#------------------------------------------------------------------------------
#$Date: 2022-03-05 00:20:47 +0200 (Sat, 05 Mar 2022) $
#$Revision: 273399 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/06/12/7061245.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7061245
loop_
_publ_author_name
'Yamada, Shigeyuki'
'Sato, Masaya'
'Uto, Eiji'
'Kataoka, Mitsuki'
'Morita, Masato'
'Konno, Tsutomu'
_publ_section_title
;
 Fluorinated tolane-based fluorophores bearing a branched flexible unit
 with aggregation-induced emission enhancement characteristics
;
_journal_issue                   7
_journal_name_full               'New Journal of Chemistry'
_journal_page_first              3392
_journal_page_last               3400
_journal_paper_doi               10.1039/D1NJ05822C
_journal_volume                  46
_journal_year                    2022
_chemical_formula_moiety         'C19 H11 F4 N O2'
_chemical_formula_sum            'C19 H11 F4 N O2'
_chemical_formula_weight         361.29
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2yn'
_space_group_name_H-M_alt        'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_audit_creation_date             2020-10-18
_audit_creation_method
;
Olex2 1.3
(compiled 2020.07.31 svn.rc2a77460 for OlexSys, GUI svn.r6145)
;
_audit_update_record
;
2021-10-29 deposited with the CCDC.	2022-01-25 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 97.582(5)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   6.1206(3)
_cell_length_b                   22.0913(10)
_cell_length_c                   11.8054(6)
_cell_measurement_reflns_used    5779
_cell_measurement_temperature    298
_cell_measurement_theta_max      27.2160
_cell_measurement_theta_min      2.7690
_cell_volume                     1582.28(13)
_computing_cell_refinement       'CrysAlisPro 1.171.39.43a (Rigaku OD, 2018)'
_computing_data_collection       'CrysAlisPro 1.171.39.43a (Rigaku OD, 2018)'
_computing_data_reduction        'CrysAlisPro 1.171.39.43a (Rigaku OD, 2018)'
_computing_molecular_graphics    'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.3 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2018/3 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT 2018/2 (Sheldrick, 2018)'
_diffrn_ambient_temperature      298
_diffrn_detector                 'CCD plate'
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_details
;
List of Runs (angles in degrees, time in seconds):

  # Type    Start    End  Width  tₑₓₚ   ω     θ     κ     φ   Frames
#--------------------------------------------------------------------------
  1  ω      9.00  35.00   0.25    0.93    --    5.00  57.00  90.00  104
  2  ω     41.00  71.00   0.25    0.93    --    5.00  57.00  90.00  120
  3  ω    -50.00  24.00   0.25    0.93    --  -11.80  76.00 150.00  296
  4  ω     29.00  76.00   0.25    0.93    --  -11.80  76.00 150.00  188
  5  ω     -5.00  74.00   0.25    0.93    --  -11.80  76.00-120.00  316
  6  ω    -53.00  -9.00   0.25    0.93    --  -11.80  76.00-120.00  176
;
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'XtaLAB AFC11 (RINC): Kappa single'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_type
'CrysAlisPro convention (1999,Acta A55,543-557)'
_diffrn_orient_matrix_UB_11      -0.0013850000
_diffrn_orient_matrix_UB_12      -0.0309209000
_diffrn_orient_matrix_UB_13      -0.0162152000
_diffrn_orient_matrix_UB_21      -0.0054687000
_diffrn_orient_matrix_UB_22      -0.0086081000
_diffrn_orient_matrix_UB_23      0.0574374000
_diffrn_orient_matrix_UB_31      -0.1168073000
_diffrn_orient_matrix_UB_32      0.0007999000
_diffrn_orient_matrix_UB_33      -0.0104356000
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0197
_diffrn_reflns_av_unetI/netI     0.0218
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.996
_diffrn_reflns_limit_h_max       7
_diffrn_reflns_limit_h_min       -7
_diffrn_reflns_limit_k_max       28
_diffrn_reflns_limit_k_min       -24
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_number            12912
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.996
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.485
_diffrn_reflns_theta_min         1.969
_diffrn_source                   'Rotating-anode X-ray tube'
_diffrn_source_type              'Rigaku (Mo) X-ray Source'
_exptl_absorpt_coefficient_mu    0.130
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.83662
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlisPro 1.171.39.43a (Rigaku Oxford Diffraction, 2018)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            colourless
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.517
_exptl_crystal_description       block
_exptl_crystal_F_000             736
_exptl_crystal_size_max          0.522
_exptl_crystal_size_mid          0.341
_exptl_crystal_size_min          0.197
_refine_diff_density_max         0.432
_refine_diff_density_min         -0.346
_refine_diff_density_rms         0.040
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.101
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     235
_refine_ls_number_reflns         3607
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.101
_refine_ls_R_factor_all          0.0628
_refine_ls_R_factor_gt           0.0485
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0736P)²+0.2798P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1406
_refine_ls_wR_factor_ref         0.1503
_reflns_Friedel_coverage         0.000
_reflns_number_gt                2663
_reflns_number_total             3607
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d1nj05822c2.cif
_cod_data_source_block           rac-cn
_cod_depositor_comments
'Adding full bibliography for 7061242--7061245.cif.'
_cod_database_code               7061245
_shelx_shelxl_version_number     2018/3
_chemical_oxdiff_formula         C19H11F4NO2
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_reflns_odcompleteness_completeness 99.60
_reflns_odcompleteness_iscentric 1
_reflns_odcompleteness_theta     27.42
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
2.a Ternary CH refined with riding coordinates:
 C00N(H00N)
2.b Secondary CH2 refined with riding coordinates:
 C00O(H00A,H00B), C00P(H00C,H00D), C00Q(H00F,H00H)
2.c Aromatic/amide H refined with riding coordinates:
 C00E(H00E), C00G(H00G), C00I(H00I), C00K(H00K)
;
_olex2_submission_special_instructions 'No special instructions were received'
_oxdiff_exptl_absorpt_empirical_details
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
;
_oxdiff_exptl_absorpt_empirical_full_max 1.336
_oxdiff_exptl_absorpt_empirical_full_min 0.636
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
F001 F 0.40864(18) 0.36512(5) 0.36843(10) 0.0659(3) Uani 1 1 d . . . . .
F002 F 1.22069(18) 0.28400(5) 0.53573(11) 0.0676(3) Uani 1 1 d . . . . .
F003 F 1.0130(2) 0.36077(5) 0.65928(10) 0.0686(3) Uani 1 1 d . . . . .
F004 F 0.6201(2) 0.28911(5) 0.24398(10) 0.0703(3) Uani 1 1 d . . . . .
O7 O -0.0155(2) 0.60704(6) 0.83883(11) 0.0627(4) Uani 1 1 d . . . . .
O006 O -0.2838(3) 0.65093(9) 1.01584(17) 0.0926(6) Uani 1 1 d . . . . .
C007 C 0.7055(3) 0.36625(7) 0.51675(14) 0.0472(4) Uani 1 1 d . . . . .
C008 C 0.3788(3) 0.48732(7) 0.68803(14) 0.0465(4) Uani 1 1 d . . . . .
C009 C 0.1246(3) 0.56834(7) 0.79492(14) 0.0474(4) Uani 1 1 d . . . . .
C00A C 0.9253(3) 0.28531(7) 0.38696(15) 0.0483(4) Uani 1 1 d . . . . .
C00B C 0.6098(3) 0.34606(7) 0.41019(15) 0.0479(4) Uani 1 1 d . . . . .
C00C C 0.7173(3) 0.30687(7) 0.34643(14) 0.0482(4) Uani 1 1 d . . . . .
C00D C 1.0209(3) 0.30425(7) 0.49383(16) 0.0487(4) Uani 1 1 d . . . . .
C00E C 0.1594(3) 0.49801(8) 0.64503(14) 0.0496(4) Uani 1 1 d . . . . .
H00E H 0.096914 0.477646 0.579733 0.059 Uiso 1 1 calc R U . . .
C00F C 0.9137(3) 0.34359(7) 0.55754(15) 0.0486(4) Uani 1 1 d . . . . .
C00G C 0.0339(3) 0.53798(8) 0.69719(14) 0.0496(4) Uani 1 1 d . . . . .
H00G H -0.112232 0.544763 0.667054 0.060 Uiso 1 1 calc R U . . .
C10 C 0.5036(3) 0.44484(8) 0.63147(16) 0.0523(4) Uani 1 1 d . . . . .
C00I C 0.4685(3) 0.51858(8) 0.78490(17) 0.0558(4) Uani 1 1 d . . . . .
H00I H 0.615309 0.512304 0.814268 0.067 Uiso 1 1 calc R U . . .
C00J C 0.5971(3) 0.40874(8) 0.58095(16) 0.0542(4) Uani 1 1 d . . . . .
C00K C 0.3434(3) 0.55893(8) 0.83865(17) 0.0574(5) Uani 1 1 d . . . . .
H00K H 0.405645 0.579602 0.903635 0.069 Uiso 1 1 calc R U . . .
C00L C 1.0401(3) 0.24460(9) 0.32104(17) 0.0612(5) Uani 1 1 d . . . . .
N00M N 1.1356(4) 0.21331(9) 0.26930(19) 0.0888(6) Uani 1 1 d . . . . .
C00N C 0.0530(4) 0.63681(8) 0.94500(18) 0.0627(5) Uani 1 1 d . . . . .
H00N H 0.195999 0.656833 0.945611 0.075 Uiso 1 1 calc R U . . .
C00O C -0.1276(4) 0.68134(10) 0.9609(2) 0.0811(7) Uani 1 1 d . . . . .
H00A H -0.067659 0.715384 1.006743 0.097 Uiso 1 1 calc R U . . .
H00B H -0.194988 0.696478 0.887348 0.097 Uiso 1 1 calc R U . . .
C00P C 0.0509(5) 0.59461(11) 1.04555(19) 0.0821(7) Uani 1 1 d . . . . .
H00C H 0.085241 0.553466 1.025265 0.099 Uiso 1 1 calc R U . . .
H00D H 0.155860 0.607534 1.109815 0.099 Uiso 1 1 calc R U . . .
C00Q C -0.1771(5) 0.59923(19) 1.0723(2) 0.1169(12) Uani 1 1 d . . . . .
H00F H -0.257970 0.562795 1.047404 0.140 Uiso 1 1 calc R U . . .
H00H H -0.175903 0.603084 1.154269 0.140 Uiso 1 1 calc R U . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_exptl_crystal_face_index_h
_exptl_crystal_face_index_k
_exptl_crystal_face_index_l
_exptl_crystal_face_perp_dist
-9 1 0 0.2716
0 -2 17 0.1648
9 0 -2 0.2239
0 2 -16 0.1692
-8 0 -1 0.2716
0 -31 -1 0.0945
0 31 1 0.0945
0 -26 9 0.1521
0 26 -9 0.1428
0 14 -15 0.1455
0 -14 15 0.1593
-1 17 14 0.1277
0 -17 -14 0.1570
0 19 13 0.1243
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C009 O7 C00N 119.76(15) . . ?
C00O O006 C00Q 107.5(2) . . ?
C00B C007 C00F 117.04(15) . . ?
C00B C007 C00J 121.53(16) . . ?
C00F C007 C00J 121.43(16) . . ?
C00E C008 C10 119.36(16) . . ?
C00I C008 C00E 118.31(15) . . ?
C00I C008 C10 122.33(16) . . ?
O7 C009 C00G 114.67(15) . . ?
O7 C009 C00K 125.38(16) . . ?
C00G C009 C00K 119.94(15) . . ?
C00C C00A C00L 121.52(17) . . ?
C00D C00A C00C 118.04(15) . . ?
C00D C00A C00L 120.44(17) . . ?
F001 C00B C007 119.49(15) . . ?
F001 C00B C00C 118.90(16) . . ?
C00C C00B C007 121.61(16) . . ?
F004 C00C C00A 119.47(15) . . ?
F004 C00C C00B 119.62(16) . . ?
C00B C00C C00A 120.91(16) . . ?
F002 C00D C00A 119.55(15) . . ?
F002 C00D C00F 119.37(17) . . ?
C00F C00D C00A 121.07(16) . . ?
C008 C00E H00E 119.4 . . ?
C00G C00E C008 121.14(15) . . ?
C00G C00E H00E 119.4 . . ?
F003 C00F C007 119.89(15) . . ?
F003 C00F C00D 118.80(16) . . ?
C00D C00F C007 121.30(16) . . ?
C009 C00G H00G 120.0 . . ?
C00E C00G C009 119.98(16) . . ?
C00E C00G H00G 120.0 . . ?
C00J C10 C008 176.5(2) . . ?
C008 C00I H00I 119.4 . . ?
C00K C00I C008 121.15(17) . . ?
C00K C00I H00I 119.4 . . ?
C10 C00J C007 178.0(2) . . ?
C009 C00K H00K 120.3 . . ?
C00I C00K C009 119.47(17) . . ?
C00I C00K H00K 120.3 . . ?
N00M C00L C00A 178.2(2) . . ?
O7 C00N H00N 111.9 . . ?
O7 C00N C00O 105.90(19) . . ?
O7 C00N C00P 111.93(16) . . ?
C00O C00N H00N 111.9 . . ?
C00O C00N C00P 102.85(19) . . ?
C00P C00N H00N 111.9 . . ?
O006 C00O C00N 107.54(18) . . ?
O006 C00O H00A 110.2 . . ?
O006 C00O H00B 110.2 . . ?
C00N C00O H00A 110.2 . . ?
C00N C00O H00B 110.2 . . ?
H00A C00O H00B 108.5 . . ?
C00N C00P H00C 111.1 . . ?
C00N C00P H00D 111.1 . . ?
H00C C00P H00D 109.0 . . ?
C00Q C00P C00N 103.4(2) . . ?
C00Q C00P H00C 111.1 . . ?
C00Q C00P H00D 111.1 . . ?
O006 C00Q C00P 109.9(2) . . ?
O006 C00Q H00F 109.7 . . ?
O006 C00Q H00H 109.7 . . ?
C00P C00Q H00F 109.7 . . ?
C00P C00Q H00H 109.7 . . ?
H00F C00Q H00H 108.2 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
F001 C00B 1.3327(19) . ?
F002 C00D 1.334(2) . ?
F003 C00F 1.328(2) . ?
F004 C00C 1.335(2) . ?
O7 C009 1.361(2) . ?
O7 C00N 1.429(2) . ?
O006 C00O 1.396(3) . ?
O006 C00Q 1.435(4) . ?
C007 C00B 1.389(2) . ?
C007 C00F 1.394(2) . ?
C007 C00J 1.424(2) . ?
C008 C00E 1.392(2) . ?
C008 C10 1.430(2) . ?
C008 C00I 1.386(3) . ?
C009 C00G 1.386(2) . ?
C009 C00K 1.386(3) . ?
C00A C00C 1.384(3) . ?
C00A C00D 1.384(3) . ?
C00A C00L 1.433(2) . ?
C00B C00C 1.371(2) . ?
C00D C00F 1.372(2) . ?
C00E H00E 0.9300 . ?
C00E C00G 1.369(2) . ?
C00G H00G 0.9300 . ?
C10 C00J 1.187(2) . ?
C00I H00I 0.9300 . ?
C00I C00K 1.383(2) . ?
C00K H00K 0.9300 . ?
C00L N00M 1.134(2) . ?
C00N H00N 0.9800 . ?
C00N C00O 1.510(3) . ?
C00N C00P 1.511(3) . ?
C00O H00A 0.9700 . ?
C00O H00B 0.9700 . ?
C00P H00C 0.9700 . ?
C00P H00D 0.9700 . ?
C00P C00Q 1.475(4) . ?
C00Q H00F 0.9700 . ?
C00Q H00H 0.9700 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
F001 C00B C00C F004 0.6(2) . . . . ?
F001 C00B C00C C00A -179.20(14) . . . . ?
F002 C00D C00F F003 0.4(2) . . . . ?
F002 C00D C00F C007 179.49(14) . . . . ?
O7 C009 C00G C00E 179.75(15) . . . . ?
O7 C009 C00K C00I -179.40(17) . . . . ?
O7 C00N C00O O006 87.7(2) . . . . ?
O7 C00N C00P C00Q -87.3(3) . . . . ?
C007 C00B C00C F004 -179.33(14) . . . . ?
C007 C00B C00C C00A 0.8(2) . . . . ?
C008 C00E C00G C009 -0.4(3) . . . . ?
C008 C00I C00K C009 0.0(3) . . . . ?
C009 O7 C00N C00O 173.23(15) . . . . ?
C009 O7 C00N C00P -75.4(2) . . . . ?
C00A C00D C00F F003 -179.52(14) . . . . ?
C00A C00D C00F C007 -0.5(3) . . . . ?
C00B C007 C00F F003 -179.43(14) . . . . ?
C00B C007 C00F C00D 1.5(2) . . . . ?
C00C C00A C00D F002 179.57(14) . . . . ?
C00C C00A C00D C00F -0.5(2) . . . . ?
C00D C00A C00C F004 -179.55(14) . . . . ?
C00D C00A C00C C00B 0.3(2) . . . . ?
C00E C008 C00I C00K 0.7(3) . . . . ?
C00F C007 C00B F001 178.32(14) . . . . ?
C00F C007 C00B C00C -1.7(2) . . . . ?
C00G C009 C00K C00I -0.8(3) . . . . ?
C10 C008 C00E C00G 179.51(16) . . . . ?
C10 C008 C00I C00K -179.30(17) . . . . ?
C00I C008 C00E C00G -0.5(2) . . . . ?
C00J C007 C00B F001 -2.4(2) . . . . ?
C00J C007 C00B C00C 177.57(15) . . . . ?
C00J C007 C00F F003 1.3(2) . . . . ?
C00J C007 C00F C00D -177.75(16) . . . . ?
C00K C009 C00G C00E 1.1(3) . . . . ?
C00L C00A C00C F004 0.5(2) . . . . ?
C00L C00A C00C C00B -179.67(16) . . . . ?
C00L C00A C00D F002 -0.5(2) . . . . ?
C00L C00A C00D C00F 179.49(16) . . . . ?
C00N O7 C009 C00G 174.42(15) . . . . ?
C00N O7 C009 C00K -7.0(3) . . . . ?
C00N C00P C00Q O006 -14.7(3) . . . . ?
C00O O006 C00Q C00P -3.9(3) . . . . ?
C00O C00N C00P C00Q 26.0(3) . . . . ?
C00P C00N C00O O006 -29.9(3) . . . . ?
C00Q O006 C00O C00N 21.3(3) . . . . ?
loop_
_exptl_oxdiff_crystal_face_indexfrac_h
_exptl_oxdiff_crystal_face_indexfrac_k
_exptl_oxdiff_crystal_face_indexfrac_l
_exptl_oxdiff_crystal_face_x
_exptl_oxdiff_crystal_face_y
_exptl_oxdiff_crystal_face_z
-8.5320 0.6929 -0.2359 -0.0058 0.0271 0.9996
-0.4006 -1.9620 16.5548 -0.2072 0.9699 -0.1275
8.6245 -0.4059 -2.2075 0.0364 -0.1705 -0.9847
-0.0350 1.9847 -16.4617 0.2056 -0.9624 0.1775
-8.4924 -0.2623 -0.7391 0.0319 0.0062 0.9995
-0.1264 -31.0798 -1.0325 0.9779 0.2089 0.0007
-0.1432 31.0885 1.0097 -0.9775 -0.2088 0.0311
0.0000 -26.0000 9.0000 0.6580 0.7407 -0.1147
-0.0000 26.0000 -9.0000 -0.6580 -0.7407 0.1147
-0.0000 14.0000 -15.0000 -0.1897 -0.9821 0.1677
0.0000 -14.0000 15.0000 0.1897 0.9821 -0.1677
-1.0000 17.0000 14.0000 -0.7513 0.6633 -0.0157
0.0000 -17.0000 -14.0000 0.7527 -0.6578 0.1325
-0.0000 19.0000 13.0000 -0.7983 0.5831 -0.1205
