#------------------------------------------------------------------------------
#$Date: 2016-03-26 03:43:34 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180193 $
#$URL: svn://www.crystallography.net/cod/cif/7/10/89/7108919.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7108919
loop_
_publ_author_name
'Dong-Bin Dang'
'Bing An'
'Yan Bai'
'Guang-Shui Zheng'
'Jing-Yang Niu'
_publ_section_title
;
 Three-dimensional homochiral manganese-lanthanide frameworks based on
 chiral camphorates with multi-coordination modes
;
_journal_issue                   22
_journal_name_full
'Chemical communications (Cambridge, England)'
_journal_page_first              2243
_journal_page_last               2245
_journal_paper_doi               10.1039/c3cc37680j
_journal_volume                  49
_journal_year                    2013
_chemical_formula_sum            'C40 H51 Eu Mn N2 O12'
_chemical_formula_weight         958.73
_chemical_name_systematic
;
?
;
_space_group_IT_number           19
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_Hall  'P 2ac 2ab'
_symmetry_space_group_name_H-M   'P 21 21 21'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   12.6092(13)
_cell_length_b                   13.0311(12)
_cell_length_c                   24.203(2)
_cell_measurement_reflns_used    377
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      13.11
_cell_measurement_theta_min      2.30
_cell_volume                     3976.8(6)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0612
_diffrn_reflns_av_sigmaI/netI    0.0777
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       26
_diffrn_reflns_limit_l_min       -28
_diffrn_reflns_number            20347
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         1.77
_exptl_absorpt_coefficient_mu    1.945
_exptl_absorpt_correction_T_max  0.8599
_exptl_absorpt_correction_T_min  0.8001
_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.601
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1956
_exptl_crystal_size_max          0.12
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.08
_refine_diff_density_max         0.690
_refine_diff_density_min         -0.779
_refine_diff_density_rms         0.094
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   0.000(16)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.034
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     505
_refine_ls_number_reflns         7010
_refine_ls_number_restraints     60
_refine_ls_restrained_S_all      1.062
_refine_ls_R_factor_all          0.0571
_refine_ls_R_factor_gt           0.0431
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0409P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0962
_refine_ls_wR_factor_ref         0.1018
_reflns_number_gt                5926
_reflns_number_total             7010
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c3cc37680j.txt
_cod_data_source_block           ddb3
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Orthorhombic' changed to
'orthorhombic' according to
/usr/data/users/saulius/automatic-downloads/retrospective/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 2281 2013-09-26 08:29:07Z andrius 
;
_cod_original_cell_volume        3976.9(7)
_cod_original_sg_symbol_H-M      P2(1)2(1)2(1)
_cod_database_code               7108919
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'-x, y+1/2, -z+1/2'
'x+1/2, -y+1/2, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Eu1 Eu 0.74251(2) 0.89551(2) 0.150387(13) 0.02878(10) Uani 1 1 d .
Mn1 Mn 0.62473(9) 1.01855(8) 0.02453(5) 0.0352(3) Uani 1 1 d .
O1 O 1.0900(4) 0.6352(4) -0.0073(2) 0.0485(14) Uani 1 1 d .
O2 O 1.1161(4) 0.6824(4) -0.0929(2) 0.0490(14) Uani 1 1 d .
O3 O 0.7744(5) 1.0179(4) -0.0196(2) 0.0546(15) Uani 1 1 d .
O4 O 0.7943(4) 0.9501(4) 0.0620(2) 0.0369(12) Uani 1 1 d .
C1 C 1.0941(5) 0.7024(6) -0.0437(3) 0.0379(18) Uani 1 1 d .
C2 C 0.8313(6) 0.9730(6) 0.0145(3) 0.0346(17) Uani 1 1 d .
C3 C 1.0697(6) 0.8158(5) -0.0286(3) 0.0360(17) Uani 1 1 d .
C4 C 0.9504(6) 0.8423(5) -0.0343(3) 0.0357(17) Uani 1 1 d .
C5 C 0.9429(6) 0.9432(6) -0.0002(3) 0.0378(18) Uani 1 1 d .
H5A H 0.9714 0.9981 -0.0236 0.045 Uiso 1 1 calc R
C6 C 1.0190(6) 0.9303(7) 0.0478(4) 0.054(2) Uani 1 1 d .
H6A H 0.9803 0.9186 0.0818 0.065 Uiso 1 1 calc R
H6B H 1.0623 0.9913 0.0521 0.065 Uiso 1 1 calc R
C7 C 1.0887(7) 0.8370(6) 0.0338(3) 0.047(2) Uani 1 1 d .
H7A H 1.0682 0.7781 0.0559 0.057 Uiso 1 1 calc R
H7B H 1.1629 0.8521 0.0408 0.057 Uiso 1 1 calc R
C8 C 1.1435(6) 0.8849(6) -0.0626(4) 0.053(2) Uani 1 1 d .
H8A H 1.1333 0.8712 -0.1013 0.080 Uiso 1 1 calc R
H8B H 1.2158 0.8711 -0.0528 0.080 Uiso 1 1 calc R
H8C H 1.1274 0.9555 -0.0552 0.080 Uiso 1 1 calc R
C9 C 0.8775(6) 0.7606(6) -0.0095(3) 0.047(2) Uani 1 1 d .
H9A H 0.8968 0.7489 0.0283 0.070 Uiso 1 1 calc R
H9B H 0.8847 0.6979 -0.0300 0.070 Uiso 1 1 calc R
H9C H 0.8053 0.7838 -0.0113 0.070 Uiso 1 1 calc R
C10 C 0.9165(8) 0.8581(7) -0.0954(3) 0.061(3) Uani 1 1 d .
H10A H 0.8424 0.8748 -0.0969 0.092 Uiso 1 1 calc R
H10B H 0.9292 0.7962 -0.1158 0.092 Uiso 1 1 calc R
H10C H 0.9569 0.9132 -0.1112 0.092 Uiso 1 1 calc R
O5 O 0.8822(6) 0.7683(5) 0.1372(3) 0.085(2) Uani 1 1 d .
O6 O 0.7710(6) 0.7368(5) 0.1982(3) 0.089(2) Uani 1 1 d U
O7 O 1.1040(5) 0.5046(5) 0.3246(3) 0.072(2) Uani 1 1 d .
O8 O 1.2014(5) 0.4582(7) 0.2574(3) 0.090(3) Uani 1 1 d .
C11 C 0.8499(8) 0.7114(7) 0.1731(4) 0.064(2) Uani 1 1 d U
C12 C 1.1143(7) 0.4909(6) 0.2749(3) 0.046(2) Uani 1 1 d .
C13 C 0.8992(6) 0.6057(6) 0.1834(3) 0.0454(19) Uani 1 1 d .
C14 C 1.0149(6) 0.6119(6) 0.2060(3) 0.0396(17) Uani 1 1 d .
C15 C 1.0249(6) 0.5040(6) 0.2346(4) 0.048(2) Uani 1 1 d .
H15A H 1.0354 0.4533 0.2052 0.058 Uiso 1 1 calc R
C16 C 0.9180(8) 0.4837(10) 0.2595(5) 0.094(4) Uani 1 1 d U
H16A H 0.9180 0.5017 0.2984 0.113 Uiso 1 1 calc R
H16B H 0.8999 0.4116 0.2560 0.113 Uiso 1 1 calc R
C17 C 0.8390(8) 0.5492(8) 0.2283(5) 0.087(4) Uani 1 1 d .
H17A H 0.8055 0.5978 0.2531 0.104 Uiso 1 1 calc R
H17B H 0.7843 0.5064 0.2120 0.104 Uiso 1 1 calc R
C18 C 0.8905(9) 0.5471(8) 0.1293(5) 0.093(4) Uani 1 1 d .
H18A H 0.8180 0.5465 0.1173 0.140 Uiso 1 1 calc R
H18B H 0.9145 0.4779 0.1347 0.140 Uiso 1 1 calc R
H18C H 0.9336 0.5799 0.1018 0.140 Uiso 1 1 calc R
C19 C 1.0272(9) 0.6985(7) 0.2468(4) 0.071(3) Uani 1 1 d .
H19A H 1.0216 0.7629 0.2278 0.106 Uiso 1 1 calc R
H19B H 1.0953 0.6938 0.2644 0.106 Uiso 1 1 calc R
H19C H 0.9724 0.6939 0.2743 0.106 Uiso 1 1 calc R
C20 C 1.0997(8) 0.6270(8) 0.1620(4) 0.079(3) Uani 1 1 d .
H20A H 1.0921 0.6938 0.1458 0.118 Uiso 1 1 calc R
H20B H 1.0919 0.5756 0.1339 0.118 Uiso 1 1 calc R
H20C H 1.1686 0.6211 0.1786 0.118 Uiso 1 1 calc R
O9 O 0.6285(5) 0.9198(5) 0.2975(2) 0.0684(19) Uani 1 1 d .
O10 O 0.5909(4) 0.8706(4) 0.2123(2) 0.0430(13) Uani 1 1 d .
O11 O 0.3481(4) 0.6572(4) 0.4274(2) 0.0425(13) Uani 1 1 d .
O12 O 0.3560(4) 0.5468(4) 0.3591(2) 0.0506(15) Uani 1 1 d .
C21 C 0.5632(6) 0.8807(6) 0.2605(3) 0.0417(19) Uani 1 1 d .
C22 C 0.3534(5) 0.6373(6) 0.3772(3) 0.0342(18) Uani 1 1 d .
C23 C 0.4571(7) 0.8461(6) 0.2805(3) 0.043(2) Uani 1 1 d .
C24 C 0.4608(7) 0.7333(7) 0.3024(4) 0.061(3) Uani 1 1 d .
C25 C 0.3552(6) 0.7271(5) 0.3357(3) 0.0375(18) Uani 1 1 d .
H25A H 0.2985 0.7144 0.3089 0.045 Uiso 1 1 calc R
C26 C 0.3342(8) 0.8310(6) 0.3608(4) 0.074(3) Uani 1 1 d .
H26A H 0.3473 0.8305 0.4003 0.089 Uiso 1 1 calc R
H26B H 0.2618 0.8528 0.3541 0.089 Uiso 1 1 calc R
C27 C 0.4159(7) 0.9026(7) 0.3298(4) 0.062(2) Uani 1 1 d .
H27A H 0.3812 0.9655 0.3182 0.074 Uiso 1 1 calc R
H27B H 0.4739 0.9204 0.3543 0.074 Uiso 1 1 calc R
C28 C 0.3752(8) 0.8569(9) 0.2337(4) 0.076(3) Uani 1 1 d .
H28A H 0.3737 0.9267 0.2212 0.114 Uiso 1 1 calc R
H28B H 0.3063 0.8379 0.2472 0.114 Uiso 1 1 calc R
H28C H 0.3946 0.8127 0.2036 0.114 Uiso 1 1 calc R
C29 C 0.4588(10) 0.6537(9) 0.2532(5) 0.092(4) Uani 1 1 d U
H29A H 0.5238 0.6584 0.2327 0.139 Uiso 1 1 calc R
H29B H 0.4001 0.6688 0.2293 0.139 Uiso 1 1 calc R
H29C H 0.4512 0.5855 0.2677 0.139 Uiso 1 1 calc R
C30 C 0.5558(7) 0.7129(8) 0.3367(5) 0.092(4) Uani 1 1 d .
H30A H 0.6182 0.7169 0.3140 0.138 Uiso 1 1 calc R
H30B H 0.5507 0.6456 0.3526 0.138 Uiso 1 1 calc R
H30C H 0.5602 0.7630 0.3657 0.138 Uiso 1 1 calc R
N1 N 0.4508(6) 1.0398(6) 0.0443(4) 0.061(2) Uani 1 1 d .
N2 N 0.5559(7) 1.1203(6) -0.0417(4) 0.069(2) Uani 1 1 d .
C31 C 0.4009(8) 0.9909(8) 0.0835(5) 0.080(4) Uani 1 1 d .
H31A H 0.4392 0.9415 0.1027 0.096 Uiso 1 1 calc R
C32 C 0.2949(10) 1.0059(10) 0.0993(5) 0.100(4) Uani 1 1 d U
H32A H 0.2602 0.9699 0.1271 0.120 Uiso 1 1 calc R
C33 C 0.2500(12) 1.0821(11) 0.0673(6) 0.113(4) Uani 1 1 d U
H33A H 0.1801 1.0989 0.0756 0.135 Uiso 1 1 calc R
C34 C 0.2945(10) 1.1355(10) 0.0255(6) 0.100(4) Uani 1 1 d U
H34A H 0.2574 1.1844 0.0052 0.120 Uiso 1 1 calc R
C35 C 0.4004(7) 1.1115(9) 0.0151(5) 0.082(4) Uani 1 1 d .
C36 C 0.4609(10) 1.1591(8) -0.0295(5) 0.078(3) Uani 1 1 d U
C37 C 0.4230(11) 1.2471(9) -0.0637(5) 0.094(4) Uani 1 1 d U
H37A H 0.3583 1.2792 -0.0573 0.113 Uiso 1 1 calc R
C38 C 0.4866(14) 1.2761(11) -0.1033(6) 0.113(5) Uani 1 1 d U
H38A H 0.4655 1.3334 -0.1234 0.136 Uiso 1 1 calc R
C39 C 0.5763(13) 1.2343(10) -0.1180(5) 0.107(4) Uani 1 1 d U
H39A H 0.6133 1.2553 -0.1492 0.129 Uiso 1 1 calc R
C40 C 0.6128(12) 1.1564(8) -0.0839(5) 0.087(4) Uani 1 1 d .
H40A H 0.6793 1.1283 -0.0908 0.104 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Mn Mn 0.3368 0.7283 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O12 Eu1 O2 86.9(2) 3_655 4_465
O12 Eu1 O4 78.64(18) 3_655 .
O2 Eu1 O4 77.28(17) 4_465 .
O12 Eu1 O6 148.6(2) 3_655 .
O2 Eu1 O6 90.8(3) 4_465 .
O4 Eu1 O6 131.3(2) . .
O12 Eu1 O5 160.4(2) 3_655 .
O2 Eu1 O5 96.8(2) 4_465 .
O4 Eu1 O5 83.44(19) . .
O6 Eu1 O5 50.9(2) . .
O12 Eu1 O10 75.97(18) 3_655 .
O2 Eu1 O10 77.00(17) 4_465 .
O4 Eu1 O10 144.51(17) . .
O6 Eu1 O10 73.0(2) . .
O5 Eu1 O10 123.6(2) . .
O12 Eu1 O7 87.4(2) 3_655 3_755
O2 Eu1 O7 157.6(2) 4_465 3_755
O4 Eu1 O7 80.33(19) . 3_755
O6 Eu1 O7 105.1(3) . 3_755
O5 Eu1 O7 81.8(3) . 3_755
O10 Eu1 O7 122.4(2) . 3_755
O12 Eu1 O8 87.8(3) 3_655 3_755
O2 Eu1 O8 150.44(19) 4_465 3_755
O4 Eu1 O8 129.89(19) . 3_755
O6 Eu1 O8 78.9(3) . 3_755
O5 Eu1 O8 97.8(3) . 3_755
O10 Eu1 O8 73.50(19) . 3_755
O7 Eu1 O8 50.8(2) 3_755 3_755
O12 Eu1 C11 173.7(2) 3_655 .
O2 Eu1 C11 94.2(3) 4_465 .
O4 Eu1 C11 107.7(2) . .
O6 Eu1 C11 25.4(2) . .
O5 Eu1 C11 25.5(2) . .
O10 Eu1 C11 98.2(2) . .
O7 Eu1 C11 93.8(3) 3_755 .
O8 Eu1 C11 88.1(3) 3_755 .
O12 Eu1 C12 91.8(2) 3_655 3_755
O2 Eu1 C12 176.5(2) 4_465 3_755
O4 Eu1 C12 105.7(2) . 3_755
O6 Eu1 C12 88.6(3) . 3_755
O5 Eu1 C12 85.5(3) . 3_755
O10 Eu1 C12 99.5(2) . 3_755
O7 Eu1 C12 25.4(2) 3_755 3_755
O8 Eu1 C12 26.1(2) 3_755 3_755
C11 Eu1 C12 86.7(3) . 3_755
O12 Eu1 Mn1 49.47(15) 3_655 .
O2 Eu1 Mn1 55.57(14) 4_465 .
O4 Eu1 Mn1 40.53(11) . .
O6 Eu1 Mn1 145.2(2) . .
O5 Eu1 Mn1 118.05(17) . .
O10 Eu1 Mn1 104.14(13) . .
O7 Eu1 Mn1 105.25(16) 3_755 .
O8 Eu1 Mn1 134.7(2) 3_755 .
C11 Eu1 Mn1 135.7(2) . .
C12 Eu1 Mn1 125.55(17) 3_755 .
O1 Mn1 O3 94.6(2) 4_465 .
O1 Mn1 O11 159.2(2) 4_465 3_655
O3 Mn1 O11 97.4(2) . 3_655
O1 Mn1 N2 109.9(2) 4_465 .
O3 Mn1 N2 89.3(3) . .
O11 Mn1 N2 87.2(2) 3_655 .
O1 Mn1 N1 87.5(2) 4_465 .
O3 Mn1 N1 161.6(3) . .
O11 Mn1 N1 86.4(2) 3_655 .
N2 Mn1 N1 72.8(4) . .
O1 Mn1 O4 84.81(19) 4_465 .
O3 Mn1 O4 55.28(18) . .
O11 Mn1 O4 88.14(18) 3_655 .
N2 Mn1 O4 143.3(3) . .
N1 Mn1 O4 143.1(3) . .
O1 Mn1 Eu1 80.55(15) 4_465 .
O3 Mn1 Eu1 93.09(15) . .
O11 Mn1 Eu1 81.86(14) 3_655 .
N2 Mn1 Eu1 169.07(19) . .
N1 Mn1 Eu1 105.3(2) . .
O4 Mn1 Eu1 37.81(11) . .
C1 O1 Mn1 121.6(5) . 4_565
C1 O2 Eu1 143.7(5) . 4_565
C2 O3 Mn1 100.1(4) . .
C2 O4 Eu1 173.6(5) . .
C2 O4 Mn1 84.4(4) . .
Eu1 O4 Mn1 101.66(17) . .
O1 C1 O2 122.6(7) . .
O1 C1 C3 119.7(7) . .
O2 C1 C3 117.8(7) . .
O3 C2 O4 120.0(7) . .
O3 C2 C5 120.3(7) . .
O4 C2 C5 119.7(7) . .
C8 C3 C4 114.2(6) . .
C8 C3 C1 108.2(6) . .
C4 C3 C1 112.5(6) . .
C8 C3 C7 109.0(7) . .
C4 C3 C7 101.3(5) . .
C1 C3 C7 111.6(6) . .
C9 C4 C3 113.2(6) . .
C9 C4 C10 107.5(7) . .
C3 C4 C10 112.4(6) . .
C9 C4 C5 110.1(6) . .
C3 C4 C5 101.5(6) . .
C10 C4 C5 112.1(6) . .
C2 C5 C6 116.1(6) . .
C2 C5 C4 113.7(6) . .
C6 C5 C4 105.9(6) . .
C2 C5 H5A 106.9 . .
C6 C5 H5A 106.9 . .
C4 C5 H5A 106.9 . .
C5 C6 C7 106.3(6) . .
C5 C6 H6A 110.5 . .
C7 C6 H6A 110.5 . .
C5 C6 H6B 110.5 . .
C7 C6 H6B 110.5 . .
H6A C6 H6B 108.7 . .
C6 C7 C3 105.4(6) . .
C6 C7 H7A 110.7 . .
C3 C7 H7A 110.7 . .
C6 C7 H7B 110.7 . .
C3 C7 H7B 110.7 . .
H7A C7 H7B 108.8 . .
C3 C8 H8A 109.5 . .
C3 C8 H8B 109.5 . .
H8A C8 H8B 109.5 . .
C3 C8 H8C 109.5 . .
H8A C8 H8C 109.5 . .
H8B C8 H8C 109.5 . .
C4 C9 H9A 109.5 . .
C4 C9 H9B 109.5 . .
H9A C9 H9B 109.5 . .
C4 C9 H9C 109.5 . .
H9A C9 H9C 109.5 . .
H9B C9 H9C 109.5 . .
C4 C10 H10A 109.5 . .
C4 C10 H10B 109.5 . .
H10A C10 H10B 109.5 . .
C4 C10 H10C 109.5 . .
H10A C10 H10C 109.5 . .
H10B C10 H10C 109.5 . .
C11 O5 Eu1 94.5(5) . .
C11 O6 Eu1 96.7(6) . .
C12 O7 Eu1 94.3(5) . 3_745
C12 O8 Eu1 93.3(5) . 3_745
O6 C11 O5 117.9(8) . .
O6 C11 C13 119.9(8) . .
O5 C11 C13 122.0(8) . .
O6 C11 Eu1 57.9(5) . .
O5 C11 Eu1 60.0(4) . .
C13 C11 Eu1 174.6(7) . .
O7 C12 O8 118.3(8) . .
O7 C12 C15 123.0(8) . .
O8 C12 C15 118.5(8) . .
O7 C12 Eu1 60.3(4) . 3_745
O8 C12 Eu1 60.6(4) . 3_745
C15 C12 Eu1 160.2(6) . 3_745
C17 C13 C18 109.7(9) . .
C17 C13 C11 110.5(7) . .
C18 C13 C11 106.4(7) . .
C17 C13 C14 104.0(6) . .
C18 C13 C14 113.3(7) . .
C11 C13 C14 113.0(7) . .
C19 C14 C20 106.9(8) . .
C19 C14 C13 111.4(7) . .
C20 C14 C13 114.7(7) . .
C19 C14 C15 111.9(7) . .
C20 C14 C15 111.5(7) . .
C13 C14 C15 100.5(6) . .
C16 C15 C12 113.1(8) . .
C16 C15 C14 105.2(7) . .
C12 C15 C14 116.6(7) . .
C16 C15 H15A 107.1 . .
C12 C15 H15A 107.1 . .
C14 C15 H15A 107.1 . .
C15 C16 C17 106.9(8) . .
C15 C16 H16A 110.3 . .
C17 C16 H16A 110.3 . .
C15 C16 H16B 110.3 . .
C17 C16 H16B 110.3 . .
H16A C16 H16B 108.6 . .
C16 C17 C13 107.6(8) . .
C16 C17 H17A 110.2 . .
C13 C17 H17A 110.2 . .
C16 C17 H17B 110.2 . .
C13 C17 H17B 110.2 . .
H17A C17 H17B 108.5 . .
C13 C18 H18A 109.5 . .
C13 C18 H18B 109.5 . .
H18A C18 H18B 109.5 . .
C13 C18 H18C 109.5 . .
H18A C18 H18C 109.5 . .
H18B C18 H18C 109.5 . .
C14 C19 H19A 109.5 . .
C14 C19 H19B 109.5 . .
H19A C19 H19B 109.5 . .
C14 C19 H19C 109.5 . .
H19A C19 H19C 109.5 . .
H19B C19 H19C 109.5 . .
C14 C20 H20A 109.5 . .
C14 C20 H20B 109.5 . .
H20A C20 H20B 109.5 . .
C14 C20 H20C 109.5 . .
H20A C20 H20C 109.5 . .
H20B C20 H20C 109.5 . .
C21 O10 Eu1 142.2(5) . .
C22 O11 Mn1 109.9(5) . 3_645
C22 O12 Eu1 144.0(5) . 3_645
O10 C21 O9 120.6(7) . .
O10 C21 C23 122.1(7) . .
O9 C21 C23 117.2(7) . .
O11 C22 O12 122.4(7) . .
O11 C22 C25 118.5(7) . .
O12 C22 C25 119.0(7) . .
C21 C23 C27 114.9(7) . .
C21 C23 C28 109.5(7) . .
C27 C23 C28 108.0(8) . .
C21 C23 C24 111.5(7) . .
C27 C23 C24 101.7(7) . .
C28 C23 C24 110.9(8) . .
C30 C24 C25 113.1(8) . .
C30 C24 C23 112.6(8) . .
C25 C24 C23 101.4(6) . .
C30 C24 C29 108.5(9) . .
C25 C24 C29 109.9(8) . .
C23 C24 C29 111.2(8) . .
C26 C25 C22 114.7(7) . .
C26 C25 C24 108.2(7) . .
C22 C25 C24 112.8(6) . .
C26 C25 H25A 106.9 . .
C22 C25 H25A 106.9 . .
C24 C25 H25A 106.9 . .
C25 C26 C27 103.0(6) . .
C25 C26 H26A 111.2 . .
C27 C26 H26A 111.2 . .
C25 C26 H26B 111.2 . .
C27 C26 H26B 111.2 . .
H26A C26 H26B 109.1 . .
C23 C27 C26 108.3(7) . .
C23 C27 H27A 110.0 . .
C26 C27 H27A 110.0 . .
C23 C27 H27B 110.0 . .
C26 C27 H27B 110.0 . .
H27A C27 H27B 108.4 . .
C23 C28 H28A 109.5 . .
C23 C28 H28B 109.5 . .
H28A C28 H28B 109.5 . .
C23 C28 H28C 109.5 . .
H28A C28 H28C 109.5 . .
H28B C28 H28C 109.5 . .
C24 C29 H29A 109.5 . .
C24 C29 H29B 109.5 . .
H29A C29 H29B 109.5 . .
C24 C29 H29C 109.5 . .
H29A C29 H29C 109.5 . .
H29B C29 H29C 109.5 . .
C24 C30 H30A 109.5 . .
C24 C30 H30B 109.5 . .
H30A C30 H30B 109.5 . .
C24 C30 H30C 109.5 . .
H30A C30 H30C 109.5 . .
H30B C30 H30C 109.5 . .
C31 N1 C35 119.9(9) . .
C31 N1 Mn1 124.2(7) . .
C35 N1 Mn1 115.8(7) . .
C36 N2 C40 121.2(10) . .
C36 N2 Mn1 114.4(8) . .
C40 N2 Mn1 123.0(8) . .
N1 C31 C32 126.1(13) . .
N1 C31 H31A 116.9 . .
C32 C31 H31A 116.9 . .
C33 C32 C31 109.7(13) . .
C33 C32 H32A 125.1 . .
C31 C32 H32A 125.1 . .
C34 C33 C32 128.4(14) . .
C34 C33 H33A 115.8 . .
C32 C33 H33A 115.8 . .
C33 C34 C35 114.7(13) . .
C33 C34 H34A 122.7 . .
C35 C34 H34A 122.7 . .
N1 C35 C34 121.2(14) . .
N1 C35 C36 116.2(9) . .
C34 C35 C36 122.6(13) . .
N2 C36 C35 118.1(10) . .
N2 C36 C37 117.1(12) . .
C35 C36 C37 124.7(12) . .
C38 C37 C36 115.6(13) . .
C38 C37 H37A 122.2 . .
C36 C37 H37A 122.2 . .
C39 C38 C37 127.7(16) . .
C39 C38 H38A 116.2 . .
C37 C38 H38A 116.2 . .
C38 C39 C40 115.6(15) . .
C38 C39 H39A 122.2 . .
C40 C39 H39A 122.2 . .
N2 C40 C39 122.4(14) . .
N2 C40 H40A 118.8 . .
C39 C40 H40A 118.8 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Eu1 O12 2.341(5) 3_655
Eu1 O2 2.346(5) 4_465
Eu1 O4 2.347(5) .
Eu1 O6 2.396(6) .
Eu1 O5 2.439(6) .
Eu1 O10 2.450(5) .
Eu1 O7 2.476(6) 3_755
Eu1 O8 2.479(6) 3_755
Eu1 C11 2.809(8) .
Eu1 C12 2.842(8) 3_755
Eu1 Mn1 3.7491(12) .
Mn1 O1 2.093(5) 4_465
Mn1 O3 2.170(5) .
Mn1 O11 2.176(5) 3_655
Mn1 N2 2.253(8) .
Mn1 N1 2.262(7) .
Mn1 O4 2.488(5) .
O1 C1 1.244(9) .
O1 Mn1 2.093(5) 4_565
O2 C1 1.251(9) .
O2 Eu1 2.346(5) 4_565
O3 C2 1.240(9) .
O4 C2 1.275(8) .
C1 C3 1.554(10) .
C2 C5 1.504(10) .
C3 C8 1.534(10) .
C3 C4 1.550(10) .
C3 C7 1.554(10) .
C4 C9 1.528(10) .
C4 C10 1.553(10) .
C4 C5 1.555(10) .
C5 C6 1.515(11) .
C5 H5A 0.9800 .
C6 C7 1.538(11) .
C6 H6A 0.9700 .
C6 H6B 0.9700 .
C7 H7A 0.9700 .
C7 H7B 0.9700 .
C8 H8A 0.9600 .
C8 H8B 0.9600 .
C8 H8C 0.9600 .
C9 H9A 0.9600 .
C9 H9B 0.9600 .
C9 H9C 0.9600 .
C10 H10A 0.9600 .
C10 H10B 0.9600 .
C10 H10C 0.9600 .
O5 C11 1.213(10) .
O6 C11 1.211(10) .
O7 C12 1.221(9) .
O7 Eu1 2.476(6) 3_745
O8 C12 1.253(10) .
O8 Eu1 2.479(6) 3_745
C11 C13 1.532(11) .
C12 C15 1.501(11) .
C12 Eu1 2.842(7) 3_745
C13 C17 1.516(13) .
C13 C18 1.518(12) .
C13 C14 1.561(10) .
C14 C19 1.507(12) .
C14 C20 1.521(11) .
C14 C15 1.572(11) .
C15 C16 1.500(13) .
C15 H15A 0.9800 .
C16 C17 1.514(13) .
C16 H16A 0.9700 .
C16 H16B 0.9700 .
C17 H17A 0.9700 .
C17 H17B 0.9700 .
C18 H18A 0.9600 .
C18 H18B 0.9600 .
C18 H18C 0.9600 .
C19 H19A 0.9600 .
C19 H19B 0.9600 .
C19 H19C 0.9600 .
C20 H20A 0.9600 .
C20 H20B 0.9600 .
C20 H20C 0.9600 .
O9 C21 1.319(9) .
O10 C21 1.227(8) .
O11 C22 1.246(9) .
O11 Mn1 2.176(5) 3_645
O12 C22 1.258(9) .
O12 Eu1 2.341(5) 3_645
C21 C23 1.492(11) .
C22 C25 1.542(9) .
C23 C27 1.494(11) .
C23 C28 1.539(12) .
C23 C24 1.562(11) .
C24 C30 1.481(13) .
C24 C25 1.558(10) .
C24 C29 1.580(15) .
C25 C26 1.506(11) .
C25 H25A 0.9800 .
C26 C27 1.579(12) .
C26 H26A 0.9700 .
C26 H26B 0.9700 .
C27 H27A 0.9700 .
C27 H27B 0.9700 .
C28 H28A 0.9600 .
C28 H28B 0.9600 .
C28 H28C 0.9600 .
C29 H29A 0.9600 .
C29 H29B 0.9600 .
C29 H29C 0.9600 .
C30 H30A 0.9600 .
C30 H30B 0.9600 .
C30 H30C 0.9600 .
N1 C31 1.304(13) .
N1 C35 1.333(13) .
N2 C36 1.333(14) .
N2 C40 1.336(14) .
C31 C32 1.404(15) .
C31 H31A 0.9300 .
C32 C33 1.381(17) .
C32 H32A 0.9300 .
C33 C34 1.349(17) .
C33 H33A 0.9300 .
C34 C35 1.395(15) .
C34 H34A 0.9300 .
C35 C36 1.459(17) .
C36 C37 1.493(15) .
C37 C38 1.306(18) .
C37 H37A 0.9300 .
C38 C39 1.304(19) .
C38 H38A 0.9300 .
C39 C40 1.385(15) .
C39 H39A 0.9300 .
C40 H40A 0.9300 .
