#------------------------------------------------------------------------------
#$Date: 2019-11-17 13:54:56 +0200 (Sun, 17 Nov 2019) $
#$Revision: 230309 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/05/69/7056987.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7056987
loop_
_publ_author_name
'Lu, Taotao'
'Yang, Chu-Fan'
'Steren, Carlos A.'
'Fei, Fan'
'Chen, Xue-Tai'
'Xue, Zi-Ling'
_publ_section_title
;
 Synthesis and characterization of Ag(i) and Au(i) complexes with
 macrocyclic hybrid amine N-heterocyclic carbene ligands
;
_journal_issue                   6
_journal_name_full               'New Journal of Chemistry'
_journal_page_first              4700
_journal_paper_doi               10.1039/C7NJ04020B
_journal_volume                  42
_journal_year                    2018
_chemical_formula_sum            'C60 H76 Ag4 F24 N20 P4'
_chemical_formula_weight         2088.76
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2017-10-17 deposited with the CCDC.
2018-02-06 downloaded from the CCDC.
;
_cell_angle_alpha                111.816(2)
_cell_angle_beta                 94.973(2)
_cell_angle_gamma                101.746(2)
_cell_formula_units_Z            1
_cell_length_a                   11.5810(10)
_cell_length_b                   13.0142(11)
_cell_length_c                   14.4842(12)
_cell_measurement_reflns_used    9341
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      27.53
_cell_measurement_theta_min      2.45
_cell_volume                     1952.3(3)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_structure_solution    'SHELXS-97 (Sheldrick 2008)'
_diffrn_ambient_temperature      150(2)
_diffrn_measured_fraction_theta_full 0.991
_diffrn_measured_fraction_theta_max 0.990
_diffrn_measurement_device_type  'APEX2 CCD detector'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0292
_diffrn_reflns_av_unetI/netI     0.0482
_diffrn_reflns_Laue_measured_fraction_full 0.991
_diffrn_reflns_Laue_measured_fraction_max 0.990
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -13
_diffrn_reflns_number            16380
_diffrn_reflns_point_group_measured_fraction_full 0.991
_diffrn_reflns_point_group_measured_fraction_max 0.990
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.544
_diffrn_reflns_theta_min         2.179
_diffrn_source                   'fine-focus sealed tube'
_exptl_absorpt_coefficient_mu    1.180
_exptl_absorpt_correction_T_max  0.7456
_exptl_absorpt_correction_T_min  0.5730
_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_colour            corlourless
_exptl_crystal_density_diffrn    1.777
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1040
_exptl_crystal_size_max          0.220
_exptl_crystal_size_mid          0.200
_exptl_crystal_size_min          0.170
_refine_diff_density_max         0.854
_refine_diff_density_min         -0.590
_refine_diff_density_rms         0.098
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.029
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     567
_refine_ls_number_reflns         8900
_refine_ls_number_restraints     144
_refine_ls_restrained_S_all      1.026
_refine_ls_R_factor_all          0.0499
_refine_ls_R_factor_gt           0.0377
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0347P)²+2.5590P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0834
_refine_ls_wR_factor_ref         0.0878
_reflns_Friedel_coverage         0.000
_reflns_number_gt                7422
_reflns_number_total             8900
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c7nj04020b2.cif
_cod_data_source_block           2
_cod_depositor_comments
'Adding full bibliography for 7056979--7056989.cif.'
_cod_database_code               7056987
_shelx_shelxl_version_number     2014/7
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.781
_shelx_estimated_absorpt_t_max   0.825
_exptl_absorpt_special_details   'SADABS (Bruker, 2014)'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.37474(2) 1.08435(2) 0.47432(2) 0.01817(7) Uani 1 1 d . . . . .
Ag2 Ag 0.52515(2) 0.94788(2) 0.30663(2) 0.02027(7) Uani 1 1 d . . . . .
C1 C 0.2214(3) 0.9499(3) 0.4297(2) 0.0164(6) Uani 1 1 d . . . . .
C2 C 0.0530(3) 0.8174(3) 0.3331(2) 0.0190(6) Uani 1 1 d . . . . .
C3 C 0.0403(3) 0.8506(3) 0.4344(2) 0.0193(6) Uani 1 1 d . . . . .
C4 C -0.0358(3) 0.7362(3) 0.2546(3) 0.0258(7) Uani 1 1 d . . . . .
H4 H -0.0261 0.7135 0.1859 0.031 Uiso 1 1 calc R U . . .
C5 C -0.1397(3) 0.6898(3) 0.2821(3) 0.0314(8) Uani 1 1 d . . . . .
H5 H -0.2032 0.6344 0.2309 0.038 Uiso 1 1 calc R U . . .
C6 C -0.1527(3) 0.7228(3) 0.3831(3) 0.0310(8) Uani 1 1 d . . . . .
H6 H -0.2250 0.6889 0.3986 0.037 Uiso 1 1 calc R U . . .
C7 C -0.0638(3) 0.8035(3) 0.4617(3) 0.0247(7) Uani 1 1 d . . . . .
H7 H -0.0733 0.8254 0.5304 0.030 Uiso 1 1 calc R U . . .
C8 C 0.2169(3) 0.8760(3) 0.2441(2) 0.0189(6) Uani 1 1 d . . . . .
H8A H 0.2789 0.9481 0.2612 0.023 Uiso 1 1 calc R U . . .
H8B H 0.1530 0.8706 0.1911 0.023 Uiso 1 1 calc R U . . .
C9 C 0.2724(3) 0.7759(3) 0.2021(2) 0.0195(6) Uani 1 1 d . . . . .
H9A H 0.2123 0.7040 0.1898 0.023 Uiso 1 1 calc R U . . .
H9B H 0.2948 0.7712 0.1365 0.023 Uiso 1 1 calc R U . . .
C10 C 0.4241(3) 0.6818(3) 0.2273(2) 0.0196(6) Uani 1 1 d . . . . .
H10A H 0.4503 0.6780 0.1632 0.023 Uiso 1 1 calc R U . . .
H10B H 0.3574 0.6134 0.2117 0.023 Uiso 1 1 calc R U . . .
C11 C 0.5267(3) 0.6801(3) 0.2976(2) 0.0180(6) Uani 1 1 d . . . . .
H11A H 0.5609 0.6156 0.2613 0.022 Uiso 1 1 calc R U . . .
H11B H 0.5903 0.7519 0.3184 0.022 Uiso 1 1 calc R U . . .
C12 C 0.5119(3) 0.7537(3) 0.4817(2) 0.0167(6) Uani 1 1 d . . . . .
C13 C 0.4035(3) 0.5907(3) 0.4869(2) 0.0187(6) Uani 1 1 d . . . . .
C14 C 0.4228(3) 0.5661(3) 0.3880(2) 0.0182(6) Uani 1 1 d . . . . .
C15 C 0.3790(3) 0.4573(3) 0.3114(3) 0.0227(7) Uani 1 1 d . . . . .
H15 H 0.3932 0.4408 0.2444 0.027 Uiso 1 1 calc R U . . .
C16 C 0.3140(3) 0.3748(3) 0.3379(3) 0.0286(8) Uani 1 1 d . . . . .
H16 H 0.2815 0.2995 0.2879 0.034 Uiso 1 1 calc R U . . .
C17 C 0.2948(3) 0.3997(3) 0.4371(3) 0.0297(8) Uani 1 1 d . . . . .
H17 H 0.2497 0.3401 0.4523 0.036 Uiso 1 1 calc R U . . .
C18 C 0.3385(3) 0.5068(3) 0.5138(3) 0.0245(7) Uani 1 1 d . . . . .
H18 H 0.3252 0.5226 0.5809 0.029 Uiso 1 1 calc R U . . .
C19 C 0.4640(3) 0.7686(3) 0.6493(2) 0.0192(6) Uani 1 1 d . . . . .
H19A H 0.5321 0.8377 0.6755 0.023 Uiso 1 1 calc R U . . .
H19B H 0.4780 0.7196 0.6853 0.023 Uiso 1 1 calc R U . . .
C20 C 0.3491(3) 0.8042(3) 0.6713(2) 0.0194(6) Uani 1 1 d . . . . .
H20A H 0.2806 0.7355 0.6423 0.023 Uiso 1 1 calc R U . . .
H20B H 0.3528 0.8381 0.7454 0.023 Uiso 1 1 calc R U . . .
C21 C 0.2080(3) 0.9092(3) 0.6487(2) 0.0194(6) Uani 1 1 d . . . . .
H21A H 0.2106 0.9449 0.7225 0.023 Uiso 1 1 calc R U . . .
H21B H 0.1470 0.8350 0.6214 0.023 Uiso 1 1 calc R U . . .
C22 C 0.1714(3) 0.9860(3) 0.6011(2) 0.0189(6) Uani 1 1 d . . . . .
H22A H 0.0994 1.0080 0.6260 0.023 Uiso 1 1 calc R U . . .
H22B H 0.2367 1.0567 0.6224 0.023 Uiso 1 1 calc R U . . .
C23A C 0.3917(3) 0.9986(3) 0.0914(3) 0.0241(7) Uani 1 1 d . . . . .
C24A C 0.3259(4) 1.0133(4) 0.0096(3) 0.0461(11) Uani 1 1 d . . . . .
H24A H 0.3777 1.0697 -0.0086 0.069 Uiso 1 1 calc R U . . .
H24B H 0.2557 1.0403 0.0312 0.069 Uiso 1 1 calc R U . . .
H24C H 0.2997 0.9400 -0.0491 0.069 Uiso 1 1 calc R U . . .
F1A F 0.0062(2) 0.0066(2) 0.24863(18) 0.0402(6) Uani 1 1 d . . . . .
F2A F 0.1041(2) 0.1691(2) 0.1380(2) 0.0488(6) Uani 1 1 d . . . . .
F3A F 0.1893(2) 0.10457(19) 0.24389(19) 0.0397(5) Uani 1 1 d . . . . .
F4A F 0.0660(2) -0.0218(2) 0.10002(18) 0.0498(7) Uani 1 1 d . . . . .
F5A F -0.0800(2) 0.0714(2) 0.1431(2) 0.0514(7) Uani 1 1 d . . . . .
F6A F 0.0441(2) 0.1968(2) 0.28749(18) 0.0432(6) Uani 1 1 d . . . . .
F1B F 0.4945(3) 0.7166(2) 0.8577(2) 0.0593(7) Uani 1 1 d . . . . .
F2B F 0.2653(3) 0.5726(3) 0.9011(3) 0.0767(10) Uani 1 1 d . . . . .
F3B F 0.4177(3) 0.7221(3) 0.9964(2) 0.0754(10) Uani 1 1 d . . . . .
F4B F 0.3069(3) 0.7272(3) 0.8638(3) 0.0880(12) Uani 1 1 d . . . . .
F5B F 0.3474(3) 0.5627(3) 0.7624(2) 0.0755(10) Uani 1 1 d . . . . .
F6B F 0.4550(4) 0.5610(3) 0.8945(3) 0.0866(12) Uani 1 1 d . . . . .
N1 N 0.1452(2) 0.9306(2) 0.49041(19) 0.0172(5) Uani 1 1 d . . . . .
N2 N 0.1658(2) 0.8804(2) 0.33413(19) 0.0174(5) Uani 1 1 d . . . . .
N3 N 0.3804(2) 0.7867(2) 0.27191(19) 0.0166(5) Uani 1 1 d . . . . .
H3 H 0.3554 0.7893 0.3370 0.020 Uiso 1 1 calc R U . . .
N4 N 0.4891(2) 0.6680(2) 0.38771(19) 0.0163(5) Uani 1 1 d . . . . .
N5 N 0.4598(2) 0.7065(2) 0.54146(19) 0.0180(5) Uani 1 1 d . . . . .
N6 N 0.3278(2) 0.8884(2) 0.62945(19) 0.0165(5) Uani 1 1 d . . . . .
H6A H 0.3240 0.8530 0.5547 0.020 Uiso 1 1 calc R U . . .
P1A P 0.05413(8) 0.08779(8) 0.19254(7) 0.02546(19) Uani 1 1 d . . . . .
P1B P 0.37980(11) 0.64453(9) 0.88022(7) 0.0372(3) Uani 1 1 d . . . . .
N7A N 0.4430(3) 0.9870(3) 0.1549(2) 0.0316(7) Uani 1 1 d . . . . .
N7C N 0.2069(3) 0.6821(3) 0.4071(3) 0.0416(9) Uani 1 1 d . . . . .
C23C C 0.1331(5) 0.6010(4) 0.3798(4) 0.0486(11) Uani 1 1 d . . . . .
C24C C 0.0351(6) 0.4972(6) 0.3470(6) 0.089(2) Uani 1 1 d . . . . .
H24D H -0.0056 0.4980 0.4037 0.134 Uiso 1 1 calc R U . . .
H24E H 0.0674 0.4298 0.3235 0.134 Uiso 1 1 calc R U . . .
H24F H -0.0223 0.4944 0.2916 0.134 Uiso 1 1 calc R U . . .
N7D N 1.077(2) 0.4876(17) 0.080(2) 0.101(5) Uani 0.39(3) 1 d D U P A 1
C23D C 1.014(3) 0.401(2) 0.068(2) 0.079(5) Uani 0.39(3) 1 d D U P A 1
C24D C 0.935(4) 0.288(3) 0.046(4) 0.063(6) Uani 0.39(3) 1 d D U P A 1
H24G H 0.9434 0.2333 -0.0198 0.095 Uiso 0.39(3) 1 calc R U P A 1
H24H H 0.8512 0.2929 0.0436 0.095 Uiso 0.39(3) 1 calc R U P A 1
H24I H 0.9566 0.2617 0.0986 0.095 Uiso 0.39(3) 1 calc R U P A 1
N7W N 1.1257(15) 0.4802(10) 0.1281(13) 0.097(4) Uani 0.61(3) 1 d D U P A 2
C23W C 1.0462(15) 0.4000(12) 0.0923(12) 0.064(3) Uani 0.61(3) 1 d D U P A 2
C24W C 0.949(2) 0.2939(19) 0.040(3) 0.061(4) Uani 0.61(3) 1 d D U P A 2
H24J H 0.8948 0.3040 -0.0102 0.091 Uiso 0.61(3) 1 calc R U P A 2
H24K H 0.9041 0.2774 0.0891 0.091 Uiso 0.61(3) 1 calc R U P A 2
H24L H 0.9836 0.2301 0.0056 0.091 Uiso 0.61(3) 1 calc R U P A 2
N7B N 0.666(3) 0.828(3) 0.1903(17) 0.027(4) Uani 0.33(2) 1 d D U P B 3
C23B C 0.686(2) 0.7695(18) 0.1179(16) 0.028(3) Uani 0.33(2) 1 d D U P B 3
C24B C 0.711(2) 0.684(2) 0.0263(13) 0.054(5) Uani 0.33(2) 1 d D U P B 3
H24M H 0.6696 0.6883 -0.0337 0.081 Uiso 0.33(2) 1 calc R U P B 3
H24N H 0.6824 0.6075 0.0252 0.081 Uiso 0.33(2) 1 calc R U P B 3
H24O H 0.7975 0.7005 0.0266 0.081 Uiso 0.33(2) 1 calc R U P B 3
N7Y N 0.6539(13) 0.8425(13) 0.1806(8) 0.025(2) Uani 0.67(2) 1 d D U P B 4
C23Y C 0.6997(11) 0.8007(10) 0.1173(8) 0.032(2) Uani 0.67(2) 1 d D U P B 4
C24Y C 0.7563(10) 0.7465(13) 0.0325(7) 0.054(3) Uani 0.67(2) 1 d D U P B 4
H24P H 0.7821 0.6825 0.0401 0.082 Uiso 0.67(2) 1 calc R U P B 4
H24Q H 0.8260 0.8026 0.0310 0.082 Uiso 0.67(2) 1 calc R U P B 4
H24R H 0.6988 0.7181 -0.0307 0.082 Uiso 0.67(2) 1 calc R U P B 4
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C12 Ag1 C1 162.23(11) 2_676 .
C12 Ag1 Ag2 96.49(8) 2_676 .
C1 Ag1 Ag2 96.01(8) . .
N6 Ag2 N3 169.58(9) 2_676 .
N6 Ag2 N7A 93.62(10) 2_676 .
N3 Ag2 N7A 95.72(10) . .
N6 Ag2 N7Y 91.7(4) 2_676 .
N3 Ag2 N7Y 94.0(4) . .
N7A Ag2 N7Y 82.9(3) . .
N6 Ag2 N7B 92.7(8) 2_676 .
N3 Ag2 N7B 92.0(8) . .
N7A Ag2 N7B 89.2(6) . .
N6 Ag2 Ag1 86.50(6) 2_676 .
N3 Ag2 Ag1 87.40(6) . .
N7A Ag2 Ag1 99.41(7) . .
N7Y Ag2 Ag1 177.1(3) . .
N7B Ag2 Ag1 171.4(5) . .
N1 C1 N2 106.1(3) . .
N1 C1 Ag1 125.4(2) . .
N2 C1 Ag1 127.2(2) . .
N2 C2 C4 132.0(3) . .
N2 C2 C3 105.6(3) . .
C4 C2 C3 122.4(3) . .
N1 C3 C7 132.5(3) . .
N1 C3 C2 106.3(3) . .
C7 C3 C2 121.2(3) . .
C2 C4 C5 116.3(3) . .
C2 C4 H4 121.9 . .
C5 C4 H4 121.9 . .
C4 C5 C6 121.5(4) . .
C4 C5 H5 119.3 . .
C6 C5 H5 119.3 . .
C7 C6 C5 122.4(3) . .
C7 C6 H6 118.8 . .
C5 C6 H6 118.8 . .
C6 C7 C3 116.3(3) . .
C6 C7 H7 121.8 . .
C3 C7 H7 121.8 . .
N2 C8 C9 113.1(3) . .
N2 C8 H8A 109.0 . .
C9 C8 H8A 109.0 . .
N2 C8 H8B 109.0 . .
C9 C8 H8B 109.0 . .
H8A C8 H8B 107.8 . .
N3 C9 C8 112.2(3) . .
N3 C9 H9A 109.2 . .
C8 C9 H9A 109.2 . .
N3 C9 H9B 109.2 . .
C8 C9 H9B 109.2 . .
H9A C9 H9B 107.9 . .
N3 C10 C11 112.0(3) . .
N3 C10 H10A 109.2 . .
C11 C10 H10A 109.2 . .
N3 C10 H10B 109.2 . .
C11 C10 H10B 109.2 . .
H10A C10 H10B 107.9 . .
N4 C11 C10 112.0(3) . .
N4 C11 H11A 109.2 . .
C10 C11 H11A 109.2 . .
N4 C11 H11B 109.2 . .
C10 C11 H11B 109.2 . .
H11A C11 H11B 107.9 . .
N5 C12 N4 106.0(3) . .
N5 C12 Ag1 127.6(2) . 2_676
N4 C12 Ag1 125.9(2) . 2_676
C18 C13 N5 132.8(3) . .
C18 C13 C14 121.4(3) . .
N5 C13 C14 105.9(3) . .
C15 C14 N4 131.7(3) . .
C15 C14 C13 122.1(3) . .
N4 C14 C13 106.2(3) . .
C16 C15 C14 116.5(3) . .
C16 C15 H15 121.8 . .
C14 C15 H15 121.8 . .
C15 C16 C17 121.3(3) . .
C15 C16 H16 119.3 . .
C17 C16 H16 119.3 . .
C18 C17 C16 122.8(3) . .
C18 C17 H17 118.6 . .
C16 C17 H17 118.6 . .
C17 C18 C13 116.0(3) . .
C17 C18 H18 122.0 . .
C13 C18 H18 122.0 . .
N5 C19 C20 112.2(3) . .
N5 C19 H19A 109.2 . .
C20 C19 H19A 109.2 . .
N5 C19 H19B 109.2 . .
C20 C19 H19B 109.2 . .
H19A C19 H19B 107.9 . .
N6 C20 C19 112.8(2) . .
N6 C20 H20A 109.0 . .
C19 C20 H20A 109.0 . .
N6 C20 H20B 109.0 . .
C19 C20 H20B 109.0 . .
H20A C20 H20B 107.8 . .
N6 C21 C22 112.5(2) . .
N6 C21 H21A 109.1 . .
C22 C21 H21A 109.1 . .
N6 C21 H21B 109.1 . .
C22 C21 H21B 109.1 . .
H21A C21 H21B 107.8 . .
N1 C22 C21 112.5(2) . .
N1 C22 H22A 109.1 . .
C21 C22 H22A 109.1 . .
N1 C22 H22B 109.1 . .
C21 C22 H22B 109.1 . .
H22A C22 H22B 107.8 . .
N7A C23A C24A 179.9(5) . .
C23A C24A H24A 109.5 . .
C23A C24A H24B 109.5 . .
H24A C24A H24B 109.5 . .
C23A C24A H24C 109.5 . .
H24A C24A H24C 109.5 . .
H24B C24A H24C 109.5 . .
C1 N1 C3 110.9(3) . .
C1 N1 C22 124.5(3) . .
C3 N1 C22 124.6(3) . .
C1 N2 C2 111.0(3) . .
C1 N2 C8 124.0(3) . .
C2 N2 C8 125.0(3) . .
C9 N3 C10 108.2(2) . .
C9 N3 Ag2 112.83(18) . .
C10 N3 Ag2 112.00(19) . .
C9 N3 H3 107.9 . .
C10 N3 H3 107.9 . .
Ag2 N3 H3 107.9 . .
C12 N4 C14 110.8(2) . .
C12 N4 C11 125.3(3) . .
C14 N4 C11 123.9(3) . .
C12 N5 C13 111.2(3) . .
C12 N5 C19 124.1(3) . .
C13 N5 C19 124.7(3) . .
C20 N6 C21 107.6(2) . .
C20 N6 Ag2 112.7(2) . 2_676
C21 N6 Ag2 111.99(19) . 2_676
C20 N6 H6A 108.1 . .
C21 N6 H6A 108.1 . .
Ag2 N6 H6A 108.1 2_676 .
F5A P1A F2A 91.17(14) . .
F5A P1A F4A 91.18(15) . .
F2A P1A F4A 91.11(14) . .
F5A P1A F6A 89.98(14) . .
F2A P1A F6A 89.91(14) . .
F4A P1A F6A 178.44(15) . .
F5A P1A F1A 89.87(14) . .
F2A P1A F1A 178.94(15) . .
F4A P1A F1A 89.07(13) . .
F6A P1A F1A 89.90(13) . .
F5A P1A F3A 179.28(14) . .
F2A P1A F3A 89.36(13) . .
F4A P1A F3A 89.31(14) . .
F6A P1A F3A 89.53(13) . .
F1A P1A F3A 89.60(13) . .
F4B P1B F3B 91.4(2) . .
F4B P1B F2B 90.9(2) . .
F3B P1B F2B 90.17(18) . .
F4B P1B F6B 178.60(19) . .
F3B P1B F6B 89.56(19) . .
F2B P1B F6B 90.2(2) . .
F4B P1B F1B 88.80(18) . .
F3B P1B F1B 90.50(17) . .
F2B P1B F1B 179.27(19) . .
F6B P1B F1B 90.15(19) . .
F4B P1B F5B 91.6(2) . .
F3B P1B F5B 176.8(2) . .
F2B P1B F5B 90.95(18) . .
F6B P1B F5B 87.44(19) . .
F1B P1B F5B 88.40(16) . .
C23A N7A Ag2 170.2(3) . .
N7C C23C C24C 178.2(6) . .
C23C C24C H24D 109.5 . .
C23C C24C H24E 109.5 . .
H24D C24C H24E 109.5 . .
C23C C24C H24F 109.5 . .
H24D C24C H24F 109.5 . .
H24E C24C H24F 109.5 . .
N7D C23D C24D 176(4) . .
C23D C24D H24G 109.5 . .
C23D C24D H24H 109.5 . .
H24G C24D H24H 109.5 . .
C23D C24D H24I 109.5 . .
H24G C24D H24I 109.5 . .
H24H C24D H24I 109.5 . .
N7W C23W C24W 176(2) . .
C23W C24W H24J 109.5 . .
C23W C24W H24K 109.5 . .
H24J C24W H24K 109.5 . .
C23W C24W H24L 109.5 . .
H24J C24W H24L 109.5 . .
H24K C24W H24L 109.5 . .
C23B N7B Ag2 154(3) . .
N7B C23B C24B 175(2) . .
C23B C24B H24M 109.5 . .
C23B C24B H24N 109.5 . .
H24M C24B H24N 109.5 . .
C23B C24B H24O 109.5 . .
H24M C24B H24O 109.5 . .
H24N C24B H24O 109.5 . .
C23Y N7Y Ag2 170.4(11) . .
N7Y C23Y C24Y 178.0(14) . .
C23Y C24Y H24P 109.5 . .
C23Y C24Y H24Q 109.5 . .
H24P C24Y H24Q 109.5 . .
C23Y C24Y H24R 109.5 . .
H24P C24Y H24R 109.5 . .
H24Q C24Y H24R 109.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 C12 2.074(3) 2_676
Ag1 C1 2.080(3) .
Ag1 Ag2 3.2977(4) .
Ag2 N6 2.254(3) 2_676
Ag2 N3 2.259(3) .
Ag2 N7A 2.581(3) .
Ag2 N7Y 2.623(10) .
Ag2 N7B 2.74(2) .
C1 N1 1.351(4) .
C1 N2 1.351(4) .
C2 N2 1.389(4) .
C2 C4 1.389(5) .
C2 C3 1.398(4) .
C3 N1 1.380(4) .
C3 C7 1.395(4) .
C4 C5 1.393(5) .
C4 H4 0.9500 .
C5 C6 1.394(5) .
C5 H5 0.9500 .
C6 C7 1.389(5) .
C6 H6 0.9500 .
C7 H7 0.9500 .
C8 N2 1.465(4) .
C8 C9 1.517(4) .
C8 H8A 0.9900 .
C8 H8B 0.9900 .
C9 N3 1.487(4) .
C9 H9A 0.9900 .
C9 H9B 0.9900 .
C10 N3 1.490(4) .
C10 C11 1.506(4) .
C10 H10A 0.9900 .
C10 H10B 0.9900 .
C11 N4 1.463(4) .
C11 H11A 0.9900 .
C11 H11B 0.9900 .
C12 N5 1.352(4) .
C12 N4 1.362(4) .
C12 Ag1 2.074(3) 2_676
C13 C18 1.393(5) .
C13 N5 1.395(4) .
C13 C14 1.396(4) .
C14 C15 1.390(4) .
C14 N4 1.392(4) .
C15 C16 1.376(5) .
C15 H15 0.9500 .
C16 C17 1.399(5) .
C16 H16 0.9500 .
C17 C18 1.378(5) .
C17 H17 0.9500 .
C18 H18 0.9500 .
C19 N5 1.459(4) .
C19 C20 1.517(4) .
C19 H19A 0.9900 .
C19 H19B 0.9900 .
C20 N6 1.486(4) .
C20 H20A 0.9900 .
C20 H20B 0.9900 .
C21 N6 1.497(4) .
C21 C22 1.512(4) .
C21 H21A 0.9900 .
C21 H21B 0.9900 .
C22 N1 1.466(4) .
C22 H22A 0.9900 .
C22 H22B 0.9900 .
C23A N7A 1.125(5) .
C23A C24A 1.446(5) .
C24A H24A 0.9800 .
C24A H24B 0.9800 .
C24A H24C 0.9800 .
F1A P1A 1.600(2) .
F2A P1A 1.591(2) .
F3A P1A 1.610(2) .
F4A P1A 1.594(2) .
F5A P1A 1.591(3) .
F6A P1A 1.600(2) .
F1B P1B 1.596(3) .
F2B P1B 1.581(3) .
F3B P1B 1.572(3) .
F4B P1B 1.566(3) .
F5B P1B 1.600(3) .
F6B P1B 1.582(3) .
N3 H3 1.0000 .
N6 Ag2 2.254(3) 2_676
N6 H6A 1.0000 .
N7C C23C 1.125(6) .
C23C C24C 1.464(8) .
C24C H24D 0.9800 .
C24C H24E 0.9800 .
C24C H24F 0.9800 .
N7D C23D 1.153(16) .
C23D C24D 1.472(17) .
C24D H24G 0.9800 .
C24D H24H 0.9800 .
C24D H24I 0.9800 .
N7W C23W 1.154(11) .
C23W C24W 1.480(13) .
C24W H24J 0.9800 .
C24W H24K 0.9800 .
C24W H24L 0.9800 .
N7B C23B 1.122(16) .
C23B C24B 1.473(15) .
C24B H24M 0.9800 .
C24B H24N 0.9800 .
C24B H24O 0.9800 .
N7Y C23Y 1.117(10) .
C23Y C24Y 1.455(9) .
C24Y H24P 0.9800 .
C24Y H24Q 0.9800 .
C24Y H24R 0.9800 .
