#------------------------------------------------------------------------------
#$Date: 2023-10-06 03:33:44 +0300 (Fri, 06 Oct 2023) $
#$Revision: 286778 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/06/26/7062605.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7062605
loop_
_publ_author_name
'Starynowicz, Przemysław'
_publ_section_title
;
 Europium(ii) bis[tetrafluoro-2-(pentafluoroethoxy)ethanesulfonate] --
 structure and spectroscopic properties of a new near-UV emitter
;
_journal_issue                   35
_journal_name_full               'New Journal of Chemistry'
_journal_page_first              16368
_journal_page_last               16373
_journal_paper_doi               10.1039/D3NJ02429F
_journal_volume                  47
_journal_year                    2023
_chemical_formula_sum            'C12 H12 Eu F27 O18 S3'
_chemical_formula_weight         1205.36
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_atom_sites_solution_primary     vecmap
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-2018/3
_audit_update_record
;
2023-07-14 deposited with the CCDC.	2023-07-19 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 96.17(6)
_cell_angle_gamma                90
_cell_formula_units_Z            8
_cell_length_a                   16.934(6)
_cell_length_b                   12.916(4)
_cell_length_c                   32.216(16)
_cell_measurement_reflns_used    66215
_cell_measurement_temperature    100.00(10)
_cell_measurement_theta_max      48.3780
_cell_measurement_theta_min      1.8410
_cell_volume                     7005(5)
_computing_cell_refinement       'CrysAlisPro 1.171.42.50a (Rigaku OD, 2022)'
_computing_data_collection       'CrysAlisPro 1.171.42.50a (Rigaku OD, 2022)'
_computing_data_reduction        'CrysAlisPro 1.171.42.50a (Rigaku OD, 2022)'
_computing_molecular_graphics    'Diamond version 4.6.8'
_computing_publication_material  'publCIF (version 1.9.21_c)'
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018)'
_computing_structure_solution    SHELXS
_diffrn_ambient_environment      N~2~
_diffrn_ambient_temperature      100.00(10)
_diffrn_detector                 'Hybrid Pixel Array Detector'
_diffrn_detector_area_resol_mean 10.0000
_diffrn_detector_type            'HyPix-Arc 150'
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.869
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'XtaLAB Synergy R, DW system, HyPix-Arc 150'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_unetI/netI     0.0585
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.869
_diffrn_reflns_limit_h_max       33
_diffrn_reflns_limit_h_min       -34
_diffrn_reflns_limit_k_max       25
_diffrn_reflns_limit_k_min       -25
_diffrn_reflns_limit_l_max       65
_diffrn_reflns_limit_l_min       -56
_diffrn_reflns_number            84091
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.869
_diffrn_reflns_theta_full        27.500
_diffrn_reflns_theta_max         48.420
_diffrn_reflns_theta_min         1.658
_diffrn_source                   'Rotating-anode X-ray tube'
_diffrn_source_type              'Rigaku (Mo) X-ray Source'
_exptl_absorpt_coefficient_mu    2.183
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.92841
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlisPro 1.171.42.50a (Rigaku Oxford Diffraction, 2022)
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            'irregular plate'
_exptl_crystal_density_diffrn    2.286
_exptl_crystal_description       colourless
_exptl_crystal_F_000             4656
_exptl_crystal_recrystallization_method 'Re-crystallisation from solvent: water'
_exptl_crystal_size_max          0.314
_exptl_crystal_size_mid          0.164
_exptl_crystal_size_min          0.051
_refine_diff_density_max         8.862
_refine_diff_density_min         -2.704
_refine_diff_density_rms         0.288
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.062
_refine_ls_hydrogen_treatment    undef
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1096
_refine_ls_number_reflns         84091
_refine_ls_number_restraints     8
_refine_ls_restrained_S_all      1.061
_refine_ls_R_factor_all          0.1538
_refine_ls_R_factor_gt           0.0927
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0826P)²+60.9735P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2194
_refine_ls_wR_factor_ref         0.2479
_reflns_Friedel_coverage         0.000
_reflns_number_gt                51179
_reflns_number_total             84091
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d3nj02429f2.cif
_cod_data_source_block           euf3mo
_cod_depositor_comments
'Adding full bibliography for 7062603--7062605.cif.'
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               7062605
_shelx_shelxl_version_number     2018/3
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.61752(2) 0.21376(2) 0.00571(2) 0.02062(5) Uani 1 1 d . . . . .
Eu2 Eu 1.11404(2) 0.28555(2) -0.01081(2) 0.02038(5) Uani 1 1 d . . . . .
S1 S 0.68036(8) -0.02228(10) 0.06673(5) 0.0245(3) Uani 1 1 d . . . . .
S2 S 0.47123(8) 0.40275(11) -0.05188(5) 0.0258(3) Uani 1 1 d . . . . .
S3 S 0.43472(7) 0.17694(11) 0.06053(5) 0.0244(3) Uani 1 1 d . . . . .
S4 S 1.15217(7) 0.53115(10) -0.06581(5) 0.0229(2) Uani 1 1 d . . . . .
S5 S 0.99820(8) 0.09738(10) 0.05184(5) 0.0230(2) Uani 1 1 d . . . . .
S6 S 0.90805(7) 0.32378(10) -0.06429(5) 0.0237(2) Uani 1 1 d . . . . .
F11 F 0.5820(3) -0.0210(4) 0.12273(17) 0.0459(11) Uani 1 1 d . . . . .
F12 F 0.6540(3) 0.1195(4) 0.12054(18) 0.0504(12) Uani 1 1 d . . . . .
F13 F 0.7795(3) 0.0309(4) 0.15850(19) 0.0556(14) Uani 1 1 d . . . . .
F14 F 0.6778(4) 0.0012(6) 0.1915(2) 0.0724(19) Uani 1 1 d . . . . .
F21 F 0.4230(4) 0.2709(4) -0.10899(19) 0.0553(14) Uani 1 1 d . . . . .
F22 F 0.4066(4) 0.4344(5) -0.12571(19) 0.0611(15) Uani 1 1 d . . . . .
F23 F 0.5770(4) 0.2827(5) -0.11505(19) 0.0676(18) Uani 1 1 d . . . . .
F24 F 0.5728(4) 0.4459(5) -0.1239(2) 0.079(2) Uani 1 1 d . . . . .
F25 F 0.6209(5) 0.3276(9) -0.1957(3) 0.100(3) Uani 1 1 d . . . . .
F26 F 0.5515(10) 0.4695(8) -0.2091(4) 0.162(6) Uani 1 1 d . . . . .
F27 F 0.4326(7) 0.3582(10) -0.2493(3) 0.139(5) Uani 1 1 d . . . . .
F28 F 0.5028(6) 0.2212(9) -0.2395(3) 0.109(3) Uani 1 1 d . . . . .
F29 F 0.5447(8) 0.3476(10) -0.2746(3) 0.136(4) Uani 1 1 d . . . . .
F31 F 0.5016(3) 0.1971(4) 0.13644(17) 0.0482(12) Uani 1 1 d . . . . .
F32 F 0.4418(3) 0.3341(3) 0.10983(16) 0.0450(11) Uani 1 1 d . . . . .
F33 F 0.3723(3) 0.2584(4) 0.17317(16) 0.0497(12) Uani 1 1 d . . . . .
F34 F 0.2985(3) 0.2416(5) 0.11558(19) 0.0583(15) Uani 1 1 d . . . . .
F35 F 0.2550(6) 0.1094(7) 0.1780(3) 0.112(4) Uani 1 1 d . . . . .
F36 F 0.2491(6) 0.0164(12) 0.1195(3) 0.153(5) Uani 1 1 d . . . . .
F37 F 0.3717(13) -0.021(2) 0.2067(4) 0.312(17) Uani 1 1 d . . . . .
F38 F 0.3534(9) -0.1050(6) 0.1471(3) 0.141(5) Uani 1 1 d . . . . .
F39 F 0.2529(10) -0.0959(8) 0.1824(3) 0.175(7) Uani 1 1 d . . . . .
F41 F 1.1125(3) 0.4479(4) -0.13831(15) 0.0418(10) Uani 1 1 d . . . . .
F42 F 1.0287(2) 0.5592(4) -0.11806(15) 0.0396(10) Uani 1 1 d . . . . .
F43 F 1.1494(4) 0.7133(4) -0.1260(2) 0.0536(14) Uani 1 1 d . . . . .
F44 F 1.0846(4) 0.6444(6) -0.18000(19) 0.0672(18) Uani 1 1 d . . . . .
F45 F 1.2315(4) 0.7450(5) -0.1903(2) 0.0656(17) Uani 1 1 d . . . . .
F46 F 1.2008(5) 0.6136(7) -0.2300(2) 0.085(2) Uani 1 1 d . . . . .
F47 F 1.3330(4) 0.5143(5) -0.1991(2) 0.0657(17) Uani 1 1 d . . . . .
F48 F 1.3633(4) 0.6408(6) -0.1559(3) 0.080(2) Uani 1 1 d . . . . .
F49 F 1.3560(5) 0.6660(8) -0.2227(3) 0.104(3) Uani 1 1 d . . . . .
F51 F 1.1071(3) 0.1438(5) 0.11156(17) 0.0530(13) Uani 1 1 d . . . . .
F52 F 1.0012(3) 0.2373(3) 0.10908(16) 0.0424(10) Uani 1 1 d . . . . .
F53 F 0.9248(4) 0.0467(6) 0.12993(18) 0.073(2) Uani 1 1 d . . . . .
F54 F 1.0424(6) -0.0131(5) 0.1432(2) 0.090(3) Uani 1 1 d . . . . .
F55 F 0.9660(6) -0.0064(6) 0.2125(2) 0.087(3) Uani 1 1 d . . . . .
F56 F 1.0876(5) 0.0449(7) 0.2255(2) 0.090(3) Uani 1 1 d . . . . .
F57 F 1.0003(5) 0.1032(6) 0.28446(18) 0.0725(19) Uani 1 1 d . . . . .
F58 F 1.0325(5) 0.2343(6) 0.2483(2) 0.081(2) Uani 1 1 d . . . . .
F59 F 0.9156(5) 0.1769(8) 0.2392(2) 0.093(3) Uani 1 1 d . . . . .
F61 F 0.8906(4) 0.1859(4) -0.12170(18) 0.0624(16) Uani 1 1 d . . . . .
F62 F 0.9695(4) 0.3110(5) -0.13459(19) 0.0579(15) Uani 1 1 d . . . . .
F63 F 0.7642(3) 0.3240(5) -0.1316(2) 0.0668(18) Uani 1 1 d . . . . .
F64 F 0.8260(6) 0.2904(4) -0.1853(2) 0.079(2) Uani 1 1 d . . . . .
F65 F 0.7347(4) 0.5209(6) -0.1510(3) 0.094(3) Uani 1 1 d . . . . .
F66 F 0.7689(5) 0.4714(6) -0.2101(3) 0.096(3) Uani 1 1 d . . . . .
F67 F 0.7879(4) 0.6767(5) -0.1976(2) 0.0644(16) Uani 1 1 d . . . . .
F68 F 0.8992(4) 0.5978(6) -0.1973(3) 0.094(3) Uani 1 1 d . . . . .
F69 F 0.8592(5) 0.6455(5) -0.1401(3) 0.084(2) Uani 1 1 d . . . . .
O11 O 0.6306(2) 0.0496(3) 0.04065(17) 0.0308(10) Uani 1 1 d . . . . .
O12 O 0.6562(2) -0.1276(3) 0.06013(16) 0.0296(9) Uani 1 1 d . . . . .
O13 O 0.7647(2) -0.0030(3) 0.06713(17) 0.0311(10) Uani 1 1 d . . . . .
O14 O 0.7222(4) -0.1262(5) 0.1526(2) 0.0460(13) Uani 1 1 d . . . . .
O21 O 0.5311(2) 0.3335(3) -0.03225(16) 0.0289(9) Uani 1 1 d . . . . .
O22 O 0.3937(3) 0.3876(4) -0.03796(18) 0.0385(11) Uani 1 1 d . . . . .
O23 O 0.4968(2) 0.5090(3) -0.05282(15) 0.0295(10) Uani 1 1 d . . . . .
O24 O 0.5040(4) 0.3435(7) -0.1714(2) 0.0584(18) Uani 1 1 d . . . . .
O31 O 0.5098(2) 0.2152(3) 0.04831(17) 0.0301(9) Uani 1 1 d . . . . .
O32 O 0.4310(3) 0.0652(3) 0.06564(17) 0.0324(10) Uani 1 1 d . . . . .
O33 O 0.3665(3) 0.2233(4) 0.03769(18) 0.0341(10) Uani 1 1 d . . . . .
O34 O 0.3643(5) 0.1031(5) 0.1443(2) 0.0545(17) Uani 1 1 d . . . . .
O41 O 1.1090(2) 0.4447(3) -0.05005(15) 0.0259(8) Uani 1 1 d . . . . .
O42 O 1.2357(2) 0.5113(3) -0.06845(17) 0.0297(9) Uani 1 1 d . . . . .
O43 O 1.1342(2) 0.6285(3) -0.04628(17) 0.0291(9) Uani 1 1 d . . . . .
O44 O 1.2085(3) 0.5913(4) -0.16026(18) 0.0393(11) Uani 1 1 d . . . . .
O51 O 1.0463(2) 0.1624(3) 0.02746(15) 0.0266(8) Uani 1 1 d . . . . .
O52 O 1.0213(2) -0.0105(3) 0.05271(16) 0.0271(8) Uani 1 1 d . . . . .
O53 O 0.9146(2) 0.1157(4) 0.04417(17) 0.0333(10) Uani 1 1 d . . . . .
O54 O 1.0081(4) 0.1265(5) 0.17650(17) 0.0423(13) Uani 1 1 d . . . . .
O61 O 0.9856(2) 0.2817(3) -0.04939(17) 0.0311(10) Uani 1 1 d . . . . .
O62 O 0.9045(3) 0.4351(3) -0.06373(17) 0.0309(9) Uani 1 1 d . . . . .
O63 O 0.8434(3) 0.2712(4) -0.04811(18) 0.0346(11) Uani 1 1 d . . . . .
O64 O 0.8496(3) 0.4398(4) -0.15262(17) 0.0374(11) Uani 1 1 d . . . . .
OW1 O 0.6317(2) 0.3549(3) 0.05363(15) 0.0266(8) Uani 1 1 d . . . . .
OW2 O 0.7528(2) 0.2022(3) 0.03787(16) 0.0272(9) Uani 1 1 d . . . . .
OW3 O 0.6971(2) 0.3312(3) -0.02878(17) 0.0319(10) Uani 1 1 d . . . . .
OW4 O 0.5128(2) 0.1134(3) -0.03271(17) 0.0321(10) Uani 1 1 d . . . . .
OW5 O 0.6751(3) 0.1090(4) -0.04419(17) 0.0325(10) Uani 1 1 d . . . . .
OW6 O 1.2354(2) 0.2980(3) -0.04467(17) 0.0298(10) Uani 1 1 d . . . . .
OW7 O 1.2096(2) 0.1701(4) 0.02344(17) 0.0324(10) Uani 1 1 d . . . . .
OW8 O 1.1907(2) 0.3947(4) 0.03801(17) 0.0339(10) Uani 1 1 d . . . . .
OW9 O 1.0275(2) 0.3871(3) 0.02824(17) 0.0310(9) Uani 1 1 d . . . . .
OW10 O 1.1088(2) 0.1441(3) -0.05844(15) 0.0259(8) Uani 1 1 d . . . . .
OW11 O 1.3378(3) 0.4627(4) 0.0341(2) 0.0379(11) Uani 1 1 d . . . . .
OW12 O 0.8247(3) 0.0359(3) -0.02950(18) 0.0338(10) Uani 1 1 d . . . . .
C11 C 0.6550(4) 0.0154(6) 0.1186(3) 0.0379(15) Uani 1 1 d . . . . .
C12 C 0.7117(5) -0.0216(7) 0.1570(3) 0.0452(18) Uani 1 1 d . . . . .
C13 C 0.7494(10) -0.1795(15) 0.1875(6) 0.049(4) Uiso 0.507(14) 1 d D . P A 1
C14 C 0.7924(7) -0.2743(11) 0.1710(3) 0.053(5) Uiso 0.507(14) 1 d D . P A 1
F15 F 0.8102(8) -0.1264(11) 0.2109(4) 0.054(4) Uiso 0.507(14) 1 d D . P A 1
F16 F 0.6897(10) -0.2139(14) 0.2083(5) 0.084(5) Uiso 0.507(14) 1 d . . P A 1
F17 F 0.7481(7) -0.3276(9) 0.1426(4) 0.039(3) Uiso 0.507(14) 1 d D . P A 1
F18 F 0.8159(8) -0.3425(10) 0.2000(4) 0.051(3) Uiso 0.507(14) 1 d D . P A 1
F19 F 0.8559(7) -0.2408(11) 0.1550(4) 0.057(3) Uiso 0.507(14) 1 d D . P A 1
C130 C 0.7853(12) -0.1814(14) 0.1765(5) 0.043(4) Uiso 0.493(14) 1 d D . P A 2
C140 C 0.7564(7) -0.2885(12) 0.1842(4) 0.043(4) Uiso 0.493(14) 1 d D . P A 2
F150 F 0.7902(10) -0.1377(12) 0.2161(4) 0.055(4) Uiso 0.493(14) 1 d D . P A 2
F160 F 0.8493(8) -0.1815(13) 0.1569(4) 0.063(4) Uiso 0.493(14) 1 d . . P A 2
F170 F 0.7363(11) -0.3398(14) 0.1494(4) 0.069(5) Uiso 0.493(14) 1 d D . P A 2
F180 F 0.8085(10) -0.3363(13) 0.2107(5) 0.069(5) Uiso 0.493(14) 1 d D . P A 2
F190 F 0.6893(8) -0.2897(13) 0.2012(5) 0.073(4) Uiso 0.493(14) 1 d D . P A 2
C21 C 0.4575(4) 0.3643(5) -0.1058(2) 0.0340(13) Uani 1 1 d . . . . .
C22 C 0.5299(5) 0.3607(7) -0.1301(3) 0.0433(17) Uani 1 1 d . . . . .
C23 C 0.5478(9) 0.3619(17) -0.2024(4) 0.098(6) Uani 1 1 d . . . . .
C24 C 0.5057(11) 0.3273(17) -0.2434(4) 0.103(7) Uani 1 1 d . . . . .
C31 C 0.4363(4) 0.2310(4) 0.1130(2) 0.0291(12) Uani 1 1 d . . . . .
C32 C 0.3654(5) 0.2070(6) 0.1376(2) 0.0348(14) Uani 1 1 d . . . . .
C33 C 0.3021(7) 0.0549(9) 0.1585(4) 0.068(3) Uani 1 1 d . . . . .
C34 C 0.3228(17) -0.0508(10) 0.1721(7) 0.157(12) Uani 1 1 d . . . . .
C41 C 1.1061(4) 0.5394(5) -0.1202(2) 0.0298(11) Uani 1 1 d . . . . .
C42 C 1.1383(5) 0.6249(6) -0.1477(3) 0.0393(16) Uani 1 1 d . . . . .
C43 C 1.2378(6) 0.6439(8) -0.1933(3) 0.051(2) Uani 1 1 d . . . . .
C44 C 1.3254(6) 0.6161(9) -0.1930(4) 0.058(3) Uani 1 1 d . . . . .
C51 C 1.0280(4) 0.1423(5) 0.1054(2) 0.0302(12) Uani 1 1 d . . . . .
C52 C 0.9996(5) 0.0742(6) 0.1403(3) 0.0418(16) Uani 1 1 d . . . . .
C53 C 1.0137(7) 0.0747(8) 0.2138(3) 0.052(2) Uani 1 1 d . . . . .
C54 C 0.9898(7) 0.1488(10) 0.2474(3) 0.057(2) Uani 1 1 d . . . . .
C61 C 0.9009(5) 0.2886(5) -0.1196(2) 0.0363(14) Uani 1 1 d . . . . .
C62 C 0.8324(6) 0.3378(6) -0.1484(3) 0.0458(19) Uani 1 1 d . . . . .
C63 C 0.7959(5) 0.5062(7) -0.1730(3) 0.0472(19) Uani 1 1 d . . . . .
C64 C 0.8373(5) 0.6095(7) -0.1773(3) 0.0467(19) Uani 1 1 d . . . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O21 Eu1 OW3 72.15(15) . . ?
O21 Eu1 OW1 81.33(17) . . ?
OW3 Eu1 OW1 78.03(17) . . ?
O21 Eu1 OW5 107.20(18) . . ?
OW3 Eu1 OW5 75.77(17) . . ?
OW1 Eu1 OW5 148.10(15) . . ?
O21 Eu1 O31 79.94(17) . . ?
OW3 Eu1 O31 139.95(15) . . ?
OW1 Eu1 O31 69.71(15) . . ?
OW5 Eu1 O31 141.32(16) . . ?
O21 Eu1 O11 146.86(14) . . ?
OW3 Eu1 O11 138.86(14) . . ?
OW1 Eu1 O11 111.96(17) . . ?
OW5 Eu1 O11 77.96(18) . . ?
O31 Eu1 O11 77.05(16) . . ?
O21 Eu1 OW2 139.86(14) . . ?
OW3 Eu1 OW2 71.42(16) . . ?
OW1 Eu1 OW2 75.21(15) . . ?
OW5 Eu1 OW2 79.42(17) . . ?
O31 Eu1 OW2 119.98(18) . . ?
O11 Eu1 OW2 73.05(14) . . ?
O21 Eu1 OW4 73.09(16) . . ?
OW3 Eu1 OW4 121.43(19) . . ?
OW1 Eu1 OW4 139.12(15) . . ?
OW5 Eu1 OW4 71.52(16) . . ?
O31 Eu1 OW4 74.75(17) . . ?
O11 Eu1 OW4 78.05(16) . . ?
OW2 Eu1 OW4 142.50(14) . . ?
OW10 Eu2 O51 80.48(15) . . ?
OW10 Eu2 OW7 78.16(17) . . ?
O51 Eu2 OW7 71.55(15) . . ?
OW10 Eu2 O61 71.30(16) . . ?
O51 Eu2 O61 78.04(17) . . ?
OW7 Eu2 O61 139.79(15) . . ?
OW10 Eu2 OW8 148.99(15) . . ?
O51 Eu2 OW8 108.13(18) . . ?
OW7 Eu2 OW8 76.74(18) . . ?
O61 Eu2 OW8 139.06(16) . . ?
OW10 Eu2 O41 108.63(16) . . ?
O51 Eu2 O41 148.14(14) . . ?
OW7 Eu2 O41 139.54(14) . . ?
O61 Eu2 O41 76.44(15) . . ?
OW8 Eu2 O41 80.11(17) . . ?
OW10 Eu2 OW9 140.25(14) . . ?
O51 Eu2 OW9 74.95(15) . . ?
OW7 Eu2 OW9 121.21(19) . . ?
O61 Eu2 OW9 73.34(17) . . ?
OW8 Eu2 OW9 69.74(16) . . ?
O41 Eu2 OW9 79.67(16) . . ?
OW10 Eu2 OW6 74.73(15) . . ?
O51 Eu2 OW6 138.90(14) . . ?
OW7 Eu2 OW6 71.62(16) . . ?
O61 Eu2 OW6 122.27(18) . . ?
OW8 Eu2 OW6 80.27(17) . . ?
O41 Eu2 OW6 72.09(14) . . ?
OW9 Eu2 OW6 141.76(14) . . ?
O12 S1 O13 115.5(3) . . ?
O12 S1 O11 112.5(3) . . ?
O13 S1 O11 113.8(3) . . ?
O12 S1 C11 107.3(3) . . ?
O13 S1 C11 105.9(3) . . ?
O11 S1 C11 100.3(3) . . ?
O23 S2 O22 114.9(3) . . ?
O23 S2 O21 113.6(3) . . ?
O22 S2 O21 113.5(3) . . ?
O23 S2 C21 104.5(3) . . ?
O22 S2 C21 103.6(3) . . ?
O21 S2 C21 105.3(3) . . ?
O33 S3 O32 115.5(3) . . ?
O33 S3 O31 113.5(3) . . ?
O32 S3 O31 114.6(3) . . ?
O33 S3 C31 104.3(3) . . ?
O32 S3 C31 105.7(3) . . ?
O31 S3 C31 101.2(3) . . ?
O42 S4 O43 115.5(3) . . ?
O42 S4 O41 114.5(3) . . ?
O43 S4 O41 112.1(3) . . ?
O42 S4 C41 105.7(3) . . ?
O43 S4 C41 105.9(3) . . ?
O41 S4 C41 101.5(3) . . ?
O53 S5 O52 115.0(3) . . ?
O53 S5 O51 114.3(3) . . ?
O52 S5 O51 113.6(3) . . ?
O53 S5 C51 106.1(3) . . ?
O52 S5 C51 103.8(3) . . ?
O51 S5 C51 102.2(3) . . ?
O63 S6 O62 115.7(3) . . ?
O63 S6 O61 113.6(3) . . ?
O62 S6 O61 114.0(3) . . ?
O63 S6 C61 105.2(4) . . ?
O62 S6 C61 105.2(3) . . ?
O61 S6 C61 101.1(3) . . ?
S1 O11 Eu1 148.4(3) . . ?
C13 O14 C12 116.8(10) . . ?
C12 O14 C130 122.0(9) . . ?
S2 O21 Eu1 172.8(3) . . ?
C23 O24 C22 123.6(9) . . ?
S3 O31 Eu1 153.1(3) . . ?
C33 O34 C32 122.3(8) . . ?
S4 O41 Eu2 147.8(3) . . ?
C42 O44 C43 117.6(7) . . ?
S5 O51 Eu2 173.0(3) . . ?
C52 O54 C53 120.5(7) . . ?
S6 O61 Eu2 154.7(3) . . ?
C62 O64 C63 121.2(7) . . ?
F11 C11 F12 109.3(6) . . ?
F11 C11 C12 108.1(7) . . ?
F12 C11 C12 106.2(7) . . ?
F11 C11 S1 107.7(5) . . ?
F12 C11 S1 108.2(6) . . ?
C12 C11 S1 117.2(5) . . ?
F13 C12 F14 107.7(8) . . ?
F13 C12 O14 112.6(8) . . ?
F14 C12 O14 112.0(8) . . ?
F13 C12 C11 109.2(7) . . ?
F14 C12 C11 108.0(7) . . ?
O14 C12 C11 107.2(7) . . ?
F16 C13 O14 112.0(15) . . ?
F16 C13 F15 116.3(17) . . ?
O14 C13 F15 111.4(14) . . ?
F16 C13 C14 108.4(15) . . ?
O14 C13 C14 104.3(13) . . ?
F15 C13 C14 103.2(14) . . ?
F18 C14 F19 107.5(13) . . ?
F18 C14 F17 104.5(13) . . ?
F19 C14 F17 109.2(12) . . ?
F18 C14 C13 113.8(13) . . ?
F19 C14 C13 108.0(13) . . ?
F17 C14 C13 113.5(12) . . ?
F160 C130 F150 118.1(16) . . ?
F160 C130 O14 110.4(13) . . ?
F150 C130 O14 105.0(13) . . ?
F160 C130 C140 112.3(15) . . ?
F150 C130 C140 102.2(13) . . ?
O14 C130 C140 108.1(13) . . ?
F170 C140 F180 114.3(16) . . ?
F170 C140 F190 101.2(14) . . ?
F180 C140 F190 105.9(14) . . ?
F170 C140 C130 112.6(13) . . ?
F180 C140 C130 109.5(14) . . ?
F190 C140 C130 113.0(14) . . ?
F21 C21 F22 108.3(6) . . ?
F21 C21 C22 107.5(7) . . ?
F22 C21 C22 106.3(7) . . ?
F21 C21 S2 109.5(5) . . ?
F22 C21 S2 106.4(5) . . ?
C22 C21 S2 118.5(5) . . ?
F24 C22 F23 105.9(8) . . ?
F24 C22 O24 113.3(8) . . ?
F23 C22 O24 110.2(8) . . ?
F24 C22 C21 110.8(7) . . ?
F23 C22 C21 108.4(7) . . ?
O24 C22 C21 108.2(7) . . ?
F25 C23 O24 114.2(13) . . ?
F25 C23 F26 107.5(15) . . ?
O24 C23 F26 109.4(14) . . ?
F25 C23 C24 113.2(13) . . ?
O24 C23 C24 111.0(14) . . ?
F26 C23 C24 100.6(14) . . ?
F29 C24 F27 112.6(13) . . ?
F29 C24 F28 107.4(13) . . ?
F27 C24 F28 106.0(19) . . ?
F29 C24 C23 113.1(18) . . ?
F27 C24 C23 113.2(13) . . ?
F28 C24 C23 103.7(13) . . ?
F32 C31 F31 107.9(6) . . ?
F32 C31 C32 107.6(5) . . ?
F31 C31 C32 106.5(6) . . ?
F32 C31 S3 107.7(5) . . ?
F31 C31 S3 109.0(5) . . ?
C32 C31 S3 117.7(5) . . ?
F33 C32 F34 106.4(7) . . ?
F33 C32 O34 111.3(7) . . ?
F34 C32 O34 112.7(7) . . ?
F33 C32 C31 110.1(6) . . ?
F34 C32 C31 108.6(6) . . ?
O34 C32 C31 107.7(6) . . ?
F35 C33 O34 117.7(10) . . ?
F35 C33 C34 120.5(11) . . ?
O34 C33 C34 111.2(13) . . ?
F35 C33 F36 103.8(10) . . ?
O34 C33 F36 106.2(11) . . ?
C34 C33 F36 92.4(14) . . ?
F38 C34 F37 116(3) . . ?
F38 C34 F39 110.5(15) . . ?
F37 C34 F39 112.3(14) . . ?
F38 C34 C33 116.2(15) . . ?
F37 C34 C33 94.7(16) . . ?
F39 C34 C33 106(2) . . ?
F41 C41 F42 108.5(5) . . ?
F41 C41 C42 109.3(6) . . ?
F42 C41 C42 107.4(6) . . ?
F41 C41 S4 108.7(5) . . ?
F42 C41 S4 106.2(5) . . ?
C42 C41 S4 116.5(5) . . ?
F44 C42 F43 107.0(7) . . ?
F44 C42 O44 111.9(7) . . ?
F43 C42 O44 110.3(7) . . ?
F44 C42 C41 109.2(6) . . ?
F43 C42 C41 110.1(7) . . ?
O44 C42 C41 108.3(6) . . ?
F45 C43 F46 108.7(9) . . ?
F45 C43 O44 112.9(8) . . ?
F46 C43 O44 111.1(8) . . ?
F45 C43 C44 108.7(8) . . ?
F46 C43 C44 107.5(9) . . ?
O44 C43 C44 107.8(8) . . ?
F49 C44 F48 110.3(10) . . ?
F49 C44 F47 108.9(10) . . ?
F48 C44 F47 108.8(10) . . ?
F49 C44 C43 110.0(10) . . ?
F48 C44 C43 108.9(9) . . ?
F47 C44 C43 109.9(8) . . ?
F52 C51 F51 108.8(6) . . ?
F52 C51 C52 109.1(6) . . ?
F51 C51 C52 106.6(6) . . ?
F52 C51 S5 108.4(5) . . ?
F51 C51 S5 108.3(5) . . ?
C52 C51 S5 115.4(5) . . ?
F53 C52 F54 106.8(8) . . ?
F53 C52 O54 111.3(8) . . ?
F54 C52 O54 111.0(7) . . ?
F53 C52 C51 109.4(7) . . ?
F54 C52 C51 108.8(7) . . ?
O54 C52 C51 109.5(6) . . ?
F55 C53 F56 109.5(9) . . ?
F55 C53 O54 112.0(8) . . ?
F56 C53 O54 111.4(9) . . ?
F55 C53 C54 108.2(9) . . ?
F56 C53 C54 107.1(8) . . ?
O54 C53 C54 108.4(8) . . ?
F59 C54 F58 106.6(10) . . ?
F59 C54 F57 109.8(9) . . ?
F58 C54 F57 109.3(9) . . ?
F59 C54 C53 110.6(9) . . ?
F58 C54 C53 110.7(9) . . ?
F57 C54 C53 109.8(9) . . ?
F62 C61 F61 107.9(7) . . ?
F62 C61 C62 108.6(7) . . ?
F61 C61 C62 107.0(7) . . ?
F62 C61 S6 109.2(6) . . ?
F61 C61 S6 106.9(5) . . ?
C62 C61 S6 116.9(6) . . ?
F64 C62 F63 108.0(8) . . ?
F64 C62 O64 110.8(7) . . ?
F63 C62 O64 111.8(8) . . ?
F64 C62 C61 109.4(8) . . ?
F63 C62 C61 109.0(7) . . ?
O64 C62 C61 107.7(7) . . ?
F66 C63 F65 108.6(9) . . ?
F66 C63 O64 111.8(8) . . ?
F65 C63 O64 110.4(8) . . ?
F66 C63 C64 109.7(8) . . ?
F65 C63 C64 108.5(8) . . ?
O64 C63 C64 107.8(7) . . ?
F68 C64 F69 109.4(9) . . ?
F68 C64 F67 109.4(8) . . ?
F69 C64 F67 108.8(8) . . ?
F68 C64 C63 110.4(9) . . ?
F69 C64 C63 108.5(8) . . ?
F67 C64 C63 110.3(7) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O21 2.375(4) . yes
Eu1 OW3 2.383(4) . yes
Eu1 OW1 2.384(4) . yes
Eu1 OW5 2.389(5) . yes
Eu1 O31 2.397(4) . yes
Eu1 O11 2.399(4) . yes
Eu1 OW2 2.415(4) . yes
Eu1 OW4 2.425(4) . yes
Eu2 OW10 2.381(4) . yes
Eu2 O51 2.381(4) . yes
Eu2 OW7 2.383(4) . yes
Eu2 O61 2.386(5) . yes
Eu2 OW8 2.389(5) . yes
Eu2 O41 2.409(4) . yes
Eu2 OW9 2.418(4) . yes
Eu2 OW6 2.433(4) . yes
S1 O12 1.430(4) . ?
S1 O13 1.448(4) . ?
S1 O11 1.459(4) . ?
S1 C11 1.836(8) . ?
S2 O23 1.440(4) . ?
S2 O22 1.445(5) . ?
S2 O21 1.446(4) . ?
S2 C21 1.797(8) . ?
S3 O33 1.433(5) . ?
S3 O32 1.455(5) . ?
S3 O31 1.458(4) . ?
S3 C31 1.826(7) . ?
S4 O42 1.448(4) . ?
S4 O43 1.454(5) . ?
S4 O41 1.456(4) . ?
S4 C41 1.842(7) . ?
S5 O53 1.431(4) . ?
S5 O52 1.446(4) . ?
S5 O51 1.457(4) . ?
S5 C51 1.838(7) . ?
S6 O63 1.433(5) . ?
S6 O62 1.439(4) . ?
S6 O61 1.455(4) . ?
S6 C61 1.829(8) . ?
F11 C11 1.342(8) . ?
F12 C11 1.345(9) . ?
F13 C12 1.330(10) . ?
F14 C12 1.338(11) . ?
F21 C21 1.339(8) . ?
F22 C21 1.362(9) . ?
F23 C22 1.343(11) . ?
F24 C22 1.322(10) . ?
F25 C23 1.311(17) . ?
F26 C23 1.41(2) . ?
F27 C24 1.296(18) . ?
F28 C24 1.38(2) . ?
F29 C24 1.289(18) . ?
F31 C31 1.343(8) . ?
F32 C31 1.340(7) . ?
F33 C32 1.318(9) . ?
F34 C32 1.347(10) . ?
F35 C33 1.279(14) . ?
F36 C33 1.544(17) . ?
F37 C34 1.37(3) . ?
F38 C34 1.223(17) . ?
F39 C34 1.39(2) . ?
F41 C41 1.329(8) . ?
F42 C41 1.343(7) . ?
F43 C42 1.343(10) . ?
F44 C42 1.330(10) . ?
F45 C43 1.315(12) . ?
F46 C43 1.335(13) . ?
F47 C44 1.338(13) . ?
F48 C44 1.333(13) . ?
F49 C44 1.305(12) . ?
F51 C51 1.334(7) . ?
F52 C51 1.318(8) . ?
F53 C52 1.323(10) . ?
F54 C52 1.337(10) . ?
F55 C53 1.320(12) . ?
F56 C53 1.324(13) . ?
F57 C54 1.326(12) . ?
F58 C54 1.319(14) . ?
F59 C54 1.306(13) . ?
F61 C61 1.338(9) . ?
F62 C61 1.337(10) . ?
F63 C62 1.340(11) . ?
F64 C62 1.332(10) . ?
F65 C63 1.331(12) . ?
F66 C63 1.311(12) . ?
F67 C64 1.327(10) . ?
F68 C64 1.296(11) . ?
F69 C64 1.303(12) . ?
O14 C13 1.355(19) . ?
O14 C12 1.373(11) . ?
O14 C130 1.437(19) . ?
O24 C23 1.327(15) . ?
O24 C22 1.372(11) . ?
O34 C33 1.347(12) . ?
O34 C32 1.359(9) . ?
O44 C42 1.366(9) . ?
O44 C43 1.398(10) . ?
O54 C52 1.342(10) . ?
O54 C53 1.371(11) . ?
O64 C62 1.360(9) . ?
O64 C63 1.366(10) . ?
C11 C12 1.557(12) . ?
C13 F16 1.35(2) . ?
C13 F15 1.391(12) . ?
C13 C14 1.55(3) . ?
C14 F18 1.314(6) . ?
C14 F19 1.314(6) . ?
C14 F17 1.314(6) . ?
C130 F160 1.31(2) . ?
C130 F150 1.391(12) . ?
C130 C140 1.50(2) . ?
C140 F170 1.314(6) . ?
C140 F180 1.314(6) . ?
C140 F190 1.314(6) . ?
C21 C22 1.527(11) . ?
C23 C24 1.50(2) . ?
C31 C32 1.542(10) . ?
C33 C34 1.46(2) . ?
C41 C42 1.552(10) . ?
C43 C44 1.524(14) . ?
C51 C52 1.544(11) . ?
C53 C54 1.531(14) . ?
C61 C62 1.542(12) . ?
C63 C64 1.520(12) . ?
