#------------------------------------------------------------------------------
#$Date: 2016-03-26 02:49:11 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180156 $
#$URL: svn://www.crystallography.net/cod/cif/7/10/52/7105292.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7105292
loop_
_publ_author_name
'Guo, Jiayi'
'Lau, Kai-Chung'
'Xi, Hong-Wei'
'Lim, Kok Hwa'
'So, Cheuk-Wai'
_publ_section_title
;
 Synthesis and characterization of a tin(II)
 bis(phosphinoyl)methanediide complex: a stannavinylidene derivative.
;
_journal_issue                   11
_journal_name_full
'Chemical communications (Cambridge, England)'
_journal_page_first              1929
_journal_page_last               1931
_journal_paper_doi               10.1039/b922377k
_journal_volume                  46
_journal_year                    2010
_chemical_formula_moiety         'C56 H58 N2 P4 S2 Si2 Sn2, C5 H12'
_chemical_formula_sum            'C61 H70 N2 P4 S2 Si2 Sn2'
_chemical_formula_weight         1312.75
_chemical_name_systematic
;
?
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 108.8510(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   10.8134(3)
_cell_length_b                   21.6674(5)
_cell_length_c                   15.5769(4)
_cell_measurement_reflns_used    9736
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      30.49
_cell_measurement_theta_min      2.76
_cell_volume                     3453.88(15)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.972
_diffrn_measured_fraction_theta_max 0.972
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0570
_diffrn_reflns_av_sigmaI/netI    0.0473
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       23
_diffrn_reflns_limit_k_min       -31
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_number            44780
_diffrn_reflns_theta_full        30.74
_diffrn_reflns_theta_max         30.74
_diffrn_reflns_theta_min         2.20
_exptl_absorpt_coefficient_mu    0.946
_exptl_absorpt_correction_T_max  0.7646
_exptl_absorpt_correction_T_min  0.7518
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.262
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1340
_exptl_crystal_size_max          0.32
_exptl_crystal_size_mid          0.32
_exptl_crystal_size_min          0.30
_refine_diff_density_max         1.858
_refine_diff_density_min         -1.147
_refine_diff_density_rms         0.202
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.208
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     412
_refine_ls_number_reflns         10468
_refine_ls_number_restraints     401
_refine_ls_restrained_S_all      1.201
_refine_ls_R_factor_all          0.0710
_refine_ls_R_factor_gt           0.0578
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1132P)²+2.7364P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1867
_refine_ls_wR_factor_ref         0.2027
_reflns_number_gt                8676
_reflns_number_total             10468
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b922377k.txt
_cod_data_source_block           scw27
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_sg_symbol_H-M      P2(1)/c
_cod_database_code               7105292
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
C2 C 0.4009(9) 0.3027(3) 0.5193(7) 0.0279(19) Uani 0.649(16) 1 d PDU A 1
C3 C 0.5287(8) 0.2800(3) 0.5402(7) 0.042(2) Uani 0.649(16) 1 d PDU A 1
H3 H 0.5995 0.3078 0.5486 0.051 Uiso 0.649(16) 1 calc PR A 1
C4 C 0.5515(10) 0.2172(4) 0.5486(9) 0.060(3) Uani 0.649(16) 1 d PDU A 1
H4 H 0.6381 0.2020 0.5615 0.072 Uiso 0.649(16) 1 calc PR A 1
C5 C 0.4509(11) 0.1765(4) 0.5385(11) 0.054(3) Uani 0.649(16) 1 d PDU A 1
H5 H 0.4674 0.1334 0.5448 0.065 Uiso 0.649(16) 1 calc PR A 1
C6 C 0.3248(10) 0.1988(3) 0.5191(9) 0.068(3) Uani 0.649(16) 1 d PDU A 1
H6 H 0.2545 0.1709 0.5126 0.081 Uiso 0.649(16) 1 calc PR A 1
C7 C 0.3008(9) 0.2613(3) 0.5092(9) 0.053(2) Uani 0.649(16) 1 d PDU A 1
H7 H 0.2137 0.2760 0.4951 0.063 Uiso 0.649(16) 1 calc PR A 1
C2A C 0.4159(18) 0.3043(5) 0.5241(17) 0.041(4) Uani 0.351(16) 1 d PDU A 2
C3A C 0.5280(15) 0.2835(6) 0.5074(12) 0.046(4) Uani 0.351(16) 1 d PDU A 2
H3A H 0.5813 0.3117 0.4885 0.056 Uiso 0.351(16) 1 calc PR A 2
C4A C 0.5612(19) 0.2223(7) 0.5184(15) 0.063(4) Uani 0.351(16) 1 d PDU A 2
H4A H 0.6376 0.2083 0.5068 0.076 Uiso 0.351(16) 1 calc PR A 2
C5A C 0.485(2) 0.1808(7) 0.546(2) 0.065(5) Uani 0.351(16) 1 d PDU A 2
H5A H 0.5075 0.1382 0.5517 0.078 Uiso 0.351(16) 1 calc PR A 2
C6A C 0.376(2) 0.2018(6) 0.5653(16) 0.070(4) Uani 0.351(16) 1 d PDU A 2
H6A H 0.3263 0.1739 0.5881 0.084 Uiso 0.351(16) 1 calc PR A 2
C7A C 0.3393(19) 0.2629(5) 0.5517(14) 0.052(3) Uani 0.351(16) 1 d PDU A 2
H7A H 0.2613 0.2765 0.5614 0.062 Uiso 0.351(16) 1 calc PR A 2
Sn1 Sn 0.34112(2) 0.531271(10) 0.412568(15) 0.02322(10) Uani 1 1 d . . .
C1 C 0.4770(4) 0.42831(16) 0.5966(2) 0.0240(6) Uani 1 1 d . . .
C8 C 0.2038(4) 0.39467(17) 0.4970(3) 0.0295(7) Uani 1 1 d . A .
C9 C 0.1635(5) 0.4190(2) 0.5655(4) 0.0454(11) Uani 1 1 d . . .
H9 H 0.2260 0.4307 0.6215 0.055 Uiso 1 1 calc R . .
C10 C 0.0312(6) 0.4262(3) 0.5517(5) 0.0639(16) Uani 1 1 d . . .
H10 H 0.0035 0.4426 0.5991 0.077 Uiso 1 1 calc R . .
C11 C -0.0596(5) 0.4103(4) 0.4716(5) 0.0708(19) Uani 1 1 d . . .
H11 H -0.1500 0.4154 0.4633 0.085 Uiso 1 1 calc R . .
C12 C -0.0206(6) 0.3871(4) 0.4031(5) 0.075(2) Uani 1 1 d . . .
H12 H -0.0837 0.3766 0.3467 0.090 Uiso 1 1 calc R . .
C13 C 0.1115(5) 0.3789(3) 0.4159(4) 0.0568(15) Uani 1 1 d . . .
H13 H 0.1384 0.3623 0.3684 0.068 Uiso 1 1 calc R . .
C14 C 0.5573(4) 0.53689(19) 0.2285(3) 0.0304(8) Uani 1 1 d . . .
C15 C 0.5678(6) 0.5562(3) 0.1461(3) 0.0483(12) Uani 1 1 d . . .
H15 H 0.5307 0.5943 0.1202 0.058 Uiso 1 1 calc R . .
C16 C 0.6328(6) 0.5194(3) 0.1022(4) 0.0594(15) Uani 1 1 d . . .
H16 H 0.6409 0.5330 0.0463 0.071 Uiso 1 1 calc R . .
C17 C 0.6859(6) 0.4636(3) 0.1372(4) 0.0559(15) Uani 1 1 d . . .
H17 H 0.7312 0.4392 0.1064 0.067 Uiso 1 1 calc R . .
C18 C 0.6726(5) 0.4432(3) 0.2189(4) 0.0493(12) Uani 1 1 d . . .
H18 H 0.7061 0.4041 0.2431 0.059 Uiso 1 1 calc R . .
C19 C 0.6101(5) 0.4804(2) 0.2644(3) 0.0369(9) Uani 1 1 d . . .
H19 H 0.6034 0.4672 0.3208 0.044 Uiso 1 1 calc R . .
C20 C 0.4542(4) 0.65730(19) 0.2464(3) 0.0334(8) Uani 1 1 d . . .
C21 C 0.3354(6) 0.6882(2) 0.2233(4) 0.0549(14) Uani 1 1 d . . .
H21 H 0.2591 0.6668 0.2241 0.066 Uiso 1 1 calc R . .
C22 C 0.3274(7) 0.7504(2) 0.1990(5) 0.0680(18) Uani 1 1 d . . .
H22 H 0.2466 0.7716 0.1859 0.082 Uiso 1 1 calc R . .
C23 C 0.4357(8) 0.7807(3) 0.1941(5) 0.074(2) Uani 1 1 d . . .
H23 H 0.4295 0.8225 0.1744 0.089 Uiso 1 1 calc R . .
C24 C 0.5533(8) 0.7505(3) 0.2176(6) 0.079(2) Uani 1 1 d . . .
H24 H 0.6292 0.7720 0.2161 0.095 Uiso 1 1 calc R . .
C25 C 0.5627(6) 0.6899(3) 0.2434(4) 0.0567(14) Uani 1 1 d . . .
H25 H 0.6451 0.6698 0.2595 0.068 Uiso 1 1 calc R . .
C26 C 0.2708(6) 0.4431(3) 0.1359(4) 0.0548(14) Uani 1 1 d . . .
H26A H 0.3469 0.4523 0.1170 0.082 Uiso 1 1 calc R . .
H26B H 0.2018 0.4248 0.0849 0.082 Uiso 1 1 calc R . .
H26C H 0.2960 0.4139 0.1867 0.082 Uiso 1 1 calc R . .
C27 C 0.0625(5) 0.4961(4) 0.2034(4) 0.0644(17) Uani 1 1 d . . .
H27A H 0.0837 0.4992 0.2693 0.097 Uiso 1 1 calc R . .
H27B H 0.0340 0.4540 0.1838 0.097 Uiso 1 1 calc R . .
H27C H -0.0078 0.5252 0.1738 0.097 Uiso 1 1 calc R . .
C28 C 0.1659(7) 0.5689(3) 0.0724(4) 0.0690(19) Uani 1 1 d . . .
H28A H 0.1249 0.6061 0.0870 0.103 Uiso 1 1 calc R . .
H28B H 0.1046 0.5484 0.0196 0.103 Uiso 1 1 calc R . .
H28C H 0.2450 0.5805 0.0586 0.103 Uiso 1 1 calc R . .
C29 C 0.145(3) 0.3539(15) 0.850(2) 0.189(12) Uani 0.50 1 d PDU . .
H29A H 0.2056 0.3251 0.8917 0.284 Uiso 0.50 1 calc PR . .
H29B H 0.1092 0.3822 0.8852 0.284 Uiso 0.50 1 calc PRD . .
H29C H 0.1918 0.3775 0.8167 0.284 Uiso 0.50 1 calc PR . .
C30 C 0.036(2) 0.3185(14) 0.785(2) 0.157(9) Uani 0.50 1 d PDU . .
H30A H -0.0105 0.2980 0.8221 0.188 Uiso 0.50 1 calc PRD . .
H30B H -0.0245 0.3499 0.7481 0.188 Uiso 0.50 1 calc PRD . .
C31 C 0.0491(19) 0.2726(13) 0.7216(16) 0.156(8) Uani 0.50 1 d PDU . .
H31A H 0.0967 0.2373 0.7576 0.188 Uiso 0.50 1 calc PR . .
H31B H 0.1064 0.2903 0.6895 0.188 Uiso 0.50 1 calc PR . .
C32 C -0.072(2) 0.2463(15) 0.6488(19) 0.195(10) Uani 0.50 1 d PDU . .
H32A H -0.1200 0.2200 0.6794 0.234 Uiso 0.50 1 calc PRD . .
H32B H -0.1302 0.2812 0.6204 0.234 Uiso 0.50 1 calc PRD . .
C33 C -0.046(3) 0.2093(13) 0.5752(19) 0.180(11) Uani 0.50 1 d PDU . .
H33A H -0.1294 0.1944 0.5330 0.270 Uiso 0.50 1 calc PRD . .
H33B H 0.0093 0.1740 0.6020 0.270 Uiso 0.50 1 calc PR . .
H33C H -0.0023 0.2352 0.5425 0.270 Uiso 0.50 1 calc PR . .
N1 N 0.3203(3) 0.54815(14) 0.2664(2) 0.0252(6) Uani 1 1 d . . .
P1 P 0.37716(9) 0.38630(4) 0.51113(6) 0.02209(18) Uani 1 1 d D . .
P2 P 0.46316(10) 0.57885(4) 0.28789(6) 0.02432(19) Uani 1 1 d . . .
S1 S 0.40282(10) 0.41294(4) 0.39293(6) 0.0271(2) Uani 1 1 d . A .
Si1 Si 0.20976(12) 0.51514(6) 0.17167(8) 0.0339(2) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sn Sn -0.6537 1.4246 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C7 C2 C3 118.5(6) . . ?
C7 C2 P1 123.5(6) . . ?
C3 C2 P1 118.0(6) . . ?
C4 C3 C2 120.0(7) . . ?
C4 C3 H3 120.0 . . ?
C2 C3 H3 120.0 . . ?
C5 C4 C3 120.8(8) . . ?
C5 C4 H4 119.6 . . ?
C3 C4 H4 119.6 . . ?
C4 C5 C6 119.3(7) . . ?
C4 C5 H5 120.3 . . ?
C6 C5 H5 120.3 . . ?
C7 C6 C5 120.3(7) . . ?
C7 C6 H6 119.9 . . ?
C5 C6 H6 119.9 . . ?
C2 C7 C6 121.1(7) . . ?
C2 C7 H7 119.5 . . ?
C6 C7 H7 119.5 . . ?
C7A C2A C3A 119.6(10) . . ?
C7A C2A P1 121.9(9) . . ?
C3A C2A P1 118.5(9) . . ?
C4A C3A C2A 119.9(11) . . ?
C4A C3A H3A 120.1 . . ?
C2A C3A H3A 120.1 . . ?
C3A C4A C5A 120.8(11) . . ?
C3A C4A H4A 119.6 . . ?
C5A C4A H4A 119.6 . . ?
C4A C5A C6A 119.3(11) . . ?
C4A C5A H5A 120.3 . . ?
C6A C5A H5A 120.3 . . ?
C7A C6A C5A 120.3(11) . . ?
C7A C6A H6A 119.8 . . ?
C5A C6A H6A 119.8 . . ?
C6A C7A C2A 120.0(11) . . ?
C6A C7A H7A 120.0 . . ?
C2A C7A H7A 120.0 . . ?
C1 Sn1 N1 70.60(12) 3_666 . ?
C1 Sn1 S1 96.45(10) 3_666 . ?
N1 Sn1 S1 89.27(8) . . ?
P1 C1 P2 135.2(2) . 3_666 ?
P1 C1 Sn1 121.46(18) . 3_666 ?
P2 C1 Sn1 93.58(16) 3_666 3_666 ?
C13 C8 C9 119.2(4) . . ?
C13 C8 P1 119.9(4) . . ?
C9 C8 P1 120.9(3) . . ?
C8 C9 C10 119.5(5) . . ?
C8 C9 H9 120.3 . . ?
C10 C9 H9 120.3 . . ?
C11 C10 C9 121.1(6) . . ?
C11 C10 H10 119.4 . . ?
C9 C10 H10 119.4 . . ?
C10 C11 C12 119.8(5) . . ?
C10 C11 H11 120.1 . . ?
C12 C11 H11 120.1 . . ?
C11 C12 C13 119.9(6) . . ?
C11 C12 H12 120.0 . . ?
C13 C12 H12 120.0 . . ?
C8 C13 C12 120.5(5) . . ?
C8 C13 H13 119.8 . . ?
C12 C13 H13 119.8 . . ?
C19 C14 C15 119.4(4) . . ?
C19 C14 P2 117.4(3) . . ?
C15 C14 P2 123.0(4) . . ?
C16 C15 C14 119.4(5) . . ?
C16 C15 H15 120.3 . . ?
C14 C15 H15 120.3 . . ?
C17 C16 C15 121.7(5) . . ?
C17 C16 H16 119.1 . . ?
C15 C16 H16 119.1 . . ?
C16 C17 C18 119.1(5) . . ?
C16 C17 H17 120.4 . . ?
C18 C17 H17 120.4 . . ?
C19 C18 C17 119.5(5) . . ?
C19 C18 H18 120.2 . . ?
C17 C18 H18 120.2 . . ?
C18 C19 C14 120.8(4) . . ?
C18 C19 H19 119.6 . . ?
C14 C19 H19 119.6 . . ?
C25 C20 C21 118.0(4) . . ?
C25 C20 P2 122.9(4) . . ?
C21 C20 P2 118.9(3) . . ?
C20 C21 C22 120.5(6) . . ?
C20 C21 H21 119.8 . . ?
C22 C21 H21 119.8 . . ?
C23 C22 C21 120.1(6) . . ?
C23 C22 H22 120.0 . . ?
C21 C22 H22 120.0 . . ?
C22 C23 C24 119.5(5) . . ?
C22 C23 H23 120.2 . . ?
C24 C23 H23 120.2 . . ?
C25 C24 C23 120.8(6) . . ?
C25 C24 H24 119.6 . . ?
C23 C24 H24 119.6 . . ?
C24 C25 C20 121.1(6) . . ?
C24 C25 H25 119.4 . . ?
C20 C25 H25 119.4 . . ?
Si1 C26 H26A 109.5 . . ?
Si1 C26 H26B 109.5 . . ?
H26A C26 H26B 109.5 . . ?
Si1 C26 H26C 109.5 . . ?
H26A C26 H26C 109.5 . . ?
H26B C26 H26C 109.5 . . ?
Si1 C27 H27A 109.5 . . ?
Si1 C27 H27B 109.5 . . ?
H27A C27 H27B 109.5 . . ?
Si1 C27 H27C 109.5 . . ?
H27A C27 H27C 109.5 . . ?
H27B C27 H27C 109.5 . . ?
Si1 C28 H28A 109.5 . . ?
Si1 C28 H28B 109.5 . . ?
H28A C28 H28B 109.5 . . ?
Si1 C28 H28C 109.5 . . ?
H28A C28 H28C 109.5 . . ?
H28B C28 H28C 109.5 . . ?
C30 C29 H29A 109.5 . . ?
C30 C29 H29B 109.5 . . ?
H29A C29 H29B 109.5 . . ?
C30 C29 H29C 109.5 . . ?
H29A C29 H29C 109.5 . . ?
H29B C29 H29C 109.5 . . ?
C31 C30 C29 126.3(19) . . ?
C31 C30 H30A 105.7 . . ?
C29 C30 H30A 105.7 . . ?
C31 C30 H30B 105.7 . . ?
C29 C30 H30B 105.7 . . ?
H30A C30 H30B 106.2 . . ?
C30 C31 C32 120.9(19) . . ?
C30 C31 H31A 107.1 . . ?
C32 C31 H31A 107.1 . . ?
C30 C31 H31B 107.1 . . ?
C32 C31 H31B 107.1 . . ?
H31A C31 H31B 106.8 . . ?
C33 C32 C31 116.0(18) . . ?
C33 C32 H32A 108.3 . . ?
C31 C32 H32A 108.3 . . ?
C33 C32 H32B 108.3 . . ?
C31 C32 H32B 108.3 . . ?
H32A C32 H32B 107.4 . . ?
C32 C33 H33A 109.5 . . ?
C32 C33 H33B 109.5 . . ?
H33A C33 H33B 109.5 . . ?
C32 C33 H33C 109.5 . . ?
H33A C33 H33C 109.5 . . ?
H33B C33 H33C 109.5 . . ?
P2 N1 Si1 134.4(2) . . ?
P2 N1 Sn1 94.66(14) . . ?
Si1 N1 Sn1 127.93(17) . . ?
C1 P1 C2A 111.9(8) . . ?
C1 P1 C8 114.37(18) . . ?
C2A P1 C8 107.5(5) . . ?
C1 P1 C2 116.1(3) . . ?
C2A P1 C2 5.0(9) . . ?
C8 P1 C2 102.8(3) . . ?
C1 P1 S1 108.81(12) . . ?
C2A P1 S1 106.5(7) . . ?
C8 P1 S1 107.36(13) . . ?
C2 P1 S1 106.7(3) . . ?
N1 P2 C1 101.06(17) . 3_666 ?
N1 P2 C20 112.07(19) . . ?
C1 P2 C20 114.78(18) 3_666 . ?
N1 P2 C14 110.06(18) . . ?
C1 P2 C14 113.87(19) 3_666 . ?
C20 P2 C14 105.14(19) . . ?
P1 S1 Sn1 93.22(4) . . ?
N1 Si1 C26 113.1(2) . . ?
N1 Si1 C27 106.3(2) . . ?
C26 Si1 C27 108.2(3) . . ?
N1 Si1 C28 111.7(2) . . ?
C26 Si1 C28 107.3(3) . . ?
C27 Si1 C28 110.3(3) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
C2 C7 1.375(9) . ?
C2 C3 1.403(9) . ?
C2 P1 1.828(6) . ?
C3 C4 1.383(9) . ?
C3 H3 0.9500 . ?
C4 C5 1.370(10) . ?
C4 H4 0.9500 . ?
C5 C6 1.385(10) . ?
C5 H5 0.9500 . ?
C6 C7 1.377(9) . ?
C6 H6 0.9500 . ?
C7 H7 0.9500 . ?
C2A C7A 1.381(12) . ?
C2A C3A 1.394(12) . ?
C2A P1 1.822(11) . ?
C3A C4A 1.371(12) . ?
C3A H3A 0.9500 . ?
C4A C5A 1.377(13) . ?
C4A H4A 0.9500 . ?
C5A C6A 1.386(13) . ?
C5A H5A 0.9500 . ?
C6A C7A 1.380(12) . ?
C6A H6A 0.9500 . ?
C7A H7A 0.9500 . ?
Sn1 C1 2.199(4) 3_666 ?
Sn1 N1 2.244(3) . ?
Sn1 S1 2.6915(9) . ?
C1 P1 1.685(4) . ?
C1 P2 1.711(4) 3_666 ?
C1 Sn1 2.199(3) 3_666 ?
C8 C13 1.376(6) . ?
C8 C9 1.380(6) . ?
C8 P1 1.824(4) . ?
C9 C10 1.385(7) . ?
C9 H9 0.9500 . ?
C10 C11 1.360(9) . ?
C10 H10 0.9500 . ?
C11 C12 1.363(10) . ?
C11 H11 0.9500 . ?
C12 C13 1.389(8) . ?
C12 H12 0.9500 . ?
C13 H13 0.9500 . ?
C14 C19 1.389(6) . ?
C14 C15 1.389(6) . ?
C14 P2 1.824(4) . ?
C15 C16 1.381(8) . ?
C15 H15 0.9500 . ?
C16 C17 1.373(9) . ?
C16 H16 0.9500 . ?
C17 C18 1.398(8) . ?
C17 H17 0.9500 . ?
C18 C19 1.384(6) . ?
C18 H18 0.9500 . ?
C19 H19 0.9500 . ?
C20 C25 1.382(7) . ?
C20 C21 1.389(7) . ?
C20 P2 1.810(4) . ?
C21 C22 1.394(7) . ?
C21 H21 0.9500 . ?
C22 C23 1.368(10) . ?
C22 H22 0.9500 . ?
C23 C24 1.370(11) . ?
C23 H23 0.9500 . ?
C24 C25 1.369(8) . ?
C24 H24 0.9500 . ?
C25 H25 0.9500 . ?
C26 Si1 1.850(6) . ?
C26 H26A 0.9800 . ?
C26 H26B 0.9800 . ?
C26 H26C 0.9800 . ?
C27 Si1 1.859(6) . ?
C27 H27A 0.9800 . ?
C27 H27B 0.9800 . ?
C27 H27C 0.9800 . ?
C28 Si1 1.871(6) . ?
C28 H28A 0.9800 . ?
C28 H28B 0.9800 . ?
C28 H28C 0.9800 . ?
C29 C30 1.494(13) . ?
C29 H29A 0.9800 . ?
C29 H29B 0.9800 . ?
C29 H29C 0.9800 . ?
C30 C31 1.438(16) . ?
C30 H30A 0.9900 . ?
C30 H30B 0.9900 . ?
C31 C32 1.538(16) . ?
C31 H31A 0.9900 . ?
C31 H31B 0.9900 . ?
C32 C33 1.498(14) . ?
C32 H32A 0.9900 . ?
C32 H32B 0.9900 . ?
C33 H33A 0.9800 . ?
C33 H33B 0.9800 . ?
C33 H33C 0.9800 . ?
N1 P2 1.615(3) . ?
N1 Si1 1.726(3) . ?
P1 S1 2.0323(12) . ?
P2 C1 1.711(4) 3_666 ?
