#------------------------------------------------------------------------------
#$Date: 2018-09-10 15:51:50 +0300 (Mon, 10 Sep 2018) $
#$Revision: 210751 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/10/22/7102226.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7102226
loop_
_publ_author_name
'Zhang, Xue-Li'
'Guo, Cui-Ping'
'Yang, Qing-Yuan'
'Wang, Wei'
'Liu, Wei-Sheng'
'Kang, Bei-Sheng'
'Su, Cheng-Yong'
_publ_section_title
;
 Formation of two (6,3) networks showing structural diversity,
 Borromean topology and conformational chirality in the same crystal
;
_journal_coden_ASTM              CHCOFS
_journal_issue                   41
_journal_name_full
;
 Chemical Communications (Cambridge, United Kingdom)
;
_journal_page_first              4242
_journal_page_last               4244
_journal_paper_doi               10.1039/b709118d
_journal_year                    2007
_chemical_formula_sum            'C194 H160 Ag5 Cl6 F30 N36 O Sb5'
_chemical_formula_weight         4942.38
_space_group_IT_number           182
_symmetry_cell_setting           hexagonal
_symmetry_space_group_name_Hall  'P 6c 2c'
_symmetry_space_group_name_H-M   'P 63 2 2'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                120.00
_cell_formula_units_Z            2
_cell_length_a                   17.791(4)
_cell_length_b                   17.791(4)
_cell_length_c                   37.231(15)
_cell_measurement_temperature    173(2)
_cell_volume                     10206(5)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.990
_diffrn_measured_fraction_theta_max 0.990
_diffrn_measurement_device_type  'Apex II'
_diffrn_measurement_method       'ω scan'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.1056
_diffrn_reflns_av_sigmaI/netI    0.0552
_diffrn_reflns_limit_h_max       22
_diffrn_reflns_limit_h_min       -22
_diffrn_reflns_limit_k_max       22
_diffrn_reflns_limit_k_min       -22
_diffrn_reflns_limit_l_max       45
_diffrn_reflns_limit_l_min       -44
_diffrn_reflns_number            65372
_diffrn_reflns_theta_full        26.17
_diffrn_reflns_theta_max         26.17
_diffrn_reflns_theta_min         2.35
_diffrn_standards_decay_%        0
_exptl_absorpt_coefficient_mu    1.285
_exptl_absorpt_correction_T_max  0.7311
_exptl_absorpt_correction_T_min  0.7148
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS Bruker 1997'
_exptl_crystal_colour            Colorless
_exptl_crystal_density_diffrn    1.608
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Block
_exptl_crystal_F_000             4892
_exptl_crystal_size_max          0.28
_exptl_crystal_size_mid          0.28
_exptl_crystal_size_min          0.26
_refine_diff_density_max         2.241
_refine_diff_density_min         -1.599
_refine_diff_density_rms         0.152
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   -0.03(7)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.034
_refine_ls_hydrogen_treatment    geom
_refine_ls_matrix_type           full
_refine_ls_number_parameters     463
_refine_ls_number_reflns         6784
_refine_ls_number_restraints     158
_refine_ls_restrained_S_all      1.047
_refine_ls_R_factor_all          0.1193
_refine_ls_R_factor_gt           0.0721
_refine_ls_shift/su_max          0.033
_refine_ls_shift/su_mean         0.003
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0910P)²+53.6227P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1818
_refine_ls_wR_factor_ref         0.2111
_reflns_number_gt                4311
_reflns_number_total             6784
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b709118d.txt
_cod_data_source_block           1
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Hexagonal' changed to 'hexagonal'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from
2010-06-29.

'_exptl_absorpt_correction_type' value 'Multi-scan' changed
to 'multi-scan' according to
'/home/saulius/struct/CIF-dictionaries/cif_core.dic' dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_sg_symbol_H-M      P6(3)22
_cod_database_code               7102226
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-y, x-y, z'
'-x+y, -x, z'
'-x, -y, z+1/2'
'y, -x+y, z+1/2'
'x-y, x, z+1/2'
'y, x, -z'
'x-y, -y, -z'
'-x, -x+y, -z'
'-y, -x, -z+1/2'
'-x+y, y, -z+1/2'
'x, x-y, -z+1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.28773(9) 0.14386(4) 0.2500 0.0953(3) Uani 1 2 d S . .
Ag2 Ag 0.6667 0.3333 0.11906(2) 0.0483(2) Uani 1 3 d S . .
N1 N 0.2897(5) 0.1616(4) 0.30570(17) 0.074(2) Uani 1 1 d . . .
N2 N 0.3216(4) 0.2245(4) 0.35781(17) 0.0593(17) Uani 1 1 d . . .
N3 N 0.2609(3) 0.5866(3) 0.36925(14) 0.0414(14) Uani 1 1 d . . .
N4 N 0.5310(3) 0.3082(3) 0.11190(16) 0.0458(15) Uani 1 1 d . . .
N5 N 0.4131(3) 0.2913(3) 0.08339(15) 0.0424(14) Uani 1 1 d . . .
N6 N 0.2583(3) 0.5874(3) 0.04144(14) 0.0347(13) Uani 1 1 d . . .
C1 C 0.3435(6) 0.2307(5) 0.3227(2) 0.070(2) Uani 1 1 d . . .
C2 C 0.2276(5) 0.1059(6) 0.3301(2) 0.069(2) Uani 1 1 d . . .
C3 C 0.2503(4) 0.1474(4) 0.3639(2) 0.0505(19) Uani 1 1 d . . .
C4 C 0.2034(5) 0.1086(6) 0.3942(2) 0.063(2) Uani 1 1 d . . .
H4A H 0.2178 0.1382 0.4166 0.076 Uiso 1 1 calc R . .
C5 C 0.1360(5) 0.0267(6) 0.3912(3) 0.091(3) Uani 1 1 d . . .
H5A H 0.1043 -0.0025 0.4122 0.110 Uiso 1 1 calc R . .
C6 C 0.1120(5) -0.0156(6) 0.3587(3) 0.091(4) Uani 1 1 d . . .
H6A H 0.0629 -0.0723 0.3573 0.110 Uiso 1 1 calc R . .
C7 C 0.1603(6) 0.0252(6) 0.3277(3) 0.082(3) Uani 1 1 d . . .
H7A H 0.1452 -0.0043 0.3053 0.098 Uiso 1 1 calc R . .
C8 C 0.3727(5) 0.2935(4) 0.3849(2) 0.061(2) Uani 1 1 d . . .
H8A H 0.4348 0.3109 0.3830 0.073 Uiso 1 1 calc R . .
H8B H 0.3526 0.2704 0.4093 0.073 Uiso 1 1 calc R . .
C9 C 0.3620(4) 0.3721(4) 0.37869(18) 0.0484(18) Uani 1 1 d . . .
C10 C 0.4329(4) 0.4516(4) 0.3752(2) 0.060(2) Uani 1 1 d . . .
H10A H 0.4885 0.4563 0.3747 0.072 Uiso 1 1 calc R . .
C11 C 0.4280(4) 0.5248(4) 0.3723(2) 0.0475(19) Uani 1 1 d . . .
H11A H 0.4796 0.5798 0.3711 0.057 Uiso 1 1 calc R . .
C12 C 0.3479(4) 0.5198(4) 0.37100(17) 0.0429(17) Uani 1 1 d . . .
C13 C 0.2745(4) 0.4377(4) 0.3741(2) 0.053(2) Uani 1 1 d . . .
H13A H 0.2186 0.4324 0.3737 0.064 Uiso 1 1 calc R . .
C14 C 0.2811(4) 0.3640(5) 0.3778(2) 0.059(2) Uani 1 1 d . . .
H14A H 0.2304 0.3085 0.3796 0.071 Uiso 1 1 calc R . .
C15 C 0.3401(4) 0.5970(4) 0.36939(17) 0.0414(17) Uani 1 1 d . . .
C16 C 0.4892(4) 0.2891(4) 0.08069(19) 0.0426(17) Uani 1 1 d . . .
C17 C 0.4069(4) 0.3142(4) 0.11791(19) 0.0418(17) Uani 1 1 d . . .
C18 C 0.4811(4) 0.3245(4) 0.13563(18) 0.0424(17) Uani 1 1 d . . .
C19 C 0.4942(5) 0.3466(5) 0.1711(2) 0.059(2) Uani 1 1 d . . .
H19A H 0.5438 0.3531 0.1835 0.071 Uiso 1 1 calc R . .
C20 C 0.4328(6) 0.3592(5) 0.1884(2) 0.070(3) Uani 1 1 d . . .
H20A H 0.4413 0.3754 0.2130 0.084 Uiso 1 1 calc R . .
C21 C 0.3600(6) 0.3492(6) 0.1714(2) 0.074(3) Uani 1 1 d . . .
H21A H 0.3189 0.3579 0.1843 0.089 Uiso 1 1 calc R . .
C22 C 0.3464(4) 0.3263(4) 0.1351(2) 0.052(2) Uani 1 1 d . . .
H22A H 0.2964 0.3193 0.1229 0.063 Uiso 1 1 calc R . .
C23 C 0.5186(4) 0.2648(5) 0.04770(17) 0.0547(19) Uani 1 1 d . . .
H23A H 0.5744 0.2680 0.0523 0.082 Uiso 1 1 calc R . .
H23B H 0.5252 0.3047 0.0282 0.082 Uiso 1 1 calc R . .
H23C H 0.4754 0.2054 0.0408 0.082 Uiso 1 1 calc R . .
C24 C 0.3556(4) 0.2828(4) 0.05350(19) 0.0423(18) Uani 1 1 d . . .
H24A H 0.2968 0.2332 0.0582 0.051 Uiso 1 1 calc R . .
H24B H 0.3775 0.2705 0.0311 0.051 Uiso 1 1 calc R . .
C25 C 0.3506(4) 0.3652(4) 0.04875(17) 0.0388(16) Uani 1 1 d . . .
C26 C 0.2713(4) 0.3604(4) 0.0480(2) 0.0462(19) Uani 1 1 d . . .
H26A H 0.2196 0.3057 0.0498 0.055 Uiso 1 1 calc R . .
C27 C 0.2669(4) 0.4351(4) 0.04481(19) 0.0454(18) Uani 1 1 d . . .
H27A H 0.2119 0.4315 0.0441 0.054 Uiso 1 1 calc R . .
C28 C 0.3419(4) 0.5156(3) 0.04261(16) 0.0353(15) Uani 1 1 d . . .
C29 C 0.4223(4) 0.5188(4) 0.04274(18) 0.0410(17) Uani 1 1 d . . .
H29A H 0.4745 0.5732 0.0411 0.049 Uiso 1 1 calc R . .
C30 C 0.4258(4) 0.4431(4) 0.04534(19) 0.0451(19) Uani 1 1 d . . .
H30A H 0.4802 0.4451 0.0447 0.054 Uiso 1 1 calc R . .
C31 C 0.3373(4) 0.5953(4) 0.04199(17) 0.0354(15) Uani 1 1 d . . .
C32 C 0.4225(6) 0.3047(6) 0.3075(3) 0.091(3) Uani 1 1 d . . .
H32A H 0.4247 0.2962 0.2816 0.137 Uiso 1 1 calc R . .
H32B H 0.4739 0.3087 0.3190 0.137 Uiso 1 1 calc R . .
H32C H 0.4213 0.3585 0.3118 0.137 Uiso 1 1 calc R . .
Sb1 Sb 0.6667 0.3333 0.2500 0.0465(3) Uani 1 6 d SDU . .
F1 F 0.6667 0.3333 0.30026(15) 0.0616(18) Uani 1 3 d SDU . .
F2 F 0.6066(3) 0.3934(3) 0.2500 0.106(5) Uani 0.50 2 d SPDU . .
F3 F 0.5480(6) 0.2537(8) 0.2506(8) 0.061(6) Uani 0.25 1 d PDU . .
F4 F 0.7737(8) 0.4348(9) 0.2526(6) 0.031(5) Uani 0.17 1 d PDU . .
Sb2 Sb 0.72682(5) 0.72682(5) 0.0000 0.06428(16) Uani 1 2 d SDU . .
F7 F 0.6789(4) 0.7803(4) -0.02474(19) 0.133(2) Uani 1 1 d DU . .
F5 F 0.7672(6) 0.8113(5) 0.0347(3) 0.193(3) Uani 1 1 d DU . .
F6 F 0.6871(5) 0.6401(5) -0.0338(2) 0.161(3) Uani 1 1 d DU . .
Sb3 Sb 1.15427(15) 0.3085(3) 0.2500 0.1803(16) Uani 0.33 2 d SPDU . .
F8 F 1.2083(4) 0.4167(7) 0.2500 0.210(7) Uani 0.33 2 d SPDU . .
F9 F 1.1661(9) 0.3102(7) 0.2941(3) 0.192(7) Uani 0.33 1 d PDU . .
F10 F 1.0614(6) 0.3078(8) 0.2542(5) 0.179(7) Uani 0.33 1 d PDU . .
F11 F 1.1005(4) 0.2011(8) 0.2500 0.198(7) Uani 0.33 2 d SPDU . .
C33 C 1.4110(3) 0.5890(3) 0.2500 0.24(2) Uiso 0.67 2 d SPD A 1
Cl3 Cl 1.3263(6) 0.5055(6) 0.2246(6) 0.250 Uiso 0.17 1 d PD . 1
Cl2 Cl 1.4945(5) 0.5857(7) 0.2280(6) 0.160(10) Uiso 0.17 1 d PD A 1
Cl1 Cl 1.4132(8) 0.6736(6) 0.2253(7) 0.250 Uiso 0.17 1 d PD . 1
Cl5 Cl 1.3572(9) 0.5534(12) 0.2104(3) 0.250 Uiso 0.33 1 d PD B 2
Cl4 Cl 1.4672(4) 0.5328(4) 0.2500 0.268(14) Uiso 0.33 2 d SPD C 2
O2 O 1.0000 1.0000 0.0000 0.20(2) Uiso 0.50 6 d SP . .
O1 O 1.0000 0.0000 0.2500 0.172(19) Uiso 0.50 6 d SP . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sb Sb -0.5866 1.5461 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N1 Ag1 N1 178.4(4) . 12
N4 Ag2 N4 118.61(6) 2_655 3_665
N4 Ag2 N4 118.61(6) 2_655 .
N4 Ag2 N4 118.61(6) 3_665 .
C1 N1 C2 107.9(7) . .
C1 N1 Ag1 125.4(6) . .
C2 N1 Ag1 126.3(5) . .
C3 N2 C1 109.5(6) . .
C3 N2 C8 126.9(6) . .
C1 N2 C8 123.6(6) . .
C15 N3 C15 115.7(7) . 3_565
C16 N4 C18 106.1(6) . .
C16 N4 Ag2 124.3(5) . .
C18 N4 Ag2 128.5(4) . .
C17 N5 C16 107.8(5) . .
C17 N5 C24 125.9(6) . .
C16 N5 C24 125.9(6) . .
C31 N6 C31 115.0(6) . 3_565
N1 C1 N2 110.6(7) . .
N1 C1 C32 125.9(8) . .
N2 C1 C32 123.3(7) . .
C7 C2 N1 133.6(9) . .
C7 C2 C3 119.2(8) . .
N1 C2 C3 107.0(6) . .
N2 C3 C4 133.1(7) . .
N2 C3 C2 105.0(6) . .
C4 C3 C2 121.9(6) . .
C5 C4 C3 117.7(8) . .
C5 C4 H4A 121.1 . .
C3 C4 H4A 121.1 . .
C4 C5 C6 121.8(9) . .
C4 C5 H5A 119.1 . .
C6 C5 H5A 119.1 . .
C5 C6 C7 119.9(8) . .
C5 C6 H6A 120.1 . .
C7 C6 H6A 120.1 . .
C2 C7 C6 119.3(9) . .
C2 C7 H7A 120.3 . .
C6 C7 H7A 120.3 . .
N2 C8 C9 110.4(7) . .
N2 C8 H8A 109.6 . .
C9 C8 H8A 109.6 . .
N2 C8 H8B 109.6 . .
C9 C8 H8B 109.6 . .
H8A C8 H8B 108.1 . .
C10 C9 C14 119.2(7) . .
C10 C9 C8 119.8(7) . .
C14 C9 C8 120.9(6) . .
C9 C10 C11 122.7(7) . .
C9 C10 H10A 118.7 . .
C11 C10 H10A 118.7 . .
C10 C11 C12 120.1(6) . .
C10 C11 H11A 119.9 . .
C12 C11 H11A 119.9 . .
C11 C12 C13 117.4(7) . .
C11 C12 C15 121.7(6) . .
C13 C12 C15 120.8(7) . .
C14 C13 C12 121.5(7) . .
C14 C13 H13A 119.2 . .
C12 C13 H13A 119.2 . .
C9 C14 C13 119.0(6) . .
C9 C14 H14A 120.5 . .
C13 C14 H14A 120.5 . .
N3 C15 N3 124.3(7) . 2_665
N3 C15 C12 117.9(6) . .
N3 C15 C12 117.8(6) 2_665 .
N4 C16 N5 111.1(6) . .
N4 C16 C23 124.5(6) . .
N5 C16 C23 124.3(6) . .
C22 C17 N5 132.7(7) . .
C22 C17 C18 121.7(7) . .
N5 C17 C18 105.6(6) . .
C19 C18 N4 130.2(7) . .
C19 C18 C17 120.4(7) . .
N4 C18 C17 109.5(6) . .
C18 C19 C20 117.6(8) . .
C18 C19 H19A 121.2 . .
C20 C19 H19A 121.2 . .
C21 C20 C19 122.6(8) . .
C21 C20 H20A 118.7 . .
C19 C20 H20A 118.7 . .
C20 C21 C22 119.9(9) . .
C20 C21 H21A 120.1 . .
C22 C21 H21A 120.1 . .
C17 C22 C21 117.8(7) . .
C17 C22 H22A 121.1 . .
C21 C22 H22A 121.1 . .
C16 C23 H23A 109.5 . .
C16 C23 H23B 109.5 . .
H23A C23 H23B 109.5 . .
C16 C23 H23C 109.5 . .
H23A C23 H23C 109.5 . .
H23B C23 H23C 109.5 . .
N5 C24 C25 111.2(5) . .
N5 C24 H24A 109.4 . .
C25 C24 H24A 109.4 . .
N5 C24 H24B 109.4 . .
C25 C24 H24B 109.4 . .
H24A C24 H24B 108.0 . .
C30 C25 C26 121.1(6) . .
C30 C25 C24 119.2(6) . .
C26 C25 C24 119.7(5) . .
C25 C26 C27 119.7(5) . .
C25 C26 H26A 120.2 . .
C27 C26 H26A 120.2 . .
C26 C27 C28 120.9(7) . .
C26 C27 H27A 119.6 . .
C28 C27 H27A 119.6 . .
C27 C28 C29 118.5(6) . .
C27 C28 C31 120.7(6) . .
C29 C28 C31 120.7(5) . .
C30 C29 C28 120.1(5) . .
C30 C29 H29A 119.9 . .
C28 C29 H29A 119.9 . .
C25 C30 C29 119.7(6) . .
C25 C30 H30A 120.1 . .
C29 C30 H30A 120.2 . .
N6 C31 N6 125.0(6) . 2_665
N6 C31 C28 117.6(5) . .
N6 C31 C28 117.4(6) 2_665 .
C1 C32 H32A 109.5 . .
C1 C32 H32B 109.5 . .
H32A C32 H32B 109.5 . .
C1 C32 H32C 109.5 . .
H32A C32 H32C 109.5 . .
H32B C32 H32C 109.5 . .
F2 Sb1 F2 120.0 2_655 3_665
F2 Sb1 F2 120.0 2_655 .
F2 Sb1 F2 120.000(1) 3_665 .
F2 Sb1 F4 27.5(6) 2_655 3_665
F2 Sb1 F4 92.7(6) 3_665 3_665
F2 Sb1 F4 147.2(6) . 3_665
F2 Sb1 F4 92.7(6) 2_655 12
F2 Sb1 F4 27.5(6) 3_665 12
F2 Sb1 F4 147.2(6) . 12
F4 Sb1 F4 65.6(12) 3_665 12
F2 Sb1 F4 27.5(6) 2_655 10_665
F2 Sb1 F4 147.2(6) 3_665 10_665
F2 Sb1 F4 92.7(6) . 10_665
F4 Sb1 F4 55.0(12) 3_665 10_665
F4 Sb1 F4 119.73(13) 12 10_665
F2 Sb1 F4 147.2(6) 2_655 .
F2 Sb1 F4 27.5(6) 3_665 .
F2 Sb1 F4 92.7(6) . .
F4 Sb1 F4 119.73(13) 3_665 .
F4 Sb1 F4 55.0(12) 12 .
F4 Sb1 F4 174.7(12) 10_665 .
F2 Sb1 F4 92.7(6) 2_655 2_655
F2 Sb1 F4 147.2(6) 3_665 2_655
F2 Sb1 F4 27.5(6) . 2_655
F4 Sb1 F4 119.73(13) 3_665 2_655
F4 Sb1 F4 174.7(12) 12 2_655
F4 Sb1 F4 65.6(12) 10_665 2_655
F4 Sb1 F4 119.73(13) . 2_655
F2 Sb1 F4 147.2(6) 2_655 11_655
F2 Sb1 F4 92.7(6) 3_665 11_655
F2 Sb1 F4 27.5(6) . 11_655
F4 Sb1 F4 174.7(12) 3_665 11_655
F4 Sb1 F4 119.73(13) 12 11_655
F4 Sb1 F4 119.73(13) 10_665 11_655
F4 Sb1 F4 65.6(12) . 11_655
F4 Sb1 F4 55.0(12) 2_655 11_655
F2 Sb1 F3 48.8(5) 2_655 11_655
F2 Sb1 F3 71.2(5) 3_665 11_655
F2 Sb1 F3 168.8(5) . 11_655
F4 Sb1 F3 21.8(7) 3_665 11_655
F4 Sb1 F3 43.9(8) 12 11_655
F4 Sb1 F3 76.1(8) 10_665 11_655
F4 Sb1 F3 98.6(7) . 11_655
F4 Sb1 F3 141.4(7) 2_655 11_655
F4 Sb1 F3 163.4(9) 11_655 11_655
F2 Sb1 F3 71.2(5) 2_655 2_655
F2 Sb1 F3 48.8(5) 3_665 2_655
F2 Sb1 F3 168.8(5) . 2_655
F4 Sb1 F3 43.9(8) 3_665 2_655
F4 Sb1 F3 21.8(7) 12 2_655
F4 Sb1 F3 98.6(7) 10_665 2_655
F4 Sb1 F3 76.1(8) . 2_655
F4 Sb1 F3 163.4(9) 2_655 2_655
F4 Sb1 F3 141.4(7) 11_655 2_655
F3 Sb1 F3 22.4(10) 11_655 2_655
F2 Sb1 F3 48.8(5) 2_655 .
F2 Sb1 F3 168.8(5) 3_665 .
F2 Sb1 F3 71.2(5) . .
F4 Sb1 F3 76.1(8) 3_665 .
F4 Sb1 F3 141.4(7) 12 .
F4 Sb1 F3 21.8(7) 10_665 .
F4 Sb1 F3 163.4(9) . .
F4 Sb1 F3 43.9(8) 2_655 .
F4 Sb1 F3 98.6(7) 11_655 .
F3 Sb1 F3 97.6(10) 11_655 .
F3 Sb1 F3 119.99(4) 2_655 .
F4 F2 F4 153.7(19) 2_655 11_655
F4 F2 F3 12.8(13) 2_655 12
F4 F2 F3 142.2(13) 11_655 12
F4 F2 F3 142.2(13) 2_655 3_665
F4 F2 F3 12.8(13) 11_655 3_665
F3 F2 F3 132.2(10) 12 3_665
F4 F2 Sb1 76.8(9) 2_655 .
F4 F2 Sb1 76.8(9) 11_655 .
F3 F2 Sb1 66.1(5) 12 .
F3 F2 Sb1 66.1(5) 3_665 .
F4 F3 F3 154(4) 10_665 12
F4 F3 F4 146.0(18) 10_665 2_655
F3 F3 F4 12.8(19) 12 2_655
F4 F3 F2 16.2(16) 10_665 2_655
F3 F3 F2 143.7(8) 12 2_655
F4 F3 F2 132.9(9) 2_655 2_655
F4 F3 Sb1 78.7(11) 10_665 .
F3 F3 Sb1 78.8(5) 12 .
F4 F3 Sb1 67.9(6) 2_655 .
F2 F3 Sb1 65.1(5) 2_655 .
F3 F4 F2 151(3) 10_665 3_665
F3 F4 F3 13(2) 10_665 3_665
F2 F4 F3 143.1(14) 3_665 3_665
F3 F4 F4 139.3(19) 10_665 12
F2 F4 F4 13.2(9) 3_665 12
F3 F4 F4 130.2(8) 3_665 12
F3 F4 Sb1 79.5(11) 10_665 .
F2 F4 Sb1 75.7(9) 3_665 .
F3 F4 Sb1 68.3(7) 3_665 .
F4 F4 Sb1 62.5(6) 12 .
F7 Sb2 F7 176.9(4) 7 .
F7 Sb2 F5 86.9(4) 7 .
F7 Sb2 F5 91.2(4) . .
F7 Sb2 F5 91.2(4) 7 7
F7 Sb2 F5 86.9(4) . 7
F5 Sb2 F5 105.5(6) . 7
F7 Sb2 F6 90.5(4) 7 7
F7 Sb2 F6 91.5(4) . 7
F5 Sb2 F6 75.1(4) . 7
F5 Sb2 F6 178.2(4) 7 7
F7 Sb2 F6 91.5(4) 7 .
F7 Sb2 F6 90.5(4) . .
F5 Sb2 F6 178.2(4) . .
F5 Sb2 F6 75.1(4) 7 .
F6 Sb2 F6 104.5(5) 7 .
F10 Sb3 F10 179.2(10) . 11_755
F10 Sb3 F9 91.4(7) . .
F10 Sb3 F9 88.7(7) 11_755 .
F10 Sb3 F9 88.7(7) . 11_755
F10 Sb3 F9 91.4(7) 11_755 11_755
F9 Sb3 F9 178.2(8) . 11_755
F10 Sb3 F11 89.6(5) . .
F10 Sb3 F11 89.6(5) 11_755 .
F9 Sb3 F11 90.9(4) . .
F9 Sb3 F11 90.9(4) 11_755 .
F10 Sb3 F8 90.4(5) . .
F10 Sb3 F8 90.4(5) 11_755 .
F9 Sb3 F8 89.1(4) . .
F9 Sb3 F8 89.1(4) 11_755 .
F11 Sb3 F8 180.000(1) . .
Sb3 F8 Cl3 130.3(4) . .
Sb3 F8 Cl3 130.3(5) . 11_755
Cl3 F8 Cl3 99.4(9) . 11_755
Cl2 C33 Cl2 78.1(12) 10_775 .
Cl2 C33 Cl1 97.5(8) 10_775 10_775
Cl2 C33 Cl1 175.6(11) . 10_775
Cl2 C33 Cl1 175.6(11) 10_775 .
Cl2 C33 Cl1 97.5(7) . .
Cl1 C33 Cl1 86.8(14) 10_775 .
Cl2 C33 Cl3 96.0(7) 10_775 10_775
Cl2 C33 Cl3 84.9(8) . 10_775
Cl1 C33 Cl3 94.9(7) 10_775 10_775
Cl1 C33 Cl3 84.2(9) . 10_775
Cl2 C33 Cl3 84.9(8) 10_775 .
Cl2 C33 Cl3 96.0(7) . .
Cl1 C33 Cl3 84.2(9) 10_775 .
Cl1 C33 Cl3 94.9(7) . .
Cl3 C33 Cl3 178.9(10) 10_775 .
C33 Cl3 F8 119.9(11) . .
C33 Cl3 Cl1 87.3(7) . 3_775
F8 Cl3 Cl1 80.6(6) . 3_775
C33 Cl3 Cl1 47.4(5) . 10_775
F8 Cl3 Cl1 78.6(8) . 10_775
Cl1 Cl3 Cl1 56.1(11) 3_775 10_775
C33 Cl3 Cl2 46.7(5) . 10_775
F8 Cl3 Cl2 94.4(9) . 10_775
Cl1 Cl3 Cl2 123.0(10) 3_775 10_775
Cl1 Cl3 Cl2 67.2(8) 10_775 10_775
C33 Cl2 Cl2 50.9(6) . 10_775
C33 Cl2 Cl3 48.3(5) . 10_775
Cl2 Cl2 Cl3 69.7(9) 10_775 10_775
C33 Cl1 Cl1 90.9(14) . 12
C33 Cl1 Cl3 136.6(11) . 2_755
Cl1 Cl1 Cl3 64.0(7) 12 2_755
C33 Cl1 Cl3 48.3(5) . 10_775
Cl1 Cl1 Cl3 59.9(10) 12 10_775
Cl3 Cl1 Cl3 88.4(9) 2_755 10_775
C33 Cl1 Cl1 85.0(6) . 3_775
Cl1 Cl1 Cl1 92.4(2) 12 3_775
Cl3 Cl1 Cl1 128.0(6) 2_755 3_775
Cl3 Cl1 Cl1 120.4(6) 10_775 3_775
C33 Cl1 Cl1 133.6(7) . 2_755
Cl1 Cl1 Cl1 63.7(6) 12 2_755
Cl3 Cl1 Cl1 68.0(6) 2_755 2_755
Cl3 Cl1 Cl1 123.6(6) 10_775 2_755
Cl1 Cl1 Cl1 60.000(2) 3_775 2_755
C33 Cl1 Cl1 46.6(7) . 10_775
Cl1 Cl1 Cl1 61.9(12) 12 10_775
Cl3 Cl1 Cl1 125.8(14) 2_755 10_775
Cl3 Cl1 Cl1 66.0(10) 10_775 10_775
Cl1 Cl1 Cl1 54.5(8) 3_775 10_775
Cl1 Cl1 Cl1 87.1(3) 2_755 10_775
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 N1 2.095(6) .
Ag1 N1 2.095(6) 12
Ag2 N4 2.240(6) 2_655
Ag2 N4 2.240(6) 3_665
Ag2 N4 2.240(6) .
N1 C1 1.284(10) .
N1 C2 1.390(10) .
N2 C3 1.343(8) .
N2 C1 1.354(10) .
N2 C8 1.493(10) .
N3 C15 1.326(8) .
N3 C15 1.341(8) 3_565
N4 C16 1.329(9) .
N4 C18 1.382(9) .
N5 C17 1.369(9) .
N5 C16 1.377(9) .
N5 C24 1.468(8) .
N6 C31 1.340(8) .
N6 C31 1.342(7) 3_565
C1 C32 1.477(12) .
C2 C7 1.335(11) .
C2 C3 1.414(11) .
C3 C4 1.367(10) .
C4 C5 1.352(12) .
C4 H4A 0.9500 .
C5 C6 1.376(15) .
C5 H5A 0.9500 .
C6 C7 1.405(14) .
C6 H6A 0.9500 .
C7 H7A 0.9500 .
C8 C9 1.520(11) .
C8 H8A 0.9900 .
C8 H8B 0.9900 .
C9 C10 1.352(8) .
C9 C14 1.374(11) .
C10 C11 1.353(11) .
C10 H10A 0.9500 .
C11 C12 1.382(10) .
C11 H11A 0.9500 .
C12 C13 1.395(9) .
C12 C15 1.449(11) .
C13 C14 1.381(11) .
C13 H13A 0.9500 .
C14 H14A 0.9500 .
C15 N3 1.341(8) 2_665
C16 C23 1.482(10) .
C17 C22 1.358(10) .
C17 C18 1.404(10) .
C18 C19 1.366(10) .
C19 C20 1.378(13) .
C19 H19A 0.9500 .
C20 C21 1.371(13) .
C20 H20A 0.9500 .
C21 C22 1.399(11) .
C21 H21A 0.9500 .
C22 H22A 0.9500 .
C23 H23A 0.9800 .
C23 H23B 0.9800 .
C23 H23C 0.9800 .
C24 C25 1.523(9) .
C24 H24A 0.9900 .
C24 H24B 0.9900 .
C25 C30 1.368(7) .
C25 C26 1.371(9) .
C26 C27 1.375(10) .
C26 H26A 0.9500 .
C27 C28 1.389(8) .
C27 H27A 0.9500 .
C28 C29 1.402(9) .
C28 C31 1.462(9) .
C29 C30 1.384(10) .
C29 H29A 0.9500 .
C30 H30A 0.9500 .
C31 N6 1.342(7) 2_665
C32 H32A 0.9800 .
C32 H32B 0.9800 .
C32 H32C 0.9800 .
Sb1 F2 1.850(10) 2_655
Sb1 F2 1.850(10) 3_665
Sb1 F2 1.850(10) .
Sb1 F4 1.859(10) 3_665
Sb1 F4 1.859(10) 12
Sb1 F4 1.859(10) 10_665
Sb1 F4 1.859(10) .
Sb1 F4 1.859(10) 2_655
Sb1 F4 1.859(10) 11_655
Sb1 F3 1.864(9) 11_655
Sb1 F3 1.864(9) 2_655
Sb1 F3 1.864(9) .
F2 F4 0.881(19) 2_655
F2 F4 0.88(2) 11_655
F2 F3 1.535(15) 12
F2 F3 1.535(15) 3_665
F3 F4 0.70(2) 10_665
F3 F3 0.72(3) 12
F3 F4 1.39(3) 2_655
F3 F2 1.535(15) 2_655
F4 F3 0.70(2) 10_665
F4 F2 0.881(19) 3_665
F4 F3 1.39(3) 3_665
F4 F4 1.72(4) 12
Sb2 F7 1.815(6) 7
Sb2 F7 1.815(6) .
Sb2 F5 1.834(8) .
Sb2 F5 1.834(8) 7
Sb2 F6 1.837(7) 7
Sb2 F6 1.837(7) .
Sb3 F10 1.653(11) .
Sb3 F10 1.653(11) 11_755
Sb3 F9 1.654(11) .
Sb3 F9 1.654(11) 11_755
Sb3 F11 1.656(12) .
Sb3 F8 1.666(11) .
F8 Cl3 2.116(16) .
F8 Cl3 2.116(16) 11_755
C33 Cl2 1.725(12) 10_775
C33 Cl2 1.725(12) .
C33 Cl1 1.746(13) 10_775
C33 Cl1 1.746(13) .
C33 Cl3 1.770(12) 10_775
C33 Cl3 1.770(12) .
Cl3 Cl1 2.271(19) 3_775
Cl3 Cl1 2.36(3) 10_775
Cl3 Cl2 2.36(3) 10_775
Cl2 Cl2 2.17(3) 10_775
Cl2 Cl3 2.36(3) 10_775
Cl1 Cl1 2.18(5) 12
Cl1 Cl3 2.271(19) 2_755
Cl1 Cl3 2.36(3) 10_775
Cl1 Cl1 2.36(2) 3_775
Cl1 Cl1 2.36(2) 2_755
Cl1 Cl1 2.40(4) 10_775
