#------------------------------------------------------------------------------
#$Date: 2020-12-06 16:33:14 +0200 (Sun, 06 Dec 2020) $
#$Revision: 259617 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/06/00/7060075.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7060075
loop_
_publ_author_name
'Mironova, Olga A.'
'Ryadun, Aleksey A.'
'Sukhikh, Taisiya S.'
'Konchenko, Sergey N.'
'Pushkarevsky, Nikolay A.'
_publ_section_title
;
 Synthesis and luminescence studies of lanthanide complexes (Gd, Tb, Dy)
 with phenyl- and 2-pyridylthiolates supported by a bulky β-diketiminate
 ligand. Impact of the ligand environment on terbium(iii) emission
;
_journal_issue                   45
_journal_name_full               'New Journal of Chemistry'
_journal_page_first              19769
_journal_page_last               19779
_journal_paper_doi               10.1039/D0NJ04201C
_journal_volume                  44
_journal_year                    2020
_chemical_formula_moiety         'C33 H49 Dy I2 N2 O, C2 H4 O0.5'
_chemical_formula_sum            'C35 H53 Dy I2 N2 O1.5'
_chemical_formula_weight         942.09
_chemical_properties_physical    Air-sensitive,Moisture-sensitive
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_Hall           '-C 2yc'
_space_group_name_H-M_alt        'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_audit_creation_date             2020-07-21
_audit_creation_method
;
Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_audit_update_record
;
2020-07-24 deposited with the CCDC.	2020-10-20 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 116.2470(10)
_cell_angle_gamma                90
_cell_formula_units_Z            8
_cell_length_a                   31.9845(6)
_cell_length_b                   12.1125(3)
_cell_length_c                   21.4148(5)
_cell_measurement_reflns_used    9426
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      26.30
_cell_measurement_theta_min      2.26
_cell_volume                     7441.0(3)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'ShelXT (Sheldrick, 2015)'
_diffrn_ambient_temperature      150(2)
_diffrn_detector                 CCD
_diffrn_detector_area_resol_mean 8.33
_diffrn_detector_type            'Bruker APEXII CCD area detector'
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.989
_diffrn_measurement_device       'κ-geometry diffractometer'
_diffrn_measurement_device_type  'Bruker APEX diffractometer'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0317
_diffrn_reflns_av_unetI/netI     0.0389
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.989
_diffrn_reflns_limit_h_max       33
_diffrn_reflns_limit_h_min       -40
_diffrn_reflns_limit_k_max       11
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       26
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_number            24646
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.989
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         26.477
_diffrn_reflns_theta_min         1.947
_diffrn_source                   'sealed tube'
_exptl_absorpt_coefficient_mu    3.697
_exptl_absorpt_correction_T_max  0.7454
_exptl_absorpt_correction_T_min  0.5946
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
'SADABS-2012/1 (Bruker,2012) was used for absorption correction. wR2(int) was 0.0786 before and 0.0437 after correction. The Ratio of minimum to maximum transmission is 0.7977. The λ/2 correction factor is 0.0015.'
_exptl_crystal_colour            yellow
_exptl_crystal_colour_primary    yellow
_exptl_crystal_density_diffrn    1.682
_exptl_crystal_description       block
_exptl_crystal_F_000             3688
_exptl_crystal_size_max          0.35
_exptl_crystal_size_mid          0.23
_exptl_crystal_size_min          0.17
_refine_diff_density_max         0.869
_refine_diff_density_min         -0.904
_refine_diff_density_rms         0.109
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.032
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     385
_refine_ls_number_reflns         7616
_refine_ls_number_restraints     21
_refine_ls_restrained_S_all      1.033
_refine_ls_R_factor_all          0.0367
_refine_ls_R_factor_gt           0.0274
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0188P)²+7.6537P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0502
_refine_ls_wR_factor_ref         0.0530
_reflns_Friedel_coverage         0.000
_reflns_number_gt                6389
_reflns_number_total             7616
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d0nj04201c2.cif
_cod_data_source_block           moa40_2
_cod_depositor_comments
'Adding full bibliography for 7060074--7060081.cif.'
_cod_original_formula_sum        'C35 H53 Dy I2 N2 O1.50'
_cod_database_code               7060075
_shelx_shelxl_version_number     2017/1
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_max   0.572
_shelx_estimated_absorpt_t_min   0.358
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2. Uiso/Uaniso restraints and constraints
Uanis(C29) \\sim Ueq, Uanis(C28) \\sim Ueq: with sigma of 0.01 and sigma for
terminal atoms of 0.02
3. Rigid body (RIGU) restrains
 C27, C29, C28
 with sigma for 1-2 distances of 0.004 and sigma for 1-3 distances of 0.004
4.a Ternary CH refined with riding coordinates:
 C12(H12), C15(H15), C24(H24), C27(H27)
4.b Secondary CH2 refined with riding coordinates:
 C30(H30A,H30B), C31(H31A,H31B), C32(H32A,H32B), C33(H33A,H33B), C1S(H1SA,
 H1SB), C2S(H2SA,H2SB)
4.c Aromatic/amide H refined with riding coordinates:
 C2(H2), C8(H8), C9(H9), C10(H10), C20(H20), C21(H21), C22(H22)
4.d Idealised Me refined as rotating group:
 C4(H4A,H4B,H4C), C5(H5A,H5B,H5C), C13(H13A,H13B,H13C), C14(H14A,H14B,H14C),
 C16(H16A,H16B,H16C), C17(H17A,H17B,H17C), C25(H25A,H25B,H25C), C26(H26A,H26B,
 H26C), C28(H28A,H28B,H28C), C29(H29A,H29B,H29C)
;
_olex2_submission_special_instructions 'No special instructions were received'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Dy1 Dy 0.60875(2) 0.67597(2) 0.49211(2) 0.01820(5) Uani 1 1 d . . . . .
I1 I 0.63796(2) 0.61292(2) 0.38334(2) 0.02998(7) Uani 1 1 d . . . . .
I2 I 0.54980(2) 0.63264(2) 0.56469(2) 0.03029(7) Uani 1 1 d . . . . .
O1 O 0.53488(7) 0.70937(18) 0.39799(11) 0.0236(5) Uani 1 1 d . . . . .
N1 N 0.64648(9) 0.8389(2) 0.52008(13) 0.0175(6) Uani 1 1 d . . . . .
N2 N 0.67428(9) 0.6184(2) 0.58686(13) 0.0198(6) Uani 1 1 d . . . . .
C1 C 0.69249(11) 0.8470(3) 0.54217(16) 0.0199(7) Uani 1 1 d . . . . .
C2 C 0.72283(11) 0.7576(3) 0.56978(16) 0.0229(8) Uani 1 1 d . . . . .
H2 H 0.753009 0.767870 0.572384 0.027 Uiso 1 1 calc R . . . .
C3 C 0.71578(12) 0.6556(3) 0.59415(17) 0.0233(8) Uani 1 1 d . . . . .
C4 C 0.71422(12) 0.9562(3) 0.53903(19) 0.0312(9) Uani 1 1 d . . . . .
H4A H 0.720671 0.957341 0.498351 0.047 Uiso 1 1 calc GR . . . .
H4B H 0.743412 0.966035 0.581433 0.047 Uiso 1 1 calc GR . . . .
H4C H 0.692690 1.016275 0.535263 0.047 Uiso 1 1 calc GR . . . .
C5 C 0.75866(12) 0.5849(3) 0.6317(2) 0.0372(10) Uani 1 1 d . . . . .
H5A H 0.761868 0.566301 0.678149 0.056 Uiso 1 1 calc GR . . . .
H5B H 0.786299 0.625635 0.636086 0.056 Uiso 1 1 calc GR . . . .
H5C H 0.755598 0.516923 0.605203 0.056 Uiso 1 1 calc GR . . . .
C6 C 0.61549(10) 0.9333(3) 0.49987(16) 0.0164(7) Uani 1 1 d . . . . .
C7 C 0.59863(11) 0.9803(3) 0.43372(16) 0.0206(7) Uani 1 1 d . . . . .
C8 C 0.56474(11) 1.0620(3) 0.41495(18) 0.0248(8) Uani 1 1 d . . . . .
H8 H 0.552711 1.093559 0.369730 0.030 Uiso 1 1 calc R . . . .
C9 C 0.54836(12) 1.0978(3) 0.46108(19) 0.0282(8) Uani 1 1 d . . . . .
H9 H 0.525184 1.153728 0.447653 0.034 Uiso 1 1 calc R . . . .
C10 C 0.56573(12) 1.0522(3) 0.52698(18) 0.0263(8) Uani 1 1 d . . . . .
H10 H 0.554146 1.077603 0.558328 0.032 Uiso 1 1 calc R . . . .
C11 C 0.59971(11) 0.9702(3) 0.54868(16) 0.0203(7) Uani 1 1 d . . . . .
C12 C 0.61582(12) 0.9475(3) 0.37987(17) 0.0258(8) Uani 1 1 d . . . . .
H12 H 0.640130 0.888971 0.400804 0.031 Uiso 1 1 calc R . . . .
C13 C 0.57668(13) 0.9013(3) 0.31334(18) 0.0361(9) Uani 1 1 d . . . . .
H13A H 0.562395 0.837867 0.324870 0.054 Uiso 1 1 calc GR . . . .
H13B H 0.589474 0.877903 0.281471 0.054 Uiso 1 1 calc GR . . . .
H13C H 0.553069 0.958550 0.290976 0.054 Uiso 1 1 calc GR . . . .
C14 C 0.63827(13) 1.0472(3) 0.3624(2) 0.0360(10) Uani 1 1 d . . . . .
H14A H 0.614745 1.104841 0.340593 0.054 Uiso 1 1 calc GR . . . .
H14B H 0.650925 1.024524 0.330258 0.054 Uiso 1 1 calc GR . . . .
H14C H 0.663503 1.076110 0.405270 0.054 Uiso 1 1 calc GR . . . .
C15 C 0.61948(11) 0.9246(3) 0.62190(16) 0.0229(8) Uani 1 1 d . . . . .
H15 H 0.624686 0.843765 0.618943 0.028 Uiso 1 1 calc R . . . .
C16 C 0.66648(13) 0.9758(3) 0.66834(18) 0.0377(10) Uani 1 1 d . . . . .
H16A H 0.688175 0.962685 0.648106 0.057 Uiso 1 1 calc GR . . . .
H16B H 0.678854 0.942310 0.714723 0.057 Uiso 1 1 calc GR . . . .
H16C H 0.662706 1.055463 0.672110 0.057 Uiso 1 1 calc GR . . . .
C17 C 0.58666(13) 0.9372(3) 0.65637(19) 0.0356(9) Uani 1 1 d . . . . .
H17A H 0.584666 1.015288 0.666812 0.053 Uiso 1 1 calc GR . . . .
H17B H 0.598781 0.894408 0.699640 0.053 Uiso 1 1 calc GR . . . .
H17C H 0.555579 0.910091 0.624663 0.053 Uiso 1 1 calc GR . . . .
C18 C 0.67339(11) 0.5246(3) 0.62871(17) 0.0248(8) Uani 1 1 d . . . . .
C19 C 0.67751(11) 0.5448(3) 0.69595(17) 0.0243(8) Uani 1 1 d . . . . .
C20 C 0.67569(12) 0.4555(3) 0.73491(19) 0.0328(9) Uani 1 1 d . . . . .
H20 H 0.679733 0.467033 0.781132 0.039 Uiso 1 1 calc R . . . .
C21 C 0.66815(14) 0.3507(3) 0.7080(2) 0.0405(10) Uani 1 1 d . . . . .
H21 H 0.666658 0.290672 0.735523 0.049 Uiso 1 1 calc R . . . .
C22 C 0.66271(14) 0.3320(3) 0.6414(2) 0.0427(10) Uani 1 1 d . . . . .
H22 H 0.656832 0.259187 0.623031 0.051 Uiso 1 1 calc R . . . .
C23 C 0.66571(13) 0.4182(3) 0.60085(19) 0.0320(9) Uani 1 1 d . . . . .
C24 C 0.68316(13) 0.6599(3) 0.72648(18) 0.0294(9) Uani 1 1 d . . . . .
H24 H 0.673352 0.713637 0.687057 0.035 Uiso 1 1 calc R . . . .
C25 C 0.65261(15) 0.6796(4) 0.7632(2) 0.0509(12) Uani 1 1 d . . . . .
H25A H 0.620228 0.661126 0.731646 0.076 Uiso 1 1 calc GR . . . .
H25B H 0.654562 0.757408 0.776763 0.076 Uiso 1 1 calc GR . . . .
H25C H 0.663344 0.632995 0.804797 0.076 Uiso 1 1 calc GR . . . .
C26 C 0.73325(15) 0.6856(4) 0.7764(3) 0.0628(14) Uani 1 1 d . . . . .
H26A H 0.744050 0.633518 0.815384 0.094 Uiso 1 1 calc GR . . . .
H26B H 0.735304 0.761065 0.794023 0.094 Uiso 1 1 calc GR . . . .
H26C H 0.752834 0.678902 0.751997 0.094 Uiso 1 1 calc GR . . . .
C27 C 0.65820(15) 0.3957(3) 0.5268(2) 0.0424(10) Uani 1 1 d . U . . .
H27 H 0.668219 0.462968 0.509862 0.051 Uiso 1 1 calc R . . . .
C28 C 0.60615(17) 0.3772(4) 0.4789(2) 0.0680(15) Uani 1 1 d . U . . .
H28A H 0.595948 0.308296 0.491821 0.102 Uiso 1 1 calc GR . . . .
H28B H 0.601253 0.372614 0.430435 0.102 Uiso 1 1 calc GR . . . .
H28C H 0.588074 0.439006 0.483881 0.102 Uiso 1 1 calc GR . . . .
C29 C 0.6871(2) 0.2983(4) 0.5219(3) 0.097(2) Uani 1 1 d . U . . .
H29A H 0.720274 0.312666 0.551437 0.146 Uiso 1 1 calc GR . . . .
H29B H 0.681881 0.289070 0.473528 0.146 Uiso 1 1 calc GR . . . .
H29C H 0.677793 0.230851 0.537688 0.146 Uiso 1 1 calc GR . . . .
C30 C 0.50061(12) 0.7915(3) 0.3954(2) 0.0309(9) Uani 1 1 d . . . . .
H30A H 0.497583 0.850940 0.361914 0.037 Uiso 1 1 calc R . . . .
H30B H 0.509815 0.824759 0.441861 0.037 Uiso 1 1 calc R . . . .
C31 C 0.45564(12) 0.7290(3) 0.3721(2) 0.0348(9) Uani 1 1 d . . . . .
H31A H 0.428450 0.777958 0.347631 0.042 Uiso 1 1 calc R . . . .
H31B H 0.453140 0.693880 0.412096 0.042 Uiso 1 1 calc R . . . .
C32 C 0.45915(12) 0.6431(3) 0.3232(2) 0.0337(9) Uani 1 1 d . . . . .
H32A H 0.439288 0.578294 0.319413 0.040 Uiso 1 1 calc R . . . .
H32B H 0.449954 0.674285 0.276257 0.040 Uiso 1 1 calc R . . . .
C33 C 0.51007(12) 0.6124(3) 0.35754(18) 0.0319(9) Uani 1 1 d . . . . .
H33A H 0.515420 0.547749 0.388416 0.038 Uiso 1 1 calc R . . . .
H33B H 0.520910 0.594178 0.322039 0.038 Uiso 1 1 calc R . . . .
O1S O 0.500000 0.1827(3) 0.250000 0.0514(11) Uani 1 2 d S T P . .
C1S C 0.47047(18) 0.2518(4) 0.2631(3) 0.0721(16) Uani 1 1 d . . . . .
H1SA H 0.472841 0.234925 0.309790 0.087 Uiso 1 1 calc R . . . .
H1SB H 0.437964 0.237312 0.228465 0.087 Uiso 1 1 calc R . . . .
C2S C 0.4807(2) 0.3640(4) 0.2604(4) 0.113(3) Uani 1 1 d . . . . .
H2SA H 0.490528 0.399459 0.306391 0.136 Uiso 1 1 calc R . . . .
H2SB H 0.453140 0.403707 0.225623 0.136 Uiso 1 1 calc R . . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
I I -0.4742 1.8119 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
I1 Dy1 I2 149.036(9) . . ?
O1 Dy1 I1 85.28(5) . . ?
O1 Dy1 I2 81.39(5) . . ?
N1 Dy1 I1 96.70(6) . . ?
N1 Dy1 I2 113.88(6) . . ?
N1 Dy1 O1 107.00(8) . . ?
N1 Dy1 N2 81.85(9) . . ?
N2 Dy1 I1 97.75(6) . . ?
N2 Dy1 I2 91.53(6) . . ?
N2 Dy1 O1 170.32(8) . . ?
C30 O1 Dy1 126.71(19) . . ?
C30 O1 C33 108.8(2) . . ?
C33 O1 Dy1 116.22(19) . . ?
C1 N1 Dy1 122.3(2) . . ?
C1 N1 C6 123.4(3) . . ?
C6 N1 Dy1 113.38(19) . . ?
C3 N2 Dy1 118.1(2) . . ?
C3 N2 C18 118.5(3) . . ?
C18 N2 Dy1 121.6(2) . . ?
N1 C1 C2 122.9(3) . . ?
N1 C1 C4 120.3(3) . . ?
C2 C1 C4 116.7(3) . . ?
C3 C2 C1 130.2(3) . . ?
N2 C3 C2 124.6(3) . . ?
N2 C3 C5 119.3(3) . . ?
C2 C3 C5 116.2(3) . . ?
C7 C6 N1 122.1(3) . . ?
C7 C6 C11 121.1(3) . . ?
C11 C6 N1 116.6(3) . . ?
C6 C7 C12 123.5(3) . . ?
C8 C7 C6 119.1(3) . . ?
C8 C7 C12 117.4(3) . . ?
C9 C8 C7 120.8(3) . . ?
C8 C9 C10 119.9(3) . . ?
C9 C10 C11 121.9(3) . . ?
C6 C11 C15 121.8(3) . . ?
C10 C11 C6 117.3(3) . . ?
C10 C11 C15 120.9(3) . . ?
C7 C12 C14 110.0(3) . . ?
C13 C12 C7 112.2(3) . . ?
C13 C12 C14 109.9(3) . . ?
C11 C15 C16 111.6(3) . . ?
C11 C15 C17 113.7(3) . . ?
C16 C15 C17 109.5(3) . . ?
C19 C18 N2 118.4(3) . . ?
C23 C18 N2 120.4(3) . . ?
C23 C18 C19 121.1(3) . . ?
C18 C19 C24 122.7(3) . . ?
C20 C19 C18 118.1(3) . . ?
C20 C19 C24 119.2(3) . . ?
C21 C20 C19 121.2(3) . . ?
C20 C21 C22 120.4(4) . . ?
C21 C22 C23 120.8(4) . . ?
C18 C23 C27 121.9(3) . . ?
C22 C23 C18 118.3(3) . . ?
C22 C23 C27 119.7(4) . . ?
C19 C24 C25 112.7(3) . . ?
C26 C24 C19 112.4(3) . . ?
C26 C24 C25 109.0(3) . . ?
C23 C27 C28 110.3(3) . . ?
C23 C27 C29 112.8(3) . . ?
C29 C27 C28 110.6(4) . . ?
O1 C30 C31 105.1(3) . . ?
C30 C31 C32 102.9(3) . . ?
C33 C32 C31 103.1(3) . . ?
O1 C33 C32 106.0(3) . . ?
C1S O1S C1S 105.4(5) 2_655 . ?
O1S C1S C2S 112.7(4) . . ?
C1S C2S C2S 104.5(3) . 2_655 ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Dy1 I1 2.9675(2) . ?
Dy1 I2 2.9729(3) . ?
Dy1 O1 2.366(2) . ?
Dy1 N1 2.252(3) . ?
Dy1 N2 2.288(3) . ?
O1 C30 1.463(4) . ?
O1 C33 1.467(4) . ?
N1 C1 1.335(4) . ?
N1 C6 1.448(4) . ?
N2 C3 1.344(4) . ?
N2 C18 1.455(4) . ?
C1 C2 1.398(5) . ?
C1 C4 1.510(5) . ?
C2 C3 1.398(5) . ?
C3 C5 1.512(5) . ?
C6 C7 1.395(4) . ?
C6 C11 1.419(4) . ?
C7 C8 1.390(4) . ?
C7 C12 1.533(4) . ?
C8 C9 1.377(5) . ?
C9 C10 1.383(5) . ?
C10 C11 1.392(5) . ?
C11 C15 1.512(4) . ?
C12 C13 1.527(5) . ?
C12 C14 1.534(5) . ?
C15 C16 1.520(5) . ?
C15 C17 1.535(4) . ?
C18 C19 1.408(4) . ?
C18 C23 1.395(5) . ?
C19 C20 1.383(5) . ?
C19 C24 1.517(5) . ?
C20 C21 1.370(5) . ?
C21 C22 1.377(6) . ?
C22 C23 1.389(5) . ?
C23 C27 1.521(5) . ?
C24 C25 1.519(5) . ?
C24 C26 1.514(5) . ?
C27 C28 1.537(6) . ?
C27 C29 1.531(6) . ?
C30 C31 1.502(5) . ?
C31 C32 1.515(5) . ?
C32 C33 1.507(5) . ?
O1S C1S 1.380(5) 2_655 ?
O1S C1S 1.380(5) . ?
C1S C2S 1.405(7) . ?
C2S C2S 1.488(9) 2_655 ?
