O3 C7 C8 124.9(5) . .
O3 C7 C6 117.2(5) . .
C8 C7 C6 117.9(5) . .
C9 C8 C7 126.4(5) . .
C9 C8 H8 116.8 . .
C7 C8 H8 116.8 . .
O4 C9 C8 125.3(5) . .
O4 C9 C10 115.0(5) . .
C8 C9 C10 119.7(5) . .
C9 C10 H10A 109.5 . .
C9 C10 H10B 109.5 . .
H10A C10 H10B 109.5 . .
C9 C10 H10C 109.5 . .
H10A C10 H10C 109.5 . .
H10B C10 H10C 109.5 . .
O5 C11 C12 120.6(4) . .
O5 C11 C16 121.7(5) . .
C12 C11 C16 117.7(4) . .
C13 C12 C11 121.5(5) . .
C13 C12 H12 119.3 . .
C11 C12 H12 119.3 . .
C14 C13 C12 120.5(5) . .
C14 C13 H13 119.8 . .
C12 C13 H13 119.8 . .
C15 C14 C13 119.3(5) . .
C15 C14 H14 120.4 . .
C13 C14 H14 120.4 . .
C14 C15 C16 121.2(5) . .
C14 C15 H15 119.4 . .
C16 C15 H15 119.4 . .
C15 C16 C11 119.8(5) . .
C15 C16 C17 119.9(4) . .
C11 C16 C17 120.3(4) . .
N1 C17 N2 106.9(4) . .
N1 C17 C16 127.4(4) . .
N2 C17 C16 125.7(4) . .
N2 C18 C20 109.4(5) . .
N2 C18 C19 106.8(4) . .
C20 C18 C19 110.9(5) . .
N2 C18 C21 99.9(4) . .
C20 C18 C21 115.3(4) . .
C19 C18 C21 113.5(5) . .
C18 C19 H19A 109.5 . .
C18 C19 H19B 109.5 . .
H19A C19 H19B 109.5 . .
C18 C19 H19C 109.5 . .
H19A C19 H19C 109.5 . .
H19B C19 H19C 109.5 . .
C18 C20 H20A 109.5 . .
C18 C20 H20B 109.5 . .
H20A C20 H20B 109.5 . .
C18 C20 H20C 109.5 . .
H20A C20 H20C 109.5 . .
H20B C20 H20C 109.5 . .
N1 C21 C23 105.3(4) . .
N1 C21 C22 110.8(5) . .
C23 C21 C22 110.5(4) . .
N1 C21 C18 100.0(4) . .
C23 C21 C18 113.4(5) . .
C22 C21 C18 115.8(4) . .
C21 C22 H22A 109.5 . .
C21 C22 H22B 109.5 . .
H22A C22 H22B 109.5 . .
C21 C22 H22C 109.5 . .
H22A C22 H22C 109.5 . .
H22B C22 H22C 109.5 . .
C21 C23 H23A 109.5 . .
C21 C23 H23B 109.5 . .
H23A C23 H23B 109.5 . .
C21 C23 H23C 109.5 . .
H23A C23 H23C 109.5 . .
H23B C23 H23C 109.5 . .
O6 N1 C17 126.5(4) . .
O6 N1 C21 121.4(4) . .
C17 N1 C21 111.7(4) . .
O7 N2 C17 125.4(4) . .
O7 N2 C18 121.4(4) . .
C17 N2 C18 113.0(4) . .
C2 O1 Eu1 137.6(3) . .
C4 O2 Eu1 134.8(3) . .
C7 O3 Eu1 133.9(4) . .
C9 O4 Eu1 134.6(4) . .
C11 O5 Eu1 125.9(3) . 2_766
C11 O5 Eu1 120.5(3) . .
Eu1 O5 Eu1 113.02(11) 2_766 .
N1 O6 Eu1 137.0(3) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Eu1 O1 2.300(3) .
Eu1 O4 2.315(4) .
Eu1 O3 2.348(3) .
Eu1 O6 2.349(3) .
Eu1 O2 2.360(4) .
Eu1 O5 2.379(3) 2_766
Eu1 O5 2.397(3) .
Eu1 Eu1 3.9829(11) 2_766
C1 C2 1.498(7) .
C1 H1A 0.9600 .
C1 H1B 0.9600 .
C1 H1C 0.9600 .
C2 O1 1.268(6) .
C2 C3 1.391(7) .
C3 C4 1.390(7) .
C3 H3 0.9300 .
C4 O2 1.268(6) .
C4 C5 1.505(7) .
C5 H5A 0.9600 .
C5 H5B 0.9600 .
C5 H5C 0.9600 .
C6 C7 1.514(7) .
C6 H6A 0.9600 .
C6 H6B 0.9600 .
C6 H6C 0.9600 .
C7 O3 1.272(6) .
C7 C8 1.389(8) .
C8 C9 1.378(8) .
C8 H8 0.9300 .
C9 O4 1.279(6) .
C9 C10 1.519(8) .
C10 H10A 0.9600 .
C10 H10B 0.9600 .
C10 H10C 0.9600 .
C11 O5 1.352(5) .
C11 C12 1.394(7) .
C11 C16 1.407(7) .
C12 C13 1.384(6) .
C12 H12 0.9300 .
C13 C14 1.382(7) .
C13 H13 0.9300 .
C14 C15 1.369(7) .
C14 H14 0.9300 .
C15 C16 1.404(6) .
C15 H15 0.9300 .
C16 C17 1.454(7) .
C17 N1 1.342(6) .
C17 N2 1.362(6) .
C18 N2 1.494(6) .
C18 C20 1.516(7) .
C18 C19 1.528(7) .
C18 C21 1.549(7) .
C19 H19A 0.9600 .
C19 H19B 0.9600 .
C19 H19C 0.9600 .
C20 H20A 0.9600 .
C20 H20B 0.9600 .
C20 H20C 0.9600 .
C21 N1 1.503(6) .
C21 C23 1.516(7) .
C21 C22 1.525(8) .
C22 H22A 0.9600 .
C22 H22B 0.9600 .
C22 H22C 0.9600 .
C23 H23A 0.9600 .
C23 H23B 0.9600 .
C23 H23C 0.9600 .
N1 O6 1.293(5) .
N2 O7 1.279(5) .
O5 Eu1 2.379(3) 2_766
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O1 C2 C3 C4 0.8(7) . .
C1 C2 C3 C4 179.4(4) . .
C2 C3 C4 O2 0.0(8) . .
C2 C3 C4 C5 178.9(4) . .
O3 C7 C8 C9 1.3(9) . .
C6 C7 C8 C9 -179.0(5) . .
C7 C8 C9 O4 0.4(9) . .
C7 C8 C9 C10 -177.6(6) . .
O5 C11 C12 C13 -174.3(5) . .
C16 C11 C12 C13 3.8(7) . .
C11 C12 C13 C14 -0.6(8) . .
C12 C13 C14 C15 -2.1(8) . .
C13 C14 C15 C16 1.4(8) . .
C14 C15 C16 C11 1.9(8) . .
C14 C15 C16 C17 -179.3(5) . .
O5 C11 C16 C15 173.7(5) . .
C12 C11 C16 C15 -4.5(7) . .
O5 C11 C16 C17 -5.1(7) . .
C12 C11 C16 C17 176.8(5) . .
C15 C16 C17 N1 138.4(5) . .
C11 C16 C17 N1 -42.9(8) . .
C15 C16 C17 N2 -38.8(8) . .
C11 C16 C17 N2 139.9(5) . .
N2 C18 C21 N1 -26.0(5) . .
C20 C18 C21 N1 -143.1(5) . .
C19 C18 C21 N1 87.4(5) . .
N2 C18 C21 C23 85.6(5) . .
C20 C18 C21 C23 -31.4(7) . .
C19 C18 C21 C23 -161.0(5) . .
N2 C18 C21 C22 -145.0(5) . .
C20 C18 C21 C22 97.9(6) . .
C19 C18 C21 C22 -31.6(7) . .
N2 C17 N1 O6 169.8(4) . .
C16 C17 N1 O6 -7.8(8) . .
N2 C17 N1 C21 -17.2(5) . .
C16 C17 N1 C21 165.2(5) . .
C23 C21 N1 O6 83.9(6) . .
C22 C21 N1 O6 -35.6(6) . .
C18 C21 N1 O6 -158.2(4) . .
C23 C21 N1 C17 -89.5(5) . .
C22 C21 N1 C17 150.9(4) . .
C18 C21 N1 C17 28.3(5) . .
N1 C17 N2 O7 -177.5(5) . .
C16 C17 N2 O7 0.2(8) . .
N1 C17 N2 C18 -2.4(6) . .
C16 C17 N2 C18 175.2(5) . .
C20 C18 N2 O7 -43.9(6) . .
C19 C18 N2 O7 76.2(6) . .
C21 C18 N2 O7 -165.3(5) . .
C20 C18 N2 C17 140.8(4) . .
C19 C18 N2 C17 -99.1(5) . .
C21 C18 N2 C17 19.4(6) . .
C3 C2 O1 Eu1 -4.8(7) . .
C1 C2 O1 Eu1 176.6(3) . .
O4 Eu1 O1 C2 49.9(5) . .
O3 Eu1 O1 C2 94.3(4) . .
O6 Eu1 O1 C2 -63.2(4) . .
O2 Eu1 O1 C2 5.0(4) . .
O5 Eu1 O1 C2 171.0(4) 2_766 .
O5 Eu1 O1 C2 -128.7(4) . .
Eu1 Eu1 O1 C2 -157.6(4) 2_766 .
C3 C4 O2 Eu1 2.8(7) . .
C5 C4 O2 Eu1 -176.2(3) . .
O1 Eu1 O2 C4 -3.9(4) . .
O4 Eu1 O2 C4 -163.0(4) . .
O3 Eu1 O2 C4 -87.8(4) . .
O6 Eu1 O2 C4 116.0(4) . .
O5 Eu1 O2 C4 -118.7(5) 2_766 .
O5 Eu1 O2 C4 59.9(5) . .
Eu1 Eu1 O2 C4 59.3(6) 2_766 .
C8 C7 O3 Eu1 -1.6(8) . .
C6 C7 O3 Eu1 178.7(4) . .
O1 Eu1 O3 C7 -158.1(5) . .
O4 Eu1 O3 C7 0.5(5) . .
O6 Eu1 O3 C7 -26.7(6) . .
O2 Eu1 O3 C7 -84.6(5) . .
O5 Eu1 O3 C7 88.0(5) 2_766 .
O5 Eu1 O3 C7 131.8(5) . .
Eu1 Eu1 O3 C7 106.3(5) 2_766 .
C8 C9 O4 Eu1 -1.7(8) . .
C10 C9 O4 Eu1 176.4(4) . .
O1 Eu1 O4 C9 47.2(6) . .
O3 Eu1 O4 C9 1.1(5) . .
O6 Eu1 O4 C9 168.6(5) . .
O2 Eu1 O4 C9 89.9(5) . .
O5 Eu1 O4 C9 -80.1(5) 2_766 .
O5 Eu1 O4 C9 -134.7(4) . .
Eu1 Eu1 O4 C9 -103.7(5) 2_766 .
C12 C11 O5 Eu1 78.4(5) . 2_766
C16 C11 O5 Eu1 -99.7(5) . 2_766
C12 C11 O5 Eu1 -92.4(5) . .
C16 C11 O5 Eu1 89.6(5) . .
O1 Eu1 O5 C11 52.8(3) . .
O4 Eu1 O5 C11 -126.3(3) . .
O3 Eu1 O5 C11 124.0(3) . .
O6 Eu1 O5 C11 -66.3(3) . .
O2 Eu1 O5 C11 -7.8(4) . .
O5 Eu1 O5 C11 171.9(4) 2_766 .
Eu1 Eu1 O5 C11 171.9(4) 2_766 .
O1 Eu1 O5 Eu1 -119.09(15) . 2_766
O4 Eu1 O5 Eu1 61.85(19) . 2_766
O3 Eu1 O5 Eu1 -47.8(2) . 2_766
O6 Eu1 O5 Eu1 121.81(16) . 2_766
O2 Eu1 O5 Eu1 -179.63(12) . 2_766
O5 Eu1 O5 Eu1 0.0 2_766 2_766
C17 N1 O6 Eu1 65.6(7) . .
C21 N1 O6 Eu1 -106.8(5) . .
O1 Eu1 O6 N1 -94.8(4) . .
O4 Eu1 O6 N1 113.3(4) . .
O3 Eu1 O6 N1 140.0(4) . .
O2 Eu1 O6 N1 -160.1(4) . .
O5 Eu1 O6 N1 32.2(4) 2_766 .
O5 Eu1 O6 N1 -24.1(4) . .
Eu1 Eu1 O6 N1 3.8(4) 2_766 .
