#------------------------------------------------------------------------------
#$Date: 2021-12-07 05:39:34 +0200 (Tue, 07 Dec 2021) $
#$Revision: 271191 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/06/09/7060974.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7060974
loop_
_publ_author_name
'Loganathan, Pushparaj'
'Pillai, Renjith S.'
'Jeevananthan, Velusamy'
'David, Ezhumalai'
'Palanisami, Nallasamy'
'Bhuvanesh, Nattamai S. P.'
'Shanmugan, Swaminathan'
_publ_section_title
;
 Assembly of discrete and oligomeric structures of organotin double-decker
 silsesquioxanes: inherent stability studies
;
_journal_issue                   43
_journal_name_full               'New Journal of Chemistry'
_journal_page_first              20144
_journal_page_last               20154
_journal_paper_doi               10.1039/D1NJ03128G
_journal_volume                  45
_journal_year                    2021
_chemical_formula_moiety         'C32 H38 O7 Si4 Sn'
_chemical_formula_sum            'C32 H38 O7 Si4 Sn'
_chemical_formula_weight         765.67
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2021-09-25 deposited with the CCDC.	2021-09-29 downloaded from the CCDC.
;
_cell_angle_alpha                115.770(7)
_cell_angle_beta                 102.852(7)
_cell_angle_gamma                101.735(5)
_cell_formula_units_Z            2
_cell_length_a                   11.0582(12)
_cell_length_b                   13.6018(11)
_cell_length_c                   14.649(2)
_cell_measurement_reflns_used    4224
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      56.147
_cell_measurement_theta_min      5.240
_cell_volume                     1818.0(4)
_computing_cell_refinement       'APEX2/SAINT (Bruker, 2004)'
_computing_data_collection       'APEX2 (Bruker, 2004)'
_computing_data_reduction        'SAINT/XPREP (Bruker, 2004)'
_computing_molecular_graphics
'ORTEP3 (Farrugia, 1997) and Mercury (Bruno et al., 2002)'
_computing_publication_material  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SIR92 (Altornare et al., 2014)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.987
_diffrn_measured_fraction_theta_max 0.987
_diffrn_measurement_device_type  'Bruker axs kappa apex2 CCD Diffractometer'
_diffrn_measurement_method       'ω and φ scan'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0353
_diffrn_reflns_av_unetI/netI     0.0626
_diffrn_reflns_Laue_measured_fraction_full 0.987
_diffrn_reflns_Laue_measured_fraction_max 0.987
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -9
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            11597
_diffrn_reflns_point_group_measured_fraction_full 0.987
_diffrn_reflns_point_group_measured_fraction_max 0.987
_diffrn_reflns_theta_full        24.997
_diffrn_reflns_theta_max         24.997
_diffrn_reflns_theta_min         2.103
_exptl_absorpt_coefficient_mu    0.877
_exptl_absorpt_correction_T_max  0.844
_exptl_absorpt_correction_T_min  0.621
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS V2012/1 (Bruker AXS Inc.)'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.399
_exptl_crystal_description       block
_exptl_crystal_F_000             784
_exptl_crystal_size_max          0.600
_exptl_crystal_size_mid          0.300
_exptl_crystal_size_min          0.200
_refine_diff_density_max         1.180
_refine_diff_density_min         -0.709
_refine_diff_density_rms         0.098
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.017
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     400
_refine_ls_number_reflns         6322
_refine_ls_number_restraints     184
_refine_ls_restrained_S_all      1.020
_refine_ls_R_factor_all          0.0666
_refine_ls_R_factor_gt           0.0460
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0876P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1188
_refine_ls_wR_factor_ref         0.1430
_reflns_Friedel_coverage         0.000
_reflns_number_gt                4914
_reflns_number_total             6322
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d1nj03128g2.cif
_cod_data_source_block           shelx
_cod_depositor_comments
'Adding full bibliography for 7060973--7060974.cif.'
_cod_database_code               7060974
_shelx_shelxl_version_number     2014/7
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.621
_shelx_estimated_absorpt_t_max   0.844
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
C29 C 0.0037(7) 0.5143(7) 0.3075(6) 0.072(2) Uani 1 1 d . U . . .
H29A H -0.0534 0.4608 0.2327 0.087 Uiso 1 1 calc R U . . .
H29B H -0.0445 0.5618 0.3428 0.087 Uiso 1 1 calc R U . . .
C1 C 0.3286(8) 0.3170(7) 0.7275(6) 0.081(2) Uani 1 1 d . U . . .
H1 H 0.2552 0.2894 0.6662 0.098 Uiso 1 1 calc R U . . .
C2 C 0.3183(11) 0.2825(8) 0.8030(9) 0.107(3) Uani 1 1 d . U . . .
H2 H 0.2378 0.2332 0.7917 0.129 Uiso 1 1 calc R U . . .
C3 C 0.4216(13) 0.3186(9) 0.8909(8) 0.109(3) Uani 1 1 d . U . . .
H3 H 0.4141 0.2933 0.9398 0.131 Uiso 1 1 calc R U . . .
C4 C 0.5354(12) 0.3910(8) 0.9079(7) 0.114(4) Uani 1 1 d . U . . .
H4 H 0.6070 0.4181 0.9703 0.137 Uiso 1 1 calc R U . . .
C5 C 0.5504(8) 0.4275(6) 0.8348(5) 0.075(2) Uani 1 1 d . U . . .
H5 H 0.6318 0.4770 0.8478 0.089 Uiso 1 1 calc R U . . .
C6 C 0.4436(6) 0.3900(4) 0.7419(4) 0.0447(13) Uani 1 1 d . U . . .
C7 C 0.3166(7) 0.6638(6) 0.8334(5) 0.0650(17) Uani 1 1 d . U . . .
H7 H 0.3040 0.5875 0.8170 0.078 Uiso 1 1 calc R U . . .
C8 C 0.3296(9) 0.7467(8) 0.9365(5) 0.090(2) Uani 1 1 d . U . . .
H8 H 0.3244 0.7252 0.9881 0.108 Uiso 1 1 calc R U . . .
C9 C 0.3499(8) 0.8581(7) 0.9622(6) 0.089(2) Uani 1 1 d . U . . .
H9 H 0.3575 0.9127 1.0312 0.107 Uiso 1 1 calc R U . . .
C10 C 0.3594(8) 0.8919(6) 0.8879(6) 0.078(2) Uani 1 1 d . U . . .
H10 H 0.3742 0.9690 0.9061 0.094 Uiso 1 1 calc R U . . .
C11 C 0.3466(6) 0.8091(5) 0.7850(5) 0.0554(15) Uani 1 1 d . U . . .
H11 H 0.3549 0.8321 0.7349 0.067 Uiso 1 1 calc R U . . .
C12 C 0.3219(5) 0.6933(5) 0.7546(4) 0.0437(12) Uani 1 1 d . U . . .
C13 C 0.4764(6) 0.1286(4) 0.3790(4) 0.0457(13) Uani 1 1 d . U . . .
C14 C 0.3766(8) 0.0356(5) 0.2911(5) 0.079(2) Uani 1 1 d . U . . .
H14 H 0.3072 0.0475 0.2530 0.095 Uiso 1 1 calc R U . . .
C15 C 0.3773(13) -0.0779(6) 0.2575(7) 0.117(4) Uani 1 1 d . U . . .
H15 H 0.3115 -0.1400 0.1949 0.141 Uiso 1 1 calc R U . . .
C30 C 0.1170(11) 0.5880(11) 0.3090(12) 0.164(5) Uani 1 1 d . U . . .
H30A H 0.1620 0.5398 0.2696 0.197 Uiso 1 1 calc R U . . .
H30B H 0.1767 0.6380 0.3835 0.197 Uiso 1 1 calc R U . . .
C16 C 0.4697(14) -0.0967(8) 0.3136(10) 0.119(4) Uani 1 1 d . U . . .
H16 H 0.4653 -0.1726 0.2937 0.143 Uiso 1 1 calc R U . . .
C17 C 0.5684(12) -0.0104(9) 0.3971(11) 0.143(4) Uani 1 1 d . U . . .
H17 H 0.6361 -0.0251 0.4338 0.171 Uiso 1 1 calc R U . . .
C18 C 0.5730(9) 0.1051(7) 0.4322(8) 0.116(4) Uani 1 1 d . U . . .
H18 H 0.6431 0.1658 0.4926 0.139 Uiso 1 1 calc R U . . .
C19 C 0.1947(6) 0.2459(4) 0.1418(4) 0.0461(13) Uani 1 1 d . U . . .
C20 C 0.2559(10) 0.1972(8) 0.0693(6) 0.103(3) Uani 1 1 d . U . . .
H20 H 0.3469 0.2150 0.0944 0.124 Uiso 1 1 calc R U . . .
C21 C 0.1836(12) 0.1217(9) -0.0406(7) 0.134(4) Uani 1 1 d . U . . .
H21 H 0.2250 0.0883 -0.0888 0.160 Uiso 1 1 calc R U . . .
C22 C 0.0478(12) 0.0977(10) -0.0763(7) 0.141(4) Uani 1 1 d . U . . .
H22 H -0.0023 0.0465 -0.1491 0.170 Uiso 1 1 calc R U . . .
C23 C -0.0106(11) 0.1462(12) -0.0089(7) 0.170(6) Uani 1 1 d . U . . .
H23 H -0.1007 0.1325 -0.0340 0.204 Uiso 1 1 calc R U . . .
C24 C 0.0627(9) 0.2172(10) 0.0988(6) 0.126(4) Uani 1 1 d . U . . .
H24 H 0.0187 0.2478 0.1457 0.151 Uiso 1 1 calc R U . . .
C25 C -0.0365(6) 0.2538(5) 0.3703(6) 0.0659(18) Uani 1 1 d . U . . .
H25A H -0.0887 0.2625 0.4168 0.079 Uiso 1 1 calc R U . . .
H25B H -0.0959 0.1995 0.2964 0.079 Uiso 1 1 calc R U . . .
C26 C 0.0617(8) 0.2024(7) 0.3992(8) 0.097(3) Uani 1 1 d . U . . .
H26A H 0.1262 0.2588 0.4707 0.116 Uiso 1 1 calc R U . . .
H26B H 0.1079 0.1855 0.3482 0.116 Uiso 1 1 calc R U . . .
C27 C -0.0008(10) 0.0910(7) 0.3987(8) 0.109(3) Uani 1 1 d . U . . .
H27A H -0.0719 0.0373 0.3300 0.130 Uiso 1 1 calc R U . . .
H27B H -0.0383 0.1091 0.4555 0.130 Uiso 1 1 calc R U . . .
C28 C 0.0989(14) 0.0339(12) 0.4161(11) 0.186(6) Uani 1 1 d . U . . .
H28A H 0.1375 0.0174 0.3609 0.278 Uiso 1 1 calc R U . . .
H28B H 0.0559 -0.0372 0.4125 0.278 Uiso 1 1 calc R U . . .
H28C H 0.1668 0.0852 0.4860 0.278 Uiso 1 1 calc R U . . .
O1 O 0.3680(4) 0.2775(3) 0.3324(3) 0.0454(9) Uani 1 1 d . . . . .
O2 O 0.6237(3) 0.3550(3) 0.4365(3) 0.0389(8) Uani 1 1 d . . . . .
O3 O 0.4643(4) 0.3360(3) 0.5386(3) 0.0428(8) Uani 1 1 d . . . . .
O4 O 0.5947(4) 0.5486(3) 0.7034(3) 0.0458(9) Uani 1 1 d . . . . .
O5 O 0.3369(3) 0.4764(3) 0.6121(3) 0.0414(8) Uani 1 1 d . . . . .
O6 O 0.1382(3) 0.5339(3) 0.5429(2) 0.0352(7) Uani 1 1 d . . . . .
O7 O 0.2069(4) 0.3971(3) 0.3549(3) 0.0504(9) Uani 1 1 d . . . . .
Si1 Si 0.46186(13) 0.43988(11) 0.64589(10) 0.0320(3) Uani 1 1 d . . . . .
Si2 Si 0.48244(13) 0.27947(10) 0.42303(10) 0.0319(3) Uani 1 1 d . . . . .
Si3 Si 0.29281(13) 0.34715(11) 0.28755(10) 0.0323(3) Uani 1 1 d . . . . .
Si4 Si 0.29252(12) 0.58303(11) 0.61297(10) 0.0314(3) Uani 1 1 d . . . . .
Sn1 Sn 0.04248(3) 0.41628(3) 0.38326(3) 0.03636(14) Uani 1 1 d . . . . .
C31 C 0.0903(15) 0.6651(13) 0.2605(14) 0.216(7) Uani 1 1 d D U . . .
H31A H 0.0453 0.7134 0.2997 0.260 Uiso 1 1 calc R U . . .
H31B H 0.1743 0.7163 0.2721 0.260 Uiso 1 1 calc R U . . .
C32 C 0.015(2) 0.6049(18) 0.1501(15) 0.359(16) Uani 1 1 d D U . . .
H32A H -0.0299 0.5255 0.1277 0.539 Uiso 1 1 calc R U . . .
H32B H 0.0718 0.6076 0.1097 0.539 Uiso 1 1 calc R U . . .
H32C H -0.0487 0.6403 0.1371 0.539 Uiso 1 1 calc R U . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sn Sn -0.6537 1.4246 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C30 C29 Sn1 115.6(6) . . ?
C30 C29 H29A 108.4 . . ?
Sn1 C29 H29A 108.4 . . ?
C30 C29 H29B 108.4 . . ?
Sn1 C29 H29B 108.4 . . ?
H29A C29 H29B 107.4 . . ?
C6 C1 C2 121.1(8) . . ?
C6 C1 H1 119.4 . . ?
C2 C1 H1 119.4 . . ?
C3 C2 C1 121.3(9) . . ?
C3 C2 H2 119.4 . . ?
C1 C2 H2 119.4 . . ?
C4 C3 C2 119.1(8) . . ?
C4 C3 H3 120.5 . . ?
C2 C3 H3 120.5 . . ?
C3 C4 C5 121.7(9) . . ?
C3 C4 H4 119.2 . . ?
C5 C4 H4 119.2 . . ?
C4 C5 C6 120.1(8) . . ?
C4 C5 H5 120.0 . . ?
C6 C5 H5 120.0 . . ?
C1 C6 C5 116.8(6) . . ?
C1 C6 Si1 122.9(5) . . ?
C5 C6 Si1 120.3(5) . . ?
C12 C7 C8 120.9(7) . . ?
C12 C7 H7 119.5 . . ?
C8 C7 H7 119.5 . . ?
C9 C8 C7 120.4(7) . . ?
C9 C8 H8 119.8 . . ?
C7 C8 H8 119.8 . . ?
C8 C9 C10 120.8(7) . . ?
C8 C9 H9 119.6 . . ?
C10 C9 H9 119.6 . . ?
C9 C10 C11 118.8(7) . . ?
C9 C10 H10 120.6 . . ?
C11 C10 H10 120.6 . . ?
C12 C11 C10 122.1(6) . . ?
C12 C11 H11 119.0 . . ?
C10 C11 H11 119.0 . . ?
C11 C12 C7 117.0(5) . . ?
C11 C12 Si4 120.8(4) . . ?
C7 C12 Si4 122.2(4) . . ?
C18 C13 C14 116.7(6) . . ?
C18 C13 Si2 121.2(5) . . ?
C14 C13 Si2 122.2(5) . . ?
C13 C14 C15 120.7(8) . . ?
C13 C14 H14 119.6 . . ?
C15 C14 H14 119.6 . . ?
C16 C15 C14 120.5(9) . . ?
C16 C15 H15 119.8 . . ?
C14 C15 H15 119.8 . . ?
C29 C30 C31 115.9(10) . . ?
C29 C30 H30A 108.3 . . ?
C31 C30 H30A 108.3 . . ?
C29 C30 H30B 108.3 . . ?
C31 C30 H30B 108.3 . . ?
H30A C30 H30B 107.4 . . ?
C15 C16 C17 120.8(8) . . ?
C15 C16 H16 119.6 . . ?
C17 C16 H16 119.6 . . ?
C16 C17 C18 120.5(10) . . ?
C16 C17 H17 119.8 . . ?
C18 C17 H17 119.8 . . ?
C13 C18 C17 120.7(9) . . ?
C13 C18 H18 119.6 . . ?
C17 C18 H18 119.6 . . ?
C24 C19 C20 115.8(6) . . ?
C24 C19 Si3 123.6(5) . . ?
C20 C19 Si3 120.5(5) . . ?
C19 C20 C21 121.1(9) . . ?
C19 C20 H20 119.4 . . ?
C21 C20 H20 119.4 . . ?
C22 C21 C20 118.3(9) . . ?
C22 C21 H21 120.9 . . ?
C20 C21 H21 120.9 . . ?
C23 C22 C21 121.0(8) . . ?
C23 C22 H22 119.5 . . ?
C21 C22 H22 119.5 . . ?
C22 C23 C24 119.1(10) . . ?
C22 C23 H23 120.4 . . ?
C24 C23 H23 120.4 . . ?
C19 C24 C23 124.5(9) . . ?
C19 C24 H24 117.8 . . ?
C23 C24 H24 117.8 . . ?
C26 C25 Sn1 115.6(5) . . ?
C26 C25 H25A 108.4 . . ?
Sn1 C25 H25A 108.4 . . ?
C26 C25 H25B 108.4 . . ?
Sn1 C25 H25B 108.4 . . ?
H25A C25 H25B 107.4 . . ?
C25 C26 C27 113.0(7) . . ?
C25 C26 H26A 109.0 . . ?
C27 C26 H26A 109.0 . . ?
C25 C26 H26B 109.0 . . ?
C27 C26 H26B 109.0 . . ?
H26A C26 H26B 107.8 . . ?
C26 C27 C28 111.6(9) . . ?
C26 C27 H27A 109.3 . . ?
C28 C27 H27A 109.3 . . ?
C26 C27 H27B 109.3 . . ?
C28 C27 H27B 109.3 . . ?
H27A C27 H27B 108.0 . . ?
C27 C28 H28A 109.5 . . ?
C27 C28 H28B 109.5 . . ?
H28A C28 H28B 109.5 . . ?
C27 C28 H28C 109.5 . . ?
H28A C28 H28C 109.5 . . ?
H28B C28 H28C 109.5 . . ?
Si2 O1 Si3 149.6(2) . . ?
Si2 O2 Si4 147.1(2) . 2_666 ?
Si1 O3 Si2 154.7(2) . . ?
Si1 O4 Si3 156.0(2) . 2_666 ?
Si1 O5 Si4 144.1(2) . . ?
Si4 O6 Sn1 129.18(19) . . ?
Si4 O6 Sn1 125.64(17) . 2_566 ?
Sn1 O6 Sn1 105.12(13) . 2_566 ?
Si3 O7 Sn1 157.2(2) . . ?
O4 Si1 O3 111.2(2) . . ?
O4 Si1 O5 110.28(19) . . ?
O3 Si1 O5 108.22(19) . . ?
O4 Si1 C6 108.5(2) . . ?
O3 Si1 C6 109.6(2) . . ?
O5 Si1 C6 109.0(2) . . ?
O1 Si2 O2 110.04(19) . . ?
O1 Si2 O3 111.3(2) . . ?
O2 Si2 O3 107.97(19) . . ?
O1 Si2 C13 108.2(2) . . ?
O2 Si2 C13 109.4(2) . . ?
O3 Si2 C13 109.8(2) . . ?
O7 Si3 O4 110.3(2) . 2_666 ?
O7 Si3 O1 111.2(2) . . ?
O4 Si3 O1 107.25(19) 2_666 . ?
O7 Si3 C19 112.7(2) . . ?
O4 Si3 C19 107.5(2) 2_666 . ?
O1 Si3 C19 107.6(2) . . ?
O6 Si4 O2 109.90(18) . 2_666 ?
O6 Si4 O5 108.76(18) . . ?
O2 Si4 O5 111.08(19) 2_666 . ?
O6 Si4 C12 109.4(2) . . ?
O2 Si4 C12 108.3(2) 2_666 . ?
O5 Si4 C12 109.5(2) . . ?
O7 Sn1 O6 94.18(14) . . ?
O7 Sn1 C25 98.0(2) . . ?
O6 Sn1 C25 107.2(2) . . ?
O7 Sn1 C29 98.9(2) . . ?
O6 Sn1 C29 105.7(2) . . ?
C25 Sn1 C29 141.5(3) . . ?
O7 Sn1 O6 169.05(13) . 2_566 ?
O6 Sn1 O6 74.88(13) . 2_566 ?
C25 Sn1 O6 84.82(19) . 2_566 ?
C29 Sn1 O6 85.0(2) . 2_566 ?
C32 C31 C30 115.1(15) . . ?
C32 C31 H31A 108.5 . . ?
C30 C31 H31A 108.5 . . ?
C32 C31 H31B 108.5 . . ?
C30 C31 H31B 108.5 . . ?
H31A C31 H31B 107.5 . . ?
C31 C32 H32A 109.5 . . ?
C31 C32 H32B 109.5 . . ?
H32A C32 H32B 109.5 . . ?
C31 C32 H32C 109.5 . . ?
H32A C32 H32C 109.5 . . ?
H32B C32 H32C 109.5 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C29 C30 1.427(11) . ?
C29 Sn1 2.121(6) . ?
C29 H29A 0.9700 . ?
C29 H29B 0.9700 . ?
C1 C6 1.354(9) . ?
C1 C2 1.393(10) . ?
C1 H1 0.9300 . ?
C2 C3 1.332(13) . ?
C2 H2 0.9300 . ?
C3 C4 1.326(14) . ?
C3 H3 0.9300 . ?
C4 C5 1.389(10) . ?
C4 H4 0.9300 . ?
C5 C6 1.394(8) . ?
C5 H5 0.9300 . ?
C6 Si1 1.838(5) . ?
C7 C12 1.385(8) . ?
C7 C8 1.389(9) . ?
C7 H7 0.9300 . ?
C8 C9 1.348(10) . ?
C8 H8 0.9300 . ?
C9 C10 1.367(10) . ?
C9 H9 0.9300 . ?
C10 C11 1.388(8) . ?
C10 H10 0.9300 . ?
C11 C12 1.384(7) . ?
C11 H11 0.9300 . ?
C12 Si4 1.859(5) . ?
C13 C18 1.355(9) . ?
C13 C14 1.364(8) . ?
C13 Si2 1.846(5) . ?
C14 C15 1.404(10) . ?
C14 H14 0.9300 . ?
C15 C16 1.304(13) . ?
C15 H15 0.9300 . ?
C30 C31 1.540(13) . ?
C30 H30A 0.9700 . ?
C30 H30B 0.9700 . ?
C16 C17 1.305(14) . ?
C16 H16 0.9300 . ?
C17 C18 1.410(11) . ?
C17 H17 0.9300 . ?
C18 H18 0.9300 . ?
C19 C24 1.351(10) . ?
C19 C20 1.384(10) . ?
C19 Si3 1.854(5) . ?
C20 C21 1.393(11) . ?
C20 H20 0.9300 . ?
C21 C22 1.393(15) . ?
C21 H21 0.9300 . ?
C22 C23 1.310(14) . ?
C22 H22 0.9300 . ?
C23 C24 1.366(11) . ?
C23 H23 0.9300 . ?
C24 H24 0.9300 . ?
C25 C26 1.487(9) . ?
C25 Sn1 2.112(6) . ?
C25 H25A 0.9700 . ?
C25 H25B 0.9700 . ?
C26 C27 1.529(10) . ?
C26 H26A 0.9700 . ?
C26 H26B 0.9700 . ?
C27 C28 1.510(13) . ?
C27 H27A 0.9700 . ?
C27 H27B 0.9700 . ?
C28 H28A 0.9600 . ?
C28 H28B 0.9600 . ?
C28 H28C 0.9600 . ?
O1 Si2 1.604(3) . ?
O1 Si3 1.625(3) . ?
O2 Si2 1.603(4) . ?
O2 Si4 1.613(3) 2_666 ?
O3 Si1 1.603(3) . ?
O3 Si2 1.607(4) . ?
O4 Si1 1.593(4) . ?
O4 Si3 1.619(4) 2_666 ?
O5 Si1 1.610(3) . ?
O5 Si4 1.619(3) . ?
O6 Si4 1.604(3) . ?
O6 Sn1 2.026(3) . ?
O6 Sn1 2.549(3) 2_566 ?
O7 Si3 1.560(4) . ?
O7 Sn1 1.995(4) . ?
Si3 O4 1.619(4) 2_666 ?
Si4 O2 1.613(3) 2_666 ?
Sn1 O6 2.549(3) 2_566 ?
C31 C32 1.397(16) . ?
C31 H31A 0.9700 . ?
C31 H31B 0.9700 . ?
C32 H32A 0.9600 . ?
C32 H32B 0.9600 . ?
C32 H32C 0.9600 . ?
