#------------------------------------------------------------------------------
#$Date: 2019-11-17 13:54:56 +0200 (Sun, 17 Nov 2019) $
#$Revision: 230309 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/05/69/7056986.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7056986
loop_
_publ_author_name
'Lu, Taotao'
'Yang, Chu-Fan'
'Steren, Carlos A.'
'Fei, Fan'
'Chen, Xue-Tai'
'Xue, Zi-Ling'
_publ_section_title
;
 Synthesis and characterization of Ag(i) and Au(i) complexes with
 macrocyclic hybrid amine N-heterocyclic carbene ligands
;
_journal_issue                   6
_journal_name_full               'New Journal of Chemistry'
_journal_page_first              4700
_journal_paper_doi               10.1039/C7NJ04020B
_journal_volume                  42
_journal_year                    2018
_chemical_formula_moiety         'C50 H48 Ag3 N12, 3(F6 P), 2(C2 H3 N)'
_chemical_formula_sum            'C54 H54 Ag3 F18 N14 P3'
_chemical_formula_weight         1657.63
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_Hall           '-C 2yc'
_space_group_name_H-M_alt        'C 1 2/c 1'
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   mixed
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2017-10-17 deposited with the CCDC.
2018-02-06 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 111.780(2)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   19.8816(15)
_cell_length_b                   19.6411(15)
_cell_length_c                   17.4125(13)
_cell_measurement_reflns_used    7573
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      27.41
_cell_measurement_theta_min      2.52
_cell_volume                     6314.1(8)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_structure_solution    'SHELXS-97 (Sheldrick 2008)'
_diffrn_ambient_temperature      150(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device_type  'PHOTON 100 CMOS detector'
_diffrn_measurement_method       'omega scan'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0702
_diffrn_reflns_av_unetI/netI     0.0735
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.995
_diffrn_reflns_limit_h_max       25
_diffrn_reflns_limit_h_min       -23
_diffrn_reflns_limit_k_max       25
_diffrn_reflns_limit_k_min       -20
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_number            25191
_diffrn_reflns_point_group_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.995
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.540
_diffrn_reflns_theta_min         2.206
_diffrn_source                   'rotating microfocus (TXS)'
_exptl_absorpt_coefficient_mu    1.100
_exptl_absorpt_correction_T_max  0.7456
_exptl_absorpt_correction_T_min  0.5672
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS (Bruker, 2014)'
_exptl_crystal_density_diffrn    1.744
_exptl_crystal_description       plate
_exptl_crystal_F_000             3296
_exptl_crystal_size_max          0.220
_exptl_crystal_size_mid          0.200
_exptl_crystal_size_min          0.090
_refine_diff_density_max         1.076
_refine_diff_density_min         -1.610
_refine_diff_density_rms         0.136
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.055
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     447
_refine_ls_number_reflns         7245
_refine_ls_number_restraints     117
_refine_ls_restrained_S_all      1.063
_refine_ls_R_factor_all          0.0877
_refine_ls_R_factor_gt           0.0594
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0882P)²+4.1552P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1423
_refine_ls_wR_factor_ref         0.1535
_reflns_Friedel_coverage         0.000
_reflns_number_gt                5457
_reflns_number_total             7245
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c7nj04020b2.cif
_cod_data_source_block           1
_cod_depositor_comments
'Adding full bibliography for 7056979--7056989.cif.'
_cod_database_code               7056986
_shelx_shelxl_version_number     2014/7
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.794
_shelx_estimated_absorpt_t_max   0.907
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
Ag1 Ag 0.43092(2) 0.21528(2) 0.67943(2) 0.01671(13) Uani 1 1 d . . .
Ag2 Ag 0.5000 0.36978(3) 0.7500 0.01923(15) Uani 1 2 d S T P
C1 C 0.3652(2) 0.1938(3) 0.7443(3) 0.0161(10) Uani 1 1 d . . .
C2 C 0.2628(3) 0.1779(2) 0.7710(3) 0.0160(10) Uani 1 1 d . . .
C3 C 0.3159(3) 0.1351(3) 0.8222(3) 0.0153(10) Uani 1 1 d . . .
C4 C 0.3016(3) 0.0910(3) 0.8772(4) 0.0236(12) Uani 1 1 d . . .
H4 H 0.3377 0.0613 0.9124 0.028 Uiso 1 1 calc R U .
C5 C 0.2326(3) 0.0927(3) 0.8777(4) 0.0297(14) Uani 1 1 d . . .
H5 H 0.2207 0.0634 0.9142 0.036 Uiso 1 1 calc R U .
C6 C 0.1795(3) 0.1362(3) 0.8261(4) 0.0289(14) Uani 1 1 d . . .
H6 H 0.1327 0.1360 0.8290 0.035 Uiso 1 1 calc R U .
C7 C 0.1928(3) 0.1797(3) 0.7709(3) 0.0225(12) Uani 1 1 d . . .
H7 H 0.1565 0.2089 0.7352 0.027 Uiso 1 1 calc R U .
C8 C 0.2567(3) 0.2629(3) 0.6598(3) 0.0195(11) Uani 1 1 d . . .
H8A H 0.2079 0.2451 0.6269 0.023 Uiso 1 1 calc R U .
H8B H 0.2834 0.2686 0.6221 0.023 Uiso 1 1 calc R U .
C9 C 0.2493(2) 0.3309(3) 0.6949(3) 0.0174(11) Uani 1 1 d . . .
C10 C 0.1837(3) 0.3557(3) 0.6938(4) 0.0258(13) Uani 1 1 d . . .
H10 H 0.1408 0.3296 0.6698 0.031 Uiso 1 1 calc R U .
C11 C 0.1813(3) 0.4180(3) 0.7277(4) 0.0312(14) Uani 1 1 d . . .
H11 H 0.1366 0.4353 0.7276 0.037 Uiso 1 1 calc R U .
C12 C 0.2439(3) 0.4557(3) 0.7620(3) 0.0243(12) Uani 1 1 d . . .
H12 H 0.2438 0.4990 0.7862 0.029 Uiso 1 1 calc R U .
C13 C 0.3074(3) 0.4272(3) 0.7594(3) 0.0168(10) Uani 1 1 d . . .
C14 C 0.3789(3) 0.4646(3) 0.7944(3) 0.0197(11) Uani 1 1 d . . .
H14A H 0.3990 0.4698 0.7505 0.024 Uiso 1 1 calc R U .
H14B H 0.3704 0.5107 0.8119 0.024 Uiso 1 1 calc R U .
C15 C 0.4839(3) 0.3870(2) 0.8611(3) 0.0158(10) Uani 1 1 d . . .
C16 C 0.4917(2) 0.3965(2) 0.9942(3) 0.0146(10) Uani 1 1 d . . .
C17 C 0.4346(2) 0.4370(3) 0.9457(3) 0.0153(10) Uani 1 1 d . . .
C18 C 0.3938(3) 0.4755(3) 0.9792(3) 0.0190(11) Uani 1 1 d . . .
H18 H 0.3549 0.5034 0.9460 0.023 Uiso 1 1 calc R U .
C19 C 0.4133(3) 0.4707(3) 1.0646(4) 0.0241(12) Uani 1 1 d . . .
H19 H 0.3870 0.4962 1.0905 0.029 Uiso 1 1 calc R U .
C20 C 0.4703(3) 0.4297(3) 1.1127(3) 0.0209(11) Uani 1 1 d . . .
H20 H 0.4820 0.4283 1.1708 0.025 Uiso 1 1 calc R U .
C21 C 0.5105(3) 0.3907(3) 1.0792(3) 0.0210(11) Uani 1 1 d . . .
H21 H 0.5487 0.3619 1.1122 0.025 Uiso 1 1 calc R U .
C22 C 0.5829(2) 0.3212(3) 0.9685(3) 0.0203(12) Uani 1 1 d . . .
H22A H 0.6197 0.3396 1.0198 0.024 Uiso 1 1 calc R U .
H22B H 0.6049 0.3187 0.9260 0.024 Uiso 1 1 calc R U .
C23 C 0.5612(3) 0.2503(3) 0.9850(3) 0.0198(11) Uani 1 1 d . . .
H23A H 0.6053 0.2225 1.0115 0.024 Uiso 1 1 calc R U .
H23B H 0.5352 0.2533 1.0235 0.024 Uiso 1 1 calc R U .
C24 C 0.4934(3) 0.1489(3) 0.9255(3) 0.0198(11) Uani 1 1 d . . .
H24A H 0.4662 0.1529 0.9627 0.024 Uiso 1 1 calc R U .
H24B H 0.5376 0.1218 0.9545 0.024 Uiso 1 1 calc R U .
C25 C 0.4465(3) 0.1118(3) 0.8459(3) 0.0177(11) Uani 1 1 d . . .
H25A H 0.4730 0.1093 0.8079 0.021 Uiso 1 1 calc R U .
H25B H 0.4373 0.0646 0.8597 0.021 Uiso 1 1 calc R U .
C26 C 0.3242(3) 0.2964(3) 0.9265(4) 0.0274(13) Uani 1 1 d . . .
C27 C 0.2565(3) 0.3249(4) 0.9295(4) 0.0402(16) Uani 1 1 d . . .
H27A H 0.2572 0.3746 0.9247 0.060 Uiso 1 1 calc R U .
H27B H 0.2524 0.3127 0.9822 0.060 Uiso 1 1 calc R U .
H27C H 0.2150 0.3064 0.8837 0.060 Uiso 1 1 calc R U .
F1 F 0.2209(2) 0.49986(17) 0.4479(2) 0.0402(9) Uani 1 1 d . . .
F2 F 0.1994(2) 0.34078(18) 0.4710(2) 0.0443(10) Uani 1 1 d . . .
F3 F 0.1669(2) 0.4368(2) 0.5189(3) 0.0501(11) Uani 1 1 d . . .
F4 F 0.13630(19) 0.42177(19) 0.3812(2) 0.0435(10) Uani 1 1 d . . .
F5 F 0.25457(19) 0.40377(19) 0.4017(2) 0.0380(9) Uani 1 1 d . . .
F6 F 0.28425(18) 0.41930(19) 0.5391(2) 0.0397(9) Uani 1 1 d . . .
N1 N 0.3773(2) 0.1462(2) 0.8044(3) 0.0169(9) Uani 1 1 d . . .
N2 N 0.2949(2) 0.2133(2) 0.7239(3) 0.0148(9) Uani 1 1 d . . .
N3 N 0.3110(2) 0.3668(2) 0.7269(3) 0.0187(9) Uani 1 1 d . . .
N4 N 0.4316(2) 0.4295(2) 0.8645(3) 0.0159(9) Uani 1 1 d . . .
N5 N 0.5204(2) 0.3672(2) 0.9399(3) 0.0155(9) Uani 1 1 d . . .
N6 N 0.5143(2) 0.2171(2) 0.9077(3) 0.0146(9) Uani 1 1 d . . .
H6A H 0.476(3) 0.247(3) 0.893(3) 0.017 Uiso 1 1 d . U .
N7 N 0.3754(3) 0.2755(3) 0.9226(4) 0.0384(14) Uani 1 1 d . . .
P1 P 0.21073(8) 0.42054(8) 0.46030(10) 0.0266(4) Uani 1 1 d . . .
P2 P 0.0000 0.27757(19) 0.7500 0.0695(10) Uani 1 2 d DS TU P
F7 F -0.0175(7) 0.3556(4) 0.7535(12) 0.112(5) Uani 0.5 1 d D U P
F8 F 0.0112(7) 0.1975(4) 0.7463(12) 0.065(4) Uani 0.5 1 d D U P
F9 F 0.0273(7) 0.2904(8) 0.6776(8) 0.117(6) Uani 0.5 1 d D U P
F10 F -0.0811(5) 0.2676(8) 0.6840(8) 0.081(5) Uani 0.5 1 d D U P
F11 F -0.0317(5) 0.2635(7) 0.8217(7) 0.066(4) Uani 0.5 1 d D U P
F12 F 0.0774(5) 0.2875(9) 0.8154(8) 0.103(6) Uani 0.5 1 d D U P
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C1 Ag1 N6 165.81(18) . 2_656
C1 Ag1 Ag1 97.38(14) . 2_656
N6 Ag1 Ag1 91.67(11) 2_656 2_656
C1 Ag1 Ag2 103.88(14) . .
N6 Ag1 Ag2 89.88(11) 2_656 .
Ag1 Ag1 Ag2 64.243(8) 2_656 .
C15 Ag2 C15 161.5(3) 2_656 .
C15 Ag2 Ag1 89.44(14) 2_656 .
C15 Ag2 Ag1 107.46(13) . .
C15 Ag2 Ag1 107.46(13) 2_656 2_656
C15 Ag2 Ag1 89.44(14) . 2_656
Ag1 Ag2 Ag1 51.515(16) . 2_656
N1 C1 N2 105.4(4) . .
N1 C1 Ag1 126.6(3) . .
N2 C1 Ag1 126.6(4) . .
C3 C2 C7 122.6(5) . .
C3 C2 N2 106.0(4) . .
C7 C2 N2 131.4(5) . .
N1 C3 C2 106.5(4) . .
N1 C3 C4 132.2(5) . .
C2 C3 C4 121.3(5) . .
C5 C4 C3 116.4(5) . .
C5 C4 H4 121.8 . .
C3 C4 H4 121.8 . .
C4 C5 C6 122.0(5) . .
C4 C5 H5 119.0 . .
C6 C5 H5 119.0 . .
C7 C6 C5 122.1(5) . .
C7 C6 H6 119.0 . .
C5 C6 H6 119.0 . .
C6 C7 C2 115.7(5) . .
C6 C7 H7 122.2 . .
C2 C7 H7 122.2 . .
N2 C8 C9 112.6(4) . .
N2 C8 H8A 109.1 . .
C9 C8 H8A 109.1 . .
N2 C8 H8B 109.1 . .
C9 C8 H8B 109.1 . .
H8A C8 H8B 107.8 . .
N3 C9 C10 122.1(5) . .
N3 C9 C8 115.1(4) . .
C10 C9 C8 122.9(5) . .
C11 C10 C9 119.5(5) . .
C11 C10 H10 120.2 . .
C9 C10 H10 120.2 . .
C10 C11 C12 119.8(5) . .
C10 C11 H11 120.1 . .
C12 C11 H11 120.1 . .
C11 C12 C13 116.9(5) . .
C11 C12 H12 121.6 . .
C13 C12 H12 121.6 . .
N3 C13 C12 124.3(5) . .
N3 C13 C14 114.5(4) . .
C12 C13 C14 121.2(5) . .
N4 C14 C13 112.7(4) . .
N4 C14 H14A 109.1 . .
C13 C14 H14A 109.1 . .
N4 C14 H14B 109.1 . .
C13 C14 H14B 109.1 . .
H14A C14 H14B 107.8 . .
N5 C15 N4 105.4(4) . .
N5 C15 Ag2 132.9(4) . .
N4 C15 Ag2 121.5(4) . .
C17 C16 C21 122.0(5) . .
C17 C16 N5 105.8(4) . .
C21 C16 N5 132.2(5) . .
C18 C17 C16 122.1(5) . .
C18 C17 N4 132.0(5) . .
C16 C17 N4 105.8(4) . .
C17 C18 C19 116.0(5) . .
C17 C18 H18 122.0 . .
C19 C18 H18 122.0 . .
C20 C19 C18 121.6(5) . .
C20 C19 H19 119.2 . .
C18 C19 H19 119.2 . .
C21 C20 C19 122.4(5) . .
C21 C20 H20 118.8 . .
C19 C20 H20 118.8 . .
C20 C21 C16 115.8(5) . .
C20 C21 H21 122.1 . .
C16 C21 H21 122.1 . .
N5 C22 C23 111.4(4) . .
N5 C22 H22A 109.3 . .
C23 C22 H22A 109.3 . .
N5 C22 H22B 109.3 . .
C23 C22 H22B 109.3 . .
H22A C22 H22B 108.0 . .
N6 C23 C22 111.2(4) . .
N6 C23 H23A 109.4 . .
C22 C23 H23A 109.4 . .
N6 C23 H23B 109.4 . .
C22 C23 H23B 109.4 . .
H23A C23 H23B 108.0 . .
N6 C24 C25 111.5(4) . .
N6 C24 H24A 109.3 . .
C25 C24 H24A 109.3 . .
N6 C24 H24B 109.3 . .
C25 C24 H24B 109.3 . .
H24A C24 H24B 108.0 . .
N1 C25 C24 111.8(4) . .
N1 C25 H25A 109.2 . .
C24 C25 H25A 109.2 . .
N1 C25 H25B 109.2 . .
C24 C25 H25B 109.2 . .
H25A C25 H25B 107.9 . .
N7 C26 C27 178.4(7) . .
C26 C27 H27A 109.5 . .
C26 C27 H27B 109.5 . .
H27A C27 H27B 109.5 . .
C26 C27 H27C 109.5 . .
H27A C27 H27C 109.5 . .
H27B C27 H27C 109.5 . .
C1 N1 C3 111.3(4) . .
C1 N1 C25 124.5(4) . .
C3 N1 C25 124.2(4) . .
C1 N2 C2 110.8(4) . .
C1 N2 C8 125.3(4) . .
C2 N2 C8 123.9(4) . .
C13 N3 C9 117.4(4) . .
C15 N4 C17 111.3(4) . .
C15 N4 C14 125.6(4) . .
C17 N4 C14 123.1(4) . .
C15 N5 C16 111.6(4) . .
C15 N5 C22 126.2(4) . .
C16 N5 C22 122.1(4) . .
C24 N6 C23 110.1(4) . .
C24 N6 Ag1 112.8(3) . 2_656
C23 N6 Ag1 109.5(3) . 2_656
C24 N6 H6A 111(3) . .
C23 N6 H6A 99(3) . .
Ag1 N6 H6A 113(3) 2_656 .
F6 P1 F1 90.6(2) . .
F6 P1 F3 89.8(2) . .
F1 P1 F3 91.1(2) . .
F6 P1 F2 90.5(2) . .
F1 P1 F2 178.9(3) . .
F3 P1 F2 89.3(2) . .
F6 P1 F5 90.2(2) . .
F1 P1 F5 89.3(2) . .
F3 P1 F5 179.6(2) . .
F2 P1 F5 90.3(2) . .
F6 P1 F4 179.6(2) . .
F1 P1 F4 89.5(2) . .
F3 P1 F4 89.8(2) . .
F2 P1 F4 89.4(2) . .
F5 P1 F4 90.2(2) . .
F12 P2 F12 165.6(13) . 2_556
F12 P2 F9 91.4(7) . .
F12 P2 F9 86.3(7) 2_556 .
F12 P2 F9 86.3(7) . 2_556
F12 P2 F9 91.4(7) 2_556 2_556
F9 P2 F9 161.5(11) . 2_556
F12 P2 F7 74.6(11) . 2_556
F12 P2 F7 91.3(6) 2_556 2_556
F9 P2 F7 70.5(9) . 2_556
F9 P2 F7 91.2(6) 2_556 2_556
F12 P2 F7 91.3(6) . .
F12 P2 F7 74.6(11) 2_556 .
F9 P2 F7 91.2(6) . .
F9 P2 F7 70.5(9) 2_556 .
F7 P2 F7 27.4(7) 2_556 .
F12 P2 F8 102.1(11) . 2_556
F12 P2 F8 92.2(6) 2_556 2_556
F9 P2 F8 106.7(10) . 2_556
F9 P2 F8 91.8(6) 2_556 2_556
F7 P2 F8 175.4(5) 2_556 2_556
F7 P2 F8 157.1(6) . 2_556
F12 P2 F8 92.2(6) . .
F12 P2 F8 102.1(11) 2_556 .
F9 P2 F8 91.8(6) . .
F9 P2 F8 106.7(10) 2_556 .
F7 P2 F8 157.1(6) 2_556 .
F7 P2 F8 175.4(5) . .
F8 P2 F8 18.3(8) 2_556 .
F12 P2 F10 14.3(11) . 2_556
F12 P2 F10 178.5(9) 2_556 2_556
F9 P2 F10 92.3(7) . 2_556
F9 P2 F10 90.0(7) 2_556 2_556
F7 P2 F10 88.3(6) 2_556 2_556
F7 P2 F10 105.5(10) . 2_556
F8 P2 F10 88.2(6) 2_556 2_556
F8 P2 F10 77.9(10) . 2_556
F12 P2 F10 178.5(9) . .
F12 P2 F10 14.3(11) 2_556 .
F9 P2 F10 90.0(7) . .
F9 P2 F10 92.3(7) 2_556 .
F7 P2 F10 105.5(10) 2_556 .
F7 P2 F10 88.3(6) . .
F8 P2 F10 77.9(10) 2_556 .
F8 P2 F10 88.2(6) . .
F10 P2 F10 166.0(12) 2_556 .
F12 P2 F11 91.3(7) . 2_556
F12 P2 F11 91.1(7) 2_556 2_556
F9 P2 F11 19.3(8) . 2_556
F9 P2 F11 177.4(8) 2_556 2_556
F7 P2 F11 88.9(5) 2_556 2_556
F7 P2 F11 110.5(8) . 2_556
F8 P2 F11 87.9(5) 2_556 2_556
F8 P2 F11 72.6(9) . 2_556
F10 P2 F11 87.5(6) 2_556 2_556
F10 P2 F11 90.2(6) . 2_556
F12 P2 F11 91.1(7) . .
F12 P2 F11 91.3(7) 2_556 .
F9 P2 F11 177.4(8) . .
F9 P2 F11 19.3(8) 2_556 .
F7 P2 F11 110.5(8) 2_556 .
F7 P2 F11 88.9(5) . .
F8 P2 F11 72.6(9) 2_556 .
F8 P2 F11 87.9(5) . .
F10 P2 F11 90.2(6) 2_556 .
F10 P2 F11 87.5(6) . .
F11 P2 F11 160.4(10) 2_556 .
F7 F7 P2 76.3(4) 2_556 .
F8 F8 P2 80.8(4) 2_556 .
F11 F9 P2 85.6(19) 2_556 .
F12 F10 P2 75(2) 2_556 .
F9 F11 P2 75.2(17) 2_556 .
F10 F12 P2 91(3) 2_556 .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 C1 2.063(5) .
Ag1 N6 2.172(4) 2_656
Ag1 Ag1 2.9284(8) 2_656
Ag1 Ag2 3.3693(7) .
Ag2 C15 2.103(5) 2_656
Ag2 C15 2.103(5) .
Ag2 Ag1 3.3693(7) 2_656
C1 N1 1.357(6) .
C1 N2 1.362(6) .
C2 C3 1.384(7) .
C2 C7 1.391(6) .
C2 N2 1.398(6) .
C3 N1 1.384(6) .
C3 C4 1.397(7) .
C4 C5 1.376(7) .
C4 H4 0.9500 .
C5 C6 1.396(8) .
C5 H5 0.9500 .
C6 C7 1.382(8) .
C6 H6 0.9500 .
C7 H7 0.9500 .
C8 N2 1.463(7) .
C8 C9 1.500(7) .
C8 H8A 0.9900 .
C8 H8B 0.9900 .
C9 N3 1.344(6) .
C9 C10 1.385(7) .
C10 C11 1.367(8) .
C10 H10 0.9500 .
C11 C12 1.380(8) .
C11 H11 0.9500 .
C12 C13 1.397(7) .
C12 H12 0.9500 .
C13 N3 1.327(7) .
C13 C14 1.513(7) .
C14 N4 1.454(6) .
C14 H14A 0.9900 .
C14 H14B 0.9900 .
C15 N5 1.350(7) .
C15 N4 1.352(6) .
C16 C17 1.387(7) .
C16 C21 1.391(7) .
C16 N5 1.395(6) .
C17 C18 1.386(7) .
C17 N4 1.400(6) .
C18 C19 1.393(8) .
C18 H18 0.9500 .
C19 C20 1.390(8) .
C19 H19 0.9500 .
C20 C21 1.383(7) .
C20 H20 0.9500 .
C21 H21 0.9500 .
C22 N5 1.465(6) .
C22 C23 1.517(7) .
C22 H22A 0.9900 .
C22 H22B 0.9900 .
C23 N6 1.474(6) .
C23 H23A 0.9900 .
C23 H23B 0.9900 .
C24 N6 1.469(6) .
C24 C25 1.538(7) .
C24 H24A 0.9900 .
C24 H24B 0.9900 .
C25 N1 1.461(6) .
C25 H25A 0.9900 .
C25 H25B 0.9900 .
C26 N7 1.122(7) .
C26 C27 1.477(8) .
C27 H27A 0.9800 .
C27 H27B 0.9800 .
C27 H27C 0.9800 .
F1 P1 1.596(4) .
F2 P1 1.603(4) .
F3 P1 1.601(4) .
F4 P1 1.604(4) .
F5 P1 1.603(3) .
F6 P1 1.591(4) .
N6 Ag1 2.172(4) 2_656
N6 H6A 0.92(5) .
P2 F12 1.550(10) .
P2 F12 1.550(10) 2_556
P2 F9 1.568(10) .
P2 F9 1.568(10) 2_556
P2 F7 1.578(8) 2_556
P2 F7 1.579(8) .
P2 F8 1.593(8) 2_556
P2 F8 1.593(8) .
P2 F10 1.607(9) 2_556
P2 F10 1.607(9) .
P2 F11 1.617(10) 2_556
P2 F11 1.617(10) .
F7 F7 0.75(2) 2_556
F8 F8 0.51(2) 2_556
F9 F11 0.53(2) 2_556
F10 F12 0.40(3) 2_556
F11 F9 0.53(2) 2_556
F12 F10 0.40(3) 2_556
