#------------------------------------------------------------------------------
#$Date: 2016-03-26 01:57:47 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180116 $
#$URL: svn://www.crystallography.net/cod/cif/7/10/14/7101436.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7101436
loop_
_publ_author_name
'Norbert Mitzel'
'Raphael J. F. Berger'
'Roland Frohlich'
'Surajit Jana'
_publ_section_title
;
First mixed hydrazide/hydroxylamide metal aggregates -
fine tuning the N:O content of zinc compounds
;
_journal_issue                   38
_journal_name_full               'Chemical Communications'
_journal_paper_doi               10.1039/b608135e
_journal_year                    2006
_chemical_formula_moiety         'C34 H82 N8 O4 Zn5'
_chemical_formula_sum            'C34 H82 N8 O4 Zn5'
_chemical_formula_weight         993.93
_chemical_name_systematic
;
?
;
_space_group_IT_number           60
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_Hall  '-P 2n 2ab'
_symmetry_space_group_name_H-M   'P b c n'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   11.369(2)
_cell_length_b                   15.909(3)
_cell_length_c                   25.860(5)
_cell_measurement_reflns_used    25240
_cell_measurement_temperature    153(2)
_cell_measurement_theta_max      25.1
_cell_measurement_theta_min      3.8
_cell_volume                     4677.3(15)
_computing_cell_refinement       'STOE X-AREA'
_computing_data_collection       'STOE IPDS 1'
_computing_data_reduction        'STOE X-AREA'
_computing_molecular_graphics    'SHELXL 5.01'
_computing_publication_material  'SHELXL 5.01'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      153(2)
_diffrn_measured_fraction_theta_full 0.887
_diffrn_measured_fraction_theta_max 0.887
_diffrn_measurement_device_type  'Stoe IPDS 1'
_diffrn_measurement_method       'Phi scans 0.9 deg'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0843
_diffrn_reflns_av_sigmaI/netI    0.0455
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       30
_diffrn_reflns_limit_l_min       -30
_diffrn_reflns_number            23657
_diffrn_reflns_theta_full        24.60
_diffrn_reflns_theta_max         24.60
_diffrn_reflns_theta_min         4.12
_diffrn_standards_decay_%        0
_exptl_absorpt_coefficient_mu    2.568
_exptl_absorpt_correction_T_max  0.7586
_exptl_absorpt_correction_T_min  0.5304
_exptl_absorpt_correction_type   numerical
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.411
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       'square plate'
_exptl_crystal_F_000             2096
_exptl_crystal_size_max          0.25
_exptl_crystal_size_mid          0.24
_exptl_crystal_size_min          0.10
_refine_diff_density_max         1.187
_refine_diff_density_min         -0.548
_refine_diff_density_rms         0.104
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.195
_refine_ls_hydrogen_treatment    noref
_refine_ls_matrix_type           full
_refine_ls_number_parameters     217
_refine_ls_number_reflns         3498
_refine_ls_number_restraints     2
_refine_ls_restrained_S_all      1.200
_refine_ls_R_factor_all          0.0931
_refine_ls_R_factor_gt           0.0759
_refine_ls_shift/su_max          0.005
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0467P)²+28.6066P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1533
_refine_ls_wR_factor_ref         0.1611
_reflns_number_gt                2902
_reflns_number_total             3498
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b608135e.txt
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Orthorhombic' changed to 'orthorhombic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_sg_symbol_H-M      Pbcn
_cod_database_code               7101436
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, -y+1/2, z+1/2'
'x+1/2, -y+1/2, -z'
'-x, y, -z+1/2'
'-x, -y, -z'
'x-1/2, y-1/2, -z-1/2'
'-x-1/2, y-1/2, z'
'x, -y, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Zn1 Zn 0.0000 0.29963(7) 0.2500 0.0277(3) Uani 1 2 d S
Zn2 Zn 0.08381(7) 0.22914(6) 0.36522(4) 0.0392(3) Uani 1 1 d .
Zn3 Zn 0.20078(7) 0.23649(6) 0.17461(4) 0.0392(3) Uani 1 1 d .
O21 O 0.1223(4) 0.2394(3) 0.2881(2) 0.0371(13) Uani 1 1 d .
O31 O -0.0661(5) 0.1659(4) 0.3522(2) 0.0490(15) Uani 1 1 d .
N11 N -0.0889(5) 0.3375(4) 0.3118(2) 0.0320(14) Uani 1 1 d .
H11C H -0.1325 0.3853 0.3039 0.038 Uiso 1 1 d R
N12 N -0.0089(5) 0.3546(4) 0.3549(3) 0.0377(15) Uani 1 1 d .
N22 N 0.2117(5) 0.1985(4) 0.2574(3) 0.0430(17) Uani 1 1 d .
N32 N -0.1100(7) 0.1012(5) 0.3876(4) 0.061(2) Uani 1 1 d .
C1 C 0.3580(9) 0.2443(7) 0.1407(5) 0.068(3) Uiso 1 1 d D
H1A H 0.3493 0.2792 0.1092 0.081 Uiso 1 1 calc R
H1B H 0.4113 0.2748 0.1644 0.081 Uiso 1 1 calc R
C2 C 0.4152(17) 0.1664(11) 0.1259(8) 0.168(8) Uiso 1 1 d D
H2A H 0.3709 0.1187 0.1399 0.202 Uiso 1 1 calc R
H2B H 0.4955 0.1656 0.1397 0.202 Uiso 1 1 calc R
H2C H 0.4178 0.1624 0.0881 0.202 Uiso 1 1 calc R
C3 C 0.2183(10) 0.2137(8) 0.4131(5) 0.080(3) Uiso 1 1 d D
H3A H 0.2673 0.1683 0.3982 0.096 Uiso 1 1 calc R
H3B H 0.2657 0.2658 0.4110 0.096 Uiso 1 1 calc R
C4 C 0.2064(14) 0.1944(11) 0.4684(6) 0.136(6) Uiso 1 1 d D
H4A H 0.1592 0.2381 0.4852 0.163 Uiso 1 1 calc R
H4B H 0.2846 0.1924 0.4844 0.163 Uiso 1 1 calc R
H4C H 0.1676 0.1398 0.4726 0.163 Uiso 1 1 calc R
C9 C -0.0816(7) 0.3783(6) 0.4001(4) 0.052(2) Uani 1 1 d .
H9A H -0.1331 0.3307 0.4097 0.062 Uiso 1 1 calc R
H9B H -0.1323 0.4266 0.3909 0.062 Uiso 1 1 calc R
C10 C -0.0050(10) 0.4018(7) 0.4459(4) 0.071(3) Uani 1 1 d .
H10A H 0.0414 0.3521 0.4568 0.085 Uiso 1 1 calc R
H10B H -0.0557 0.4186 0.4753 0.085 Uiso 1 1 calc R
C11 C 0.0781(10) 0.4735(7) 0.4327(5) 0.079(4) Uani 1 1 d .
H11A H 0.1325 0.4837 0.4620 0.094 Uiso 1 1 calc R
H11B H 0.0326 0.5255 0.4265 0.094 Uiso 1 1 calc R
C12 C 0.1480(9) 0.4505(6) 0.3845(4) 0.063(3) Uani 1 1 d .
H12A H 0.1962 0.4992 0.3737 0.076 Uiso 1 1 calc R
H12B H 0.2018 0.4033 0.3925 0.076 Uiso 1 1 calc R
C13 C 0.0672(7) 0.4255(5) 0.3410(4) 0.043(2) Uani 1 1 d .
H13A H 0.0176 0.4742 0.3314 0.052 Uiso 1 1 calc R
H13B H 0.1150 0.4100 0.3105 0.052 Uiso 1 1 calc R
C19 C 0.3266(7) 0.2240(7) 0.2790(5) 0.067(3) Uani 1 1 d .
H19A H 0.3901 0.1957 0.2594 0.080 Uiso 1 1 calc R
H19B H 0.3316 0.2052 0.3154 0.080 Uiso 1 1 calc R
C20 C 0.3461(7) 0.3194(7) 0.2768(5) 0.066(3) Uani 1 1 d .
H20A H 0.4291 0.3319 0.2836 0.079 Uiso 1 1 calc R
H20B H 0.2970 0.3469 0.3029 0.079 Uiso 1 1 calc R
H20C H 0.3248 0.3402 0.2424 0.079 Uiso 1 1 calc R
C21 C 0.1918(8) 0.1069(5) 0.2648(4) 0.059(3) Uani 1 1 d .
H21A H 0.1093 0.0934 0.2558 0.070 Uiso 1 1 calc R
H21B H 0.2037 0.0927 0.3017 0.070 Uiso 1 1 calc R
C22 C 0.2750(10) 0.0527(7) 0.2315(5) 0.082(4) Uani 1 1 d .
H22A H 0.2630 -0.0068 0.2397 0.124 Uiso 1 1 calc R
H22B H 0.3567 0.0682 0.2387 0.124 Uiso 1 1 calc R
H22C H 0.2580 0.0623 0.1948 0.124 Uiso 1 1 calc R
C27 C -0.0232(11) 0.0350(7) 0.3896(5) 0.081(4) Uani 1 1 d .
H27A H 0.0558 0.0599 0.3945 0.097 Uiso 1 1 calc R
H27B H -0.0398 -0.0022 0.4194 0.097 Uiso 1 1 calc R
C28 C -0.0247(18) -0.0136(11) 0.3425(9) 0.168(9) Uani 1 1 d .
H28A H 0.0506 -0.0428 0.3385 0.252 Uiso 1 1 calc R
H28B H -0.0373 0.0238 0.3129 0.252 Uiso 1 1 calc R
H28C H -0.0885 -0.0550 0.3441 0.252 Uiso 1 1 calc R
C29 C -0.1263(10) 0.1398(8) 0.4372(5) 0.075(3) Uani 1 1 d .
H29A H -0.1750 0.1910 0.4330 0.090 Uiso 1 1 calc R
H29B H -0.0488 0.1574 0.4509 0.090 Uiso 1 1 calc R
C30 C -0.1840(15) 0.0831(11) 0.4756(7) 0.139(7) Uani 1 1 d .
H30A H -0.1937 0.1129 0.5084 0.208 Uiso 1 1 calc R
H30B H -0.1350 0.0332 0.4809 0.208 Uiso 1 1 calc R
H30C H -0.2613 0.0659 0.4625 0.208 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Zn Zn 0.2839 1.4301 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O21 Zn1 O21 121.4(3) . 4
O21 Zn1 N11 96.0(2) . .
O21 Zn1 N11 101.1(2) 4 .
O21 Zn1 N11 101.1(2) . 4
O21 Zn1 N11 96.0(2) 4 4
N11 Zn1 N11 144.6(4) . 4
C3 Zn2 O31 134.2(4) . .
C3 Zn2 O21 116.9(4) . .
O31 Zn2 O21 93.3(2) . .
C3 Zn2 N12 122.7(4) . .
O31 Zn2 N12 91.6(2) . .
O21 Zn2 N12 85.1(2) . .
C1 Zn3 O31 124.2(4) . 4
C1 Zn3 N11 125.0(3) . 4
O31 Zn3 N11 91.4(2) 4 4
C1 Zn3 N22 112.9(4) . .
O31 Zn3 N22 102.7(3) 4 .
N11 Zn3 N22 94.7(2) 4 .
N22 O21 Zn1 116.3(5) . .
N22 O21 Zn2 130.5(4) . .
Zn1 O21 Zn2 112.2(2) . .
N32 O31 Zn2 122.4(5) . .
N32 O31 Zn3 110.2(4) . 4
Zn2 O31 Zn3 114.9(3) . 4
N12 N11 Zn1 110.7(4) . .
N12 N11 Zn3 113.3(4) . 4
Zn1 N11 Zn3 102.3(3) . 4
N12 N11 H11C 110.3 . .
Zn1 N11 H11C 110.0 . .
Zn3 N11 H11C 110.0 4 .
N11 N12 C13 108.9(6) . .
N11 N12 C9 107.5(6) . .
C13 N12 C9 109.1(6) . .
N11 N12 Zn2 102.4(4) . .
C13 N12 Zn2 115.5(5) . .
C9 N12 Zn2 113.0(5) . .
O21 N22 C19 106.8(7) . .
O21 N22 C21 105.4(6) . .
C19 N22 C21 110.8(7) . .
O21 N22 Zn3 111.5(4) . .
C19 N22 Zn3 109.7(6) . .
C21 N22 Zn3 112.4(6) . .
C29 N32 C27 111.6(10) . .
C29 N32 O31 107.6(7) . .
C27 N32 O31 107.5(7) . .
C2 C1 Zn3 117.7(10) . .
C2 C1 H1A 107.9 . .
Zn3 C1 H1A 107.9 . .
C2 C1 H1B 107.9 . .
Zn3 C1 H1B 107.9 . .
H1A C1 H1B 107.2 . .
C1 C2 H2A 109.5 . .
C1 C2 H2B 109.5 . .
H2A C2 H2B 109.5 . .
C1 C2 H2C 109.5 . .
H2A C2 H2C 109.5 . .
H2B C2 H2C 109.5 . .
C4 C3 Zn2 124.3(10) . .
C4 C3 H3A 106.3 . .
Zn2 C3 H3A 106.3 . .
C4 C3 H3B 106.3 . .
Zn2 C3 H3B 106.3 . .
H3A C3 H3B 106.4 . .
C3 C4 H4A 109.5 . .
C3 C4 H4B 109.5 . .
H4A C4 H4B 109.5 . .
C3 C4 H4C 109.5 . .
H4A C4 H4C 109.5 . .
H4B C4 H4C 109.5 . .
N12 C9 C10 111.0(7) . .
N12 C9 H9A 109.4 . .
C10 C9 H9A 109.4 . .
N12 C9 H9B 109.4 . .
C10 C9 H9B 109.4 . .
H9A C9 H9B 108.0 . .
C9 C10 C11 111.5(9) . .
C9 C10 H10A 109.3 . .
C11 C10 H10A 109.3 . .
C9 C10 H10B 109.3 . .
C11 C10 H10B 109.3 . .
H10A C10 H10B 108.0 . .
C10 C11 C12 109.1(8) . .
C10 C11 H11A 109.9 . .
C12 C11 H11A 109.9 . .
C10 C11 H11B 109.9 . .
C12 C11 H11B 109.9 . .
H11A C11 H11B 108.3 . .
C13 C12 C11 110.9(8) . .
C13 C12 H12A 109.5 . .
C11 C12 H12A 109.5 . .
C13 C12 H12B 109.5 . .
C11 C12 H12B 109.5 . .
H12A C12 H12B 108.0 . .
N12 C13 C12 112.3(8) . .
N12 C13 H13A 109.1 . .
C12 C13 H13A 109.1 . .
N12 C13 H13B 109.1 . .
C12 C13 H13B 109.1 . .
H13A C13 H13B 107.9 . .
N22 C19 C20 112.7(7) . .
N22 C19 H19A 109.0 . .
C20 C19 H19A 109.0 . .
N22 C19 H19B 109.0 . .
C20 C19 H19B 109.0 . .
H19A C19 H19B 107.8 . .
C19 C20 H20A 109.5 . .
C19 C20 H20B 109.5 . .
H20A C20 H20B 109.5 . .
C19 C20 H20C 109.5 . .
H20A C20 H20C 109.5 . .
H20B C20 H20C 109.5 . .
N22 C21 C22 112.5(8) . .
N22 C21 H21A 109.1 . .
C22 C21 H21A 109.1 . .
N22 C21 H21B 109.1 . .
C22 C21 H21B 109.1 . .
H21A C21 H21B 107.8 . .
C21 C22 H22A 109.5 . .
C21 C22 H22B 109.5 . .
H22A C22 H22B 109.5 . .
C21 C22 H22C 109.5 . .
H22A C22 H22C 109.5 . .
H22B C22 H22C 109.5 . .
C28 C27 N32 110.7(13) . .
C28 C27 H27A 109.5 . .
N32 C27 H27A 109.5 . .
C28 C27 H27B 109.5 . .
N32 C27 H27B 109.5 . .
H27A C27 H27B 108.1 . .
C27 C28 H28A 109.5 . .
C27 C28 H28B 109.5 . .
H28A C28 H28B 109.5 . .
C27 C28 H28C 109.5 . .
H28A C28 H28C 109.5 . .
H28B C28 H28C 109.5 . .
N32 C29 C30 113.1(12) . .
N32 C29 H29A 109.0 . .
C30 C29 H29A 109.0 . .
N32 C29 H29B 109.0 . .
C30 C29 H29B 109.0 . .
H29A C29 H29B 107.8 . .
C29 C30 H30A 109.5 . .
C29 C30 H30B 109.5 . .
H30A C30 H30B 109.5 . .
C29 C30 H30C 109.5 . .
H30A C30 H30C 109.5 . .
H30B C30 H30C 109.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Zn1 O21 1.956(5) .
Zn1 O21 1.956(5) 4
Zn1 N11 1.986(6) .
Zn1 N11 1.986(6) 4
Zn2 C3 1.984(12) .
Zn2 O31 2.008(6) .
Zn2 O21 2.047(6) .
Zn2 N12 2.273(6) .
Zn3 C1 1.995(10) .
Zn3 O31 2.022(6) 4
Zn3 N11 2.080(6) 4
Zn3 N22 2.228(8) .
O21 N22 1.445(8) .
O31 N32 1.465(9) .
O31 Zn3 2.022(6) 4
N11 N12 1.464(8) .
N11 Zn3 2.080(6) 4
N11 H11C 0.9300 .
N12 C13 1.466(10) .
N12 C9 1.480(10) .
N22 C19 1.478(11) .
N22 C21 1.486(11) .
N32 C29 1.434(14) .
N32 C27 1.444(13) .
C1 C2 1.450(14) .
C1 H1A 0.9900 .
C1 H1B 0.9900 .
C2 H2A 0.9800 .
C2 H2B 0.9800 .
C2 H2C 0.9800 .
C3 C4 1.469(15) .
C3 H3A 0.9900 .
C3 H3B 0.9900 .
C4 H4A 0.9800 .
C4 H4B 0.9800 .
C4 H4C 0.9800 .
C9 C10 1.517(13) .
C9 H9A 0.9900 .
C9 H9B 0.9900 .
C10 C11 1.520(15) .
C10 H10A 0.9900 .
C10 H10B 0.9900 .
C11 C12 1.522(15) .
C11 H11A 0.9900 .
C11 H11B 0.9900 .
C12 C13 1.506(12) .
C12 H12A 0.9900 .
C12 H12B 0.9900 .
C13 H13A 0.9900 .
C13 H13B 0.9900 .
C19 C20 1.534(14) .
C19 H19A 0.9900 .
C19 H19B 0.9900 .
C20 H20A 0.9800 .
C20 H20B 0.9800 .
C20 H20C 0.9800 .
C21 C22 1.543(13) .
C21 H21A 0.9900 .
C21 H21B 0.9900 .
C22 H22A 0.9800 .
C22 H22B 0.9800 .
C22 H22C 0.9800 .
C27 C28 1.44(2) .
C27 H27A 0.9900 .
C27 H27B 0.9900 .
C28 H28A 0.9800 .
C28 H28B 0.9800 .
C28 H28C 0.9800 .
C29 C30 1.493(15) .
C29 H29A 0.9900 .
C29 H29B 0.9900 .
C30 H30A 0.9800 .
C30 H30B 0.9800 .
C30 H30C 0.9800 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O21 Zn1 O21 N22 72.6(4) 4 .
N11 Zn1 O21 N22 179.5(5) . .
N11 Zn1 O21 N22 -31.6(5) 4 .
O21 Zn1 O21 Zn2 -97.5(2) 4 .
N11 Zn1 O21 Zn2 9.5(3) . .
N11 Zn1 O21 Zn2 158.4(3) 4 .
C3 Zn2 O21 N22 35.9(7) . .
O31 Zn2 O21 N22 -108.5(6) . .
N12 Zn2 O21 N22 160.3(6) . .
C3 Zn2 O21 Zn1 -155.8(4) . .
O31 Zn2 O21 Zn1 59.8(3) . .
N12 Zn2 O21 Zn1 -31.5(3) . .
C3 Zn2 O31 N32 13.4(9) . .
O21 Zn2 O31 N32 147.0(6) . .
N12 Zn2 O31 N32 -127.8(6) . .
C3 Zn2 O31 Zn3 151.8(5) . 4
O21 Zn2 O31 Zn3 -74.6(3) . 4
N12 Zn2 O31 Zn3 10.6(3) . 4
O21 Zn1 N11 N12 33.9(5) . .
O21 Zn1 N11 N12 157.6(4) 4 .
N11 Zn1 N11 N12 -85.0(4) 4 .
O21 Zn1 N11 Zn3 -87.0(3) . 4
O21 Zn1 N11 Zn3 36.6(3) 4 4
N11 Zn1 N11 Zn3 154.1(3) 4 4
Zn1 N11 N12 C13 64.7(6) . .
Zn3 N11 N12 C13 178.9(4) 4 .
Zn1 N11 N12 C9 -177.2(5) . .
Zn3 N11 N12 C9 -63.1(6) 4 .
Zn1 N11 N12 Zn2 -58.0(4) . .
Zn3 N11 N12 Zn2 56.1(4) 4 .
C3 Zn2 N12 N11 172.8(5) . .
O31 Zn2 N12 N11 -39.4(4) . .
O21 Zn2 N12 N11 53.8(4) . .
C3 Zn2 N12 C13 54.7(7) . .
O31 Zn2 N12 C13 -157.5(6) . .
O21 Zn2 N12 C13 -64.3(5) . .
C3 Zn2 N12 C9 -71.8(7) . .
O31 Zn2 N12 C9 75.9(5) . .
O21 Zn2 N12 C9 169.1(5) . .
Zn1 O21 N22 C19 130.4(6) . .
Zn2 O21 N22 C19 -61.7(8) . .
Zn1 O21 N22 C21 -111.7(6) . .
Zn2 O21 N22 C21 56.2(8) . .
Zn1 O21 N22 Zn3 10.5(6) . .
Zn2 O21 N22 Zn3 178.4(3) . .
C1 Zn3 N22 O21 144.9(5) . .
O31 Zn3 N22 O21 -78.9(5) 4 .
N11 Zn3 N22 O21 13.6(5) 4 .
C1 Zn3 N22 C19 26.7(7) . .
O31 Zn3 N22 C19 162.9(6) 4 .
N11 Zn3 N22 C19 -104.6(6) 4 .
C1 Zn3 N22 C21 -97.1(6) . .
O31 Zn3 N22 C21 39.1(5) 4 .
N11 Zn3 N22 C21 131.6(5) 4 .
Zn2 O31 N32 C29 58.7(8) . .
Zn3 O31 N32 C29 -81.4(8) 4 .
Zn2 O31 N32 C27 -61.7(10) . .
Zn3 O31 N32 C27 158.2(8) 4 .
O31 Zn3 C1 C2 -48.3(14) 4 .
N11 Zn3 C1 C2 -169.2(11) 4 .
N22 Zn3 C1 C2 77.0(13) . .
O31 Zn2 C3 C4 -46.0(15) . .
O21 Zn2 C3 C4 -171.8(11) . .
N12 Zn2 C3 C4 86.0(13) . .
N11 N12 C9 C10 -176.9(7) . .
C13 N12 C9 C10 -59.1(10) . .
Zn2 N12 C9 C10 70.8(9) . .
N12 C9 C10 C11 57.7(11) . .
C9 C10 C11 C12 -53.8(11) . .
C10 C11 C12 C13 53.3(12) . .
N11 N12 C13 C12 176.7(6) . .
C9 N12 C13 C12 59.7(9) . .
Zn2 N12 C13 C12 -68.8(8) . .
C11 C12 C13 N12 -57.9(10) . .
O21 N22 C19 C20 -60.4(10) . .
C21 N22 C19 C20 -174.7(8) . .
Zn3 N22 C19 C20 60.6(9) . .
O21 N22 C21 C22 176.1(8) . .
C19 N22 C21 C22 -68.7(12) . .
Zn3 N22 C21 C22 54.4(10) . .
C29 N32 C27 C28 168.7(11) . .
O31 N32 C27 C28 -73.5(13) . .
C27 N32 C29 C30 -68.8(13) . .
O31 N32 C29 C30 173.4(10) . .
