#------------------------------------------------------------------------------
#$Date: 2019-11-17 13:50:29 +0200 (Sun, 17 Nov 2019) $
#$Revision: 230281 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/05/68/7056865.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7056865
loop_
_publ_author_name
'Massoud, Salah S.'
'Henary, Maher M.'
'Maxwell, Lindley'
'Martín, Alejandro'
'Ruiz, Eliseo'
'Vicente, Ramon'
'Fischer, Roland C.'
'Mautner, Franz A.'
_publ_section_title
;
 Structure, magnetic properties and DFT calculations of azido-copper(ii)
 complexes with different azido-bonding, nuclearity and dimensionality
;
_journal_issue                   4
_journal_name_full               'New Journal of Chemistry'
_journal_page_first              2627
_journal_paper_doi               10.1039/C7NJ04150K
_journal_volume                  42
_journal_year                    2018
_chemical_formula_moiety         'C14 H36 Cu2 N13, Cl O4'
_chemical_formula_sum            'C14 H36 Cl Cu2 N13 O4'
_chemical_formula_weight         613.11
_chemical_name_common            '[Cu2(N3)3(Et2,Me-en)2]n(ClO4)n'
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   mixed
_audit_creation_method           SHELXL-2016/6
_audit_update_record
;
2017-06-13 deposited with the CCDC.
2018-01-08 downloaded from the CCDC.
;
_cell_angle_alpha                70.941(13)
_cell_angle_beta                 82.294(14)
_cell_angle_gamma                82.146(14)
_cell_formula_units_Z            2
_cell_length_a                   7.8921(9)
_cell_length_b                   12.8529(12)
_cell_length_c                   13.2899(14)
_cell_measurement_reflns_used    2000
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      26.00
_cell_measurement_theta_min      1.80
_cell_volume                     1256.5(3)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-2016/6 (Sheldrick, 2016)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.992
_diffrn_measured_fraction_theta_max 0.986
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       ω-scans
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0183
_diffrn_reflns_av_unetI/netI     0.0291
_diffrn_reflns_Laue_measured_fraction_full 0.992
_diffrn_reflns_Laue_measured_fraction_max 0.986
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_h_min       -9
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            10079
_diffrn_reflns_point_group_measured_fraction_full 0.992
_diffrn_reflns_point_group_measured_fraction_max 0.986
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         26.340
_diffrn_reflns_theta_min         1.629
_exptl_absorpt_coefficient_mu    1.847
_exptl_absorpt_correction_T_max  0.7718
_exptl_absorpt_correction_T_min  0.4910
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            green
_exptl_crystal_density_diffrn    1.621
_exptl_crystal_description       prism
_exptl_crystal_F_000             636
_exptl_crystal_size_max          0.440
_exptl_crystal_size_mid          0.350
_exptl_crystal_size_min          0.150
_refine_diff_density_max         1.803
_refine_diff_density_min         -0.912
_refine_diff_density_rms         0.100
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.024
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     319
_refine_ls_number_reflns         5039
_refine_ls_number_restraints     2
_refine_ls_restrained_S_all      1.024
_refine_ls_R_factor_all          0.0437
_refine_ls_R_factor_gt           0.0406
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0561P)²+2.8965P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1047
_refine_ls_wR_factor_ref         0.1072
_reflns_Friedel_coverage         0.000
_reflns_number_gt                4643
_reflns_number_total             5039
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c7nj04150k2.cif
_cod_data_source_block           s2743a
_cod_depositor_comments
'Adding full bibliography for 7056862--7056865.cif.'
_cod_database_code               7056865
_shelx_shelxl_version_number     2016/6
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.497
_shelx_estimated_absorpt_t_max   0.769
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
Cu1 Cu 0.39086(4) 0.10322(3) 0.64122(3) 0.01606(11) Uani 1 1 d . .
Cu2 Cu 0.66148(4) 0.45454(3) 0.34046(3) 0.01399(11) Uani 1 1 d . .
N11 N 0.6334(3) 0.0780(2) 0.5843(2) 0.0213(5) Uani 1 1 d . .
N12 N 0.6688(3) 0.0450(2) 0.5093(2) 0.0174(5) Uani 1 1 d . .
N13 N 0.7114(3) 0.0135(2) 0.4362(2) 0.0237(6) Uani 1 1 d . .
N21 N 0.3461(3) 0.2470(2) 0.5257(2) 0.0243(6) Uani 1 1 d . .
N22 N 0.4217(3) 0.2811(2) 0.4398(2) 0.0173(5) Uani 1 1 d . .
N23 N 0.4892(3) 0.3200(2) 0.3542(2) 0.0195(5) Uani 1 1 d . .
N31 N 0.6899(3) 0.3920(2) 0.4954(2) 0.0185(5) Uani 1 1 d . .
N32 N 0.6017(3) 0.4134(2) 0.56607(19) 0.0169(5) Uani 1 1 d . .
N33 N 0.5227(4) 0.4279(2) 0.6426(2) 0.0242(6) Uani 1 1 d . .
N1 N 0.4406(3) -0.0098(2) 0.7906(2) 0.0169(5) Uani 1 1 d . .
N2 N 0.1550(3) 0.1273(2) 0.7138(2) 0.0197(5) Uani 1 1 d D .
H91 H 0.149(5) 0.183(2) 0.735(3) 0.030 Uiso 1 1 d D U
N3 N 0.9033(3) 0.3816(2) 0.30724(19) 0.0155(5) Uani 1 1 d . .
N4 N 0.6567(3) 0.5189(2) 0.1814(2) 0.0177(5) Uani 1 1 d D .
H92 H 0.700(5) 0.5804(19) 0.159(3) 0.027 Uiso 1 1 d D U
C3 C 1.0341(4) 0.4142(3) 0.3598(3) 0.0210(6) Uani 1 1 d . .
H3A H 1.150113 0.395186 0.327864 0.025 Uiso 1 1 calc R U
H3B H 1.025978 0.370696 0.436654 0.025 Uiso 1 1 calc R U
C1 C 0.8965(4) 0.2587(2) 0.3478(3) 0.0199(6) Uani 1 1 d . .
H1A H 0.813362 0.239720 0.308535 0.024 Uiso 1 1 calc R U
H1B H 0.851365 0.237757 0.424105 0.024 Uiso 1 1 calc R U
C7 C 0.5886(4) 0.0198(3) 0.8306(3) 0.0211(6) Uani 1 1 d . .
H7A H 0.696274 -0.000538 0.790768 0.025 Uiso 1 1 calc R U
H7B H 0.593894 -0.023768 0.907026 0.025 Uiso 1 1 calc R U
C6 C 0.9406(4) 0.4218(3) 0.1882(2) 0.0220(6) Uani 1 1 d . .
H6A H 1.019697 0.365760 0.164513 0.026 Uiso 1 1 calc R U
H6B H 0.997223 0.490962 0.166607 0.026 Uiso 1 1 calc R U
C5 C 0.7756(4) 0.4427(3) 0.1358(2) 0.0211(6) Uani 1 1 d . .
H5A H 0.797956 0.476440 0.057406 0.025 Uiso 1 1 calc R U
H5B H 0.724929 0.372373 0.150086 0.025 Uiso 1 1 calc R U
C9 C 0.4799(4) -0.1225(2) 0.7774(2) 0.0198(6) Uani 1 1 d . .
H9A H 0.573224 -0.118644 0.718858 0.024 Uiso 1 1 calc R U
H9B H 0.376887 -0.141204 0.754408 0.024 Uiso 1 1 calc R U
C4 C 1.0133(4) 0.5367(3) 0.3490(3) 0.0260(7) Uani 1 1 d . .
H4A H 1.035231 0.580137 0.273615 0.039 Uiso 1 1 calc R U
H4B H 1.095212 0.551259 0.390840 0.039 Uiso 1 1 calc R U
H4C H 0.895939 0.557469 0.375620 0.039 Uiso 1 1 calc R U
C10 C 0.5333(5) -0.2167(3) 0.8759(3) 0.0294(7) Uani 1 1 d . .
H10A H 0.636174 -0.200048 0.899378 0.044 Uiso 1 1 calc R U
H10B H 0.558418 -0.285719 0.858039 0.044 Uiso 1 1 calc R U
H10C H 0.439720 -0.224629 0.933499 0.044 Uiso 1 1 calc R U
C8 C 0.5771(4) 0.1422(3) 0.8189(3) 0.0265(7) Uani 1 1 d . .
H8A H 0.572914 0.185904 0.743330 0.040 Uiso 1 1 calc R U
H8B H 0.678099 0.157289 0.845508 0.040 Uiso 1 1 calc R U
H8C H 0.472839 0.162407 0.860306 0.040 Uiso 1 1 calc R U
C11 C 0.2810(4) -0.0061(3) 0.8645(2) 0.0209(6) Uani 1 1 d . .
H11A H 0.285693 0.049359 0.900843 0.025 Uiso 1 1 calc R U
H11B H 0.272507 -0.079188 0.919754 0.025 Uiso 1 1 calc R U
C12 C 0.1256(4) 0.0241(3) 0.8018(3) 0.0231(7) Uani 1 1 d . .
H12A H 0.111346 -0.035731 0.772901 0.028 Uiso 1 1 calc R U
H12B H 0.020589 0.035410 0.848426 0.028 Uiso 1 1 calc R U
C2 C 1.0662(4) 0.1885(3) 0.3378(3) 0.0256(7) Uani 1 1 d . .
H2A H 1.113015 0.208047 0.262650 0.038 Uiso 1 1 calc R U
H2B H 1.046817 0.110070 0.364206 0.038 Uiso 1 1 calc R U
H2C H 1.147929 0.202409 0.380279 0.038 Uiso 1 1 calc R U
C15 C 0.4872(4) 0.5423(3) 0.1400(2) 0.0232(7) Uani 1 1 d . .
H15A H 0.501591 0.569027 0.061640 0.035 Uiso 1 1 calc R U
H15B H 0.418008 0.598919 0.166563 0.035 Uiso 1 1 calc R U
H15C H 0.428994 0.474484 0.164168 0.035 Uiso 1 1 calc R U
C13 C 0.0101(4) 0.1634(3) 0.6465(3) 0.0277(7) Uani 1 1 d . .
H13A H 0.004603 0.109621 0.609362 0.042 Uiso 1 1 calc R U
H13B H 0.026987 0.235987 0.593793 0.042 Uiso 1 1 calc R U
H13C H -0.097539 0.168672 0.691674 0.042 Uiso 1 1 calc R U
Cl1 Cl 0.96272(11) 0.75195(6) 0.04607(6) 0.02584(18) Uani 1 1 d . .
O1 O 0.8289(4) 0.7317(2) 0.1357(2) 0.0409(7) Uani 1 1 d . .
O2 O 1.1160(5) 0.7488(6) 0.0815(3) 0.141(3) Uani 1 1 d . .
O3 O 0.9158(5) 0.8537(3) -0.0288(3) 0.0719(12) Uani 1 1 d . .
O4 O 0.9578(8) 0.6658(3) 0.0029(3) 0.104(2) Uani 1 1 d . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N11 Cu1 N21 93.85(11) . .
N11 Cu1 N2 173.85(11) . .
N21 Cu1 N2 89.60(11) . .
N11 Cu1 N1 90.80(10) . .
N21 Cu1 N1 160.57(11) . .
N2 Cu1 N1 84.31(10) . .
N11 Cu1 N13 94.17(10) . 2_656
N21 Cu1 N13 98.47(11) . 2_656
N2 Cu1 N13 90.36(10) . 2_656
N1 Cu1 N13 100.00(10) . 2_656
N31 Cu2 N33 94.47(10) . 2_666
N31 Cu2 N4 174.59(10) . .
N33 Cu2 N4 88.80(11) 2_666 .
N31 Cu2 N3 89.53(10) . .
N33 Cu2 N3 159.14(11) 2_666 .
N4 Cu2 N3 85.91(10) . .
N31 Cu2 N23 90.28(10) . .
N33 Cu2 N23 98.14(11) 2_666 .
N4 Cu2 N23 93.53(10) . .
N3 Cu2 N23 102.31(10) . .
N12 N11 Cu1 121.3(2) . .
N13 N12 N11 176.7(3) . .
N12 N13 Cu1 136.5(2) . 2_656
N22 N21 Cu1 129.2(2) . .
N23 N22 N21 176.1(3) . .
N22 N23 Cu2 114.8(2) . .
N32 N31 Cu2 127.4(2) . .
N33 N32 N31 174.1(3) . .
N32 N33 Cu2 131.4(2) . 2_666
C7 N1 C11 110.9(2) . .
C7 N1 C9 110.4(2) . .
C11 N1 C9 110.3(2) . .
C7 N1 Cu1 110.37(18) . .
C11 N1 Cu1 107.08(18) . .
C9 N1 Cu1 107.73(18) . .
C13 N2 C12 111.3(3) . .
C13 N2 Cu1 117.6(2) . .
C12 N2 Cu1 106.75(19) . .
C13 N2 H91 98(3) . .
C12 N2 H91 113(3) . .
Cu1 N2 H91 110(3) . .
C3 N3 C6 110.5(2) . .
C3 N3 C1 110.5(2) . .
C6 N3 C1 111.2(2) . .
C3 N3 Cu2 110.66(18) . .
C6 N3 Cu2 106.14(18) . .
C1 N3 Cu2 107.66(17) . .
C15 N4 C5 112.8(2) . .
C15 N4 Cu2 116.91(19) . .
C5 N4 Cu2 105.58(18) . .
C15 N4 H92 105(3) . .
C5 N4 H92 106(3) . .
Cu2 N4 H92 110(3) . .
N3 C3 C4 113.5(3) . .
N3 C3 H3A 108.9 . .
C4 C3 H3A 108.9 . .
N3 C3 H3B 108.9 . .
C4 C3 H3B 108.9 . .
H3A C3 H3B 107.7 . .
N3 C1 C2 116.1(3) . .
N3 C1 H1A 108.3 . .
C2 C1 H1A 108.3 . .
N3 C1 H1B 108.3 . .
C2 C1 H1B 108.3 . .
H1A C1 H1B 107.4 . .
N1 C7 C8 112.9(3) . .
N1 C7 H7A 109.0 . .
C8 C7 H7A 109.0 . .
N1 C7 H7B 109.0 . .
C8 C7 H7B 109.0 . .
H7A C7 H7B 107.8 . .
N3 C6 C5 109.9(2) . .
N3 C6 H6A 109.7 . .
C5 C6 H6A 109.7 . .
N3 C6 H6B 109.7 . .
C5 C6 H6B 109.7 . .
H6A C6 H6B 108.2 . .
N4 C5 C6 107.4(2) . .
N4 C5 H5A 110.2 . .
C6 C5 H5A 110.2 . .
N4 C5 H5B 110.2 . .
C6 C5 H5B 110.2 . .
H5A C5 H5B 108.5 . .
N1 C9 C10 116.2(3) . .
N1 C9 H9A 108.2 . .
C10 C9 H9A 108.2 . .
N1 C9 H9B 108.2 . .
C10 C9 H9B 108.2 . .
H9A C9 H9B 107.4 . .
C3 C4 H4A 109.5 . .
C3 C4 H4B 109.5 . .
H4A C4 H4B 109.5 . .
C3 C4 H4C 109.5 . .
H4A C4 H4C 109.5 . .
H4B C4 H4C 109.5 . .
C9 C10 H10A 109.5 . .
C9 C10 H10B 109.5 . .
H10A C10 H10B 109.5 . .
C9 C10 H10C 109.5 . .
H10A C10 H10C 109.5 . .
H10B C10 H10C 109.5 . .
C7 C8 H8A 109.5 . .
C7 C8 H8B 109.5 . .
H8A C8 H8B 109.5 . .
C7 C8 H8C 109.5 . .
H8A C8 H8C 109.5 . .
H8B C8 H8C 109.5 . .
N1 C11 C12 109.7(2) . .
N1 C11 H11A 109.7 . .
C12 C11 H11A 109.7 . .
N1 C11 H11B 109.7 . .
C12 C11 H11B 109.7 . .
H11A C11 H11B 108.2 . .
N2 C12 C11 107.0(3) . .
N2 C12 H12A 110.3 . .
C11 C12 H12A 110.3 . .
N2 C12 H12B 110.3 . .
C11 C12 H12B 110.3 . .
H12A C12 H12B 108.6 . .
C1 C2 H2A 109.5 . .
C1 C2 H2B 109.5 . .
H2A C2 H2B 109.5 . .
C1 C2 H2C 109.5 . .
H2A C2 H2C 109.5 . .
H2B C2 H2C 109.5 . .
N4 C15 H15A 109.5 . .
N4 C15 H15B 109.5 . .
H15A C15 H15B 109.5 . .
N4 C15 H15C 109.5 . .
H15A C15 H15C 109.5 . .
H15B C15 H15C 109.5 . .
N2 C13 H13A 109.5 . .
N2 C13 H13B 109.5 . .
H13A C13 H13B 109.5 . .
N2 C13 H13C 109.5 . .
H13A C13 H13C 109.5 . .
H13B C13 H13C 109.5 . .
O2 Cl1 O3 112.6(3) . .
O2 Cl1 O4 112.0(4) . .
O3 Cl1 O4 109.7(3) . .
O2 Cl1 O1 110.0(2) . .
O3 Cl1 O1 108.1(2) . .
O4 Cl1 O1 104.0(2) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Cu1 N11 1.986(3) .
Cu1 N21 2.003(3) .
Cu1 N2 2.012(3) .
Cu1 N1 2.092(3) .
Cu1 N13 2.350(3) 2_656
Cu2 N31 1.983(2) .
Cu2 N33 1.996(3) 2_666
Cu2 N4 2.006(3) .
Cu2 N3 2.067(2) .
Cu2 N23 2.290(3) .
N11 N12 1.191(4) .
N12 N13 1.163(4) .
N21 N22 1.189(4) .
N22 N23 1.169(4) .
N31 N32 1.176(4) .
N32 N33 1.174(4) .
N1 C7 1.487(4) .
N1 C11 1.495(4) .
N1 C9 1.501(4) .
N2 C13 1.477(4) .
N2 C12 1.476(4) .
N2 H91 0.851(15) .
N3 C3 1.494(4) .
N3 C6 1.496(4) .
N3 C1 1.499(4) .
N4 C15 1.471(4) .
N4 C5 1.480(4) .
N4 H92 0.850(15) .
C3 C4 1.521(5) .
C3 H3A 0.9900 .
C3 H3B 0.9900 .
C1 C2 1.524(4) .
C1 H1A 0.9900 .
C1 H1B 0.9900 .
C7 C8 1.521(4) .
C7 H7A 0.9900 .
C7 H7B 0.9900 .
C6 C5 1.510(4) .
C6 H6A 0.9900 .
C6 H6B 0.9900 .
C5 H5A 0.9900 .
C5 H5B 0.9900 .
C9 C10 1.527(4) .
C9 H9A 0.9900 .
C9 H9B 0.9900 .
C4 H4A 0.9800 .
C4 H4B 0.9800 .
C4 H4C 0.9800 .
C10 H10A 0.9800 .
C10 H10B 0.9800 .
C10 H10C 0.9800 .
C8 H8A 0.9800 .
C8 H8B 0.9800 .
C8 H8C 0.9800 .
C11 C12 1.510(4) .
C11 H11A 0.9900 .
C11 H11B 0.9900 .
C12 H12A 0.9900 .
C12 H12B 0.9900 .
C2 H2A 0.9800 .
C2 H2B 0.9800 .
C2 H2C 0.9800 .
C15 H15A 0.9800 .
C15 H15B 0.9800 .
C15 H15C 0.9800 .
C13 H13A 0.9800 .
C13 H13B 0.9800 .
C13 H13C 0.9800 .
Cl1 O2 1.346(4) .
Cl1 O3 1.398(3) .
Cl1 O4 1.411(4) .
Cl1 O1 1.462(3) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
C6 N3 C3 C4 73.5(3)
C1 N3 C3 C4 -162.9(3)
Cu2 N3 C3 C4 -43.8(3)
C3 N3 C1 C2 -55.1(3)
C6 N3 C1 C2 68.1(3)
Cu2 N3 C1 C2 -176.0(2)
C11 N1 C7 C8 -72.2(3)
C9 N1 C7 C8 165.3(3)
Cu1 N1 C7 C8 46.3(3)
C3 N3 C6 C5 -151.0(3)
C1 N3 C6 C5 85.8(3)
Cu2 N3 C6 C5 -31.0(3)
C15 N4 C5 C6 -177.5(2)
Cu2 N4 C5 C6 -48.7(3)
N3 C6 C5 N4 54.2(3)
C7 N1 C9 C10 55.1(3)
C11 N1 C9 C10 -67.8(3)
Cu1 N1 C9 C10 175.6(2)
C7 N1 C11 C12 150.1(3)
C9 N1 C11 C12 -87.3(3)
Cu1 N1 C11 C12 29.6(3)
C13 N2 C12 C11 179.4(3)
Cu1 N2 C12 C11 49.9(3)
N1 C11 C12 N2 -53.3(3)
