#------------------------------------------------------------------------------
#$Date: 2016-03-26 03:21:29 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180179 $
#$URL: svn://www.crystallography.net/cod/cif/7/10/75/7107528.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7107528
loop_
_publ_author_name
'Andrew Stephenson'
'Michael D. Ward'
_publ_section_title
;
 A triple helix of double helicates: three hierarchical levels of
 self-assembly in a single structure
;
_journal_name_full               Chem.Commun.
_journal_page_first              3605
_journal_paper_doi               10.1039/c2cc30197k
_journal_volume                  48
_journal_year                    2012
_chemical_formula_moiety
'3(C62 H48 Ag2 N12 O2),3(C H3 N O2),6(B F4),H2O'
_chemical_formula_sum            'C63 H51.667 Ag2 B2 F8 N13 O4.333'
_chemical_formula_weight         1449.53
_chemical_name_systematic
;
?
;
_space_group_IT_number           173
_symmetry_cell_setting           hexagonal
_symmetry_space_group_name_Hall  'P 6c'
_symmetry_space_group_name_H-M   'P 63'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                120.00
_cell_formula_units_Z            6
_cell_length_a                   21.2675(6)
_cell_length_b                   21.2675(6)
_cell_length_c                   25.9142(10)
_cell_measurement_reflns_used    9981
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      21.25
_cell_measurement_theta_min      2.35
_cell_volume                     10150.8(6)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0629
_diffrn_reflns_av_sigmaI/netI    0.0361
_diffrn_reflns_limit_h_max       27
_diffrn_reflns_limit_h_min       -27
_diffrn_reflns_limit_k_max       27
_diffrn_reflns_limit_k_min       -27
_diffrn_reflns_limit_l_max       33
_diffrn_reflns_limit_l_min       -32
_diffrn_reflns_number            154617
_diffrn_reflns_theta_full        27.64
_diffrn_reflns_theta_max         27.64
_diffrn_reflns_theta_min         1.36
_exptl_absorpt_coefficient_mu    0.656
_exptl_absorpt_correction_T_max  0.9433
_exptl_absorpt_correction_T_min  0.8800
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.423
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             4388
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.16
_exptl_crystal_size_min          0.09
_refine_diff_density_max         2.531
_refine_diff_density_min         -2.295
_refine_diff_density_rms         0.193
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   0.20(5)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.481
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     674
_refine_ls_number_reflns         15618
_refine_ls_number_restraints     815
_refine_ls_restrained_S_all      1.471
_refine_ls_R_factor_all          0.1342
_refine_ls_R_factor_gt           0.1200
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.2000P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.3588
_refine_ls_wR_factor_ref         0.3673
_reflns_number_gt                12188
_reflns_number_total             15618
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c2cc30197k.txt
_cod_data_source_block           imw1616p63
_cod_original_sg_symbol_H-M      'P6(3) '
_cod_database_code               7107528
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'x-y, x, z+1/2'
'-y, x-y, z'
'-x, -y, z+1/2'
'-x+y, -x, z'
'y, -x+y, z+1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ag1 Ag 1.30902(5) 1.03173(5) 0.20227(4) 0.0582(3) Uani 1 1 d .
Ag2 Ag 1.31889(5) 1.26397(4) -0.20031(4) 0.0576(3) Uani 1 1 d .
N111 N 1.3129(3) 0.9354(3) 0.1676(3) 0.053(2) Uani 1 1 d GU
C112 C 1.2741(4) 0.9063(4) 0.1222(3) 0.057(2) Uani 1 1 d GU
C113 C 1.2808(5) 0.8530(4) 0.0959(3) 0.071(3) Uani 1 1 d GU
H113 H 1.2549 0.8335 0.0655 0.085 Uiso 1 1 calc R
C114 C 1.3261(5) 0.8288(4) 0.1148(3) 0.076(3) Uani 1 1 d GU
H114 H 1.3305 0.7931 0.0972 0.091 Uiso 1 1 calc R
C115 C 1.3648(5) 0.8579(5) 0.1602(4) 0.069(3) Uani 1 1 d GU
H115 H 1.3952 0.8418 0.1729 0.083 Uiso 1 1 calc R
C116 C 1.3582(4) 0.9113(4) 0.1865(3) 0.060(3) Uani 1 1 d GU
H116 H 1.3841 0.9307 0.2169 0.072 Uiso 1 1 calc R
N121 N 1.1766(3) 1.0037(3) 0.1055(3) 0.0512(19) Uani 1 1 d GU
N122 N 1.2328(3) 0.9946(3) 0.1274(3) 0.054(2) Uani 1 1 d GU
C123 C 1.2299(3) 0.9327(4) 0.1043(4) 0.058(2) Uani 1 1 d GU
C124 C 1.1720(4) 0.9036(3) 0.0681(3) 0.060(3) Uani 1 1 d GU
H124 H 1.1581 0.8629 0.0475 0.072 Uiso 1 1 calc R
C125 C 1.1390(4) 0.9474(4) 0.0689(3) 0.059(3) Uani 1 1 d GU
H125 H 1.0997 0.9405 0.0489 0.071 Uiso 1 1 calc R
C126 C 1.1722(5) 1.0651(6) 0.1212(5) 0.055(2) Uani 1 1 d U
H12A H 1.1793 1.0714 0.1582 0.066 Uiso 1 1 calc R
H12B H 1.1242 1.0574 0.1134 0.066 Uiso 1 1 calc R
N131 N 1.2879(4) 1.1630(4) -0.2573(3) 0.058(2) Uani 1 1 d GU
C132 C 1.3472(3) 1.1556(5) -0.2704(4) 0.077(3) Uani 1 1 d GU
C133 C 1.3394(5) 1.1038(6) -0.3065(5) 0.098(4) Uani 1 1 d GU
H133 H 1.3791 1.0988 -0.3153 0.118 Uiso 1 1 calc R
C134 C 1.2723(6) 1.0594(6) -0.3294(5) 0.104(4) Uani 1 1 d GU
H134 H 1.2671 1.0247 -0.3535 0.125 Uiso 1 1 calc R
C135 C 1.2130(4) 1.0668(5) -0.3162(4) 0.093(4) Uani 1 1 d GU
H135 H 1.1681 1.0372 -0.3315 0.112 Uiso 1 1 calc R
C136 C 1.2208(3) 1.1186(4) -0.2802(4) 0.066(3) Uani 1 1 d GU
H136 H 1.1811 1.1236 -0.2713 0.080 Uiso 1 1 calc R
N141 N 1.4944(4) 1.2952(5) -0.2012(4) 0.083(3) Uani 1 1 d GU
N142 N 1.4211(3) 1.2589(5) -0.2182(4) 0.059(2) Uani 1 1 d GU
C143 C 1.4091(4) 1.1974(5) -0.2475(4) 0.076(3) Uani 1 1 d GU
C144 C 1.4750(5) 1.1957(5) -0.2486(5) 0.084(3) Uani 1 1 d GU
H144 H 1.4823 1.1611 -0.2652 0.101 Uiso 1 1 calc R
C145 C 1.5277(4) 1.2562(6) -0.2200(5) 0.089(4) Uani 1 1 d GU
H145 H 1.5757 1.2681 -0.2146 0.107 Uiso 1 1 calc R
C146 C 1.5147(8) 1.3626(10) -0.1729(7) 0.084(4) Uani 1 1 d U
H14A H 1.5668 1.3888 -0.1674 0.101 Uiso 1 1 calc R
H14B H 1.5025 1.3930 -0.1936 0.101 Uiso 1 1 calc R
C151 C 1.2286(3) 1.1327(3) 0.0943(2) 0.051(2) Uani 1 1 d GU
C152 C 1.2947(3) 1.1753(3) 0.11892(17) 0.058(2) Uani 1 1 d GU
H152 H 1.3038 1.1609 0.1506 0.070 Uiso 1 1 calc R
C153 C 1.3472(3) 1.2396(3) 0.09626(15) 0.059(2) Uani 1 1 d GU
H153 H 1.3914 1.2681 0.1128 0.071 Uiso 1 1 calc R
C154 C 1.3335(2) 1.2612(2) 0.04894(16) 0.058(2) Uani 1 1 d GU
C155 C 1.26742(19) 1.2186(2) 0.02429(18) 0.060(3) Uani 1 1 d GU
H155 H 1.2583 1.2330 -0.0074 0.072 Uiso 1 1 calc R
C156 C 1.2149(2) 1.1543(3) 0.0469(2) 0.052(2) Uani 1 1 d GU
H156 H 1.1707 1.1258 0.0304 0.063 Uiso 1 1 calc R
C161 C 1.4789(3) 1.3492(3) -0.12419(19) 0.057(2) Uani 1 1 d GU
C162 C 1.4832(3) 1.4095(3) -0.0998(2) 0.066(3) Uani 1 1 d GU
H162 H 1.5080 1.4549 -0.1154 0.079 Uiso 1 1 calc R
C163 C 1.4506(3) 1.4019(2) -0.0520(2) 0.068(3) Uani 1 1 d GU
H163 H 1.4535 1.4422 -0.0356 0.081 Uiso 1 1 calc R
C164 C 1.4135(2) 1.33412(19) -0.02858(17) 0.058(2) Uani 1 1 d GU
C165 C 1.4092(2) 1.2739(2) -0.05300(16) 0.058(2) Uani 1 1 d GU
H165 H 1.3844 1.2285 -0.0374 0.069 Uiso 1 1 calc R
C166 C 1.4418(3) 1.2814(3) -0.10080(18) 0.054(2) Uani 1 1 d GU
H166 H 1.4389 1.2411 -0.1171 0.064 Uiso 1 1 calc R
C171 C 1.3905(6) 1.3302(6) 0.0290(5) 0.053(2) Uani 1 1 d U
O172 O 1.4220(5) 1.3875(5) 0.0537(5) 0.078(3) Uani 1 1 d .
N211 N 1.2942(4) 1.1109(3) 0.2523(3) 0.058(2) Uani 1 1 d GU
C212 C 1.3524(3) 1.1816(4) 0.2534(4) 0.067(3) Uani 1 1 d GU
C213 C 1.3426(5) 1.2377(3) 0.2714(5) 0.084(4) Uani 1 1 d GU
H213 H 1.3815 1.2850 0.2721 0.101 Uiso 1 1 calc R
C214 C 1.2746(6) 1.2230(4) 0.2884(5) 0.103(4) Uani 1 1 d GU
H214 H 1.2680 1.2605 0.3004 0.124 Uiso 1 1 calc R
C215 C 1.2164(4) 1.1523(5) 0.2873(5) 0.085(4) Uani 1 1 d GU
H215 H 1.1709 1.1425 0.2987 0.102 Uiso 1 1 calc R
C216 C 1.2262(3) 1.0963(3) 0.2693(4) 0.059(3) Uani 1 1 d GU
H216 H 1.1873 1.0490 0.2686 0.070 Uiso 1 1 calc R
N221 N 1.4939(4) 1.1645(5) 0.1972(4) 0.070(2) Uani 1 1 d GU
N222 N 1.4213(3) 1.1368(4) 0.2143(4) 0.069(3) Uani 1 1 d GU
C223 C 1.4166(4) 1.1945(5) 0.2380(4) 0.071(3) Uani 1 1 d GU
C224 C 1.4862(5) 1.2578(4) 0.2355(5) 0.087(4) Uani 1 1 d GU
H224 H 1.4983 1.3034 0.2482 0.104 Uiso 1 1 calc R
C225 C 1.5340(3) 1.2393(4) 0.2103(5) 0.087(4) Uani 1 1 d GU
H225 H 1.5829 1.2707 0.2035 0.104 Uiso 1 1 calc R
C226 C 1.5129(6) 1.1187(8) 0.1732(6) 0.066(3) Uani 1 1 d U
H22A H 1.4959 1.0748 0.1935 0.079 Uiso 1 1 calc R
H22B H 1.5653 1.1421 0.1705 0.079 Uiso 1 1 calc R
N231 N 1.3179(4) 1.3616(3) -0.1671(3) 0.053(2) Uani 1 1 d GU
C232 C 1.2726(4) 1.3496(3) -0.1251(3) 0.057(2) Uani 1 1 d GU
C233 C 1.2778(6) 1.4082(5) -0.0976(3) 0.085(4) Uani 1 1 d GU
H233 H 1.2475 1.4002 -0.0695 0.101 Uiso 1 1 calc R
C234 C 1.3282(7) 1.4787(4) -0.1121(4) 0.092(4) Uani 1 1 d GU
H234 H 1.3317 1.5178 -0.0937 0.110 Uiso 1 1 calc R
C235 C 1.3735(6) 1.4906(3) -0.1542(4) 0.079(4) Uani 1 1 d GU
H235 H 1.4072 1.5378 -0.1639 0.095 Uiso 1 1 calc R
C236 C 1.3683(4) 1.4321(3) -0.1816(3) 0.061(3) Uani 1 1 d GU
H236 H 1.3986 1.4401 -0.2098 0.073 Uiso 1 1 calc R
N241 N 1.1791(3) 1.1562(3) -0.1134(3) 0.055(2) Uani 1 1 d GDU
N242 N 1.2362(3) 1.2240(3) -0.1312(3) 0.0481(18) Uani 1 1 d GU
C243 C 1.2254(4) 1.2797(3) -0.1105(3) 0.057(2) Uani 1 1 d GU
C244 C 1.1615(4) 1.2463(4) -0.0798(3) 0.059(3) Uani 1 1 d GU
H244 H 1.1419 1.2702 -0.0617 0.071 Uiso 1 1 calc R
C245 C 1.1329(3) 1.1700(4) -0.0816(3) 0.061(3) Uani 1 1 d GU
H245 H 1.0912 1.1352 -0.0649 0.073 Uiso 1 1 calc R
C246 C 1.1729(7) 1.0910(6) -0.1256(6) 0.062(3) Uani 1 1 d DU
H24A H 1.1745 1.0870 -0.1628 0.074 Uiso 1 1 calc R
H24B H 1.1263 1.0522 -0.1137 0.074 Uiso 1 1 calc R
C251 C 1.4771(3) 1.0983(4) 0.1162(2) 0.064(2) Uani 1 1 d GU
C252 C 1.4789(3) 1.0419(4) 0.0903(2) 0.067(3) Uani 1 1 d GU
H252 H 1.4998 1.0174 0.1060 0.081 Uiso 1 1 calc R
C253 C 1.4495(3) 1.0222(4) 0.0411(2) 0.069(3) Uani 1 1 d GU
H253 H 1.4507 0.9845 0.0238 0.083 Uiso 1 1 calc R
C254 C 1.4184(2) 1.0589(3) 0.01772(18) 0.065(2) Uani 1 1 d GU
C255 C 1.4166(2) 1.1153(3) 0.04358(18) 0.071(3) Uani 1 1 d GU
H255 H 1.3957 1.1398 0.0279 0.086 Uiso 1 1 calc R
C256 C 1.4460(3) 1.1349(4) 0.0928(2) 0.071(3) Uani 1 1 d GU
H256 H 1.4448 1.1726 0.1101 0.085 Uiso 1 1 calc R
C261 C 1.2336(3) 1.0819(3) -0.1012(2) 0.064(3) Uani 1 1 d GU
C262 C 1.2957(3) 1.0980(4) -0.12920(19) 0.061(3) Uani 1 1 d GU
H262 H 1.3013 1.1158 -0.1627 0.073 Uiso 1 1 calc R
C263 C 1.3493(3) 1.0875(4) -0.10713(16) 0.061(3) Uani 1 1 d GU
H263 H 1.3908 1.0983 -0.1258 0.074 Uiso 1 1 calc R
C264 C 1.3409(2) 1.0609(3) -0.05709(16) 0.060(2) Uani 1 1 d GU
C265 C 1.27879(19) 1.0448(3) -0.02913(18) 0.063(3) Uani 1 1 d GU
H265 H 1.2731 1.0270 0.0043 0.075 Uiso 1 1 calc R
C266 C 1.2252(2) 1.0553(4) -0.0512(2) 0.054(2) Uani 1 1 d GU
H266 H 1.1836 1.0445 -0.0325 0.064 Uiso 1 1 calc R
C271 C 1.4004(7) 1.0472(9) -0.0376(6) 0.072(3) Uani 1 1 d U
O272 O 1.4308(5) 1.0233(8) -0.0626(4) 0.084(3) Uani 1 1 d .
B11 B 0.6667 0.3333 0.6638(5) 0.046(4) Uani 1 3 d SDU
F12 F 0.6667 0.3333 0.7168(5) 0.112(6) Uani 1 3 d SDU
F13 F 0.6062(5) 0.2708(4) 0.6464(4) 0.076(2) Uani 1 1 d DU
B21 B 1.0000 1.0000 0.5057(6) 0.048(4) Uani 1 3 d SDU
F22 F 1.0562(3) 1.0636(3) 0.4862(3) 0.0669(19) Uani 1 1 d DU
F23 F 1.0000 1.0000 0.5599(5) 0.069(3) Uani 1 3 d SDU
B31 B 0.4392(7) 0.4357(6) 0.2520(5) 0.065(3) Uani 1 1 d DU
F32 F 0.4727(6) 0.5078(4) 0.2611(5) 0.119(4) Uani 1 1 d DU
F33 F 0.3795(6) 0.4002(5) 0.2840(4) 0.104(4) Uani 1 1 d DU
F34 F 0.4880(5) 0.4124(5) 0.2637(4) 0.094(3) Uani 1 1 d DU
F35 F 0.4184(7) 0.4185(8) 0.2032(4) 0.133(5) Uani 1 1 d DU
C11S C 0.341(2) 0.4632(17) 0.1026(12) 0.163(5) Uani 1 1 d DU
H11A H 0.3704 0.5134 0.1118 0.245 Uiso 1 1 calc R
H11B H 0.3706 0.4406 0.1027 0.245 Uiso 1 1 calc R
H11C H 0.3024 0.4392 0.1270 0.245 Uiso 1 1 calc R
N12S N 0.3101(12) 0.4573(11) 0.0499(10) 0.166(5) Uani 1 1 d DU
O13S O 0.3099(14) 0.5058(10) 0.0230(11) 0.168(5) Uani 1 1 d DU
O14S O 0.2731(13) 0.3934(9) 0.0381(10) 0.164(5) Uani 1 1 d DU
O1S O 0.6667 0.3333 0.8777(12) 0.116(8) Uani 1 3 d S
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
B B 0.0013 0.0007 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N211 Ag1 N111 167.1(3) . .
N211 Ag1 N222 70.7(3) . .
N111 Ag1 N222 115.7(3) . .
N211 Ag1 N122 112.7(3) . .
N111 Ag1 N122 72.9(2) . .
N222 Ag1 N122 128.5(3) . .
N211 Ag1 Ag2 81.6(2) . 6_565
N111 Ag1 Ag2 85.6(2) . 6_565
N222 Ag1 Ag2 109.7(2) . 6_565
N122 Ag1 Ag2 121.74(17) . 6_565
N231 Ag2 N142 124.7(3) . .
N231 Ag2 N242 72.1(2) . .
N142 Ag2 N242 134.2(3) . .
N231 Ag2 N131 158.2(3) . .
N142 Ag2 N131 71.0(3) . .
N242 Ag2 N131 108.8(3) . .
N231 Ag2 Ag1 83.49(19) . 2_654
N142 Ag2 Ag1 106.6(2) . 2_654
N242 Ag2 Ag1 118.15(17) . 2_654
N131 Ag2 Ag1 77.02(19) . 2_654
C112 N111 C116 120.0 . .
C112 N111 Ag1 117.1(3) . .
C116 N111 Ag1 122.5(3) . .
C113 C112 N111 120.0 . .
C113 C112 C123 121.9(6) . .
N111 C112 C123 118.1(6) . .
C114 C113 C112 120.0 . .
C114 C113 H113 120.0 . .
C112 C113 H113 120.0 . .
C113 C114 C115 120.0 . .
C113 C114 H114 120.0 . .
C115 C114 H114 120.0 . .
C116 C115 C114 120.0 . .
C116 C115 H115 120.0 . .
C114 C115 H115 120.0 . .
C115 C116 N111 120.0 . .
C115 C116 H116 120.0 . .
N111 C116 H116 120.0 . .
C126 N121 N122 117.3(6) . .
C126 N121 C125 134.5(6) . .
N122 N121 C125 108.0 . .
N121 N122 C123 108.0 . .
N121 N122 Ag1 139.1(4) . .
C123 N122 Ag1 110.8(4) . .
C112 C123 C124 131.0(6) . .
C112 C123 N122 120.5(6) . .
C124 C123 N122 108.0 . .
C125 C124 C123 108.0 . .
C125 C124 H124 126.0 . .
C123 C124 H124 126.0 . .
C124 C125 N121 108.0 . .
C124 C125 H125 126.0 . .
N121 C125 H125 126.0 . .
N121 C126 C151 111.0(9) . .
N121 C126 H12A 109.4 . .
C151 C126 H12A 109.4 . .
N121 C126 H12B 109.4 . .
C151 C126 H12B 109.4 . .
H12A C126 H12B 108.0 . .
C132 N131 C136 120.0 . .
C132 N131 Ag2 113.1(4) . .
C136 N131 Ag2 126.6(4) . .
C143 C132 C133 121.8(7) . .
C143 C132 N131 118.2(7) . .
C133 C132 N131 120.0 . .
C132 C133 C134 120.0 . .
C132 C133 H133 120.0 . .
C134 C133 H133 120.0 . .
C133 C134 C135 120.0 . .
C133 C134 H134 120.0 . .
C135 C134 H134 120.0 . .
C136 C135 C134 120.0 . .
C136 C135 H135 120.0 . .
C134 C135 H135 120.0 . .
C135 C136 N131 120.0 . .
C135 C136 H136 120.0 . .
N131 C136 H136 120.0 . .
C145 N141 N142 108.0 . .
C145 N141 C146 138.8(9) . .
N142 N141 C146 113.1(9) . .
C143 N142 N141 108.0 . .
C143 N142 Ag2 114.6(5) . .
N141 N142 Ag2 136.5(5) . .
C132 C143 C144 130.1(8) . .
C132 C143 N142 121.8(7) . .
C144 C143 N142 108.0 . .
C143 C144 C145 108.0 . .
C143 C144 H144 126.0 . .
C145 C144 H144 126.0 . .
C144 C145 N141 108.0 . .
C144 C145 H145 126.0 . .
N141 C145 H145 126.0 . .
C161 C146 N141 112.4(11) . .
C161 C146 H14A 109.1 . .
N141 C146 H14A 109.1 . .
C161 C146 H14B 109.1 . .
N141 C146 H14B 109.1 . .
H14A C146 H14B 107.9 . .
C152 C151 C156 120.0 . .
C152 C151 C126 118.2(5) . .
C156 C151 C126 121.8(5) . .
C153 C152 C151 120.0 . .
C153 C152 H152 120.0 . .
C151 C152 H152 120.0 . .
C152 C153 C154 120.0 . .
C152 C153 H153 120.0 . .
C154 C153 H153 120.0 . .
C155 C154 C153 120.0 . .
C155 C154 C171 123.8(5) . .
C153 C154 C171 116.2(5) . .
C156 C155 C154 120.0 . .
C156 C155 H155 120.0 . .
C154 C155 H155 120.0 . .
C155 C156 C151 120.0 . .
C155 C156 H156 120.0 . .
C151 C156 H156 120.0 . .
C162 C161 C166 120.0 . .
C162 C161 C146 115.9(8) . .
C166 C161 C146 124.1(8) . .
C161 C162 C163 120.0 . .
C161 C162 H162 120.0 . .
C163 C162 H162 120.0 . .
C164 C163 C162 120.0 . .
C164 C163 H163 120.0 . .
C162 C163 H163 120.0 . .
C163 C164 C165 120.0 . .
C163 C164 C171 118.2(4) . .
C165 C164 C171 120.8(4) . .
C166 C165 C164 120.0 . .
C166 C165 H165 120.0 . .
C164 C165 H165 120.0 . .
C165 C166 C161 120.0 . .
C165 C166 H166 120.0 . .
C161 C166 H166 120.0 . .
O172 C171 C154 125.4(12) . .
O172 C171 C164 116.2(10) . .
C154 C171 C164 118.4(8) . .
C212 N211 C216 120.0 . .
C212 N211 Ag1 115.8(4) . .
C216 N211 Ag1 122.0(4) . .
C223 C212 C213 120.7(6) . .
C223 C212 N211 119.3(6) . .
C213 C212 N211 120.0 . .
C212 C213 C214 120.0 . .
C212 C213 H213 120.0 . .
C214 C213 H213 120.0 . .
C215 C214 C213 120.0 . .
C215 C214 H214 120.0 . .
C213 C214 H214 120.0 . .
C216 C215 C214 120.0 . .
C216 C215 H215 120.0 . .
C214 C215 H215 120.0 . .
C215 C216 N211 120.0 . .
C215 C216 H216 120.0 . .
N211 C216 H216 120.0 . .
C226 N221 N222 119.3(8) . .
C226 N221 C225 132.7(8) . .
N222 N221 C225 108.0 . .
C223 N222 N221 108.0 . .
C223 N222 Ag1 113.8(4) . .
N221 N222 Ag1 137.3(4) . .
C212 C223 C224 133.9(7) . .
C212 C223 N222 117.9(7) . .
C224 C223 N222 108.0 . .
C223 C224 C225 108.0 . .
C223 C224 H224 126.0 . .
C225 C224 H224 126.0 . .
C224 C225 N221 108.0 . .
C224 C225 H225 126.0 . .
N221 C225 H225 126.0 . .
N221 C226 C251 109.8(9) . .
N221 C226 H22A 109.7 . .
C251 C226 H22A 109.7 . .
N221 C226 H22B 109.7 . .
C251 C226 H22B 109.7 . .
H22A C226 H22B 108.2 . .
C232 N231 C236 120.0 . .
C232 N231 Ag2 117.0(3) . .
C236 N231 Ag2 122.1(3) . .
C243 C232 N231 118.7(6) . .
C243 C232 C233 121.3(6) . .
N231 C232 C233 120.0 . .
C234 C233 C232 120.0 . .
C234 C233 H233 120.0 . .
C232 C233 H233 120.0 . .
C233 C234 C235 120.0 . .
C233 C234 H234 120.0 . .
C235 C234 H234 120.0 . .
C236 C235 C234 120.0 . .
C236 C235 H235 120.0 . .
C234 C235 H235 120.0 . .
C235 C236 N231 120.0 . .
C235 C236 H236 120.0 . .
N231 C236 H236 120.0 . .
C246 N241 N242 123.7(7) . .
C246 N241 C245 128.3(7) . .
N242 N241 C245 108.0 . .
C243 N242 N241 108.0 . .
C243 N242 Ag2 113.0(4) . .
N241 N242 Ag2 136.2(4) . .
C232 C243 N242 117.7(6) . .
C232 C243 C244 134.2(6) . .
N242 C243 C244 108.0 . .
C245 C244 C243 108.0 . .
C245 C244 H244 126.0 . .
C243 C244 H244 126.0 . .
N241 C245 C244 108.0 . .
N241 C245 H245 126.0 . .
C244 C245 H245 126.0 . .
N241 C246 C261 112.0(9) . .
N241 C246 H24A 109.2 . .
C261 C246 H24A 109.2 . .
N241 C246 H24B 109.2 . .
C261 C246 H24B 109.2 . .
H24A C246 H24B 107.9 . .
C252 C251 C256 120.0 . .
C252 C251 C226 117.4(6) . .
C256 C251 C226 122.6(6) . .
C253 C252 C251 120.0 . .
C253 C252 H252 120.0 . .
C251 C252 H252 120.0 . .
C252 C253 C254 120.0 . .
C252 C253 H253 120.0 . .
C254 C253 H253 120.0 . .
C255 C254 C253 120.0 . .
C255 C254 C271 119.9(5) . .
C253 C254 C271 119.0(5) . .
C254 C255 C256 120.0 . .
C254 C255 H255 120.0 . .
C256 C255 H255 120.0 . .
C255 C256 C251 120.0 . .
C255 C256 H256 120.0 . .
C251 C256 H256 120.0 . .
C266 C261 C262 120.0 . .
C266 C261 C246 119.3(6) . .
C262 C261 C246 120.7(6) . .
C263 C262 C261 120.0 . .
C263 C262 H262 120.0 . .
C261 C262 H262 120.0 . .
C262 C263 C264 120.0 . .
C262 C263 H263 120.0 . .
C264 C263 H263 120.0 . .
C263 C264 C265 120.0 . .
C263 C264 C271 115.9(6) . .
C265 C264 C271 124.0(6) . .
C266 C265 C264 120.0 . .
C266 C265 H265 120.0 . .
C264 C265 H265 120.0 . .
C265 C266 C261 120.0 . .
C265 C266 H266 120.0 . .
C261 C266 H266 120.0 . .
O272 C271 C254 116.8(10) . .
O272 C271 C264 125.6(14) . .
C254 C271 C264 117.5(10) . .
F12 B11 F13 109.0(7) . .
F12 B11 F13 109.0(7) . 3_655
F13 B11 F13 110.0(7) . 3_655
F12 B11 F13 109.0(7) . 5_665
F13 B11 F13 110.0(7) . 5_665
F13 B11 F13 110.0(7) 3_655 5_665
F22 B21 F22 107.2(8) 3_765 5_675
F22 B21 F22 107.2(8) 3_765 .
F22 B21 F22 107.2(8) 5_675 .
F22 B21 F23 111.6(7) 3_765 .
F22 B21 F23 111.6(7) 5_675 .
F22 B21 F23 111.6(7) . .
F35 B31 F32 113.2(11) . .
F35 B31 F33 109.4(11) . .
F32 B31 F33 109.6(10) . .
F35 B31 F34 108.3(12) . .
F32 B31 F34 107.6(10) . .
F33 B31 F34 108.7(9) . .
N12S C11S H11A 109.5 . .
N12S C11S H11B 109.5 . .
H11A C11S H11B 109.5 . .
N12S C11S H11C 109.5 . .
H11A C11S H11C 109.5 . .
H11B C11S H11C 109.5 . .
O14S N12S O13S 121(2) . .
O14S N12S C11S 110(2) . .
O13S N12S C11S 129(2) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 N211 2.269(6) .
Ag1 N111 2.275(5) .
Ag1 N222 2.336(6) .
Ag1 N122 2.396(5) .
Ag1 Ag2 2.9870(14) 6_565
Ag2 N231 2.258(5) .
Ag2 N142 2.278(6) .
Ag2 N242 2.350(5) .
Ag2 N131 2.410(7) .
Ag2 Ag1 2.9869(14) 2_654
N111 C112 1.3900 .
N111 C116 1.3900 .
C112 C113 1.3900 .
C112 C123 1.395(7) .
C113 C114 1.3900 .
C113 H113 0.9300 .
C114 C115 1.3900 .
C114 H114 0.9300 .
C115 C116 1.3900 .
C115 H115 0.9300 .
C116 H116 0.9300 .
N121 C126 1.415(14) .
N121 N122 1.4200 .
N121 C125 1.4200 .
N122 C123 1.4200 .
C123 C124 1.4200 .
C124 C125 1.4200 .
C124 H124 0.9300 .
C125 H125 0.9300 .
C126 C151 1.506(11) .
C126 H12A 0.9700 .
C126 H12B 0.9700 .
N131 C132 1.3900 .
N131 C136 1.3900 .
C132 C143 1.306(9) .
C132 C133 1.3900 .
C133 C134 1.3900 .
C133 H133 0.9300 .
C134 C135 1.3900 .
C134 H134 0.9300 .
C135 C136 1.3900 .
C135 H135 0.9300 .
C136 H136 0.9300 .
N141 C145 1.4200 .
N141 N142 1.4200 .
N141 C146 1.47(2) .
N142 C143 1.4200 .
C143 C144 1.4200 .
C144 C145 1.4200 .
C144 H144 0.9300 .
C145 H145 0.9300 .
C146 C161 1.427(17) .
C146 H14A 0.9700 .
C146 H14B 0.9700 .
C151 C152 1.3900 .
C151 C156 1.3900 .
C152 C153 1.3900 .
C152 H152 0.9300 .
C153 C154 1.3900 .
C153 H153 0.9300 .
C154 C155 1.3900 .
C154 C171 1.453(11) .
C155 C156 1.3900 .
C155 H155 0.9300 .
C156 H156 0.9300 .
C161 C162 1.3900 .
C161 C166 1.3900 .
C162 C163 1.3900 .
C162 H162 0.9300 .
C163 C164 1.3900 .
C163 H163 0.9300 .
C164 C165 1.3902 .
C164 C171 1.560(14) .
C165 C166 1.3897 .
C165 H165 0.9300 .
C166 H166 0.9300 .
C171 O172 1.237(15) .
N211 C212 1.3900 .
N211 C216 1.3900 .
C212 C223 1.312(9) .
C212 C213 1.3900 .
C213 C214 1.3900 .
C213 H213 0.9300 .
C214 C215 1.3900 .
C214 H214 0.9300 .
C215 C216 1.3900 .
C215 H215 0.9300 .
C216 H216 0.9300 .
N221 C226 1.375(16) .
N221 N222 1.4200 .
N221 C225 1.4200 .
N222 C223 1.4200 .
C223 C224 1.4200 .
C224 C225 1.4200 .
C224 H224 0.9300 .
C225 H225 0.9300 .
C226 C251 1.618(16) .
C226 H22A 0.9700 .
C226 H22B 0.9700 .
N231 C232 1.3900 .
N231 C236 1.3900 .
C232 C243 1.368(7) .
C232 C233 1.3900 .
C233 C234 1.3900 .
C233 H233 0.9300 .
C234 C235 1.3900 .
C234 H234 0.9300 .
C235 C236 1.3900 .
C235 H235 0.9300 .
C236 H236 0.9300 .
N241 C246 1.365(12) .
N241 N242 1.4200 .
N241 C245 1.4200 .
N242 C243 1.4200 .
C243 C244 1.4200 .
C244 C245 1.4200 .
C244 H244 0.9300 .
C245 H245 0.9300 .
C246 C261 1.533(13) .
C246 H24A 0.9700 .
C246 H24B 0.9700 .
C251 C252 1.3900 .
C251 C256 1.3900 .
C252 C253 1.3900 .
C252 H252 0.9300 .
C253 C254 1.3900 .
C253 H253 0.9300 .
C254 C255 1.3900 .
C254 C271 1.473(18) .
C255 C256 1.3900 .
C255 H255 0.9300 .
C256 H256 0.9300 .
C261 C266 1.3900 .
C261 C262 1.3900 .
C262 C263 1.3899 .
C262 H262 0.9300 .
C263 C264 1.3900 .
C263 H263 0.9300 .
C264 C265 1.3900 .
C264 C271 1.520(12) .
C265 C266 1.3899 .
C265 H265 0.9300 .
C266 H266 0.9300 .
C271 O272 1.193(18) .
B11 F12 1.374(16) .
B11 F13 1.384(8) .
B11 F13 1.384(8) 3_655
B11 F13 1.384(8) 5_665
B21 F22 1.377(8) 3_765
B21 F22 1.377(8) 5_675
B21 F22 1.377(8) .
B21 F23 1.402(16) .
B31 F35 1.331(14) .
B31 F32 1.349(12) .
B31 F33 1.383(13) .
B31 F34 1.389(14) .
C11S N12S 1.493(19) .
C11S H11A 0.9600 .
C11S H11B 0.9600 .
C11S H11C 0.9600 .
N12S O14S 1.220(17) .
N12S O13S 1.247(17) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
N211 Ag1 N111 C112 119.9(11) .
N222 Ag1 N111 C112 -122.9(4) .
N122 Ag1 N111 C112 2.2(4) .
Ag2 Ag1 N111 C112 127.4(4) 6_565
N211 Ag1 N111 C116 -67.6(12) .
N222 Ag1 N111 C116 49.6(5) .
N122 Ag1 N111 C116 174.7(5) .
Ag2 Ag1 N111 C116 -60.2(4) 6_565
C116 N111 C112 C113 0.0 .
Ag1 N111 C112 C113 172.7(5) .
C116 N111 C112 C123 -179.3(8) .
Ag1 N111 C112 C123 -6.6(7) .
N111 C112 C113 C114 0.0 .
C123 C112 C113 C114 179.3(8) .
C112 C113 C114 C115 0.0 .
C113 C114 C115 C116 0.0 .
C114 C115 C116 N111 0.0 .
C112 N111 C116 C115 0.0 .
Ag1 N111 C116 C115 -172.3(5) .
C126 N121 N122 C123 -176.6(8) .
C125 N121 N122 C123 0.0 .
C126 N121 N122 Ag1 22.5(10) .
C125 N121 N122 Ag1 -160.9(7) .
N211 Ag1 N122 N121 -5.0(7) .
N111 Ag1 N122 N121 162.7(7) .
N222 Ag1 N122 N121 -87.7(7) .
Ag2 Ag1 N122 N121 89.1(6) 6_565
N211 Ag1 N122 C123 -165.5(4) .
N111 Ag1 N122 C123 2.1(4) .
N222 Ag1 N122 C123 111.8(4) .
Ag2 Ag1 N122 C123 -71.4(4) 6_565
C113 C112 C123 C124 18.2(11) .
N111 C112 C123 C124 -162.5(6) .
C113 C112 C123 N122 -170.2(5) .
N111 C112 C123 N122 9.1(9) .
N121 N122 C123 C112 -173.3(9) .
Ag1 N122 C123 C112 -6.6(7) .
N121 N122 C123 C124 0.0 .
Ag1 N122 C123 C124 166.7(5) .
C112 C123 C124 C125 172.4(10) .
N122 C123 C124 C125 0.0 .
C123 C124 C125 N121 0.0 .
C126 N121 C125 C124 175.7(10) .
N122 N121 C125 C124 0.0 .
N122 N121 C126 C151 78.0(10) .
C125 N121 C126 C151 -97.5(9) .
N231 Ag2 N131 C132 139.8(7) .
N142 Ag2 N131 C132 -0.1(5) .
N242 Ag2 N131 C132 -131.5(5) .
Ag1 Ag2 N131 C132 112.9(5) 2_654
N231 Ag2 N131 C136 -34.3(11) .
N142 Ag2 N131 C136 -174.1(7) .
N242 Ag2 N131 C136 54.5(6) .
Ag1 Ag2 N131 C136 -61.2(6) 2_654
C136 N131 C132 C143 -178.9(11) .
Ag2 N131 C132 C143 6.6(10) .
C136 N131 C132 C133 0.0 .
Ag2 N131 C132 C133 -174.5(6) .
C143 C132 C133 C134 178.9(11) .
N131 C132 C133 C134 0.0 .
C132 C133 C134 C135 0.0 .
C133 C134 C135 C136 0.0 .
C134 C135 C136 N131 0.0 .
C132 N131 C136 C135 0.0 .
Ag2 N131 C136 C135 173.7(7) .
C145 N141 N142 C143 0.0 .
C146 N141 N142 C143 176.6(11) .
C145 N141 N142 Ag2 168.1(9) .
C146 N141 N142 Ag2 -15.3(13) .
N231 Ag2 N142 C143 -168.9(5) .
N242 Ag2 N142 C143 92.3(6) .
N131 Ag2 N142 C143 -5.8(5) .
Ag1 Ag2 N142 C143 -75.3(5) 2_654
N231 Ag2 N142 N141 23.5(9) .
N242 Ag2 N142 N141 -75.2(9) .
N131 Ag2 N142 N141 -173.4(9) .
Ag1 Ag2 N142 N141 117.1(8) 2_654
C133 C132 C143 C144 -7.4(14) .
N131 C132 C143 C144 171.4(7) .
C133 C132 C143 N142 168.0(7) .
N131 C132 C143 N142 -13.1(14) .
N141 N142 C143 C132 -176.4(12) .
Ag2 N142 C143 C132 12.6(12) .
N141 N142 C143 C144 0.0 .
Ag2 N142 C143 C144 -171.0(7) .
C132 C143 C144 C145 176.0(14) .
N142 C143 C144 C145 0.0 .
C143 C144 C145 N141 0.0 .
N142 N141 C145 C144 0.0 .
C146 N141 C145 C144 -175.3(16) .
C145 N141 C146 C161 -116.6(12) .
N142 N141 C146 C161 68.2(15) .
N121 C126 C151 C152 -93.6(9) .
N121 C126 C151 C156 88.8(7) .
C156 C151 C152 C153 0.0 .
C126 C151 C152 C153 -177.6(6) .
C151 C152 C153 C154 0.0 .
C152 C153 C154 C155 0.0 .
C152 C153 C154 C171 178.1(6) .
C153 C154 C155 C156 0.0 .
C171 C154 C155 C156 -177.9(6) .
C154 C155 C156 C151 0.0 .
C152 C151 C156 C155 0.0 .
C126 C151 C156 C155 177.5(7) .
N141 C146 C161 C162 -167.3(9) .
N141 C146 C161 C166 13.3(17) .
C166 C161 C162 C163 0.0 .
C146 C161 C162 C163 -179.4(9) .
C161 C162 C163 C164 0.0 .
C162 C163 C164 C165 0.0 .
C162 C163 C164 C171 168.5(5) .
C163 C164 C165 C166 0.0 .
C171 C164 C165 C166 -168.2(5) .
C164 C165 C166 C161 0.0 .
C162 C161 C166 C165 0.0 .
C146 C161 C166 C165 179.4(10) .
C155 C154 C171 O172 129.5(10) .
C153 C154 C171 O172 -48.5(13) .
C155 C154 C171 C164 -48.8(10) .
C153 C154 C171 C164 133.2(6) .
C163 C164 C171 O172 -17.7(11) .
C165 C164 C171 O172 150.8(8) .
C163 C164 C171 C154 160.8(6) .
C165 C164 C171 C154 -30.8(10) .
N111 Ag1 N211 C212 135.8(11) .
N222 Ag1 N211 C212 13.9(5) .
N122 Ag1 N211 C212 -110.7(5) .
Ag2 Ag1 N211 C212 128.3(5) 6_565
N111 Ag1 N211 C216 -61.2(13) .
N222 Ag1 N211 C216 177.0(6) .
N122 Ag1 N211 C216 52.3(6) .
Ag2 Ag1 N211 C216 -68.7(5) 6_565
C216 N211 C212 C223 179.0(11) .
Ag1 N211 C212 C223 -17.7(10) .
C216 N211 C212 C213 0.0 .
Ag1 N211 C212 C213 163.4(6) .
C223 C212 C213 C214 -179.0(11) .
N211 C212 C213 C214 0.0 .
C212 C213 C214 C215 0.0 .
C213 C214 C215 C216 0.0 .
C214 C215 C216 N211 0.0 .
C212 N211 C216 C215 0.0 .
Ag1 N211 C216 C215 -162.3(7) .
C226 N221 N222 C223 179.3(11) .
C225 N221 N222 C223 0.0 .
C226 N221 N222 Ag1 -13.2(13) .
C225 N221 N222 Ag1 167.6(9) .
N211 Ag1 N222 C223 -9.7(5) .
N111 Ag1 N222 C223 -177.5(5) .
N122 Ag1 N222 C223 94.4(6) .
Ag2 Ag1 N222 C223 -82.8(5) 6_565
N211 Ag1 N222 N221 -176.7(8) .
N111 Ag1 N222 N221 15.4(9) .
N122 Ag1 N222 N221 -72.7(8) .
Ag2 Ag1 N222 N221 110.1(7) 6_565
C213 C212 C223 C224 1.2(14) .
N211 C212 C223 C224 -177.7(8) .
C213 C212 C223 N222 -172.6(6) .
N211 C212 C223 N222 8.5(12) .
N221 N222 C223 C212 175.3(11) .
Ag1 N222 C223 C212 4.5(10) .
N221 N222 C223 C224 0.0 .
Ag1 N222 C223 C224 -170.8(7) .
C212 C223 C224 C225 -174.2(13) .
N222 C223 C224 C225 0.0 .
C223 C224 C225 N221 0.0 .
C226 N221 C225 C224 -179.1(13) .
N222 N221 C225 C224 0.0 .
N222 N221 C226 C251 71.7(11) .
C225 N221 C226 C251 -109.3(11) .
N142 Ag2 N231 C232 -131.2(5) .
N242 Ag2 N231 C232 0.7(5) .
N131 Ag2 N231 C232 96.8(8) .
Ag1 Ag2 N231 C232 123.1(5) 2_654
N142 Ag2 N231 C236 38.2(6) .
N242 Ag2 N231 C236 170.1(6) .
N131 Ag2 N231 C236 -93.8(8) .
Ag1 Ag2 N231 C236 -67.5(5) 2_654
C236 N231 C232 C243 -177.6(9) .
Ag2 N231 C232 C243 -8.0(9) .
C236 N231 C232 C233 0.0 .
Ag2 N231 C232 C233 169.6(6) .
C243 C232 C233 C234 177.5(9) .
N231 C232 C233 C234 0.0 .
C232 C233 C234 C235 0.0 .
C233 C234 C235 C236 0.0 .
C234 C235 C236 N231 0.0 .
C232 N231 C236 C235 0.0 .
Ag2 N231 C236 C235 -169.1(6) .
C246 N241 N242 C243 -179.4(10) .
C245 N241 N242 C243 0.0 .
C246 N241 N242 Ag2 22.0(11) .
C245 N241 N242 Ag2 -158.7(7) .
N231 Ag2 N242 C243 6.0(4) .
N142 Ag2 N242 C243 127.4(5) .
N131 Ag2 N242 C243 -151.1(4) .
Ag1 Ag2 N242 C243 -66.0(4) 2_654
N231 Ag2 N242 N241 163.9(6) .
N142 Ag2 N242 N241 -74.7(7) .
N131 Ag2 N242 N241 6.8(6) .
Ag1 Ag2 N242 N241 91.9(6) 2_654
N231 C232 C243 N242 13.9(10) .
C233 C232 C243 N242 -163.6(6) .
N231 C232 C243 C244 -161.6(7) .
C233 C232 C243 C244 20.8(11) .
N241 N242 C243 C232 -176.7(9) .
Ag2 N242 C243 C232 -12.6(8) .
N241 N242 C243 C244 0.0 .
Ag2 N242 C243 C244 164.1(5) .
C232 C243 C244 C245 175.9(11) .
N242 C243 C244 C245 0.0 .
C246 N241 C245 C244 179.3(10) .
N242 N241 C245 C244 0.0 .
C243 C244 C245 N241 0.0 .
N242 N241 C246 C261 67.6(12) .
C245 N241 C246 C261 -111.6(9) .
N221 C226 C251 C252 -168.0(7) .
N221 C226 C251 C256 12.5(11) .
C256 C251 C252 C253 0.0 .
C226 C251 C252 C253 -179.6(6) .
C251 C252 C253 C254 0.0 .
C252 C253 C254 C255 0.0 .
C252 C253 C254 C271 168.4(7) .
C253 C254 C255 C256 0.0 .
C271 C254 C255 C256 -168.3(7) .
C254 C255 C256 C251 0.0 .
C252 C251 C256 C255 0.0 .
C226 C251 C256 C255 179.5(6) .
N241 C246 C261 C266 85.9(9) .
N241 C246 C261 C262 -95.9(10) .
C266 C261 C262 C263 0.0 .
C246 C261 C262 C263 -178.2(6) .
C261 C262 C263 C264 0.0 .
C262 C263 C264 C265 0.0 .
C262 C263 C264 C271 176.5(8) .
C263 C264 C265 C266 0.0 .
C271 C264 C265 C266 -176.3(8) .
C264 C265 C266 C261 0.0 .
C262 C261 C266 C265 0.0 .
C246 C261 C266 C265 178.2(6) .
C255 C254 C271 O272 148.2(11) .
C253 C254 C271 O272 -20.1(16) .
C255 C254 C271 C264 -36.3(13) .
C253 C254 C271 C264 155.3(7) .
C263 C264 C271 O272 -38.2(17) .
C265 C264 C271 O272 138.2(13) .
C263 C264 C271 C254 146.8(8) .
C265 C264 C271 C254 -36.8(15) .
