#------------------------------------------------------------------------------
#$Date: 2018-07-12 00:31:41 +0300 (Thu, 12 Jul 2018) $
#$Revision: 208980 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/10/13/7101389.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7101389
loop_
_publ_author_name
'Yang, Xiaoping'
'Hahn, Benjamin P.'
'Jones, Richard A.'
'Stevenson, Keith J.'
'Swinnea, J. Steven'
'Wu, Qiaoyin'
_publ_section_title
;
 Reversible guest molecule encapsulation in the 3-D framework of
 a heteropolynuclear luminescent Zn4Eu2 cage complex
;
_journal_coden_ASTM              CHCOFS
_journal_issue                   36
_journal_name_full
;
 Chemical Communications (Cambridge, United Kingdom)
;
_journal_page_first              3827
_journal_page_last               3829
_journal_paper_doi               10.1039/b607183j
_journal_year                    2006
_chemical_formula_sum            'C52 H64 Br4 Eu2 N2 O34 Zn4'
_chemical_formula_weight         2146.09
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                102.47(3)
_cell_angle_beta                 104.01(3)
_cell_angle_gamma                101.11(3)
_cell_formula_units_Z            1
_cell_length_a                   11.390(2)
_cell_length_b                   13.007(3)
_cell_length_c                   13.194(3)
_cell_measurement_reflns_used    CCD
_cell_measurement_temperature    153(1)
_cell_volume                     1788.8(6)
_computing_cell_refinement       'Collect software, Nonius B.V. 1998'
_computing_data_collection       'Collect software, Nonius B.V. 1998'
_computing_data_reduction
;
DENZO and Scalepack (Otwinoski and Minor, 1997)
;
_computing_molecular_graphics    'XL SHELXTL/PC, Siemens Analytical'
_computing_structure_refinement  'XL SHELXTL/PC, Siemens Analytical'
_computing_structure_solution
;

SIR97 - Altomare A., Burla M.C., Camalli M., Cascarano G.L., Giacovazzo C.,
Guagliardi A., Moliterni A.G.G., Polidori G.,Spagna R.
;
_diffrn_ambient_temperature      153(1)
_diffrn_measured_fraction_theta_full 0.989
_diffrn_measured_fraction_theta_max 0.989
_diffrn_measurement_device_type  CCD
_diffrn_measurement_method       ω-scans
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0317
_diffrn_reflns_av_sigmaI/netI    0.0654
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            12619
_diffrn_reflns_theta_full        27.52
_diffrn_reflns_theta_max         27.52
_diffrn_reflns_theta_min         3.27
_exptl_absorpt_coefficient_mu    5.368
_exptl_absorpt_correction_T_max  0.5219
_exptl_absorpt_correction_T_min  0.3356
_exptl_absorpt_correction_type   gaussian
_exptl_absorpt_process_details
;
Absorption correction given as Gaussian
;
_exptl_crystal_colour            Yellow
_exptl_crystal_density_diffrn    1.992
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Block
_exptl_crystal_F_000             1048
_exptl_crystal_size_max          0.25
_exptl_crystal_size_mid          0.22
_exptl_crystal_size_min          0.18
_refine_diff_density_max         1.285
_refine_diff_density_min         -1.575
_refine_diff_density_rms         0.170
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   0.10(8)
_refine_ls_extinction_coef       0.0031(4)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.050
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     447
_refine_ls_number_reflns         8137
_refine_ls_number_restraints     295
_refine_ls_restrained_S_all      1.050
_refine_ls_R_factor_all          0.0659
_refine_ls_R_factor_gt           0.0398
_refine_ls_shift/su_max          0.006
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0397P)²+3.8114P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0894
_refine_ls_wR_factor_ref         0.0988
_reflns_number_gt                6104
_reflns_number_total             8137
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b607183j.txt
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from
2010-06-29.

'_exptl_absorpt_correction_type' value 'Gaussian' changed to
'gaussian' according to
'/home/saulius/struct/CIF-dictionaries/cif_core.dic' dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7101389
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Eu1 Eu 0.510874(16) 0.233950(13) -0.009117(13) 0.01674(4) Uani 1 1 d U
Zn2 Zn 0.78148(4) 0.13957(3) 0.05712(3) 0.01754(9) Uani 1 1 d U
Zn1 Zn 0.60071(3) 0.05320(3) -0.20322(3) 0.01505(9) Uani 1 1 d U
Br1 Br 1.18262(4) 0.67683(3) 0.20154(4) 0.03721(11) Uani 1 1 d U
Br1' Br 0.41381(4) 0.34985(3) -0.59257(3) 0.03413(10) Uani 1 1 d U
N1 N 0.4176(3) 0.3681(2) 0.1506(2) 0.0249(7) Uani 1 1 d U
O1 O 0.9601(2) 0.27225(19) 0.1718(2) 0.0304(7) Uani 1 1 d U
O2 O 0.7406(2) 0.28508(17) 0.06552(17) 0.0169(6) Uani 1 1 d U
O3 O 0.6070(2) 0.41289(18) -0.03384(18) 0.0195(6) Uani 1 1 d U
O1' O 0.5984(2) 0.10232(18) -0.36130(18) 0.0208(6) Uani 1 1 d U
O2' O 0.5278(2) 0.18479(16) -0.19542(16) 0.0136(5) Uani 1 1 d U
O3' O 0.3629(2) 0.30811(17) -0.12868(17) 0.0175(6) Uani 1 1 d U
O4 O 0.8931(2) 0.1132(2) -0.0309(2) 0.0353(7) Uani 1 1 d U
O5 O 0.7711(2) 0.0474(2) -0.20382(19) 0.0258(6) Uani 1 1 d U
O6 O 0.8071(2) 0.08084(18) 0.18166(18) 0.0207(6) Uani 1 1 d U
O7 O 0.5245(2) 0.14789(17) 0.14064(17) 0.0169(6) Uani 1 1 d U
O8 O 0.5325(2) 0.38976(19) 0.15477(19) 0.0262(6) Uani 1 1 d U
O9 O 0.3459(2) 0.2839(2) 0.07893(19) 0.0243(6) Uani 1 1 d U
O10 O 0.6639(2) -0.07536(17) 0.09254(18) 0.0184(6) Uani 1 1 d U
O11 O 0.60845(19) 0.08040(17) -0.04658(16) 0.0133(5) Uani 1 1 d DU
H11A H 0.5715 0.0293 -0.0275 0.016 Uiso 1 1 d RD
O12 O 0.3782(3) 0.4282(2) 0.2119(2) 0.0355(7) Uani 1 1 d U
O13 O 0.5285(2) 0.08272(17) 0.28389(17) 0.0175(6) Uani 1 1 d U
C1 C 1.0807(4) 0.2531(4) 0.2103(5) 0.0610(16) Uani 1 1 d U
H1A H 1.1205 0.2967 0.2841 0.092 Uiso 1 1 calc R
H1B H 1.1316 0.2725 0.1656 0.092 Uiso 1 1 calc R
H1C H 1.0709 0.1774 0.2072 0.092 Uiso 1 1 calc R
C2 C 0.9559(3) 0.3704(3) 0.1515(3) 0.0224(9) Uani 1 1 d U
C3 C 1.0586(3) 0.4585(3) 0.1818(3) 0.0256(9) Uani 1 1 d U
H3A H 1.1378 0.4537 0.2172 0.031 Uiso 1 1 calc R
C4 C 1.0413(3) 0.5559(3) 0.1581(3) 0.0240(9) Uani 1 1 d U
C5 C 0.9276(3) 0.5623(3) 0.1024(3) 0.0239(9) Uani 1 1 d U
H5A H 0.9184 0.6266 0.0852 0.029 Uiso 1 1 calc R
C6 C 0.8226(3) 0.4712(3) 0.0703(3) 0.0188(8) Uani 1 1 d U
C7 C 0.8359(3) 0.3736(3) 0.0956(3) 0.0171(8) Uani 1 1 d U
C8 C 0.7079(3) 0.4822(3) 0.0041(3) 0.0198(8) Uani 1 1 d U
H8A H 0.7103 0.5487 -0.0118 0.024 Uiso 1 1 calc R
C1' C 0.6693(3) 0.0746(3) -0.4346(3) 0.0271(9) Uani 1 1 d U
H1'A H 0.6139 0.0450 -0.5074 0.041 Uiso 1 1 calc R
H1'B H 0.7113 0.0214 -0.4147 0.041 Uiso 1 1 calc R
H1'C H 0.7301 0.1388 -0.4308 0.041 Uiso 1 1 calc R
C2' C 0.5369(3) 0.1816(3) -0.3733(3) 0.0164(8) Uani 1 1 d U
C3' C 0.5106(3) 0.2172(3) -0.4649(3) 0.0200(8) Uani 1 1 d U
H3'A H 0.5344 0.1871 -0.5249 0.024 Uiso 1 1 calc R
C4' C 0.4479(3) 0.2991(3) -0.4668(3) 0.0233(9) Uani 1 1 d U
C5' C 0.4082(3) 0.3420(3) -0.3809(3) 0.0202(8) Uani 1 1 d U
H5'A H 0.3673 0.3971 -0.3834 0.024 Uiso 1 1 calc R
C6' C 0.4294(3) 0.3021(2) -0.2881(3) 0.0161(8) Uani 1 1 d U
C7' C 0.4981(3) 0.2228(3) -0.2815(2) 0.0144(8) Uani 1 1 d U
C8' C 0.3689(3) 0.3405(3) -0.2089(3) 0.0207(9) Uani 1 1 d U
H8'A H 0.3301 0.3956 -0.2194 0.025 Uiso 1 1 calc R
C9 C 0.8752(3) 0.0804(3) -0.1317(3) 0.0267(9) Uani 1 1 d U
C10 C 0.9919(4) 0.0852(4) -0.1683(4) 0.0458(13) Uani 1 1 d U
H10B H 1.0620 0.0913 -0.1078 0.069 Uiso 1 1 calc R
H10C H 1.0078 0.1474 -0.1959 0.069 Uiso 1 1 calc R
H10D H 0.9798 0.0200 -0.2245 0.069 Uiso 1 1 calc R
C11 C 0.7438(3) -0.0126(2) 0.1777(3) 0.0154(8) Uani 1 1 d U
C12 C 0.7694(3) -0.0451(3) 0.2813(3) 0.0217(9) Uani 1 1 d U
H12B H 0.7657 -0.1214 0.2656 0.032 Uiso 1 1 calc R
H12C H 0.7078 -0.0307 0.3170 0.032 Uiso 1 1 calc R
H12D H 0.8512 -0.0039 0.3279 0.032 Uiso 1 1 calc R
C13 C 0.5682(3) 0.1544(3) 0.2395(3) 0.0160(8) Uani 1 1 d U
C14 C 0.6739(3) 0.2503(3) 0.3102(3) 0.0233(9) Uani 1 1 d U
H14A H 0.7192 0.2313 0.3718 0.035 Uiso 1 1 calc R
H14B H 0.6409 0.3105 0.3347 0.035 Uiso 1 1 calc R
H14C H 0.7293 0.2707 0.2693 0.035 Uiso 1 1 calc R
C15 C 0.9005(8) 0.5308(8) 0.3940(7) 0.139(4) Uani 1 1 d U
H15A H 0.9500 0.4816 0.3760 0.208 Uiso 1 1 calc R
H15B H 0.8319 0.5221 0.3312 0.208 Uiso 1 1 calc R
H15C H 0.8686 0.5151 0.4515 0.208 Uiso 1 1 calc R
C16 C 0.9770(8) 0.6410(7) 0.4289(8) 0.133(4) Uani 1 1 d U
H16A H 1.0460 0.6506 0.4929 0.160 Uiso 1 1 calc R
H16B H 1.0116 0.6567 0.3719 0.160 Uiso 1 1 calc R
C17 C 0.9555(8) 0.8091(6) 0.5037(9) 0.154(5) Uani 1 1 d U
H17A H 0.9990 0.8423 0.4594 0.184 Uiso 1 1 calc R
H17B H 1.0183 0.8106 0.5689 0.184 Uiso 1 1 calc R
C18 C 0.8719(6) 0.8777(5) 0.5362(5) 0.083(2) Uani 1 1 d U
H18A H 0.9214 0.9503 0.5758 0.125 Uiso 1 1 calc R
H18B H 0.8291 0.8467 0.5813 0.125 Uiso 1 1 calc R
H18C H 0.8115 0.8799 0.4723 0.125 Uiso 1 1 calc R
O1W O 0.9027(6) 0.7125(6) 0.4529(5) 0.168(3) Uani 1 1 d U
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Br Br -0.2901 2.4595 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Zn Zn 0.2839 1.4301 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O10 Eu1 O2 140.88(8) 2_655 .
O10 Eu1 O7 79.64(8) 2_655 .
O2 Eu1 O7 82.25(8) . .
O10 Eu1 O2' 79.41(8) 2_655 .
O2 Eu1 O2' 90.42(8) . .
O7 Eu1 O2' 136.07(7) . .
O10 Eu1 O11 75.57(8) 2_655 .
O2 Eu1 O11 65.83(7) . .
O7 Eu1 O11 71.39(8) . .
O2' Eu1 O11 66.18(8) . .
O10 Eu1 O3 142.13(8) 2_655 .
O2 Eu1 O3 68.28(8) . .
O7 Eu1 O3 137.02(7) . .
O2' Eu1 O3 76.58(8) . .
O11 Eu1 O3 119.14(8) . .
O10 Eu1 O3' 79.31(8) 2_655 .
O2 Eu1 O3' 132.64(8) . .
O7 Eu1 O3' 140.92(8) . .
O2' Eu1 O3' 70.52(8) . .
O11 Eu1 O3' 132.94(7) . .
O3 Eu1 O3' 65.28(8) . .
O10 Eu1 O8 126.14(9) 2_655 .
O2 Eu1 O8 81.77(9) . .
O7 Eu1 O8 76.23(8) . .
O2' Eu1 O8 145.57(8) . .
O11 Eu1 O8 136.42(8) . .
O3 Eu1 O8 69.36(8) . .
O3' Eu1 O8 90.38(8) . .
O10 Eu1 O9 77.26(8) 2_655 .
O2 Eu1 O9 129.83(7) . .
O7 Eu1 O9 74.17(8) . .
O2' Eu1 O9 136.39(8) . .
O11 Eu1 O9 139.16(8) . .
O3 Eu1 O9 100.98(8) . .
O3' Eu1 O9 69.28(8) . .
O8 Eu1 O9 50.09(8) . .
O10 Eu1 N1 101.87(8) 2_655 .
O2 Eu1 N1 106.23(8) . .
O7 Eu1 N1 74.46(8) . .
O2' Eu1 N1 147.91(8) . .
O11 Eu1 N1 145.66(8) . .
O3 Eu1 N1 84.27(8) . .
O3' Eu1 N1 78.17(8) . .
O8 Eu1 N1 25.13(8) . .
O9 Eu1 N1 24.99(7) . .
O10 Eu1 Zn2 106.94(6) 2_655 .
O2 Eu1 Zn2 34.02(5) . .
O7 Eu1 Zn2 66.12(6) . .
O2' Eu1 Zn2 83.93(6) . .
O11 Eu1 Zn2 33.64(5) . .
O3 Eu1 Zn2 99.19(6) . .
O3' Eu1 Zn2 152.31(6) . .
O8 Eu1 Zn2 105.91(7) . .
O9 Eu1 Zn2 138.17(6) . .
N1 Eu1 Zn2 124.90(6) . .
O10 Eu1 Zn1 73.27(6) 2_655 .
O2 Eu1 Zn1 77.55(6) . .
O7 Eu1 Zn1 103.09(6) . .
O2' Eu1 Zn1 33.55(5) . .
O11 Eu1 Zn1 32.72(5) . .
O3 Eu1 Zn1 100.32(6) . .
O3' Eu1 Zn1 101.82(6) . .
O8 Eu1 Zn1 159.18(6) . .
O9 Eu1 Zn1 150.37(5) . .
N1 Eu1 Zn1 174.98(6) . .
Zn2 Eu1 Zn1 56.66(3) . .
O6 Zn2 O4 114.46(12) . .
O6 Zn2 O11 113.59(9) . .
O4 Zn2 O11 105.19(10) . .
O6 Zn2 O2 121.51(10) . .
O4 Zn2 O2 113.11(12) . .
O11 Zn2 O2 83.82(9) . .
O6 Zn2 O1 81.31(9) . .
O4 Zn2 O1 82.41(11) . .
O11 Zn2 O1 156.98(9) . .
O2 Zn2 O1 73.26(9) . .
O6 Zn2 Eu1 116.86(8) . .
O4 Zn2 Eu1 127.59(9) . .
O11 Zn2 Eu1 43.44(6) . .
O2 Zn2 Eu1 42.94(6) . .
O1 Zn2 Eu1 114.82(7) . .
O5 Zn1 O13 114.56(10) . 2_655
O5 Zn1 O11 103.91(10) . .
O13 Zn1 O11 107.76(9) 2_655 .
O5 Zn1 O2' 127.73(10) . .
O13 Zn1 O2' 111.37(9) 2_655 .
O11 Zn1 O2' 84.15(9) . .
O5 Zn1 O1' 82.02(10) . .
O13 Zn1 O1' 91.25(9) 2_655 .
O11 Zn1 O1' 154.75(8) . .
O2' Zn1 O1' 73.30(9) . .
O5 Zn1 Eu1 127.33(7) . .
O13 Zn1 Eu1 114.40(8) 2_655 .
O11 Zn1 Eu1 42.22(7) . .
O2' Zn1 Eu1 42.04(6) . .
O1' Zn1 Eu1 114.96(6) . .
O12 N1 O9 121.9(3) . .
O12 N1 O8 121.1(3) . .
O9 N1 O8 117.0(3) . .
O12 N1 Eu1 175.6(2) . .
O9 N1 Eu1 58.54(17) . .
O8 N1 Eu1 58.54(16) . .
C2 O1 C1 118.0(3) . .
C2 O1 Zn2 109.24(19) . .
C1 O1 Zn2 124.9(2) . .
C7 O2 Zn2 117.7(2) . .
C7 O2 Eu1 138.7(2) . .
Zn2 O2 Eu1 103.04(9) . .
C8 O3 Eu1 137.3(2) . .
C2' O1' C1' 118.0(3) . .
C2' O1' Zn1 112.9(2) . .
C1' O1' Zn1 128.1(2) . .
C7' O2' Zn1 120.9(2) . .
C7' O2' Eu1 134.7(2) . .
Zn1 O2' Eu1 104.41(9) . .
C8' O3' Eu1 131.5(2) . .
C9 O4 Zn2 133.0(2) . .
C9 O5 Zn1 133.4(3) . .
C11 O6 Zn2 122.0(2) . .
C13 O7 Eu1 149.2(2) . .
N1 O8 Eu1 96.33(17) . .
N1 O9 Eu1 96.5(2) . .
C11 O10 Eu1 148.3(2) . 2_655
Zn1 O11 Zn2 114.59(11) . .
Zn1 O11 Eu1 105.07(10) . .
Zn2 O11 Eu1 102.92(9) . .
Zn1 O11 H11A 117.6 . .
Zn2 O11 H11A 107.7 . .
Eu1 O11 H11A 107.8 . .
C13 O13 Zn1 123.41(19) . 2_655
O1 C1 H1A 109.5 . .
O1 C1 H1B 109.5 . .
H1A C1 H1B 109.5 . .
O1 C1 H1C 109.5 . .
H1A C1 H1C 109.5 . .
H1B C1 H1C 109.5 . .
O1 C2 C3 124.2(3) . .
O1 C2 C7 113.4(3) . .
C3 C2 C7 122.4(3) . .
C2 C3 C4 118.6(3) . .
C2 C3 H3A 120.7 . .
C4 C3 H3A 120.7 . .
C5 C4 C3 121.1(3) . .
C5 C4 Br1 120.6(3) . .
C3 C4 Br1 118.3(3) . .
C4 C5 C6 120.0(3) . .
C4 C5 H5A 120.0 . .
C6 C5 H5A 120.0 . .
C7 C6 C5 120.3(3) . .
C7 C6 C8 123.2(3) . .
C5 C6 C8 116.2(3) . .
O2 C7 C2 119.9(3) . .
O2 C7 C6 122.6(3) . .
C2 C7 C6 117.5(3) . .
O3 C8 C6 126.8(3) . .
O3 C8 H8A 116.6 . .
C6 C8 H8A 116.6 . .
O1' C1' H1'A 109.5 . .
O1' C1' H1'B 109.5 . .
H1'A C1' H1'B 109.5 . .
O1' C1' H1'C 109.5 . .
H1'A C1' H1'C 109.5 . .
H1'B C1' H1'C 109.5 . .
O1' C2' C3' 124.7(3) . .
O1' C2' C7' 113.2(3) . .
C3' C2' C7' 122.0(3) . .
C2' C3' C4' 119.2(3) . .
C2' C3' H3'A 120.4 . .
C4' C3' H3'A 120.4 . .
C5' C4' C3' 121.4(3) . .
C5' C4' Br1' 119.4(3) . .
C3' C4' Br1' 119.2(3) . .
C4' C5' C6' 119.9(3) . .
C4' C5' H5'A 120.1 . .
C6' C5' H5'A 120.1 . .
C7' C6' C5' 120.0(3) . .
C7' C6' C8' 123.9(3) . .
C5' C6' C8' 115.9(3) . .
O2' C7' C6' 124.1(3) . .
O2' C7' C2' 118.6(3) . .
C6' C7' C2' 117.3(3) . .
O3' C8' C6' 127.0(3) . .
O3' C8' H8'A 116.5 . .
C6' C8' H8'A 116.5 . .
O5 C9 O4 126.3(4) . .
O5 C9 C10 117.7(4) . .
O4 C9 C10 116.0(3) . .
C9 C10 H10B 109.5 . .
C9 C10 H10C 109.5 . .
H10B C10 H10C 109.5 . .
C9 C10 H10D 109.5 . .
H10B C10 H10D 109.5 . .
H10C C10 H10D 109.5 . .
O10 C11 O6 122.9(3) . .
O10 C11 C12 121.0(3) . .
O6 C11 C12 116.1(3) . .
C11 C12 H12B 109.5 . .
C11 C12 H12C 109.5 . .
H12B C12 H12C 109.5 . .
C11 C12 H12D 109.5 . .
H12B C12 H12D 109.5 . .
H12C C12 H12D 109.5 . .
O7 C13 O13 123.4(3) . .
O7 C13 C14 119.3(3) . .
O13 C13 C14 117.3(3) . .
C13 C14 H14A 109.5 . .
C13 C14 H14B 109.5 . .
H14A C14 H14B 109.5 . .
C13 C14 H14C 109.5 . .
H14A C14 H14C 109.5 . .
H14B C14 H14C 109.5 . .
C16 C15 H15A 109.5 . .
C16 C15 H15B 109.5 . .
H15A C15 H15B 109.5 . .
C16 C15 H15C 109.5 . .
H15A C15 H15C 109.5 . .
H15B C15 H15C 109.5 . .
O1W C16 C15 108.9(8) . .
O1W C16 H16A 109.9 . .
C15 C16 H16A 109.9 . .
O1W C16 H16B 109.9 . .
C15 C16 H16B 109.9 . .
H16A C16 H16B 108.3 . .
O1W C17 C18 115.8(8) . .
O1W C17 H17A 108.3 . .
C18 C17 H17A 108.3 . .
O1W C17 H17B 108.3 . .
C18 C17 H17B 108.3 . .
H17A C17 H17B 107.4 . .
C17 C18 H18A 109.5 . .
C17 C18 H18B 109.5 . .
H18A C18 H18B 109.5 . .
C17 C18 H18C 109.5 . .
H18A C18 H18C 109.5 . .
H18B C18 H18C 109.5 . .
C17 O1W C16 118.7(8) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Eu1 O10 2.409(2) 2_655
Eu1 O2 2.461(2) .
Eu1 O7 2.461(2) .
Eu1 O2' 2.467(2) .
Eu1 O11 2.483(2) .
Eu1 O3 2.498(2) .
Eu1 O3' 2.501(2) .
Eu1 O8 2.550(2) .
Eu1 O9 2.550(3) .
Eu1 N1 2.971(3) .
Eu1 Zn2 3.5197(10) .
Eu1 Zn1 3.5679(12) .
Zn2 O6 1.940(2) .
Zn2 O4 1.947(3) .
Zn2 O11 2.001(2) .
Zn2 O2 2.021(2) .
Zn2 O1 2.331(3) .
Zn1 O5 1.958(2) .
Zn1 O13 1.962(2) 2_655
Zn1 O11 1.997(2) .
Zn1 O2' 2.036(2) .
Zn1 O1' 2.305(2) .
Br1 C4 1.892(3) .
Br1' C4' 1.897(4) .
N1 O12 1.227(4) .
N1 O9 1.263(3) .
N1 O8 1.269(4) .
O1 C2 1.367(4) .
O1 C1 1.434(5) .
O2 C7 1.331(4) .
O3 C8 1.229(4) .
O1' C2' 1.369(4) .
O1' C1' 1.434(4) .
O2' C7' 1.330(4) .
O3' C8' 1.232(4) .
O4 C9 1.258(5) .
O5 C9 1.256(4) .
O6 C11 1.272(4) .
O7 C13 1.257(4) .
O10 C11 1.257(4) .
O10 Eu1 2.409(2) 2_655
O11 H11A 0.8355 .
O13 C13 1.272(4) .
O13 Zn1 1.962(2) 2_655
C1 H1A 0.9600 .
C1 H1B 0.9600 .
C1 H1C 0.9600 .
C2 C3 1.379(5) .
C2 C7 1.401(5) .
C3 C4 1.407(5) .
C3 H3A 0.9300 .
C4 C5 1.354(5) .
C5 C6 1.416(5) .
C5 H5A 0.9300 .
C6 C7 1.407(5) .
C6 C8 1.436(5) .
C8 H8A 0.9300 .
C1' H1'A 0.9600 .
C1' H1'B 0.9600 .
C1' H1'C 0.9600 .
C2' C3' 1.372(5) .
C2' C7' 1.421(5) .
C3' C4' 1.393(5) .
C3' H3'A 0.9300 .
C4' C5' 1.368(5) .
C5' C6' 1.416(5) .
C5' H5'A 0.9300 .
C6' C7' 1.415(5) .
C6' C8' 1.440(5) .
C8' H8'A 0.9300 .
C9 C10 1.515(5) .
C10 H10B 0.9600 .
C10 H10C 0.9600 .
C10 H10D 0.9600 .
C11 C12 1.495(5) .
C12 H12B 0.9600 .
C12 H12C 0.9600 .
C12 H12D 0.9600 .
C13 C14 1.500(4) .
C14 H14A 0.9600 .
C14 H14B 0.9600 .
C14 H14C 0.9600 .
C15 C16 1.437(12) .
C15 H15A 0.9600 .
C15 H15B 0.9600 .
C15 H15C 0.9600 .
C16 O1W 1.410(10) .
C16 H16A 0.9700 .
C16 H16B 0.9700 .
C17 O1W 1.241(9) .
C17 C18 1.499(11) .
C17 H17A 0.9700 .
C17 H17B 0.9700 .
C18 H18A 0.9600 .
C18 H18B 0.9600 .
C18 H18C 0.9600 .
