#------------------------------------------------------------------------------
#$Date: 2025-08-22 00:26:11 +0300 (Fri, 22 Aug 2025) $
#$Revision: 301853 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/10/79/7107980.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7107980
loop_
_publ_author_name
'Michael Lipschutz'
'T.Don Tilley'
_publ_section_title
;
 Synthesis and reactivity of a conveniently prepared two-coordinate
 bis(amido) nickel(II) complex
;
_journal_name_full               Chem.Commun.
_journal_page_first              7146
_journal_paper_doi               10.1039/c2cc32974c
_journal_volume                  48
_journal_year                    2012
_chemical_formula_sum            'C37 H62 N4 Ni Si2'
_chemical_formula_weight         677.80
_chemical_name_common            Ni(N(SiMe3)(DIPP))2(DMAP)
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                84.922(2)
_cell_angle_beta                 74.854(2)
_cell_angle_gamma                69.522(2)
_cell_formula_units_Z            2
_cell_length_a                   10.5555(4)
_cell_length_b                   12.6703(5)
_cell_length_c                   16.2859(6)
_cell_measurement_reflns_used    9951
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      25.37
_cell_measurement_theta_min      2.59
_cell_volume                     1969.57(13)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    ORTEP-32
_computing_publication_material  WinGX
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    SIR-97
_diffrn_ambient_temperature      100(2)
_diffrn_detector_area_resol_mean 8.366
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  'QUAZAR multilayer mirrors'
_diffrn_radiation_source         'microfocus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0479
_diffrn_reflns_av_sigmaI/netI    0.0378
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            37916
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.40
_diffrn_reflns_theta_min         1.30
_exptl_absorpt_coefficient_mu    0.582
_exptl_absorpt_correction_T_max  0.9659
_exptl_absorpt_correction_T_min  0.9025
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    1.143
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             736
_exptl_crystal_size_max          0.18
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.06
_refine_diff_density_max         0.314
_refine_diff_density_min         -0.275
_refine_diff_density_rms         0.052
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.046
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     398
_refine_ls_number_reflns         7213
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.046
_refine_ls_R_factor_all          0.0423
_refine_ls_R_factor_gt           0.0333
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0336P)²+1.2003P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0788
_refine_ls_wR_factor_ref         0.0839
_reflns_number_gt                6101
_reflns_number_total             7213
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c2cc32974c.txt
_cod_data_source_block           shelxl_b
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7107980
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
C1 C 0.81270(18) 0.44646(16) 0.73955(12) 0.0151(4) Uani 1 1 d .
C2 C 0.78240(19) 0.49411(16) 0.66205(12) 0.0166(4) Uani 1 1 d .
C3 C 0.8215(2) 0.58625(17) 0.62839(13) 0.0221(5) Uani 1 1 d .
H3 H 0.8036 0.6167 0.5755 0.026 Uiso 1 1 calc R
C4 C 0.8859(2) 0.63405(17) 0.67036(14) 0.0248(5) Uani 1 1 d .
H4 H 0.9098 0.6980 0.6472 0.030 Uiso 1 1 calc R
C5 C 0.9151(2) 0.58873(17) 0.74592(13) 0.0226(5) Uani 1 1 d .
H5 H 0.9592 0.6223 0.7746 0.027 Uiso 1 1 calc R
C6 C 0.88179(19) 0.49463(16) 0.78156(12) 0.0177(4) Uani 1 1 d .
C7 C 0.9237(2) 0.44225(18) 0.86267(13) 0.0224(5) Uani 1 1 d .
H7 H 0.9402 0.3598 0.8600 0.027 Uiso 1 1 calc R
C8 C 0.8089(2) 0.4882(2) 0.94297(14) 0.0352(6) Uani 1 1 d .
H8A H 0.7219 0.4808 0.9378 0.053 Uiso 1 1 calc R
H8B H 0.7947 0.5679 0.9502 0.053 Uiso 1 1 calc R
H8C H 0.8363 0.4455 0.9924 0.053 Uiso 1 1 calc R
C9 C 1.0588(2) 0.4540(2) 0.87167(15) 0.0355(6) Uani 1 1 d .
H9A H 1.1331 0.4250 0.8203 0.053 Uiso 1 1 calc R
H9B H 1.0857 0.4110 0.9211 0.053 Uiso 1 1 calc R
H9C H 1.0442 0.5336 0.8794 0.053 Uiso 1 1 calc R
C10 C 0.7116(2) 0.44512(17) 0.61310(13) 0.0213(4) Uani 1 1 d .
H10 H 0.6839 0.3847 0.6489 0.026 Uiso 1 1 calc R
C11 C 0.8108(3) 0.3911(2) 0.52982(15) 0.0375(6) Uani 1 1 d .
H11A H 0.7625 0.3595 0.5001 0.056 Uiso 1 1 calc R
H11B H 0.8921 0.3308 0.5419 0.056 Uiso 1 1 calc R
H11C H 0.8416 0.4481 0.4939 0.056 Uiso 1 1 calc R
C12 C 0.5787(2) 0.5336(2) 0.59567(15) 0.0334(6) Uani 1 1 d .
H12A H 0.5155 0.5676 0.6495 0.050 Uiso 1 1 calc R
H12B H 0.5324 0.4974 0.5680 0.050 Uiso 1 1 calc R
H12C H 0.6033 0.5922 0.5584 0.050 Uiso 1 1 calc R
C13 C 0.6095(3) 0.2895(2) 0.93507(15) 0.0388(6) Uani 1 1 d .
H13A H 0.6626 0.2093 0.9239 0.058 Uiso 1 1 calc R
H13B H 0.5133 0.2986 0.9663 0.058 Uiso 1 1 calc R
H13C H 0.6528 0.3201 0.9691 0.058 Uiso 1 1 calc R
C14 C 0.5027(2) 0.3154(2) 0.77935(17) 0.0383(6) Uani 1 1 d .
H14A H 0.5498 0.2349 0.7664 0.057 Uiso 1 1 calc R
H14B H 0.4927 0.3572 0.7265 0.057 Uiso 1 1 calc R
H14C H 0.4101 0.3273 0.8176 0.057 Uiso 1 1 calc R
C15 C 0.5058(2) 0.51995(18) 0.85281(14) 0.0261(5) Uani 1 1 d .
H15A H 0.5544 0.5533 0.8810 0.039 Uiso 1 1 calc R
H15B H 0.4131 0.5281 0.8895 0.039 Uiso 1 1 calc R
H15C H 0.4962 0.5586 0.7988 0.039 Uiso 1 1 calc R
C16 C 1.16306(18) 0.02500(16) 0.75333(12) 0.0156(4) Uani 1 1 d .
C17 C 1.18296(19) -0.08026(17) 0.71897(12) 0.0183(4) Uani 1 1 d .
C18 C 1.2181(2) -0.17768(17) 0.76744(13) 0.0226(5) Uani 1 1 d .
H18 H 1.2313 -0.2479 0.7439 0.027 Uiso 1 1 calc R
C19 C 1.2343(2) -0.17509(18) 0.84861(13) 0.0252(5) Uani 1 1 d .
H19 H 1.2559 -0.2421 0.8812 0.030 Uiso 1 1 calc R
C20 C 1.2184(2) -0.07327(18) 0.88144(13) 0.0227(5) Uani 1 1 d .
H20 H 1.2306 -0.0712 0.9370 0.027 Uiso 1 1 calc R
C21 C 1.18497(19) 0.02673(17) 0.83551(12) 0.0178(4) Uani 1 1 d .
C22 C 1.1712(2) 0.13465(17) 0.87692(12) 0.0196(4) Uani 1 1 d .
H22 H 1.1551 0.1967 0.8343 0.023 Uiso 1 1 calc R
C23 C 1.0457(2) 0.16628(19) 0.95407(13) 0.0264(5) Uani 1 1 d .
H23A H 1.0378 0.2365 0.9791 0.040 Uiso 1 1 calc R
H23B H 1.0584 0.1060 0.9964 0.040 Uiso 1 1 calc R
H23C H 0.9604 0.1766 0.9361 0.040 Uiso 1 1 calc R
C24 C 1.3053(2) 0.1240(2) 0.90229(14) 0.0277(5) Uani 1 1 d .
H24A H 1.2939 0.1948 0.9280 0.042 Uiso 1 1 calc R
H24B H 1.3836 0.1075 0.8516 0.042 Uiso 1 1 calc R
H24C H 1.3240 0.0627 0.9435 0.042 Uiso 1 1 calc R
C25 C 1.1668(2) -0.09103(17) 0.63058(13) 0.0212(4) Uani 1 1 d .
H25 H 1.1225 -0.0136 0.6097 0.025 Uiso 1 1 calc R
C26 C 1.3096(2) -0.14428(19) 0.56900(13) 0.0270(5) Uani 1 1 d .
H26A H 1.2970 -0.1502 0.5123 0.040 Uiso 1 1 calc R
H26B H 1.3561 -0.2196 0.5892 0.040 Uiso 1 1 calc R
H26C H 1.3670 -0.0971 0.5662 0.040 Uiso 1 1 calc R
C27 C 1.0739(2) -0.16024(19) 0.62974(15) 0.0290(5) Uani 1 1 d .
H27A H 1.0655 -0.1639 0.5716 0.044 Uiso 1 1 calc R
H27B H 0.9812 -0.1245 0.6671 0.044 Uiso 1 1 calc R
H27C H 1.1156 -0.2366 0.6500 0.044 Uiso 1 1 calc R
C28 C 1.2220(2) 0.14880(19) 0.51790(13) 0.0273(5) Uani 1 1 d .
H28A H 1.2473 0.0676 0.5100 0.041 Uiso 1 1 calc R
H28B H 1.2887 0.1765 0.4763 0.041 Uiso 1 1 calc R
H28C H 1.1279 0.1876 0.5098 0.041 Uiso 1 1 calc R
C29 C 1.4105(2) 0.11327(19) 0.63643(14) 0.0252(5) Uani 1 1 d .
H29A H 1.4396 0.0310 0.6330 0.038 Uiso 1 1 calc R
H29B H 1.4181 0.1346 0.6909 0.038 Uiso 1 1 calc R
H29C H 1.4707 0.1407 0.5897 0.038 Uiso 1 1 calc R
C30 C 1.1758(2) 0.33259(17) 0.63517(14) 0.0263(5) Uani 1 1 d .
H30A H 1.0791 0.3682 0.6309 0.039 Uiso 1 1 calc R
H30B H 1.2376 0.3587 0.5885 0.039 Uiso 1 1 calc R
H30C H 1.1844 0.3529 0.6897 0.039 Uiso 1 1 calc R
C31 C 0.77700(19) 0.07916(17) 0.70365(12) 0.0184(4) Uani 1 1 d .
H31 H 0.7792 0.1240 0.6537 0.022 Uiso 1 1 calc R
C32 C 0.71069(19) 0.00184(16) 0.71210(12) 0.0180(4) Uani 1 1 d .
H32 H 0.6701 -0.0063 0.6684 0.022 Uiso 1 1 calc R
C33 C 0.70258(19) -0.06572(16) 0.78555(12) 0.0174(4) Uani 1 1 d .
C34 C 0.7717(2) -0.05019(17) 0.84461(12) 0.0199(4) Uani 1 1 d .
H34 H 0.7724 -0.0941 0.8950 0.024 Uiso 1 1 calc R
C35 C 0.8377(2) 0.02817(17) 0.82938(12) 0.0191(4) Uani 1 1 d .
H35 H 0.8854 0.0348 0.8697 0.023 Uiso 1 1 calc R
C36 C 0.5676(2) -0.16051(18) 0.73667(13) 0.0240(5) Uani 1 1 d .
H36A H 0.4735 -0.1048 0.7444 0.036 Uiso 1 1 calc R
H36B H 0.5618 -0.2364 0.7445 0.036 Uiso 1 1 calc R
H36C H 0.6231 -0.1538 0.6792 0.036 Uiso 1 1 calc R
C37 C 0.6117(2) -0.1963(2) 0.88066(14) 0.0305(5) Uani 1 1 d .
H37A H 0.5607 -0.2473 0.8791 0.046 Uiso 1 1 calc R
H37B H 0.5574 -0.1397 0.9254 0.046 Uiso 1 1 calc R
H37C H 0.7021 -0.2395 0.8925 0.046 Uiso 1 1 calc R
N1 N 0.77764(16) 0.34910(13) 0.77341(9) 0.0142(3) Uani 1 1 d .
N2 N 1.11697(16) 0.12859(13) 0.70918(10) 0.0143(3) Uani 1 1 d .
N3 N 0.83948(16) 0.09611(13) 0.76127(10) 0.0165(4) Uani 1 1 d .
N4 N 0.63375(17) -0.14040(14) 0.79892(10) 0.0209(4) Uani 1 1 d .
Si1 Si 0.60876(6) 0.36673(5) 0.83206(3) 0.01956(13) Uani 1 1 d .
Si2 Si 1.22606(5) 0.17689(5) 0.62844(3) 0.01619(13) Uani 1 1 d .
Ni1 Ni 0.92785(2) 0.21704(2) 0.739895(15) 0.01383(8) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ni Ni 0.3393 1.1124 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
C2 C1 C6 118.92(17)
C2 C1 N1 120.18(17)
C6 C1 N1 120.88(16)
C3 C2 C1 119.53(18)
C3 C2 C10 118.94(17)
C1 C2 C10 121.51(17)
C4 C3 C2 121.25(19)
C4 C3 H3 119.4
C2 C3 H3 119.4
C5 C4 C3 119.65(19)
C5 C4 H4 120.2
C3 C4 H4 120.2
C4 C5 C6 121.65(19)
C4 C5 H5 119.2
C6 C5 H5 119.2
C5 C6 C1 118.96(18)
C5 C6 C7 120.24(18)
C1 C6 C7 120.76(17)
C6 C7 C8 112.76(17)
C6 C7 C9 113.63(18)
C8 C7 C9 108.91(18)
C6 C7 H7 107.1
C8 C7 H7 107.1
C9 C7 H7 107.1
C7 C8 H8A 109.5
C7 C8 H8B 109.5
H8A C8 H8B 109.5
C7 C8 H8C 109.5
H8A C8 H8C 109.5
H8B C8 H8C 109.5
C7 C9 H9A 109.5
C7 C9 H9B 109.5
H9A C9 H9B 109.5
C7 C9 H9C 109.5
H9A C9 H9C 109.5
H9B C9 H9C 109.5
C2 C10 C11 111.42(17)
C2 C10 C12 112.07(17)
C11 C10 C12 110.06(18)
C2 C10 H10 107.7
C11 C10 H10 107.7
C12 C10 H10 107.7
C10 C11 H11A 109.5
C10 C11 H11B 109.5
H11A C11 H11B 109.5
C10 C11 H11C 109.5
H11A C11 H11C 109.5
H11B C11 H11C 109.5
C10 C12 H12A 109.5
C10 C12 H12B 109.5
H12A C12 H12B 109.5
C10 C12 H12C 109.5
H12A C12 H12C 109.5
H12B C12 H12C 109.5
Si1 C13 H13A 109.5
Si1 C13 H13B 109.5
H13A C13 H13B 109.5
Si1 C13 H13C 109.5
H13A C13 H13C 109.5
H13B C13 H13C 109.5
Si1 C14 H14A 109.5
Si1 C14 H14B 109.5
H14A C14 H14B 109.5
Si1 C14 H14C 109.5
H14A C14 H14C 109.5
H14B C14 H14C 109.5
Si1 C15 H15A 109.5
Si1 C15 H15B 109.5
H15A C15 H15B 109.5
Si1 C15 H15C 109.5
H15A C15 H15C 109.5
H15B C15 H15C 109.5
C17 C16 C21 118.33(17)
C17 C16 N2 122.02(17)
C21 C16 N2 119.60(17)
C18 C17 C16 119.57(18)
C18 C17 C25 118.29(18)
C16 C17 C25 122.14(17)
C19 C18 C17 121.91(19)
C19 C18 H18 119.0
C17 C18 H18 119.0
C20 C19 C18 118.68(19)
C20 C19 H19 120.7
C18 C19 H19 120.7
C19 C20 C21 121.95(19)
C19 C20 H20 119.0
C21 C20 H20 119.0
C20 C21 C16 119.49(18)
C20 C21 C22 118.01(18)
C16 C21 C22 122.49(17)
C21 C22 C23 110.84(17)
C21 C22 C24 111.25(17)
C23 C22 C24 110.63(16)
C21 C22 H22 108.0
C23 C22 H22 108.0
C24 C22 H22 108.0
C22 C23 H23A 109.5
C22 C23 H23B 109.5
H23A C23 H23B 109.5
C22 C23 H23C 109.5
H23A C23 H23C 109.5
H23B C23 H23C 109.5
C22 C24 H24A 109.5
C22 C24 H24B 109.5
H24A C24 H24B 109.5
C22 C24 H24C 109.5
H24A C24 H24C 109.5
H24B C24 H24C 109.5
C17 C25 C27 112.47(17)
C17 C25 C26 110.75(16)
C27 C25 C26 109.24(17)
C17 C25 H25 108.1
C27 C25 H25 108.1
C26 C25 H25 108.1
C25 C26 H26A 109.5
C25 C26 H26B 109.5
H26A C26 H26B 109.5
C25 C26 H26C 109.5
H26A C26 H26C 109.5
H26B C26 H26C 109.5
C25 C27 H27A 109.5
C25 C27 H27B 109.5
H27A C27 H27B 109.5
C25 C27 H27C 109.5
H27A C27 H27C 109.5
H27B C27 H27C 109.5
Si2 C28 H28A 109.5
Si2 C28 H28B 109.5
H28A C28 H28B 109.5
Si2 C28 H28C 109.5
H28A C28 H28C 109.5
H28B C28 H28C 109.5
Si2 C29 H29A 109.5
Si2 C29 H29B 109.5
H29A C29 H29B 109.5
Si2 C29 H29C 109.5
H29A C29 H29C 109.5
H29B C29 H29C 109.5
Si2 C30 H30A 109.5
Si2 C30 H30B 109.5
H30A C30 H30B 109.5
Si2 C30 H30C 109.5
H30A C30 H30C 109.5
H30B C30 H30C 109.5
N3 C31 C32 124.58(18)
N3 C31 H31 117.7
C32 C31 H31 117.7
C31 C32 C33 120.04(18)
C31 C32 H32 120.0
C33 C32 H32 120.0
N4 C33 C32 122.66(18)
N4 C33 C34 122.09(18)
C32 C33 C34 115.25(17)
C35 C34 C33 120.18(18)
C35 C34 H34 119.9
C33 C34 H34 119.9
N3 C35 C34 124.33(18)
N3 C35 H35 117.8
C34 C35 H35 117.8
N4 C36 H36A 109.5
N4 C36 H36B 109.5
H36A C36 H36B 109.5
N4 C36 H36C 109.5
H36A C36 H36C 109.5
H36B C36 H36C 109.5
N4 C37 H37A 109.5
N4 C37 H37B 109.5
H37A C37 H37B 109.5
N4 C37 H37C 109.5
H37A C37 H37C 109.5
H37B C37 H37C 109.5
C1 N1 Si1 119.08(12)
C1 N1 Ni1 111.26(11)
Si1 N1 Ni1 129.56(9)
C16 N2 Si2 123.71(12)
C16 N2 Ni1 118.41(11)
Si2 N2 Ni1 117.89(8)
C35 N3 C31 115.51(16)
C35 N3 Ni1 125.24(13)
C31 N3 Ni1 119.24(13)
C33 N4 C37 120.37(17)
C33 N4 C36 122.39(17)
C37 N4 C36 116.98(16)
N1 Si1 C13 110.85(9)
N1 Si1 C15 110.52(9)
C13 Si1 C15 109.72(10)
N1 Si1 C14 115.41(9)
C13 Si1 C14 105.64(12)
C15 Si1 C14 104.35(11)
N2 Si2 C30 110.48(9)
N2 Si2 C29 110.73(9)
C30 Si2 C29 107.84(10)
N2 Si2 C28 114.83(9)
C30 Si2 C28 105.09(10)
C29 Si2 C28 107.51(10)
N1 Ni1 N2 155.07(7)
N1 Ni1 N3 103.71(6)
N2 Ni1 N3 100.47(6)
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
C1 C2 1.414(3)
C1 C6 1.421(3)
C1 N1 1.434(2)
C2 C3 1.393(3)
C2 C10 1.517(3)
C3 C4 1.378(3)
C3 H3 0.9500
C4 C5 1.374(3)
C4 H4 0.9500
C5 C6 1.395(3)
C5 H5 0.9500
C6 C7 1.525(3)
C7 C8 1.527(3)
C7 C9 1.530(3)
C7 H7 1.0000
C8 H8A 0.9800
C8 H8B 0.9800
C8 H8C 0.9800
C9 H9A 0.9800
C9 H9B 0.9800
C9 H9C 0.9800
C10 C11 1.525(3)
C10 C12 1.535(3)
C10 H10 1.0000
C11 H11A 0.9800
C11 H11B 0.9800
C11 H11C 0.9800
C12 H12A 0.9800
C12 H12B 0.9800
C12 H12C 0.9800
C13 Si1 1.866(2)
C13 H13A 0.9800
C13 H13B 0.9800
C13 H13C 0.9800
C14 Si1 1.878(2)
C14 H14A 0.9800
C14 H14B 0.9800
C14 H14C 0.9800
C15 Si1 1.874(2)
C15 H15A 0.9800
C15 H15B 0.9800
C15 H15C 0.9800
C16 C17 1.418(3)
C16 C21 1.420(3)
C16 N2 1.430(2)
C17 C18 1.395(3)
C17 C25 1.516(3)
C18 C19 1.381(3)
C18 H18 0.9500
C19 C20 1.379(3)
C19 H19 0.9500
C20 C21 1.395(3)
C20 H20 0.9500
C21 C22 1.522(3)
C22 C23 1.530(3)
C22 C24 1.535(3)
C22 H22 1.0000
C23 H23A 0.9800
C23 H23B 0.9800
C23 H23C 0.9800
C24 H24A 0.9800
C24 H24B 0.9800
C24 H24C 0.9800
C25 C27 1.530(3)
C25 C26 1.533(3)
C25 H25 1.0000
C26 H26A 0.9800
C26 H26B 0.9800
C26 H26C 0.9800
C27 H27A 0.9800
C27 H27B 0.9800
C27 H27C 0.9800
C28 Si2 1.880(2)
C28 H28A 0.9800
C28 H28B 0.9800
C28 H28C 0.9800
C29 Si2 1.863(2)
C29 H29A 0.9800
C29 H29B 0.9800
C29 H29C 0.9800
C30 Si2 1.860(2)
C30 H30A 0.9800
C30 H30B 0.9800
C30 H30C 0.9800
C31 N3 1.349(2)
C31 C32 1.369(3)
C31 H31 0.9500
C32 C33 1.410(3)
C32 H32 0.9500
C33 N4 1.354(2)
C33 C34 1.413(3)
C34 C35 1.372(3)
C34 H34 0.9500
C35 N3 1.343(2)
C35 H35 0.9500
C36 N4 1.456(3)
C36 H36A 0.9800
C36 H36B 0.9800
C36 H36C 0.9800
C37 N4 1.454(3)
C37 H37A 0.9800
C37 H37B 0.9800
C37 H37C 0.9800
N1 Si1 1.7347(16)
N1 Ni1 1.8614(15)
N2 Si2 1.7289(16)
N2 Ni1 1.8717(15)
N3 Ni1 2.0187(16)
loop_
_cod_related_entry_id
_cod_related_entry_database
_cod_related_entry_code
1 PubChem 139182611
