#------------------------------------------------------------------------------
#$Date: 2022-11-07 07:45:58 +0200 (Mon, 07 Nov 2022) $
#$Revision: 279025 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/06/18/7061852.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7061852
loop_
_publ_author_name
'Dkhar, Lincoln'
'Gupta, Hrishikesh'
'Poluri, Krishna Mohan'
'Gannon, Paige M.'
'Kaminsky, Werner'
'Kollipara, Mohan Rao'
_publ_section_title
;
 Influence of counterions on the formation of supramolecular platinum
 group metal complexes containing pyridyl thioamide derivatives:
 antioxidant and antimicrobial studies
;
_journal_issue                   40
_journal_name_full               'New Journal of Chemistry'
_journal_page_first              19241
_journal_page_last               19253
_journal_paper_doi               10.1039/D2NJ03108F
_journal_volume                  46
_journal_year                    2022
_chemical_formula_moiety         'C21 H28 Cl2 N2 Ru S'
_chemical_formula_sum            'C21 H28 Cl2 N2 Ru S'
_chemical_formula_weight         512.48
_space_group_IT_number           14
_space_group_name_Hall           '-P 2yab'
_space_group_name_H-M_alt        'P 1 21/a 1'
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      14
_symmetry_space_group_name_Hall  '-P 2yab'
_symmetry_space_group_name_H-M   'P 1 21/a 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   direct
_audit_conform_dict_location     ftp://ftp.iucr.org/pub/cif_core.dic
_audit_conform_dict_name         cif_core.dic
_audit_conform_dict_version      2.4.3
_audit_creation_date             2020-02-12T12:18:07-00:00
_audit_creation_method           'WinGX routine CIF_UPDATE'
_audit_update_record
;
2022-02-26 deposited with the CCDC.	2022-09-12 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 108.9790(10)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   12.5100(2)
_cell_length_b                   14.7339(3)
_cell_length_c                   12.8760(3)
_cell_measurement_reflns_used    5404
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      20
_cell_measurement_theta_min      2
_cell_measurement_wavelength     0.71073
_cell_volume                     2244.30(8)
_computing_cell_refinement       'HKL Scalepack (Otwinowski & Minor 1997)'
_computing_data_collection       'Collect (Bruker AXS BV, 1997-2004)'
_computing_data_reduction
'HKL Denzo and Scalepack (Otwinowski & Minor 1997)'
_computing_molecular_graphics    'ORTEP-3 for Windows (Farrugia, 2012)'
_computing_publication_material  'WinGX publication routines (Farrugia, 2012)'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_structure_solution    'SIR-92 (Altomare et al., 1994)'
_diffrn_ambient_temperature      100(2)
_diffrn_detector                 'CCD plate'
_diffrn_detector_area_resol_mean 9
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.99
_diffrn_measurement_device       '95mm CCD camera on κ-goniostat'
_diffrn_measurement_device_type  KappaCCD
_diffrn_measurement_method       'CCD rotation images, thick slices'
_diffrn_orient_matrix_UB_11      -0.01145
_diffrn_orient_matrix_UB_12      -0.027189
_diffrn_orient_matrix_UB_13      -0.073996
_diffrn_orient_matrix_UB_21      -0.083603
_diffrn_orient_matrix_UB_22      0
_diffrn_orient_matrix_UB_23      -0.014936
_diffrn_orient_matrix_UB_31      -0.005006
_diffrn_orient_matrix_UB_32      0.062187
_diffrn_orient_matrix_UB_33      -0.032352
_diffrn_radiation_monochromator  'horizonally mounted graphite crystal'
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0478
_diffrn_reflns_av_unetI/netI     0.0685
_diffrn_reflns_Laue_measured_fraction_full 0.997
_diffrn_reflns_Laue_measured_fraction_max 0.99
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            9829
_diffrn_reflns_point_group_measured_fraction_full 0.997
_diffrn_reflns_point_group_measured_fraction_max 0.99
_diffrn_reflns_theta_full        25
_diffrn_reflns_theta_max         28.277
_diffrn_reflns_theta_min         3.09
_diffrn_source                   'Enraf Nonius FR590'
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    1.038
_exptl_absorpt_correction_T_max  0.167
_exptl_absorpt_correction_T_min  -0.189
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'Scalepack 2008'
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    1.517
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             1048
_exptl_crystal_size_max          0.55
_exptl_crystal_size_mid          0.3
_exptl_crystal_size_min          0.15
_refine_diff_density_max         1.408
_refine_diff_density_min         -1.452
_refine_diff_density_rms         0.142
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.999
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_constraints    0
_refine_ls_number_parameters     247
_refine_ls_number_reflns         5512
_refine_ls_number_restraints     6
_refine_ls_restrained_S_all      1
_refine_ls_R_factor_all          0.0646
_refine_ls_R_factor_gt           0.0429
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0200P)²+7.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0878
_refine_ls_wR_factor_ref         0.0955
_reflns_Friedel_coverage         0
_reflns_number_gt                4056
_reflns_number_total             5512
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d2nj03108f2.cif
_cod_data_source_block           shelx
_cod_depositor_comments
'Adding full bibliography for 7061852--7061867.cif.'
_cod_original_sg_symbol_H-M      P21/a
_cod_database_code               7061852
_shelx_estimated_absorpt_t_min   0.599
_shelx_estimated_absorpt_t_max   0.86
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z'
'-x, -y, -z'
'x-1/2, -y-1/2, z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.5467(3) 0.4230(2) 0.8370(3) 0.0165(7) Uani 1 1 d . . . . .
C2 C 0.6271(3) 0.3523(2) 0.8851(3) 0.0164(7) Uani 1 1 d . . . . .
H2 H 0.7051 0.3671 0.9136 0.02 Uiso 1 1 calc R U . . .
C3 C 0.5938(3) 0.2630(2) 0.8909(3) 0.0171(7) Uani 1 1 d . . . . .
H3 H 0.6494 0.2181 0.9224 0.021 Uiso 1 1 calc R U . . .
C4 C 0.4760(3) 0.2373(3) 0.8498(3) 0.0176(7) Uani 1 1 d . . . . .
C5 C 0.3992(3) 0.3064(2) 0.8042(3) 0.0157(7) Uani 1 1 d . U . . .
H5 H 0.3212 0.2914 0.7763 0.019 Uiso 1 1 calc R U . . .
C6 C 0.4311(3) 0.3975(3) 0.7971(3) 0.0169(7) Uani 1 1 d . . . . .
H6 H 0.3749 0.442 0.7655 0.02 Uiso 1 1 calc R U . . .
C7 C 0.5883(3) 0.5188(2) 0.8308(3) 0.0199(8) Uani 1 1 d . . . . .
H7 H 0.6629 0.5144 0.8182 0.024 Uiso 1 1 calc R U . . .
C8 C 0.6080(4) 0.5658(3) 0.9416(3) 0.0264(9) Uani 1 1 d . . . . .
H8A H 0.5354 0.5745 0.9539 0.04 Uiso 1 1 calc R U . . .
H8B H 0.6437 0.625 0.9412 0.04 Uiso 1 1 calc R U . . .
H8C H 0.6574 0.5282 1.0004 0.04 Uiso 1 1 calc R U . . .
C9 C 0.5099(3) 0.5753(3) 0.7382(3) 0.0242(8) Uani 1 1 d . . . . .
H9A H 0.4945 0.5426 0.6685 0.036 Uiso 1 1 calc R U . . .
H9B H 0.546 0.6335 0.7337 0.036 Uiso 1 1 calc R U . . .
H9C H 0.4387 0.5861 0.7526 0.036 Uiso 1 1 calc R U . . .
C10 C 0.4422(3) 0.1405(3) 0.8514(3) 0.0231(8) Uani 1 1 d . . . . .
H10A H 0.4494 0.1228 0.9268 0.035 Uiso 1 1 calc R U . . .
H10B H 0.4914 0.1021 0.8242 0.035 Uiso 1 1 calc R U . . .
H10C H 0.3635 0.1328 0.8043 0.035 Uiso 1 1 calc R U . . .
C11 C 0.3243(3) 0.2388(2) 0.5378(3) 0.0158(7) Uani 1 1 d . . . . .
H11 H 0.3376 0.187 0.5842 0.019 Uiso 1 1 calc R U . . .
C12 C 0.2318(3) 0.2382(2) 0.4429(3) 0.0164(7) Uani 1 1 d . . . . .
H12 H 0.1825 0.1874 0.4254 0.02 Uiso 1 1 calc R U . . .
C13 C 0.2119(3) 0.3131(2) 0.3733(3) 0.0137(7) Uani 1 1 d . . . . .
C14 C 0.2856(3) 0.3862(2) 0.4034(3) 0.0168(7) Uani 1 1 d . . . . .
H14 H 0.2746 0.4384 0.3578 0.02 Uiso 1 1 calc R U . . .
C15 C 0.3752(3) 0.3822(2) 0.5003(3) 0.0170(7) Uani 1 1 d . . . . .
H15 H 0.4242 0.4331 0.5205 0.02 Uiso 1 1 calc R U . . .
C16 C 0.1174(3) 0.3157(2) 0.2667(3) 0.0149(7) Uani 1 1 d . . . . .
C17 C -0.0168(3) 0.3286(3) 0.3714(3) 0.0200(8) Uani 1 1 d . . . . .
H17A H 0.0522 0.3234 0.4362 0.024 Uiso 1 1 calc R U . . .
H17B H -0.0707 0.2811 0.3768 0.024 Uiso 1 1 calc R U . . .
C18 C -0.0698(3) 0.4225(3) 0.3691(3) 0.0260(9) Uani 1 1 d . . . . .
H18A H -0.0939 0.4299 0.4345 0.031 Uiso 1 1 calc R U . . .
H18B H -0.0128 0.4698 0.3715 0.031 Uiso 1 1 calc R U . . .
C19 C -0.1713(3) 0.4344(3) 0.2656(4) 0.0329(10) Uani 1 1 d . . . . .
H19A H -0.1993 0.4975 0.2619 0.039 Uiso 1 1 calc R U . . .
H19B H -0.2328 0.3933 0.2688 0.039 Uiso 1 1 calc R U . . .
C20 C -0.1407(4) 0.4136(3) 0.1625(3) 0.0319(10) Uani 1 1 d . . . . .
H20A H -0.0877 0.4603 0.1531 0.038 Uiso 1 1 calc R U . . .
H20B H -0.2098 0.4156 0.0973 0.038 Uiso 1 1 calc R U . . .
C21 C -0.0860(3) 0.3200(3) 0.1709(3) 0.0201(8) Uani 1 1 d . . . . .
H21A H -0.1413 0.2725 0.1729 0.024 Uiso 1 1 calc R U . . .
H21B H -0.0622 0.309 0.1058 0.024 Uiso 1 1 calc R U . . .
N1 N 0.3966(2) 0.30948(19) 0.5677(2) 0.0127(5) Uani 1 1 d . . . . .
N2 N 0.0119(2) 0.3155(2) 0.2705(2) 0.0155(6) Uani 1 1 d . . . . .
S1 S 0.15250(8) 0.31756(8) 0.15193(7) 0.0297(2) Uani 1 1 d . . . . .
Cl1 Cl 0.58753(7) 0.16920(6) 0.66352(7) 0.01828(18) Uani 1 1 d . . . . .
Cl2 Cl 0.64146(7) 0.38674(6) 0.63336(7) 0.01685(18) Uani 1 1 d . . . . .
Ru1 Ru 0.52546(2) 0.30888(2) 0.72198(2) 0.01255(8) Uani 1 1 d . . . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0 0 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ru Ru -1.2594 0.8363 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C6 C1 C2 116.8(3) . . ?
C6 C1 C7 123.7(3) . . ?
C2 C1 C7 119.5(3) . . ?
C6 C1 Ru1 70.6(2) . . ?
C2 C1 Ru1 69.53(19) . . ?
C7 C1 Ru1 130.2(2) . . ?
C3 C2 C1 121.9(3) . . ?
C3 C2 Ru1 71.4(2) . . ?
C1 C2 Ru1 71.96(19) . . ?
C3 C2 H2 119 . . ?
C1 C2 H2 119 . . ?
Ru1 C2 H2 130.4 . . ?
C2 C3 C4 121.1(3) . . ?
C2 C3 Ru1 71.25(19) . . ?
C4 C3 Ru1 72.08(19) . . ?
C2 C3 H3 119.4 . . ?
C4 C3 H3 119.4 . . ?
Ru1 C3 H3 129.8 . . ?
C5 C4 C3 116.4(3) . . ?
C5 C4 C10 123.1(3) . . ?
C3 C4 C10 120.4(3) . . ?
C5 C4 Ru1 70.02(19) . . ?
C3 C4 Ru1 69.36(19) . . ?
C10 C4 Ru1 128.2(2) . . ?
C4 C5 C6 123.5(3) . . ?
C4 C5 Ru1 72.91(19) . . ?
C6 C5 Ru1 71.75(19) . . ?
C4 C5 H5 118.2 . . ?
C6 C5 H5 118.2 . . ?
Ru1 C5 H5 129.9 . . ?
C5 C6 C1 120.3(3) . . ?
C5 C6 Ru1 70.40(19) . . ?
C1 C6 Ru1 71.64(19) . . ?
C5 C6 H6 119.9 . . ?
C1 C6 H6 119.9 . . ?
Ru1 C6 H6 130.8 . . ?
C1 C7 C9 114.0(3) . . ?
C1 C7 C8 109.1(3) . . ?
C9 C7 C8 110.5(3) . . ?
C1 C7 H7 107.7 . . ?
C9 C7 H7 107.7 . . ?
C8 C7 H7 107.7 . . ?
C7 C8 H8A 109.5 . . ?
C7 C8 H8B 109.5 . . ?
H8A C8 H8B 109.5 . . ?
C7 C8 H8C 109.5 . . ?
H8A C8 H8C 109.5 . . ?
H8B C8 H8C 109.5 . . ?
C7 C9 H9A 109.5 . . ?
C7 C9 H9B 109.5 . . ?
H9A C9 H9B 109.5 . . ?
C7 C9 H9C 109.5 . . ?
H9A C9 H9C 109.5 . . ?
H9B C9 H9C 109.5 . . ?
C4 C10 H10A 109.5 . . ?
C4 C10 H10B 109.5 . . ?
H10A C10 H10B 109.5 . . ?
C4 C10 H10C 109.5 . . ?
H10A C10 H10C 109.5 . . ?
H10B C10 H10C 109.5 . . ?
N1 C11 C12 123.2(3) . . ?
N1 C11 H11 118.4 . . ?
C12 C11 H11 118.4 . . ?
C11 C12 C13 119.1(3) . . ?
C11 C12 H12 120.4 . . ?
C13 C12 H12 120.4 . . ?
C14 C13 C12 118.2(3) . . ?
C14 C13 C16 119.5(3) . . ?
C12 C13 C16 122.3(3) . . ?
C15 C14 C13 119.2(3) . . ?
C15 C14 H14 120.4 . . ?
C13 C14 H14 120.4 . . ?
N1 C15 C14 123.2(3) . . ?
N1 C15 H15 118.4 . . ?
C14 C15 H15 118.4 . . ?
N2 C16 C13 117.6(3) . . ?
N2 C16 S1 125.3(3) . . ?
C13 C16 S1 117.1(2) . . ?
N2 C17 C18 109.3(3) . . ?
N2 C17 H17A 109.8 . . ?
C18 C17 H17A 109.8 . . ?
N2 C17 H17B 109.8 . . ?
C18 C17 H17B 109.8 . . ?
H17A C17 H17B 108.3 . . ?
C19 C18 C17 110.7(3) . . ?
C19 C18 H18A 109.5 . . ?
C17 C18 H18A 109.5 . . ?
C19 C18 H18B 109.5 . . ?
C17 C18 H18B 109.5 . . ?
H18A C18 H18B 108.1 . . ?
C18 C19 C20 111.3(3) . . ?
C18 C19 H19A 109.4 . . ?
C20 C19 H19A 109.4 . . ?
C18 C19 H19B 109.4 . . ?
C20 C19 H19B 109.4 . . ?
H19A C19 H19B 108 . . ?
C19 C20 C21 110.7(3) . . ?
C19 C20 H20A 109.5 . . ?
C21 C20 H20A 109.5 . . ?
C19 C20 H20B 109.5 . . ?
C21 C20 H20B 109.5 . . ?
H20A C20 H20B 108.1 . . ?
N2 C21 C20 109.3(3) . . ?
N2 C21 H21A 109.8 . . ?
C20 C21 H21A 109.8 . . ?
N2 C21 H21B 109.8 . . ?
C20 C21 H21B 109.8 . . ?
H21A C21 H21B 108.3 . . ?
C15 N1 C11 117.0(3) . . ?
C15 N1 Ru1 122.6(2) . . ?
C11 N1 Ru1 120.0(2) . . ?
C16 N2 C21 121.7(3) . . ?
C16 N2 C17 124.1(3) . . ?
C21 N2 C17 113.2(3) . . ?
N1 Ru1 C2 159.66(12) . . ?
N1 Ru1 C5 90.29(12) . . ?
C2 Ru1 C5 79.79(13) . . ?
N1 Ru1 C3 151.08(12) . . ?
C2 Ru1 C3 37.35(14) . . ?
C5 Ru1 C3 67.51(13) . . ?
N1 Ru1 C6 93.27(11) . . ?
C2 Ru1 C6 68.03(13) . . ?
C5 Ru1 C6 37.84(14) . . ?
C3 Ru1 C6 80.55(13) . . ?
N1 Ru1 C1 121.23(12) . . ?
C2 Ru1 C1 38.52(13) . . ?
C5 Ru1 C1 68.40(13) . . ?
C3 Ru1 C1 68.96(13) . . ?
C6 Ru1 C1 37.76(13) . . ?
N1 Ru1 C4 112.96(12) . . ?
C2 Ru1 C4 68.70(13) . . ?
C5 Ru1 C4 37.07(13) . . ?
C3 Ru1 C4 38.56(13) . . ?
C6 Ru1 C4 68.43(14) . . ?
C1 Ru1 C4 82.23(13) . . ?
N1 Ru1 Cl1 86.25(8) . . ?
C2 Ru1 Cl1 114.10(10) . . ?
C5 Ru1 Cl1 119.91(10) . . ?
C3 Ru1 Cl1 89.15(10) . . ?
C6 Ru1 Cl1 157.75(10) . . ?
C1 Ru1 Cl1 152.18(9) . . ?
C4 Ru1 Cl1 91.26(10) . . ?
N1 Ru1 Cl2 86.88(8) . . ?
C2 Ru1 Cl2 93.71(10) . . ?
C5 Ru1 Cl2 152.37(10) . . ?
C3 Ru1 Cl2 121.44(10) . . ?
C6 Ru1 Cl2 114.86(10) . . ?
C1 Ru1 Cl2 89.74(9) . . ?
C4 Ru1 Cl2 160.00(10) . . ?
Cl1 Ru1 Cl2 87.35(3) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C1 C6 1.419(5) . ?
C1 C2 1.441(5) . ?
C1 C7 1.514(5) . ?
C1 Ru1 2.200(3) . ?
C2 C3 1.388(5) . ?
C2 Ru1 2.167(3) . ?
C2 H2 0.95 . ?
C3 C4 1.445(5) . ?
C3 Ru1 2.169(3) . ?
C3 H3 0.95 . ?
C4 C5 1.391(5) . ?
C4 C10 1.490(5) . ?
C4 Ru1 2.206(3) . ?
C5 C6 1.412(5) . ?
C5 Ru1 2.169(3) . ?
C5 H5 0.95 . ?
C6 Ru1 2.186(3) . ?
C6 H6 0.95 . ?
C7 C9 1.522(5) . ?
C7 C8 1.532(5) . ?
C7 H7 1 . ?
C8 H8A 0.98 . ?
C8 H8B 0.98 . ?
C8 H8C 0.98 . ?
C9 H9A 0.98 . ?
C9 H9B 0.98 . ?
C9 H9C 0.98 . ?
C10 H10A 0.98 . ?
C10 H10B 0.98 . ?
C10 H10C 0.98 . ?
C11 N1 1.350(4) . ?
C11 C12 1.383(5) . ?
C11 H11 0.95 . ?
C12 C13 1.391(5) . ?
C12 H12 0.95 . ?
C13 C14 1.389(5) . ?
C13 C16 1.493(5) . ?
C14 C15 1.380(5) . ?
C14 H14 0.95 . ?
C15 N1 1.350(4) . ?
C15 H15 0.95 . ?
C16 N2 1.335(4) . ?
C16 S1 1.674(3) . ?
C17 N2 1.469(4) . ?
C17 C18 1.530(5) . ?
C17 H17A 0.99 . ?
C17 H17B 0.99 . ?
C18 C19 1.523(5) . ?
C18 H18A 0.99 . ?
C18 H18B 0.99 . ?
C19 C20 1.527(6) . ?
C19 H19A 0.99 . ?
C19 H19B 0.99 . ?
C20 C21 1.528(5) . ?
C20 H20A 0.99 . ?
C20 H20B 0.99 . ?
C21 N2 1.459(4) . ?
C21 H21A 0.99 . ?
C21 H21B 0.99 . ?
N1 Ru1 2.113(3) . ?
Cl1 Ru1 2.4053(9) . ?
Cl2 Ru1 2.4085(9) . ?
