#------------------------------------------------------------------------------
#$Date: 2016-03-26 00:47:40 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180096 $
#$URL: svn://www.crystallography.net/cod/cif/7/05/42/7054273.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7054273
loop_
_publ_author_name
'Hashemi, Lida'
'Morsali, Ali'
'Büyükgüngor, Orhan'
_publ_section_title
;
 Anion influence on transformations of a nonporous 3D to porous 3D
 coordination polymer
;
_journal_name_full               'New Journal of Chemistry'
_journal_paper_doi               10.1039/c4nj00175c
_journal_year                    2014
_chemical_formula_moiety         'C32 H28 N12 Pb2 S4'
_chemical_formula_sum            'C32 H28 N12 Pb2 S4'
_chemical_formula_weight         1123.28
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 109.200(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   16.3972(5)
_cell_length_b                   14.1233(3)
_cell_length_c                   20.3576(6)
_cell_measurement_reflns_used    3315
_cell_measurement_temperature    296
_cell_measurement_theta_max      28.02
_cell_measurement_theta_min      1.94
_cell_volume                     4452.2(2)
_computing_cell_refinement       X-AREA
_computing_data_collection       'X-AREA (Stoe & Cie, 2002)'
_computing_data_reduction        'X-RED32 (Stoe & Cie, 2002)'
_computing_molecular_graphics    'ORTEP-3 for Windows (Farrugia, 1997)'
_computing_publication_material  'WinGX (Farrugia, 1999)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      296
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'STOE IPDS 2'
_diffrn_measurement_method       'rotation method'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0625
_diffrn_reflns_av_sigmaI/netI    0.0492
_diffrn_reflns_limit_h_max       20
_diffrn_reflns_limit_h_min       -20
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       25
_diffrn_reflns_limit_l_min       -25
_diffrn_reflns_number            33115
_diffrn_reflns_theta_full        26.50
_diffrn_reflns_theta_max         26.50
_diffrn_reflns_theta_min         1.95
_exptl_absorpt_coefficient_mu    7.776
_exptl_absorpt_correction_T_max  0.3633
_exptl_absorpt_correction_T_min  0.0802
_exptl_absorpt_correction_type   integration
_exptl_absorpt_process_details   '(X-RED32; Stoe & Cie, 2002)'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.676
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             2128
_exptl_crystal_size_max          0.54
_exptl_crystal_size_mid          0.34
_exptl_crystal_size_min          0.12
_refine_diff_density_max         1.908
_refine_diff_density_min         -1.317
_refine_diff_density_rms         0.145
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.128
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     455
_refine_ls_number_reflns         9221
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.128
_refine_ls_R_factor_all          0.0774
_refine_ls_R_factor_gt           0.0548
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0416P)²+14.5400P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1058
_refine_ls_wR_factor_ref         0.1130
_reflns_number_gt                7222
_reflns_number_total             9221
_reflns_threshold_expression     >2σ(I)
_cod_data_source_file            c4nj00175c2.cif
_cod_data_source_block           morsali14
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               7054273
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
C1 C 0.5832(7) 0.4125(8) 0.4531(5) 0.055(2) Uani 1 1 d .
C2 C 0.3982(7) 0.2657(7) 0.6016(5) 0.053(2) Uani 1 1 d .
C3 C 0.6467(6) 0.2231(8) 0.6563(5) 0.054(2) Uani 1 1 d .
H3 H 0.5969 0.2189 0.6686 0.065 Uiso 1 1 calc R
C4 C 0.7247(6) 0.2356(7) 0.7089(5) 0.048(2) Uani 1 1 d .
H4 H 0.7272 0.2417 0.7550 0.058 Uiso 1 1 calc R
C5 C 0.7992(5) 0.2390(7) 0.6908(4) 0.044(2) Uani 1 1 d .
C6 C 0.7918(6) 0.2323(8) 0.6218(5) 0.054(2) Uani 1 1 d .
H6 H 0.8404 0.2346 0.6079 0.064 Uiso 1 1 calc R
C7 C 0.7096(6) 0.2219(8) 0.5730(5) 0.059(3) Uani 1 1 d .
H7 H 0.7045 0.2184 0.5262 0.071 Uiso 1 1 calc R
C8 C 0.8872(6) 0.2480(8) 0.7454(4) 0.050(2) Uani 1 1 d .
C9 C 0.8939(8) 0.2681(12) 0.8173(5) 0.089(5) Uani 1 1 d .
H9A H 0.8679 0.2175 0.8349 0.133 Uiso 1 1 calc R
H9B H 0.8646 0.3263 0.8192 0.133 Uiso 1 1 calc R
H9C H 0.9537 0.2737 0.8451 0.133 Uiso 1 1 calc R
C10 C 0.3344(6) 0.2585(8) 0.3374(5) 0.058(3) Uani 1 1 d .
H10 H 0.3835 0.2630 0.3243 0.069 Uiso 1 1 calc R
C11 C 0.2555(6) 0.2611(9) 0.2861(5) 0.064(3) Uani 1 1 d .
H11 H 0.2516 0.2653 0.2396 0.077 Uiso 1 1 calc R
C12 C 0.1813(6) 0.2573(7) 0.3050(4) 0.048(2) Uani 1 1 d .
C13 C 0.1920(6) 0.2511(9) 0.3743(5) 0.060(3) Uani 1 1 d .
H13 H 0.1440 0.2495 0.3891 0.072 Uiso 1 1 calc R
C14 C 0.2735(6) 0.2473(9) 0.4219(5) 0.061(3) Uani 1 1 d .
H14 H 0.2793 0.2427 0.4688 0.073 Uiso 1 1 calc R
C15 C 0.0945(6) 0.2604(8) 0.2508(5) 0.060(3) Uani 1 1 d .
C16 C 0.0862(8) 0.2617(13) 0.1766(5) 0.094(5) Uani 1 1 d .
H16A H 0.0435 0.2162 0.1520 0.141 Uiso 1 1 calc R
H16B H 0.1407 0.2460 0.1715 0.141 Uiso 1 1 calc R
H16C H 0.0688 0.3237 0.1579 0.141 Uiso 1 1 calc R
N1 N 0.5402(7) 0.3556(7) 0.4670(5) 0.072(3) Uani 1 1 d .
N2 N 0.4459(6) 0.2598(7) 0.5709(4) 0.061(2) Uani 1 1 d .
N3 N 0.6387(4) 0.2167(6) 0.5899(4) 0.050(2) Uani 1 1 d .
N4 N 0.3451(5) 0.2499(7) 0.4043(4) 0.056(2) Uani 1 1 d .
N5 N 0.9509(5) 0.2348(8) 0.7222(4) 0.063(2) Uani 1 1 d .
N6 N 0.0317(5) 0.2601(8) 0.2752(4) 0.065(3) Uani 1 1 d .
S1 S 0.6406(2) 0.4954(2) 0.43512(15) 0.0724(8) Uani 1 1 d .
S2 S 0.3317(3) 0.2784(3) 0.6440(2) 0.1038(14) Uani 1 1 d .
Pb1 Pb 0.49872(2) 0.19700(3) 0.485920(17) 0.04394(10) Uani 1 1 d .
C17 C 0.4424(6) 0.4792(7) 0.0925(5) 0.051(2) Uani 1 1 d .
C18 C 0.5612(7) 0.2880(7) 0.3077(6) 0.058(3) Uani 1 1 d .
C19 C 0.7669(7) 0.5010(9) 0.3001(6) 0.066(3) Uani 1 1 d .
H19 H 0.7641 0.4973 0.3449 0.079 Uiso 1 1 calc R
C20 C 0.8467(6) 0.4989(9) 0.2916(5) 0.063(3) Uani 1 1 d .
H20 H 0.8962 0.4933 0.3303 0.075 Uiso 1 1 calc R
C21 C 0.8538(6) 0.5048(7) 0.2266(5) 0.052(2) Uani 1 1 d .
C22 C 0.7779(6) 0.5112(8) 0.1707(5) 0.054(2) Uani 1 1 d .
H22 H 0.7789 0.5149 0.1253 0.065 Uiso 1 1 calc R
C23 C 0.7003(6) 0.5118(8) 0.1844(5) 0.055(2) Uani 1 1 d .
H23 H 0.6496 0.5150 0.1466 0.066 Uiso 1 1 calc R
C24 C 0.9395(6) 0.5044(8) 0.2163(5) 0.056(3) Uani 1 1 d .
C25 C 0.9451(7) 0.5034(10) 0.1441(5) 0.077(4) Uani 1 1 d .
H25A H 1.0030 0.4886 0.1463 0.116 Uiso 1 1 calc R
H25B H 0.9294 0.5646 0.1231 0.116 Uiso 1 1 calc R
H25C H 0.9063 0.4565 0.1166 0.116 Uiso 1 1 calc R
C26 C 0.3243(7) 0.4993(9) 0.2368(6) 0.069(3) Uani 1 1 d .
H26 H 0.3285 0.4910 0.1927 0.083 Uiso 1 1 calc R
C27 C 0.2435(6) 0.4978(9) 0.2433(6) 0.066(3) Uani 1 1 d .
H27 H 0.1948 0.4898 0.2043 0.079 Uiso 1 1 calc R
C28 C 0.2351(5) 0.5082(7) 0.3080(5) 0.045(2) Uani 1 1 d .
C29 C 0.3109(6) 0.5220(8) 0.3629(5) 0.058(3) Uani 1 1 d .
H29 H 0.3089 0.5294 0.4078 0.070 Uiso 1 1 calc R
C30 C 0.3874(6) 0.5246(9) 0.3518(6) 0.062(3) Uani 1 1 d .
H30 H 0.4367 0.5361 0.3897 0.074 Uiso 1 1 calc R
C31 C 0.1483(6) 0.5087(7) 0.3173(5) 0.050(2) Uani 1 1 d .
C32 C 0.1418(7) 0.5119(12) 0.3866(6) 0.087(4) Uani 1 1 d .
H32A H 0.1206 0.5728 0.3943 0.130 Uiso 1 1 calc R
H32B H 0.1978 0.5015 0.4204 0.130 Uiso 1 1 calc R
H32C H 0.1028 0.4636 0.3911 0.130 Uiso 1 1 calc R
N7 N 0.4881(6) 0.4782(7) 0.1492(5) 0.070(3) Uani 1 1 d .
N8 N 0.5538(8) 0.3609(8) 0.2847(5) 0.082(3) Uani 1 1 d .
N9 N 0.6934(5) 0.5083(6) 0.2468(4) 0.055(2) Uani 1 1 d .
N10 N 0.3967(5) 0.5118(7) 0.2897(5) 0.058(2) Uani 1 1 d .
N11 N 1.0045(5) 0.5066(7) 0.2724(5) 0.064(2) Uani 1 1 d .
N12 N 0.0834(5) 0.5066(7) 0.2607(4) 0.063(2) Uani 1 1 d .
S3 S 0.3801(2) 0.4818(2) 0.01203(15) 0.0733(8) Uani 1 1 d .
S4 S 0.5706(3) 0.1844(2) 0.34176(18) 0.0862(10) Uani 1 1 d .
Pb2 Pb 0.54682(2) 0.53118(3) 0.273325(17) 0.04414(10) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pb Pb -3.3944 10.1111 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_3
N1 C1 S1 177.3(11) .
N2 C2 S2 177.8(11) .
N3 C3 C4 123.8(9) .
N3 C3 H3 118.1 .
C4 C3 H3 118.1 .
C3 C4 C5 118.1(8) .
C3 C4 H4 121.0 .
C5 C4 H4 121.0 .
C6 C5 C4 118.6(8) .
C6 C5 C8 120.1(8) .
C4 C5 C8 121.3(8) .
C5 C6 C7 118.4(8) .
C5 C6 H6 120.8 .
C7 C6 H6 120.8 .
N3 C7 C6 123.4(8) .
N3 C7 H7 118.3 .
C6 C7 H7 118.3 .
N5 C8 C9 126.2(9) .
N5 C8 C5 114.2(8) .
C9 C8 C5 119.6(9) .
C8 C9 H9A 109.5 .
C8 C9 H9B 109.5 .
H9A C9 H9B 109.5 .
C8 C9 H9C 109.5 .
H9A C9 H9C 109.5 .
H9B C9 H9C 109.5 .
N4 C10 C11 124.1(9) .
N4 C10 H10 117.9 .
C11 C10 H10 117.9 .
C10 C11 C12 118.7(9) .
C10 C11 H11 120.7 .
C12 C11 H11 120.7 .
C13 C12 C11 117.5(8) .
C13 C12 C15 122.2(9) .
C11 C12 C15 120.3(8) .
C12 C13 C14 119.8(9) .
C12 C13 H13 120.1 .
C14 C13 H13 120.1 .
N4 C14 C13 123.2(9) .
N4 C14 H14 118.4 .
C13 C14 H14 118.4 .
N6 C15 C16 125.7(9) .
N6 C15 C12 114.0(8) .
C16 C15 C12 120.3(9) .
C15 C16 H16A 109.5 .
C15 C16 H16B 109.5 .
H16A C16 H16B 109.5 .
C15 C16 H16C 109.5 .
H16A C16 H16C 109.5 .
H16B C16 H16C 109.5 .
C1 N1 Pb1 155.0(9) .
C2 N2 Pb1 155.0(9) .
C7 N3 C3 117.7(7) .
C7 N3 Pb1 114.6(6) .
C3 N3 Pb1 127.7(6) .
C10 N4 C14 116.7(8) .
C10 N4 Pb1 116.9(6) .
C14 N4 Pb1 124.5(6) .
C8 N5 N6 112.5(8) 4_666
C15 N6 N5 112.1(8) 4_465
N2 Pb1 N1 87.6(3) .
N2 Pb1 N3 78.4(3) .
N1 Pb1 N3 79.0(3) .
N2 Pb1 N4 81.3(3) .
N1 Pb1 N4 84.1(3) .
N3 Pb1 N4 154.0(3) .
N7 C17 S3 178.4(10) .
N8 C18 S4 178.8(10) .
N9 C19 C20 122.8(10) .
N9 C19 H19 118.6 .
C20 C19 H19 118.6 .
C21 C20 C19 120.5(10) .
C21 C20 H20 119.7 .
C19 C20 H20 119.7 .
C20 C21 C22 117.3(8) .
C20 C21 C24 121.4(9) .
C22 C21 C24 121.3(9) .
C21 C22 C23 118.0(9) .
C21 C22 H22 121.0 .
C23 C22 H22 121.0 .
N9 C23 C22 124.8(9) .
N9 C23 H23 117.6 .
C22 C23 H23 117.6 .
N11 C24 C21 114.9(9) .
N11 C24 C25 124.9(9) .
C21 C24 C25 120.1(8) .
C24 C25 H25A 109.5 .
C24 C25 H25B 109.5 .
H25A C25 H25B 109.5 .
C24 C25 H25C 109.5 .
H25A C25 H25C 109.5 .
H25B C25 H25C 109.5 .
N10 C26 C27 123.7(10) .
N10 C26 H26 118.1 .
C27 C26 H26 118.1 .
C26 C27 C28 119.7(9) .
C26 C27 H27 120.2 .
C28 C27 H27 120.2 .
C27 C28 C29 116.2(8) .
C27 C28 C31 121.4(8) .
C29 C28 C31 122.4(8) .
C30 C29 C28 120.4(9) .
C30 C29 H29 119.8 .
C28 C29 H29 119.8 .
N10 C30 C29 123.9(10) .
N10 C30 H30 118.0 .
C29 C30 H30 118.0 .
N12 C31 C32 124.7(9) .
N12 C31 C28 115.3(8) .
C32 C31 C28 120.0(9) .
C31 C32 H32A 109.5 .
C31 C32 H32B 109.5 .
H32A C32 H32B 109.5 .
C31 C32 H32C 109.5 .
H32A C32 H32C 109.5 .
H32B C32 H32C 109.5 .
C17 N7 Pb2 156.3(9) .
C18 N8 Pb2 161.7(9) .
C23 N9 C19 116.5(8) .
C23 N9 Pb2 124.4(6) .
C19 N9 Pb2 118.8(6) .
C26 N10 C30 116.0(8) .
C26 N10 Pb2 122.7(6) .
C30 N10 Pb2 121.0(6) .
C24 N11 N12 113.2(8) 1_655
C31 N12 N11 112.9(8) 1_455
N8 Pb2 N7 77.8(3) .
N8 Pb2 N10 84.3(3) .
N7 Pb2 N10 91.8(3) .
N8 Pb2 N9 83.1(3) .
N7 Pb2 N9 80.3(3) .
N10 Pb2 N9 166.3(3) .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C1 N1 1.165(14) .
C1 S1 1.617(12) .
C2 N2 1.154(12) .
C2 S2 1.609(11) .
C3 N3 1.319(11) .
C3 C4 1.383(12) .
C3 H3 0.9300 .
C4 C5 1.388(12) .
C4 H4 0.9300 .
C5 C6 1.373(12) .
C5 C8 1.509(11) .
C6 C7 1.394(12) .
C6 H6 0.9300 .
C7 N3 1.318(12) .
C7 H7 0.9300 .
C8 N5 1.293(12) .
C8 C9 1.459(13) .
C9 H9A 0.9600 .
C9 H9B 0.9600 .
C9 H9C 0.9600 .
C10 N4 1.319(12) .
C10 C11 1.370(13) .
C10 H10 0.9300 .
C11 C12 1.393(13) .
C11 H11 0.9300 .
C12 C13 1.367(12) .
C12 C15 1.488(12) .
C13 C14 1.370(13) .
C13 H13 0.9300 .
C14 N4 1.337(12) .
C14 H14 0.9300 .
C15 N6 1.282(13) .
C15 C16 1.471(14) .
C16 H16A 0.9600 .
C16 H16B 0.9600 .
C16 H16C 0.9600 .
N1 Pb1 2.408(11) .
N2 Pb1 2.348(8) .
N3 Pb1 2.574(7) .
N4 Pb1 2.629(8) .
N5 N6 1.408(10) 4_666
N6 N5 1.408(10) 4_465
C17 N7 1.151(12) .
C17 S3 1.622(10) .
C18 N8 1.122(14) .
C18 S4 1.604(11) .
C19 N9 1.334(13) .
C19 C20 1.375(13) .
C19 H19 0.9300 .
C20 C21 1.368(14) .
C20 H20 0.9300 .
C21 C22 1.386(13) .
C21 C24 1.487(12) .
C22 C23 1.389(13) .
C22 H22 0.9300 .
C23 N9 1.314(12) .
C23 H23 0.9300 .
C24 N11 1.281(12) .
C24 C25 1.504(14) .
C25 H25A 0.9600 .
C25 H25B 0.9600 .
C25 H25C 0.9600 .
C26 N10 1.327(13) .
C26 C27 1.375(13) .
C26 H26 0.9300 .
C27 C28 1.376(13) .
C27 H27 0.9300 .
C28 C29 1.386(13) .
C28 C31 1.497(11) .
C29 C30 1.346(14) .
C29 H29 0.9300 .
C30 N10 1.335(13) .
C30 H30 0.9300 .
C31 N12 1.286(12) .
C31 C32 1.450(14) .
C32 H32A 0.9600 .
C32 H32B 0.9600 .
C32 H32C 0.9600 .
N7 Pb2 2.504(9) .
N8 Pb2 2.415(11) .
N9 Pb2 2.650(8) .
N10 Pb2 2.606(8) .
N11 N12 1.391(10) 1_655
N12 N11 1.391(10) 1_455
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_4
N3 C3 C4 C5 -1.9(16) .
C3 C4 C5 C6 1.7(15) .
C3 C4 C5 C8 -177.2(9) .
C4 C5 C6 C7 -0.4(16) .
C8 C5 C6 C7 178.6(10) .
C5 C6 C7 N3 -1.1(18) .
C6 C5 C8 N5 -9.6(15) .
C4 C5 C8 N5 169.3(10) .
C6 C5 C8 C9 171.6(12) .
C4 C5 C8 C9 -9.5(16) .
N4 C10 C11 C12 2(2) .
C10 C11 C12 C13 0.0(18) .
C10 C11 C12 C15 179.7(11) .
C11 C12 C13 C14 -1.1(18) .
C15 C12 C13 C14 179.2(11) .
C12 C13 C14 N4 0(2) .
C13 C12 C15 N6 2.3(17) .
C11 C12 C15 N6 -177.5(11) .
C13 C12 C15 C16 -176.6(13) .
C11 C12 C15 C16 3.7(18) .
C6 C7 N3 C3 1.0(17) .
C6 C7 N3 Pb1 -179.8(9) .
C4 C3 N3 C7 0.5(16) .
C4 C3 N3 Pb1 -178.6(8) .
C11 C10 N4 C14 -2.6(18) .
C11 C10 N4 Pb1 162.4(10) .
C13 C14 N4 C10 1.4(18) .
C13 C14 N4 Pb1 -162.4(9) .
C9 C8 N5 N6 1.2(18) 4_666
C5 C8 N5 N6 -177.5(9) 4_666
C16 C15 N6 N5 -2.5(19) 4_465
C12 C15 N6 N5 178.7(10) 4_465
C2 N2 Pb1 N1 142(2) .
C2 N2 Pb1 N3 -138(2) .
C2 N2 Pb1 N4 58(2) .
C1 N1 Pb1 N2 148(2) .
C1 N1 Pb1 N3 69(2) .
C1 N1 Pb1 N4 -131(2) .
C7 N3 Pb1 N2 -157.9(8) .
C3 N3 Pb1 N2 21.2(9) .
C7 N3 Pb1 N1 -68.1(8) .
C3 N3 Pb1 N1 111.0(9) .
C7 N3 Pb1 N4 -118.4(8) .
C3 N3 Pb1 N4 60.8(11) .
C10 N4 Pb1 N2 161.8(9) .
C14 N4 Pb1 N2 -34.5(9) .
C10 N4 Pb1 N1 73.3(8) .
C14 N4 Pb1 N1 -123.0(10) .
C10 N4 Pb1 N3 122.7(8) .
C14 N4 Pb1 N3 -73.6(12) .
N9 C19 C20 C21 0(2) .
C19 C20 C21 C22 -1.2(18) .
C19 C20 C21 C24 178.8(11) .
C20 C21 C22 C23 0.5(16) .
C24 C21 C22 C23 -179.5(10) .
C21 C22 C23 N9 1.1(17) .
C20 C21 C24 N11 -5.9(16) .
C22 C21 C24 N11 174.1(10) .
C20 C21 C24 C25 175.3(11) .
C22 C21 C24 C25 -4.7(17) .
N10 C26 C27 C28 -1(2) .
C26 C27 C28 C29 1.5(17) .
C26 C27 C28 C31 178.9(11) .
C27 C28 C29 C30 0.0(17) .
C31 C28 C29 C30 -177.4(11) .
C28 C29 C30 N10 -2.0(19) .
C27 C28 C31 N12 -5.4(15) .
C29 C28 C31 N12 171.8(10) .
C27 C28 C31 C32 174.9(12) .
C29 C28 C31 C32 -7.8(16) .
C22 C23 N9 C19 -1.9(17) .
C22 C23 N9 Pb2 172.0(8) .
C20 C19 N9 C23 1.1(17) .
C20 C19 N9 Pb2 -173.1(9) .
C27 C26 N10 C30 -0.8(19) .
C27 C26 N10 Pb2 -173.6(10) .
C29 C30 N10 C26 2.4(18) .
C29 C30 N10 Pb2 175.4(9) .
C21 C24 N11 N12 -179.7(9) 1_655
C25 C24 N11 N12 -1.0(17) 1_655
C32 C31 N12 N11 -0.8(17) 1_455
C28 C31 N12 N11 179.6(9) 1_455
C18 N8 Pb2 N7 -169(4) .
C18 N8 Pb2 N10 -75(3) .
C18 N8 Pb2 N9 110(3) .
C17 N7 Pb2 N8 139(2) .
C17 N7 Pb2 N10 55(2) .
C17 N7 Pb2 N9 -136(2) .
C26 N10 Pb2 N8 -90.0(9) .
C30 N10 Pb2 N8 97.5(9) .
C26 N10 Pb2 N7 -12.4(9) .
C30 N10 Pb2 N7 175.1(9) .
C26 N10 Pb2 N9 -66.9(16) .
C30 N10 Pb2 N9 120.6(12) .
C23 N9 Pb2 N8 102.8(9) .
C19 N9 Pb2 N8 -83.5(8) .
C23 N9 Pb2 N7 24.0(8) .
C19 N9 Pb2 N7 -162.3(9) .
C23 N9 Pb2 N10 79.7(15) .
C19 N9 Pb2 N10 -106.6(13) .
