#------------------------------------------------------------------------------
#$Date: 2016-03-26 03:24:32 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180181 $
#$URL: svn://www.crystallography.net/cod/cif/7/10/77/7107722.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7107722
loop_
_publ_author_name
'Jin Tong'
'Shu-Yan Yu'
'Hui Li'
_publ_section_title
;
 Programmable Self-Assembly of Homo- or Hetero- Metallomacrocycles using
 4-(1H-pyrazolyl-4-yl)pyridine
;
_journal_name_full               Chem.Commun.
_journal_page_first              5343
_journal_paper_doi               10.1039/c2cc31234d
_journal_volume                  48
_journal_year                    2012
_chemical_formula_moiety
'C92 H72 N24 Pd2 Pt4, H1.20 O0.60, 8(N O3), 7.4(H2 O)'
_chemical_formula_sum            'C92 H88 N32 O32 Pd2 Pt4'
_chemical_formula_weight         3147.10
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                116.487(2)
_cell_angle_beta                 102.313(4)
_cell_angle_gamma                96.752(2)
_cell_formula_units_Z            1
_cell_length_a                   15.2067(15)
_cell_length_b                   15.8034(16)
_cell_length_c                   17.2256(19)
_cell_measurement_reflns_used    7173
_cell_measurement_temperature    291(2)
_cell_measurement_theta_max      25.93
_cell_measurement_theta_min      2.13
_cell_volume                     3511.2(6)
_computing_cell_refinement       SMART
_computing_data_collection       'SMART (Bruker, 2000)'
_computing_data_reduction        'SAINT (Bruker, 2000)'
_computing_molecular_graphics    SHELXTL
_computing_publication_material  SHELXTL
_computing_structure_refinement  SHELXTL
_computing_structure_solution    'SHELXTL (Bruker, 2000)'
_diffrn_ambient_temperature      291(2)
_diffrn_measured_fraction_theta_full 0.987
_diffrn_measured_fraction_theta_max 0.987
_diffrn_measurement_device_type  'Bruker Smart Apex CCD'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0341
_diffrn_reflns_av_sigmaI/netI    0.0733
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            31419
_diffrn_reflns_theta_full        26.00
_diffrn_reflns_theta_max         26.00
_diffrn_reflns_theta_min         2.07
_exptl_absorpt_coefficient_mu    4.292
_exptl_absorpt_correction_T_max  0.4257
_exptl_absorpt_correction_T_min  0.3795
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS; Bruker, 2000'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.488
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1524
_exptl_crystal_size_max          0.28
_exptl_crystal_size_mid          0.26
_exptl_crystal_size_min          0.24
_refine_diff_density_max         1.416
_refine_diff_density_min         -1.429
_refine_diff_density_rms         0.111
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.085
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     808
_refine_ls_number_reflns         13629
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.085
_refine_ls_R_factor_all          0.0834
_refine_ls_R_factor_gt           0.0561
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0505P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1073
_refine_ls_wR_factor_ref         0.1127
_reflns_number_gt                9250
_reflns_number_total             13629
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c2cc31234d.txt
_cod_data_source_block           2
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7107722
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
C1 C 0.2109(4) 0.4379(5) -0.0086(5) 0.0447(16) Uani 1 1 d .
H1 H 0.1914 0.4505 0.0423 0.054 Uiso 1 1 calc R
C2 C 0.1803(5) 0.4791(4) -0.0622(4) 0.0423(16) Uani 1 1 d .
H2 H 0.1406 0.5201 -0.0461 0.051 Uiso 1 1 calc R
C3 C 0.2063(4) 0.4617(4) -0.1369(4) 0.0390(14) Uani 1 1 d .
H3 H 0.1866 0.4922 -0.1704 0.047 Uiso 1 1 calc R
C4 C 0.2611(4) 0.3996(5) -0.1626(4) 0.0420(15) Uani 1 1 d .
H4 H 0.2778 0.3852 -0.2152 0.050 Uiso 1 1 calc R
C5 C 0.2927(4) 0.3571(4) -0.1095(4) 0.0405(15) Uani 1 1 d .
C6 C 0.3518(4) 0.2869(5) -0.1286(4) 0.0423(15) Uani 1 1 d .
C7 C 0.3800(5) 0.2501(5) -0.2089(5) 0.0482(17) Uani 1 1 d .
H7 H 0.3648 0.2716 -0.2512 0.058 Uiso 1 1 calc R
C8 C 0.4298(4) 0.1827(5) -0.2206(5) 0.0446(17) Uani 1 1 d .
H8 H 0.4524 0.1611 -0.2705 0.054 Uiso 1 1 calc R
C9 C 0.4485(5) 0.1454(5) -0.1662(5) 0.0505(17) Uani 1 1 d .
H9 H 0.4748 0.0921 -0.1822 0.061 Uiso 1 1 calc R
C10 C 0.4272(5) 0.1893(5) -0.0804(5) 0.0458(16) Uani 1 1 d .
H10 H 0.4474 0.1720 -0.0358 0.055 Uiso 1 1 calc R
C11 C 0.2303(4) -0.0279(5) -0.0367(4) 0.0452(17) Uani 1 1 d .
H11 H 0.2908 0.0002 0.0018 0.054 Uiso 1 1 calc R
C12 C 0.2083(4) -0.1255(4) -0.1050(4) 0.0409(15) Uani 1 1 d .
H12 H 0.2531 -0.1614 -0.1106 0.049 Uiso 1 1 calc R
C13 C 0.1178(5) -0.1683(4) -0.1647(5) 0.0476(18) Uani 1 1 d .
H13 H 0.1020 -0.2303 -0.2148 0.057 Uiso 1 1 calc R
C14 C 0.0535(5) -0.1134(4) -0.1452(4) 0.0459(17) Uani 1 1 d .
H14 H -0.0091 -0.1420 -0.1767 0.055 Uiso 1 1 calc R
C15 C 0.0820(4) -0.0129(4) -0.0771(4) 0.0346(13) Uani 1 1 d .
C16 C 0.0164(5) 0.0521(5) -0.0661(5) 0.0495(17) Uani 1 1 d .
C17 C -0.0741(5) 0.0266(5) -0.1176(5) 0.0445(16) Uani 1 1 d .
H17 H -0.1014 -0.0380 -0.1615 0.053 Uiso 1 1 calc R
C18 C -0.1254(4) 0.0956(5) -0.1051(5) 0.0457(16) Uani 1 1 d .
H18 H -0.1866 0.0780 -0.1409 0.055 Uiso 1 1 calc R
C19 C -0.0847(4) 0.1911(5) -0.0387(5) 0.0503(19) Uani 1 1 d .
H19 H -0.1173 0.2393 -0.0302 0.060 Uiso 1 1 calc R
C20 C 0.0080(5) 0.2142(5) 0.0162(5) 0.0504(18) Uani 1 1 d .
H20 H 0.0365 0.2776 0.0624 0.060 Uiso 1 1 calc R
C21 C 0.1806(4) 0.3598(4) 0.2224(4) 0.0404(15) Uani 1 1 d .
H21 H 0.1404 0.3352 0.2453 0.049 Uiso 1 1 calc R
C22 C 0.2211(5) 0.4587(4) 0.2564(4) 0.0410(15) Uani 1 1 d .
C23 C 0.2776(4) 0.4633(4) 0.2043(4) 0.0338(13) Uani 1 1 d .
H23 H 0.3144 0.5199 0.2129 0.041 Uiso 1 1 calc R
C24 C 0.2327(5) 0.7194(5) 0.4304(5) 0.0485(17) Uani 1 1 d .
H24 H 0.2583 0.7824 0.4434 0.058 Uiso 1 1 calc R
C25 C 0.2462(4) 0.6349(4) 0.3536(4) 0.0417(16) Uani 1 1 d .
H25 H 0.2824 0.6446 0.3197 0.050 Uiso 1 1 calc R
C26 C 0.2052(5) 0.5413(5) 0.3322(5) 0.0447(16) Uani 1 1 d .
C27 C 0.1564(4) 0.5327(5) 0.3892(4) 0.0393(14) Uani 1 1 d .
H27 H 0.1324 0.4711 0.3805 0.047 Uiso 1 1 calc R
C28 C 0.1433(4) 0.6105(5) 0.4558(4) 0.0390(14) Uani 1 1 d .
H28 H 0.1049 0.6015 0.4883 0.047 Uiso 1 1 calc R
C29 C 0.0019(4) 0.7621(5) 0.4082(4) 0.0452(17) Uani 1 1 d .
H29 H 0.0298 0.7146 0.3752 0.054 Uiso 1 1 calc R
C30 C -0.0801(4) 0.7678(4) 0.3647(5) 0.054(2) Uani 1 1 d .
H30 H -0.1075 0.7231 0.3034 0.065 Uiso 1 1 calc R
C31 C -0.1248(5) 0.8381(5) 0.4084(5) 0.0462(16) Uani 1 1 d .
H31 H -0.1807 0.8425 0.3775 0.055 Uiso 1 1 calc R
C32 C -0.0823(4) 0.9023(5) 0.5010(5) 0.0510(19) Uani 1 1 d .
H32 H -0.1108 0.9492 0.5340 0.061 Uiso 1 1 calc R
C33 C 0.0045(5) 0.8950(5) 0.5437(4) 0.0461(16) Uani 1 1 d .
C34 C 0.0567(4) 0.9634(4) 0.6376(4) 0.0396(14) Uani 1 1 d .
C35 C 0.0256(5) 1.0410(5) 0.6944(4) 0.0441(16) Uani 1 1 d .
H35 H -0.0341 1.0469 0.6747 0.053 Uiso 1 1 calc R
C36 C 0.0812(5) 1.1063(5) 0.7766(4) 0.0445(16) Uani 1 1 d .
H36 H 0.0664 1.1641 0.8116 0.053 Uiso 1 1 calc R
C37 C 0.1693(5) 1.0819(5) 0.8103(5) 0.0519(19) Uani 1 1 d .
H37 H 0.2069 1.1208 0.8700 0.062 Uiso 1 1 calc R
C38 C 0.1918(4) 1.0077(4) 0.7560(4) 0.0372(14) Uani 1 1 d .
H38 H 0.2492 0.9973 0.7761 0.045 Uiso 1 1 calc R
C39 C 0.2756(4) 0.7631(4) 0.6915(4) 0.0344(13) Uani 1 1 d .
H39 H 0.2182 0.7252 0.6810 0.041 Uiso 1 1 calc R
C40 C 0.3556(4) 0.7548(4) 0.7420(4) 0.0409(15) Uani 1 1 d .
H40 H 0.3506 0.7119 0.7651 0.049 Uiso 1 1 calc R
C41 C 0.4415(4) 0.8089(4) 0.7583(4) 0.0342(13) Uani 1 1 d .
C42 C 0.4435(4) 0.8694(4) 0.7212(4) 0.0394(15) Uani 1 1 d .
H42 H 0.5004 0.9063 0.7294 0.047 Uiso 1 1 calc R
C43 C 0.3660(4) 0.8770(4) 0.6737(4) 0.0410(15) Uani 1 1 d .
H43 H 0.3709 0.9197 0.6504 0.049 Uiso 1 1 calc R
C44 C 0.5287(5) 0.7432(5) 0.8550(4) 0.0403(15) Uani 1 1 d .
H44 H 0.4770 0.7074 0.8572 0.048 Uiso 1 1 calc R
C45 C 0.5256(4) 0.7951(4) 0.8097(4) 0.0412(15) Uani 1 1 d .
C46 C 0.6220(4) 0.8395(5) 0.8284(4) 0.0435(16) Uani 1 1 d .
H46 H 0.6433 0.8801 0.8071 0.052 Uiso 1 1 calc R
N1 N 0.2694(4) 0.3790(4) -0.0312(3) 0.0401(12) Uani 1 1 d .
N2 N 0.3754(4) 0.2579(4) -0.0683(4) 0.0438(13) Uani 1 1 d .
N3 N 0.1690(3) 0.0261(3) -0.0246(3) 0.0374(12) Uani 1 1 d .
N4 N 0.0545(3) 0.1429(4) 0.0006(3) 0.0394(12) Uani 1 1 d .
N5 N 0.2102(4) 0.3057(4) 0.1498(3) 0.0382(12) Uani 1 1 d .
N6 N 0.2702(3) 0.3712(4) 0.1384(4) 0.0403(12) Uani 1 1 d .
N7 N 0.1855(4) 0.7056(4) 0.4788(4) 0.0435(13) Uani 1 1 d .
N8 N 0.0462(4) 0.8233(3) 0.4992(4) 0.0388(12) Uani 1 1 d .
N9 N 0.1363(3) 0.9417(4) 0.6694(4) 0.0432(13) Uani 1 1 d .
N10 N 0.2798(3) 0.8246(4) 0.6577(4) 0.0390(12) Uani 1 1 d .
N11 N 0.6180(4) 0.7512(4) 0.8965(4) 0.0437(13) Uani 1 1 d .
N12 N 0.6731(4) 0.8133(4) 0.8793(3) 0.0373(12) Uani 1 1 d .
N13 N 0.3164(4) 0.6889(4) 0.9573(4) 0.0434(13) Uani 1 1 d .
N14 N 0.1707(4) 0.8587(4) 0.3212(4) 0.0484(14) Uani 1 1 d .
N15 N 0.4989(4) 0.7270(5) 0.4988(4) 0.0532(16) Uani 1 1 d .
N16 N 0.9484(5) 0.6804(5) 0.5992(4) 0.0564(16) Uani 1 1 d .
O1 O 0.3705(3) 0.6788(3) 1.0184(3) 0.0505(12) Uani 1 1 d .
O2 O 0.2491(3) 0.7251(3) 0.9736(3) 0.0519(12) Uani 1 1 d .
O3 O 0.3269(3) 0.6585(3) 0.8806(3) 0.0448(11) Uani 1 1 d .
O4 O 0.1491(3) 0.9056(4) 0.3902(3) 0.0531(13) Uani 1 1 d .
O5 O 0.1107(3) 0.8239(3) 0.2438(3) 0.0512(12) Uani 1 1 d .
O6 O 0.2479(3) 0.8399(3) 0.3262(3) 0.0505(12) Uani 1 1 d .
O7 O 0.4706(3) 0.8028(4) 0.5080(4) 0.0629(15) Uani 1 1 d .
O8 O 0.5719(4) 0.7176(4) 0.4740(3) 0.0587(14) Uani 1 1 d .
O9 O 0.4549(3) 0.6640(4) 0.5107(3) 0.0510(12) Uani 1 1 d .
O10 O 0.9019(3) 0.6756(4) 0.5275(3) 0.0569(13) Uani 1 1 d .
O11 O 1.0302(4) 0.6681(4) 0.6057(4) 0.0668(15) Uani 1 1 d .
O12 O 0.9177(3) 0.6985(3) 0.6638(3) 0.0480(11) Uani 1 1 d .
O1W O 0.6385(8) 0.6505(8) 0.6188(8) 0.031(3) Uani 0.30 1 d P
H1X H 0.6934 0.6737 0.6224 0.037 Uiso 0.30 1 d PR
H1Y H 0.6206 0.6938 0.6589 0.037 Uiso 0.30 1 d PR
O2W O 0.2577(13) 0.4049(14) 0.6335(12) 0.080(6) Uani 0.30 1 d P
H2X H 0.2871 0.3626 0.6344 0.095 Uiso 0.30 1 d PR
H2Y H 0.2033 0.3890 0.6357 0.095 Uiso 0.30 1 d PR
O3W O 0.4828(10) 0.5502(10) 0.9312(10) 0.047(4) Uani 0.30 1 d P
H3X H 0.4614 0.5356 0.9665 0.056 Uiso 0.30 1 d PR
H3Y H 0.5379 0.5430 0.9361 0.056 Uiso 0.30 1 d PR
O4W O 0.3397(9) 0.5162(10) 0.5415(8) 0.040(4) Uani 0.30 1 d P
H4X H 0.3596 0.5212 0.5937 0.048 Uiso 0.30 1 d PR
H4Y H 0.2809 0.5048 0.5258 0.048 Uiso 0.30 1 d PR
O5W O 0.2614(8) 0.0621(10) 0.3606(9) 0.040(3) Uani 0.30 1 d P
H5X H 0.2713 0.1238 0.3854 0.047 Uiso 0.30 1 d PR
H5Y H 0.3121 0.0465 0.3730 0.047 Uiso 0.30 1 d PR
O6W O 0.3654(9) 0.9131(10) 0.0828(10) 0.041(3) Uani 0.30 1 d P
H6X H 0.3591 0.8845 0.1137 0.049 Uiso 0.30 1 d PR
H6Y H 0.3876 0.9739 0.1184 0.049 Uiso 0.30 1 d PR
O7W O 0.5164(9) 0.5417(10) 0.2309(10) 0.043(4) Uani 0.30 1 d P
H7X H 0.5170 0.5823 0.2111 0.052 Uiso 0.30 1 d PR
H7Y H 0.4886 0.5576 0.2713 0.052 Uiso 0.30 1 d PR
O8W O 0.6694(9) 0.8247(9) 0.4569(9) 0.039(3) Uani 0.30 1 d P
H8X H 0.6387 0.7691 0.4130 0.047 Uiso 0.30 1 d PR
H8Y H 0.6885 0.8200 0.5046 0.047 Uiso 0.30 1 d PR
O9W O 0.0221(10) 0.4345(10) 0.0744(11) 0.049(4) Uani 0.30 1 d P
H9X H 0.0771 0.4675 0.1069 0.058 Uiso 0.30 1 d PR
H9Y H 0.0169 0.4176 0.0190 0.058 Uiso 0.30 1 d PR
O10W O 0.4812(8) -0.0200(10) 0.5826(10) 0.040(4) Uani 0.30 1 d P
H10X H 0.4544 0.0191 0.6162 0.048 Uiso 0.30 1 d PR
H10Y H 0.5144 0.0095 0.5639 0.048 Uiso 0.30 1 d PR
O11W O 0.3260(11) 0.7307(13) 0.1487(11) 0.058(5) Uani 0.30 1 d P
H11X H 0.3016 0.6699 0.1162 0.070 Uiso 0.30 1 d PR
H11Y H 0.3606 0.7488 0.1234 0.070 Uiso 0.30 1 d PR
O12W O 0.5000 0.0000 1.0000 0.050(3) Uani 0.60 2 d SP
H12X H 0.5094 -0.0154 0.9490 0.060 Uiso 0.30 1 d PR
H12Y H 0.4653 0.0398 1.0098 0.060 Uiso 0.30 1 d PR
O13W O 0.8543(9) 0.4112(9) 0.2737(9) 0.060(3) Uani 0.40 1 d P
H13X H 0.8590 0.3789 0.2206 0.071 Uiso 0.40 1 d PR
H13Y H 0.8998 0.4609 0.3051 0.071 Uiso 0.40 1 d PR
Pd1 Pd 0.16250(3) 0.82297(3) 0.57610(3) 0.04070(13) Uani 1 1 d .
Pt1 Pt 0.32439(2) 0.31315(2) 0.03666(2) 0.05375(10) Uani 1 1 d .
Pt2 Pt 0.19152(2) 0.16752(2) 0.06568(2) 0.05119(9) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pd Pd -0.9988 1.0072 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N1 C1 C2 119.2(6) . .
N1 C1 H1 120.4 . .
C2 C1 H1 120.4 . .
C3 C2 C1 122.1(6) . .
C3 C2 H2 119.0 . .
C1 C2 H2 119.0 . .
C2 C3 C4 119.4(6) . .
C2 C3 H3 120.3 . .
C4 C3 H3 120.3 . .
C3 C4 C5 119.4(6) . .
C3 C4 H4 120.3 . .
C5 C4 H4 120.3 . .
N1 C5 C4 120.6(6) . .
N1 C5 C6 113.2(6) . .
C4 C5 C6 126.2(6) . .
N2 C6 C7 121.3(6) . .
N2 C6 C5 116.1(6) . .
C7 C6 C5 122.5(6) . .
C8 C7 C6 116.7(7) . .
C8 C7 H7 121.7 . .
C6 C7 H7 121.7 . .
C9 C8 C7 124.3(7) . .
C9 C8 H8 117.9 . .
C7 C8 H8 117.9 . .
C8 C9 C10 118.6(7) . .
C8 C9 H9 120.7 . .
C10 C9 H9 120.7 . .
N2 C10 C9 116.7(6) . .
N2 C10 H10 121.6 . .
C9 C10 H10 121.6 . .
N3 C11 C12 123.1(6) . .
N3 C11 H11 118.5 . .
C12 C11 H11 118.5 . .
C13 C12 C11 119.0(6) . .
C13 C12 H12 120.5 . .
C11 C12 H12 120.5 . .
C14 C13 C12 116.4(5) . .
C14 C13 H13 121.8 . .
C12 C13 H13 121.8 . .
C13 C14 C15 120.7(6) . .
C13 C14 H14 119.6 . .
C15 C14 H14 119.6 . .
N3 C15 C14 120.4(6) . .
N3 C15 C16 118.1(5) . .
C14 C15 C16 121.5(6) . .
N4 C16 C17 120.2(6) . .
N4 C16 C15 113.3(6) . .
C17 C16 C15 126.5(6) . .
C16 C17 C18 120.8(6) . .
C16 C17 H17 119.6 . .
C18 C17 H17 119.6 . .
C17 C18 C19 119.2(6) . .
C17 C18 H18 120.4 . .
C19 C18 H18 120.4 . .
C18 C19 C20 118.5(6) . .
C18 C19 H19 120.8 . .
C20 C19 H19 120.8 . .
N4 C20 C19 119.4(6) . .
N4 C20 H20 120.3 . .
C19 C20 H20 120.3 . .
N5 C21 C22 108.5(5) . .
N5 C21 H21 125.7 . .
C22 C21 H21 125.7 . .
C23 C22 C21 107.1(5) . .
C23 C22 C26 126.8(6) . .
C21 C22 C26 126.1(6) . .
N6 C23 C22 108.7(6) . .
N6 C23 H23 125.6 . .
C22 C23 H23 125.6 . .
N7 C24 C25 119.7(6) . .
N7 C24 H24 120.2 . .
C25 C24 H24 120.2 . .
C26 C25 C24 120.1(6) . .
C26 C25 H25 120.0 . .
C24 C25 H25 120.0 . .
C25 C26 C27 116.6(6) . .
C25 C26 C22 118.8(6) . .
C27 C26 C22 124.5(6) . .
C28 C27 C26 121.4(6) . .
C28 C27 H27 119.3 . .
C26 C27 H27 119.3 . .
C27 C28 N7 122.2(6) . .
C27 C28 H28 118.9 . .
N7 C28 H28 118.9 . .
C30 C29 N8 123.0(6) . .
C30 C29 H29 118.5 . .
N8 C29 H29 118.5 . .
C29 C30 C31 122.0(6) . .
C29 C30 H30 119.0 . .
C31 C30 H30 119.0 . .
C30 C31 C32 117.1(6) . .
C30 C31 H31 121.4 . .
C32 C31 H31 121.4 . .
C31 C32 C33 119.1(6) . .
C31 C32 H32 120.5 . .
C33 C32 H32 120.5 . .
N8 C33 C32 122.4(6) . .
N8 C33 C34 114.9(6) . .
C32 C33 C34 122.6(6) . .
N9 C34 C35 121.5(6) . .
N9 C34 C33 114.7(5) . .
C35 C34 C33 123.5(6) . .
C36 C35 C34 120.0(6) . .
C36 C35 H35 120.0 . .
C34 C35 H35 120.0 . .
C35 C36 C37 116.7(6) . .
C35 C36 H36 121.6 . .
C37 C36 H36 121.6 . .
C38 C37 C36 119.2(6) . .
C38 C37 H37 120.4 . .
C36 C37 H37 120.4 . .
C37 C38 N9 124.0(6) . .
C37 C38 H38 118.0 . .
N9 C38 H38 118.0 . .
N10 C39 C40 121.2(6) . .
N10 C39 H39 119.4 . .
C40 C39 H39 119.4 . .
C41 C40 C39 121.1(6) . .
C41 C40 H40 119.5 . .
C39 C40 H40 119.5 . .
C42 C41 C40 116.2(6) . .
C42 C41 C45 124.4(6) . .
C40 C41 C45 119.4(6) . .
C43 C42 C41 121.8(6) . .
C43 C42 H42 119.1 . .
C41 C42 H42 119.1 . .
C42 C43 N10 122.8(6) . .
C42 C43 H43 118.6 . .
N10 C43 H43 118.6 . .
N11 C44 C45 110.0(6) . .
N11 C44 H44 125.0 . .
C45 C44 H44 125.0 . .
C44 C45 C46 104.5(6) . .
C44 C45 C41 127.5(6) . .
C46 C45 C41 127.9(6) . .
N12 C46 C45 108.6(7) . .
N12 C46 H46 125.7 . .
C45 C46 H46 125.7 . .
C1 N1 C5 119.2(6) . .
C1 N1 Pt1 126.4(4) . .
C5 N1 Pt1 114.4(4) . .
C6 N2 C10 121.7(6) . .
C6 N2 Pt1 115.3(5) . .
C10 N2 Pt1 122.9(5) . .
C15 N3 C11 119.6(5) . .
C15 N3 Pt2 112.9(4) . .
C11 N3 Pt2 127.5(4) . .
C16 N4 C20 121.8(6) . .
C16 N4 Pt2 114.2(4) . .
C20 N4 Pt2 123.7(4) . .
C21 N5 N6 107.3(5) . .
C21 N5 Pt2 136.3(4) . .
N6 N5 Pt2 116.4(4) . .
C23 N6 N5 108.4(5) . .
C23 N6 Pt1 135.1(5) . .
N5 N6 Pt1 116.5(4) . .
C24 N7 C28 119.7(6) . .
C24 N7 Pd1 117.5(5) . .
C28 N7 Pd1 122.4(4) . .
C33 N8 C29 116.2(5) . .
C33 N8 Pd1 114.6(4) . .
C29 N8 Pd1 129.2(4) . .
C34 N9 C38 117.1(5) . .
C34 N9 Pd1 113.8(4) . .
C38 N9 Pd1 128.6(4) . .
C39 N10 C43 116.9(5) . .
C39 N10 Pd1 118.5(4) . .
C43 N10 Pd1 124.3(4) . .
C44 N11 N12 106.9(5) . .
C44 N11 Pt1 132.6(5) . 2_666
N12 N11 Pt1 120.3(4) . 2_666
C46 N12 N11 110.0(5) . .
C46 N12 Pt2 137.4(5) . 2_666
N11 N12 Pt2 112.5(4) . 2_666
O3 N13 O2 120.1(6) . .
O3 N13 O1 120.6(5) . .
O2 N13 O1 119.2(5) . .
O4 N14 O6 120.8(6) . .
O4 N14 O5 119.3(6) . .
O6 N14 O5 119.7(6) . .
O9 N15 O8 122.2(6) . .
O9 N15 O7 121.2(6) . .
O8 N15 O7 116.5(7) . .
O12 N16 O10 121.6(7) . .
O12 N16 O11 119.5(7) . .
O10 N16 O11 118.8(6) . .
H1X O1W H1Y 109.5 . .
H2X O2W H2Y 109.5 . .
H3X O3W H3Y 109.5 . .
H4X O4W H4Y 109.5 . .
H5X O5W H5Y 109.5 . .
H6X O6W H6Y 109.5 . .
H7X O7W H7Y 109.5 . .
H8X O8W H8Y 109.5 . .
H9X O9W H9Y 109.5 . .
H10X O10W H10Y 109.5 . .
H11X O11W H11Y 109.5 . .
H12X O12W H12Y 109.5 . .
H13X O13W H13Y 109.5 . .
N8 Pd1 N7 96.1(2) . .
N8 Pd1 N9 81.7(2) . .
N7 Pd1 N9 177.5(2) . .
N8 Pd1 N10 178.3(2) . .
N7 Pd1 N10 85.4(2) . .
N9 Pd1 N10 96.8(2) . .
N6 Pt1 N11 84.7(2) . 2_666
N6 Pt1 N2 177.3(2) . .
N11 Pt1 N2 98.0(2) 2_666 .
N6 Pt1 N1 96.4(2) . .
N11 Pt1 N1 178.5(2) 2_666 .
N2 Pt1 N1 80.9(2) . .
N6 Pt1 Pt2 62.90(16) . .
N11 Pt1 Pt2 61.98(16) 2_666 .
N2 Pt1 Pt2 118.21(15) . .
N1 Pt1 Pt2 119.44(14) . .
N5 Pt2 N12 86.1(2) . 2_666
N5 Pt2 N3 177.7(2) . .
N12 Pt2 N3 95.7(2) 2_666 .
N5 Pt2 N4 96.7(2) . .
N12 Pt2 N4 175.92(19) 2_666 .
N3 Pt2 N4 81.5(2) . .
N5 Pt2 Pt1 64.19(16) . .
N12 Pt2 Pt1 65.09(15) 2_666 .
N3 Pt2 Pt1 115.22(15) . .
N4 Pt2 Pt1 113.39(16) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C1 N1 1.352(8) .
C1 C2 1.385(10) .
C1 H1 0.9300 .
C2 C3 1.346(9) .
C2 H2 0.9300 .
C3 C4 1.347(9) .
C3 H3 0.9300 .
C4 C5 1.399(10) .
C4 H4 0.9300 .
C5 N1 1.370(8) .
C5 C6 1.477(9) .
C6 N2 1.314(8) .
C6 C7 1.424(9) .
C7 C8 1.346(9) .
C7 H7 0.9300 .
C8 C9 1.315(10) .
C8 H8 0.9300 .
C9 C10 1.454(10) .
C9 H9 0.9300 .
C10 N2 1.381(9) .
C10 H10 0.9300 .
C11 N3 1.324(8) .
C11 C12 1.403(8) .
C11 H11 0.9300 .
C12 C13 1.402(9) .
C12 H12 0.9300 .
C13 C14 1.379(9) .
C13 H13 0.9300 .
C14 C15 1.430(8) .
C14 H14 0.9300 .
C15 N3 1.322(8) .
C15 C16 1.495(9) .
C16 N4 1.328(8) .
C16 C17 1.369(10) .
C17 C18 1.381(9) .
C17 H17 0.9300 .
C18 C19 1.381(9) .
C18 H18 0.9300 .
C19 C20 1.420(9) .
C19 H19 0.9300 .
C20 N4 1.357(8) .
C20 H20 0.9300 .
C21 N5 1.369(8) .
C21 C22 1.403(8) .
C21 H21 0.9300 .
C22 C23 1.386(9) .
C22 C26 1.469(8) .
C23 N6 1.361(7) .
C23 H23 0.9300 .
C24 N7 1.281(9) .
C24 C25 1.476(9) .
C24 H24 0.9300 .
C25 C26 1.381(8) .
C25 H25 0.9300 .
C26 C27 1.393(9) .
C27 C28 1.328(8) .
C27 H27 0.9300 .
C28 N7 1.400(8) .
C28 H28 0.9300 .
C29 C30 1.347(9) .
C29 N8 1.374(8) .
C29 H29 0.9300 .
C30 C31 1.383(9) .
C30 H30 0.9300 .
C31 C32 1.397(9) .
C31 H31 0.9300 .
C32 C33 1.412(9) .
C32 H32 0.9300 .
C33 N8 1.369(8) .
C33 C34 1.451(9) .
C34 N9 1.366(8) .
C34 C35 1.396(9) .
C35 C36 1.329(9) .
C35 H35 0.9300 .
C36 C37 1.506(10) .
C36 H36 0.9300 .
C37 C38 1.273(9) .
C37 H37 0.9300 .
C38 N9 1.376(8) .
C38 H38 0.9300 .
C39 N10 1.338(8) .
C39 C40 1.394(8) .
C39 H39 0.9300 .
C40 C41 1.373(8) .
C40 H40 0.9300 .
C41 C42 1.367(9) .
C41 C45 1.491(9) .
C42 C43 1.335(8) .
C42 H42 0.9300 .
C43 N10 1.367(8) .
C43 H43 0.9300 .
C44 N11 1.354(8) .
C44 C45 1.359(9) .
C44 H44 0.9300 .
C45 C46 1.449(9) .
C46 N12 1.286(8) .
C46 H46 0.9300 .
N1 Pt1 2.006(6) .
N2 Pt1 1.995(6) .
N3 Pt2 2.006(5) .
N4 Pt2 2.043(5) .
N5 N6 1.407(8) .
N5 Pt2 1.950(5) .
N6 Pt1 1.988(5) .
N7 Pd1 2.000(5) .
N8 Pd1 1.973(5) .
N9 Pd1 2.005(5) .
N10 Pd1 2.012(5) .
N11 N12 1.387(7) .
N11 Pt1 1.988(6) 2_666
N12 Pt2 1.998(5) 2_666
N13 O3 1.243(7) .
N13 O2 1.253(7) .
N13 O1 1.275(7) .
N14 O4 1.228(7) .
N14 O6 1.240(7) .
N14 O5 1.274(7) .
N15 O9 1.250(8) .
N15 O8 1.274(7) .
N15 O7 1.275(8) .
N16 O12 1.228(7) .
N16 O10 1.251(8) .
N16 O11 1.270(8) .
O1W H1X 0.8499 .
O1W H1Y 0.8501 .
O2W H2X 0.8500 .
O2W H2Y 0.8501 .
O3W H3X 0.8500 .
O3W H3Y 0.8500 .
O4W H4X 0.8500 .
O4W H4Y 0.8500 .
O5W H5X 0.8500 .
O5W H5Y 0.8500 .
O6W H6X 0.8500 .
O6W H6Y 0.8500 .
O7W H7X 0.8500 .
O7W H7Y 0.8500 .
O8W H8X 0.8500 .
O8W H8Y 0.8499 .
O9W H9X 0.8499 .
O9W H9Y 0.8499 .
O10W H10X 0.8500 .
O10W H10Y 0.8500 .
O11W H11X 0.8500 .
O11W H11Y 0.8500 .
O12W H12X 0.8500 .
O12W H12Y 0.8500 .
O13W H13X 0.8499 .
O13W H13Y 0.8500 .
Pt1 N11 1.988(6) 2_666
Pt1 Pt2 3.1612(5) .
Pt2 N12 1.998(5) 2_666
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
N1 C1 C2 C3 0.7(9) . .
C1 C2 C3 C4 2.4(9) . .
C2 C3 C4 C5 -2.2(9) . .
C3 C4 C5 N1 -0.9(9) . .
C3 C4 C5 C6 179.1(6) . .
N1 C5 C6 N2 -1.7(8) . .
C4 C5 C6 N2 178.3(6) . .
N1 C5 C6 C7 176.6(6) . .
C4 C5 C6 C7 -3.5(10) . .
N2 C6 C7 C8 1.6(9) . .
C5 C6 C7 C8 -176.6(6) . .
C6 C7 C8 C9 4.3(10) . .
C7 C8 C9 C10 -9.9(10) . .
C8 C9 C10 N2 9.7(9) . .
N3 C11 C12 C13 1.2(11) . .
C11 C12 C13 C14 -7.1(10) . .
C12 C13 C14 C15 10.2(11) . .
C13 C14 C15 N3 -7.7(10) . .
C13 C14 C15 C16 169.1(7) . .
N3 C15 C16 N4 -3.4(9) . .
C14 C15 C16 N4 179.8(6) . .
N3 C15 C16 C17 175.8(7) . .
C14 C15 C16 C17 -1.1(11) . .
N4 C16 C17 C18 4.2(11) . .
C15 C16 C17 C18 -174.9(7) . .
C16 C17 C18 C19 -1.0(11) . .
C17 C18 C19 C20 -1.9(12) . .
C18 C19 C20 N4 1.7(12) . .
N5 C21 C22 C23 -1.4(8) . .
N5 C21 C22 C26 177.9(6) . .
C21 C22 C23 N6 2.0(7) . .
C26 C22 C23 N6 -177.2(6) . .
N7 C24 C25 C26 2.4(10) . .
C24 C25 C26 C27 -3.5(10) . .
C24 C25 C26 C22 -179.1(6) . .
C23 C22 C26 C25 3.1(11) . .
C21 C22 C26 C25 -176.0(7) . .
C23 C22 C26 C27 -172.1(7) . .
C21 C22 C26 C27 8.8(12) . .
C25 C26 C27 C28 5.7(10) . .
C22 C26 C27 C28 -179.0(6) . .
C26 C27 C28 N7 -6.8(10) . .
N8 C29 C30 C31 1.8(12) . .
C29 C30 C31 C32 -1.5(11) . .
C30 C31 C32 C33 2.6(11) . .
C31 C32 C33 N8 -4.3(11) . .
C31 C32 C33 C34 175.1(7) . .
N8 C33 C34 N9 -4.7(9) . .
C32 C33 C34 N9 176.0(7) . .
N8 C33 C34 C35 -179.4(6) . .
C32 C33 C34 C35 1.2(11) . .
N9 C34 C35 C36 12.4(10) . .
C33 C34 C35 C36 -173.2(7) . .
C34 C35 C36 C37 -11.0(10) . .
C35 C36 C37 C38 8.2(11) . .
C36 C37 C38 N9 -6.1(11) . .
N10 C39 C40 C41 -0.5(9) . .
C39 C40 C41 C42 -0.9(9) . .
C39 C40 C41 C45 -177.7(5) . .
C40 C41 C42 C43 1.5(9) . .
C45 C41 C42 C43 178.1(6) . .
C41 C42 C43 N10 -0.7(10) . .
N11 C44 C45 C46 -1.5(7) . .
N11 C44 C45 C41 -177.4(5) . .
C42 C41 C45 C44 173.7(6) . .
C40 C41 C45 C44 -9.8(9) . .
C42 C41 C45 C46 -1.2(10) . .
C40 C41 C45 C46 175.3(6) . .
C44 C45 C46 N12 0.3(7) . .
C41 C45 C46 N12 176.1(5) . .
C2 C1 N1 C5 -3.8(9) . .
C2 C1 N1 Pt1 178.9(4) . .
C4 C5 N1 C1 3.9(9) . .
C6 C5 N1 C1 -176.1(5) . .
C4 C5 N1 Pt1 -178.4(4) . .
C6 C5 N1 Pt1 1.6(6) . .
C7 C6 N2 C10 -1.1(9) . .
C5 C6 N2 C10 177.1(5) . .
C7 C6 N2 Pt1 -177.3(5) . .
C5 C6 N2 Pt1 1.0(7) . .
C9 C10 N2 C6 -4.4(9) . .
C9 C10 N2 Pt1 171.5(4) . .
C14 C15 N3 C11 1.4(9) . .
C16 C15 N3 C11 -175.5(6) . .
C14 C15 N3 Pt2 -179.8(5) . .
C16 C15 N3 Pt2 3.3(7) . .
C12 C11 N3 C15 1.7(10) . .
C12 C11 N3 Pt2 -176.9(5) . .
C17 C16 N4 C20 -4.4(11) . .
C15 C16 N4 C20 174.8(6) . .
C17 C16 N4 Pt2 -177.6(5) . .
C15 C16 N4 Pt2 1.6(8) . .
C19 C20 N4 C16 1.5(11) . .
C19 C20 N4 Pt2 173.9(5) . .
C22 C21 N5 N6 0.2(7) . .
C22 C21 N5 Pt2 178.8(5) . .
C22 C23 N6 N5 -1.9(6) . .
C22 C23 N6 Pt1 179.2(5) . .
C21 N5 N6 C23 1.0(6) . .
Pt2 N5 N6 C23 -177.9(4) . .
C21 N5 N6 Pt1 -179.8(4) . .
Pt2 N5 N6 Pt1 1.3(5) . .
C25 C24 N7 C28 -3.1(9) . .
C25 C24 N7 Pd1 -175.9(5) . .
C27 C28 N7 C24 5.4(10) . .
C27 C28 N7 Pd1 177.8(5) . .
C32 C33 N8 C29 4.3(10) . .
C34 C33 N8 C29 -175.1(6) . .
C32 C33 N8 Pd1 -175.7(6) . .
C34 C33 N8 Pd1 5.0(8) . .
C30 C29 N8 C33 -3.1(10) . .
C30 C29 N8 Pd1 176.9(6) . .
C35 C34 N9 C38 -9.5(9) . .
C33 C34 N9 C38 175.6(6) . .
C35 C34 N9 Pd1 177.0(5) . .
C33 C34 N9 Pd1 2.1(7) . .
C37 C38 N9 C34 6.8(10) . .
C37 C38 N9 Pd1 179.1(6) . .
C40 C39 N10 C43 1.3(8) . .
C40 C39 N10 Pd1 174.5(4) . .
C42 C43 N10 C39 -0.7(9) . .
C42 C43 N10 Pd1 -173.5(5) . .
C45 C44 N11 N12 2.2(7) . .
C45 C44 N11 Pt1 -173.2(4) . 2_666
C45 C46 N12 N11 1.0(6) . .
C45 C46 N12 Pt2 177.2(4) . 2_666
C44 N11 N12 C46 -2.0(6) . .
Pt1 N11 N12 C46 174.0(4) 2_666 .
C44 N11 N12 Pt2 -179.2(4) . 2_666
Pt1 N11 N12 Pt2 -3.2(5) 2_666 2_666
C33 N8 Pd1 N7 178.1(5) . .
C29 N8 Pd1 N7 -1.9(6) . .
C33 N8 Pd1 N9 -3.0(5) . .
C29 N8 Pd1 N9 177.0(6) . .
C33 N8 Pd1 N10 26(7) . .
C29 N8 Pd1 N10 -154(7) . .
C24 N7 Pd1 N8 89.4(5) . .
C28 N7 Pd1 N8 -83.1(5) . .
C24 N7 Pd1 N9 64(5) . .
C28 N7 Pd1 N9 -109(5) . .
C24 N7 Pd1 N10 -91.4(5) . .
C28 N7 Pd1 N10 96.1(5) . .
C34 N9 Pd1 N8 0.4(5) . .
C38 N9 Pd1 N8 -172.2(6) . .
C34 N9 Pd1 N7 26(5) . .
C38 N9 Pd1 N7 -146(5) . .
C34 N9 Pd1 N10 -178.8(5) . .
C38 N9 Pd1 N10 8.6(6) . .
C39 N10 Pd1 N8 73(7) . .
C43 N10 Pd1 N8 -115(7) . .
C39 N10 Pd1 N7 -79.8(4) . .
C43 N10 Pd1 N7 92.9(5) . .
C39 N10 Pd1 N9 101.3(4) . .
C43 N10 Pd1 N9 -86.0(5) . .
C23 N6 Pt1 N11 116.9(6) . 2_666
N5 N6 Pt1 N11 -62.0(4) . 2_666
C23 N6 Pt1 N2 -67(5) . .
N5 N6 Pt1 N2 114(5) . .
C23 N6 Pt1 N1 -62.0(6) . .
N5 N6 Pt1 N1 119.1(4) . .
C23 N6 Pt1 Pt2 178.1(6) . .
N5 N6 Pt1 Pt2 -0.8(3) . .
C6 N2 Pt1 N6 5(5) . .
C10 N2 Pt1 N6 -171(4) . .
C6 N2 Pt1 N11 -179.0(5) . 2_666
C10 N2 Pt1 N11 4.9(5) . 2_666
C6 N2 Pt1 N1 -0.1(4) . .
C10 N2 Pt1 N1 -176.2(5) . .
C6 N2 Pt1 Pt2 118.5(4) . .
C10 N2 Pt1 Pt2 -57.6(5) . .
C1 N1 Pt1 N6 -3.1(5) . .
C5 N1 Pt1 N6 179.4(4) . .
C1 N1 Pt1 N11 -138(8) . 2_666
C5 N1 Pt1 N11 45(8) . 2_666
C1 N1 Pt1 N2 176.6(5) . .
C5 N1 Pt1 N2 -0.8(4) . .
C1 N1 Pt1 Pt2 59.3(5) . .
C5 N1 Pt1 Pt2 -118.2(4) . .
C21 N5 Pt2 N12 -115.1(6) . 2_666
N6 N5 Pt2 N12 63.3(4) . 2_666
C21 N5 Pt2 N3 105(6) . .
N6 N5 Pt2 N3 -76(6) . .
C21 N5 Pt2 N4 68.0(6) . .
N6 N5 Pt2 N4 -113.6(4) . .
C21 N5 Pt2 Pt1 -179.3(7) . .
N6 N5 Pt2 Pt1 -0.8(3) . .
C15 N3 Pt2 N5 -39(6) . .
C11 N3 Pt2 N5 139(5) . .
C15 N3 Pt2 N12 -178.9(4) . 2_666
C11 N3 Pt2 N12 -0.2(6) . 2_666
C15 N3 Pt2 N4 -1.9(4) . .
C11 N3 Pt2 N4 176.8(6) . .
C15 N3 Pt2 Pt1 -113.8(4) . .
C11 N3 Pt2 Pt1 64.9(6) . .
C16 N4 Pt2 N5 178.6(5) . .
C20 N4 Pt2 N5 5.6(6) . .
C16 N4 Pt2 N12 47(3) . 2_666
C20 N4 Pt2 N12 -126(3) . 2_666
C16 N4 Pt2 N3 0.0(5) . .
C20 N4 Pt2 N3 -173.0(6) . .
C16 N4 Pt2 Pt1 113.9(5) . .
C20 N4 Pt2 Pt1 -59.1(6) . .
N6 Pt1 Pt2 N5 0.6(2) . .
N11 Pt1 Pt2 N5 99.5(2) 2_666 .
N2 Pt1 Pt2 N5 -176.6(2) . .
N1 Pt1 Pt2 N5 -81.0(2) . .
N6 Pt1 Pt2 N12 -97.5(2) . 2_666
N11 Pt1 Pt2 N12 1.4(2) 2_666 2_666
N2 Pt1 Pt2 N12 85.3(2) . 2_666
N1 Pt1 Pt2 N12 -179.1(2) . 2_666
N6 Pt1 Pt2 N3 178.2(2) . .
N11 Pt1 Pt2 N3 -83.0(2) 2_666 .
N2 Pt1 Pt2 N3 0.9(2) . .
N1 Pt1 Pt2 N3 96.5(2) . .
N6 Pt1 Pt2 N4 86.7(2) . .
N11 Pt1 Pt2 N4 -174.5(2) 2_666 .
N2 Pt1 Pt2 N4 -90.6(2) . .
N1 Pt1 Pt2 N4 5.0(2) . .
