#------------------------------------------------------------------------------
#$Date: 2016-03-26 00:37:17 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180088 $
#$URL: svn://www.crystallography.net/cod/cif/7/05/34/7053422.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7053422
loop_
_publ_author_name
'Mayoral, María José'
'Ovejero, Paloma'
'Campo, José Antonio'
'Heras, José Vicente'
'Torres, María Rosario'
'Lodeiro, Carlos'
'Cano, Mercedes'
_publ_section_title
;
 Silver pyrazole complexes with tunable liquid crystals and luminescent
 properties
;
_journal_issue                   12
_journal_name_full               'New Journal of Chemistry'
_journal_page_first              2766
_journal_paper_doi               10.1039/b9nj00753a
_journal_volume                  34
_journal_year                    2010
_chemical_formula_moiety         'C20 H20 Ag N4 O2, C7 H7 O3 S'
_chemical_formula_sum            'C27 H27 Ag N4 O5 S'
_chemical_formula_weight         627.46
_chemical_name_systematic
;
?
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   'geom and Fourier'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 109.930(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   10.2226(7)
_cell_length_b                   21.9026(14)
_cell_length_c                   12.9463(9)
_cell_measurement_temperature    296(2)
_cell_volume                     2725.1(3)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SHELXTL'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.902
_diffrn_measured_fraction_theta_max 0.902
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0529
_diffrn_reflns_av_sigmaI/netI    0.0714
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_k_min       -25
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_number            15883
_diffrn_reflns_theta_full        25.57
_diffrn_reflns_theta_max         25.57
_diffrn_reflns_theta_min         1.86
_exptl_absorpt_coefficient_mu    0.860
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.529
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prismatic
_exptl_crystal_F_000             1280
_exptl_crystal_size_max          0.35
_exptl_crystal_size_mid          0.26
_exptl_crystal_size_min          0.18
_refine_diff_density_max         1.827
_refine_diff_density_min         -0.614
_refine_diff_density_rms         0.073
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.945
_refine_ls_hydrogen_treatment    'constr and fixed'
_refine_ls_matrix_type           full
_refine_ls_number_parameters     349
_refine_ls_number_reflns         4613
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.945
_refine_ls_R_factor_all          0.1149
_refine_ls_R_factor_gt           0.0448
_refine_ls_shift/su_max          0.026
_refine_ls_shift/su_mean         0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0730P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1253
_refine_ls_wR_factor_ref         0.1499
_reflns_number_gt                2167
_reflns_number_total             4613
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b9nj00753a.txt
_cod_data_source_block           compound_10
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 1891 2012-01-12 08:04:46Z andrius 
;
_cod_original_sg_symbol_H-M      P2(1)/c
_cod_database_code               7053422
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
N4 N 0.0388(4) 0.5352(2) 0.7787(3) 0.0557(12) Uani 1 1 d .
N1 N 0.4884(5) 0.4200(2) 0.5853(4) 0.0682(14) Uani 1 1 d .
N3 N 0.0994(6) 0.5114(2) 0.8819(4) 0.0643(14) Uani 1 1 d .
C3 C 0.5472(6) 0.3509(3) 0.7219(5) 0.0601(16) Uani 1 1 d .
C4 C 0.4731(6) 0.3222(3) 0.6273(5) 0.0785(19) Uani 1 1 d .
H4A H 0.4498 0.2810 0.6188 0.094 Uiso 1 1 calc R
C5 C 0.4390(7) 0.3660(3) 0.5462(5) 0.081(2) Uani 1 1 d .
H5 H 0.3875 0.3585 0.4729 0.098 Uiso 1 1 calc R
C6 C 0.6145(6) 0.3293(3) 0.8345(5) 0.0575(15) Uani 1 1 d .
C7 C 0.6819(6) 0.3674(3) 0.9201(5) 0.0676(17) Uani 1 1 d .
H7 H 0.6874 0.4089 0.9068 0.081 Uiso 1 1 calc R
C8 C 0.7427(6) 0.3451(3) 1.0274(5) 0.0730(18) Uani 1 1 d .
H8 H 0.7869 0.3716 1.0847 0.088 Uiso 1 1 calc R
C9 C 0.7367(7) 0.2838(3) 1.0475(5) 0.0718(18) Uani 1 1 d .
C10 C 0.6728(7) 0.2446(3) 0.9614(6) 0.081(2) Uani 1 1 d .
H10 H 0.6710 0.2029 0.9740 0.098 Uiso 1 1 calc R
C11 C 0.6113(7) 0.2676(3) 0.8557(5) 0.0788(19) Uani 1 1 d .
H11 H 0.5673 0.2410 0.7984 0.095 Uiso 1 1 calc R
C12 C 0.8431(8) 0.2982(3) 1.2407(5) 0.104(3) Uani 1 1 d .
H12A H 0.9246 0.3187 1.2375 0.156 Uiso 1 1 calc R
H12B H 0.8665 0.2749 1.3074 0.156 Uiso 1 1 calc R
H12C H 0.7732 0.3278 1.2391 0.156 Uiso 1 1 calc R
C14 C 0.2532(6) 0.5139(3) 0.7931(5) 0.0732(19) Uani 1 1 d .
H14 H 0.3364 0.5099 0.7794 0.088 Uiso 1 1 calc R
C13 C 0.1290(6) 0.5371(3) 0.7227(4) 0.0539(14) Uani 1 1 d .
C16 C 0.0925(5) 0.5613(2) 0.6110(4) 0.0505(14) Uani 1 1 d .
C17 C -0.0427(6) 0.5798(3) 0.5498(4) 0.0647(17) Uani 1 1 d .
H17 H -0.1115 0.5783 0.5818 0.078 Uiso 1 1 calc R
C18 C -0.0765(6) 0.6003(3) 0.4432(5) 0.0709(18) Uani 1 1 d .
H18 H -0.1672 0.6121 0.4038 0.085 Uiso 1 1 calc R
C19 C 0.0258(6) 0.6032(3) 0.3951(4) 0.0567(15) Uani 1 1 d .
C20 C 0.1594(6) 0.5855(3) 0.4541(4) 0.0606(16) Uani 1 1 d .
H20 H 0.2281 0.5871 0.4222 0.073 Uiso 1 1 calc R
C21 C 0.1917(6) 0.5653(3) 0.5618(4) 0.0644(16) Uani 1 1 d .
H21 H 0.2829 0.5542 0.6014 0.077 Uiso 1 1 calc R
C22 C 0.0833(6) 0.6219(3) 0.2343(4) 0.0767(19) Uani 1 1 d .
H22A H 0.1564 0.6504 0.2695 0.115 Uiso 1 1 calc R
H22B H 0.0394 0.6333 0.1587 0.115 Uiso 1 1 calc R
H22C H 0.1217 0.5816 0.2382 0.115 Uiso 1 1 calc R
C23 C 0.7008(6) 0.6237(2) 0.8733(4) 0.0494(14) Uani 1 1 d .
C24 C 0.8147(6) 0.6613(3) 0.9008(5) 0.0739(19) Uani 1 1 d .
H24 H 0.8758 0.6596 0.8616 0.089 Uiso 1 1 calc R
C25 C 0.8383(7) 0.7021(3) 0.9883(6) 0.086(2) Uani 1 1 d .
H25 H 0.9147 0.7281 1.0065 0.103 Uiso 1 1 calc R
C26 C 0.7496(8) 0.7042(3) 1.0480(5) 0.0730(19) Uani 1 1 d .
C27 C 0.6359(7) 0.6673(3) 1.0162(6) 0.079(2) Uani 1 1 d .
H27 H 0.5739 0.6688 1.0547 0.095 Uiso 1 1 calc R
C28 C 0.6100(6) 0.6280(3) 0.9293(5) 0.0623(16) Uani 1 1 d .
H28 H 0.5299 0.6042 0.9084 0.075 Uiso 1 1 calc R
C29 C 0.7792(8) 0.7477(3) 1.1448(5) 0.121(3) Uani 1 1 d .
H29A H 0.6929 0.7627 1.1491 0.181 Uiso 1 1 calc R
H29B H 0.8339 0.7814 1.1350 0.181 Uiso 1 1 calc R
H29C H 0.8294 0.7265 1.2114 0.181 Uiso 1 1 calc R
O1 O 0.7909(5) 0.2582(2) 1.1486(4) 0.0964(15) Uani 1 1 d .
O2 O -0.0178(4) 0.62264(19) 0.2887(3) 0.0770(12) Uani 1 1 d .
O3 O 0.7041(6) 0.51064(19) 0.8244(3) 0.1020(17) Uani 1 1 d .
O4 O 0.5288(4) 0.5741(3) 0.6979(3) 0.1003(16) Uani 1 1 d .
O5 O 0.7684(4) 0.5833(2) 0.7118(3) 0.0834(13) Uani 1 1 d .
S1 S 0.67181(16) 0.56898(8) 0.76809(11) 0.0626(5) Uani 1 1 d .
N2 N 0.5553(5) 0.4104(2) 0.6948(3) 0.0621(13) Uani 1 1 d .
C15 C 0.2281(7) 0.4979(3) 0.8890(5) 0.0723(18) Uani 1 1 d .
H15 H 0.2936 0.4801 0.9501 0.087 Uiso 1 1 calc R
Ag1 Ag 0.5000 0.5000 0.5000 0.0719(3) Uani 1 2 d S
Ag2 Ag 0.0000 0.5000 1.0000 0.0753(3) Uani 1 2 d S
H2 H 0.5936 0.4447 0.7375 0.150 Uiso 1 1 d .
H4 H -0.0666 0.5494 0.7549 0.150 Uiso 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C13 N4 N3 111.7(4) . .
C13 N4 H4 130.2 . .
N3 N4 H4 118.1 . .
C5 N1 N2 104.6(5) . .
C5 N1 Ag1 129.1(4) . .
N2 N1 Ag1 125.3(4) . .
C15 N3 N4 105.1(4) . .
C15 N3 Ag2 129.4(4) . .
N4 N3 Ag2 125.4(4) . .
C4 C3 N2 106.0(5) . .
C4 C3 C6 132.7(6) . .
N2 C3 C6 121.2(5) . .
C3 C4 C5 106.5(6) . .
C3 C4 H4A 126.8 . .
C5 C4 H4A 126.8 . .
N1 C5 C4 111.7(6) . .
N1 C5 H5 124.2 . .
C4 C5 H5 124.2 . .
C11 C6 C7 118.3(6) . .
C11 C6 C3 118.7(6) . .
C7 C6 C3 123.0(6) . .
C6 C7 C8 121.3(6) . .
C6 C7 H7 119.4 . .
C8 C7 H7 119.4 . .
C9 C8 C7 119.7(6) . .
C9 C8 H8 120.1 . .
C7 C8 H8 120.1 . .
O1 C9 C8 123.9(6) . .
O1 C9 C10 116.5(6) . .
C8 C9 C10 119.6(6) . .
C9 C10 C11 120.0(6) . .
C9 C10 H10 120.0 . .
C11 C10 H10 120.0 . .
C6 C11 C10 121.1(6) . .
C6 C11 H11 119.4 . .
C10 C11 H11 119.4 . .
O1 C12 H12A 109.5 . .
O1 C12 H12B 109.5 . .
H12A C12 H12B 109.5 . .
O1 C12 H12C 109.5 . .
H12A C12 H12C 109.5 . .
H12B C12 H12C 109.5 . .
C13 C14 C15 105.8(5) . .
C13 C14 H14 127.1 . .
C15 C14 H14 127.1 . .
N4 C13 C14 106.0(5) . .
N4 C13 C16 123.4(5) . .
C14 C13 C16 130.6(5) . .
C21 C16 C17 117.6(5) . .
C21 C16 C13 120.2(5) . .
C17 C16 C13 122.2(5) . .
C18 C17 C16 121.5(5) . .
C18 C17 H17 119.2 . .
C16 C17 H17 119.2 . .
C17 C18 C19 119.6(5) . .
C17 C18 H18 120.2 . .
C19 C18 H18 120.2 . .
O2 C19 C20 124.8(5) . .
O2 C19 C18 115.5(5) . .
C20 C19 C18 119.7(5) . .
C19 C20 C21 120.0(5) . .
C19 C20 H20 120.0 . .
C21 C20 H20 120.0 . .
C16 C21 C20 121.7(5) . .
C16 C21 H21 119.2 . .
C20 C21 H21 119.2 . .
O2 C22 H22A 109.5 . .
O2 C22 H22B 109.5 . .
H22A C22 H22B 109.5 . .
O2 C22 H22C 109.5 . .
H22A C22 H22C 109.5 . .
H22B C22 H22C 109.5 . .
C28 C23 C24 119.6(5) . .
C28 C23 S1 119.6(5) . .
C24 C23 S1 120.8(5) . .
C23 C24 C25 119.4(6) . .
C23 C24 H24 120.3 . .
C25 C24 H24 120.3 . .
C26 C25 C24 120.8(6) . .
C26 C25 H25 119.6 . .
C24 C25 H25 119.6 . .
C27 C26 C25 117.9(6) . .
C27 C26 C29 122.1(7) . .
C25 C26 C29 120.0(7) . .
C26 C27 C28 121.9(6) . .
C26 C27 H27 119.0 . .
C28 C27 H27 119.0 . .
C23 C28 C27 120.3(6) . .
C23 C28 H28 119.8 . .
C27 C28 H28 119.8 . .
C26 C29 H29A 109.5 . .
C26 C29 H29B 109.5 . .
H29A C29 H29B 109.5 . .
C26 C29 H29C 109.5 . .
H29A C29 H29C 109.5 . .
H29B C29 H29C 109.5 . .
C9 O1 C12 117.7(5) . .
C19 O2 C22 116.8(5) . .
O4 S1 O5 112.7(3) . .
O4 S1 O3 113.2(3) . .
O5 S1 O3 111.4(3) . .
O4 S1 C23 107.5(3) . .
O5 S1 C23 106.2(3) . .
O3 S1 C23 105.1(2) . .
C3 N2 N1 111.3(5) . .
C3 N2 H2 131.8 . .
N1 N2 H2 116.8 . .
N3 C15 C14 111.3(5) . .
N3 C15 H15 124.4 . .
C14 C15 H15 124.4 . .
N1 Ag1 N1 180.00(16) . 3_666
N3 Ag2 N3 180.000(1) 3_567 .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
N4 C13 1.354(6) .
N4 N3 1.371(6) .
N4 H4 1.0610 .
N1 C5 1.317(7) .
N1 N2 1.364(6) .
N1 Ag1 2.095(5) .
N3 C15 1.321(7) .
N3 Ag2 2.119(5) .
C3 C4 1.355(7) .
C3 N2 1.360(7) .
C3 C6 1.462(7) .
C4 C5 1.378(8) .
C4 H4A 0.9300 .
C5 H5 0.9300 .
C6 C11 1.380(8) .
C6 C7 1.372(8) .
C7 C8 1.402(7) .
C7 H7 0.9300 .
C8 C9 1.372(8) .
C8 H8 0.9300 .
C9 O1 1.357(7) .
C9 C10 1.382(9) .
C10 C11 1.391(8) .
C10 H10 0.9300 .
C11 H11 0.9300 .
C12 O1 1.428(7) .
C12 H12A 0.9600 .
C12 H12B 0.9600 .
C12 H12C 0.9600 .
C14 C13 1.383(7) .
C14 C15 1.395(8) .
C14 H14 0.9300 .
C13 C16 1.464(7) .
C16 C21 1.372(7) .
C16 C17 1.399(7) .
C17 C18 1.378(7) .
C17 H17 0.9300 .
C18 C19 1.389(7) .
C18 H18 0.9300 .
C19 O2 1.363(6) .
C19 C20 1.373(7) .
C20 C21 1.390(7) .
C20 H20 0.9300 .
C21 H21 0.9300 .
C22 O2 1.436(6) .
C22 H22A 0.9600 .
C22 H22B 0.9600 .
C22 H22C 0.9600 .
C23 C28 1.362(7) .
C23 C24 1.370(7) .
C23 S1 1.762(5) .
C24 C25 1.398(8) .
C24 H24 0.9300 .
C25 C26 1.378(8) .
C25 H25 0.9300 .
C26 C27 1.359(8) .
C26 C29 1.520(8) .
C27 C28 1.369(8) .
C27 H27 0.9300 .
C28 H28 0.9300 .
C29 H29A 0.9600 .
C29 H29B 0.9600 .
C29 H29C 0.9600 .
O3 S1 1.452(4) .
O4 S1 1.439(4) .
O5 S1 1.447(4) .
N2 H2 0.9362 .
C15 H15 0.9300 .
Ag1 N1 2.095(5) 3_666
Ag2 N3 2.119(5) 3_567
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
N2 H2 O3 0.94 1.94 2.865(6) 169.8 .
N2 H2 S1 0.94 2.83 3.690(5) 153.7 .
N4 H4 O5 1.06 1.75 2.805(6) 171.5 1_455
N4 H4 S1 1.06 2.77 3.780(5) 159.0 1_455
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_4
C13 N4 N3 C15 -0.5(6) .
C13 N4 N3 Ag2 179.5(4) .
N2 C3 C4 C5 0.0(7) .
C6 C3 C4 C5 -178.4(6) .
N2 N1 C5 C4 -0.4(8) .
Ag1 N1 C5 C4 168.6(4) .
C3 C4 C5 N1 0.3(8) .
C4 C3 C6 C11 2.7(10) .
N2 C3 C6 C11 -175.5(5) .
C4 C3 C6 C7 -177.9(6) .
N2 C3 C6 C7 3.9(9) .
C11 C6 C7 C8 -1.9(9) .
C3 C6 C7 C8 178.7(5) .
C6 C7 C8 C9 0.9(9) .
C7 C8 C9 O1 -179.1(6) .
C7 C8 C9 C10 1.1(10) .
O1 C9 C10 C11 178.2(6) .
C8 C9 C10 C11 -2.0(10) .
C7 C6 C11 C10 1.0(10) .
C3 C6 C11 C10 -179.6(6) .
C9 C10 C11 C6 1.0(10) .
N3 N4 C13 C14 -0.5(6) .
N3 N4 C13 C16 -179.1(5) .
C15 C14 C13 N4 1.3(7) .
C15 C14 C13 C16 179.7(6) .
N4 C13 C16 C21 175.9(5) .
C14 C13 C16 C21 -2.3(10) .
N4 C13 C16 C17 -5.4(9) .
C14 C13 C16 C17 176.4(6) .
C21 C16 C17 C18 1.2(9) .
C13 C16 C17 C18 -177.5(6) .
C16 C17 C18 C19 -0.5(10) .
C17 C18 C19 O2 178.5(5) .
C17 C18 C19 C20 0.1(9) .
O2 C19 C20 C21 -178.7(6) .
C18 C19 C20 C21 -0.4(9) .
C17 C16 C21 C20 -1.5(9) .
C13 C16 C21 C20 177.2(5) .
C19 C20 C21 C16 1.2(9) .
C28 C23 C24 C25 2.0(9) .
S1 C23 C24 C25 -176.8(5) .
C23 C24 C25 C26 1.0(10) .
C24 C25 C26 C27 -2.7(10) .
C24 C25 C26 C29 178.3(6) .
C25 C26 C27 C28 1.3(10) .
C29 C26 C27 C28 -179.7(6) .
C24 C23 C28 C27 -3.4(9) .
S1 C23 C28 C27 175.5(5) .
C26 C27 C28 C23 1.7(10) .
C8 C9 O1 C12 7.3(10) .
C10 C9 O1 C12 -172.9(6) .
C20 C19 O2 C22 2.7(8) .
C18 C19 O2 C22 -175.6(5) .
C28 C23 S1 O4 48.6(5) .
C24 C23 S1 O4 -132.5(5) .
C28 C23 S1 O5 169.5(4) .
C24 C23 S1 O5 -11.6(5) .
C28 C23 S1 O3 -72.3(5) .
C24 C23 S1 O3 106.6(5) .
C4 C3 N2 N1 -0.2(7) .
C6 C3 N2 N1 178.4(5) .
C5 N1 N2 C3 0.4(7) .
Ag1 N1 N2 C3 -169.2(4) .
N4 N3 C15 C14 1.4(7) .
Ag2 N3 C15 C14 -178.7(4) .
C13 C14 C15 N3 -1.7(8) .
C5 N1 Ag1 N1 104(100) 3_666
N2 N1 Ag1 N1 -89(100) 3_666
C15 N3 Ag2 N3 -101(100) 3_567
N4 N3 Ag2 N3 79(100) 3_567
