#------------------------------------------------------------------------------
#$Date: 2016-03-26 00:47:40 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180096 $
#$URL: svn://www.crystallography.net/cod/cif/7/05/42/7054272.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7054272
loop_
_publ_author_name
'Hashemi, Lida'
'Morsali, Ali'
'Büyükgüngor, Orhan'
_publ_section_title
;
 Anion influence on transformations of a nonporous 3D to porous 3D
 coordination polymer
;
_journal_name_full               'New Journal of Chemistry'
_journal_paper_doi               10.1039/c4nj00175c
_journal_year                    2014
_chemical_formula_moiety         'C30 H28 N12 O6 Pb2 S2'
_chemical_formula_sum            'C30 H28 N12 O6 Pb2 S2'
_chemical_formula_weight         1131.14
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.072(4)
_cell_angle_beta                 91.404(4)
_cell_angle_gamma                108.250(4)
_cell_formula_units_Z            2
_cell_length_a                   7.8060(4)
_cell_length_b                   12.1582(6)
_cell_length_c                   20.5067(10)
_cell_measurement_reflns_used    20202
_cell_measurement_temperature    296
_cell_measurement_theta_max      28.03
_cell_measurement_theta_min      1.76
_cell_volume                     1847.69(16)
_computing_cell_refinement       X-AREA
_computing_data_collection       'X-AREA (Stoe & Cie, 2002)'
_computing_data_reduction        'X-RED32 (Stoe & Cie, 2002)'
_computing_molecular_graphics    'ORTEP-3 for Windows (Farrugia, 1997)'
_computing_publication_material  'WinGX (Farrugia, 1999)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      296
_diffrn_measured_fraction_theta_full 0.992
_diffrn_measured_fraction_theta_max 0.992
_diffrn_measurement_device_type  'STOE IPDS 2'
_diffrn_measurement_method       'rotation method'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0508
_diffrn_reflns_av_sigmaI/netI    0.0380
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_h_min       -9
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       25
_diffrn_reflns_limit_l_min       -25
_diffrn_reflns_number            20202
_diffrn_reflns_theta_full        26.50
_diffrn_reflns_theta_max         26.50
_diffrn_reflns_theta_min         1.76
_exptl_absorpt_coefficient_mu    9.272
_exptl_absorpt_correction_T_max  0.3907
_exptl_absorpt_correction_T_min  0.1153
_exptl_absorpt_correction_type   integration
_exptl_absorpt_process_details   '(X-RED32; Stoe & Cie, 2002)'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    2.033
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             1072
_exptl_crystal_size_max          0.44
_exptl_crystal_size_mid          0.28
_exptl_crystal_size_min          0.15
_refine_diff_density_max         0.955
_refine_diff_density_min         -1.589
_refine_diff_density_rms         0.126
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.009
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     473
_refine_ls_number_reflns         7593
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.009
_refine_ls_R_factor_all          0.0381
_refine_ls_R_factor_gt           0.0278
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0375P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0626
_refine_ls_wR_factor_ref         0.0658
_reflns_number_gt                6362
_reflns_number_total             7593
_reflns_threshold_expression     >2σ(I)
_cod_data_source_file            c4nj00175c2.cif
_cod_data_source_block           morsali13
_cod_database_code               7054272
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
C1 C 0.5810(7) 0.1971(5) 0.8992(3) 0.0509(14) Uani 1 1 d .
H1 H 0.4583 0.1873 0.9014 0.061 Uiso 1 1 calc R
C2 C 0.6408(7) 0.1025(5) 0.9117(3) 0.0488(13) Uani 1 1 d .
H2 H 0.5595 0.0316 0.9231 0.059 Uiso 1 1 calc R
C3 C 0.8236(6) 0.1151(4) 0.9071(3) 0.0381(10) Uani 1 1 d .
C4 C 0.9365(7) 0.2233(4) 0.8922(3) 0.0470(13) Uani 1 1 d .
H4 H 1.0600 0.2361 0.8896 0.056 Uiso 1 1 calc R
C5 C 0.8664(7) 0.3130(5) 0.8811(3) 0.0521(14) Uani 1 1 d .
H5 H 0.9453 0.3854 0.8709 0.063 Uiso 1 1 calc R
C6 C 0.8951(6) 0.0155(4) 0.9160(2) 0.0386(10) Uani 1 1 d .
C7 C 0.7722(8) -0.1008(5) 0.9322(4) 0.0635(18) Uani 1 1 d .
H7A H 0.8408 -0.1460 0.9516 0.095 Uiso 1 1 calc R
H7B H 0.7119 -0.1387 0.8931 0.095 Uiso 1 1 calc R
H7C H 0.6845 -0.0930 0.9623 0.095 Uiso 1 1 calc R
C8 C 0.1582(13) 0.9615(7) 0.7931(3) 0.085(3) Uani 1 1 d .
H8A H 0.1033 1.0214 0.7979 0.128 Uiso 1 1 calc R
H8B H 0.0813 0.9001 0.7663 0.128 Uiso 1 1 calc R
H8C H 0.2729 0.9927 0.7729 0.128 Uiso 1 1 calc R
C9 C 0.1853(7) 0.9149(4) 0.8592(2) 0.0410(11) Uani 1 1 d .
C10 C 0.2713(6) 0.8212(4) 0.8636(2) 0.0354(10) Uani 1 1 d .
C11 C 0.2725(6) 0.7614(4) 0.9206(2) 0.0363(10) Uani 1 1 d .
H11 H 0.2222 0.7803 0.9580 0.044 Uiso 1 1 calc R
C12 C 0.3487(6) 0.6740(4) 0.9217(2) 0.0401(11) Uani 1 1 d .
H12 H 0.3457 0.6334 0.9603 0.048 Uiso 1 1 calc R
C13 C 0.4275(8) 0.7022(5) 0.8159(3) 0.0550(14) Uani 1 1 d .
H13 H 0.4820 0.6832 0.7796 0.066 Uiso 1 1 calc R
C14 C 0.3503(9) 0.7903(5) 0.8106(3) 0.0539(14) Uani 1 1 d .
H14 H 0.3522 0.8283 0.7712 0.065 Uiso 1 1 calc R
C15 C 0.7083(6) 0.5994(4) 1.0131(2) 0.0360(10) Uani 1 1 d .
C16 C 0.6332(7) 0.2833(5) 0.6766(3) 0.0500(13) Uani 1 1 d .
H16 H 0.6681 0.3086 0.7191 0.060 Uiso 1 1 calc R
C17 C 0.4753(7) 0.1913(5) 0.6666(3) 0.0450(12) Uani 1 1 d .
H17 H 0.4059 0.1570 0.7018 0.054 Uiso 1 1 calc R
C18 C 0.4225(6) 0.1514(4) 0.6034(2) 0.0380(10) Uani 1 1 d .
C19 C 0.5298(6) 0.2095(5) 0.5532(3) 0.0496(13) Uani 1 1 d .
H19 H 0.4984 0.1871 0.5100 0.059 Uiso 1 1 calc R
C20 C 0.6824(7) 0.3000(6) 0.5680(3) 0.0563(15) Uani 1 1 d .
H20 H 0.7521 0.3381 0.5337 0.068 Uiso 1 1 calc R
C21 C 0.2558(6) 0.0531(4) 0.5901(2) 0.0369(10) Uani 1 1 d .
C22 C 0.2230(7) -0.0012(6) 0.5236(3) 0.0585(15) Uani 1 1 d .
H22A H 0.1302 -0.0748 0.5254 0.088 Uiso 1 1 calc R
H22B H 0.3322 -0.0121 0.5087 0.088 Uiso 1 1 calc R
H22C H 0.1854 0.0485 0.4940 0.088 Uiso 1 1 calc R
C23 C 1.8414(8) 1.0563(6) 0.6719(4) 0.076(2) Uani 1 1 d .
H23A H 1.9540 1.0968 0.6935 0.114 Uiso 1 1 calc R
H23B H 1.7458 1.0415 0.7024 0.114 Uiso 1 1 calc R
H23C H 1.8186 1.1027 0.6369 0.114 Uiso 1 1 calc R
C24 C 1.8504(6) 0.9442(4) 0.6450(2) 0.0400(10) Uani 1 1 d .
C25 C 1.6822(6) 0.8441(4) 0.6377(2) 0.0361(10) Uani 1 1 d .
C26 C 1.5130(6) 0.8594(5) 0.6375(3) 0.0425(11) Uani 1 1 d .
H26 H 1.5027 0.9331 0.6422 0.051 Uiso 1 1 calc R
C27 C 1.3610(6) 0.7649(5) 0.6304(3) 0.0435(11) Uani 1 1 d .
H27 H 1.2491 0.7770 0.6295 0.052 Uiso 1 1 calc R
C28 C 1.5307(7) 0.6424(5) 0.6247(3) 0.0533(14) Uani 1 1 d .
H28 H 1.5375 0.5677 0.6206 0.064 Uiso 1 1 calc R
C29 C 1.6875(6) 0.7328(5) 0.6303(3) 0.0448(12) Uani 1 1 d .
H29 H 1.7980 0.7189 0.6291 0.054 Uiso 1 1 calc R
C30 C 0.8988(7) 0.6094(5) 0.5146(3) 0.0482(12) Uani 1 1 d .
N1 N 0.6920(6) 0.3008(4) 0.8843(2) 0.0487(11) Uani 1 1 d .
N2 N 1.0635(5) 0.0387(4) 0.9066(2) 0.0419(9) Uani 1 1 d .
N3 N 0.1359(5) 0.9483(4) 0.9121(2) 0.0410(9) Uani 1 1 d .
N4 N 0.4268(6) 0.6439(4) 0.8705(2) 0.0431(9) Uani 1 1 d .
N5 N 0.6139(6) 0.6038(4) 1.0551(2) 0.0514(11) Uani 1 1 d .
N6 N 0.2541(7) 0.3481(4) 0.7536(2) 0.0541(12) Uani 1 1 d .
N7 N 0.7363(6) 0.3365(4) 0.6284(2) 0.0528(12) Uani 1 1 d .
N8 N 0.1504(5) 0.0220(4) 0.6377(2) 0.0432(10) Uani 1 1 d .
N9 N 1.9956(5) 0.9285(4) 0.6266(2) 0.0432(10) Uani 1 1 d .
N10 N 1.3658(5) 0.6573(4) 0.6249(2) 0.0467(10) Uani 1 1 d .
N11 N 0.9573(8) 0.5794(5) 0.5608(2) 0.0623(14) Uani 1 1 d .
N12 N 0.9099(6) 0.6169(4) 0.7559(2) 0.0502(11) Uani 1 1 d .
O1 O 0.3218(6) 0.2983(4) 0.7952(2) 0.0671(12) Uani 1 1 d .
O2 O 0.1137(8) 0.2964(4) 0.7239(3) 0.097(2) Uani 1 1 d .
O3 O 0.3320(7) 0.4516(4) 0.7419(3) 0.0924(19) Uani 1 1 d .
O4 O 1.0151(6) 0.6645(4) 0.7127(2) 0.0658(12) Uani 1 1 d .
O5 O 0.8381(7) 0.6733(4) 0.7904(3) 0.0796(14) Uani 1 1 d .
O6 O 0.8783(8) 0.5116(4) 0.7654(3) 0.0869(16) Uani 1 1 d .
S1 S 0.84388(17) 0.59592(14) 0.95477(7) 0.0538(3) Uani 1 1 d .
S2 S 0.8193(3) 0.65568(19) 0.44915(9) 0.0769(6) Uani 1 1 d .
Pb1 Pb 0.58202(2) 0.479064(14) 0.854759(8) 0.03377(6) Uani 1 1 d .
Pb2 Pb 1.06833(2) 0.481515(15) 0.651452(8) 0.03673(6) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pb Pb -3.3944 10.1111 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N1 C1 C2 122.7(5) . .
N1 C1 H1 118.6 . .
C2 C1 H1 118.6 . .
C1 C2 C3 119.3(5) . .
C1 C2 H2 120.4 . .
C3 C2 H2 120.4 . .
C4 C3 C2 117.1(4) . .
C4 C3 C6 120.9(4) . .
C2 C3 C6 122.0(4) . .
C3 C4 C5 119.9(5) . .
C3 C4 H4 120.0 . .
C5 C4 H4 120.0 . .
N1 C5 C4 123.1(5) . .
N1 C5 H5 118.4 . .
C4 C5 H5 118.4 . .
N2 C6 C7 124.6(4) . .
N2 C6 C3 114.9(4) . .
C7 C6 C3 120.5(4) . .
C6 C7 H7A 109.5 . .
C6 C7 H7B 109.5 . .
H7A C7 H7B 109.5 . .
C6 C7 H7C 109.5 . .
H7A C7 H7C 109.5 . .
H7B C7 H7C 109.5 . .
C9 C8 H8A 109.5 . .
C9 C8 H8B 109.5 . .
H8A C8 H8B 109.5 . .
C9 C8 H8C 109.5 . .
H8A C8 H8C 109.5 . .
H8B C8 H8C 109.5 . .
N3 C9 C10 117.1(4) . .
N3 C9 C8 124.1(4) . .
C10 C9 C8 118.8(5) . .
C14 C10 C11 117.4(4) . .
C14 C10 C9 121.2(4) . .
C11 C10 C9 121.5(4) . .
C12 C11 C10 119.3(5) . .
C12 C11 H11 120.3 . .
C10 C11 H11 120.3 . .
N4 C12 C11 123.7(4) . .
N4 C12 H12 118.2 . .
C11 C12 H12 118.2 . .
N4 C13 C14 122.8(5) . .
N4 C13 H13 118.6 . .
C14 C13 H13 118.6 . .
C10 C14 C13 119.9(5) . .
C10 C14 H14 120.1 . .
C13 C14 H14 120.1 . .
N5 C15 S1 178.7(5) . .
N7 C16 C17 123.2(5) . .
N7 C16 H16 118.4 . .
C17 C16 H16 118.4 . .
C16 C17 C18 119.1(5) . .
C16 C17 H17 120.5 . .
C18 C17 H17 120.5 . .
C19 C18 C17 117.2(5) . .
C19 C18 C21 121.6(5) . .
C17 C18 C21 121.2(4) . .
C20 C19 C18 119.4(5) . .
C20 C19 H19 120.3 . .
C18 C19 H19 120.3 . .
N7 C20 C19 123.7(5) . .
N7 C20 H20 118.1 . .
C19 C20 H20 118.1 . .
N8 C21 C18 115.8(5) . .
N8 C21 C22 125.1(4) . .
C18 C21 C22 119.1(4) . .
C21 C22 H22A 109.5 . .
C21 C22 H22B 109.5 . .
H22A C22 H22B 109.5 . .
C21 C22 H22C 109.5 . .
H22A C22 H22C 109.5 . .
H22B C22 H22C 109.5 . .
C24 C23 H23A 109.5 . .
C24 C23 H23B 109.5 . .
H23A C23 H23B 109.5 . .
C24 C23 H23C 109.5 . .
H23A C23 H23C 109.5 . .
H23B C23 H23C 109.5 . .
N9 C24 C25 116.8(5) . .
N9 C24 C23 123.6(5) . .
C25 C24 C23 119.6(5) . .
C29 C25 C26 117.1(4) . .
C29 C25 C24 121.5(4) . .
C26 C25 C24 121.4(5) . .
C27 C26 C25 119.6(5) . .
C27 C26 H26 120.2 . .
C25 C26 H26 120.2 . .
N10 C27 C26 123.3(5) . .
N10 C27 H27 118.4 . .
C26 C27 H27 118.4 . .
N10 C28 C29 122.6(5) . .
N10 C28 H28 118.7 . .
C29 C28 H28 118.7 . .
C28 C29 C25 120.2(5) . .
C28 C29 H29 119.9 . .
C25 C29 H29 119.9 . .
N11 C30 S2 178.4(6) . .
C5 N1 C1 117.8(4) . .
C5 N1 Pb1 118.6(3) . .
C1 N1 Pb1 123.5(3) . .
C6 N2 N3 117.3(4) . 1_645
C9 N3 N2 115.5(4) . 1_465
C13 N4 C12 117.0(4) . .
C13 N4 Pb1 111.3(3) . .
C12 N4 Pb1 131.6(3) . .
C15 N5 Pb1 153.3(4) . 2_667
O2 N6 O3 119.8(5) . .
O2 N6 O1 121.2(5) . .
O3 N6 O1 119.0(5) . .
C16 N7 C20 117.4(5) . .
C16 N7 Pb2 121.5(4) . .
C20 N7 Pb2 120.1(3) . .
C21 N8 N9 116.6(4) . 1_345
C24 N9 N8 114.7(5) . 1_765
C27 N10 C28 117.1(4) . .
C27 N10 Pb2 118.8(3) . .
C28 N10 Pb2 121.3(4) . .
C30 N11 Pb2 170.2(5) . .
O4 N12 O6 119.3(5) . .
O4 N12 O5 120.9(5) . .
O6 N12 O5 119.8(5) . .
N6 O1 Pb1 102.6(3) . .
N12 O4 Pb2 102.0(4) . .
C15 S1 Pb1 99.59(17) . .
C30 S2 Pb2 99.5(2) . 2_766
N5 Pb1 N1 79.15(16) 2_667 .
N5 Pb1 N4 80.54(15) 2_667 .
N1 Pb1 N4 158.38(15) . .
N5 Pb1 O1 77.77(15) 2_667 .
N1 Pb1 O1 77.64(14) . .
N4 Pb1 O1 105.15(14) . .
N5 Pb1 S1 85.58(12) 2_667 .
N1 Pb1 S1 83.58(11) . .
N4 Pb1 S1 87.57(10) . .
O1 Pb1 S1 156.87(9) . .
N11 Pb2 N7 78.00(17) . .
N11 Pb2 N10 78.26(17) . .
N7 Pb2 N10 155.43(15) . .
N11 Pb2 O4 77.62(16) . .
N7 Pb2 O4 104.33(15) . .
N10 Pb2 O4 76.55(13) . .
N11 Pb2 S2 87.62(13) . 2_766
N7 Pb2 S2 85.32(12) . 2_766
N10 Pb2 S2 87.45(11) . 2_766
O4 Pb2 S2 160.04(10) . 2_766
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C1 N1 1.329(7) .
C1 C2 1.392(7) .
C1 H1 0.9300 .
C2 C3 1.393(7) .
C2 H2 0.9300 .
C3 C4 1.373(7) .
C3 C6 1.494(6) .
C4 C5 1.382(7) .
C4 H4 0.9300 .
C5 N1 1.326(7) .
C5 H5 0.9300 .
C6 N2 1.275(6) .
C6 C7 1.482(7) .
C7 H7A 0.9600 .
C7 H7B 0.9600 .
C7 H7C 0.9600 .
C8 C9 1.506(7) .
C8 H8A 0.9600 .
C8 H8B 0.9600 .
C8 H8C 0.9600 .
C9 N3 1.269(7) .
C9 C10 1.494(6) .
C10 C14 1.370(7) .
C10 C11 1.380(6) .
C11 C12 1.370(6) .
C11 H11 0.9300 .
C12 N4 1.334(7) .
C12 H12 0.9300 .
C13 N4 1.324(7) .
C13 C14 1.387(7) .
C13 H13 0.9300 .
C14 H14 0.9300 .
C15 N5 1.159(6) .
C15 S1 1.625(5) .
C16 N7 1.325(7) .
C16 C17 1.391(7) .
C16 H16 0.9300 .
C17 C18 1.391(7) .
C17 H17 0.9300 .
C18 C19 1.390(7) .
C18 C21 1.485(6) .
C19 C20 1.372(8) .
C19 H19 0.9300 .
C20 N7 1.330(7) .
C20 H20 0.9300 .
C21 N8 1.272(6) .
C21 C22 1.495(7) .
C22 H22A 0.9600 .
C22 H22B 0.9600 .
C22 H22C 0.9600 .
C23 C24 1.491(8) .
C23 H23A 0.9600 .
C23 H23B 0.9600 .
C23 H23C 0.9600 .
C24 N9 1.273(6) .
C24 C25 1.489(6) .
C25 C29 1.376(7) .
C25 C26 1.390(6) .
C26 C27 1.373(7) .
C26 H26 0.9300 .
C27 N10 1.324(7) .
C27 H27 0.9300 .
C28 N10 1.355(7) .
C28 C29 1.367(7) .
C28 H28 0.9300 .
C29 H29 0.9300 .
C30 N11 1.149(7) .
C30 S2 1.638(6) .
N1 Pb1 2.635(4) .
N2 N3 1.388(5) 1_645
N3 N2 1.388(5) 1_465
N4 Pb1 2.670(4) .
N5 Pb1 2.440(4) 2_667
N6 O2 1.226(6) .
N6 O3 1.240(6) .
N6 O1 1.246(6) .
N7 Pb2 2.669(4) .
N8 N9 1.389(5) 1_345
N9 N8 1.389(5) 1_765
N10 Pb2 2.686(4) .
N11 Pb2 2.490(5) .
N12 O4 1.238(6) .
N12 O6 1.242(6) .
N12 O5 1.243(6) .
O1 Pb1 2.743(5) .
O4 Pb2 2.701(5) .
S1 Pb1 2.8933(15) .
S2 Pb2 2.9671(19) 2_766
Pb1 N5 2.440(5) 2_667
Pb2 S2 2.9671(19) 2_766
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_4
N1 C1 C2 C3 -1.6(10) .
C1 C2 C3 C4 2.1(9) .
C1 C2 C3 C6 -176.3(5) .
C2 C3 C4 C5 -1.5(9) .
C6 C3 C4 C5 176.9(5) .
C3 C4 C5 N1 0.3(10) .
C4 C3 C6 N2 -2.2(8) .
C2 C3 C6 N2 176.1(5) .
C4 C3 C6 C7 179.9(6) .
C2 C3 C6 C7 -1.8(8) .
N3 C9 C10 C14 -171.2(5) .
C8 C9 C10 C14 10.3(8) .
N3 C9 C10 C11 9.6(7) .
C8 C9 C10 C11 -168.9(6) .
C14 C10 C11 C12 -1.0(8) .
C9 C10 C11 C12 178.2(5) .
C10 C11 C12 N4 1.5(8) .
C11 C10 C14 C13 -0.1(9) .
C9 C10 C14 C13 -179.3(6) .
N4 C13 C14 C10 0.9(10) .
N7 C16 C17 C18 0.8(9) .
C16 C17 C18 C19 -2.1(8) .
C16 C17 C18 C21 179.6(5) .
C17 C18 C19 C20 1.5(8) .
C21 C18 C19 C20 179.9(5) .
C18 C19 C20 N7 0.4(10) .
C19 C18 C21 N8 -166.4(5) .
C17 C18 C21 N8 11.8(7) .
C19 C18 C21 C22 13.3(7) .
C17 C18 C21 C22 -168.5(5) .
N9 C24 C25 C29 18.9(7) .
C23 C24 C25 C29 -162.2(6) .
N9 C24 C25 C26 -160.7(5) .
C23 C24 C25 C26 18.2(8) .
C29 C25 C26 C27 0.3(7) .
C24 C25 C26 C27 179.8(5) .
C25 C26 C27 N10 1.4(8) .
N10 C28 C29 C25 1.2(9) .
C26 C25 C29 C28 -1.5(8) .
C24 C25 C29 C28 178.9(5) .
C4 C5 N1 C1 0.3(10) .
C4 C5 N1 Pb1 -176.5(5) .
C2 C1 N1 C5 0.3(9) .
C2 C1 N1 Pb1 177.0(5) .
C7 C6 N2 N3 -0.1(8) 1_645
C3 C6 N2 N3 -177.9(4) 1_645
C10 C9 N3 N2 177.4(4) 1_465
C8 C9 N3 N2 -4.2(8) 1_465
C14 C13 N4 C12 -0.5(9) .
C14 C13 N4 Pb1 178.1(5) .
C11 C12 N4 C13 -0.8(8) .
C11 C12 N4 Pb1 -179.0(4) .
S1 C15 N5 Pb1 -133(22) 2_667
C17 C16 N7 C20 1.1(9) .
C17 C16 N7 Pb2 -167.3(4) .
C19 C20 N7 C16 -1.7(10) .
C19 C20 N7 Pb2 166.8(5) .
C18 C21 N8 N9 -178.7(4) 1_345
C22 C21 N8 N9 1.6(8) 1_345
C25 C24 N9 N8 -176.6(4) 1_765
C23 C24 N9 N8 4.6(8) 1_765
C26 C27 N10 C28 -1.6(8) .
C26 C27 N10 Pb2 159.7(4) .
C29 C28 N10 C27 0.3(9) .
C29 C28 N10 Pb2 -160.5(5) .
S2 C30 N11 Pb2 -152(18) .
O2 N6 O1 Pb1 -168.6(6) .
O3 N6 O1 Pb1 12.0(7) .
O6 N12 O4 Pb2 9.1(6) .
O5 N12 O4 Pb2 -172.1(5) .
N5 C15 S1 Pb1 -149(22) .
N11 C30 S2 Pb2 114(20) 2_766
C5 N1 Pb1 N5 -142.4(5) 2_667
C1 N1 Pb1 N5 41.0(5) 2_667
C5 N1 Pb1 N4 -122.1(5) .
C1 N1 Pb1 N4 61.3(7) .
C5 N1 Pb1 O1 137.9(5) .
C1 N1 Pb1 O1 -38.7(5) .
C5 N1 Pb1 S1 -55.6(4) .
C1 N1 Pb1 S1 127.7(5) .
C13 N4 Pb1 N5 -154.9(4) 2_667
C12 N4 Pb1 N5 23.4(5) 2_667
C13 N4 Pb1 N1 -175.1(4) .
C12 N4 Pb1 N1 3.2(7) .
C13 N4 Pb1 O1 -80.4(4) .
C12 N4 Pb1 O1 97.9(5) .
C13 N4 Pb1 S1 119.2(4) .
C12 N4 Pb1 S1 -62.5(5) .
N6 O1 Pb1 N5 119.0(4) 2_667
N6 O1 Pb1 N1 -159.6(4) .
N6 O1 Pb1 N4 42.5(4) .
N6 O1 Pb1 S1 164.0(3) .
C15 S1 Pb1 N5 -25.5(2) 2_667
C15 S1 Pb1 N1 -105.1(2) .
C15 S1 Pb1 N4 55.1(2) .
C15 S1 Pb1 O1 -69.3(3) .
C30 N11 Pb2 N7 -49(3) .
C30 N11 Pb2 N10 125(3) .
C30 N11 Pb2 O4 -157(3) .
C30 N11 Pb2 S2 37(3) 2_766
C16 N7 Pb2 N11 -141.7(5) .
C20 N7 Pb2 N11 50.3(5) .
C16 N7 Pb2 N10 -156.9(4) .
C20 N7 Pb2 N10 35.0(7) .
C16 N7 Pb2 O4 -68.0(5) .
C20 N7 Pb2 O4 124.0(5) .
C16 N7 Pb2 S2 129.7(5) 2_766
C20 N7 Pb2 S2 -38.3(5) 2_766
C27 N10 Pb2 N11 59.8(4) .
C28 N10 Pb2 N11 -139.7(5) .
C27 N10 Pb2 N7 75.0(6) .
C28 N10 Pb2 N7 -124.5(5) .
C27 N10 Pb2 O4 -20.1(4) .
C28 N10 Pb2 O4 140.4(5) .
C27 N10 Pb2 S2 147.9(4) 2_766
C28 N10 Pb2 S2 -51.6(4) 2_766
N12 O4 Pb2 N11 123.7(4) .
N12 O4 Pb2 N7 49.7(4) .
N12 O4 Pb2 N10 -155.6(4) .
N12 O4 Pb2 S2 166.8(2) 2_766
