#------------------------------------------------------------------------------
#$Date: 2016-08-07 12:30:58 +0300 (Sun, 07 Aug 2016) $
#$Revision: 185579 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/05/55/7055501.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7055501
loop_
_publ_author_name
'Mitrofanov, Alexander Yu.'
'Rousselin, Yoann'
'Guilard, Roger'
'Brandès, Stéphane'
'Bessmertnykh-Lemeune, Alla G.'
'Uvarova, Marina A.'
'Nefedov, Sergey E.'
_publ_section_title
;
 Copper(ii) complexes with phosphorylated 1,10-phenanthrolines: from
 molecules to infinite supramolecular arrays
;
_journal_issue                   7
_journal_name_full               'New J. Chem.'
_journal_page_first              5896
_journal_paper_doi               10.1039/C5NJ03572D
_journal_volume                  40
_journal_year                    2016
_chemical_formula_moiety         'C40 H52 Cu2 N8 O24 P4'
_chemical_formula_sum            'C40 H52 Cu2 N8 O24 P4'
_chemical_formula_weight         1279.85
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     iterative
_audit_creation_date             2014-06-24
_audit_creation_method
;
Olex2 1.2
(compiled 2014.06.23 svn.r2948 for OlexSys, GUI svn.r4855)
;
_audit_update_record
;
2014-06-24 deposited with the CCDC.
2016-04-26 downloaded from the CCDC.
;
_cell_angle_alpha                105.813(2)
_cell_angle_beta                 92.591(3)
_cell_angle_gamma                90.967(2)
_cell_formula_units_Z            1
_cell_length_a                   7.7003(6)
_cell_length_b                   9.8407(8)
_cell_length_c                   17.8602(16)
_cell_measurement_temperature    115
_cell_volume                     1300.23(19)
_computing_cell_refinement       'SAINT v8.34A (Bruker, 2013)'
_computing_data_collection       'APEX2 (Bruker, 2014)'
_computing_data_reduction        'SAINT v8.34A (Bruker, 2013)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2008)'
_computing_structure_solution    'olex2.solve (Bourhis et al., 2013)'
_diffrn_ambient_temperature      115.0
_diffrn_detector                 'CCD Plate'
_diffrn_detector_area_resol_mean '512 x 512'
_diffrn_detector_type            APEX2
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.987
_diffrn_measurement_device       'κ-geometry diffractometer'
_diffrn_measurement_device_type  'Nonius Kappa Apex II'
_diffrn_measurement_method       'φ and ω scans''
_diffrn_radiation_collimation    '0.6 mm'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0490
_diffrn_reflns_av_unetI/netI     0.0312
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.987
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_number            50096
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.987
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.843
_diffrn_reflns_theta_min         2.727
_diffrn_source                   'X-ray tube'
_diffrn_source_target            Mo
_diffrn_source_type              'Siemens KFF Mo 2K-180'
_exptl_absorpt_coefficient_mu    1.033
_exptl_absorpt_correction_T_max  0.74
_exptl_absorpt_correction_T_min  0.65
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            'clear light blue'
_exptl_crystal_colour_lustre     clear
_exptl_crystal_colour_modifier   light
_exptl_crystal_colour_primary    blue
_exptl_crystal_density_diffrn    1.635
_exptl_crystal_description       prism
_exptl_crystal_F_000             658
_exptl_crystal_recrystallization_method
'Re-crystallisation from solvent: DCM / diethyl ether'
_exptl_crystal_size_max          0.1
_exptl_crystal_size_mid          0.1
_exptl_crystal_size_min          0.07
_refine_diff_density_max         0.633
_refine_diff_density_min         -0.637
_refine_diff_density_rms         0.078
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.039
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_constraints    0
_refine_ls_number_parameters     356
_refine_ls_number_reflns         6099
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.039
_refine_ls_R_factor_all          0.0471
_refine_ls_R_factor_gt           0.0319
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0486P)²+0.6505P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0792
_refine_ls_wR_factor_ref         0.0867
_reflns_Friedel_coverage         0.000
_reflns_number_gt                4983
_reflns_number_total             6099
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c5nj03572d2.cif
_cod_data_source_block           13al0205
_cod_depositor_comments
'Adding full bibliography for 7055499--7055503.cif.'
_cod_database_code               7055501
_shelxl_version_number           2014-3
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_max   0.931
_shelx_estimated_absorpt_t_min   0.904
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2.a Secondary CH2 refined with riding coordinates:
 C1(H1A,H1B), C3(H3A,H3B), C17(H17A,H17B), C19(H19A,H19B)
2.b Aromatic/amide H refined with riding coordinates:
 C6(H6), C7(H7), C10(H10), C11(H11), C14(H14), C16(H16)
2.c Idealised Me refined as rotating group:
 C2(H2A,H2B,H2C), C4(H4A,H4B,H4C), C18(H18A,H18B,H18C), C20(H20A,H20B,H20C)
;
_olex2_exptl_crystal_mounting_method
'The crystal was mounted on a mylar loop oil'
_olex2_submission_special_instructions 'No special instructions were received'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
C1 C -0.2578(3) 0.1703(2) -0.28668(12) 0.0203(5) Uani 1 1 d .
H1A H -0.2263 0.1359 -0.3416 0.024 Uiso 1 1 calc R
H1B H -0.2902 0.2704 -0.2767 0.024 Uiso 1 1 calc R
C2 C -0.4080(3) 0.0837(3) -0.27222(16) 0.0331(6) Uani 1 1 d .
H2A H -0.5023 0.0801 -0.3115 0.050 Uiso 1 1 calc GR
H2B H -0.4493 0.1266 -0.2202 0.050 Uiso 1 1 calc GR
H2C H -0.3705 -0.0124 -0.2755 0.050 Uiso 1 1 calc GR
C3 C 0.2698(3) 0.3667(2) -0.23183(12) 0.0221(5) Uani 1 1 d .
H3A H 0.3976 0.3618 -0.2247 0.027 Uiso 1 1 calc R
H3B H 0.2372 0.4659 -0.2093 0.027 Uiso 1 1 calc R
C4 C 0.2173(4) 0.3215(3) -0.31730(13) 0.0323(6) Uani 1 1 d .
H4A H 0.2849 0.3769 -0.3445 0.049 Uiso 1 1 calc GR
H4B H 0.0931 0.3373 -0.3246 0.049 Uiso 1 1 calc GR
H4C H 0.2398 0.2209 -0.3385 0.049 Uiso 1 1 calc GR
C5 C -0.0261(3) 0.2468(2) -0.08400(11) 0.0122(4) Uani 1 1 d .
C6 C 0.0868(3) 0.3202(2) -0.02054(11) 0.0121(4) Uani 1 1 d .
H6 H 0.1705 0.3865 -0.0282 0.015 Uiso 1 1 calc R
C7 C -0.1435(3) 0.1470(2) -0.07388(11) 0.0131(4) Uani 1 1 d .
H7 H -0.2168 0.0946 -0.1165 0.016 Uiso 1 1 calc R
C8 C -0.1543(3) 0.1228(2) -0.00006(11) 0.0124(4) Uani 1 1 d .
C9 C -0.0415(2) 0.2039(2) 0.05984(11) 0.0111(4) Uani 1 1 d .
C10 C -0.2716(3) 0.0211(2) 0.01645(11) 0.0135(4) Uani 1 1 d .
H10 H -0.3444 -0.0372 -0.0246 0.016 Uiso 1 1 calc R
C11 C -0.2803(3) 0.0070(2) 0.08932(11) 0.0139(4) Uani 1 1 d .
H11 H -0.3592 -0.0610 0.0988 0.017 Uiso 1 1 calc R
C12 C -0.1722(3) 0.0930(2) 0.15267(11) 0.0124(4) Uani 1 1 d .
C13 C -0.0515(3) 0.1886(2) 0.13698(11) 0.0117(4) Uani 1 1 d .
C14 C 0.0537(3) 0.2648(2) 0.26516(11) 0.0139(4) Uani 1 1 d .
H14 H 0.1316 0.3229 0.3040 0.017 Uiso 1 1 calc R
C15 C -0.0658(3) 0.1741(2) 0.28689(11) 0.0141(4) Uani 1 1 d .
C16 C -0.1775(3) 0.0879(2) 0.23059(11) 0.0140(4) Uani 1 1 d .
H16 H -0.2576 0.0253 0.2443 0.017 Uiso 1 1 calc R
C17 C -0.2266(3) 0.3918(3) 0.47158(13) 0.0261(5) Uani 1 1 d .
H17A H -0.3302 0.3384 0.4427 0.031 Uiso 1 1 calc R
H17B H -0.2307 0.4896 0.4669 0.031 Uiso 1 1 calc R
C18 C -0.2288(3) 0.3936(3) 0.55554(13) 0.0318(6) Uani 1 1 d .
H18A H -0.2340 0.2964 0.5597 0.048 Uiso 1 1 calc GR
H18B H -0.3310 0.4435 0.5785 0.048 Uiso 1 1 calc GR
H18C H -0.1230 0.4421 0.5834 0.048 Uiso 1 1 calc GR
C19 C 0.1903(3) 0.1195(3) 0.47626(13) 0.0297(6) Uani 1 1 d .
H19A H 0.1788 0.0207 0.4792 0.036 Uiso 1 1 calc R
H19B H 0.1221 0.1799 0.5176 0.036 Uiso 1 1 calc R
C20 C 0.3766(3) 0.1673(3) 0.48754(16) 0.0418(7) Uani 1 1 d .
H20A H 0.4423 0.1090 0.4454 0.063 Uiso 1 1 calc GR
H20B H 0.4239 0.1578 0.5377 0.063 Uiso 1 1 calc GR
H20C H 0.3863 0.2664 0.4870 0.063 Uiso 1 1 calc GR
N1 N 0.0786(2) 0.29870(17) 0.04938(9) 0.0118(3) Uani 1 1 d .
N2 N 0.0611(2) 0.27191(17) 0.19219(9) 0.0118(3) Uani 1 1 d .
N3 N 0.4677(3) 0.3402(2) 0.25306(11) 0.0261(4) Uani 1 1 d .
N4 N 0.5206(2) 0.38733(18) 0.05730(10) 0.0163(4) Uani 1 1 d .
O1 O -0.11032(19) 0.15853(15) -0.23481(8) 0.0166(3) Uani 1 1 d .
O2 O -0.08433(19) 0.42484(15) -0.17714(8) 0.0172(3) Uani 1 1 d .
O3 O 0.18391(18) 0.27502(15) -0.19057(8) 0.0160(3) Uani 1 1 d .
O4 O -0.2062(2) 0.07531(17) 0.40058(9) 0.0226(3) Uani 1 1 d .
O5 O -0.0696(2) 0.32614(16) 0.43795(8) 0.0225(3) Uani 1 1 d .
O6 O 0.1251(2) 0.12919(17) 0.39993(8) 0.0223(3) Uani 1 1 d .
O7 O 0.36812(19) 0.44188(16) 0.24788(8) 0.0183(3) Uani 1 1 d .
O8 O 0.4619(2) 0.2310(2) 0.19792(11) 0.0372(4) Uani 1 1 d .
O9 O 0.5626(3) 0.3569(3) 0.31220(11) 0.0501(6) Uani 1 1 d .
O10 O 0.41384(19) 0.47121(15) 0.10112(8) 0.0182(3) Uani 1 1 d .
O11 O 0.4705(2) 0.26569(16) 0.02216(10) 0.0277(4) Uani 1 1 d .
O12 O 0.6671(2) 0.43417(17) 0.05168(9) 0.0247(4) Uani 1 1 d .
P1 P -0.01389(7) 0.28794(5) -0.17545(3) 0.01149(11) Uani 1 1 d .
P2 P -0.06842(7) 0.16822(6) 0.38642(3) 0.01585(12) Uani 1 1 d .
Cu1 Cu 0.22951(3) 0.38383(2) 0.14663(2) 0.01113(8) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_3
H1A C1 H1B 108.3 .
C2 C1 H1A 109.9 .
C2 C1 H1B 109.9 .
O1 C1 H1A 109.9 .
O1 C1 H1B 109.9 .
O1 C1 C2 108.73(18) .
C1 C2 H2A 109.5 .
C1 C2 H2B 109.5 .
C1 C2 H2C 109.5 .
H2A C2 H2B 109.5 .
H2A C2 H2C 109.5 .
H2B C2 H2C 109.5 .
H3A C3 H3B 108.1 .
C4 C3 H3A 109.5 .
C4 C3 H3B 109.5 .
O3 C3 H3A 109.5 .
O3 C3 H3B 109.5 .
O3 C3 C4 110.73(18) .
C3 C4 H4A 109.5 .
C3 C4 H4B 109.5 .
C3 C4 H4C 109.5 .
H4A C4 H4B 109.5 .
H4A C4 H4C 109.5 .
H4B C4 H4C 109.5 .
C6 C5 P1 118.96(15) .
C7 C5 C6 119.40(17) .
C7 C5 P1 121.64(14) .
C5 C6 H6 119.2 .
N1 C6 C5 121.67(17) .
N1 C6 H6 119.2 .
C5 C7 H7 120.1 .
C5 C7 C8 119.74(17) .
C8 C7 H7 120.1 .
C7 C8 C10 124.04(17) .
C9 C8 C7 116.73(18) .
C9 C8 C10 119.23(17) .
C8 C9 C13 119.36(17) .
N1 C9 C8 123.64(17) .
N1 C9 C13 117.00(16) .
C8 C10 H10 119.5 .
C11 C10 C8 121.09(18) .
C11 C10 H10 119.5 .
C10 C11 H11 119.5 .
C10 C11 C12 121.03(18) .
C12 C11 H11 119.5 .
C13 C12 C11 118.65(17) .
C13 C12 C16 116.89(17) .
C16 C12 C11 124.46(18) .
C12 C13 C9 120.54(17) .
N2 C13 C9 115.95(17) .
N2 C13 C12 123.51(17) .
C15 C14 H14 118.9 .
N2 C14 H14 118.9 .
N2 C14 C15 122.22(18) .
C14 C15 P2 120.17(15) .
C16 C15 C14 119.27(18) .
C16 C15 P2 120.54(15) .
C12 C16 H16 120.2 .
C15 C16 C12 119.70(18) .
C15 C16 H16 120.2 .
H17A C17 H17B 108.1 .
C18 C17 H17A 109.6 .
C18 C17 H17B 109.6 .
O5 C17 H17A 109.6 .
O5 C17 H17B 109.6 .
O5 C17 C18 110.13(19) .
C17 C18 H18A 109.5 .
C17 C18 H18B 109.5 .
C17 C18 H18C 109.5 .
H18A C18 H18B 109.5 .
H18A C18 H18C 109.5 .
H18B C18 H18C 109.5 .
H19A C19 H19B 108.4 .
C20 C19 H19A 110.0 .
C20 C19 H19B 110.0 .
O6 C19 H19A 110.0 .
O6 C19 H19B 110.0 .
O6 C19 C20 108.4(2) .
C19 C20 H20A 109.5 .
C19 C20 H20B 109.5 .
C19 C20 H20C 109.5 .
H20A C20 H20B 109.5 .
H20A C20 H20C 109.5 .
H20B C20 H20C 109.5 .
C6 N1 C9 118.74(16) .
C6 N1 Cu1 128.90(13) .
C9 N1 Cu1 112.32(12) .
C13 N2 Cu1 112.43(13) .
C14 N2 C13 118.38(17) .
C14 N2 Cu1 129.09(13) .
O8 N3 O7 118.09(18) .
O9 N3 O7 118.1(2) .
O9 N3 O8 123.8(2) .
O11 N4 O10 119.22(17) .
O12 N4 O10 118.06(17) .
O12 N4 O11 122.71(18) .
C1 O1 P1 124.05(13) .
P1 O2 Cu1 161.01(9) 2_565
C3 O3 P1 120.50(13) .
C17 O5 P2 122.50(14) .
C19 O6 P2 120.72(14) .
N3 O7 Cu1 108.95(12) .
N4 O10 Cu1 117.50(12) .
O1 P1 C5 103.44(9) .
O2 P1 C5 114.91(9) .
O2 P1 O1 113.66(8) .
O2 P1 O3 113.99(8) .
O3 P1 C5 102.58(9) .
O3 P1 O1 107.07(8) .
O4 P2 C15 113.68(9) .
O4 P2 O5 115.26(9) .
O4 P2 O6 117.80(9) .
O5 P2 C15 106.64(9) .
O6 P2 C15 100.06(9) .
O6 P2 O5 101.53(9) .
N1 Cu1 N2 81.79(6) .
N1 Cu1 O2 93.25(6) 2_565
N2 Cu1 O2 94.48(6) 2_565
O7 Cu1 N1 171.19(6) .
O7 Cu1 N2 90.38(6) .
O7 Cu1 O2 91.37(6) 2_565
O10 Cu1 N1 99.17(6) .
O10 Cu1 N2 172.33(6) .
O10 Cu1 O2 93.06(6) 2_565
O10 Cu1 O7 88.05(6) .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C1 H1A 0.9900 .
C1 H1B 0.9900 .
C1 C2 1.498(3) .
C1 O1 1.459(2) .
C2 H2A 0.9800 .
C2 H2B 0.9800 .
C2 H2C 0.9800 .
C3 H3A 0.9900 .
C3 H3B 0.9900 .
C3 C4 1.503(3) .
C3 O3 1.477(2) .
C4 H4A 0.9800 .
C4 H4B 0.9800 .
C4 H4C 0.9800 .
C5 C6 1.416(3) .
C5 C7 1.377(3) .
C5 P1 1.792(2) .
C6 H6 0.9500 .
C6 N1 1.326(2) .
C7 H7 0.9500 .
C7 C8 1.408(3) .
C8 C9 1.401(3) .
C8 C10 1.435(3) .
C9 C13 1.432(3) .
C9 N1 1.357(2) .
C10 H10 0.9500 .
C10 C11 1.351(3) .
C11 H11 0.9500 .
C11 C12 1.435(3) .
C12 C13 1.402(3) .
C12 C16 1.409(3) .
C13 N2 1.362(2) .
C14 H14 0.9500 .
C14 C15 1.410(3) .
C14 N2 1.328(2) .
C15 C16 1.379(3) .
C15 P2 1.795(2) .
C16 H16 0.9500 .
C17 H17A 0.9900 .
C17 H17B 0.9900 .
C17 C18 1.496(3) .
C17 O5 1.456(3) .
C18 H18A 0.9800 .
C18 H18B 0.9800 .
C18 H18C 0.9800 .
C19 H19A 0.9900 .
C19 H19B 0.9900 .
C19 C20 1.490(4) .
C19 O6 1.459(2) .
C20 H20A 0.9800 .
C20 H20B 0.9800 .
C20 H20C 0.9800 .
N1 Cu1 2.0152(16) .
N2 Cu1 2.0229(16) .
N3 O7 1.292(3) .
N3 O8 1.242(3) .
N3 O9 1.228(3) .
N4 O10 1.303(2) .
N4 O11 1.236(2) .
N4 O12 1.230(2) .
O1 P1 1.5679(14) .
O2 P1 1.4681(15) .
O2 Cu1 2.1584(14) 2_565
O3 P1 1.5602(15) .
O4 P2 1.4638(15) .
O5 P2 1.5760(16) .
O6 P2 1.5699(16) .
O7 Cu1 1.9944(14) .
O10 Cu1 1.9643(14) .
Cu1 O2 2.1584(14) 2_565
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
C1 O1 P1 C5 124.51(16) .
C1 O1 P1 O2 -0.77(18) .
C1 O1 P1 O3 -127.57(16) .
C2 C1 O1 P1 -123.21(18) .
C3 O3 P1 C5 -147.01(14) .
C3 O3 P1 O1 104.46(15) .
C3 O3 P1 O2 -22.14(17) .
C4 C3 O3 P1 -73.3(2) .
C5 C6 N1 C9 -0.1(3) .
C5 C6 N1 Cu1 177.42(14) .
C5 C7 C8 C9 -0.2(3) .
C5 C7 C8 C10 -179.80(19) .
C6 C5 C7 C8 2.3(3) .
C6 C5 P1 O1 163.05(15) .
C6 C5 P1 O2 -72.47(18) .
C6 C5 P1 O3 51.79(17) .
C7 C5 C6 N1 -2.3(3) .
C7 C5 P1 O1 -17.65(19) .
C7 C5 P1 O2 106.83(17) .
C7 C5 P1 O3 -128.91(17) .
C7 C8 C9 C13 177.35(18) .
C7 C8 C9 N1 -2.3(3) .
C7 C8 C10 C11 -177.41(19) .
C8 C9 C13 C12 0.3(3) .
C8 C9 C13 N2 -179.37(17) .
C8 C9 N1 C6 2.4(3) .
C8 C9 N1 Cu1 -175.46(15) .
C8 C10 C11 C12 -0.1(3) .
C9 C8 C10 C11 3.0(3) .
C9 C13 N2 C14 178.03(17) .
C9 C13 N2 Cu1 -5.3(2) .
C10 C8 C9 C13 -3.0(3) .
C10 C8 C9 N1 177.35(18) .
C10 C11 C12 C13 -2.6(3) .
C10 C11 C12 C16 177.84(19) .
C11 C12 C13 C9 2.5(3) .
C11 C12 C13 N2 -177.85(18) .
C11 C12 C16 C15 179.10(19) .
C12 C13 N2 C14 -1.6(3) .
C12 C13 N2 Cu1 175.05(15) .
C13 C9 N1 C6 -177.22(17) .
C13 C9 N1 Cu1 4.9(2) .
C13 C12 C16 C15 -0.4(3) .
C14 C15 C16 C12 -0.8(3) .
C14 C15 P2 O4 176.60(16) .
C14 C15 P2 O5 48.47(19) .
C14 C15 P2 O6 -56.89(18) .
C15 C14 N2 C13 0.2(3) .
C15 C14 N2 Cu1 -175.82(15) .
C16 C12 C13 C9 -177.90(18) .
C16 C12 C13 N2 1.7(3) .
C16 C15 P2 O4 -4.9(2) .
C16 C15 P2 O5 -133.02(17) .
C16 C15 P2 O6 121.62(18) .
C17 O5 P2 C15 102.20(17) .
C17 O5 P2 O4 -24.99(19) .
C17 O5 P2 O6 -153.50(16) .
C18 C17 O5 P2 100.3(2) .
C19 O6 P2 C15 176.69(18) .
C19 O6 P2 O4 -59.6(2) .
C19 O6 P2 O5 67.24(18) .
C20 C19 O6 P2 -146.35(19) .
N1 C9 C13 C12 179.94(18) .
N1 C9 C13 N2 0.3(3) .
N2 C14 C15 C16 1.0(3) .
N2 C14 C15 P2 179.52(15) .
O8 N3 O7 Cu1 0.3(2) .
O9 N3 O7 Cu1 -179.63(18) .
O11 N4 O10 Cu1 27.2(2) .
O12 N4 O10 Cu1 -154.03(14) .
P1 C5 C6 N1 177.02(15) .
P1 C5 C7 C8 -176.95(15) .
P2 C15 C16 C12 -179.35(15) .
Cu1 O2 P1 C5 -19.6(3) 2_565
Cu1 O2 P1 O1 99.3(3) 2_565
Cu1 O2 P1 O3 -137.6(3) 2_565
