#------------------------------------------------------------------------------
#$Date: 2021-05-05 11:59:25 +0300 (Wed, 05 May 2021) $
#$Revision: 264937 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/06/04/7060469.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7060469
loop_
_publ_author_name
'Kukkonen, Esa'
'Lahtinen, Elmeri'
'Myllyperkiö, Pasi'
'Haukka, Matti'
'Konu, Jari'
_publ_section_title
;
 Nonlinear optical properties of diaromatic stilbene, butadiene and
 thiophene derivatives
;
_journal_issue                   15
_journal_name_full               'New Journal of Chemistry'
_journal_page_first              6640
_journal_page_last               6650
_journal_paper_doi               10.1039/D1NJ00456E
_journal_volume                  45
_journal_year                    2021
_chemical_formula_moiety         'C14 H9 Br N2 O5'
_chemical_formula_sum            'C14 H9 Br N2 O5'
_chemical_formula_weight         365.14
_space_group_crystal_system      monoclinic
_space_group_IT_number           9
_space_group_name_Hall           'C -2yc'
_space_group_name_H-M_alt        'C 1 c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_audit_creation_date             2021-02-24
_audit_creation_method
;
Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_audit_update_record
;
2021-03-10 deposited with the CCDC.	2021-03-19 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 93.319(2)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   3.82360(10)
_cell_length_b                   26.8722(5)
_cell_length_c                   13.2409(2)
_cell_measurement_reflns_used    3851
_cell_measurement_temperature    120.00(10)
_cell_measurement_theta_max      75.9940
_cell_measurement_theta_min      4.6650
_cell_volume                     1358.20(5)
_computing_cell_refinement       'CrysAlisPro 1.171.38.43 (Rigaku OD, 2015)'
_computing_data_collection       'CrysAlisPro 1.171.38.43 (Rigaku OD, 2015)'
_computing_data_reduction        'CrysAlisPro 1.171.38.43 (Rigaku OD, 2015)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'ShelXT (Sheldrick, 2015)'
_diffrn_ambient_environment      N~2~
_diffrn_ambient_temperature      120.00(10)
_diffrn_detector                 'CCD plate'
_diffrn_detector_area_resol_mean 5.1977
_diffrn_detector_type            Atlas
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.985
_diffrn_measurement_details
;
List of Runs (angles in degrees, time in seconds):

  # Type    Start    End  Width  tₑₓₚ   ω     θ     κ     φ   Frames
#--------------------------------------------------------------------------
  1  ω    -61.00  27.00   1.00    1.50    --  -41.65  37.00-150.00   88
  2  ω   -121.00  -1.00   1.00    1.50    --  -41.65 -19.00  30.00  120
  3  ω     25.00  67.00   1.00    1.50    --   41.65-125.00 -60.00   42
  4  ω      1.00  83.00   1.00    1.50    --   41.65 -99.00   0.00   82
  5  ω     68.00  98.00   1.00    1.50    --   41.65-125.00 -60.00   30
  6  ω     77.00 116.00   1.00    7.00    --  112.00-111.00 -30.00   39
  7  ω     68.00 151.00   1.00    7.00    --  112.00 178.00-180.00   83
  8  ω     57.00 151.00   1.00    7.00    --  112.00 178.00-150.00   94
  9  ω     37.00 116.00   1.00    7.00    --  112.00-111.00-180.00   79
 10  ω    150.00 178.00   1.00    7.00    --  112.00  45.00 -30.00   28
 11  ω     41.00 140.00   1.00    7.00    --  112.00 -30.00 150.00   99
 12  ω    133.00 177.00   1.00    7.00    --  112.00  15.00-150.00   44
 13  ω     86.00 132.00   1.00    7.00    --  112.00  45.00 -30.00   46
 14  ω     61.00 115.00   1.00    7.00    --  112.00  15.00-150.00   54
 15  ω     36.00 140.00   1.00    7.00    --  112.00 -77.00-180.00  104
 16  ω     42.00 129.00   1.00    7.00    --  112.00 -61.00 -60.00   87
 17  ω     39.00 140.00   1.00    7.00    --  112.00 -30.00 -60.00  101
;
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'SuperNova, Dual, Cu at zero, Atlas'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_type
'CrysAlisPro convention (1999,Acta A55,543-557)'
_diffrn_orient_matrix_UB_11      0.0361770000
_diffrn_orient_matrix_UB_12      0.0556393000
_diffrn_orient_matrix_UB_13      -0.0254254000
_diffrn_orient_matrix_UB_21      -0.0745792000
_diffrn_orient_matrix_UB_22      0.0135918000
_diffrn_orient_matrix_UB_23      0.1097502000
_diffrn_orient_matrix_UB_31      0.3948638000
_diffrn_orient_matrix_UB_32      -0.0025351000
_diffrn_orient_matrix_UB_33      0.0299700000
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54184
_diffrn_reflns_av_R_equivalents  0.0220
_diffrn_reflns_av_unetI/netI     0.0256
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.985
_diffrn_reflns_limit_h_max       4
_diffrn_reflns_limit_h_min       -4
_diffrn_reflns_limit_k_max       32
_diffrn_reflns_limit_k_min       -33
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            5023
_diffrn_reflns_point_group_measured_fraction_full 0.728
_diffrn_reflns_point_group_measured_fraction_max 0.707
_diffrn_reflns_theta_full        67.684
_diffrn_reflns_theta_max         76.739
_diffrn_reflns_theta_min         3.289
_diffrn_source                   'micro-focus sealed X-ray tube'
_diffrn_source_type              'SuperNova (Cu) X-ray Source'
_exptl_absorpt_coefficient_mu    4.397
_exptl_absorpt_correction_T_max  0.914
_exptl_absorpt_correction_T_min  0.356
_exptl_absorpt_correction_type   analytical
_exptl_absorpt_process_details
;
CrysAlisPro 1.171.38.43 (Rigaku Oxford Diffraction, 2015)
Analytical numeric absorption correction using a multifaceted crystal
			model based on expressions derived by R.C. Clark & J.S. Reid.
(Clark, R. C. & Reid, J. S. (1995). Acta Cryst. A51, 887-897)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            orange
_exptl_crystal_colour_primary    orange
_exptl_crystal_density_diffrn    1.786
_exptl_crystal_description       needle
_exptl_crystal_F_000             728
_exptl_crystal_size_max          0.612
_exptl_crystal_size_mid          0.071
_exptl_crystal_size_min          0.02
_refine_diff_density_max         0.358
_refine_diff_density_min         -0.312
_refine_diff_density_rms         0.053
_refine_ls_abs_structure_details
;
 Classical Flack method preferred over Parsons because s.u. lower.
;
_refine_ls_abs_structure_Flack   -0.01(2)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.050
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     200
_refine_ls_number_reflns         2021
_refine_ls_number_restraints     2
_refine_ls_restrained_S_all      1.049
_refine_ls_R_factor_all          0.0300
_refine_ls_R_factor_gt           0.0296
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0600P)²+0.8315P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0821
_refine_ls_wR_factor_ref         0.0826
_reflns_Friedel_coverage         0.427
_reflns_Friedel_fraction_full    0.455
_reflns_Friedel_fraction_max     0.426
_reflns_number_gt                1997
_reflns_number_total             2021
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d1nj00456e2.cif
_cod_data_source_block           compound_1b
_cod_depositor_comments
'Adding full bibliography for 7060468--7060480.cif.'
_cod_database_code               7060469
_shelx_shelxl_version_number     2018/3
_chemical_oxdiff_formula         'C14 H19 N2 O5 Br1'
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_max   0.917
_shelx_estimated_absorpt_t_min   0.174
_reflns_odcompleteness_completeness 99.65
_reflns_odcompleteness_iscentric 1
_reflns_odcompleteness_theta     74.33
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All O(H) groups
2.a Aromatic/amide H refined with riding coordinates:
 C2(H2), C3(H3), C5(H5A), C6(H6), C7(H7), C8(H8), C10(H10), C12(H12)
2.b Idealised tetrahedral OH refined as rotating group:
 O5(H5)
;
_ins_header
;
TITL ek1917_a_Cc in Cc 
REM Cc (#9 in standard setting)
CELL 1.54184   3.823607  26.872166  13.240861  90.0000  93.3186  90.0000
ZERR    4.00   0.000066   0.000512   0.000247   0.0000   0.0017   0.0000
LATT -7
SYMM  x,-y, z+1/2 
SFAC C H N O Br
UNIT 56.00 76.00 8.00 20.00 4.00
TREF
HKLF 4
END
;
_olex2_submission_special_instructions 'No special instructions were received'
_oxdiff_exptl_absorpt_empirical_details
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
;
_oxdiff_exptl_absorpt_empirical_full_max 2.333
_oxdiff_exptl_absorpt_empirical_full_min 0.483
loop_
_space_group_symop_operation_xyz
'x, y, z'
'x, -y, z+1/2'
'x+1/2, y+1/2, z'
'x+1/2, -y+1/2, z+1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Br1 Br 0.69425(9) 0.62154(2) 0.08945(5) 0.03985(16) Uani 1 1 d . . . . .
O1 O -0.0316(10) 0.46383(12) 0.8523(3) 0.0372(8) Uani 1 1 d . . . . .
O2 O -0.1933(10) 0.53490(13) 0.9109(2) 0.0372(7) Uani 1 1 d . . . . .
O3 O 1.1973(10) 0.79594(12) 0.2112(3) 0.0415(8) Uani 1 1 d . . . . .
O4 O 1.0536(14) 0.81217(13) 0.3627(3) 0.0506(10) Uani 1 1 d . . . . .
O5 O 0.7600(10) 0.74591(11) 0.4693(3) 0.0370(7) Uani 1 1 d . . . . .
H5 H 0.834477 0.773949 0.458867 0.056 Uiso 1 1 calc GR . . . .
N1 N -0.0563(9) 0.50962(13) 0.8472(3) 0.0262(7) Uani 1 1 d . . . . .
N2 N 1.0539(12) 0.78476(16) 0.2882(4) 0.0347(10) Uani 1 1 d . . . . .
C1 C 0.0801(10) 0.53429(14) 0.7591(3) 0.0202(7) Uani 1 1 d . . . . .
C2 C 0.0550(10) 0.58577(13) 0.7516(3) 0.0212(7) Uani 1 1 d . . . . .
H2 H -0.039349 0.604419 0.802541 0.025 Uiso 1 1 calc R . . . .
C3 C 0.1735(10) 0.60857(13) 0.6664(3) 0.0209(7) Uani 1 1 d . . . . .
H3 H 0.156835 0.642966 0.659987 0.025 Uiso 1 1 calc R . . . .
C4 C 0.3183(10) 0.58077(12) 0.5898(3) 0.0188(6) Uani 1 1 d . . . . .
C5 C 0.3385(11) 0.52875(13) 0.6002(3) 0.0212(7) Uani 1 1 d . . . . .
H5A H 0.434856 0.509888 0.549912 0.025 Uiso 1 1 calc R . . . .
C6 C 0.2165(10) 0.50520(12) 0.6846(3) 0.0221(7) Uani 1 1 d . . . . .
H6 H 0.226112 0.470751 0.690878 0.027 Uiso 1 1 calc R . . . .
C7 C 0.4514(10) 0.60313(14) 0.4991(3) 0.0205(7) Uani 1 1 d . . . . .
H7 H 0.528177 0.581407 0.450432 0.025 Uiso 1 1 calc R . . . .
C8 C 0.4737(11) 0.65194(14) 0.4792(3) 0.0225(7) Uani 1 1 d . . . . .
H8 H 0.402117 0.674545 0.527035 0.027 Uiso 1 1 calc R . . . .
C9 C 0.6061(10) 0.67104(14) 0.3852(3) 0.0232(7) Uani 1 1 d . . . . .
C10 C 0.5903(11) 0.64293(14) 0.2965(3) 0.0247(7) Uani 1 1 d . . . . .
H10 H 0.490979 0.611335 0.296438 0.030 Uiso 1 1 calc R . . . .
C11 C 0.7213(12) 0.66147(15) 0.2078(3) 0.0269(8) Uani 1 1 d . . . . .
C12 C 0.8695(11) 0.70810(16) 0.2041(3) 0.0298(9) Uani 1 1 d . . . . .
H12 H 0.958204 0.720201 0.145003 0.036 Uiso 1 1 calc R . . . .
C13 C 0.8815(11) 0.73646(15) 0.2923(3) 0.0277(8) Uani 1 1 d . . . . .
C14 C 0.7507(12) 0.71952(16) 0.3829(4) 0.0254(8) Uani 1 1 d . . . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Br Br -0.6763 1.2805 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_exptl_crystal_face_index_h
_exptl_crystal_face_index_k
_exptl_crystal_face_index_l
_exptl_crystal_face_perp_dist
0 2 5 0.0354
-2 2 0 0.2734
0 -2 -5 0.0354
2 -2 0 0.3304
0 10 -1 0.0194
0 -10 1 0.0010
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C14 O5 H5 109.5 . . ?
O1 N1 C1 117.8(4) . . ?
O2 N1 O1 123.3(3) . . ?
O2 N1 C1 119.0(3) . . ?
O3 N2 O4 122.8(4) . . ?
O3 N2 C13 118.3(5) . . ?
O4 N2 C13 118.8(4) . . ?
C2 C1 N1 118.8(3) . . ?
C6 C1 N1 118.6(3) . . ?
C6 C1 C2 122.5(3) . . ?
C1 C2 H2 120.8 . . ?
C3 C2 C1 118.4(3) . . ?
C3 C2 H2 120.8 . . ?
C2 C3 H3 119.4 . . ?
C2 C3 C4 121.1(3) . . ?
C4 C3 H3 119.4 . . ?
C3 C4 C5 118.8(3) . . ?
C3 C4 C7 123.2(3) . . ?
C5 C4 C7 118.0(3) . . ?
C4 C5 H5A 119.6 . . ?
C6 C5 C4 120.9(3) . . ?
C6 C5 H5A 119.6 . . ?
C1 C6 C5 118.3(3) . . ?
C1 C6 H6 120.8 . . ?
C5 C6 H6 120.8 . . ?
C4 C7 H7 116.8 . . ?
C8 C7 C4 126.4(3) . . ?
C8 C7 H7 116.8 . . ?
C7 C8 H8 118.7 . . ?
C7 C8 C9 122.6(4) . . ?
C9 C8 H8 118.7 . . ?
C10 C9 C8 121.8(4) . . ?
C10 C9 C14 118.5(4) . . ?
C14 C9 C8 119.7(4) . . ?
C9 C10 H10 119.5 . . ?
C11 C10 C9 121.0(4) . . ?
C11 C10 H10 119.5 . . ?
C10 C11 Br1 119.2(3) . . ?
C12 C11 Br1 119.3(3) . . ?
C12 C11 C10 121.5(4) . . ?
C11 C12 H12 121.2 . . ?
C11 C12 C13 117.6(4) . . ?
C13 C12 H12 121.2 . . ?
C12 C13 N2 116.7(4) . . ?
C12 C13 C14 122.9(4) . . ?
C14 C13 N2 120.3(4) . . ?
O5 C14 C9 117.2(4) . . ?
O5 C14 C13 124.3(4) . . ?
C13 C14 C9 118.4(4) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Br1 C11 1.897(4) . ?
O1 N1 1.236(5) . ?
O2 N1 1.224(5) . ?
O3 N2 1.223(6) . ?
O4 N2 1.231(7) . ?
O5 H5 0.8200 . ?
O5 C14 1.345(6) . ?
N1 C1 1.463(4) . ?
N2 C13 1.458(6) . ?
C1 C2 1.390(5) . ?
C1 C6 1.385(6) . ?
C2 H2 0.9300 . ?
C2 C3 1.382(5) . ?
C3 H3 0.9300 . ?
C3 C4 1.400(5) . ?
C4 C5 1.406(4) . ?
C4 C7 1.460(5) . ?
C5 H5A 0.9300 . ?
C5 C6 1.388(5) . ?
C6 H6 0.9300 . ?
C7 H7 0.9300 . ?
C7 C8 1.342(5) . ?
C8 H8 0.9300 . ?
C8 C9 1.463(5) . ?
C9 C10 1.395(6) . ?
C9 C14 1.416(6) . ?
C10 H10 0.9300 . ?
C10 C11 1.395(5) . ?
C11 C12 1.377(6) . ?
C12 H12 0.9300 . ?
C12 C13 1.392(7) . ?
C13 C14 1.402(6) . ?
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
_geom_hbond_publ_flag
O5 H5 O4 0.82 1.87 2.571(5) 142.4 . yes
C3 H3 O3 0.93 2.53 3.221(5) 131.8 4_365 yes
C7 H7 O1 0.93 2.50 3.372(5) 156.1 2_664 yes
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Br1 C11 C12 C13 179.4(3) . . . . ?
O1 N1 C1 C2 179.9(4) . . . . ?
O1 N1 C1 C6 2.5(6) . . . . ?
O2 N1 C1 C2 1.1(6) . . . . ?
O2 N1 C1 C6 -176.4(4) . . . . ?
O3 N2 C13 C12 -5.0(6) . . . . ?
O3 N2 C13 C14 172.3(4) . . . . ?
O4 N2 C13 C12 176.1(5) . . . . ?
O4 N2 C13 C14 -6.6(7) . . . . ?
N1 C1 C2 C3 -177.8(3) . . . . ?
N1 C1 C6 C5 178.6(4) . . . . ?
N2 C13 C14 O5 2.5(7) . . . . ?
N2 C13 C14 C9 -175.9(4) . . . . ?
C1 C2 C3 C4 -0.5(6) . . . . ?
C2 C1 C6 C5 1.3(6) . . . . ?
C2 C3 C4 C5 0.6(6) . . . . ?
C2 C3 C4 C7 -179.2(4) . . . . ?
C3 C4 C5 C6 0.2(6) . . . . ?
C3 C4 C7 C8 4.2(7) . . . . ?
C4 C5 C6 C1 -1.1(6) . . . . ?
C4 C7 C8 C9 -179.0(4) . . . . ?
C5 C4 C7 C8 -175.6(4) . . . . ?
C6 C1 C2 C3 -0.5(6) . . . . ?
C7 C4 C5 C6 -180.0(4) . . . . ?
C7 C8 C9 C10 25.3(6) . . . . ?
C7 C8 C9 C14 -155.5(4) . . . . ?
C8 C9 C10 C11 -179.3(4) . . . . ?
C8 C9 C14 O5 0.3(6) . . . . ?
C8 C9 C14 C13 178.8(4) . . . . ?
C9 C10 C11 Br1 179.8(3) . . . . ?
C9 C10 C11 C12 -0.2(7) . . . . ?
C10 C9 C14 O5 179.5(4) . . . . ?
C10 C9 C14 C13 -2.0(6) . . . . ?
C10 C11 C12 C13 -0.6(7) . . . . ?
C11 C12 C13 N2 177.2(4) . . . . ?
C11 C12 C13 C14 0.0(7) . . . . ?
C12 C13 C14 O5 179.7(4) . . . . ?
C12 C13 C14 C9 1.3(6) . . . . ?
C14 C9 C10 C11 1.5(6) . . . . ?
loop_
_exptl_oxdiff_crystal_face_indexfrac_h
_exptl_oxdiff_crystal_face_indexfrac_k
_exptl_oxdiff_crystal_face_indexfrac_l
_exptl_oxdiff_crystal_face_x
_exptl_oxdiff_crystal_face_y
_exptl_oxdiff_crystal_face_z
-0.0005 1.9962 4.9997 -0.0161 0.5759 0.1446
-2.4997 1.5025 -0.0038 -0.0067 0.2064 -0.9910
0.0005 -1.9962 -4.9997 0.0161 -0.5759 -0.1446
2.4997 -1.5025 0.0038 0.0067 -0.2064 0.9910
-0.0015 10.0037 -1.0014 0.5820 0.0262 -0.0560
0.0015 -10.0037 1.0014 -0.5820 -0.0262 0.0560
