#------------------------------------------------------------------------------
#$Date: 2023-05-05 06:06:37 +0300 (Fri, 05 May 2023) $
#$Revision: 283419 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/06/22/7062290.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7062290
loop_
_publ_author_name
'Leitner, Zdeněk'
'Císařová, Ivana'
'Štěpnička, Petr'
_publ_section_title
;
 Synthesis and characterisation of group 11 metal complexes with a
 guanidine-tagged triphenylphosphine and evaluation of the isolated Au(i)
 complexes in gold-mediated organic reactions
;
_journal_issue                   12
_journal_name_full               'New Journal of Chemistry'
_journal_page_first              5930
_journal_page_last               5938
_journal_paper_doi               10.1039/D3NJ00451A
_journal_volume                  47
_journal_year                    2023
_chemical_formula_moiety         'C50 H60 Ag N6 P2, F6 Sb'
_chemical_formula_sum            'C50 H60 Ag F6 N6 P2 Sb'
_chemical_formula_weight         1150.60
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-2017/1
_audit_update_record
;
2023-01-23 deposited with the CCDC.	2023-02-16 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 94.6170(10)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   9.0246(3)
_cell_length_b                   13.8102(4)
_cell_length_c                   41.5886(14)
_cell_measurement_reflns_used    9523
_cell_measurement_temperature    120(2)
_cell_measurement_theta_max      27.49
_cell_measurement_theta_min      2.46
_cell_volume                     5166.4(3)
_computing_cell_refinement       'SAINT V8.40B (Bruker Nano, Inc., 2019)'
_computing_data_collection       'Bruker Instrument Service vV6.2.15'
_computing_data_reduction        'SAINT V8.40B (Bruker Nano, Inc., 2019)'
_computing_molecular_graphics    'PLATON (Spek, 2017)'
_computing_publication_material  'PLATON (Spek, 2017)'
_computing_structure_refinement  'SHELXL-2017 (Sheldrick, 2017)'
_computing_structure_solution    'SHELXT 2018 (Sheldrick, 2018)'
_diffrn_ambient_temperature      120(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Bruker D8 VENTURE Kappa Duo'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  'Quazar Mo multilayer optic'
_diffrn_radiation_source         'I\mS micro-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0228
_diffrn_reflns_av_unetI/netI     0.0150
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.999
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       53
_diffrn_reflns_limit_l_min       -54
_diffrn_reflns_number            76434
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.999
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.489
_diffrn_reflns_theta_min         1.965
_exptl_absorpt_coefficient_mu    1.025
_exptl_absorpt_correction_T_max  0.92
_exptl_absorpt_correction_T_min  0.80
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS-2016/2 - Bruker AXS'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.479
_exptl_crystal_description       prism
_exptl_crystal_F_000             2336
_exptl_crystal_size_max          0.16
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.08
_refine_diff_density_max         1.693
_refine_diff_density_min         -1.239
_refine_diff_density_rms         0.078
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.214
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     603
_refine_ls_number_reflns         11855
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.214
_refine_ls_R_factor_all          0.0394
_refine_ls_R_factor_gt           0.0372
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0020P)²+13.3230P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0728
_refine_ls_wR_factor_ref         0.0735
_reflns_Friedel_coverage         0.000
_reflns_number_gt                11298
_reflns_number_total             11855
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d3nj00451a2.cif
_cod_data_source_block           zl165
_cod_depositor_comments
'Adding full bibliography for 7062284--7062291.cif.'
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               7062290
_shelx_shelxl_version_number     2017/1
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.853
_shelx_estimated_absorpt_t_max   0.922
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.89376(2) 0.74589(2) 0.37433(2) 0.01951(5) Uani 1 1 d . . . . .
P1 P 1.00050(7) 0.74059(5) 0.42907(2) 0.01555(13) Uani 1 1 d . . . . .
N1 N 0.7234(3) 0.63950(17) 0.40740(5) 0.0199(5) Uani 1 1 d . . . . .
N2 N 0.6748(3) 0.51573(18) 0.37065(5) 0.0234(5) Uani 1 1 d . . . . .
H2N H 0.650778 0.462441 0.369650 0.028 Uiso 1 1 d R U . . .
N3 N 0.7303(3) 0.47654(18) 0.42448(6) 0.0274(6) Uani 1 1 d . . . . .
H3N H 0.766861 0.495463 0.443211 0.033 Uiso 1 1 d R U . . .
C1 C 0.7095(3) 0.5467(2) 0.40131(7) 0.0208(5) Uani 1 1 d . . . . .
C2 C 0.7251(3) 0.67162(19) 0.43956(6) 0.0178(5) Uani 1 1 d . . . . .
C3 C 0.8457(3) 0.72547(19) 0.45375(6) 0.0163(5) Uani 1 1 d . . . . .
C4 C 0.8403(3) 0.76429(19) 0.48472(6) 0.0197(5) Uani 1 1 d . . . . .
H4 H 0.921945 0.801018 0.493982 0.024 Uiso 1 1 calc R U . . .
C5 C 0.7172(3) 0.7497(2) 0.50202(6) 0.0229(6) Uani 1 1 d . . . . .
H5 H 0.714402 0.775636 0.523121 0.028 Uiso 1 1 calc R U . . .
C6 C 0.5978(3) 0.6967(2) 0.48808(7) 0.0242(6) Uani 1 1 d . . . . .
H6 H 0.513079 0.686506 0.499819 0.029 Uiso 1 1 calc R U . . .
C7 C 0.6005(3) 0.6585(2) 0.45732(7) 0.0230(6) Uani 1 1 d . . . . .
H7 H 0.517352 0.623068 0.448139 0.028 Uiso 1 1 calc R U . . .
C8 C 1.1145(3) 0.8363(2) 0.44836(6) 0.0179(5) Uani 1 1 d . . . . .
C9 C 1.0936(4) 0.9300(2) 0.43674(7) 0.0277(6) Uani 1 1 d . . . . .
H9 H 1.023211 0.941916 0.418947 0.033 Uiso 1 1 calc R U . . .
C10 C 1.1750(4) 1.0065(2) 0.45098(8) 0.0345(7) Uani 1 1 d . . . . .
H10 H 1.159962 1.070539 0.443022 0.041 Uiso 1 1 calc R U . . .
C11 C 1.2781(4) 0.9888(2) 0.47679(8) 0.0318(7) Uani 1 1 d . . . . .
H11 H 1.333032 1.041036 0.486671 0.038 Uiso 1 1 calc R U . . .
C12 C 1.3016(4) 0.8960(2) 0.48827(8) 0.0313(7) Uani 1 1 d . . . . .
H12 H 1.373211 0.884258 0.505851 0.038 Uiso 1 1 calc R U . . .
C13 C 1.2202(3) 0.8196(2) 0.47406(7) 0.0246(6) Uani 1 1 d . . . . .
H13 H 1.236675 0.755624 0.481928 0.030 Uiso 1 1 calc R U . . .
C14 C 1.1077(3) 0.62967(19) 0.43648(6) 0.0162(5) Uani 1 1 d . . . . .
C15 C 1.1088(3) 0.5799(2) 0.46577(6) 0.0198(5) Uani 1 1 d . . . . .
H15 H 1.050140 0.602631 0.482174 0.024 Uiso 1 1 calc R U . . .
C16 C 1.1955(3) 0.4974(2) 0.47100(7) 0.0246(6) Uani 1 1 d . . . . .
H16 H 1.196854 0.464140 0.491020 0.029 Uiso 1 1 calc R U . . .
C17 C 1.2801(3) 0.4636(2) 0.44690(7) 0.0255(6) Uani 1 1 d . . . . .
H17 H 1.339969 0.407514 0.450523 0.031 Uiso 1 1 calc R U . . .
C18 C 1.2775(3) 0.5115(2) 0.41758(7) 0.0248(6) Uani 1 1 d . . . . .
H18 H 1.334183 0.487661 0.401008 0.030 Uiso 1 1 calc R U . . .
C19 C 1.1917(3) 0.5946(2) 0.41245(7) 0.0203(5) Uani 1 1 d . . . . .
H19 H 1.190490 0.627495 0.392374 0.024 Uiso 1 1 calc R U . . .
C20 C 0.7621(3) 0.3744(2) 0.41860(7) 0.0252(6) Uani 1 1 d . . . . .
H20 H 0.684810 0.349483 0.402086 0.030 Uiso 1 1 calc R U . . .
C21 C 0.7491(5) 0.3188(3) 0.44944(8) 0.0453(9) Uani 1 1 d . . . . .
H21A H 0.821970 0.343586 0.466183 0.068 Uiso 1 1 calc R U . . .
H21B H 0.768183 0.250047 0.445735 0.068 Uiso 1 1 calc R U . . .
H21C H 0.648701 0.326769 0.456445 0.068 Uiso 1 1 calc R U . . .
C22 C 0.9134(5) 0.3606(3) 0.40571(11) 0.0538(11) Uani 1 1 d . . . . .
H22A H 0.919379 0.399899 0.386236 0.081 Uiso 1 1 calc R U . . .
H22B H 0.927099 0.292176 0.400455 0.081 Uiso 1 1 calc R U . . .
H22C H 0.991279 0.380806 0.422114 0.081 Uiso 1 1 calc R U . . .
C23 C 0.6155(3) 0.5787(2) 0.34448(6) 0.0219(6) Uani 1 1 d . . . . .
H23 H 0.684521 0.634862 0.342990 0.026 Uiso 1 1 calc R U . . .
C24 C 0.4614(3) 0.6178(2) 0.34996(7) 0.0294(7) Uani 1 1 d . . . . .
H24A H 0.389884 0.564323 0.349139 0.044 Uiso 1 1 calc R U . . .
H24B H 0.431251 0.665139 0.333131 0.044 Uiso 1 1 calc R U . . .
H24C H 0.464177 0.649156 0.371148 0.044 Uiso 1 1 calc R U . . .
C25 C 0.6129(4) 0.5218(3) 0.31314(7) 0.0302(7) Uani 1 1 d . . . . .
H25A H 0.713913 0.500704 0.309567 0.045 Uiso 1 1 calc R U . . .
H25B H 0.574445 0.562994 0.295178 0.045 Uiso 1 1 calc R U . . .
H25C H 0.548553 0.464993 0.314482 0.045 Uiso 1 1 calc R U . . .
P51 P 0.96997(7) 0.73167(5) 0.32010(2) 0.01663(13) Uani 1 1 d . . . . .
N51 N 0.7100(3) 0.84092(17) 0.34000(5) 0.0202(5) Uani 1 1 d . . . . .
N52 N 0.6814(3) 0.96390(18) 0.37640(6) 0.0272(5) Uani 1 1 d . . . . .
H52N H 0.670073 1.023634 0.380334 0.033 Uiso 1 1 d R U . . .
N53 N 0.7254(3) 1.00368(19) 0.32353(6) 0.0310(6) Uani 1 1 d . . . . .
H53N H 0.769309 0.989627 0.305302 0.037 Uiso 1 1 d R U . . .
C51 C 0.7037(3) 0.9335(2) 0.34623(7) 0.0230(6) Uani 1 1 d . . . . .
C52 C 0.6932(3) 0.8090(2) 0.30767(6) 0.0184(5) Uani 1 1 d . . . . .
C53 C 0.7993(3) 0.74846(19) 0.29480(6) 0.0174(5) Uani 1 1 d . . . . .
C54 C 0.7724(3) 0.7101(2) 0.26375(6) 0.0196(5) Uani 1 1 d . . . . .
H54 H 0.843766 0.668309 0.255477 0.024 Uiso 1 1 calc R U . . .
C55 C 0.6432(3) 0.7322(2) 0.24486(6) 0.0228(6) Uani 1 1 d . . . . .
H55 H 0.626194 0.706336 0.223721 0.027 Uiso 1 1 calc R U . . .
C56 C 0.5390(3) 0.7928(2) 0.25736(7) 0.0257(6) Uani 1 1 d . . . . .
H56 H 0.450611 0.808871 0.244521 0.031 Uiso 1 1 calc R U . . .
C57 C 0.5624(3) 0.8300(2) 0.28831(7) 0.0249(6) Uani 1 1 d . . . . .
H57 H 0.488919 0.870304 0.296533 0.030 Uiso 1 1 calc R U . . .
C58 C 1.0560(3) 0.6205(2) 0.30746(6) 0.0203(5) Uani 1 1 d . . . . .
C59 C 1.0262(3) 0.5370(2) 0.32466(8) 0.0267(6) Uani 1 1 d . . . . .
H59 H 0.960376 0.540250 0.341333 0.032 Uiso 1 1 calc R U . . .
C60 C 1.0915(4) 0.4493(2) 0.31773(9) 0.0350(7) Uani 1 1 d . . . . .
H60 H 1.069575 0.392643 0.329415 0.042 Uiso 1 1 calc R U . . .
C61 C 1.1885(4) 0.4449(3) 0.29372(9) 0.0369(8) Uani 1 1 d . . . . .
H61 H 1.233819 0.385086 0.288945 0.044 Uiso 1 1 calc R U . . .
C62 C 1.2200(4) 0.5270(3) 0.27666(8) 0.0319(7) Uani 1 1 d . . . . .
H62 H 1.286885 0.523245 0.260201 0.038 Uiso 1 1 calc R U . . .
C63 C 1.1548(3) 0.6151(2) 0.28331(7) 0.0258(6) Uani 1 1 d . . . . .
H63 H 1.177288 0.671392 0.271500 0.031 Uiso 1 1 calc R U . . .
C64 C 1.0825(3) 0.8316(2) 0.30736(7) 0.0199(5) Uani 1 1 d . . . . .
C65 C 1.0716(3) 0.8666(2) 0.27580(7) 0.0269(6) Uani 1 1 d . . . . .
H65 H 1.006526 0.835767 0.259855 0.032 Uiso 1 1 calc R U . . .
C66 C 1.1550(4) 0.9461(2) 0.26745(8) 0.0327(7) Uani 1 1 d . . . . .
H66 H 1.147168 0.969249 0.245871 0.039 Uiso 1 1 calc R U . . .
C67 C 1.2494(4) 0.9914(2) 0.29064(9) 0.0320(7) Uani 1 1 d . . . . .
H67 H 1.306173 1.045800 0.284965 0.038 Uiso 1 1 calc R U . . .
C68 C 1.2612(4) 0.9577(2) 0.32197(8) 0.0314(7) Uani 1 1 d . . . . .
H68 H 1.326401 0.988851 0.337803 0.038 Uiso 1 1 calc R U . . .
C69 C 1.1780(3) 0.8785(2) 0.33042(7) 0.0236(6) Uani 1 1 d . . . . .
H69 H 1.186111 0.855969 0.352075 0.028 Uiso 1 1 calc R U . . .
C70 C 0.6323(3) 0.9006(2) 0.40171(7) 0.0246(6) Uani 1 1 d . . . . .
H70 H 0.698363 0.842370 0.403294 0.030 Uiso 1 1 calc R U . . .
C71 C 0.4731(4) 0.8665(2) 0.39474(8) 0.0325(7) Uani 1 1 d . . . . .
H71A H 0.405821 0.922226 0.394789 0.049 Uiso 1 1 calc R U . . .
H71B H 0.448303 0.820302 0.411366 0.049 Uiso 1 1 calc R U . . .
H71C H 0.462290 0.835042 0.373563 0.049 Uiso 1 1 calc R U . . .
C72 C 0.6514(4) 0.9551(3) 0.43372(7) 0.0348(8) Uani 1 1 d . . . . .
H72A H 0.754912 0.976325 0.437675 0.052 Uiso 1 1 calc R U . . .
H72B H 0.625982 0.912226 0.451234 0.052 Uiso 1 1 calc R U . . .
H72C H 0.585717 1.011674 0.432802 0.052 Uiso 1 1 calc R U . . .
C73 C 0.7758(4) 1.1023(2) 0.33116(8) 0.0309(7) Uani 1 1 d . . . . .
H73 H 0.707533 1.130718 0.346422 0.037 Uiso 1 1 calc R U . . .
C74 C 0.7599(6) 1.1605(3) 0.30042(10) 0.0578(12) Uani 1 1 d . . . . .
H74A H 0.840444 1.143819 0.286978 0.087 Uiso 1 1 calc R U . . .
H74B H 0.764817 1.229733 0.305638 0.087 Uiso 1 1 calc R U . . .
H74C H 0.663947 1.145967 0.288677 0.087 Uiso 1 1 calc R U . . .
C75 C 0.9308(5) 1.1045(4) 0.34734(13) 0.0640(13) Uani 1 1 d . . . . .
H75A H 0.936509 1.061804 0.366214 0.096 Uiso 1 1 calc R U . . .
H75B H 0.955676 1.170851 0.354207 0.096 Uiso 1 1 calc R U . . .
H75C H 1.001192 1.082440 0.332158 0.096 Uiso 1 1 calc R U . . .
Sb1 Sb 0.37989(2) 0.22059(2) 0.37722(2) 0.02543(5) Uani 1 1 d . . . . .
F1 F 0.3734(4) 0.2610(2) 0.41977(6) 0.0747(9) Uani 1 1 d . . . . .
F2 F 0.1926(3) 0.26953(19) 0.36604(9) 0.0859(11) Uani 1 1 d . . . . .
F3 F 0.4626(2) 0.33988(14) 0.36677(6) 0.0471(6) Uani 1 1 d . . . . .
F4 F 0.5722(2) 0.17266(15) 0.38909(5) 0.0446(5) Uani 1 1 d . . . . .
F5 F 0.3000(3) 0.10123(15) 0.38735(6) 0.0500(6) Uani 1 1 d . . . . .
F6 F 0.3994(3) 0.17711(19) 0.33538(5) 0.0633(8) Uani 1 1 d . . . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sb Sb -0.5866 1.5461 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P1 Ag1 P51 139.42(2) . . ?
P1 Ag1 N51 139.64(5) . . ?
P51 Ag1 N51 74.51(5) . . ?
P1 Ag1 N1 71.95(5) . . ?
P51 Ag1 N1 132.26(5) . . ?
N51 Ag1 N1 101.97(8) . . ?
C3 P1 C8 105.57(12) . . ?
C3 P1 C14 103.30(12) . . ?
C8 P1 C14 105.17(12) . . ?
C3 P1 Ag1 105.79(8) . . ?
C8 P1 Ag1 124.40(9) . . ?
C14 P1 Ag1 110.64(8) . . ?
C1 N1 C2 119.0(2) . . ?
C1 N1 Ag1 120.13(18) . . ?
C2 N1 Ag1 111.27(17) . . ?
C1 N2 C23 123.7(2) . . ?
C1 N2 H2N 113.3 . . ?
C23 N2 H2N 116.4 . . ?
C1 N3 C20 125.6(2) . . ?
C1 N3 H3N 116.2 . . ?
C20 N3 H3N 112.2 . . ?
N1 C1 N2 120.1(3) . . ?
N1 C1 N3 123.4(3) . . ?
N2 C1 N3 116.5(3) . . ?
C7 C2 C3 118.1(2) . . ?
C7 C2 N1 120.7(2) . . ?
C3 C2 N1 120.9(2) . . ?
C4 C3 C2 120.3(2) . . ?
C4 C3 P1 124.3(2) . . ?
C2 C3 P1 115.39(19) . . ?
C5 C4 C3 120.7(3) . . ?
C5 C4 H4 119.6 . . ?
C3 C4 H4 119.6 . . ?
C4 C5 C6 119.1(3) . . ?
C4 C5 H5 120.4 . . ?
C6 C5 H5 120.4 . . ?
C7 C6 C5 121.0(3) . . ?
C7 C6 H6 119.5 . . ?
C5 C6 H6 119.5 . . ?
C6 C7 C2 120.7(3) . . ?
C6 C7 H7 119.7 . . ?
C2 C7 H7 119.7 . . ?
C9 C8 C13 119.1(3) . . ?
C9 C8 P1 117.8(2) . . ?
C13 C8 P1 123.1(2) . . ?
C8 C9 C10 120.5(3) . . ?
C8 C9 H9 119.8 . . ?
C10 C9 H9 119.8 . . ?
C11 C10 C9 119.6(3) . . ?
C11 C10 H10 120.2 . . ?
C9 C10 H10 120.2 . . ?
C12 C11 C10 120.5(3) . . ?
C12 C11 H11 119.7 . . ?
C10 C11 H11 119.7 . . ?
C11 C12 C13 119.8(3) . . ?
C11 C12 H12 120.1 . . ?
C13 C12 H12 120.1 . . ?
C12 C13 C8 120.4(3) . . ?
C12 C13 H13 119.8 . . ?
C8 C13 H13 119.8 . . ?
C19 C14 C15 119.3(2) . . ?
C19 C14 P1 118.9(2) . . ?
C15 C14 P1 121.8(2) . . ?
C16 C15 C14 120.3(3) . . ?
C16 C15 H15 119.9 . . ?
C14 C15 H15 119.9 . . ?
C17 C16 C15 119.8(3) . . ?
C17 C16 H16 120.1 . . ?
C15 C16 H16 120.1 . . ?
C18 C17 C16 120.2(3) . . ?
C18 C17 H17 119.9 . . ?
C16 C17 H17 119.9 . . ?
C17 C18 C19 119.9(3) . . ?
C17 C18 H18 120.0 . . ?
C19 C18 H18 120.0 . . ?
C14 C19 C18 120.4(3) . . ?
C14 C19 H19 119.8 . . ?
C18 C19 H19 119.8 . . ?
N3 C20 C21 108.6(3) . . ?
N3 C20 C22 112.0(3) . . ?
C21 C20 C22 111.7(3) . . ?
N3 C20 H20 108.1 . . ?
C21 C20 H20 108.1 . . ?
C22 C20 H20 108.1 . . ?
C20 C21 H21A 109.5 . . ?
C20 C21 H21B 109.5 . . ?
H21A C21 H21B 109.5 . . ?
C20 C21 H21C 109.5 . . ?
H21A C21 H21C 109.5 . . ?
H21B C21 H21C 109.5 . . ?
C20 C22 H22A 109.5 . . ?
C20 C22 H22B 109.5 . . ?
H22A C22 H22B 109.5 . . ?
C20 C22 H22C 109.5 . . ?
H22A C22 H22C 109.5 . . ?
H22B C22 H22C 109.5 . . ?
N2 C23 C25 108.1(2) . . ?
N2 C23 C24 112.5(2) . . ?
C25 C23 C24 111.1(2) . . ?
N2 C23 H23 108.3 . . ?
C25 C23 H23 108.3 . . ?
C24 C23 H23 108.3 . . ?
C23 C24 H24A 109.5 . . ?
C23 C24 H24B 109.5 . . ?
H24A C24 H24B 109.5 . . ?
C23 C24 H24C 109.5 . . ?
H24A C24 H24C 109.5 . . ?
H24B C24 H24C 109.5 . . ?
C23 C25 H25A 109.5 . . ?
C23 C25 H25B 109.5 . . ?
H25A C25 H25B 109.5 . . ?
C23 C25 H25C 109.5 . . ?
H25A C25 H25C 109.5 . . ?
H25B C25 H25C 109.5 . . ?
C53 P51 C58 107.69(12) . . ?
C53 P51 C64 101.70(12) . . ?
C58 P51 C64 107.17(13) . . ?
C53 P51 Ag1 103.84(9) . . ?
C58 P51 Ag1 119.92(9) . . ?
C64 P51 Ag1 114.69(9) . . ?
C51 N51 C52 119.4(2) . . ?
C51 N51 Ag1 116.23(18) . . ?
C52 N51 Ag1 113.53(16) . . ?
C51 N52 C70 123.9(3) . . ?
C51 N52 H52N 120.6 . . ?
C70 N52 H52N 113.2 . . ?
C51 N53 C73 124.4(3) . . ?
C51 N53 H53N 121.3 . . ?
C73 N53 H53N 103.4 . . ?
N51 C51 N52 119.9(3) . . ?
N51 C51 N53 122.8(3) . . ?
N52 C51 N53 117.2(3) . . ?
C57 C52 C53 118.1(2) . . ?
C57 C52 N51 120.1(2) . . ?
C53 C52 N51 121.5(2) . . ?
C54 C53 C52 120.2(2) . . ?
C54 C53 P51 124.4(2) . . ?
C52 C53 P51 115.35(19) . . ?
C55 C54 C53 121.0(3) . . ?
C55 C54 H54 119.5 . . ?
C53 C54 H54 119.5 . . ?
C54 C55 C56 118.9(3) . . ?
C54 C55 H55 120.5 . . ?
C56 C55 H55 120.5 . . ?
C57 C56 C55 120.9(3) . . ?
C57 C56 H56 119.6 . . ?
C55 C56 H56 119.6 . . ?
C56 C57 C52 120.9(3) . . ?
C56 C57 H57 119.6 . . ?
C52 C57 H57 119.6 . . ?
C59 C58 C63 119.0(3) . . ?
C59 C58 P51 116.5(2) . . ?
C63 C58 P51 124.4(2) . . ?
C60 C59 C58 120.9(3) . . ?
C60 C59 H59 119.6 . . ?
C58 C59 H59 119.6 . . ?
C61 C60 C59 119.5(3) . . ?
C61 C60 H60 120.2 . . ?
C59 C60 H60 120.2 . . ?
C62 C61 C60 120.3(3) . . ?
C62 C61 H61 119.8 . . ?
C60 C61 H61 119.8 . . ?
C61 C62 C63 120.7(3) . . ?
C61 C62 H62 119.7 . . ?
C63 C62 H62 119.7 . . ?
C62 C63 C58 119.7(3) . . ?
C62 C63 H63 120.2 . . ?
C58 C63 H63 120.2 . . ?
C65 C64 C69 118.7(3) . . ?
C65 C64 P51 122.6(2) . . ?
C69 C64 P51 118.7(2) . . ?
C66 C65 C64 120.6(3) . . ?
C66 C65 H65 119.7 . . ?
C64 C65 H65 119.7 . . ?
C67 C66 C65 119.9(3) . . ?
C67 C66 H66 120.1 . . ?
C65 C66 H66 120.1 . . ?
C68 C67 C66 120.2(3) . . ?
C68 C67 H67 119.9 . . ?
C66 C67 H67 119.9 . . ?
C67 C68 C69 120.2(3) . . ?
C67 C68 H68 119.9 . . ?
C69 C68 H68 119.9 . . ?
C68 C69 C64 120.5(3) . . ?
C68 C69 H69 119.7 . . ?
C64 C69 H69 119.7 . . ?
N52 C70 C71 112.6(2) . . ?
N52 C70 C72 108.2(3) . . ?
C71 C70 C72 111.0(3) . . ?
N52 C70 H70 108.3 . . ?
C71 C70 H70 108.3 . . ?
C72 C70 H70 108.3 . . ?
C70 C71 H71A 109.5 . . ?
C70 C71 H71B 109.5 . . ?
H71A C71 H71B 109.5 . . ?
C70 C71 H71C 109.5 . . ?
H71A C71 H71C 109.5 . . ?
H71B C71 H71C 109.5 . . ?
C70 C72 H72A 109.5 . . ?
C70 C72 H72B 109.5 . . ?
H72A C72 H72B 109.5 . . ?
C70 C72 H72C 109.5 . . ?
H72A C72 H72C 109.5 . . ?
H72B C72 H72C 109.5 . . ?
N53 C73 C75 112.3(3) . . ?
N53 C73 C74 107.8(3) . . ?
C75 C73 C74 113.0(3) . . ?
N53 C73 H73 107.9 . . ?
C75 C73 H73 107.9 . . ?
C74 C73 H73 107.9 . . ?
C73 C74 H74A 109.5 . . ?
C73 C74 H74B 109.5 . . ?
H74A C74 H74B 109.5 . . ?
C73 C74 H74C 109.5 . . ?
H74A C74 H74C 109.5 . . ?
H74B C74 H74C 109.5 . . ?
C73 C75 H75A 109.5 . . ?
C73 C75 H75B 109.5 . . ?
H75A C75 H75B 109.5 . . ?
C73 C75 H75C 109.5 . . ?
H75A C75 H75C 109.5 . . ?
H75B C75 H75C 109.5 . . ?
F2 Sb1 F1 91.83(16) . . ?
F2 Sb1 F5 91.02(11) . . ?
F1 Sb1 F5 90.45(12) . . ?
F2 Sb1 F6 92.08(16) . . ?
F1 Sb1 F6 176.09(14) . . ?
F5 Sb1 F6 89.62(10) . . ?
F2 Sb1 F3 89.61(11) . . ?
F1 Sb1 F3 90.04(12) . . ?
F5 Sb1 F3 179.18(11) . . ?
F6 Sb1 F3 89.84(10) . . ?
F2 Sb1 F4 178.94(13) . . ?
F1 Sb1 F4 87.41(12) . . ?
F5 Sb1 F4 89.72(10) . . ?
F6 Sb1 F4 88.68(12) . . ?
F3 Sb1 F4 89.65(10) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 P1 2.4009(7) . ?
Ag1 P51 2.4181(7) . ?
Ag1 N51 2.476(2) . ?
Ag1 N1 2.599(2) . ?
P1 C3 1.811(3) . ?
P1 C8 1.821(3) . ?
P1 C14 1.825(3) . ?
N1 C1 1.310(4) . ?
N1 C2 1.408(3) . ?
N2 C1 1.358(3) . ?
N2 C23 1.461(3) . ?
N2 H2N 0.7675 . ?
N3 C1 1.369(4) . ?
N3 C20 1.464(4) . ?
N3 H3N 0.8618 . ?
C2 C7 1.406(4) . ?
C2 C3 1.408(4) . ?
C3 C4 1.399(4) . ?
C4 C5 1.387(4) . ?
C4 H4 0.9500 . ?
C5 C6 1.390(4) . ?
C5 H5 0.9500 . ?
C6 C7 1.386(4) . ?
C6 H6 0.9500 . ?
C7 H7 0.9500 . ?
C8 C9 1.389(4) . ?
C8 C13 1.393(4) . ?
C9 C10 1.392(4) . ?
C9 H9 0.9500 . ?
C10 C11 1.384(5) . ?
C10 H10 0.9500 . ?
C11 C12 1.378(5) . ?
C11 H11 0.9500 . ?
C12 C13 1.390(4) . ?
C12 H12 0.9500 . ?
C13 H13 0.9500 . ?
C14 C19 1.390(4) . ?
C14 C15 1.398(4) . ?
C15 C16 1.389(4) . ?
C15 H15 0.9500 . ?
C16 C17 1.389(4) . ?
C16 H16 0.9500 . ?
C17 C18 1.386(4) . ?
C17 H17 0.9500 . ?
C18 C19 1.390(4) . ?
C18 H18 0.9500 . ?
C19 H19 0.9500 . ?
C20 C21 1.507(4) . ?
C20 C22 1.518(5) . ?
C20 H20 1.0000 . ?
C21 H21A 0.9800 . ?
C21 H21B 0.9800 . ?
C21 H21C 0.9800 . ?
C22 H22A 0.9800 . ?
C22 H22B 0.9800 . ?
C22 H22C 0.9800 . ?
C23 C25 1.520(4) . ?
C23 C24 1.526(4) . ?
C23 H23 1.0000 . ?
C24 H24A 0.9800 . ?
C24 H24B 0.9800 . ?
C24 H24C 0.9800 . ?
C25 H25A 0.9800 . ?
C25 H25B 0.9800 . ?
C25 H25C 0.9800 . ?
P51 C53 1.809(3) . ?
P51 C58 1.817(3) . ?
P51 C64 1.818(3) . ?
N51 C51 1.307(4) . ?
N51 C52 1.411(3) . ?
N52 C51 1.353(4) . ?
N52 C70 1.464(4) . ?
N52 H52N 0.8488 . ?
N53 C51 1.377(4) . ?
N53 C73 1.462(4) . ?
N53 H53N 0.9044 . ?
C52 C57 1.405(4) . ?
C52 C53 1.409(4) . ?
C53 C54 1.399(4) . ?
C54 C55 1.386(4) . ?
C54 H54 0.9500 . ?
C55 C56 1.391(4) . ?
C55 H55 0.9500 . ?
C56 C57 1.386(4) . ?
C56 H56 0.9500 . ?
C57 H57 0.9500 . ?
C58 C59 1.395(4) . ?
C58 C63 1.398(4) . ?
C59 C60 1.387(4) . ?
C59 H59 0.9500 . ?
C60 C61 1.382(5) . ?
C60 H60 0.9500 . ?
C61 C62 1.379(5) . ?
C61 H61 0.9500 . ?
C62 C63 1.389(4) . ?
C62 H62 0.9500 . ?
C63 H63 0.9500 . ?
C64 C65 1.394(4) . ?
C64 C69 1.396(4) . ?
C65 C66 1.391(4) . ?
C65 H65 0.9500 . ?
C66 C67 1.384(5) . ?
C66 H66 0.9500 . ?
C67 C68 1.380(5) . ?
C67 H67 0.9500 . ?
C68 C69 1.388(4) . ?
C68 H68 0.9500 . ?
C69 H69 0.9500 . ?
C70 C71 1.517(4) . ?
C70 C72 1.527(4) . ?
C70 H70 1.0000 . ?
C71 H71A 0.9800 . ?
C71 H71B 0.9800 . ?
C71 H71C 0.9800 . ?
C72 H72A 0.9800 . ?
C72 H72B 0.9800 . ?
C72 H72C 0.9800 . ?
C73 C75 1.502(5) . ?
C73 C74 1.508(5) . ?
C73 H73 1.0000 . ?
C74 H74A 0.9800 . ?
C74 H74B 0.9800 . ?
C74 H74C 0.9800 . ?
C75 H75A 0.9800 . ?
C75 H75B 0.9800 . ?
C75 H75C 0.9800 . ?
Sb1 F2 1.845(2) . ?
Sb1 F1 1.861(2) . ?
Sb1 F5 1.861(2) . ?
Sb1 F6 1.863(2) . ?
Sb1 F3 1.8741(19) . ?
Sb1 F4 1.886(2) . ?
