#------------------------------------------------------------------------------
#$Date: 2016-02-13 14:50:18 +0200 (Sat, 13 Feb 2016) $
#$Revision: 176428 $
#$URL: svn://www.crystallography.net/cod/cif/7/05/49/7054976.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7054976
loop_
_publ_author_name
'Wu, Huilu'
'Zhang, Jiawen'
'Chen, Chengyong'
'Zhang, Han'
'Peng, Hongping'
'Wang, Fei'
'Yang, Zaihui'
_publ_section_title
;
 Synthesis, crystal structure, and DNA-binding studies of different
 coordinate binuclear silver(i) complexes with benzimidazole open-chain
 ether ligands
;
_journal_issue                   9
_journal_name_full               'New J. Chem.'
_journal_page_first              7172
_journal_paper_doi               10.1039/C5NJ01684C
_journal_volume                  39
_journal_year                    2015
_chemical_formula_sum            'C48 H44 Ag2 N14 O18'
_chemical_formula_weight         1320.71
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_audit_update_record
;
2015-06-19 deposited with the CCDC.
2015-07-02 downloaded from the CCDC.
;
_cell_angle_alpha                110.5830(10)
_cell_angle_beta                 102.7630(10)
_cell_angle_gamma                97.5890(10)
_cell_formula_units_Z            1
_cell_length_a                   7.09520(10)
_cell_length_b                   12.8978(3)
_cell_length_c                   15.0574(4)
_cell_measurement_reflns_used    7749
_cell_measurement_temperature    153(2)
_cell_measurement_theta_max      27.5
_cell_measurement_theta_min      3.16
_cell_volume                     1224.46(5)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART APEX II'
_computing_data_reduction        'Bruker SAINT'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      153(2)
_diffrn_measured_fraction_theta_full 0.991
_diffrn_measured_fraction_theta_max 0.991
_diffrn_measurement_device_type  'Bruker APEX II area detector'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0151
_diffrn_reflns_av_sigmaI/netI    0.0192
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_h_min       -8
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            12128
_diffrn_reflns_theta_full        27.48
_diffrn_reflns_theta_max         27.48
_diffrn_reflns_theta_min         3.02
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    0.895
_exptl_absorpt_correction_T_max  0.874
_exptl_absorpt_correction_T_min  0.790
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.791
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             668
_exptl_crystal_size_max          0.29
_exptl_crystal_size_mid          0.22
_exptl_crystal_size_min          0.15
_refine_diff_density_max         0.519
_refine_diff_density_min         -0.582
_refine_diff_density_rms         0.115
_refine_ls_extinction_coef       0.0052(8)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.031
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     379
_refine_ls_number_reflns         5557
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.031
_refine_ls_R_factor_all          0.0245
_refine_ls_R_factor_gt           0.0223
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0515P)²+0.9730P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0731
_refine_ls_wR_factor_ref         0.0781
_reflns_number_gt                5204
_reflns_number_total             5557
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c5nj01684c1.cif
_cod_data_source_block           g0531
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 3271 2015-04-21 07:52:19Z andrius 

 Adding full bibliography for 7054975--7054977.cif.
;
_cod_original_sg_symbol_H-M      P_-1
_cod_database_code               7054976
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ag Ag 0.66384(2) 0.735797(12) 0.156651(10) 0.01770(7) Uani 1 1 d .
O1 O 0.3144(2) 0.40855(12) 0.15284(10) 0.0153(3) Uani 1 1 d .
O2 O 0.0434(2) 0.61242(13) 0.15297(11) 0.0211(3) Uani 1 1 d .
O3 O 0.2723(3) 0.81388(17) 0.16226(14) 0.0376(4) Uani 1 1 d .
O4 O 0.1434(3) 0.93461(14) 0.25692(12) 0.0307(4) Uani 1 1 d .
O5 O 0.4108(3) 0.94396(13) 0.59598(12) 0.0274(4) Uani 1 1 d .
O6 O 0.3825(3) 0.78299(14) 0.61281(11) 0.0280(4) Uani 1 1 d .
O7 O -0.0645(2) 0.43372(13) 0.20130(11) 0.0210(3) Uani 1 1 d .
O8 O 0.1360(3) 0.43468(14) 0.33191(12) 0.0305(4) Uani 1 1 d .
O9 O 0.2588(3) 0.58159(17) 0.00659(14) 0.0280(4) Uani 1 1 d .
N1 N 0.6418(2) 0.66286(14) 0.26031(12) 0.0137(3) Uani 1 1 d .
N2 N 0.6434(2) 0.53988(14) 0.33328(12) 0.0146(3) Uani 1 1 d .
N3 N 0.2656(2) 0.17463(14) -0.07104(12) 0.0133(3) Uani 1 1 d .
N4 N 0.2340(2) 0.14304(13) 0.06168(12) 0.0125(3) Uani 1 1 d .
N5 N 0.2066(3) 0.84816(15) 0.23331(13) 0.0205(4) Uani 1 1 d .
N6 N 0.3664(3) 0.83903(15) 0.56119(13) 0.0187(3) Uani 1 1 d .
N7 N 0.0665(3) 0.48381(15) 0.27951(13) 0.0169(3) Uani 1 1 d .
C1 C 0.7204(3) 0.72306(16) 0.36216(14) 0.0132(3) Uani 1 1 d .
C2 C 0.7903(3) 0.83979(18) 0.41789(16) 0.0205(4) Uani 1 1 d .
H2A H 0.7910 0.8928 0.3872 0.025 Uiso 1 1 calc R
C3 C 0.8586(3) 0.87520(19) 0.51971(17) 0.0259(5) Uani 1 1 d .
H3A H 0.9066 0.9542 0.5596 0.031 Uiso 1 1 calc R
C4 C 0.8588(4) 0.7974(2) 0.56563(16) 0.0280(5) Uani 1 1 d .
H4A H 0.9071 0.8252 0.6358 0.034 Uiso 1 1 calc R
C5 C 0.7907(3) 0.6815(2) 0.51150(16) 0.0231(4) Uani 1 1 d .
H5A H 0.7909 0.6286 0.5423 0.028 Uiso 1 1 calc R
C6 C 0.7215(3) 0.64660(16) 0.40888(14) 0.0145(4) Uani 1 1 d .
C7 C 0.5983(3) 0.55424(16) 0.24662(14) 0.0141(4) Uani 1 1 d .
C8 C 0.5023(3) 0.45886(17) 0.14860(15) 0.0167(4) Uani 1 1 d .
H8A H 0.4842 0.4876 0.0951 0.020 Uiso 1 1 calc R
H8B H 0.5851 0.4022 0.1357 0.020 Uiso 1 1 calc R
C9 C 0.1898(3) 0.33269(16) 0.05801(14) 0.0152(4) Uani 1 1 d .
H9A H 0.1961 0.3694 0.0106 0.018 Uiso 1 1 calc R
H9B H 0.0512 0.3205 0.0613 0.018 Uiso 1 1 calc R
C10 C 0.2392(3) 0.21879(16) 0.01803(14) 0.0123(3) Uani 1 1 d .
C11 C 0.2528(3) 0.04169(16) -0.00486(14) 0.0128(3) Uani 1 1 d .
C12 C 0.2538(3) -0.06346(17) 0.00114(15) 0.0152(4) Uani 1 1 d .
H12A H 0.2441 -0.0756 0.0588 0.018 Uiso 1 1 calc R
C13 C 0.2696(3) -0.14941(17) -0.08152(16) 0.0180(4) Uani 1 1 d .
H13A H 0.2708 -0.2227 -0.0808 0.022 Uiso 1 1 calc R
C14 C 0.2841(3) -0.13062(17) -0.16668(15) 0.0188(4) Uani 1 1 d .
H14A H 0.2920 -0.1921 -0.2225 0.023 Uiso 1 1 calc R
C15 C 0.2872(3) -0.02534(18) -0.17139(14) 0.0175(4) Uani 1 1 d .
H15A H 0.2996 -0.0129 -0.2286 0.021 Uiso 1 1 calc R
C16 C 0.2713(3) 0.06183(16) -0.08843(14) 0.0131(3) Uani 1 1 d .
C17 C 0.6214(3) 0.43249(18) 0.34685(17) 0.0233(4) Uani 1 1 d .
H17A H 0.5629 0.3690 0.2823 0.035 Uiso 1 1 calc R
H17B H 0.5346 0.4323 0.3892 0.035 Uiso 1 1 calc R
H17C H 0.7520 0.4242 0.3782 0.035 Uiso 1 1 calc R
C18 C 0.2139(3) 0.16111(17) 0.16011(14) 0.0162(4) Uani 1 1 d .
H18A H 0.2039 0.2397 0.1932 0.024 Uiso 1 1 calc R
H18B H 0.3304 0.1471 0.1992 0.024 Uiso 1 1 calc R
H18C H 0.0940 0.1086 0.1540 0.024 Uiso 1 1 calc R
C19 C 0.1228(3) 0.65997(17) 0.24425(14) 0.0152(4) Uani 1 1 d .
C20 C 0.2073(3) 0.78196(17) 0.29482(15) 0.0158(4) Uani 1 1 d .
C21 C 0.2825(3) 0.84054(17) 0.39469(15) 0.0169(4) Uani 1 1 d .
H21A H 0.3279 0.9210 0.4225 0.020 Uiso 1 1 calc R
C22 C 0.2911(3) 0.77943(17) 0.45516(14) 0.0156(4) Uani 1 1 d .
C23 C 0.2246(3) 0.66269(17) 0.41502(14) 0.0158(4) Uani 1 1 d .
H23A H 0.2358 0.6218 0.4568 0.019 Uiso 1 1 calc R
C24 C 0.1418(3) 0.60531(16) 0.31412(14) 0.0146(4) Uani 1 1 d .
H9BO H 0.205(5) 0.599(3) 0.049(3) 0.037(8) Uiso 1 1 d .
H9AO H 0.175(4) 0.537(3) -0.041(2) 0.022(7) Uiso 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N3 Ag N1 169.94(6) 2_665 .
C9 O1 C8 112.12(14) . .
H9BO O9 H9AO 105(3) . .
C7 N1 C1 105.72(16) . .
C7 N1 Ag 129.50(13) . .
C1 N1 Ag 123.11(13) . .
C7 N2 C6 107.53(16) . .
C7 N2 C17 127.46(17) . .
C6 N2 C17 124.99(17) . .
C10 N3 C16 106.05(15) . .
C10 N3 Ag 126.54(13) . 2_665
C16 N3 Ag 126.57(13) . 2_665
C10 N4 C11 107.18(15) . .
C10 N4 C18 128.13(16) . .
C11 N4 C18 124.68(16) . .
O4 N5 O3 124.36(18) . .
O4 N5 C20 118.06(18) . .
O3 N5 C20 117.56(17) . .
O6 N6 O5 123.09(18) . .
O6 N6 C22 118.58(17) . .
O5 N6 C22 118.32(17) . .
O7 N7 O8 122.29(18) . .
O7 N7 C24 119.57(17) . .
O8 N7 C24 118.13(17) . .
N1 C1 C2 130.41(18) . .
N1 C1 C6 109.19(16) . .
C2 C1 C6 120.40(18) . .
C3 C2 C1 117.3(2) . .
C3 C2 H2A 121.4 . .
C1 C2 H2A 121.4 . .
C2 C3 C4 121.7(2) . .
C2 C3 H3A 119.1 . .
C4 C3 H3A 119.1 . .
C5 C4 C3 121.8(2) . .
C5 C4 H4A 119.1 . .
C3 C4 H4A 119.1 . .
C4 C5 C6 116.1(2) . .
C4 C5 H5A 122.0 . .
C6 C5 H5A 122.0 . .
N2 C6 C5 131.77(19) . .
N2 C6 C1 105.45(16) . .
C5 C6 C1 122.78(19) . .
N1 C7 N2 112.11(17) . .
N1 C7 C8 124.41(17) . .
N2 C7 C8 123.43(17) . .
O1 C8 C7 106.48(15) . .
O1 C8 H8A 110.4 . .
C7 C8 H8A 110.4 . .
O1 C8 H8B 110.4 . .
C7 C8 H8B 110.4 . .
H8A C8 H8B 108.6 . .
O1 C9 C10 115.32(16) . .
O1 C9 H9A 108.4 . .
C10 C9 H9A 108.4 . .
O1 C9 H9B 108.4 . .
C10 C9 H9B 108.4 . .
H9A C9 H9B 107.5 . .
N3 C10 N4 112.12(16) . .
N3 C10 C9 123.14(17) . .
N4 C10 C9 124.11(17) . .
N4 C11 C12 131.31(17) . .
N4 C11 C16 106.06(16) . .
C12 C11 C16 122.62(18) . .
C13 C12 C11 116.34(18) . .
C13 C12 H12A 121.8 . .
C11 C12 H12A 121.8 . .
C12 C13 C14 121.44(18) . .
C12 C13 H13A 119.3 . .
C14 C13 H13A 119.3 . .
C15 C14 C13 121.92(18) . .
C15 C14 H14A 119.0 . .
C13 C14 H14A 119.0 . .
C14 C15 C16 117.05(18) . .
C14 C15 H15A 121.5 . .
C16 C15 H15A 121.5 . .
N3 C16 C15 130.84(18) . .
N3 C16 C11 108.54(16) . .
C15 C16 C11 120.60(18) . .
N2 C17 H17A 109.5 . .
N2 C17 H17B 109.5 . .
H17A C17 H17B 109.5 . .
N2 C17 H17C 109.5 . .
H17A C17 H17C 109.5 . .
H17B C17 H17C 109.5 . .
N4 C18 H18A 109.5 . .
N4 C18 H18B 109.5 . .
H18A C18 H18B 109.5 . .
N4 C18 H18C 109.5 . .
H18A C18 H18C 109.5 . .
H18B C18 H18C 109.5 . .
O2 C19 C24 126.35(19) . .
O2 C19 C20 122.73(18) . .
C24 C19 C20 110.91(17) . .
C21 C20 C19 125.76(18) . .
C21 C20 N5 116.97(18) . .
C19 C20 N5 117.24(17) . .
C20 C21 C22 118.35(19) . .
C20 C21 H21A 120.8 . .
C22 C21 H21A 120.8 . .
C23 C22 C21 120.91(18) . .
C23 C22 N6 119.35(17) . .
C21 C22 N6 119.73(18) . .
C24 C23 C22 119.92(18) . .
C24 C23 H23A 120.0 . .
C22 C23 H23A 120.0 . .
C23 C24 N7 115.91(17) . .
C23 C24 C19 123.98(18) . .
N7 C24 C19 120.08(17) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag N3 2.1038(15) 2_665
Ag N1 2.1088(16) .
O1 C9 1.417(2) .
O1 C8 1.429(2) .
O2 C19 1.248(2) .
O3 N5 1.225(3) .
O4 N5 1.222(2) .
O5 N6 1.233(2) .
O6 N6 1.232(2) .
O7 N7 1.221(2) .
O8 N7 1.237(2) .
O9 H9BO 0.80(3) .
O9 H9AO 0.79(3) .
N1 C7 1.325(2) .
N1 C1 1.392(2) .
N2 C7 1.357(2) .
N2 C6 1.384(3) .
N2 C17 1.463(2) .
N3 C10 1.327(2) .
N3 C16 1.393(2) .
N3 Ag 2.1038(15) 2_665
N4 C10 1.357(2) .
N4 C11 1.384(2) .
N4 C18 1.459(2) .
N5 C20 1.464(2) .
N6 C22 1.441(2) .
N7 C24 1.447(2) .
C1 C2 1.395(3) .
C1 C6 1.398(3) .
C2 C3 1.384(3) .
C2 H2A 0.9500 .
C3 C4 1.405(4) .
C3 H3A 0.9500 .
C4 C5 1.383(3) .
C4 H4A 0.9500 .
C5 C6 1.396(3) .
C5 H5A 0.9500 .
C7 C8 1.488(3) .
C8 H8A 0.9900 .
C8 H8B 0.9900 .
C9 C10 1.500(3) .
C9 H9A 0.9900 .
C9 H9B 0.9900 .
C11 C12 1.391(3) .
C11 C16 1.401(3) .
C12 C13 1.384(3) .
C12 H12A 0.9500 .
C13 C14 1.408(3) .
C13 H13A 0.9500 .
C14 C15 1.382(3) .
C14 H14A 0.9500 .
C15 C16 1.395(3) .
C15 H15A 0.9500 .
C17 H17A 0.9800 .
C17 H17B 0.9800 .
C17 H17C 0.9800 .
C18 H18A 0.9800 .
C18 H18B 0.9800 .
C18 H18C 0.9800 .
C19 C24 1.451(3) .
C19 C20 1.457(3) .
C20 C21 1.363(3) .
C21 C22 1.395(3) .
C21 H21A 0.9500 .
C22 C23 1.379(3) .
C23 C24 1.379(3) .
C23 H23A 0.9500 .
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
O9 H9BO O2 0.80(3) 2.11(4) 2.895(2) 169(3) .
O9 H9BO O3 0.80(3) 2.60(3) 3.061(3) 118(3) .
O9 H9AO O2 0.79(3) 2.18(3) 2.951(2) 166(3) 2_565
O9 H9AO O7 0.79(3) 2.55(3) 3.054(2) 123(2) 2_565
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
N3 Ag N1 C7 -129.3(3) 2_665
N3 Ag N1 C1 33.8(4) 2_665
C7 N1 C1 C2 -179.8(2) .
Ag N1 C1 C2 13.7(3) .
C7 N1 C1 C6 -0.3(2) .
Ag N1 C1 C6 -166.84(13) .
N1 C1 C2 C3 179.2(2) .
C6 C1 C2 C3 -0.2(3) .
C1 C2 C3 C4 0.2(3) .
C2 C3 C4 C5 0.0(4) .
C3 C4 C5 C6 -0.2(3) .
C7 N2 C6 C5 179.6(2) .
C17 N2 C6 C5 -2.1(3) .
C7 N2 C6 C1 -0.3(2) .
C17 N2 C6 C1 178.01(18) .
C4 C5 C6 N2 -179.7(2) .
C4 C5 C6 C1 0.2(3) .
N1 C1 C6 N2 0.4(2) .
C2 C1 C6 N2 179.91(18) .
N1 C1 C6 C5 -179.53(18) .
C2 C1 C6 C5 0.0(3) .
C1 N1 C7 N2 0.1(2) .
Ag N1 C7 N2 165.49(13) .
C1 N1 C7 C8 177.33(17) .
Ag N1 C7 C8 -17.3(3) .
C6 N2 C7 N1 0.1(2) .
C17 N2 C7 N1 -178.12(19) .
C6 N2 C7 C8 -177.14(17) .
C17 N2 C7 C8 4.6(3) .
C9 O1 C8 C7 167.37(15) .
N1 C7 C8 O1 -116.1(2) .
N2 C7 C8 O1 60.8(2) .
C8 O1 C9 C10 76.7(2) .
C16 N3 C10 N4 2.1(2) .
Ag N3 C10 N4 -167.90(12) 2_665
C16 N3 C10 C9 -169.11(17) .
Ag N3 C10 C9 20.9(3) 2_665
C11 N4 C10 N3 -1.7(2) .
C18 N4 C10 N3 177.87(17) .
C11 N4 C10 C9 169.38(17) .
C18 N4 C10 C9 -11.0(3) .
O1 C9 C10 N3 -127.92(19) .
O1 C9 C10 N4 61.9(2) .
C10 N4 C11 C12 -178.9(2) .
C18 N4 C11 C12 1.5(3) .
C10 N4 C11 C16 0.6(2) .
C18 N4 C11 C16 -179.02(17) .
N4 C11 C12 C13 178.03(19) .
C16 C11 C12 C13 -1.4(3) .
C11 C12 C13 C14 0.1(3) .
C12 C13 C14 C15 1.3(3) .
C13 C14 C15 C16 -1.2(3) .
C10 N3 C16 C15 176.9(2) .
Ag N3 C16 C15 -13.1(3) 2_665
C10 N3 C16 C11 -1.7(2) .
Ag N3 C16 C11 168.35(12) 2_665
C14 C15 C16 N3 -178.51(19) .
C14 C15 C16 C11 -0.1(3) .
N4 C11 C16 N3 0.6(2) .
C12 C11 C16 N3 -179.79(17) .
N4 C11 C16 C15 -178.10(17) .
C12 C11 C16 C15 1.5(3) .
O2 C19 C20 C21 174.76(19) .
C24 C19 C20 C21 -4.3(3) .
O2 C19 C20 N5 -3.4(3) .
C24 C19 C20 N5 177.50(17) .
O4 N5 C20 C21 -47.6(3) .
O3 N5 C20 C21 131.3(2) .
O4 N5 C20 C19 130.7(2) .
O3 N5 C20 C19 -50.3(3) .
C19 C20 C21 C22 3.8(3) .
N5 C20 C21 C22 -177.99(18) .
C20 C21 C22 C23 -0.2(3) .
C20 C21 C22 N6 -178.86(18) .
O6 N6 C22 C23 5.1(3) .
O5 N6 C22 C23 -174.50(19) .
O6 N6 C22 C21 -176.23(19) .
O5 N6 C22 C21 4.2(3) .
C21 C22 C23 C24 -2.3(3) .
N6 C22 C23 C24 176.33(17) .
C22 C23 C24 N7 -176.72(18) .
C22 C23 C24 C19 1.5(3) .
O7 N7 C24 C23 154.91(18) .
O8 N7 C24 C23 -23.9(3) .
O7 N7 C24 C19 -23.4(3) .
O8 N7 C24 C19 157.83(19) .
O2 C19 C24 C23 -177.48(19) .
C20 C19 C24 C23 1.5(3) .
O2 C19 C24 N7 0.7(3) .
C20 C19 C24 N7 179.71(16) .
