#------------------------------------------------------------------------------
#$Date: 2018-09-12 14:49:22 +0300 (Wed, 12 Sep 2018) $
#$Revision: 210887 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/10/65/7106584.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7106584
loop_
_publ_author_name
'Lin, Mei-Jin'
'Jouaiti, Abdelaziz'
'Grosshans, Philippe'
'Kyritsakas, Nathalie'
'Hosseini, Mir Wais'
_publ_section_title
;
 Molecular tectonics: design of enantiomerically pure helical tubular
 crystals with controlled channel size and orientation
;
_journal_coden_ASTM              CHCOFS
_journal_issue                   27
_journal_name_full
;
 Chemical Communications (Cambridge, United Kingdom)
;
_journal_page_first              7635
_journal_page_last               7637
_journal_paper_doi               10.1039/c1cc12110c
_journal_volume                  47
_journal_year                    2011
_chemical_absolute_configuration rm
_chemical_formula_moiety
'C44 H30 F6 N6 O12 Si Zn, 2(C2 H6 O), 2(C H2 Cl)'
_chemical_formula_sum            'C50 H46 Cl2 F6 N6 O14 Si Zn'
_chemical_formula_weight         1233.29
_space_group_IT_number           5
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  'C 2y'
_symmetry_space_group_name_H-M   'C 1 2 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 100.139(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   23.2747(19)
_cell_length_b                   7.5775(5)
_cell_length_c                   16.5826(12)
_cell_measurement_reflns_used    1805
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      29.97
_cell_measurement_theta_min      2.83
_cell_volume                     2878.9(4)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.967
_diffrn_measured_fraction_theta_max 0.967
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0350
_diffrn_reflns_av_sigmaI/netI    0.0880
_diffrn_reflns_limit_h_max       32
_diffrn_reflns_limit_h_min       -32
_diffrn_reflns_limit_k_max       10
_diffrn_reflns_limit_k_min       -9
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            14482
_diffrn_reflns_theta_full        30.13
_diffrn_reflns_theta_max         30.13
_diffrn_reflns_theta_min         1.98
_exptl_absorpt_coefficient_mu    0.626
_exptl_absorpt_correction_T_max  0.9754
_exptl_absorpt_correction_T_min  0.9458
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.423
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             1264
_exptl_crystal_size_max          0.09
_exptl_crystal_size_mid          0.05
_exptl_crystal_size_min          0.04
_refine_diff_density_max         1.273
_refine_diff_density_min         -1.171
_refine_diff_density_rms         0.107
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   0.004(17)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.254
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     359
_refine_ls_number_reflns         7088
_refine_ls_number_restraints     3
_refine_ls_restrained_S_all      1.255
_refine_ls_R_factor_all          0.0917
_refine_ls_R_factor_gt           0.0771
_refine_ls_shift/su_max          0.031
_refine_ls_shift/su_mean         0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0295P)²+10.1221P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1466
_refine_ls_wR_factor_ref         0.1509
_reflns_number_gt                5951
_reflns_number_total             7088
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c1cc12110c.txt
_cod_data_source_block           e1900a
_cod_depositor_comments
;
The following automatic conversions were performed:

'_exptl_crystal_density_meas' value 'none' was changed to '?' - the
value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 3008 2015-01-20 13:52:24Z robertas 
;
_cod_original_sg_symbol_H-M      C2
_cod_database_code               7106584
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Zn1 Zn 1.0000 0.78252(8) 0.5000 0.01224(15) Uani 1 2 d S . 1
Si1 Si 1.0000 0.2880(3) 0.5000 0.0147(3) Uani 1 2 d S . 1
F1 F 1.0000 0.5122(5) 0.5000 0.0239(10) Uani 1 2 d S A 1
F2 F 0.98787(14) 0.2902(5) 0.39897(15) 0.0357(7) Uani 1 1 d . B 1
F3 F 0.92846(11) 0.2878(6) 0.5002(2) 0.0400(7) Uani 1 1 d . C 1
F4 F 1.0000 1.0605(6) 0.5000 0.0241(11) Uani 1 2 d S . 1
N1 N 0.91868(14) 0.7849(7) 0.41732(19) 0.0184(7) Uani 1 1 d . . 1
C1 C 0.8759(2) 0.8961(7) 0.4285(3) 0.0207(10) Uani 1 1 d . . 1
H1 H 0.8826 0.9736 0.4743 0.025 Uiso 1 1 calc R . 1
C2 C 0.8227(2) 0.9031(7) 0.3766(3) 0.0225(10) Uani 1 1 d . . 1
H2 H 0.7928 0.9806 0.3872 0.027 Uiso 1 1 calc R . 1
C3 C 0.81382(18) 0.7932(9) 0.3079(2) 0.0210(9) Uani 1 1 d . . 1
C4 C 0.8572(2) 0.6796(7) 0.2956(3) 0.0257(11) Uani 1 1 d . . 1
H4 H 0.8520 0.6039 0.2492 0.031 Uiso 1 1 calc R . 1
C5 C 0.9089(2) 0.6768(7) 0.3518(3) 0.0243(11) Uani 1 1 d . . 1
H5 H 0.9385 0.5957 0.3438 0.029 Uiso 1 1 calc R . 1
C6 C 0.7552(2) 0.8006(8) 0.2535(3) 0.0229(10) Uani 1 1 d . . 1
O1 O 0.71249(16) 0.8604(6) 0.2730(2) 0.0371(10) Uani 1 1 d . . 1
O2 O 0.75711(14) 0.7255(5) 0.17916(19) 0.0255(8) Uani 1 1 d . . 1
C7 C 0.7019(2) 0.7135(7) 0.1249(3) 0.0234(11) Uani 1 1 d . . 1
H7 H 0.6729 0.7927 0.1445 0.028 Uiso 1 1 calc R . 1
C8 C 0.6786(2) 0.5290(8) 0.1159(3) 0.0247(10) Uani 1 1 d . . 1
H8 H 0.7115 0.4424 0.1217 0.030 Uiso 1 1 calc R . 1
C9 C 0.6441(2) 0.5259(8) 0.0279(3) 0.0270(11) Uani 1 1 d . . 1
N2 N 0.66757(17) 0.6587(6) -0.0136(2) 0.0236(9) Uani 1 1 d . . 1
C10 C 0.70778(19) 0.7632(8) 0.0376(3) 0.0232(11) Uani 1 1 d . . 1
O3 O 0.64212(15) 0.4924(5) 0.1740(2) 0.0255(8) Uani 1 1 d . . 1
C11 C 0.6408(2) 0.3238(7) 0.2000(3) 0.0272(13) Uani 1 1 d . . 1
O4 O 0.6661(2) 0.2042(6) 0.1749(3) 0.0467(12) Uani 1 1 d . . 1
C12 C 1.1044(2) 0.8091(7) 0.2666(3) 0.0214(11) Uani 1 1 d . . 1
C13 C 1.0702(2) 0.9471(7) 0.2842(3) 0.0276(12) Uani 1 1 d . . 1
H13 H 1.0668 1.0515 0.2520 0.033 Uiso 1 1 calc R . 1
C14 C 1.0409(2) 0.9317(7) 0.3489(3) 0.0256(11) Uani 1 1 d . . 1
H14 H 1.0177 1.0276 0.3614 0.031 Uiso 1 1 calc R . 1
N3 N 1.04425(14) 0.7827(7) 0.39569(19) 0.0174(7) Uani 1 1 d . . 1
C15 C 1.0767(2) 0.6491(7) 0.3766(3) 0.0221(10) Uani 1 1 d . . 1
H15 H 1.0793 0.5446 0.4087 0.027 Uiso 1 1 calc R . 1
C16 C 1.1068(2) 0.6573(7) 0.3117(3) 0.0258(11) Uani 1 1 d . . 1
H16 H 1.1289 0.5590 0.2987 0.031 Uiso 1 1 calc R . 1
O5 O 0.60551(18) 0.4275(7) 0.0010(2) 0.0436(11) Uani 1 1 d . . 1
C17 C 0.6530(2) 0.6851(7) -0.1011(3) 0.0239(11) Uani 1 1 d . . 1
C18 C 0.5949(2) 0.7100(8) -0.1355(3) 0.0350(14) Uani 1 1 d . . 1
H18 H 0.5652 0.7097 -0.1028 0.042 Uiso 1 1 calc R . 1
C19 C 0.5815(2) 0.7358(8) -0.2203(3) 0.0386(16) Uani 1 1 d . . 1
H19 H 0.5421 0.7530 -0.2458 0.046 Uiso 1 1 calc R . 1
C20 C 0.6245(3) 0.7364(7) -0.2672(3) 0.0348(14) Uani 1 1 d . . 1
H20 H 0.6148 0.7531 -0.3247 0.042 Uiso 1 1 calc R . 1
C21 C 0.6816(3) 0.7130(7) -0.2309(3) 0.0303(12) Uani 1 1 d . . 1
H21 H 0.7112 0.7170 -0.2636 0.036 Uiso 1 1 calc R . 1
C22 C 0.6970(2) 0.6836(7) -0.1473(3) 0.0245(11) Uani 1 1 d . . 1
H22 H 0.7364 0.6631 -0.1226 0.029 Uiso 1 1 calc R . 1
O6 O 0.73816(17) 0.8754(6) 0.0165(2) 0.0358(10) Uani 1 1 d . . 1
C23 C 0.7284(3) 0.4655(11) 0.4169(5) 0.060(2) Uani 1 1 d . D 1
H23A H 0.7063 0.3575 0.4223 0.090 Uiso 1 1 calc R D 1
H23B H 0.7324 0.4817 0.3594 0.090 Uiso 1 1 calc R D 1
H23C H 0.7078 0.5669 0.4349 0.090 Uiso 1 1 calc R D 1
C24 C 0.7869(3) 0.4513(8) 0.4679(4) 0.0435(16) Uani 1 1 d . D 1
H24A H 0.8106 0.5567 0.4608 0.052 Uiso 1 1 calc R D 1
H24B H 0.7838 0.4408 0.5265 0.052 Uiso 1 1 calc R D 1
O7 O 0.8123(2) 0.2986(9) 0.4412(4) 0.0726(16) Uani 1 1 d . D 1
H7A H 0.8463 0.2866 0.4679 0.109 Uiso 1 1 calc R D 1
Cl1 Cl 0.54911(12) -0.1099(6) 0.0841(2) 0.1419(14) Uani 1 1 d D E 1
C25 C 0.5167(5) 0.0842(16) 0.0399(4) 0.1419(14) Uani 1 1 d D . 1
H25A H 0.4913 0.1299 0.0771 0.170 Uiso 1 1 calc R . 1
H25B H 0.5484 0.1715 0.0403 0.170 Uiso 1 1 calc R . 1
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Zn Zn 0.2839 1.4301 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
F1 Zn1 F4 180.000(2) . . ?
F1 Zn1 N1 90.49(15) . . ?
F4 Zn1 N1 89.51(15) . . ?
F1 Zn1 N1 90.49(15) . 2_756 ?
F4 Zn1 N1 89.51(15) . 2_756 ?
N1 Zn1 N1 179.0(3) . 2_756 ?
F1 Zn1 N3 90.04(15) . 2_756 ?
F4 Zn1 N3 89.96(15) . 2_756 ?
N1 Zn1 N3 91.17(12) . 2_756 ?
N1 Zn1 N3 88.83(12) 2_756 2_756 ?
F1 Zn1 N3 90.03(15) . . ?
F4 Zn1 N3 89.97(15) . . ?
N1 Zn1 N3 88.83(12) . . ?
N1 Zn1 N3 91.17(12) 2_756 . ?
N3 Zn1 N3 179.9(3) 2_756 . ?
F2 Si1 F2 178.8(3) 2_756 . ?
F2 Si1 F3 89.46(16) 2_756 . ?
F2 Si1 F3 90.55(16) . . ?
F2 Si1 F3 90.55(16) 2_756 2_756 ?
F2 Si1 F3 89.45(16) . 2_756 ?
F3 Si1 F3 179.9(3) . 2_756 ?
F2 Si1 F1 89.41(17) 2_756 . ?
F2 Si1 F1 89.41(17) . . ?
F3 Si1 F1 90.05(17) . . ?
F3 Si1 F1 90.05(17) 2_756 . ?
F2 Si1 F4 90.59(17) 2_756 1_545 ?
F2 Si1 F4 90.59(17) . 1_545 ?
F3 Si1 F4 89.96(17) . 1_545 ?
F3 Si1 F4 89.95(17) 2_756 1_545 ?
F1 Si1 F4 179.996(3) . 1_545 ?
Si1 F1 Zn1 180.000(1) . . ?
Si1 F4 Zn1 179.996(1) 1_565 . ?
C1 N1 C5 118.0(4) . . ?
C1 N1 Zn1 120.8(3) . . ?
C5 N1 Zn1 121.2(3) . . ?
N1 C1 C2 122.9(4) . . ?
N1 C1 H1 118.5 . . ?
C2 C1 H1 118.5 . . ?
C1 C2 C3 118.3(5) . . ?
C1 C2 H2 120.8 . . ?
C3 C2 H2 120.8 . . ?
C4 C3 C2 119.3(4) . . ?
C4 C3 C6 123.4(5) . . ?
C2 C3 C6 117.2(5) . . ?
C3 C4 C5 119.0(5) . . ?
C3 C4 H4 120.5 . . ?
C5 C4 H4 120.5 . . ?
N1 C5 C4 122.4(5) . . ?
N1 C5 H5 118.8 . . ?
C4 C5 H5 118.8 . . ?
O1 C6 O2 124.5(4) . . ?
O1 C6 C3 124.5(4) . . ?
O2 C6 C3 111.0(4) . . ?
C6 O2 C7 115.2(4) . . ?
O2 C7 C8 112.9(4) . . ?
O2 C7 C10 111.1(4) . . ?
C8 C7 C10 103.2(4) . . ?
O2 C7 H7 109.8 . . ?
C8 C7 H7 109.8 . . ?
C10 C7 H7 109.8 . . ?
O3 C8 C7 111.3(4) . . ?
O3 C8 C9 111.4(4) . . ?
C7 C8 C9 103.2(4) . . ?
O3 C8 H8 110.2 . . ?
C7 C8 H8 110.2 . . ?
C9 C8 H8 110.2 . . ?
O5 C9 N2 127.3(4) . . ?
O5 C9 C8 126.8(5) . . ?
N2 C9 C8 105.9(4) . . ?
C9 N2 C10 113.1(4) . . ?
C9 N2 C17 123.8(4) . . ?
C10 N2 C17 123.1(4) . . ?
O6 C10 N2 126.4(4) . . ?
O6 C10 C7 127.5(5) . . ?
N2 C10 C7 105.9(4) . . ?
C11 O3 C8 116.8(4) . . ?
O4 C11 O3 124.5(5) . . ?
O4 C11 C12 125.0(5) . 3_445 ?
O3 C11 C12 110.5(5) . 3_445 ?
C16 C12 C13 119.6(4) . . ?
C16 C12 C11 119.1(5) . 3 ?
C13 C12 C11 121.3(5) . 3 ?
C14 C13 C12 119.1(5) . . ?
C14 C13 H13 120.5 . . ?
C12 C13 H13 120.5 . . ?
N3 C14 C13 121.9(5) . . ?
N3 C14 H14 119.1 . . ?
C13 C14 H14 119.1 . . ?
C15 N3 C14 118.1(4) . . ?
C15 N3 Zn1 123.9(4) . . ?
C14 N3 Zn1 117.9(4) . . ?
N3 C15 C16 122.4(5) . . ?
N3 C15 H15 118.8 . . ?
C16 C15 H15 118.8 . . ?
C12 C16 C15 118.9(5) . . ?
C12 C16 H16 120.5 . . ?
C15 C16 H16 120.5 . . ?
C22 C17 C18 122.5(5) . . ?
C22 C17 N2 119.3(4) . . ?
C18 C17 N2 118.3(5) . . ?
C17 C18 C19 117.5(5) . . ?
C17 C18 H18 121.2 . . ?
C19 C18 H18 121.2 . . ?
C20 C19 C18 121.0(5) . . ?
C20 C19 H19 119.5 . . ?
C18 C19 H19 119.5 . . ?
C21 C20 C19 119.9(5) . . ?
C21 C20 H20 120.0 . . ?
C19 C20 H20 120.0 . . ?
C20 C21 C22 121.3(6) . . ?
C20 C21 H21 119.4 . . ?
C22 C21 H21 119.4 . . ?
C17 C22 C21 117.8(5) . . ?
C17 C22 H22 121.1 . . ?
C21 C22 H22 121.1 . . ?
O7 C24 C23 106.1(6) . . ?
O7 C24 H24A 110.5 . . ?
C23 C24 H24A 110.5 . . ?
O7 C24 H24B 110.5 . . ?
C23 C24 H24B 110.5 . . ?
H24A C24 H24B 108.7 . . ?
C25 C25 Cl1 121.1(4) 2_655 . ?
C25 C25 H25A 107.1 2_655 . ?
Cl1 C25 H25A 107.1 . . ?
C25 C25 H25B 107.0 2_655 . ?
Cl1 C25 H25B 107.0 . . ?
H25A C25 H25B 106.8 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Zn1 F1 2.048(4) . ?
Zn1 F4 2.106(4) . ?
Zn1 N1 2.133(3) . ?
Zn1 N1 2.133(3) 2_756 ?
Zn1 N3 2.163(3) 2_756 ?
Zn1 N3 2.163(3) . ?
Si1 F2 1.649(2) 2_756 ?
Si1 F2 1.649(2) . ?
Si1 F3 1.666(3) . ?
Si1 F3 1.666(3) 2_756 ?
Si1 F1 1.699(5) . ?
Si1 F4 1.724(5) 1_545 ?
F4 Si1 1.724(5) 1_565 ?
N1 C1 1.341(6) . ?
N1 C5 1.348(6) . ?
C1 C2 1.380(6) . ?
C1 H1 0.9500 . ?
C2 C3 1.396(7) . ?
C2 H2 0.9500 . ?
C3 C4 1.370(7) . ?
C3 C6 1.498(6) . ?
C4 C5 1.386(6) . ?
C4 H4 0.9500 . ?
C5 H5 0.9500 . ?
C6 O1 1.189(6) . ?
C6 O2 1.365(6) . ?
O2 C7 1.436(5) . ?
C7 C8 1.497(8) . ?
C7 C10 1.525(6) . ?
C7 H7 1.0000 . ?
C8 O3 1.420(6) . ?
C8 C9 1.537(6) . ?
C8 H8 1.0000 . ?
C9 O5 1.191(6) . ?
C9 N2 1.385(7) . ?
N2 C10 1.394(6) . ?
N2 C17 1.445(6) . ?
C10 O6 1.196(6) . ?
O3 C11 1.351(6) . ?
C11 O4 1.194(6) . ?
C11 C12 1.511(7) 3_445 ?
C12 C16 1.368(7) . ?
C12 C13 1.376(7) . ?
C12 C11 1.511(7) 3 ?
C13 C14 1.372(7) . ?
C13 H13 0.9500 . ?
C14 N3 1.365(7) . ?
C14 H14 0.9500 . ?
N3 C15 1.334(7) . ?
C15 C16 1.386(7) . ?
C15 H15 0.9500 . ?
C16 H16 0.9500 . ?
C17 C22 1.383(7) . ?
C17 C18 1.384(7) . ?
C18 C19 1.399(7) . ?
C18 H18 0.9500 . ?
C19 C20 1.371(8) . ?
C19 H19 0.9500 . ?
C20 C21 1.370(8) . ?
C20 H20 0.9500 . ?
C21 C22 1.388(7) . ?
C21 H21 0.9500 . ?
C22 H22 0.9500 . ?
C23 C24 1.474(9) . ?
C23 H23A 0.9800 . ?
C23 H23B 0.9800 . ?
C23 H23C 0.9800 . ?
C24 O7 1.407(8) . ?
C24 H24A 0.9900 . ?
C24 H24B 0.9900 . ?
O7 H7A 0.8400 . ?
Cl1 C25 1.753(11) . ?
C25 C25 1.413(9) 2_655 ?
C25 H25A 0.9900 . ?
C25 H25B 0.9900 . ?
