#------------------------------------------------------------------------------
#$Date: 2019-11-08 02:28:39 +0200 (Fri, 08 Nov 2019) $
#$Revision: 224768 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/05/88/7058870.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7058870
loop_
_publ_author_name
'Du, Rongkai'
'Xu, Juan'
'Zhang, Lei'
'Ning, Lifeng'
'Li, Shan'
_publ_section_title
;
 Ethinyl estradiol cocrystals assembled by chain structures: improvement
 in stability and solubility
;
_journal_issue                   43
_journal_name_full               'New Journal of Chemistry'
_journal_page_first              16889
_journal_paper_doi               10.1039/C9NJ04147H
_journal_volume                  43
_journal_year                    2019
_chemical_absolute_configuration syn
_chemical_formula_moiety         'C20 H24 O2, C3 H4 N2'
_chemical_formula_sum            'C23 H28 N2 O2'
_chemical_formula_weight         364.47
_space_group_crystal_system      orthorhombic
_space_group_IT_number           19
_space_group_name_Hall           'P 2ac 2ab'
_space_group_name_H-M_alt        'P 21 21 21'
_symmetry_space_group_name_Hall  'P 2ac 2ab'
_symmetry_space_group_name_H-M   'P 21 21 21'
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     dual
_audit_creation_date             2019-07-03
_audit_creation_method
;
Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_audit_update_record
;
2019-07-05 deposited with the CCDC.    2019-10-03 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   8.5213(7)
_cell_length_b                   9.9194(6)
_cell_length_c                   24.5146(17)
_cell_measurement_reflns_used    3042
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      27.0090
_cell_measurement_theta_min      3.8880
_cell_volume                     2072.1(3)
_computing_cell_refinement       'CrysAlisPro 1.171.38.41 (Rigaku OD, 2015)'
_computing_data_collection       'CrysAlisPro 1.171.38.41 (Rigaku OD, 2015)'
_computing_data_reduction        'CrysAlisPro 1.171.38.41 (Rigaku OD, 2015)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'ShelXT (Sheldrick, 2015)'
_diffrn_ambient_temperature      293(2)
_diffrn_detector                 'CCD plate'
_diffrn_detector_area_resol_mean 16.1213
_diffrn_detector_type            Eos
_diffrn_measured_fraction_theta_full 0.995
_diffrn_measured_fraction_theta_max 0.884
_diffrn_measurement_details
;
List of Runs (angles in degrees, time in seconds):

  # Type    Start    End  Width  tₑₓₚ   ω     θ     κ     φ   Frames
#--------------------------------------------------------------------------
  1  ω      6.00  53.00   1.00    3.13    --  -16.43  19.00 -30.00   47
  2  ω      1.00  82.00   1.00    3.13    --   15.65  19.00  60.00   81
  3  ω    -25.00   0.00   1.00    3.13    --  -16.43 -99.00-120.00   25
  4  ω      5.00  31.00   1.00    3.13    --   15.65 -57.00-180.00   26
  5  ω    -33.00  -7.00   1.00    3.13    --  -16.43  57.00 -30.00   26
  6  ω    -46.00  -3.00   1.00    3.13    --  -16.43  19.00 -30.00   43
  7  ω     43.00  72.00   1.00    3.13    --   15.65 178.00 -90.00   29
;
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'Xcalibur, Eos, Gemini'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_type
'CrysAlisPro convention (1999,Acta A55,543-557)'
_diffrn_orient_matrix_UB_11      -0.0559144000
_diffrn_orient_matrix_UB_12      0.0442378000
_diffrn_orient_matrix_UB_13      0.0117424000
_diffrn_orient_matrix_UB_21      -0.0192278000
_diffrn_orient_matrix_UB_22      0.0246989000
_diffrn_orient_matrix_UB_23      -0.0263426000
_diffrn_orient_matrix_UB_31      -0.0585840000
_diffrn_orient_matrix_UB_32      -0.0503795000
_diffrn_orient_matrix_UB_33      -0.0025924000
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0264
_diffrn_reflns_av_unetI/netI     0.0417
_diffrn_reflns_Laue_measured_fraction_full 0.995
_diffrn_reflns_Laue_measured_fraction_max 0.884
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       33
_diffrn_reflns_limit_l_min       -31
_diffrn_reflns_number            12511
_diffrn_reflns_point_group_measured_fraction_full 0.994
_diffrn_reflns_point_group_measured_fraction_max 0.843
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         29.535
_diffrn_reflns_theta_min         3.563
_diffrn_source                   'fine-focus sealed X-ray tube'
_diffrn_source_type              'Enhance (Mo) X-ray Source'
_exptl_absorpt_coefficient_mu    0.075
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.82778
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlisPro 1.171.38.41 (Rigaku Oxford Diffraction, 2015)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            'clear light colourless'
_exptl_crystal_colour_lustre     clear
_exptl_crystal_colour_modifier   light
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.168
_exptl_crystal_description       block
_exptl_crystal_F_000             784
_exptl_crystal_size_max          0.34
_exptl_crystal_size_mid          0.32
_exptl_crystal_size_min          0.27
_refine_diff_density_max         0.108
_refine_diff_density_min         -0.139
_refine_diff_density_rms         0.031
_refine_ls_abs_structure_details
;
 Flack x determined using 1056 quotients [(I+)-(I-)]/[(I+)+(I-)]
 (Parsons and Flack (2004), Acta Cryst. A60, s61).
;
_refine_ls_abs_structure_Flack   0.2(8)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.018
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     257
_refine_ls_number_reflns         4885
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.018
_refine_ls_R_factor_all          0.0870
_refine_ls_R_factor_gt           0.0514
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
;
 w=1/[σ²(Fo²)+(0.0439P)²+0.2026P]
 where P=(Fo²+2Fc²)/3
;
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1001
_refine_ls_wR_factor_ref         0.1169
_reflns_Friedel_coverage         0.682
_reflns_Friedel_fraction_full    0.994
_reflns_Friedel_fraction_max     0.789
_reflns_number_gt                3259
_reflns_number_total             4885
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c9nj04147h2.cif
_cod_data_source_block           EE-IZ
_cod_depositor_comments
'Adding full bibliography for 7058869--7058873.cif.'
_cod_database_code               7058870
_shelxl_version_number           2013-2
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_max   0.980
_shelx_estimated_absorpt_t_min   0.975
_reflns_odcompleteness_completeness 99.43
_reflns_odcompleteness_iscentric 1
_reflns_odcompleteness_theta     26.32
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2.a Ternary CH refined with riding coordinates:
 C8(H8), C9(H9), C14(H14)
2.b Secondary CH2 refined with riding coordinates:
 C6(H6A,H6B), C7(H7A,H7B), C11(H11A,H11B), C12(H12A,H12B), C15(H15A,H15B),
 C16(H16A,H16B)
2.c Aromatic/amide H refined with riding coordinates:
 C1(H1), C2(H2), C4(H4), C22(H22), C23(H23), C24(H24)
2.d Idealised Me refined as rotating group:
 C18(H18A,H18B,H18C)
2.e :
 C21(H21)
;
_olex2_submission_special_instructions 'No special instructions were received'
_oxdiff_exptl_absorpt_empirical_details
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
;
_oxdiff_exptl_absorpt_empirical_full_max 1.208
_oxdiff_exptl_absorpt_empirical_full_min 0.785
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'-x, y+1/2, -z+1/2'
'x+1/2, -y+1/2, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
C1 C -0.4713(3) -0.3461(3) -0.40274(10) 0.0509(7) Uani 1 1 d .
H1 H -0.3965 -0.3221 -0.3769 0.061 Uiso 1 1 calc R
O1 O -0.4851(3) -0.4194(2) -0.54752(8) 0.0688(6) Uani 1 1 d .
H1A H -0.565(5) -0.453(4) -0.5674(14) 0.091(13) Uiso 1 1 d .
C2 C -0.4247(3) -0.3632(3) -0.45629(11) 0.0540(7) Uani 1 1 d .
H2 H -0.3203 -0.3511 -0.4662 0.065 Uiso 1 1 calc R
O2 O -0.8012(3) -0.4807(2) -0.11509(8) 0.0670(6) Uani 1 1 d .
H2A H -0.705(5) -0.458(4) -0.1044(16) 0.103(15) Uiso 1 1 d .
C3 C -0.5355(4) -0.3986(3) -0.49491(10) 0.0519(7) Uani 1 1 d .
C4 C -0.6897(4) -0.4112(3) -0.47994(10) 0.0507(6) Uani 1 1 d .
H4 H -0.7643 -0.4320 -0.5063 0.061 Uiso 1 1 calc R
C5 C -0.7372(3) -0.3936(3) -0.42615(10) 0.0458(6) Uani 1 1 d .
C6 C -0.9093(3) -0.4086(3) -0.41341(11) 0.0573(7) Uani 1 1 d .
H6A H -0.9375 -0.5032 -0.4152 0.069 Uiso 1 1 calc R
H6B H -0.9699 -0.3611 -0.4408 0.069 Uiso 1 1 calc R
C7 C -0.9519(4) -0.3541(3) -0.35738(10) 0.0548(7) Uani 1 1 d .
H7A H -1.0572 -0.3825 -0.3477 0.066 Uiso 1 1 calc R
H7B H -0.9495 -0.2564 -0.3579 0.066 Uiso 1 1 calc R
C8 C -0.8353(3) -0.4069(3) -0.31538(9) 0.0448(6) Uani 1 1 d .
H8 H -0.8274 -0.5047 -0.3201 0.054 Uiso 1 1 calc R
C9 C -0.6733(3) -0.3464(2) -0.32656(10) 0.0443(6) Uani 1 1 d .
H9 H -0.6822 -0.2493 -0.3200 0.053 Uiso 1 1 calc R
C10 C -0.6261(3) -0.3634(2) -0.38605(10) 0.0433(6) Uani 1 1 d .
C11 C -0.5513(3) -0.4003(3) -0.28565(10) 0.0544(7) Uani 1 1 d .
H11A H -0.5355 -0.4958 -0.2920 0.065 Uiso 1 1 calc R
H11B H -0.4519 -0.3550 -0.2918 0.065 Uiso 1 1 calc R
C12 C -0.6017(3) -0.3787(3) -0.22603(11) 0.0564(7) Uani 1 1 d .
H12A H -0.5259 -0.4210 -0.2020 0.068 Uiso 1 1 calc R
H12B H -0.6031 -0.2830 -0.2180 0.068 Uiso 1 1 calc R
C13 C -0.7643(3) -0.4382(2) -0.21520(10) 0.0470(7) Uani 1 1 d .
C14 C -0.8813(3) -0.3799(3) -0.25639(10) 0.0468(6) Uani 1 1 d .
H14 H -0.8787 -0.2819 -0.2516 0.056 Uiso 1 1 calc R
C15 C -1.0414(3) -0.4265(3) -0.23577(11) 0.0592(8) Uani 1 1 d .
H15A H -1.0657 -0.5163 -0.2490 0.071 Uiso 1 1 calc R
H15B H -1.1235 -0.3651 -0.2472 0.071 Uiso 1 1 calc R
C16 C -1.0228(4) -0.4257(3) -0.17312(12) 0.0657(8) Uani 1 1 d .
H16A H -1.0550 -0.5117 -0.1580 0.079 Uiso 1 1 calc R
H16B H -1.0871 -0.3553 -0.1572 0.079 Uiso 1 1 calc R
C17 C -0.8469(3) -0.3995(3) -0.16083(10) 0.0556(7) Uani 1 1 d .
C18 C -0.7551(4) -0.5927(3) -0.21808(13) 0.0658(8) Uani 1 1 d .
H18A H -0.7203 -0.6194 -0.2537 0.099 Uiso 1 1 calc GR
H18B H -0.8570 -0.6303 -0.2111 0.099 Uiso 1 1 calc GR
H18C H -0.6823 -0.6248 -0.1912 0.099 Uiso 1 1 calc GR
C20 C -0.8192(4) -0.2575(3) -0.14702(12) 0.0661(8) Uani 1 1 d .
C21 C -0.7933(5) -0.1460(4) -0.13451(16) 0.0946(12) Uani 1 1 d .
H21 H -0.7728 -0.0572 -0.1246 0.113 Uiso 1 1 calc R
N1 N -0.5263(4) -0.3997(4) -0.07353(12) 0.0850(8) Uani 1 1 d .
N2 N -0.2816(4) -0.4148(4) -0.05037(15) 0.0907(10) Uani 1 1 d .
H2B H -0.186(6) -0.456(5) -0.038(2) 0.15(2) Uiso 1 1 d .
C22 C -0.4086(5) -0.4791(4) -0.06691(15) 0.0825(10) Uani 1 1 d .
H22 H -0.4125 -0.5716 -0.0731 0.099 Uiso 1 1 calc R
C23 C -0.3194(7) -0.2841(5) -0.0451(2) 0.1230(17) Uani 1 1 d .
H23 H -0.2548 -0.2142 -0.0335 0.148 Uiso 1 1 calc R
C24 C -0.4701(6) -0.2760(5) -0.0601(2) 0.1131(15) Uani 1 1 d .
H24 H -0.5283 -0.1966 -0.0611 0.136 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
C2 C1 H1 118.8
C2 C1 C10 122.5(3)
C10 C1 H1 118.8
C3 O1 H1A 109(2)
C1 C2 H2 120.5
C1 C2 C3 119.0(3)
C3 C2 H2 120.5
C17 O2 H2A 110(2)
O1 C3 C2 117.9(3)
C4 C3 O1 122.5(3)
C4 C3 C2 119.6(2)
C3 C4 H4 119.3
C3 C4 C5 121.4(2)
C5 C4 H4 119.3
C4 C5 C6 117.9(2)
C4 C5 C10 119.8(2)
C10 C5 C6 122.3(2)
C5 C6 H6A 109.1
C5 C6 H6B 109.1
C5 C6 C7 112.6(2)
H6A C6 H6B 107.8
C7 C6 H6A 109.1
C7 C6 H6B 109.1
C6 C7 H7A 109.8
C6 C7 H7B 109.8
C6 C7 C8 109.4(2)
H7A C7 H7B 108.2
C8 C7 H7A 109.8
C8 C7 H7B 109.8
C7 C8 H8 107.7
C7 C8 C9 109.4(2)
C9 C8 H8 107.7
C14 C8 C7 114.4(2)
C14 C8 H8 107.7
C14 C8 C9 109.5(2)
C8 C9 H9 106.6
C8 C9 C11 110.9(2)
C10 C9 C8 111.5(2)
C10 C9 H9 106.6
C10 C9 C11 114.0(2)
C11 C9 H9 106.6
C1 C10 C5 117.5(2)
C1 C10 C9 121.2(2)
C5 C10 C9 121.2(2)
C9 C11 H11A 109.1
C9 C11 H11B 109.1
H11A C11 H11B 107.8
C12 C11 C9 112.5(2)
C12 C11 H11A 109.1
C12 C11 H11B 109.1
C11 C12 H12A 109.4
C11 C12 H12B 109.4
H12A C12 H12B 108.0
C13 C12 C11 111.4(2)
C13 C12 H12A 109.4
C13 C12 H12B 109.4
C12 C13 C14 109.2(2)
C12 C13 C17 117.6(2)
C12 C13 C18 109.3(2)
C14 C13 C17 100.2(2)
C14 C13 C18 112.3(2)
C18 C13 C17 108.0(2)
C8 C14 C13 113.1(2)
C8 C14 H14 106.4
C8 C14 C15 119.4(2)
C13 C14 H14 106.4
C15 C14 C13 104.4(2)
C15 C14 H14 106.4
C14 C15 H15A 111.0
C14 C15 H15B 111.0
C14 C15 C16 103.7(2)
H15A C15 H15B 109.0
C16 C15 H15A 111.0
C16 C15 H15B 111.0
C15 C16 H16A 110.3
C15 C16 H16B 110.3
C15 C16 C17 107.1(2)
H16A C16 H16B 108.6
C17 C16 H16A 110.3
C17 C16 H16B 110.3
O2 C17 C13 114.1(2)
O2 C17 C16 108.7(2)
O2 C17 C20 108.3(2)
C16 C17 C13 103.3(2)
C20 C17 C13 111.2(2)
C20 C17 C16 111.2(3)
C13 C18 H18A 109.5
C13 C18 H18B 109.5
C13 C18 H18C 109.5
H18A C18 H18B 109.5
H18A C18 H18C 109.5
H18B C18 H18C 109.5
C21 C20 C17 177.5(4)
C20 C21 H21 180.0
C22 N1 C24 104.4(4)
C22 N2 H2B 126(3)
C22 N2 C23 107.4(4)
C23 N2 H2B 126(3)
N1 C22 N2 112.5(4)
N1 C22 H22 123.8
N2 C22 H22 123.8
N2 C23 H23 127.4
C24 C23 N2 105.2(4)
C24 C23 H23 127.4
N1 C24 H24 124.8
C23 C24 N1 110.5(4)
C23 C24 H24 124.8
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
C1 H1 0.9300
C1 C2 1.382(4)
C1 C10 1.391(4)
O1 H1A 0.90(4)
O1 C3 1.375(3)
C2 H2 0.9300
C2 C3 1.382(4)
O2 H2A 0.89(4)
O2 C17 1.434(3)
C3 C4 1.370(4)
C4 H4 0.9300
C4 C5 1.390(3)
C5 C6 1.507(4)
C5 C10 1.397(3)
C6 H6A 0.9700
C6 H6B 0.9700
C6 C7 1.520(4)
C7 H7A 0.9700
C7 H7B 0.9700
C7 C8 1.523(3)
C8 H8 0.9800
C8 C9 1.530(4)
C8 C14 1.522(3)
C9 H9 0.9800
C9 C10 1.522(4)
C9 C11 1.540(4)
C11 H11A 0.9700
C11 H11B 0.9700
C11 C12 1.538(4)
C12 H12A 0.9700
C12 H12B 0.9700
C12 C13 1.530(4)
C13 C14 1.532(4)
C13 C17 1.555(4)
C13 C18 1.535(3)
C14 H14 0.9800
C14 C15 1.526(4)
C15 H15A 0.9700
C15 H15B 0.9700
C15 C16 1.544(4)
C16 H16A 0.9700
C16 H16B 0.9700
C16 C17 1.550(4)
C17 C20 1.468(4)
C18 H18A 0.9600
C18 H18B 0.9600
C18 H18C 0.9600
C20 C21 1.169(4)
C21 H21 0.9300
N1 C22 1.286(5)
N1 C24 1.358(5)
N2 H2B 0.96(5)
N2 C22 1.320(5)
N2 C23 1.342(5)
C22 H22 0.9300
C23 H23 0.9300
C23 C24 1.338(7)
C24 H24 0.9300
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
O1 H1A O2 0.90(4) 1.76(4) 2.653(3) 171(3) 2_344
O2 H2A N1 0.89(4) 1.80(4) 2.678(4) 171(4) .
N2 H2B O1 0.96(5) 1.93(5) 2.806(4) 152(4) 2_445
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
C1 C2 C3 O1 -177.9(2)
C1 C2 C3 C4 2.4(4)
O1 C3 C4 C5 178.1(2)
C2 C1 C10 C5 -2.7(4)
C2 C1 C10 C9 178.8(2)
C2 C3 C4 C5 -2.2(4)
C3 C4 C5 C6 179.7(3)
C3 C4 C5 C10 -0.5(4)
C4 C5 C6 C7 -165.9(2)
C4 C5 C10 C1 2.9(4)
C4 C5 C10 C9 -178.7(2)
C5 C6 C7 C8 -47.4(3)
C6 C5 C10 C1 -177.3(3)
C6 C5 C10 C9 1.2(4)
C6 C7 C8 C9 66.9(3)
C6 C7 C8 C14 -169.8(2)
C7 C8 C9 C10 -50.4(3)
C7 C8 C9 C11 -178.6(2)
C7 C8 C14 C13 178.1(2)
C7 C8 C14 C15 54.7(3)
C8 C9 C10 C1 -164.4(2)
C8 C9 C10 C5 17.2(3)
C8 C9 C11 C12 -54.3(3)
C8 C14 C15 C16 161.7(2)
C9 C8 C14 C13 -58.6(3)
C9 C8 C14 C15 178.0(2)
C9 C11 C12 C13 54.1(3)
C10 C1 C2 C3 0.1(4)
C10 C5 C6 C7 14.3(4)
C10 C9 C11 C12 178.9(2)
C11 C9 C10 C1 -37.8(3)
C11 C9 C10 C5 143.8(2)
C11 C12 C13 C14 -54.4(3)
C11 C12 C13 C17 -167.6(2)
C11 C12 C13 C18 68.9(3)
C12 C13 C14 C8 58.0(3)
C12 C13 C14 C15 -170.6(2)
C12 C13 C17 O2 -84.1(3)
C12 C13 C17 C16 158.1(2)
C12 C13 C17 C20 38.8(3)
C13 C14 C15 C16 34.1(3)
C14 C8 C9 C10 -176.57(19)
C14 C8 C9 C11 55.2(3)
C14 C13 C17 O2 157.7(2)
C14 C13 C17 C16 40.0(3)
C14 C13 C17 C20 -79.4(3)
C14 C15 C16 C17 -8.2(3)
C15 C16 C17 O2 -141.5(2)
C15 C16 C17 C13 -20.0(3)
C15 C16 C17 C20 99.4(3)
C17 C13 C14 C8 -177.8(2)
C17 C13 C14 C15 -46.4(3)
C18 C13 C14 C8 -63.4(3)
C18 C13 C14 C15 68.0(3)
C18 C13 C17 O2 40.1(3)
C18 C13 C17 C16 -77.7(3)
C18 C13 C17 C20 163.0(3)
N2 C23 C24 N1 1.1(6)
C22 N1 C24 C23 -0.6(6)
C22 N2 C23 C24 -1.1(6)
C23 N2 C22 N1 0.9(5)
C24 N1 C22 N2 -0.2(5)
