#------------------------------------------------------------------------------
#$Date: 2016-03-26 00:53:55 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180101 $
#$URL: svn://www.crystallography.net/cod/cif/7/05/47/7054713.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7054713
loop_
_publ_author_name
'Li, Shaobin'
'Zhang, Li'
'Ma, Huiyuan'
'Pang, Haijun'
'Zhao, Chunyan'
_publ_section_title
;
 Tuning the topology structures of polymolybdate-based hybrids from
 interpenetrated framework to interdigitated architecture via changing
 polymolybdate clusters
;
_journal_issue                   5
_journal_name_full               'New J. Chem.'
_journal_page_first              3528
_journal_paper_doi               10.1039/C5NJ00238A
_journal_volume                  39
_journal_year                    2015
_chemical_formula_sum            'C48 H44 Cu4 Mo12 N16 O42 Si'
_chemical_formula_weight         2950.53
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_audit_update_record
;
2015-01-13 deposited with the CCDC.
2015-02-13 downloaded from the CCDC.
;
_cell_angle_alpha                110.234(2)
_cell_angle_beta                 107.4080(10)
_cell_angle_gamma                102.6580(10)
_cell_formula_units_Z            1
_cell_length_a                   10.9784(9)
_cell_length_b                   14.0480(11)
_cell_length_c                   14.5469(12)
_cell_measurement_reflns_used    1719
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      23.16
_cell_measurement_theta_min      2.66
_cell_volume                     1873.7(3)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_molecular_graphics    'Bruker SMART'
_computing_publication_material  'Bruker SMART'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.995
_diffrn_measured_fraction_theta_max 0.995
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0302
_diffrn_reflns_av_sigmaI/netI    0.0756
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -8
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            9797
_diffrn_reflns_theta_full        25.14
_diffrn_reflns_theta_max         25.14
_diffrn_reflns_theta_min         1.64
_exptl_absorpt_coefficient_mu    3.164
_exptl_absorpt_correction_T_max  0.566
_exptl_absorpt_correction_T_min  0.444
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Sheldrick, 2003)'
_exptl_crystal_colour            brown
_exptl_crystal_density_diffrn    2.611
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1410.0
_exptl_crystal_size_max          0.26
_exptl_crystal_size_mid          0.22
_exptl_crystal_size_min          0.18
_refine_diff_density_max         1.202
_refine_diff_density_min         -0.965
_refine_diff_density_rms         0.168
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.041
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     574
_refine_ls_number_reflns         6667
_refine_ls_number_restraints     42
_refine_ls_restrained_S_all      1.077
_refine_ls_R_factor_all          0.0902
_refine_ls_R_factor_gt           0.0534
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0318P)²+10.0731P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0944
_refine_ls_wR_factor_ref         0.1073
_reflns_number_gt                4730
_reflns_number_total             6693
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c5nj00238a2.cif
_cod_data_source_block           Compound3
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 3086 2015-02-26 13:12:21Z robertas 

 Adding full bibliography for 7054711--7054713.cif.
;
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7054713
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Mo1 Mo 0.27968(9) 0.22788(6) 0.32308(7) 0.0296(2) Uani 1 1 d .
Mo2 Mo 0.33943(9) 0.45967(7) 0.66586(7) 0.0324(2) Uani 1 1 d .
Mo3 Mo 0.51917(9) 0.29147(7) 0.58019(7) 0.0297(2) Uani 1 1 d .
Mo4 Mo 0.69946(9) 0.57053(7) 0.76948(7) 0.0301(2) Uani 1 1 d .
Mo5 Mo 0.14302(8) 0.43186(7) 0.41097(8) 0.0328(2) Uani 1 1 d .
Mo6 Mo 0.36503(9) 0.69169(7) 0.61778(7) 0.0313(2) Uani 1 1 d .
Cu1 Cu 0.04715(14) -0.44199(10) -0.16068(11) 0.0428(4) Uani 1 1 d .
Cu2 Cu 0.70842(15) 0.57728(10) 0.07009(12) 0.0507(4) Uani 1 1 d .
Si1 Si 0.5000 0.5000 0.5000 0.0200(8) Uani 1 2 d S
N4 N 0.6296(9) 0.4257(6) -0.0065(7) 0.038(2) Uani 1 1 d .
N2 N 0.2274(8) -0.1186(6) -0.0388(6) 0.033(2) Uani 1 1 d .
C11 C 0.4563(10) 0.1602(7) -0.0423(8) 0.031(2) Uani 1 1 d .
N6 N 0.8519(8) 0.8954(6) 0.2725(7) 0.035(2) Uani 1 1 d .
N8 N -0.0980(8) -0.7610(6) -0.3582(7) 0.035(2) Uani 1 1 d .
N7 N -0.0279(8) -0.5929(6) -0.2316(7) 0.038(2) Uani 1 1 d .
C8 C 0.5653(11) 0.3591(8) 0.0224(8) 0.038(3) Uani 1 1 d .
H8 H 0.5454 0.3810 0.0825 0.046 Uiso 1 1 calc R
N3 N 0.5315(8) 0.2540(6) -0.0469(6) 0.0297(19) Uani 1 1 d .
C15 C 0.3546(11) 0.0777(7) 0.0471(8) 0.044(3) Uani 1 1 d .
H15 H 0.3376 0.0835 0.1073 0.053 Uiso 1 1 calc R
N1 N 0.1244(9) -0.2914(6) -0.0843(7) 0.041(2) Uani 1 1 d .
N5 N 0.7837(9) 0.7296(6) 0.1446(8) 0.044(2) Uani 1 1 d .
O14 O 0.1829(8) 0.1007(5) 0.2336(5) 0.050(2) Uani 1 1 d .
C14 C 0.3046(10) -0.0226(7) -0.0405(8) 0.032(2) Uani 1 1 d .
C7 C 0.7865(11) 0.7890(8) 0.2381(9) 0.041(3) Uani 1 1 d .
H7 H 0.7475 0.7606 0.2760 0.049 Uiso 1 1 calc R
C12 C 0.4088(12) 0.0601(8) -0.1296(8) 0.041(3) Uani 1 1 d .
H12 H 0.4287 0.0540 -0.1888 0.049 Uiso 1 1 calc R
O3 O 0.3493(8) 0.2123(8) 0.4431(6) 0.077(3) Uani 1 1 d .
C22 C -0.0313(10) -0.6535(8) -0.3266(8) 0.034(2) Uani 1 1 d .
H22 H 0.0064 -0.6263 -0.3658 0.041 Uiso 1 1 calc R
O7 O 0.5123(7) 0.1898(6) 0.6144(7) 0.052(2) Uani 1 1 d .
C13 C 0.3329(11) -0.0297(8) -0.1283(8) 0.039(3) Uani 1 1 d .
H13 H 0.2996 -0.0969 -0.1875 0.047 Uiso 1 1 calc R
C16 C 0.4291(11) 0.1683(8) 0.0455(8) 0.044(3) Uani 1 1 d .
H16 H 0.4614 0.2357 0.1042 0.053 Uiso 1 1 calc R
O12 O 0.3505(10) 0.6119(6) 0.6896(7) 0.082(3) Uani 1 1 d U
C20 C -0.0939(11) -0.6653(9) -0.2044(9) 0.046(3) Uani 1 1 d .
H20 H -0.1065 -0.6458 -0.1409 0.055 Uiso 1 1 calc R
C3 C 0.7826(13) 0.9637(9) 0.4173(10) 0.063(4) Uani 1 1 d .
H3 H 0.7181 0.8949 0.3912 0.075 Uiso 1 1 calc R
C9 C 0.6367(13) 0.3615(9) -0.0997(9) 0.050(3) Uani 1 1 d .
H9 H 0.6762 0.3868 -0.1391 0.060 Uiso 1 1 calc R
C5 C 0.8947(11) 0.9043(8) 0.1952(9) 0.043(3) Uani 1 1 d .
H5 H 0.9432 0.9681 0.1962 0.051 Uiso 1 1 calc R
C6 C 0.8527(11) 0.8021(9) 0.1175(10) 0.047(3) Uani 1 1 d .
H6 H 0.8681 0.7838 0.0552 0.056 Uiso 1 1 calc R
O2 O 0.6491(7) 0.4084(6) 0.6992(7) 0.074(3) Uani 1 1 d .
O4 O 0.2733(9) 0.2960(7) 0.2211(7) 0.068(3) Uani 1 1 d U
O1 O 0.8326(10) 0.5585(6) 0.7053(7) 0.067(3) Uani 1 1 d U
O9 O 0.1994(10) 0.5750(6) 0.4920(7) 0.082(3) Uani 1 1 d U
C21 C -0.1385(12) -0.7675(9) -0.2793(10) 0.051(3) Uani 1 1 d .
H21 H -0.1870 -0.8301 -0.2782 0.061 Uiso 1 1 calc R
C2 C 0.8646(10) 0.9824(7) 0.3653(9) 0.035(3) Uani 1 1 d .
C19 C 0.1948(11) -0.2220(8) -0.1071(8) 0.045(3) Uani 1 1 d .
H19 H 0.2198 -0.2424 -0.1647 0.053 Uiso 1 1 calc R
O8 O 0.5297(7) 0.5440(6) 0.7715(7) 0.067(3) Uani 1 1 d U
O6 O 0.6183(7) 0.2739(8) 0.5014(6) 0.072(3) Uani 1 1 d .
C4 C 0.7975(13) 1.0487(8) 0.5092(11) 0.064(4) Uani 1 1 d .
H4 H 0.7461 1.0356 0.5470 0.077 Uiso 1 1 calc R
C1 C 0.9544(13) 1.0837(8) 0.4029(9) 0.058(4) Uani 1 1 d .
H1 H 1.0093 1.0964 0.3674 0.070 Uiso 1 1 calc R
O5 O 0.4527(7) 0.2286(8) 0.3057(6) 0.071(3) Uani 1 1 d .
C18 C 0.1110(12) -0.2273(9) 0.0059(9) 0.050(3) Uani 1 1 d .
H18 H 0.0665 -0.2533 0.0424 0.060 Uiso 1 1 calc R
C17 C 0.1724(12) -0.1212(8) 0.0330(9) 0.050(3) Uani 1 1 d .
H17 H 0.1763 -0.0617 0.0896 0.060 Uiso 1 1 calc R
C10 C 0.5770(13) 0.2562(9) -0.1243(10) 0.055(3) Uani 1 1 d .
H10 H 0.5684 0.1963 -0.1829 0.066 Uiso 1 1 calc R
O10 O 0.3523(12) 0.4189(9) 0.3950(9) 0.022(3) Uani 0.50 1 d P
O17 O -0.0247(7) 0.3931(6) 0.3652(6) 0.053(2) Uani 1 1 d .
O15 O 0.7968(7) 0.5917(5) 0.8916(5) 0.0435(19) Uani 1 1 d .
O16 O 0.2705(7) 0.4514(5) 0.7516(5) 0.045(2) Uani 1 1 d .
O21 O 0.1578(10) 0.2849(7) 0.3550(8) 0.072(3) Uani 1 1 d U
O20 O 0.3790(7) 0.3376(6) 0.6293(8) 0.084(4) Uani 1 1 d .
C23 C 0.8865(9) 1.1515(8) 0.5451(8) 0.034(2) Uani 1 1 d .
O18 O 0.1864(10) 0.4115(6) 0.5427(6) 0.074(3) Uani 1 1 d U
C24 C 0.9665(13) 1.1677(9) 0.4916(10) 0.058(4) Uani 1 1 d .
H24 H 1.0297 1.2366 0.5161 0.070 Uiso 1 1 calc R
O19 O 0.4883(11) 0.3752(8) 0.4624(9) 0.020(3) Uani 0.50 1 d P
O13 O 0.2951(8) 0.7803(6) 0.6619(6) 0.057(2) Uani 1 1 d .
O1W O 0.5754(11) 0.0174(8) 0.6780(9) 0.099(4) Uani 1 1 d .
O11 O 0.3751(12) 0.5169(8) 0.5383(9) 0.019(3) Uani 0.50 1 d P
O22 O 0.5104(12) 0.4650(8) 0.5962(9) 0.021(3) Uani 0.50 1 d P
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Mo Mo -1.6832 0.6857 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O14 Mo1 O21 103.1(4) . .
O14 Mo1 O3 101.9(4) . .
O21 Mo1 O3 97.9(4) . .
O14 Mo1 O5 97.9(4) . .
O21 Mo1 O5 156.5(4) . .
O3 Mo1 O5 87.8(3) . .
O14 Mo1 O4 98.5(4) . .
O21 Mo1 O4 87.8(3) . .
O3 Mo1 O4 157.0(4) . .
O5 Mo1 O4 78.8(3) . .
O14 Mo1 O10 156.0(4) . .
O21 Mo1 O10 64.8(4) . .
O3 Mo1 O10 100.3(4) . .
O5 Mo1 O10 91.8(4) . .
O4 Mo1 O10 61.9(4) . .
O14 Mo1 O19 156.0(4) . .
O21 Mo1 O19 98.7(4) . .
O3 Mo1 O19 65.0(4) . .
O5 Mo1 O19 63.0(3) . .
O4 Mo1 O19 92.2(4) . .
O10 Mo1 O19 46.1(4) . .
O16 Mo2 O20 102.2(4) . .
O16 Mo2 O18 101.3(4) . .
O20 Mo2 O18 97.0(4) . .
O16 Mo2 O8 97.6(4) . .
O20 Mo2 O8 90.1(3) . .
O18 Mo2 O8 157.8(4) . .
O16 Mo2 O12 97.3(4) . .
O20 Mo2 O12 158.8(4) . .
O18 Mo2 O12 87.2(3) . .
O8 Mo2 O12 79.0(4) . .
O16 Mo2 O11 154.6(4) . .
O20 Mo2 O11 100.8(4) . .
O18 Mo2 O11 65.1(4) . .
O8 Mo2 O11 92.9(4) . .
O12 Mo2 O11 62.1(4) . .
O16 Mo2 O22 156.4(4) . .
O20 Mo2 O22 65.7(4) . .
O18 Mo2 O22 100.2(4) . .
O8 Mo2 O22 63.7(4) . .
O12 Mo2 O22 93.1(4) . .
O11 Mo2 O22 47.1(4) . .
O7 Mo3 O6 103.1(4) . .
O7 Mo3 O2 103.9(4) . .
O6 Mo3 O2 97.6(4) . .
O7 Mo3 O3 97.3(4) . .
O6 Mo3 O3 88.5(3) . .
O2 Mo3 O3 155.9(4) . .
O7 Mo3 O20 97.5(4) . .
O6 Mo3 O20 156.8(4) . .
O2 Mo3 O20 87.6(3) . .
O3 Mo3 O20 78.4(3) . .
O7 Mo3 O19 156.8(4) . .
O6 Mo3 O19 65.5(4) . .
O2 Mo3 O19 97.9(4) . .
O3 Mo3 O19 63.5(4) . .
O20 Mo3 O19 91.4(4) . .
O7 Mo3 O22 156.0(4) . .
O6 Mo3 O22 99.1(4) . .
O2 Mo3 O22 63.9(4) . .
O3 Mo3 O22 92.1(4) . .
O20 Mo3 O22 62.9(4) . .
O19 Mo3 O22 44.9(4) . .
O15 Mo4 O4 103.8(4) . 2_666
O15 Mo4 O8 102.1(4) . .
O4 Mo4 O8 96.9(4) 2_666 .
O15 Mo4 O1 98.5(4) . .
O4 Mo4 O1 89.3(3) 2_666 .
O8 Mo4 O1 156.3(4) . .
O15 Mo4 O2 96.7(4) . .
O4 Mo4 O2 157.8(4) 2_666 .
O8 Mo4 O2 86.9(3) . .
O1 Mo4 O2 79.2(3) . .
O15 Mo4 O10 157.0(4) . 2_666
O4 Mo4 O10 64.8(4) 2_666 2_666
O8 Mo4 O10 99.2(4) . 2_666
O1 Mo4 O10 62.9(4) . 2_666
O2 Mo4 O10 92.9(4) . 2_666
O15 Mo4 O22 153.7(4) . .
O4 Mo4 O22 100.5(4) 2_666 .
O8 Mo4 O22 64.8(4) . .
O1 Mo4 O22 91.6(4) . .
O2 Mo4 O22 61.3(4) . .
O10 Mo4 O22 47.0(4) 2_666 .
O17 Mo5 O9 103.3(4) . .
O17 Mo5 O1 99.9(4) . 2_666
O9 Mo5 O1 96.2(4) . 2_666
O17 Mo5 O18 100.9(4) . .
O9 Mo5 O18 88.9(3) . .
O1 Mo5 O18 156.8(4) 2_666 .
O17 Mo5 O21 98.6(4) . .
O9 Mo5 O21 157.2(4) . .
O1 Mo5 O21 86.3(3) 2_666 .
O18 Mo5 O21 80.6(4) . .
O17 Mo5 O11 158.3(4) . .
O9 Mo5 O11 64.1(4) . .
O1 Mo5 O11 99.0(4) 2_666 .
O18 Mo5 O11 63.0(4) . .
O21 Mo5 O11 93.1(4) . .
O17 Mo5 O10 152.7(4) . .
O9 Mo5 O10 99.8(4) . .
O1 Mo5 O10 63.0(4) 2_666 .
O18 Mo5 O10 93.9(4) . .
O21 Mo5 O10 61.1(4) . .
O11 Mo5 O10 48.3(4) . .
O13 Mo6 O12 103.3(5) . .
O13 Mo6 O5 102.3(4) . 2_666
O12 Mo6 O5 97.5(4) . 2_666
O13 Mo6 O9 99.1(4) . .
O12 Mo6 O9 88.8(4) . .
O5 Mo6 O9 155.6(4) 2_666 .
O13 Mo6 O6 97.2(4) . 2_666
O12 Mo6 O6 157.4(4) . 2_666
O5 Mo6 O6 87.1(3) 2_666 2_666
O9 Mo6 O6 78.6(3) . 2_666
O13 Mo6 O11 156.3(4) . .
O12 Mo6 O11 64.6(4) . .
O5 Mo6 O11 99.6(4) 2_666 .
O9 Mo6 O11 61.9(4) . .
O6 Mo6 O11 92.8(4) 2_666 .
O13 Mo6 O19 155.1(4) . 2_666
O12 Mo6 O19 99.7(4) . 2_666
O5 Mo6 O19 65.0(4) 2_666 2_666
O9 Mo6 O19 90.7(4) . 2_666
O6 Mo6 O19 62.2(4) 2_666 2_666
O11 Mo6 O19 46.4(3) . 2_666
N7 Cu1 N1 177.6(4) . .
N4 Cu2 N5 178.6(4) . .
O19 Si1 O19 180.0(9) . 2_666
O19 Si1 O22 111.2(5) . 2_666
O19 Si1 O22 68.8(5) 2_666 2_666
O19 Si1 O22 68.8(5) . .
O19 Si1 O22 111.2(5) 2_666 .
O22 Si1 O22 180.000(4) 2_666 .
O19 Si1 O11 70.6(5) . 2_666
O19 Si1 O11 109.4(5) 2_666 2_666
O22 Si1 O11 70.7(6) 2_666 2_666
O22 Si1 O11 109.3(6) . 2_666
O19 Si1 O11 109.4(5) . .
O19 Si1 O11 70.6(5) 2_666 .
O22 Si1 O11 109.3(6) 2_666 .
O22 Si1 O11 70.7(6) . .
O11 Si1 O11 180.000(3) 2_666 .
O19 Si1 O10 110.1(6) . 2_666
O19 Si1 O10 69.9(6) 2_666 2_666
O22 Si1 O10 109.2(6) 2_666 2_666
O22 Si1 O10 70.8(5) . 2_666
O11 Si1 O10 72.4(5) 2_666 2_666
O11 Si1 O10 107.6(5) . 2_666
O19 Si1 O10 69.9(6) . .
O19 Si1 O10 110.1(6) 2_666 .
O22 Si1 O10 70.8(5) 2_666 .
O22 Si1 O10 109.2(6) . .
O11 Si1 O10 107.6(5) 2_666 .
O11 Si1 O10 72.4(5) . .
O10 Si1 O10 180.000(2) 2_666 .
C8 N4 C9 106.3(8) . .
C8 N4 Cu2 126.4(7) . .
C9 N4 Cu2 127.1(7) . .
C19 N2 C17 106.6(8) . .
C19 N2 C14 127.1(8) . .
C17 N2 C14 126.3(8) . .
C16 C11 C12 120.0(9) . .
C16 C11 N3 121.4(8) . .
C12 C11 N3 118.6(8) . .
C7 N6 C5 106.3(8) . .
C7 N6 C2 127.1(9) . .
C5 N6 C2 126.4(8) . .
C22 N8 C21 107.0(8) . .
C22 N8 C23 124.4(8) . 1_434
C21 N8 C23 128.5(8) . 1_434
C22 N7 C20 104.8(9) . .
C22 N7 Cu1 125.0(7) . .
C20 N7 Cu1 130.1(8) . .
N4 C8 N3 111.1(9) . .
C8 N3 C10 106.5(8) . .
C8 N3 C11 126.2(8) . .
C10 N3 C11 127.2(8) . .
C16 C15 C14 120.2(9) . .
C19 N1 C18 104.4(9) . .
C19 N1 Cu1 128.4(7) . .
C18 N1 Cu1 127.1(7) . .
C7 N5 C6 105.3(9) . .
C7 N5 Cu2 126.2(8) . .
C6 N5 Cu2 128.4(8) . .
C15 C14 C13 119.0(9) . .
C15 C14 N2 120.4(9) . .
C13 C14 N2 120.5(8) . .
N5 C7 N6 112.2(9) . .
C13 C12 C11 119.5(9) . .
Mo1 O3 Mo3 136.6(5) . .
N7 C22 N8 110.4(9) . .
C12 C13 C14 121.0(9) . .
C15 C16 C11 120.3(9) . .
Mo6 O12 Mo2 136.4(6) . .
C21 C20 N7 112.2(10) . .
C2 C3 C4 119.2(10) . .
C10 C9 N4 108.9(10) . .
C6 C5 N6 106.6(9) . .
C5 C6 N5 109.5(10) . .
Mo3 O2 Mo4 138.6(6) . .
Mo4 O4 Mo1 136.0(5) 2_666 .
Mo5 O1 Mo4 138.0(5) 2_666 .
Mo5 O9 Mo6 137.7(6) . .
C20 C21 N8 105.6(9) . .
C1 C2 C3 119.2(10) . .
C1 C2 N6 121.3(9) . .
C3 C2 N6 119.5(8) . .
N1 C19 N2 112.9(9) . .
Mo4 O8 Mo2 136.6(4) . .
Mo3 O6 Mo6 137.1(5) . 2_666
C23 C4 C3 121.0(11) . .
C2 C1 C24 121.5(11) . .
Mo6 O5 Mo1 137.5(5) 2_666 .
C17 C18 N1 109.7(9) . .
C18 C17 N2 106.4(9) . .
C9 C10 N3 107.2(9) . .
Si1 O10 Mo4 121.3(5) . 2_666
Si1 O10 Mo1 122.3(6) . .
Mo4 O10 Mo1 96.9(4) 2_666 .
Si1 O10 Mo5 118.3(5) . .
Mo4 O10 Mo5 96.0(4) 2_666 .
Mo1 O10 Mo5 96.1(4) . .
Mo1 O21 Mo5 138.0(5) . .
Mo2 O20 Mo3 135.6(5) . .
C4 C23 C24 118.4(10) . .
C4 C23 N8 120.3(9) . 1_676
C24 C23 N8 121.1(9) . 1_676
Mo2 O18 Mo5 135.8(5) . .
C1 C24 C23 120.5(10) . .
Si1 O19 O22 55.8(5) . .
Si1 O19 Mo3 123.6(6) . .
O22 O19 Mo3 68.0(5) . .
Si1 O19 Mo6 121.0(6) . 2_666
O22 O19 Mo6 135.9(7) . 2_666
Mo3 O19 Mo6 94.9(4) . 2_666
Si1 O19 Mo1 121.2(6) . .
O22 O19 Mo1 126.2(6) . .
Mo3 O19 Mo1 94.7(4) . .
Mo6 O19 Mo1 94.3(4) 2_666 .
Si1 O11 Mo2 120.5(6) . .
Si1 O11 Mo6 121.4(5) . .
Mo2 O11 Mo6 96.7(4) . .
Si1 O11 Mo5 120.4(5) . .
Mo2 O11 Mo5 95.9(4) . .
Mo6 O11 Mo5 95.9(4) . .
Si1 O22 O19 55.3(5) . .
Si1 O22 Mo2 121.3(6) . .
O19 O22 Mo2 126.3(6) . .
Si1 O22 Mo3 122.2(6) . .
O19 O22 Mo3 67.1(5) . .
Mo2 O22 Mo3 95.5(4) . .
Si1 O22 Mo4 120.5(5) . .
O19 O22 Mo4 135.6(7) . .
Mo2 O22 Mo4 94.7(4) . .
Mo3 O22 Mo4 96.0(4) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Mo1 O14 1.658(6) .
Mo1 O21 1.798(7) .
Mo1 O3 1.795(9) .
Mo1 O5 1.989(7) .
Mo1 O4 2.018(8) .
Mo1 O10 2.357(11) .
Mo1 O19 2.425(11) .
Mo2 O16 1.664(6) .
Mo2 O20 1.802(8) .
Mo2 O18 1.830(8) .
Mo2 O8 1.966(7) .
Mo2 O12 2.014(8) .
Mo2 O11 2.361(11) .
Mo2 O22 2.384(11) .
Mo3 O7 1.661(7) .
Mo3 O6 1.797(7) .
Mo3 O2 1.805(7) .
Mo3 O3 2.005(8) .
Mo3 O20 2.017(7) .
Mo3 O19 2.379(12) .
Mo3 O22 2.394(11) .
Mo4 O15 1.657(7) .
Mo4 O4 1.782(8) 2_666
Mo4 O8 1.830(7) .
Mo4 O1 1.963(7) .
Mo4 O2 2.010(7) .
Mo4 O10 2.354(12) 2_666
Mo4 O22 2.408(12) .
Mo5 O17 1.645(7) .
Mo5 O9 1.788(8) .
Mo5 O1 1.834(7) 2_666
Mo5 O18 1.969(8) .
Mo5 O21 2.003(8) .
Mo5 O11 2.379(12) .
Mo5 O10 2.416(11) .
Mo6 O13 1.647(6) .
Mo6 O12 1.791(8) .
Mo6 O5 1.822(8) 2_666
Mo6 O9 1.992(8) .
Mo6 O6 2.000(8) 2_666
Mo6 O11 2.369(11) .
Mo6 O19 2.421(10) 2_666
Cu1 N7 1.858(8) .
Cu1 N1 1.858(8) .
Cu2 N4 1.870(8) .
Cu2 N5 1.876(8) .
Si1 O19 1.608(10) .
Si1 O19 1.608(10) 2_666
Si1 O22 1.617(11) 2_666
Si1 O22 1.617(11) .
Si1 O11 1.659(10) 2_666
Si1 O11 1.659(10) .
Si1 O10 1.662(11) 2_666
Si1 O10 1.662(11) .
N4 C8 1.307(12) .
N4 C9 1.381(13) .
N2 C19 1.337(11) .
N2 C17 1.360(12) .
N2 C14 1.440(11) .
C11 C16 1.370(13) .
C11 C12 1.382(12) .
C11 N3 1.428(11) .
N6 C7 1.340(11) .
N6 C5 1.374(13) .
N6 C2 1.416(12) .
N8 C22 1.365(11) .
N8 C21 1.373(13) .
N8 C23 1.444(12) 1_434
N7 C22 1.332(12) .
N7 C20 1.357(13) .
C8 N3 1.357(11) .
N3 C10 1.368(12) .
C15 C16 1.365(13) .
C15 C14 1.382(12) .
N1 C19 1.306(13) .
N1 C18 1.382(12) .
N5 C7 1.314(13) .
N5 C6 1.374(13) .
C14 C13 1.377(13) .
C12 C13 1.361(13) .
C20 C21 1.334(14) .
C3 C2 1.376(14) .
C3 C4 1.385(15) .
C9 C10 1.346(14) .
C5 C6 1.351(14) .
O4 Mo4 1.782(8) 2_666
O1 Mo5 1.834(7) 2_666
C2 C1 1.349(13) .
O6 Mo6 2.000(8) 2_666
C4 C23 1.367(13) .
C1 C24 1.360(15) .
O5 Mo6 1.822(7) 2_666
C18 C17 1.352(14) .
O10 Mo4 2.354(12) 2_666
C23 C24 1.369(14) .
C23 N8 1.444(12) 1_676
O19 O22 1.823(15) .
O19 Mo6 2.421(10) 2_666
