#------------------------------------------------------------------------------
#$Date: 2016-03-26 02:37:28 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180148 $
#$URL: svn://www.crystallography.net/cod/cif/7/10/45/7104554.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7104554
loop_
_publ_author_name
'Ni, Jun'
'Zhang, Li-Yi'
'Wen, Hui-Min'
'Chen, Zhong-Ning'
_publ_section_title
;
 Luminescence vapochromic properties of a platinum(II) complex with
 5,5'-bis(trimethylsilylethynyl)-2,2'-bipyridine.
;
_journal_issue                   25
_journal_name_full
'Chemical communications (Cambridge, England)'
_journal_page_first              3801
_journal_page_last               3803
_journal_paper_doi               10.1039/b901248f
_journal_volume                  34
_journal_year                    2009
_chemical_formula_sum            'C94 H90 N12 Pt2 Si4'
_chemical_formula_weight         1890.32
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.500(10)
_cell_angle_beta                 100.190(10)
_cell_angle_gamma                110.160(10)
_cell_formula_units_Z            2
_cell_length_a                   15.104(4)
_cell_length_b                   15.307(4)
_cell_length_c                   20.785(6)
_cell_measurement_reflns_used    9869
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      27.4835
_cell_measurement_theta_min      3.0839
_cell_volume                     4427(2)
_computing_cell_refinement       'CrystalClear (Rigaku/MSC Inc., 2005)'
_computing_data_collection       'CrystalClear (Rigaku/MSC Inc., 2005)'
_computing_data_reduction        'CrystalClear (Rigaku/MSC Inc., 2005)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.953
_diffrn_measured_fraction_theta_max 0.953
_diffrn_measurement_device_type  Saturn70
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0363
_diffrn_reflns_av_sigmaI/netI    0.0510
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_number            27972
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         2.24
_exptl_absorpt_coefficient_mu    3.262
_exptl_absorpt_correction_T_max  0.622
_exptl_absorpt_correction_T_min  0.559
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS, Bruker(2000)'
_exptl_crystal_colour            Red
_exptl_crystal_density_diffrn    1.418
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Block
_exptl_crystal_F_000             1900
_exptl_crystal_size_max          0.6000
_exptl_crystal_size_mid          0.1500
_exptl_crystal_size_min          0.1500
_refine_diff_density_max         1.499
_refine_diff_density_min         -1.128
_refine_diff_density_rms         0.084
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.104
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1023
_refine_ls_number_reflns         14881
_refine_ls_number_restraints     41
_refine_ls_restrained_S_all      1.104
_refine_ls_R_factor_all          0.0519
_refine_ls_R_factor_gt           0.0405
_refine_ls_shift/su_max          0.007
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0470P)²+0.9522P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1006
_refine_ls_wR_factor_ref         0.1106
_reflns_number_gt                12150
_reflns_number_total             14881
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b901248f.txt
_cod_data_source_block           1.Hexane
_cod_depositor_comments
;
The following automatic conversions were performed:
'_exptl_absorpt_correction_type' value 'Multi-scan' changed to
'multi-scan' according to
'/home/saulius/struct/CIF-dictionaries/cif_core.dic' dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7104554
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
C201 C 0.5220(8) 1.2671(8) -0.2785(6) 0.163(5) Uani 1 1 d . . .
H201 H 0.5588 1.2917 -0.3099 0.195 Uiso 1 1 calc R . .
C155 C 0.5577(8) 1.2941(7) -0.2127(6) 0.152(4) Uani 1 1 d . . .
H155 H 0.6198 1.3366 -0.1995 0.182 Uiso 1 1 calc R . .
N16 N 0.5015(6) 1.2581(6) -0.1656(4) 0.137(3) Uani 1 1 d . . .
C154 C 0.4333(8) 1.2046(9) -0.2959(4) 0.182(6) Uani 1 1 d . . .
H154 H 0.4091 1.1844 -0.3399 0.218 Uiso 1 1 calc R . .
C153 C 0.3782(6) 1.1704(7) -0.2517(4) 0.135(4) Uani 1 1 d . . .
H153 H 0.3160 1.1284 -0.2658 0.162 Uiso 1 1 calc R . .
C152 C 0.4104(5) 1.1951(6) -0.1882(4) 0.090(2) Uani 1 1 d . . .
C127 C 0.3532(5) 1.1548(5) -0.1378(3) 0.0757(17) Uani 1 1 d . . .
N20 N 0.2673(4) 1.0853(4) -0.1587(3) 0.0906(18) Uani 1 1 d . . .
C200 C 0.3850(4) 1.1818(4) -0.0747(3) 0.0726(17) Uani 1 1 d . . .
H200 H 0.4432 1.2306 -0.0613 0.087 Uiso 1 1 calc R . .
C128 C 0.2160(4) 1.0418(5) -0.1132(3) 0.0792(19) Uani 1 1 d . . .
H128 H 0.1572 0.9943 -0.1275 0.095 Uiso 1 1 calc R . .
C125 C 0.3344(5) 1.1397(5) -0.0304(3) 0.0790(18) Uani 1 1 d . . .
H125 H 0.3581 1.1609 0.0135 0.095 Uiso 1 1 calc R . .
C47 C 0.2475(4) 1.0654(4) -0.0467(3) 0.0634(15) Uani 1 1 d . . .
C46 C 0.1946(4) 1.0156(4) -0.0002(3) 0.0601(14) Uani 1 1 d . . .
C45 C 0.1465(5) 0.9713(4) 0.0368(3) 0.0672(16) Uani 1 1 d . . .
Pt1 Pt 0.055703(15) 0.891656(15) 0.086919(9) 0.05420(8) Uani 1 1 d . . .
C23 C 0.5639(4) 0.2904(4) 1.0743(3) 0.0693(16) Uani 1 1 d . . .
H23 H 0.5077 0.2406 1.0581 0.083 Uiso 1 1 calc R . .
C26 C 0.5119(5) 0.2825(5) 1.1795(3) 0.0760(17) Uani 1 1 d . . .
Pt2 Pt 0.932848(15) 0.585508(15) 0.943469(9) 0.05408(8) Uani 1 1 d . . .
Si2 Si -0.10963(15) 0.78540(14) 0.43552(8) 0.0796(5) Uani 1 1 d . . .
Si1 Si 1.25745(14) 0.83088(17) 0.65420(10) 0.0928(6) Uani 1 1 d . . .
N7 N -0.0534(3) 0.8071(3) 0.1298(2) 0.0553(11) Uani 1 1 d . . .
C19 C 0.8282(4) 0.5044(5) 0.9819(3) 0.0638(15) Uani 1 1 d . . .
N6 N -0.0542(3) 0.8388(3) 0.00569(19) 0.0546(11) Uani 1 1 d . . .
N1 N 1.0249(3) 0.6320(3) 1.0343(2) 0.0592(12) Uani 1 1 d . . .
N2 N 1.0556(3) 0.6778(3) 0.9157(2) 0.0572(11) Uani 1 1 d . . .
C36 C 0.1537(4) 0.9195(5) 0.1681(3) 0.0679(16) Uani 1 1 d D . .
C11 C 0.8095(4) 0.5387(4) 0.7998(3) 0.0629(15) Uani 1 1 d . . .
C10 C 0.8527(4) 0.5528(4) 0.8542(3) 0.0654(15) Uani 1 1 d . . .
C33 C -0.0525(4) 0.7998(4) 0.1937(2) 0.0620(15) Uani 1 1 d . . .
H33 H 0.0038 0.8334 0.2228 0.074 Uiso 1 1 calc R . .
C27 C -0.0468(4) 0.8602(4) -0.0562(2) 0.0542(14) Uani 1 1 d . . .
H27 H 0.0081 0.9072 -0.0636 0.065 Uiso 1 1 calc R . .
C7 C 1.0671(4) 0.6943(4) 0.8528(3) 0.0635(15) Uani 1 1 d . . .
H7 H 1.0177 0.6627 0.8181 0.076 Uiso 1 1 calc R . .
C15 C 0.6837(4) 0.5295(5) 0.6019(3) 0.0672(16) Uani 1 1 d . . .
C12 C 0.7630(4) 0.5321(4) 0.7324(3) 0.0617(15) Uani 1 1 d . . .
C21 C 0.7111(4) 0.4076(4) 1.0568(3) 0.0647(15) Uani 1 1 d . . .
C20 C 0.7738(4) 0.4585(4) 1.0141(3) 0.0668(15) Uani 1 1 d . . .
C1 C 1.0031(5) 0.6020(4) 1.0917(3) 0.0654(15) Uani 1 1 d . . .
H1 H 0.9423 0.5587 1.0921 0.078 Uiso 1 1 calc R . .
C25 C 0.7306(4) 0.4322(5) 1.1233(3) 0.0774(19) Uani 1 1 d . . .
H25 H 0.7883 0.4791 1.1414 0.093 Uiso 1 1 calc R . .
C34 C -0.1237(5) 0.7516(5) 0.2896(3) 0.0744(17) Uani 1 1 d . . .
N4 N 0.6966(4) 0.6031(4) 0.6424(3) 0.0902(17) Uani 1 1 d . . .
C37 C 0.2072(4) 0.9190(5) 0.2180(3) 0.0720(16) Uani 1 1 d D . .
C22 C 0.6267(5) 0.3332(5) 1.0334(4) 0.087(2) Uani 1 1 d . . .
H22 H 0.6121 0.3117 0.9895 0.104 Uiso 1 1 calc R . .
C38 C 0.2675(4) 0.9069(4) 0.2762(3) 0.0696(16) Uani 1 1 d . . .
C14 C 0.7055(4) 0.4530(4) 0.6237(3) 0.0687(15) Uani 1 1 d . . .
H14 H 0.6945 0.4020 0.5949 0.082 Uiso 1 1 calc R . .
C43 C 0.4500(4) 0.8633(5) 0.4417(3) 0.0690(16) Uani 1 1 d . . .
N8 N 0.2945(5) 0.8202(5) 0.3684(3) 0.104(2) Uani 1 1 d . . .
C35 C -0.1179(5) 0.7611(5) 0.3472(3) 0.0765(18) Uani 1 1 d . . .
C16 C 0.7356(5) 0.6026(5) 0.7061(3) 0.0838(19) Uani 1 1 d . . .
H16 H 0.7444 0.6539 0.7341 0.101 Uiso 1 1 calc R . .
C32 C -0.1293(5) 0.7457(4) 0.2191(3) 0.0658(16) Uani 1 1 d . . .
C2 C 1.1116(4) 0.6951(4) 1.0316(3) 0.0605(14) Uani 1 1 d . . .
C28 C -0.1340(4) 0.7732(4) 0.0168(2) 0.0548(13) Uani 1 1 d . . .
C29 C -0.1358(4) 0.7567(4) 0.0873(2) 0.0542(13) Uani 1 1 d . . .
C3 C 1.1277(4) 0.7219(4) 0.9665(3) 0.0616(14) Uani 1 1 d . . .
C17 C 0.6468(4) 0.5351(5) 0.5319(3) 0.0801(19) Uani 1 1 d . . .
C41 C 0.4191(4) 0.9520(4) 0.3487(3) 0.0725(17) Uani 1 1 d . . .
H41 H 0.4820 0.9933 0.3611 0.087 Uiso 1 1 calc R . .
C13 C 0.7443(4) 0.4540(4) 0.6895(3) 0.0705(16) Uani 1 1 d . . .
H13 H 0.7579 0.4025 0.7053 0.085 Uiso 1 1 calc R . .
C31 C -0.2124(5) 0.6929(5) 0.1758(3) 0.0783(19) Uani 1 1 d . . .
H31 H -0.2660 0.6545 0.1910 0.094 Uiso 1 1 calc R . .
N5 N 0.6501(4) 0.4711(5) 0.4892(3) 0.106(2) Uani 1 1 d . . .
N9 N 0.5418(5) 0.9272(5) 0.4581(3) 0.115(2) Uani 1 1 d . . .
N3 N 0.6690(4) 0.3908(4) 1.1629(3) 0.0959(18) Uani 1 1 d . . .
C30 C -0.2130(4) 0.6992(4) 0.1096(3) 0.0702(16) Uani 1 1 d . . .
H30 H -0.2674 0.6633 0.0796 0.084 Uiso 1 1 calc R . .
C24 C 0.5853(4) 0.3216(4) 1.1369(3) 0.0706(16) Uani 1 1 d . . .
C42 C 0.3861(4) 0.8797(4) 0.3842(3) 0.0692(16) Uani 1 1 d . . .
C6 C 1.1527(5) 0.7586(5) 0.8402(3) 0.0723(17) Uani 1 1 d . . .
C40 C 0.3626(5) 0.9655(5) 0.2956(3) 0.0845(19) Uani 1 1 d . . .
H40 H 0.3875 1.0154 0.2709 0.101 Uiso 1 1 calc R . .
C44 C 0.4182(5) 0.7916(5) 0.4755(3) 0.093(2) Uani 1 1 d . . .
H44 H 0.3553 0.7501 0.4637 0.112 Uiso 1 1 calc R . .
C18 C 0.6113(5) 0.6028(6) 0.5125(3) 0.096(2) Uani 1 1 d . . .
H18 H 0.6101 0.6467 0.5432 0.116 Uiso 1 1 calc R . .
C39 C 0.2357(5) 0.8358(5) 0.3149(3) 0.090(2) Uani 1 1 d . . .
H39 H 0.1718 0.7963 0.3046 0.108 Uiso 1 1 calc R . .
C8 C 1.1700(5) 0.7743(5) 0.7745(3) 0.0795(18) Uani 1 1 d . . .
C4 C 1.2107(5) 0.7870(5) 0.9555(3) 0.0796(18) Uani 1 1 d . . .
H4 H 1.2585 0.8193 0.9908 0.096 Uiso 1 1 calc R . .
C9 C 1.1960(5) 0.7940(5) 0.7240(3) 0.090(2) Uani 1 1 d . . .
C5 C 1.2241(5) 0.8052(5) 0.8928(3) 0.0836(19) Uani 1 1 d . . .
H5 H 1.2813 0.8489 0.8857 0.100 Uiso 1 1 calc R . .
Si5 Si -0.06633(13) 0.89713(14) -0.30825(7) 0.0708(5) Uani 1 1 d . . .
C117 C -0.1183(4) 0.8146(4) -0.1092(2) 0.0582(15) Uani 1 1 d . . .
C118 C -0.1997(4) 0.7448(4) -0.0971(2) 0.0637(15) Uani 1 1 d . . .
H118 H -0.2484 0.7120 -0.1317 0.076 Uiso 1 1 calc R . .
C119 C -0.2082(4) 0.7243(4) -0.0334(2) 0.0611(14) Uani 1 1 d . . .
H119 H -0.2629 0.6784 -0.0246 0.073 Uiso 1 1 calc R . .
C106 C 1.1573(5) 0.6977(5) 1.1485(3) 0.0752(18) Uani 1 1 d . . .
H106 H 1.2024 0.7209 1.1870 0.090 Uiso 1 1 calc R . .
C105 C 1.0674(5) 0.6329(4) 1.1503(3) 0.0659(15) Uani 1 1 d . . .
C116 C -0.1055(4) 0.8392(4) -0.1745(2) 0.0645(15) Uani 1 1 d . . .
N10 N 0.4350(5) 0.2050(5) 1.1532(4) 0.108(2) Uani 1 1 d . . .
C114 C 0.5213(5) 0.3262(5) 1.2386(3) 0.089(2) Uani 1 1 d . . .
H114 H 0.5749 0.3789 1.2546 0.106 Uiso 1 1 calc R . .
C107 C 1.1791(5) 0.7274(5) 1.0889(3) 0.0746(17) Uani 1 1 d . . .
H107 H 1.2398 0.7697 1.0873 0.090 Uiso 1 1 calc R . .
C115 C -0.0918(5) 0.8607(5) -0.2271(3) 0.0766(18) Uani 1 1 d . . .
C103 C 1.0393(5) 0.6001(5) 1.2112(3) 0.0727(17) Uani 1 1 d . . .
C120 C -0.1329(5) 0.6760(5) 0.4757(3) 0.090(2) Uani 1 1 d . . .
H12A H -0.1937 0.6316 0.4543 0.135 Uiso 1 1 calc R . .
H12B H -0.1345 0.6873 0.5209 0.135 Uiso 1 1 calc R . .
H12C H -0.0829 0.6517 0.4729 0.135 Uiso 1 1 calc R . .
C104 C 1.0174(5) 0.5721(5) 1.2604(3) 0.0782(18) Uani 1 1 d . . .
C108 C 0.6189(7) 0.4790(7) 0.4243(4) 0.134(4) Uani 1 1 d . . .
H108 H 0.6233 0.4364 0.3939 0.161 Uiso 1 1 calc R . .
C133 C 0.8575(5) 0.5022(5) 1.3346(4) 0.106(2) Uani 1 1 d . . .
H13A H 0.8410 0.5554 1.3210 0.159 Uiso 1 1 calc R . .
H13B H 0.8415 0.4872 1.3768 0.159 Uiso 1 1 calc R . .
H13C H 0.8223 0.4499 1.3033 0.159 Uiso 1 1 calc R . .
C112 C 0.3727(6) 0.2150(7) 1.2507(5) 0.120(3) Uani 1 1 d . . .
H112 H 0.3247 0.1925 1.2752 0.144 Uiso 1 1 calc R . .
C122 C 0.6011(5) 0.9110(7) 0.5114(4) 0.109(3) Uani 1 1 d . . .
H122 H 0.6646 0.9514 0.5227 0.131 Uiso 1 1 calc R . .
C113 C 0.4520(6) 0.2922(7) 1.2735(4) 0.112(3) Uani 1 1 d . . .
H113 H 0.4579 0.3217 1.3141 0.134 Uiso 1 1 calc R . .
C111 C 0.3654(5) 0.1727(6) 1.1926(5) 0.106(3) Uani 1 1 d . . .
H111 H 0.3119 0.1196 1.1776 0.128 Uiso 1 1 calc R . .
C110 C 0.5765(6) 0.6060(7) 0.4457(4) 0.125(4) Uani 1 1 d . . .
H110 H 0.5495 0.6505 0.4320 0.151 Uiso 1 1 calc R . .
C109 C 0.5823(7) 0.5441(9) 0.4011(4) 0.149(5) Uani 1 1 d . . .
H109 H 0.5619 0.5463 0.3564 0.179 Uiso 1 1 calc R . .
C130 C -0.1601(7) 0.9385(8) -0.3496(4) 0.172(5) Uani 1 1 d . . .
H13D H -0.2175 0.8860 -0.3656 0.258 Uiso 1 1 calc R . .
H13E H -0.1388 0.9732 -0.3856 0.258 Uiso 1 1 calc R . .
H13F H -0.1731 0.9780 -0.3192 0.258 Uiso 1 1 calc R . .
C123 C 0.5696(7) 0.8385(7) 0.5474(4) 0.122(3) Uani 1 1 d . . .
H123 H 0.6096 0.8299 0.5843 0.146 Uiso 1 1 calc R . .
C132 C 1.0184(5) 0.4221(5) 1.3531(4) 0.115(3) Uani 1 1 d . . .
H13G H 0.9762 0.3728 1.3214 0.173 Uiso 1 1 calc R . .
H13H H 1.0111 0.4034 1.3964 0.173 Uiso 1 1 calc R . .
H13I H 1.0837 0.4348 1.3485 0.173 Uiso 1 1 calc R . .
C129 C -0.0616(7) 0.7980(6) -0.3544(4) 0.135(3) Uani 1 1 d . . .
H12D H -0.1250 0.7523 -0.3665 0.203 Uiso 1 1 calc R . .
H12E H -0.0204 0.7710 -0.3279 0.203 Uiso 1 1 calc R . .
H12F H -0.0367 0.8185 -0.3933 0.203 Uiso 1 1 calc R . .
C121 C -0.2000(7) 0.8369(7) 0.4444(4) 0.143(4) Uani 1 1 d . . .
H12G H -0.1848 0.8958 0.4252 0.215 Uiso 1 1 calc R . .
H12H H -0.2004 0.8461 0.4901 0.215 Uiso 1 1 calc R . .
H12I H -0.2622 0.7957 0.4225 0.215 Uiso 1 1 calc R . .
C124 C 0.4788(8) 0.7781(7) 0.5289(5) 0.140(4) Uani 1 1 d . . .
H124 H 0.4568 0.7265 0.5527 0.168 Uiso 1 1 calc R . .
C101 C 1.2492(8) 0.9410(7) 0.6308(5) 0.177(5) Uani 1 1 d . . .
H10A H 1.2822 0.9877 0.6664 0.266 Uiso 1 1 calc R . .
H10B H 1.1829 0.9354 0.6204 0.266 Uiso 1 1 calc R . .
H10C H 1.2780 0.9587 0.5931 0.266 Uiso 1 1 calc R . .
C102 C 1.3793(7) 0.8376(11) 0.6811(6) 0.252(8) Uani 1 1 d . . .
H10D H 1.4055 0.8279 0.6440 0.378 Uiso 1 1 calc R . .
H10E H 1.3809 0.7905 0.7110 0.378 Uiso 1 1 calc R . .
H10F H 1.4167 0.8981 0.7029 0.378 Uiso 1 1 calc R . .
C100 C 1.1984(9) 0.7462(8) 0.5820(5) 0.211(6) Uani 1 1 d . . .
H10G H 1.2314 0.7666 0.5464 0.317 Uiso 1 1 calc R . .
H10H H 1.1327 0.7422 0.5693 0.317 Uiso 1 1 calc R . .
H10I H 1.2004 0.6860 0.5929 0.317 Uiso 1 1 calc R . .
C151 C 0.0134(6) 0.8699(6) 0.4664(4) 0.138(4) Uani 1 1 d . . .
H15A H 0.0587 0.8383 0.4693 0.208 Uiso 1 1 calc R . .
H15B H 0.0164 0.8967 0.5091 0.208 Uiso 1 1 calc R . .
H15C H 0.0286 0.9185 0.4369 0.208 Uiso 1 1 calc R . .
C150 C 0.0524(6) 0.9889(6) -0.2942(4) 0.131(3) Uani 1 1 d . . .
H15D H 0.0650 1.0150 -0.3349 0.196 Uiso 1 1 calc R . .
H15E H 0.1004 0.9629 -0.2769 0.196 Uiso 1 1 calc R . .
H15F H 0.0541 1.0369 -0.2635 0.196 Uiso 1 1 calc R . .
Si4 Si 0.98750(14) 0.52958(14) 1.33970(9) 0.0769(5) Uani 1 1 d . . .
C131 C 1.0616(5) 0.6247(6) 1.4035(4) 0.118(3) Uani 1 1 d . . .
H13J H 1.1284 0.6340 1.4061 0.178 Uiso 1 1 calc R . .
H13K H 1.0442 0.6080 1.4452 0.178 Uiso 1 1 calc R . .
H13L H 1.0506 0.6813 1.3924 0.178 Uiso 1 1 calc R . .
C300 C 0.5347(10) 0.5248(11) 0.9805(7) 0.201(7) Uani 1 1 d D . .
H30C H 0.5971 0.5212 0.9984 0.241 Uiso 1 1 calc R . .
H30D H 0.5409 0.5900 0.9809 0.241 Uiso 1 1 calc R . .
C301 C 0.4997(12) 0.4797(10) 0.9098(8) 0.243(10) Uani 1 1 d D . .
H30A H 0.4384 0.4864 0.8930 0.291 Uiso 1 1 calc R . .
H30B H 0.4879 0.4134 0.9116 0.291 Uiso 1 1 calc R . .
C302 C 0.5652(10) 0.5165(11) 0.8596(10) 0.275(10) Uani 1 1 d D . .
H30E H 0.6175 0.4935 0.8674 0.412 Uiso 1 1 calc R . .
H30F H 0.5900 0.5834 0.8639 0.412 Uiso 1 1 calc R . .
H30G H 0.5288 0.4953 0.8160 0.412 Uiso 1 1 calc R . .
C304 C 0.4851(12) -0.0125(13) 0.9633(2) 0.338(13) Uani 1 1 d DU . .
H30H H 0.4223 -0.0083 0.9481 0.406 Uiso 1 1 calc R . .
H30I H 0.4804 -0.0763 0.9541 0.406 Uiso 1 1 calc R . .
C305 C 0.5577(14) 0.0530(15) 0.9264(6) 0.356(14) Uani 1 1 d DU . .
H30J H 0.5596 0.1164 0.9337 0.428 Uiso 1 1 calc R . .
H30K H 0.6212 0.0517 0.9437 0.428 Uiso 1 1 calc R . .
C306 C 0.5323(17) 0.0255(13) 0.8537(5) 0.378(14) Uani 1 1 d DU . .
H30L H 0.4654 -0.0122 0.8419 0.567 Uiso 1 1 calc R . .
H30M H 0.5704 -0.0095 0.8430 0.567 Uiso 1 1 calc R . .
H30N H 0.5449 0.0806 0.8299 0.567 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C154 C201 C155 118.2(9) . . ?
C154 C201 H201 120.9 . . ?
C155 C201 H201 120.9 . . ?
C201 C155 N16 120.8(9) . . ?
C201 C155 H155 119.6 . . ?
N16 C155 H155 119.6 . . ?
C152 N16 C155 116.9(8) . . ?
C201 C154 C153 121.7(10) . . ?
C201 C154 H154 119.1 . . ?
C153 C154 H154 119.1 . . ?
C152 C153 C154 121.4(8) . . ?
C152 C153 H153 119.3 . . ?
C154 C153 H153 119.3 . . ?
C153 C152 N16 120.9(7) . . ?
C153 C152 C127 122.7(7) . . ?
N16 C152 C127 116.4(7) . . ?
C200 C127 N20 120.7(6) . . ?
C200 C127 C152 122.2(6) . . ?
N20 C127 C152 117.0(6) . . ?
C127 N20 C128 118.6(6) . . ?
C127 C200 C125 120.5(6) . . ?
C127 C200 H200 119.7 . . ?
C125 C200 H200 119.7 . . ?
N20 C128 C47 122.8(6) . . ?
N20 C128 H128 118.6 . . ?
C47 C128 H128 118.6 . . ?
C200 C125 C47 123.0(6) . . ?
C200 C125 H125 118.5 . . ?
C47 C125 H125 118.5 . . ?
C128 C47 C125 114.3(5) . . ?
C128 C47 C46 121.5(6) . . ?
C125 C47 C46 124.3(6) . . ?
C45 C46 C47 177.1(7) . . ?
C46 C45 Pt1 172.5(6) . . ?
C45 Pt1 C36 92.7(2) . . ?
C45 Pt1 N7 172.8(2) . . ?
C36 Pt1 N7 94.4(2) . . ?
C45 Pt1 N6 94.4(2) . . ?
C36 Pt1 N6 170.2(2) . . ?
N7 Pt1 N6 78.78(17) . . ?
C24 C23 C22 119.0(6) . . ?
C24 C23 H23 120.5 . . ?
C22 C23 H23 120.5 . . ?
C114 C26 N10 123.5(6) . . ?
C114 C26 C24 120.5(6) . . ?
N10 C26 C24 115.9(7) . . ?
C19 Pt2 C10 91.5(2) . . ?
C19 Pt2 N2 172.0(2) . . ?
C10 Pt2 N2 96.5(2) . . ?
C19 Pt2 N1 93.5(2) . . ?
C10 Pt2 N1 174.5(2) . . ?
N2 Pt2 N1 78.55(18) . . ?
C121 Si2 C120 110.4(4) . . ?
C121 Si2 C35 107.7(4) . . ?
C120 Si2 C35 109.1(3) . . ?
C121 Si2 C151 110.8(5) . . ?
C120 Si2 C151 112.3(4) . . ?
C35 Si2 C151 106.3(3) . . ?
C102 Si1 C101 112.4(6) . . ?
C102 Si1 C9 106.5(4) . . ?
C101 Si1 C9 109.3(4) . . ?
C102 Si1 C100 110.8(7) . . ?
C101 Si1 C100 107.0(6) . . ?
C9 Si1 C100 110.8(4) . . ?
C33 N7 C29 117.7(5) . . ?
C33 N7 Pt1 126.9(4) . . ?
C29 N7 Pt1 115.3(3) . . ?
C20 C19 Pt2 170.1(6) . . ?
C28 N6 C27 119.3(5) . . ?
C28 N6 Pt1 115.7(3) . . ?
C27 N6 Pt1 124.7(4) . . ?
C1 N1 C2 120.7(5) . . ?
C1 N1 Pt2 124.5(4) . . ?
C2 N1 Pt2 114.8(4) . . ?
C3 N2 C7 120.3(5) . . ?
C3 N2 Pt2 114.2(4) . . ?
C7 N2 Pt2 125.5(4) . . ?
C37 C36 Pt1 168.0(6) . . ?
C10 C11 C12 173.6(7) . . ?
C11 C10 Pt2 175.4(6) . . ?
N7 C33 C32 124.0(6) . . ?
N7 C33 H33 118.0 . . ?
C32 C33 H33 118.0 . . ?
N6 C27 C117 122.1(6) . . ?
N6 C27 H27 119.0 . . ?
C117 C27 H27 119.0 . . ?
N2 C7 C6 120.4(6) . . ?
N2 C7 H7 119.8 . . ?
C6 C7 H7 119.8 . . ?
N4 C15 C14 122.2(5) . . ?
N4 C15 C17 116.4(6) . . ?
C14 C15 C17 121.4(6) . . ?
C16 C12 C13 116.0(6) . . ?
C16 C12 C11 121.8(6) . . ?
C13 C12 C11 122.2(6) . . ?
C25 C21 C22 116.1(6) . . ?
C25 C21 C20 121.6(6) . . ?
C22 C21 C20 122.3(6) . . ?
C19 C20 C21 176.1(7) . . ?
N1 C1 C105 122.4(6) . . ?
N1 C1 H1 118.8 . . ?
C105 C1 H1 118.8 . . ?
N3 C25 C21 122.5(6) . . ?
N3 C25 H25 118.8 . . ?
C21 C25 H25 118.8 . . ?
C35 C34 C32 176.7(7) . . ?
C15 N4 C16 117.9(6) . . ?
C36 C37 C38 173.4(7) . . ?
C23 C22 C21 121.3(7) . . ?
C23 C22 H22 119.4 . . ?
C21 C22 H22 119.4 . . ?
C39 C38 C40 115.9(6) . . ?
C39 C38 C37 121.9(6) . . ?
C40 C38 C37 122.1(6) . . ?
C15 C14 C13 118.6(6) . . ?
C15 C14 H14 120.7 . . ?
C13 C14 H14 120.7 . . ?
C44 C43 N9 122.3(6) . . ?
C44 C43 C42 120.2(6) . . ?
N9 C43 C42 117.4(6) . . ?
C42 N8 C39 118.3(6) . . ?
C34 C35 Si2 175.3(6) . . ?
N4 C16 C12 124.7(6) . . ?
N4 C16 H16 117.6 . . ?
C12 C16 H16 117.6 . . ?
C33 C32 C31 118.3(5) . . ?
C33 C32 C34 119.0(6) . . ?
C31 C32 C34 122.5(6) . . ?
N1 C2 C107 119.1(5) . . ?
N1 C2 C3 115.9(5) . . ?
C107 C2 C3 125.0(6) . . ?
N6 C28 C119 122.1(5) . . ?
N6 C28 C29 114.9(5) . . ?
C119 C28 C29 123.0(5) . . ?
C30 C29 N7 120.9(5) . . ?
C30 C29 C28 124.2(5) . . ?
N7 C29 C28 114.8(5) . . ?
N2 C3 C4 120.4(5) . . ?
N2 C3 C2 116.5(5) . . ?
C4 C3 C2 123.1(6) . . ?
N5 C17 C18 122.0(7) . . ?
N5 C17 C15 117.2(7) . . ?
C18 C17 C15 120.8(7) . . ?
C42 C41 C40 120.6(6) . . ?
C42 C41 H41 119.7 . . ?
C40 C41 H41 119.7 . . ?
C14 C13 C12 120.5(6) . . ?
C14 C13 H13 119.8 . . ?
C12 C13 H13 119.8 . . ?
C30 C31 C32 117.9(6) . . ?
C30 C31 H31 121.1 . . ?
C32 C31 H31 121.1 . . ?
C17 N5 C108 116.7(8) . . ?
C43 N9 C122 117.0(7) . . ?
C25 N3 C24 119.0(6) . . ?
C29 C30 C31 121.2(6) . . ?
C29 C30 H30 119.4 . . ?
C31 C30 H30 119.4 . . ?
C23 C24 N3 122.1(6) . . ?
C23 C24 C26 118.9(6) . . ?
N3 C24 C26 118.9(6) . . ?
C41 C42 N8 121.1(6) . . ?
C41 C42 C43 120.3(6) . . ?
N8 C42 C43 118.7(6) . . ?
C5 C6 C7 118.3(6) . . ?
C5 C6 C8 119.5(6) . . ?
C7 C6 C8 122.2(6) . . ?
C41 C40 C38 121.7(6) . . ?
C41 C40 H40 119.2 . . ?
C38 C40 H40 119.2 . . ?
C43 C44 C124 119.1(7) . . ?
C43 C44 H44 120.4 . . ?
C124 C44 H44 120.4 . . ?
C17 C18 C110 119.4(9) . . ?
C17 C18 H18 120.3 . . ?
C110 C18 H18 120.3 . . ?
C38 C39 N8 122.5(6) . . ?
C38 C39 H39 118.8 . . ?
N8 C39 H39 118.8 . . ?
C9 C8 C6 171.5(8) . . ?
C3 C4 C5 120.5(6) . . ?
C3 C4 H4 119.8 . . ?
C5 C4 H4 119.8 . . ?
C8 C9 Si1 170.2(7) . . ?
C4 C5 C6 120.1(6) . . ?
C4 C5 H5 120.0 . . ?
C6 C5 H5 120.0 . . ?
C129 Si5 C130 111.7(5) . . ?
C129 Si5 C150 108.6(4) . . ?
C130 Si5 C150 112.0(5) . . ?
C129 Si5 C115 108.4(3) . . ?
C130 Si5 C115 109.0(3) . . ?
C150 Si5 C115 107.0(4) . . ?
C27 C117 C118 118.0(5) . . ?
C27 C117 C116 119.6(6) . . ?
C118 C117 C116 122.4(5) . . ?
C119 C118 C117 119.9(5) . . ?
C119 C118 H118 120.0 . . ?
C117 C118 H118 120.0 . . ?
C28 C119 C118 118.6(5) . . ?
C28 C119 H119 120.7 . . ?
C118 C119 H119 120.7 . . ?
C107 C106 C105 119.1(6) . . ?
C107 C106 H106 120.4 . . ?
C105 C106 H106 120.4 . . ?
C1 C105 C106 117.8(6) . . ?
C1 C105 C103 120.2(6) . . ?
C106 C105 C103 122.0(6) . . ?
C115 C116 C117 177.7(7) . . ?
C26 N10 C111 114.7(7) . . ?
C113 C114 C26 118.7(7) . . ?
C113 C114 H114 120.7 . . ?
C26 C114 H114 120.7 . . ?
C106 C107 C2 120.8(6) . . ?
C106 C107 H107 119.6 . . ?
C2 C107 H107 119.6 . . ?
C116 C115 Si5 178.1(7) . . ?
C104 C103 C105 178.5(7) . . ?
Si2 C120 H12A 109.5 . . ?
Si2 C120 H12B 109.5 . . ?
H12A C120 H12B 109.5 . . ?
Si2 C120 H12C 109.5 . . ?
H12A C120 H12C 109.5 . . ?
H12B C120 H12C 109.5 . . ?
C103 C104 Si4 177.9(7) . . ?
C109 C108 N5 124.8(10) . . ?
C109 C108 H108 117.6 . . ?
N5 C108 H108 117.6 . . ?
Si4 C133 H13A 109.5 . . ?
Si4 C133 H13B 109.5 . . ?
H13A C133 H13B 109.5 . . ?
Si4 C133 H13C 109.5 . . ?
H13A C133 H13C 109.5 . . ?
H13B C133 H13C 109.5 . . ?
C111 C112 C113 118.7(8) . . ?
C111 C112 H112 120.6 . . ?
C113 C112 H112 120.6 . . ?
C123 C122 N9 121.5(8) . . ?
C123 C122 H122 119.2 . . ?
N9 C122 H122 119.2 . . ?
C114 C113 C112 121.5(9) . . ?
C114 C113 H113 119.2 . . ?
C112 C113 H113 119.2 . . ?
C112 C111 N10 122.8(8) . . ?
C112 C111 H111 118.6 . . ?
N10 C111 H111 118.6 . . ?
C109 C110 C18 119.8(10) . . ?
C109 C110 H110 120.1 . . ?
C18 C110 H110 120.1 . . ?
C108 C109 C110 117.2(9) . . ?
C108 C109 H109 121.4 . . ?
C110 C109 H109 121.4 . . ?
Si5 C130 H13D 109.5 . . ?
Si5 C130 H13E 109.5 . . ?
H13D C130 H13E 109.5 . . ?
Si5 C130 H13F 109.5 . . ?
H13D C130 H13F 109.5 . . ?
H13E C130 H13F 109.5 . . ?
C122 C123 C124 118.7(8) . . ?
C122 C123 H123 120.6 . . ?
C124 C123 H123 120.6 . . ?
Si4 C132 H13G 109.5 . . ?
Si4 C132 H13H 109.5 . . ?
H13G C132 H13H 109.5 . . ?
Si4 C132 H13I 109.5 . . ?
H13G C132 H13I 109.5 . . ?
H13H C132 H13I 109.5 . . ?
Si5 C129 H12D 109.5 . . ?
Si5 C129 H12E 109.5 . . ?
H12D C129 H12E 109.5 . . ?
Si5 C129 H12F 109.5 . . ?
H12D C129 H12F 109.5 . . ?
H12E C129 H12F 109.5 . . ?
Si2 C121 H12G 109.5 . . ?
Si2 C121 H12H 109.5 . . ?
H12G C121 H12H 109.5 . . ?
Si2 C121 H12I 109.5 . . ?
H12G C121 H12I 109.5 . . ?
H12H C121 H12I 109.5 . . ?
C123 C124 C44 121.2(9) . . ?
C123 C124 H124 119.4 . . ?
C44 C124 H124 119.4 . . ?
Si1 C101 H10A 109.5 . . ?
Si1 C101 H10B 109.5 . . ?
H10A C101 H10B 109.5 . . ?
Si1 C101 H10C 109.5 . . ?
H10A C101 H10C 109.5 . . ?
H10B C101 H10C 109.5 . . ?
Si1 C102 H10D 109.5 . . ?
Si1 C102 H10E 109.5 . . ?
H10D C102 H10E 109.5 . . ?
Si1 C102 H10F 109.5 . . ?
H10D C102 H10F 109.5 . . ?
H10E C102 H10F 109.5 . . ?
Si1 C100 H10G 109.5 . . ?
Si1 C100 H10H 109.5 . . ?
H10G C100 H10H 109.5 . . ?
Si1 C100 H10I 109.5 . . ?
H10G C100 H10I 109.5 . . ?
H10H C100 H10I 109.5 . . ?
Si2 C151 H15A 109.5 . . ?
Si2 C151 H15B 109.5 . . ?
H15A C151 H15B 109.5 . . ?
Si2 C151 H15C 109.5 . . ?
H15A C151 H15C 109.5 . . ?
H15B C151 H15C 109.5 . . ?
Si5 C150 H15D 109.5 . . ?
Si5 C150 H15E 109.5 . . ?
H15D C150 H15E 109.5 . . ?
Si5 C150 H15F 109.5 . . ?
H15D C150 H15F 109.5 . . ?
H15E C150 H15F 109.5 . . ?
C133 Si4 C104 107.9(3) . . ?
C133 Si4 C131 112.5(4) . . ?
C104 Si4 C131 106.5(4) . . ?
C133 Si4 C132 110.3(4) . . ?
C104 Si4 C132 108.2(3) . . ?
C131 Si4 C132 111.1(4) . . ?
Si4 C131 H13J 109.5 . . ?
Si4 C131 H13K 109.5 . . ?
H13J C131 H13K 109.5 . . ?
Si4 C131 H13L 109.5 . . ?
H13J C131 H13L 109.5 . . ?
H13K C131 H13L 109.5 . . ?
C300 C300 C301 108.4(18) 2_667 . ?
C300 C300 H30C 110.0 2_667 . ?
C301 C300 H30C 110.0 . . ?
C300 C300 H30D 110.0 2_667 . ?
C301 C300 H30D 110.0 . . ?
H30C C300 H30D 108.4 . . ?
C300 C301 C302 118.1(16) . . ?
C300 C301 H30A 107.8 . . ?
C302 C301 H30A 107.8 . . ?
C300 C301 H30B 107.8 . . ?
C302 C301 H30B 107.8 . . ?
H30A C301 H30B 107.1 . . ?
C301 C302 H30E 109.5 . . ?
C301 C302 H30F 109.5 . . ?
H30E C302 H30F 109.5 . . ?
C301 C302 H30G 109.5 . . ?
H30E C302 H30G 109.5 . . ?
H30F C302 H30G 109.5 . . ?
C304 C304 C305 111.2(10) 2_657 . ?
C304 C304 H30H 109.4 2_657 . ?
C305 C304 H30H 109.4 . . ?
C304 C304 H30I 109.4 2_657 . ?
C305 C304 H30I 109.4 . . ?
H30H C304 H30I 108.0 . . ?
C306 C305 C304 111.8(10) . . ?
C306 C305 H30J 109.3 . . ?
C304 C305 H30J 109.3 . . ?
C306 C305 H30K 109.3 . . ?
C304 C305 H30K 109.3 . . ?
H30J C305 H30K 107.9 . . ?
C305 C306 H30L 109.5 . . ?
C305 C306 H30M 109.5 . . ?
H30L C306 H30M 109.5 . . ?
C305 C306 H30N 109.5 . . ?
H30L C306 H30N 109.5 . . ?
H30M C306 H30N 109.5 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C201 C154 1.334(12) . ?
C201 C155 1.382(13) . ?
C201 H201 0.9300 . ?
C155 N16 1.401(11) . ?
C155 H155 0.9300 . ?
N16 C152 1.375(10) . ?
C154 C153 1.337(10) . ?
C154 H154 0.9300 . ?
C153 C152 1.327(10) . ?
C153 H153 0.9300 . ?
C152 C127 1.478(9) . ?
C127 C200 1.324(8) . ?
C127 N20 1.358(8) . ?
N20 C128 1.361(7) . ?
C200 C125 1.331(8) . ?
C200 H200 0.9300 . ?
C128 C47 1.382(8) . ?
C128 H128 0.9300 . ?
C125 C47 1.392(8) . ?
C125 H125 0.9300 . ?
C47 C46 1.421(8) . ?
C46 C45 1.203(8) . ?
C45 Pt1 1.956(7) . ?
Pt1 C36 1.971(5) . ?
Pt1 N7 2.063(5) . ?
Pt1 N6 2.079(4) . ?
C23 C24 1.327(8) . ?
C23 C22 1.385(9) . ?
C23 H23 0.9300 . ?
C26 C114 1.353(9) . ?
C26 N10 1.368(9) . ?
C26 C24 1.507(9) . ?
Pt2 C19 1.947(6) . ?
Pt2 C10 1.983(6) . ?
Pt2 N2 2.087(5) . ?
Pt2 N1 2.091(5) . ?
Si2 C121 1.829(8) . ?
Si2 C120 1.829(6) . ?
Si2 C35 1.843(6) . ?
Si2 C151 1.856(8) . ?
Si1 C102 1.792(9) . ?
Si1 C101 1.798(9) . ?
Si1 C9 1.847(7) . ?
Si1 C100 1.850(10) . ?
N7 C33 1.331(6) . ?
N7 C29 1.365(7) . ?
C19 C20 1.193(8) . ?
N6 C28 1.335(7) . ?
N6 C27 1.345(6) . ?
N1 C1 1.336(7) . ?
N1 C2 1.344(7) . ?
N2 C3 1.352(7) . ?
N2 C7 1.364(7) . ?
C36 C37 1.199(6) . ?
C11 C10 1.178(7) . ?
C11 C12 1.438(7) . ?
C33 C32 1.369(8) . ?
C33 H33 0.9300 . ?
C27 C117 1.384(8) . ?
C27 H27 0.9300 . ?
C7 C6 1.399(8) . ?
C7 H7 0.9300 . ?
C15 N4 1.337(8) . ?
C15 C14 1.380(8) . ?
C15 C17 1.478(8) . ?
C12 C16 1.369(8) . ?
C12 C13 1.399(8) . ?
C21 C25 1.381(8) . ?
C21 C22 1.389(9) . ?
C21 C20 1.447(8) . ?
C1 C105 1.382(8) . ?
C1 H1 0.9300 . ?
C25 N3 1.349(7) . ?
C25 H25 0.9300 . ?
C34 C35 1.190(7) . ?
C34 C32 1.452(7) . ?
N4 C16 1.352(8) . ?
C37 C38 1.435(7) . ?
C22 H22 0.9300 . ?
C38 C39 1.362(8) . ?
C38 C40 1.390(8) . ?
C14 C13 1.387(7) . ?
C14 H14 0.9300 . ?
C43 C44 1.305(8) . ?
C43 N9 1.374(8) . ?
C43 C42 1.479(7) . ?
N8 C42 1.348(8) . ?
N8 C39 1.374(8) . ?
C16 H16 0.9300 . ?
C32 C31 1.388(9) . ?
C2 C107 1.384(8) . ?
C2 C3 1.454(7) . ?
C28 C119 1.379(7) . ?
C28 C29 1.492(6) . ?
C29 C30 1.357(8) . ?
C3 C4 1.364(8) . ?
C17 N5 1.336(9) . ?
C17 C18 1.355(10) . ?
C41 C42 1.334(8) . ?
C41 C40 1.336(8) . ?
C41 H41 0.9300 . ?
C13 H13 0.9300 . ?
C31 C30 1.379(7) . ?
C31 H31 0.9300 . ?
N5 C108 1.370(9) . ?
N9 C122 1.378(8) . ?
N3 C24 1.356(8) . ?
C30 H30 0.9300 . ?
C6 C5 1.381(9) . ?
C6 C8 1.442(8) . ?
C40 H40 0.9300 . ?
C44 C124 1.373(10) . ?
C44 H44 0.9300 . ?
C18 C110 1.404(10) . ?
C18 H18 0.9300 . ?
C39 H39 0.9300 . ?
C8 C9 1.190(8) . ?
C4 C5 1.370(8) . ?
C4 H4 0.9300 . ?
C5 H5 0.9300 . ?
Si5 C129 1.817(8) . ?
Si5 C130 1.828(8) . ?
Si5 C150 1.829(8) . ?
Si5 C115 1.845(6) . ?
C117 C118 1.387(8) . ?
C117 C116 1.440(7) . ?
C118 C119 1.381(7) . ?
C118 H118 0.9300 . ?
C119 H119 0.9300 . ?
C106 C107 1.377(8) . ?
C106 C105 1.386(9) . ?
C106 H106 0.9300 . ?
C105 C103 1.445(8) . ?
C116 C115 1.177(7) . ?
N10 C111 1.405(10) . ?
C114 C113 1.340(9) . ?
C114 H114 0.9300 . ?
C107 H107 0.9300 . ?
C103 C104 1.170(8) . ?
C120 H12A 0.9600 . ?
C120 H12B 0.9600 . ?
C120 H12C 0.9600 . ?
C104 Si4 1.850(7) . ?
C108 C109 1.351(14) . ?
C108 H108 0.9300 . ?
C133 Si4 1.844(7) . ?
C133 H13A 0.9600 . ?
C133 H13B 0.9600 . ?
C133 H13C 0.9600 . ?
C112 C111 1.334(11) . ?
C112 C113 1.366(12) . ?
C112 H112 0.9300 . ?
C122 C123 1.339(11) . ?
C122 H122 0.9300 . ?
C113 H113 0.9300 . ?
C111 H111 0.9300 . ?
C110 C109 1.354(14) . ?
C110 H110 0.9300 . ?
C109 H109 0.9300 . ?
C130 H13D 0.9600 . ?
C130 H13E 0.9600 . ?
C130 H13F 0.9600 . ?
C123 C124 1.348(11) . ?
C123 H123 0.9300 . ?
C132 Si4 1.870(7) . ?
C132 H13G 0.9600 . ?
C132 H13H 0.9600 . ?
C132 H13I 0.9600 . ?
C129 H12D 0.9600 . ?
C129 H12E 0.9600 . ?
C129 H12F 0.9600 . ?
C121 H12G 0.9600 . ?
C121 H12H 0.9600 . ?
C121 H12I 0.9600 . ?
C124 H124 0.9300 . ?
C101 H10A 0.9600 . ?
C101 H10B 0.9600 . ?
C101 H10C 0.9600 . ?
C102 H10D 0.9600 . ?
C102 H10E 0.9600 . ?
C102 H10F 0.9600 . ?
C100 H10G 0.9600 . ?
C100 H10H 0.9600 . ?
C100 H10I 0.9600 . ?
C151 H15A 0.9600 . ?
C151 H15B 0.9600 . ?
C151 H15C 0.9600 . ?
C150 H15D 0.9600 . ?
C150 H15E 0.9600 . ?
C150 H15F 0.9600 . ?
Si4 C131 1.858(7) . ?
C131 H13J 0.9600 . ?
C131 H13K 0.9600 . ?
C131 H13L 0.9600 . ?
C300 C300 1.45(3) 2_667 ?
C300 C301 1.540(10) . ?
C300 H30C 0.9700 . ?
C300 H30D 0.9700 . ?
C301 C302 1.542(9) . ?
C301 H30A 0.9700 . ?
C301 H30B 0.9700 . ?
C302 H30E 0.9600 . ?
C302 H30F 0.9600 . ?
C302 H30G 0.9600 . ?
C304 C304 1.516(10) 2_657 ?
C304 C305 1.533(10) . ?
C304 H30H 0.9700 . ?
C304 H30I 0.9700 . ?
C305 C306 1.512(9) . ?
C305 H30J 0.9700 . ?
C305 H30K 0.9700 . ?
C306 H30L 0.9600 . ?
C306 H30M 0.9600 . ?
C306 H30N 0.9600 . ?
