#------------------------------------------------------------------------------
#$Date: 2021-01-06 05:09:39 +0200 (Wed, 06 Jan 2021) $
#$Revision: 260556 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/06/02/7060255.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7060255
loop_
_publ_author_name
'Song, Hao'
'Zhang, Sen-Yu'
'Gu, Peng-Fei'
'Wu, Hua-Yu'
'Wang, Zi-Kun'
'Wang, Shi'
'Wang, Zheng'
'Gu, Yu-Yang'
'Li, Yong-Hua'
_publ_section_title
;
 Trapping of two mononuclear silyl platinum(ii)/palladium(ii) complexes
 and a unique dinuclear bis(μ2-disilene)(silyl)nickel(ii) complex
;
_journal_issue                   46
_journal_name_full               'New Journal of Chemistry'
_journal_page_first              20351
_journal_page_last               20357
_journal_paper_doi               10.1039/D0NJ04079G
_journal_volume                  44
_journal_year                    2020
_chemical_formula_moiety         'C40 H50 P2 Pd Si2'
_chemical_formula_sum            'C40 H50 P2 Pd Si2'
_chemical_formula_weight         755.34
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_audit_update_record
;
2019-12-17 deposited with the CCDC.	2020-10-19 downloaded from the CCDC.
;
_cell_angle_alpha                94.02(3)
_cell_angle_beta                 113.95(3)
_cell_angle_gamma                95.58(3)
_cell_formula_units_Z            2
_cell_length_a                   11.747(2)
_cell_length_b                   13.118(3)
_cell_length_c                   13.202(3)
_cell_measurement_reflns_used    8261
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      27.51
_cell_measurement_theta_min      2.63
_cell_volume                     1836.9(8)
_computing_cell_refinement       'Bruker XSCANS'
_computing_data_collection       'Bruker XSCANS'
_computing_data_reduction        'Bruker SHELXTL'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'Bruker SHELXTL'
_computing_structure_solution    'Bruker SHELXTL'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.978
_diffrn_measured_fraction_theta_max 0.978
_diffrn_measurement_device_type  'Bruker P4'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0176
_diffrn_reflns_av_sigmaI/netI    0.0195
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            15912
_diffrn_reflns_theta_full        27.51
_diffrn_reflns_theta_max         27.51
_diffrn_reflns_theta_min         1.57
_exptl_absorpt_coefficient_mu    0.685
_exptl_absorpt_correction_T_max  0.758
_exptl_absorpt_correction_T_min  0.690
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'Bruker SMART'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.366
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             788
_exptl_crystal_size_max          0.4
_exptl_crystal_size_mid          0.4
_exptl_crystal_size_min          0.4
_refine_diff_density_max         1.524
_refine_diff_density_min         -0.962
_refine_diff_density_rms         0.105
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.070
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     410
_refine_ls_number_reflns         8261
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.070
_refine_ls_R_factor_all          0.0354
_refine_ls_R_factor_gt           0.0333
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0564P)²+2.4426P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0977
_refine_ls_wR_factor_ref         0.0990
_reflns_number_gt                7624
_reflns_number_total             8261
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            d0nj04079g2.cif
_cod_data_source_block           p1
_cod_depositor_comments
;
The following automatic conversions were performed:

data item '_exptl_absorpt_correction_type' value 'MULTI-SCAN' was
changed to 'multi-scan' in accordance with the
/home/data/users/saulius/crontab/automatic-downloads/current/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 last updated on
2011-04-26.

data item '_symmetry_cell_setting' value 'Triclinic' was changed to
'triclinic' in accordance with the
/home/data/users/saulius/crontab/automatic-downloads/current/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 last updated on
2011-04-26.

Automatic conversion script
Id: cif_fix_values 7556 2019-12-06 15:28:31Z antanas 
;
_cod_original_cell_volume        1836.9(7)
_cod_database_code               7060255
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pd1 Pd 0.803197(14) 0.237815(12) 0.241039(13) 0.01362(7) Uani 1 1 d . . .
P2 P 0.70944(5) 0.18720(4) 0.36009(5) 0.01414(12) Uani 1 1 d . . .
P1 P 0.98390(5) 0.18392(4) 0.37215(5) 0.01477(12) Uani 1 1 d . . .
Si2 Si 0.88483(6) 0.27291(5) 0.10777(5) 0.01578(13) Uani 1 1 d . . .
Si1 Si 0.63570(6) 0.30785(5) 0.11207(5) 0.01553(13) Uani 1 1 d . . .
H1A H 0.5202 0.2381 0.0600 0.019 Uiso 1 1 d R . .
H1B H 0.6008 0.3947 0.1651 0.019 Uiso 1 1 d R . .
C25 C 1.1645(2) 0.4726(2) 0.5184(2) 0.0256(5) Uani 1 1 d . . .
H25A H 1.1509 0.5399 0.5048 0.031 Uiso 1 1 calc R . .
C29 C 0.6660(2) 0.36291(17) -0.00420(19) 0.0172(4) Uani 1 1 d . . .
C4 C 0.4966(3) -0.1444(2) 0.2511(3) 0.0332(6) Uani 1 1 d . . .
H4A H 0.4529 -0.2109 0.2285 0.040 Uiso 1 1 calc R . .
C14 C 0.9352(2) 0.11813(18) 0.4708(2) 0.0187(4) Uani 1 1 d . . .
H14A H 0.8978 0.0476 0.4390 0.022 Uiso 1 1 calc R . .
H14B H 1.0081 0.1163 0.5400 0.022 Uiso 1 1 calc R . .
C21 C 1.1001(2) 0.28885(18) 0.46590(19) 0.0177(4) Uani 1 1 d . . .
C16 C 1.0068(2) -0.00425(19) 0.27930(19) 0.0196(4) Uani 1 1 d . . .
H16A H 0.9234 -0.0214 0.2679 0.024 Uiso 1 1 calc R . .
C24 C 1.2684(2) 0.4549(2) 0.6102(2) 0.0272(5) Uani 1 1 d . . .
H24A H 1.3246 0.5102 0.6580 0.033 Uiso 1 1 calc R . .
C5 C 0.5278(4) -0.0907(3) 0.1773(3) 0.0458(8) Uani 1 1 d . . .
H5A H 0.5059 -0.1217 0.1051 0.055 Uiso 1 1 calc R . .
C31 C 0.6163(2) 0.45426(19) -0.1666(2) 0.0226(5) Uani 1 1 d . . .
H31A H 0.5618 0.4903 -0.2197 0.027 Uiso 1 1 calc R . .
C11 C 0.5357(3) 0.3515(2) 0.5211(2) 0.0257(5) Uani 1 1 d . . .
H11A H 0.5507 0.3779 0.5933 0.031 Uiso 1 1 calc R . .
C2 C 0.5938(2) 0.0006(2) 0.3919(2) 0.0248(5) Uani 1 1 d . . .
H2A H 0.6153 0.0310 0.4642 0.030 Uiso 1 1 calc R . .
C3 C 0.5305(3) -0.0987(2) 0.3583(3) 0.0300(6) Uani 1 1 d . . .
H3A H 0.5107 -0.1349 0.4084 0.036 Uiso 1 1 calc R . .
C26 C 1.0803(2) 0.39060(19) 0.4462(2) 0.0206(5) Uani 1 1 d . . .
H26A H 1.0106 0.4032 0.3845 0.025 Uiso 1 1 calc R . .
C30 C 0.5833(2) 0.41597(18) -0.08549(19) 0.0200(5) Uani 1 1 d . . .
H30A H 0.5061 0.4255 -0.0850 0.024 Uiso 1 1 calc R . .
C34 C 0.7826(2) 0.34837(18) -0.00458(19) 0.0185(4) Uani 1 1 d . . .
C20 C 1.1947(2) 0.11849(19) 0.3472(2) 0.0212(5) Uani 1 1 d . . .
H20A H 1.2381 0.1833 0.3821 0.025 Uiso 1 1 calc R . .
C15 C 1.0712(2) 0.09270(18) 0.33355(18) 0.0167(4) Uani 1 1 d . . .
C1 C 0.6257(2) 0.05568(18) 0.3183(2) 0.0181(4) Uani 1 1 d . . .
C28 C 1.0506(2) 0.3424(2) 0.1679(2) 0.0260(5) Uani 1 1 d . . .
H28A H 1.0725 0.3607 0.1083 0.039 Uiso 1 1 calc R . .
H28B H 1.1074 0.2982 0.2113 0.039 Uiso 1 1 calc R . .
H28C H 1.0563 0.4039 0.2147 0.039 Uiso 1 1 calc R . .
C8 C 0.4911(2) 0.27289(18) 0.3067(2) 0.0191(4) Uani 1 1 d . . .
H8A H 0.4754 0.2465 0.2343 0.023 Uiso 1 1 calc R . .
C23 C 1.2889(2) 0.3540(2) 0.6313(2) 0.0254(5) Uani 1 1 d . . .
H23A H 1.3588 0.3419 0.6932 0.030 Uiso 1 1 calc R . .
C13 C 0.8397(2) 0.17613(18) 0.49428(19) 0.0180(4) Uani 1 1 d . . .
H13A H 0.8793 0.2442 0.5334 0.022 Uiso 1 1 calc R . .
H13B H 0.8082 0.1389 0.5407 0.022 Uiso 1 1 calc R . .
C33 C 0.8142(2) 0.3865(2) -0.0880(2) 0.0243(5) Uani 1 1 d . . .
H33A H 0.8909 0.3767 -0.0895 0.029 Uiso 1 1 calc R . .
C19 C 1.2537(2) 0.0478(2) 0.3087(2) 0.0245(5) Uani 1 1 d . . .
H19A H 1.3360 0.0657 0.3175 0.029 Uiso 1 1 calc R . .
C7 C 0.6015(2) 0.25716(17) 0.39534(19) 0.0162(4) Uani 1 1 d . . .
C12 C 0.6234(2) 0.29672(19) 0.5033(2) 0.0210(5) Uani 1 1 d . . .
H12A H 0.6963 0.2867 0.5634 0.025 Uiso 1 1 calc R . .
C27 C 0.8944(3) 0.1506(2) 0.0306(2) 0.0289(6) Uani 1 1 d . . .
H27A H 0.9300 0.1671 -0.0210 0.043 Uiso 1 1 calc R . .
H27B H 0.8115 0.1131 -0.0095 0.043 Uiso 1 1 calc R . .
H27C H 0.9464 0.1091 0.0829 0.043 Uiso 1 1 calc R . .
C9 C 0.4042(2) 0.32747(19) 0.3250(2) 0.0225(5) Uani 1 1 d . . .
H9A H 0.3310 0.3374 0.2652 0.027 Uiso 1 1 calc R . .
C6 C 0.5918(3) 0.0092(2) 0.2103(2) 0.0336(6) Uani 1 1 d . . .
H6A H 0.6120 0.0449 0.1601 0.040 Uiso 1 1 calc R . .
C22 C 1.2048(2) 0.27139(19) 0.5596(2) 0.0212(5) Uani 1 1 d . . .
H22A H 1.2182 0.2042 0.5741 0.025 Uiso 1 1 calc R . .
C17 C 1.0658(2) -0.07534(19) 0.2421(2) 0.0228(5) Uani 1 1 d . . .
H17A H 1.0226 -0.1402 0.2071 0.027 Uiso 1 1 calc R . .
C10 C 0.4270(2) 0.36707(19) 0.4326(2) 0.0251(5) Uani 1 1 d . . .
H10A H 0.3693 0.4040 0.4452 0.030 Uiso 1 1 calc R . .
C18 C 1.1901(2) -0.0491(2) 0.2576(2) 0.0243(5) Uani 1 1 d . . .
H18A H 1.2303 -0.0967 0.2335 0.029 Uiso 1 1 calc R . .
C32 C 0.7311(2) 0.4388(2) -0.1686(2) 0.0260(5) Uani 1 1 d . . .
H32A H 0.7525 0.4635 -0.2238 0.031 Uiso 1 1 calc R . .
C39 C 0.9317(2) 0.66666(17) 0.17451(19) 0.0160(4) Uani 1 1 d . . .
H39A H 0.9887 0.6887 0.1424 0.024 Uiso 1 1 d R . .
H39B H 0.9156 0.7153 0.2232 0.024 Uiso 1 1 d R . .
C36 C 0.7646(2) 0.81913(17) 0.0811(2) 0.0195(4) Uani 1 1 d . . .
H36A H 0.7767 0.8279 0.1554 0.029 Uiso 1 1 d R . .
H36B H 0.6756 0.8026 0.0585 0.029 Uiso 1 1 d R . .
C37 C 0.7650(3) 0.7238(2) 0.0242(3) 0.0357(6) Uani 1 1 d . . .
H37A H 0.8242 0.7322 -0.0098 0.054 Uiso 1 1 d R . .
H37B H 0.6821 0.7001 -0.0345 0.054 Uiso 1 1 d R . .
C38 C 0.8020(3) 0.6460(2) 0.1057(3) 0.0334(6) Uani 1 1 d . . .
H38A H 0.7549 0.6488 0.1513 0.050 Uiso 1 1 d R . .
H38B H 0.7822 0.5772 0.0656 0.050 Uiso 1 1 d R . .
C40 C 0.9693(3) 0.6011(3) 0.2591(3) 0.0408(7) Uani 1 1 d . . .
H40A H 1.0594 0.6087 0.2950 0.061 Uiso 1 1 calc R . .
H40B H 0.9368 0.5309 0.2268 0.061 Uiso 1 1 calc R . .
H40C H 0.9370 0.6193 0.3132 0.061 Uiso 1 1 calc R . .
C35 C 0.7425(4) 0.8992(3) 0.0121(3) 0.0501(9) Uani 1 1 d . . .
H35A H 0.7516 0.9635 0.0560 0.075 Uiso 1 1 calc R . .
H35B H 0.6588 0.8849 -0.0459 0.075 Uiso 1 1 calc R . .
H35C H 0.8021 0.9037 -0.0206 0.075 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pd Pd -0.9988 1.0072 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Si1 Pd1 P1 174.05(2) . . ?
Si1 Pd1 P2 98.72(3) . . ?
P1 Pd1 P2 84.88(3) . . ?
Si1 Pd1 Si2 80.03(3) . . ?
P1 Pd1 Si2 96.88(3) . . ?
P2 Pd1 Si2 173.87(2) . . ?
C7 P2 C1 102.56(10) . . ?
C7 P2 C13 105.42(11) . . ?
C1 P2 C13 102.56(11) . . ?
C7 P2 Pd1 125.28(8) . . ?
C1 P2 Pd1 112.66(8) . . ?
C13 P2 Pd1 106.03(8) . . ?
C21 P1 C15 106.38(11) . . ?
C21 P1 C14 101.12(11) . . ?
C15 P1 C14 103.35(11) . . ?
C21 P1 Pd1 114.18(8) . . ?
C15 P1 Pd1 122.57(8) . . ?
C14 P1 Pd1 106.58(8) . . ?
C27 Si2 C28 103.68(13) . . ?
C27 Si2 C34 105.18(12) . . ?
C28 Si2 C34 107.78(12) . . ?
C27 Si2 Pd1 111.31(9) . . ?
C28 Si2 Pd1 114.96(9) . . ?
C34 Si2 Pd1 113.06(8) . . ?
C29 Si1 Pd1 115.36(8) . . ?
C29 Si1 H1A 106.6 . . ?
Pd1 Si1 H1A 114.5 . . ?
C29 Si1 H1B 104.2 . . ?
Pd1 Si1 H1B 111.9 . . ?
H1A Si1 H1B 103.2 . . ?
C24 C25 C26 120.5(2) . . ?
C24 C25 H25A 119.7 . . ?
C26 C25 H25A 119.7 . . ?
C30 C29 C34 120.1(2) . . ?
C30 C29 Si1 125.27(18) . . ?
C34 C29 Si1 114.62(17) . . ?
C3 C4 C5 119.6(3) . . ?
C3 C4 H4A 120.2 . . ?
C5 C4 H4A 120.2 . . ?
C13 C14 P1 109.56(15) . . ?
C13 C14 H14A 109.8 . . ?
P1 C14 H14A 109.8 . . ?
C13 C14 H14B 109.8 . . ?
P1 C14 H14B 109.8 . . ?
H14A C14 H14B 108.2 . . ?
C22 C21 C26 119.1(2) . . ?
C22 C21 P1 122.24(18) . . ?
C26 C21 P1 118.60(18) . . ?
C17 C16 C15 120.7(2) . . ?
C17 C16 H16A 119.6 . . ?
C15 C16 H16A 119.6 . . ?
C25 C24 C23 119.9(2) . . ?
C25 C24 H24A 120.0 . . ?
C23 C24 H24A 120.0 . . ?
C4 C5 C6 120.4(3) . . ?
C4 C5 H5A 119.8 . . ?
C6 C5 H5A 119.8 . . ?
C30 C31 C32 120.0(2) . . ?
C30 C31 H31A 120.0 . . ?
C32 C31 H31A 120.0 . . ?
C10 C11 C12 120.7(2) . . ?
C10 C11 H11A 119.6 . . ?
C12 C11 H11A 119.6 . . ?
C3 C2 C1 120.6(3) . . ?
C3 C2 H2A 119.7 . . ?
C1 C2 H2A 119.7 . . ?
C4 C3 C2 120.4(3) . . ?
C4 C3 H3A 119.8 . . ?
C2 C3 H3A 119.8 . . ?
C25 C26 C21 120.2(2) . . ?
C25 C26 H26A 119.9 . . ?
C21 C26 H26A 119.9 . . ?
C31 C30 C29 120.2(2) . . ?
C31 C30 H30A 119.9 . . ?
C29 C30 H30A 119.9 . . ?
C29 C34 C33 119.0(2) . . ?
C29 C34 Si2 116.19(17) . . ?
C33 C34 Si2 124.75(18) . . ?
C15 C20 C19 120.4(2) . . ?
C15 C20 H20A 119.8 . . ?
C19 C20 H20A 119.8 . . ?
C20 C15 C16 119.0(2) . . ?
C20 C15 P1 122.94(18) . . ?
C16 C15 P1 117.79(18) . . ?
C6 C1 C2 118.9(2) . . ?
C6 C1 P2 119.49(19) . . ?
C2 C1 P2 121.65(19) . . ?
Si2 C28 H28A 109.5 . . ?
Si2 C28 H28B 109.5 . . ?
H28A C28 H28B 109.5 . . ?
Si2 C28 H28C 109.5 . . ?
H28A C28 H28C 109.5 . . ?
H28B C28 H28C 109.5 . . ?
C9 C8 C7 120.9(2) . . ?
C9 C8 H8A 119.5 . . ?
C7 C8 H8A 119.5 . . ?
C22 C23 C24 119.9(2) . . ?
C22 C23 H23A 120.0 . . ?
C24 C23 H23A 120.0 . . ?
C14 C13 P2 108.30(16) . . ?
C14 C13 H13A 110.0 . . ?
P2 C13 H13A 110.0 . . ?
C14 C13 H13B 110.0 . . ?
P2 C13 H13B 110.0 . . ?
H13A C13 H13B 108.4 . . ?
C32 C33 C34 120.4(2) . . ?
C32 C33 H33A 119.8 . . ?
C34 C33 H33A 119.8 . . ?
C18 C19 C20 120.1(2) . . ?
C18 C19 H19A 119.9 . . ?
C20 C19 H19A 119.9 . . ?
C12 C7 C8 119.0(2) . . ?
C12 C7 P2 124.34(18) . . ?
C8 C7 P2 116.70(17) . . ?
C7 C12 C11 119.8(2) . . ?
C7 C12 H12A 120.1 . . ?
C11 C12 H12A 120.1 . . ?
Si2 C27 H27A 109.5 . . ?
Si2 C27 H27B 109.5 . . ?
H27A C27 H27B 109.5 . . ?
Si2 C27 H27C 109.5 . . ?
H27A C27 H27C 109.5 . . ?
H27B C27 H27C 109.5 . . ?
C10 C9 C8 119.8(2) . . ?
C10 C9 H9A 120.1 . . ?
C8 C9 H9A 120.1 . . ?
C1 C6 C5 120.1(3) . . ?
C1 C6 H6A 119.9 . . ?
C5 C6 H6A 119.9 . . ?
C23 C22 C21 120.4(2) . . ?
C23 C22 H22A 119.8 . . ?
C21 C22 H22A 119.8 . . ?
C16 C17 C18 119.7(2) . . ?
C16 C17 H17A 120.1 . . ?
C18 C17 H17A 120.1 . . ?
C11 C10 C9 119.8(2) . . ?
C11 C10 H10A 120.1 . . ?
C9 C10 H10A 120.1 . . ?
C19 C18 C17 120.0(2) . . ?
C19 C18 H18A 120.0 . . ?
C17 C18 H18A 120.0 . . ?
C31 C32 C33 120.2(2) . . ?
C31 C32 H32A 119.9 . . ?
C33 C32 H32A 119.9 . . ?
C38 C39 C40 112.2(2) . . ?
C38 C39 H39A 119.1 . . ?
C40 C39 H39A 119.2 . . ?
C38 C39 H39B 89.9 . . ?
C40 C39 H39B 89.9 . . ?
H39A C39 H39B 119.4 . . ?
C35 C36 C37 112.5(3) . . ?
C35 C36 H36A 123.8 . . ?
C37 C36 H36A 123.7 . . ?
C35 C36 H36B 89.8 . . ?
C37 C36 H36B 89.7 . . ?
H36A C36 H36B 90.0 . . ?
C36 C37 C38 109.1(3) . . ?
C36 C37 H37A 109.9 . . ?
C38 C37 H37A 109.9 . . ?
C36 C37 H37B 109.9 . . ?
C38 C37 H37B 109.9 . . ?
H37A C37 H37B 108.3 . . ?
C39 C38 C37 110.0(2) . . ?
C39 C38 H38A 109.7 . . ?
C37 C38 H38A 109.7 . . ?
C39 C38 H38B 109.7 . . ?
C37 C38 H38B 109.7 . . ?
H38A C38 H38B 108.2 . . ?
C39 C40 H40A 109.5 . . ?
C39 C40 H40B 109.5 . . ?
H40A C40 H40B 109.5 . . ?
C39 C40 H40C 109.5 . . ?
H40A C40 H40C 109.5 . . ?
H40B C40 H40C 109.5 . . ?
C36 C35 H35A 109.5 . . ?
C36 C35 H35B 109.5 . . ?
H35A C35 H35B 109.5 . . ?
C36 C35 H35C 109.5 . . ?
H35A C35 H35C 109.5 . . ?
H35B C35 H35C 109.5 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pd1 Si1 2.3378(11) . ?
Pd1 P1 2.3414(11) . ?
Pd1 P2 2.3524(8) . ?
Pd1 Si2 2.3716(8) . ?
P2 C7 1.820(2) . ?
P2 C1 1.829(2) . ?
P2 C13 1.838(2) . ?
P1 C21 1.821(3) . ?
P1 C15 1.822(2) . ?
P1 C14 1.854(2) . ?
Si2 C27 1.877(3) . ?
Si2 C28 1.885(3) . ?
Si2 C34 1.901(2) . ?
Si1 C29 1.885(2) . ?
Si1 H1A 1.4366 . ?
Si1 H1B 1.4723 . ?
C25 C24 1.381(4) . ?
C25 C26 1.388(4) . ?
C25 H25A 0.9300 . ?
C29 C30 1.403(3) . ?
C29 C34 1.403(3) . ?
C4 C3 1.378(4) . ?
C4 C5 1.385(5) . ?
C4 H4A 0.9300 . ?
C14 C13 1.533(3) . ?
C14 H14A 0.9700 . ?
C14 H14B 0.9700 . ?
C21 C22 1.398(3) . ?
C21 C26 1.401(3) . ?
C16 C17 1.389(3) . ?
C16 C15 1.396(3) . ?
C16 H16A 0.9300 . ?
C24 C23 1.396(4) . ?
C24 H24A 0.9300 . ?
C5 C6 1.391(4) . ?
C5 H5A 0.9300 . ?
C31 C30 1.387(3) . ?
C31 C32 1.393(4) . ?
C31 H31A 0.9300 . ?
C11 C10 1.382(4) . ?
C11 C12 1.397(3) . ?
C11 H11A 0.9300 . ?
C2 C3 1.382(4) . ?
C2 C1 1.396(3) . ?
C2 H2A 0.9300 . ?
C3 H3A 0.9300 . ?
C26 H26A 0.9300 . ?
C30 H30A 0.9300 . ?
C34 C33 1.404(3) . ?
C20 C15 1.391(3) . ?
C20 C19 1.395(3) . ?
C20 H20A 0.9300 . ?
C1 C6 1.390(4) . ?
C28 H28A 0.9600 . ?
C28 H28B 0.9600 . ?
C28 H28C 0.9600 . ?
C8 C9 1.390(3) . ?
C8 C7 1.396(3) . ?
C8 H8A 0.9300 . ?
C23 C22 1.391(4) . ?
C23 H23A 0.9300 . ?
C13 H13A 0.9700 . ?
C13 H13B 0.9700 . ?
C33 C32 1.394(4) . ?
C33 H33A 0.9300 . ?
C19 C18 1.383(4) . ?
C19 H19A 0.9300 . ?
C7 C12 1.392(3) . ?
C12 H12A 0.9300 . ?
C27 H27A 0.9600 . ?
C27 H27B 0.9600 . ?
C27 H27C 0.9600 . ?
C9 C10 1.386(4) . ?
C9 H9A 0.9300 . ?
C6 H6A 0.9300 . ?
C22 H22A 0.9300 . ?
C17 C18 1.394(4) . ?
C17 H17A 0.9300 . ?
C10 H10A 0.9300 . ?
C18 H18A 0.9300 . ?
C32 H32A 0.9300 . ?
C39 C38 1.408(3) . ?
C39 C40 1.411(4) . ?
C39 H39A 0.9599 . ?
C39 H39B 0.9600 . ?
C36 C35 1.412(4) . ?
C36 C37 1.415(4) . ?
C36 H36A 0.9301 . ?
C36 H36B 0.9601 . ?
C37 C38 1.500(4) . ?
C37 H37A 0.9700 . ?
C37 H37B 0.9700 . ?
C38 H38A 0.9700 . ?
C38 H38B 0.9700 . ?
C40 H40A 0.9600 . ?
C40 H40B 0.9600 . ?
C40 H40C 0.9600 . ?
C35 H35A 0.9600 . ?
C35 H35B 0.9600 . ?
C35 H35C 0.9600 . ?
