#------------------------------------------------------------------------------
#$Date: 2016-03-26 02:03:57 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180121 $
#$URL: svn://www.crystallography.net/cod/cif/7/10/19/7101954.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7101954
loop_
_publ_author_name
'Salazar-Mendoza, Domingo'
'Baudron, Stéphane A'
'Hosseini, Mir Wais'
_publ_section_title
;
 Beyond classical coordination: silver-pi interactions in metal
 dipyrrin complexes.
;
_journal_issue                   22
_journal_name_full
'Chemical communications (Cambridge, England)'
_journal_page_first              2252
_journal_page_last               2254
_journal_paper_doi               10.1039/b704466f
_journal_year                    2007
_chemical_formula_moiety         'C36 H18 Ag2 F6 N8 O6 S2 Zn, 2.5(C6 H6)'
_chemical_formula_sum            'C51 H33 Ag2 F6 N8 O6 S2 Zn'
_chemical_formula_weight         1313.08
_chemical_name_systematic
;
?
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 106.9440(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   17.9768(4)
_cell_length_b                   10.3321(2)
_cell_length_c                   28.9049(7)
_cell_measurement_reflns_used    5861
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      27.44
_cell_measurement_theta_min      2.37
_cell_volume                     5135.7(2)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'Bruker SHELXTL'
_computing_structure_solution    'Bruker SHELXTL'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0515
_diffrn_reflns_av_sigmaI/netI    0.0759
_diffrn_reflns_limit_h_max       25
_diffrn_reflns_limit_h_min       -25
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       40
_diffrn_reflns_limit_l_min       -40
_diffrn_reflns_number            48751
_diffrn_reflns_theta_full        30.06
_diffrn_reflns_theta_max         30.06
_diffrn_reflns_theta_min         1.20
_exptl_absorpt_coefficient_mu    1.380
_exptl_absorpt_correction_T_max  0.9598
_exptl_absorpt_correction_T_min  0.6365
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    1.698
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    .
_exptl_crystal_description       platelet
_exptl_crystal_F_000             2612
_exptl_crystal_size_max          0.36
_exptl_crystal_size_mid          0.07
_exptl_crystal_size_min          0.03
_refine_diff_density_max         1.404
_refine_diff_density_min         -1.029
_refine_diff_density_rms         0.180
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.023
_refine_ls_hydrogen_treatment    riding
_refine_ls_matrix_type           full
_refine_ls_number_parameters     650
_refine_ls_number_reflns         15035
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.023
_refine_ls_R_factor_all          0.1022
_refine_ls_R_factor_gt           0.0501
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0721P)²+3.4059P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1268
_refine_ls_wR_factor_ref         0.1543
_reflns_number_gt                8847
_reflns_number_total             15035
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b704466f.txt
_cod_data_source_block           e824a
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_sg_symbol_H-M      'P2(1)/n '
_cod_database_code               7101954
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.8654(3) 0.7299(4) 1.18704(16) 0.0404(11) Uani 1 1 d . . .
H1 H 0.8652 0.6876 1.1586 0.048 Uiso 1 1 calc R . .
C2 C 0.8155(3) 0.8340(4) 1.18945(17) 0.0438(11) Uani 1 1 d . . .
H2 H 0.7775 0.8708 1.1638 0.053 Uiso 1 1 calc R . .
C3 C 0.8343(3) 0.8694(4) 1.23680(17) 0.0372(10) Uani 1 1 d . . .
H3 H 0.8113 0.9356 1.2495 0.045 Uiso 1 1 calc R . .
C4 C 0.8963(2) 0.7862(3) 1.26376(15) 0.0297(9) Uani 1 1 d . . .
C5 C 0.9358(2) 0.7924(3) 1.31195(15) 0.0274(8) Uani 1 1 d . . .
C6 C 1.0014(2) 0.7178(3) 1.33770(15) 0.0273(8) Uani 1 1 d . . .
C7 C 1.0452(2) 0.7306(4) 1.38642(16) 0.0313(9) Uani 1 1 d . A .
H7 H 1.0346 0.7860 1.4090 0.038 Uiso 1 1 calc R . .
C8 C 1.1077(3) 0.6451(4) 1.39456(17) 0.0342(9) Uani 1 1 d . A .
H8 H 1.1469 0.6323 1.4234 0.041 Uiso 1 1 calc R . .
C9 C 1.0990(2) 0.5817(4) 1.34987(17) 0.0349(10) Uani 1 1 d . . .
H9 H 1.1327 0.5185 1.3448 0.042 Uiso 1 1 calc R . .
C10 C 0.9084(2) 0.8926(3) 1.34061(15) 0.0299(9) Uani 1 1 d . . .
C11 C 0.8374(2) 0.8776(4) 1.34974(15) 0.0313(9) Uani 1 1 d . . .
H11 H 0.8095 0.8012 1.3411 0.038 Uiso 1 1 calc R . .
C12 C 0.8078(2) 0.9768(4) 1.37185(15) 0.0303(9) Uani 1 1 d . . .
C13 C 0.8489(3) 1.0913(4) 1.38581(15) 0.0313(9) Uani 1 1 d . . .
H13 H 0.8288 1.1579 1.4002 0.038 Uiso 1 1 calc R . .
C14 C 0.9210(3) 1.1028(3) 1.37749(16) 0.0317(9) Uani 1 1 d . . .
C15 C 0.9508(3) 1.0049(4) 1.35494(16) 0.0319(9) Uani 1 1 d . . .
H15 H 0.9990 1.0150 1.3495 0.038 Uiso 1 1 calc R . .
C16 C 0.7329(3) 0.9611(4) 1.37989(17) 0.0362(10) Uani 1 1 d . . .
C17 C 0.9640(3) 1.2214(4) 1.39161(16) 0.0341(9) Uani 1 1 d . . .
C18 C 0.8850(3) 0.3427(4) 1.26416(17) 0.0385(10) Uani 1 1 d . . .
H18 H 0.8747 0.3821 1.2905 0.046 Uiso 1 1 calc R . .
C19 C 0.8465(3) 0.2314(4) 1.24109(19) 0.0432(11) Uani 1 1 d . . .
H19 H 0.8076 0.1852 1.2491 0.052 Uiso 1 1 calc R . .
C20 C 0.8783(3) 0.2051(4) 1.20447(18) 0.0407(11) Uani 1 1 d . . .
H20 H 0.8650 0.1369 1.1826 0.049 Uiso 1 1 calc R . .
C21 C 0.9357(2) 0.3016(3) 1.20593(15) 0.0299(9) Uani 1 1 d . . .
C22 C 0.9824(2) 0.3161(3) 1.17497(15) 0.0281(8) Uani 1 1 d . . .
C23 C 1.0388(2) 0.4126(3) 1.17702(15) 0.0281(8) Uani 1 1 d . . .
C24 C 1.0936(2) 0.4159(4) 1.15023(15) 0.0311(9) Uani 1 1 d . . .
H24 H 1.0963 0.3584 1.1260 0.037 Uiso 1 1 calc R . .
C25 C 1.1426(3) 0.5210(4) 1.16687(16) 0.0348(9) Uani 1 1 d . . .
H25 H 1.1846 0.5472 1.1566 0.042 Uiso 1 1 calc R . .
C26 C 1.1145(2) 0.5796(4) 1.20294(16) 0.0333(9) Uani 1 1 d . . .
H26 H 1.1360 0.6533 1.2201 0.040 Uiso 1 1 calc R . .
C27 C 0.9712(2) 0.2208(3) 1.13443(15) 0.0294(9) Uani 1 1 d . . .
C28 C 0.9467(2) 0.2649(4) 1.08704(15) 0.0306(9) Uani 1 1 d . . .
H28 H 0.9370 0.3526 1.0808 0.037 Uiso 1 1 calc R . .
C29 C 0.9366(2) 0.1779(4) 1.04885(15) 0.0298(9) Uani 1 1 d . . .
C30 C 0.9503(3) 0.0453(4) 1.05747(16) 0.0321(9) Uani 1 1 d . . .
H30 H 0.9432 -0.0130 1.0320 0.038 Uiso 1 1 calc R . .
C31 C 0.9745(3) 0.0037(3) 1.10492(16) 0.0323(9) Uani 1 1 d . . .
C32 C 0.9857(2) 0.0900(3) 1.14363(16) 0.0309(9) Uani 1 1 d . . .
H32 H 1.0027 0.0600 1.1753 0.037 Uiso 1 1 calc R . .
C33 C 0.9895(3) -0.1323(4) 1.11505(16) 0.0347(10) Uani 1 1 d . . .
C34 C 0.9102(3) 0.2263(4) 1.00025(17) 0.0351(10) Uani 1 1 d . . .
N8 N 0.8904(3) 0.2689(4) 0.96243(15) 0.0454(10) Uani 1 1 d . . .
C35 C 1.2178(4) 0.4207(5) 1.5399(4) 0.076(2) Uani 1 1 d . . .
C36 C 0.7999(3) 0.6560(6) 1.01000(19) 0.0531(14) Uani 1 1 d . . .
N1 N 0.9127(2) 0.6998(3) 1.23043(12) 0.0314(8) Uani 1 1 d . . .
N2 N 1.0367(2) 0.6241(3) 1.31608(13) 0.0310(8) Uani 1 1 d . . .
N3 N 0.6732(3) 0.9508(4) 1.38571(17) 0.0500(11) Uani 1 1 d . . .
N4 N 0.9968(2) 1.3163(3) 1.40272(16) 0.0462(10) Uani 1 1 d . . .
N5 N 0.9380(2) 0.3849(3) 1.24383(13) 0.0308(7) Uani 1 1 d . . .
N6 N 1.0542(2) 0.5166(3) 1.20916(13) 0.0304(7) Uani 1 1 d . . .
N7 N 1.0011(3) -0.2402(3) 1.12277(15) 0.0468(10) Uani 1 1 d . . .
O1A O 1.1067(3) 0.5816(5) 1.5057(2) 0.0582(8) Uani 0.674(3) 1 d P A 1
O2A O 1.1845(3) 0.6045(5) 1.5864(2) 0.0582(8) Uani 0.674(3) 1 d P A 1
O3A O 0.9032(3) 0.5800(5) 1.4358(2) 0.0582(8) Uani 0.674(3) 1 d P . 1
F1A F 1.2613(4) 0.3578(7) 1.5742(3) 0.0993(13) Uani 0.674(3) 1 d P A 1
F2A F 1.1873(4) 0.3358(6) 1.5008(3) 0.0993(13) Uani 0.674(3) 1 d P A 1
F3A F 1.2658(4) 0.4924(6) 1.5197(3) 0.0993(13) Uani 0.674(3) 1 d P A 1
O1B O 1.0772(7) 0.4693(10) 1.5226(5) 0.0582(8) Uani 0.326(3) 1 d P A 2
O2B O 1.1706(7) 0.6447(11) 1.5545(5) 0.0582(8) Uani 0.326(3) 1 d P A 2
O3B O 0.8576(7) 0.5319(10) 1.3956(5) 0.0582(8) Uani 0.326(3) 1 d P . 2
F1B F 1.2108(8) 0.2909(13) 1.5483(6) 0.0993(13) Uani 0.326(3) 1 d P A 2
F3B F 1.2876(9) 0.4398(13) 1.5818(6) 0.0993(13) Uani 0.326(3) 1 d P A 2
F2B F 1.2327(10) 0.4405(15) 1.5028(7) 0.0993(13) Uani 0.326(3) 1 d P A 2
O4 O 0.93581(17) 0.5518(3) 1.03141(12) 0.0371(7) Uani 1 1 d . . .
O5 O 0.9205(2) 0.7699(3) 0.99794(13) 0.0504(9) Uani 1 1 d . . .
O6 O 0.8659(2) 0.5870(3) 0.94670(12) 0.0433(8) Uani 1 1 d . . .
F4 F 0.8122(2) 0.7062(3) 1.05404(12) 0.0700(10) Uani 1 1 d . . .
F5 F 0.7524(2) 0.7357(4) 0.97846(13) 0.0871(13) Uani 1 1 d . . .
F6 F 0.7646(2) 0.5433(4) 1.00816(14) 0.0754(10) Uani 1 1 d . . .
S1 S 1.14419(7) 0.51561(10) 1.55239(5) 0.0396(3) Uani 1 1 d . . .
S2 S 0.89111(6) 0.64026(9) 0.99482(4) 0.0306(2) Uani 1 1 d . . .
Zn3 Zn 0.98835(3) 0.55723(4) 1.250485(19) 0.03172(12) Uani 1 1 d . . .
Ag1 Ag 1.06108(2) 0.59307(3) 1.085815(12) 0.03532(10) Uani 1 1 d . . .
Ag2 Ag 1.02508(2) 0.51944(3) 1.429040(15) 0.04333(11) Uani 1 1 d . . .
C37 C 0.1461(3) 0.9215(4) 0.3265(2) 0.088(3) Uani 1 1 d G . .
H37 H 0.1532 0.8339 0.3216 0.105 Uiso 1 1 calc R . .
C38 C 0.1026(3) 0.9975(6) 0.28853(17) 0.098(3) Uani 1 1 d G . .
H38 H 0.0806 0.9607 0.2582 0.118 Uiso 1 1 calc R . .
C39 C 0.0920(3) 1.1283(5) 0.29581(19) 0.0989(14) Uani 1 1 d G . .
H39 H 0.0630 1.1792 0.2704 0.119 Uiso 1 1 calc R . .
C40 C 0.1249(3) 1.1832(4) 0.3411(2) 0.0989(14) Uani 1 1 d G . .
H40 H 0.1178 1.2708 0.3460 0.119 Uiso 1 1 calc R . .
C41 C 0.1683(3) 1.1072(5) 0.37907(17) 0.0989(14) Uani 1 1 d G . .
H41 H 0.1903 1.1439 0.4094 0.119 Uiso 1 1 calc R . .
C42 C 0.1789(3) 0.9764(5) 0.3718(2) 0.0989(14) Uani 1 1 d G . .
H42 H 0.2080 0.9255 0.3972 0.119 Uiso 1 1 calc R . .
C43 C 0.1934(3) 0.0035(5) 0.1084(2) 0.0570(14) Uani 1 1 d . . .
H43 H 0.1837 -0.0041 0.0751 0.068 Uiso 1 1 calc R . .
C44 C 0.1937(3) 0.1233(5) 0.1291(2) 0.0547(14) Uani 1 1 d . . .
H44 H 0.1855 0.1971 0.1099 0.066 Uiso 1 1 calc R . .
C45 C 0.2062(3) 0.1341(6) 0.1779(2) 0.0597(15) Uani 1 1 d . . .
H45 H 0.2058 0.2149 0.1920 0.072 Uiso 1 1 calc R . .
C46 C 0.2192(4) 0.0254(8) 0.2058(2) 0.075(2) Uani 1 1 d . . .
H46 H 0.2276 0.0316 0.2390 0.090 Uiso 1 1 calc R . .
C47 C 0.2199(4) -0.0960(7) 0.1842(3) 0.093(3) Uani 1 1 d . . .
H47 H 0.2293 -0.1706 0.2030 0.112 Uiso 1 1 calc R . .
C48 C 0.2070(4) -0.1033(6) 0.1365(3) 0.082(2) Uani 1 1 d . . .
H48 H 0.2074 -0.1839 0.1223 0.099 Uiso 1 1 calc R . .
C49 C 1.0585(3) 0.9198(5) 1.49525(17) 0.0473(12) Uani 1 1 d . . .
H49 H 1.0983 0.8659 1.4922 0.057 Uiso 1 1 calc R . .
C50 C 0.9872(3) 0.8691(4) 1.49299(18) 0.0475(12) Uani 1 1 d . . .
H50 H 0.9784 0.7807 1.4882 0.057 Uiso 1 1 calc R . .
C51 C 0.9286(3) 0.9482(5) 1.49784(18) 0.0468(12) Uani 1 1 d . . .
H51 H 0.8803 0.9133 1.4965 0.056 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Zn Zn 0.2839 1.4301 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N1 C1 C2 111.8(4) . .
N1 C1 H1 124.1 . .
C2 C1 H1 124.1 . .
C3 C2 C1 106.2(4) . .
C3 C2 H2 126.9 . .
C1 C2 H2 126.9 . .
C2 C3 C4 108.1(4) . .
C2 C3 H3 126.0 . .
C4 C3 H3 126.0 . .
C5 C4 N1 125.2(4) . .
C5 C4 C3 127.8(4) . .
N1 C4 C3 106.9(4) . .
C4 C5 C6 127.7(3) . .
C4 C5 C10 116.0(4) . .
C6 C5 C10 116.2(4) . .
N2 C6 C7 108.5(4) . .
N2 C6 C5 123.7(4) . .
C7 C6 C5 127.6(3) . .
C8 C7 C6 107.3(4) . .
C8 C7 Ag2 66.5(2) . .
C6 C7 Ag2 106.4(2) . .
C8 C7 H7 126.3 . .
C6 C7 H7 126.3 . .
Ag2 C7 H7 95.6 . .
C7 C8 C9 105.7(4) . .
C7 C8 Ag2 81.2(2) . .
C9 C8 Ag2 102.2(3) . .
C7 C8 H8 127.2 . .
C9 C8 H8 127.2 . .
Ag2 C8 H8 87.2 . .
N2 C9 C8 111.3(4) . .
N2 C9 H9 124.3 . .
C8 C9 H9 124.3 . .
C15 C10 C11 119.6(3) . .
C15 C10 C5 120.4(4) . .
C11 C10 C5 119.9(3) . .
C10 C11 C12 120.1(4) . .
C10 C11 H11 119.9 . .
C12 C11 H11 119.9 . .
C13 C12 C11 121.1(4) . .
C13 C12 C16 119.4(3) . .
C11 C12 C16 119.5(4) . .
C14 C13 C12 117.8(3) . .
C14 C13 H13 121.1 . .
C12 C13 H13 121.1 . .
C13 C14 C15 121.6(4) . .
C13 C14 C17 118.2(3) . .
C15 C14 C17 120.2(4) . .
C10 C15 C14 119.8(4) . .
C10 C15 H15 120.1 . .
C14 C15 H15 120.1 . .
N3 C16 C12 178.7(6) . .
N4 C17 C14 178.8(5) . .
N5 C18 C19 112.1(4) . .
N5 C18 H18 124.0 . .
C19 C18 H18 124.0 . .
C20 C19 C18 105.7(4) . .
C20 C19 H19 127.2 . .
C18 C19 H19 127.2 . .
C19 C20 C21 107.5(4) . .
C19 C20 H20 126.3 . .
C21 C20 H20 126.3 . .
N5 C21 C22 123.6(4) . .
N5 C21 C20 108.2(4) . .
C22 C21 C20 128.2(4) . .
C21 C22 C23 127.2(4) . .
C21 C22 C27 117.4(3) . .
C23 C22 C27 115.4(3) . .
N6 C23 C22 125.0(3) . .
N6 C23 C24 108.0(3) . .
C22 C23 C24 126.7(3) . .
C25 C24 C23 107.4(3) . .
C25 C24 Ag1 71.4(2) . .
C23 C24 Ag1 111.5(3) . .
C25 C24 H24 126.3 . .
C23 C24 H24 126.3 . .
Ag1 C24 H24 87.7 . .
C24 C25 C26 105.2(4) . .
C24 C25 Ag1 76.6(3) . .
C26 C25 Ag1 109.1(3) . .
C24 C25 H25 127.4 . .
C26 C25 H25 127.4 . .
Ag1 C25 H25 85.5 . .
N6 C26 C25 111.8(4) . .
N6 C26 H26 124.1 . .
C25 C26 H26 124.1 . .
C32 C27 C28 119.8(4) . .
C32 C27 C22 121.0(4) . .
C28 C27 C22 119.2(3) . .
C27 C28 C29 120.0(4) . .
C27 C28 H28 120.0 . .
C29 C28 H28 120.0 . .
C28 C29 C30 121.0(4) . .
C28 C29 C34 118.7(4) . .
C30 C29 C34 120.4(4) . .
C31 C30 C29 118.0(4) . .
C31 C30 H30 121.0 . .
C29 C30 H30 121.0 . .
C30 C31 C32 121.7(4) . .
C30 C31 C33 119.4(4) . .
C32 C31 C33 118.9(4) . .
C27 C32 C31 119.5(4) . .
C27 C32 H32 120.2 . .
C31 C32 H32 120.2 . .
N7 C33 C31 179.5(6) . .
N8 C34 C29 177.5(5) . .
C34 N8 Ag1 138.1(4) . 3_767
F2B C35 F1A 123.2(10) . .
F2B C35 F1B 112.4(11) . .
F1A C35 F1B 54.7(8) . .
F2B C35 F3A 37.2(8) . .
F1A C35 F3A 106.8(6) . .
F1B C35 F3A 134.0(8) . .
F2B C35 F2A 61.7(10) . .
F1A C35 F2A 108.6(6) . .
F1B C35 F2A 60.0(8) . .
F3A C35 F2A 98.1(8) . .
F2B C35 F3B 110.7(11) . .
F1A C35 F3B 40.2(6) . .
F1B C35 F3B 94.8(10) . .
F3A C35 F3B 77.9(7) . .
F2A C35 F3B 141.1(7) . .
F2B C35 S1 117.7(9) . .
F1A C35 S1 117.2(7) . .
F1B C35 S1 113.1(7) . .
F3A C35 S1 112.6(4) . .
F2A C35 S1 111.7(5) . .
F3B C35 S1 105.3(7) . .
F6 C36 F4 109.0(4) . .
F6 C36 F5 108.2(5) . .
F4 C36 F5 107.9(4) . .
F6 C36 S2 111.5(4) . .
F4 C36 S2 110.7(4) . .
F5 C36 S2 109.4(4) . .
C1 N1 C4 107.0(3) . .
C1 N1 Zn3 130.4(3) . .
C4 N1 Zn3 122.5(3) . .
C9 N2 C6 107.1(4) . .
C9 N2 Zn3 129.4(3) . .
C6 N2 Zn3 122.9(3) . .
C17 N4 Ag2 161.5(4) . 1_565
C18 N5 C21 106.6(3) . .
C18 N5 Zn3 128.2(3) . .
C21 N5 Zn3 122.9(3) . .
C26 N6 C23 107.5(3) . .
C26 N6 Zn3 130.1(3) . .
C23 N6 Zn3 122.3(3) . .
C33 N7 Ag1 133.0(4) . 1_545
S1 O1A Ag2 136.1(3) . .
S1 O3A Ag2 118.6(3) 3_768 .
S2 O4 Ag1 125.82(17) . .
O1B S1 O2A 150.9(5) . .
O1B S1 O3A 54.2(6) . 3_768
O2A S1 O3A 121.4(4) . 3_768
O1B S1 O2B 126.2(7) . .
O2A S1 O2B 40.8(5) . .
O3A S1 O2B 150.6(5) 3_768 .
O1B S1 O1A 59.9(6) . .
O2A S1 O1A 110.1(3) . .
O3A S1 O1A 113.3(3) 3_768 .
O2B S1 O1A 70.3(6) . .
O1B S1 O3B 103.5(7) . 3_768
O2A S1 O3B 71.7(5) . 3_768
O3A S1 O3B 51.2(5) 3_768 3_768
O2B S1 O3B 110.5(7) . 3_768
O1A S1 O3B 150.5(5) . 3_768
O1B S1 C35 104.8(5) . .
O2A S1 C35 104.2(3) . .
O3A S1 C35 101.7(3) 3_768 .
O2B S1 C35 105.7(5) . .
O1A S1 C35 103.7(4) . .
O3B S1 C35 104.2(5) 3_768 .
O5 S2 O6 115.1(2) . .
O5 S2 O4 115.3(2) . .
O6 S2 O4 114.51(18) . .
O5 S2 C36 104.0(2) . .
O6 S2 C36 102.4(2) . .
O4 S2 C36 103.1(2) . .
N6 Zn3 N2 119.21(14) . .
N6 Zn3 N1 117.91(14) . .
N2 Zn3 N1 95.40(14) . .
N6 Zn3 N5 95.09(13) . .
N2 Zn3 N5 118.05(14) . .
N1 Zn3 N5 112.71(15) . .
N8 Ag1 O4 99.29(13) 3_767 .
N8 Ag1 N7 96.91(14) 3_767 1_565
O4 Ag1 N7 87.82(13) . 1_565
N8 Ag1 C25 121.69(15) 3_767 .
O4 Ag1 C25 138.83(13) . .
N7 Ag1 C25 90.75(14) 1_565 .
N8 Ag1 C24 145.81(15) 3_767 .
O4 Ag1 C24 108.96(12) . .
N7 Ag1 C24 102.91(13) 1_565 .
C25 Ag1 C24 32.02(14) . .
N4 Ag2 O3A 98.82(17) 1_545 .
N4 Ag2 O1A 126.21(18) 1_545 .
O3A Ag2 O1A 100.9(2) . .
N4 Ag2 C8 118.24(14) 1_545 .
O3A Ag2 C8 126.73(18) . .
O1A Ag2 C8 87.29(18) . .
N4 Ag2 C7 132.78(15) 1_545 .
O3A Ag2 C7 94.51(17) . .
O1A Ag2 C7 94.75(17) . .
C8 Ag2 C7 32.23(14) . .
C38 C37 C42 120.0 . .
C38 C37 H37 120.0 . .
C42 C37 H37 120.0 . .
C37 C38 C39 120.0 . .
C37 C38 H38 120.0 . .
C39 C38 H38 120.0 . .
C40 C39 C38 120.0 . .
C40 C39 H39 120.0 . .
C38 C39 H39 120.0 . .
C41 C40 C39 120.0 . .
C41 C40 H40 120.0 . .
C39 C40 H40 120.0 . .
C42 C41 C40 120.0 . .
C42 C41 H41 120.0 . .
C40 C41 H41 120.0 . .
C41 C42 C37 120.0 . .
C41 C42 H42 120.0 . .
C37 C42 H42 120.0 . .
C48 C43 C44 119.9(6) . .
C48 C43 H43 120.1 . .
C44 C43 H43 120.1 . .
C45 C44 C43 120.1(6) . .
C45 C44 H44 120.0 . .
C43 C44 H44 120.0 . .
C46 C45 C44 119.4(6) . .
C46 C45 H45 120.3 . .
C44 C45 H45 120.3 . .
C45 C46 C47 119.7(6) . .
C45 C46 H46 120.1 . .
C47 C46 H46 120.1 . .
C48 C47 C46 119.4(6) . .
C48 C47 H47 120.3 . .
C46 C47 H47 120.3 . .
C47 C48 C43 121.5(7) . .
C47 C48 H48 119.2 . .
C43 C48 H48 119.2 . .
C50 C49 C51 119.8(5) . 3_778
C50 C49 H49 120.1 . .
C51 C49 H49 120.1 3_778 .
C49 C50 C51 120.2(4) . .
C49 C50 H50 119.9 . .
C51 C50 H50 119.9 . .
C50 C51 C49 120.0(5) . 3_778
C50 C51 H51 120.0 . .
C49 C51 H51 120.0 3_778 .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C1 N1 1.331(6) .
C1 C2 1.416(6) .
C1 H1 0.9300 .
C2 C3 1.361(6) .
C2 H2 0.9300 .
C3 C4 1.442(6) .
C3 H3 0.9300 .
C4 C5 1.368(6) .
C4 N1 1.407(5) .
C5 C6 1.424(6) .
C5 C10 1.496(5) .
C6 N2 1.401(5) .
C6 C7 1.405(6) .
C7 C8 1.394(6) .
C7 Ag2 2.583(4) .
C7 H7 0.9300 .
C8 C9 1.416(6) .
C8 Ag2 2.397(4) .
C8 H8 0.9300 .
C9 N2 1.328(6) .
C9 H9 0.9300 .
C10 C15 1.383(5) .
C10 C11 1.385(6) .
C11 C12 1.392(5) .
C11 H11 0.9300 .
C12 C13 1.391(5) .
C12 C16 1.442(6) .
C13 C14 1.391(6) .
C13 H13 0.9300 .
C14 C15 1.392(5) .
C14 C17 1.442(5) .
C15 H15 0.9300 .
C16 N3 1.138(6) .
C17 N4 1.141(5) .
C18 N5 1.329(5) .
C18 C19 1.406(6) .
C18 H18 0.9300 .
C19 C20 1.369(6) .
C19 H19 0.9300 .
C20 C21 1.426(6) .
C20 H20 0.9300 .
C21 N5 1.385(5) .
C21 C22 1.402(5) .
C22 C23 1.410(5) .
C22 C27 1.498(5) .
C23 N6 1.394(5) .
C23 C24 1.421(5) .
C24 C25 1.392(6) .
C24 Ag1 2.554(4) .
C24 H24 0.9300 .
C25 C26 1.419(6) .
C25 Ag1 2.488(4) .
C25 H25 0.9300 .
C26 N6 1.321(5) .
C26 H26 0.9300 .
C27 C32 1.387(5) .
C27 C28 1.388(6) .
C28 C29 1.394(5) .
C28 H28 0.9300 .
C29 C30 1.402(6) .
C29 C34 1.435(6) .
C30 C31 1.381(6) .
C30 H30 0.9300 .
C31 C32 1.399(5) .
C31 C33 1.445(5) .
C32 H32 0.9300 .
C33 N7 1.144(5) .
C34 N8 1.135(6) .
N8 Ag1 2.335(4) 3_767
C35 F2B 1.195(18) .
C35 F1A 1.253(10) .
C35 F1B 1.375(15) .
C35 F3A 1.387(10) .
C35 F2A 1.408(10) .
C35 F3B 1.482(18) .
C35 S1 1.767(6) .
C36 F6 1.320(7) .
C36 F4 1.332(6) .
C36 F5 1.336(6) .
C36 S2 1.824(5) .
N1 Zn3 1.973(3) .
N2 Zn3 1.966(4) .
N4 Ag2 2.240(3) 1_565
N5 Zn3 1.981(3) .
N6 Zn3 1.956(3) .
N7 Ag1 2.438(4) 1_545
O1A S1 1.486(6) .
O1A Ag2 2.363(6) .
O2A S1 1.385(6) .
O3A S1 1.410(6) 3_768
O3A Ag2 2.341(6) .
O1B S1 1.347(12) .
O2B S1 1.411(11) .
O3B S1 1.591(13) 3_768
O4 S2 1.451(3) .
O4 Ag1 2.379(3) .
O5 S2 1.433(3) .
O6 S2 1.440(3) .
S1 O3A 1.410(6) 3_768
S1 O3B 1.591(13) 3_768
Ag1 N8 2.335(4) 3_767
Ag1 N7 2.438(4) 1_565
Ag2 N4 2.240(3) 1_545
C37 C38 1.3900 .
C37 C42 1.3900 .
C37 H37 0.9300 .
C38 C39 1.3900 .
C38 H38 0.9300 .
C39 C40 1.3900 .
C39 H39 0.9300 .
C40 C41 1.3900 .
C40 H40 0.9300 .
C41 C42 1.3900 .
C41 H41 0.9300 .
C42 H42 0.9300 .
C43 C48 1.350(9) .
C43 C44 1.374(7) .
C43 H43 0.9300 .
C44 C45 1.368(8) .
C44 H44 0.9300 .
C45 C46 1.362(9) .
C45 H45 0.9300 .
C46 C47 1.402(11) .
C46 H46 0.9300 .
C47 C48 1.330(11) .
C47 H47 0.9300 .
C48 H48 0.9300 .
C49 C50 1.369(7) .
C49 C51 1.389(7) 3_778
C49 H49 0.9300 .
C50 C51 1.372(7) .
C50 H50 0.9300 .
C51 C49 1.389(7) 3_778
C51 H51 0.9300 .
