#------------------------------------------------------------------------------
#$Date: 2016-02-14 06:40:26 +0200 (Sun, 14 Feb 2016) $
#$Revision: 176432 $
#$URL: svn://www.crystallography.net/cod/cif/7/10/90/7109021.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7109021
loop_
_publ_author_name
'Eugene Khaskin'
'Yael Diskin-Posner'
'Lev Weiner'
'Gregory Leitus'
'David Milstein'
_publ_section_title
;
 Formal loss of an H radical by a cobalt complex via metal-ligand
 cooperation
;
_journal_name_full               Chem.Commun.
_journal_page_first              2771
_journal_paper_doi               10.1039/c3cc39049g
_journal_volume                  49
_journal_year                    2013
_chemical_formula_moiety         'C24 H46 Co N P2, I'
_chemical_formula_sum            'C24 H46 Co I N P2'
_chemical_formula_weight         596.39
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                73.304(2)
_cell_angle_beta                 76.195(2)
_cell_angle_gamma                88.421(2)
_cell_formula_units_Z            2
_cell_length_a                   8.2349(3)
_cell_length_b                   12.3743(4)
_cell_length_c                   14.5566(5)
_cell_measurement_reflns_used    23965
_cell_measurement_temperature    120(2)
_cell_measurement_theta_max      28.47
_cell_measurement_theta_min      2.5495
_cell_volume                     1378.42(8)
_computing_cell_refinement       'APEX - 2'
_computing_data_collection       'APEX - 2'
_computing_data_reduction        'APEX - 2'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      120(2)
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device_type  'Bruker APEX - II Kappa CCD'
_diffrn_measurement_method       'omega and phi scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0303
_diffrn_reflns_av_sigmaI/netI    0.0348
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            24085
_diffrn_reflns_theta_full        28.47
_diffrn_reflns_theta_max         28.47
_diffrn_reflns_theta_min         1.50
_exptl_absorpt_coefficient_mu    1.869
_exptl_absorpt_correction_T_max  0.9223
_exptl_absorpt_correction_T_min  0.4273
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details   'Bruker APEX 2'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.437
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             614
_exptl_crystal_size_max          0.55
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.04
_refine_diff_density_max         1.197
_refine_diff_density_min         -0.560
_refine_diff_density_rms         0.092
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.055
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     275
_refine_ls_number_reflns         6937
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.055
_refine_ls_R_factor_all          0.0496
_refine_ls_R_factor_gt           0.0341
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0371P)²+0.9596P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0753
_refine_ls_wR_factor_ref         0.0809
_reflns_number_gt                5573
_reflns_number_total             6937
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c3cc39049g.txt
_cod_data_source_block           m1188
_cod_original_sg_symbol_Hall     -P1
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7109021
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Co1 Co 0.23638(4) 0.78650(3) 0.23559(2) 0.01792(8) Uani 1 1 d .
I1 I 0.77686(2) 0.270385(16) 0.404438(15) 0.03471(7) Uani 1 1 d .
N1 N 0.0297(3) 0.73426(18) 0.34518(15) 0.0189(4) Uani 1 1 d .
P1 P 0.18854(8) 0.95682(5) 0.25676(5) 0.01958(14) Uani 1 1 d .
P2 P 0.23347(8) 0.61154(5) 0.22132(5) 0.01746(13) Uani 1 1 d .
C1 C -0.0617(3) 0.8092(2) 0.38567(17) 0.0212(5) Uani 1 1 d .
C2 C -0.2267(3) 0.7836(2) 0.43947(18) 0.0248(6) Uani 1 1 d .
H2 H -0.2904 0.8387 0.4644 0.030 Uiso 1 1 calc R
C3 C -0.2970(3) 0.6779(3) 0.45634(19) 0.0281(6) Uani 1 1 d .
H3 H -0.4113 0.6606 0.4900 0.034 Uiso 1 1 calc R
C4 C -0.1998(3) 0.5976(2) 0.42383(18) 0.0240(6) Uani 1 1 d .
H4 H -0.2437 0.5226 0.4390 0.029 Uiso 1 1 calc R
C5 C -0.0367(3) 0.6277(2) 0.36849(17) 0.0202(5) Uani 1 1 d .
C6 C 0.0278(3) 0.9183(2) 0.37396(19) 0.0224(5) Uani 1 1 d .
H6A H 0.0809 0.9098 0.4298 0.027 Uiso 1 1 calc R
H6B H -0.0533 0.9787 0.3746 0.027 Uiso 1 1 calc R
C7 C 0.0765(3) 0.5423(2) 0.33506(18) 0.0211(5) Uani 1 1 d .
H7A H 0.0095 0.4849 0.3229 0.025 Uiso 1 1 calc R
H7B H 0.1333 0.5034 0.3875 0.025 Uiso 1 1 calc R
C8 C 0.0787(4) 1.0482(2) 0.1657(2) 0.0273(6) Uani 1 1 d .
C9 C -0.0840(4) 0.9836(3) 0.1770(2) 0.0364(7) Uani 1 1 d .
H9A H -0.1404 1.0247 0.1260 0.055 Uiso 1 1 calc R
H9B H -0.1572 0.9767 0.2425 0.055 Uiso 1 1 calc R
H9C H -0.0586 0.9082 0.1699 0.055 Uiso 1 1 calc R
C10 C 0.0359(5) 1.1634(3) 0.1818(3) 0.0418(8) Uani 1 1 d .
H10A H -0.0275 1.2043 0.1345 0.063 Uiso 1 1 calc R
H10B H 0.1395 1.2069 0.1720 0.063 Uiso 1 1 calc R
H10C H -0.0315 1.1529 0.2493 0.063 Uiso 1 1 calc R
C11 C 0.1844(4) 1.0638(3) 0.0601(2) 0.0362(7) Uani 1 1 d .
H11A H 0.2111 0.9896 0.0502 0.054 Uiso 1 1 calc R
H11B H 0.2884 1.1069 0.0501 0.054 Uiso 1 1 calc R
H11C H 0.1213 1.1047 0.0126 0.054 Uiso 1 1 calc R
C12 C 0.3536(3) 1.0377(2) 0.28277(19) 0.0242(6) Uani 1 1 d .
C13 C 0.4617(4) 0.9486(2) 0.3332(2) 0.0309(6) Uani 1 1 d .
H13A H 0.5436 0.9854 0.3547 0.046 Uiso 1 1 calc R
H13B H 0.5205 0.9088 0.2866 0.046 Uiso 1 1 calc R
H13C H 0.3903 0.8944 0.3907 0.046 Uiso 1 1 calc R
C14 C 0.2779(4) 1.1069(3) 0.3532(2) 0.0341(7) Uani 1 1 d .
H14A H 0.2169 1.0560 0.4165 0.051 Uiso 1 1 calc R
H14B H 0.2007 1.1601 0.3243 0.051 Uiso 1 1 calc R
H14C H 0.3676 1.1487 0.3639 0.051 Uiso 1 1 calc R
C15 C 0.4661(4) 1.1152(2) 0.1875(2) 0.0321(7) Uani 1 1 d .
H15A H 0.5588 1.1479 0.2036 0.048 Uiso 1 1 calc R
H15B H 0.4002 1.1759 0.1566 0.048 Uiso 1 1 calc R
H15C H 0.5107 1.0710 0.1416 0.048 Uiso 1 1 calc R
C16 C 0.4185(3) 0.5220(2) 0.23216(19) 0.0219(5) Uani 1 1 d .
C17 C 0.3722(4) 0.3946(2) 0.2732(2) 0.0285(6) Uani 1 1 d .
H17A H 0.3302 0.3693 0.2249 0.043 Uiso 1 1 calc R
H17B H 0.2853 0.3802 0.3350 0.043 Uiso 1 1 calc R
H17C H 0.4716 0.3533 0.2859 0.043 Uiso 1 1 calc R
C18 C 0.4974(3) 0.5584(2) 0.3049(2) 0.0274(6) Uani 1 1 d .
H18A H 0.5904 0.5101 0.3184 0.041 Uiso 1 1 calc R
H18B H 0.4129 0.5510 0.3668 0.041 Uiso 1 1 calc R
H18C H 0.5393 0.6372 0.2760 0.041 Uiso 1 1 calc R
C19 C 0.5481(4) 0.5433(3) 0.1333(2) 0.0300(6) Uani 1 1 d .
H19A H 0.6489 0.5025 0.1438 0.045 Uiso 1 1 calc R
H19B H 0.5769 0.6244 0.1057 0.045 Uiso 1 1 calc R
H19C H 0.5014 0.5167 0.0874 0.045 Uiso 1 1 calc R
C20 C 0.1386(3) 0.5978(2) 0.12005(19) 0.0232(5) Uani 1 1 d .
C21 C -0.0362(4) 0.6465(3) 0.1391(2) 0.0329(7) Uani 1 1 d .
H21A H -0.0858 0.6509 0.0833 0.049 Uiso 1 1 calc R
H21B H -0.0264 0.7222 0.1463 0.049 Uiso 1 1 calc R
H21C H -0.1078 0.5973 0.1998 0.049 Uiso 1 1 calc R
C22 C 0.2407(4) 0.6706(2) 0.01869(19) 0.0289(6) Uani 1 1 d .
H22A H 0.3568 0.6474 0.0081 0.043 Uiso 1 1 calc R
H22B H 0.2381 0.7503 0.0172 0.043 Uiso 1 1 calc R
H22C H 0.1921 0.6602 -0.0336 0.043 Uiso 1 1 calc R
C23 C 0.1205(4) 0.4758(2) 0.1181(2) 0.0315(7) Uani 1 1 d .
H23A H 0.0630 0.4289 0.1840 0.047 Uiso 1 1 calc R
H23B H 0.2317 0.4473 0.0984 0.047 Uiso 1 1 calc R
H23C H 0.0552 0.4732 0.0706 0.047 Uiso 1 1 calc R
C24 C 0.4464(4) 0.8380(2) 0.1285(2) 0.0276(6) Uani 1 1 d .
H24A H 0.4499 0.9204 0.1017 0.041 Uiso 1 1 calc R
H24B H 0.4477 0.8034 0.0756 0.041 Uiso 1 1 calc R
H24C H 0.5441 0.8152 0.1558 0.041 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Co Co 0.3494 0.9721 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
I I -0.4742 1.8119 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
C24 Co1 N1 178.59(11)
C24 Co1 P1 94.36(8)
N1 Co1 P1 85.62(7)
C24 Co1 P2 94.41(8)
N1 Co1 P2 85.75(7)
P1 Co1 P2 169.52(3)
C1 N1 C5 118.1(2)
C1 N1 Co1 120.51(17)
C5 N1 Co1 120.45(18)
C6 P1 C8 104.24(12)
C6 P1 C12 103.60(12)
C8 P1 C12 112.59(13)
C6 P1 Co1 99.89(9)
C8 P1 Co1 112.87(10)
C12 P1 Co1 120.77(9)
C7 P2 C16 102.92(12)
C7 P2 C20 104.00(12)
C16 P2 C20 112.17(12)
C7 P2 Co1 99.77(9)
C16 P2 Co1 120.66(9)
C20 P2 Co1 114.14(9)
N1 C1 C2 121.6(3)
N1 C1 C6 116.4(2)
C2 C1 C6 122.0(3)
C3 C2 C1 119.5(3)
C3 C2 H2 120.3
C1 C2 H2 120.3
C2 C3 C4 119.3(3)
C2 C3 H3 120.4
C4 C3 H3 120.4
C3 C4 C5 119.1(3)
C3 C4 H4 120.4
C5 C4 H4 120.4
N1 C5 C4 121.9(3)
N1 C5 C7 116.9(2)
C4 C5 C7 121.2(2)
C1 C6 P1 109.68(18)
C1 C6 H6A 109.7
P1 C6 H6A 109.7
C1 C6 H6B 109.7
P1 C6 H6B 109.7
H6A C6 H6B 108.2
C5 C7 P2 110.26(17)
C5 C7 H7A 109.6
P2 C7 H7A 109.6
C5 C7 H7B 109.6
P2 C7 H7B 109.6
H7A C7 H7B 108.1
C9 C8 C10 108.7(3)
C9 C8 C11 107.7(3)
C10 C8 C11 109.9(2)
C9 C8 P1 106.51(19)
C10 C8 P1 114.0(2)
C11 C8 P1 109.8(2)
C8 C9 H9A 109.5
C8 C9 H9B 109.5
H9A C9 H9B 109.5
C8 C9 H9C 109.5
H9A C9 H9C 109.5
H9B C9 H9C 109.5
C8 C10 H10A 109.5
C8 C10 H10B 109.5
H10A C10 H10B 109.5
C8 C10 H10C 109.5
H10A C10 H10C 109.5
H10B C10 H10C 109.5
C8 C11 H11A 109.5
C8 C11 H11B 109.5
H11A C11 H11B 109.5
C8 C11 H11C 109.5
H11A C11 H11C 109.5
H11B C11 H11C 109.5
C13 C12 C14 108.4(2)
C13 C12 C15 108.5(2)
C14 C12 C15 109.8(2)
C13 C12 P1 105.69(18)
C14 C12 P1 112.0(2)
C15 C12 P1 112.2(2)
C12 C13 H13A 109.5
C12 C13 H13B 109.5
H13A C13 H13B 109.5
C12 C13 H13C 109.5
H13A C13 H13C 109.5
H13B C13 H13C 109.5
C12 C14 H14A 109.5
C12 C14 H14B 109.5
H14A C14 H14B 109.5
C12 C14 H14C 109.5
H14A C14 H14C 109.5
H14B C14 H14C 109.5
C12 C15 H15A 109.5
C12 C15 H15B 109.5
H15A C15 H15B 109.5
C12 C15 H15C 109.5
H15A C15 H15C 109.5
H15B C15 H15C 109.5
C19 C16 C18 108.6(2)
C19 C16 C17 108.6(2)
C18 C16 C17 108.8(2)
C19 C16 P2 112.01(18)
C18 C16 P2 105.15(18)
C17 C16 P2 113.48(19)
C16 C17 H17A 109.5
C16 C17 H17B 109.5
H17A C17 H17B 109.5
C16 C17 H17C 109.5
H17A C17 H17C 109.5
H17B C17 H17C 109.5
C16 C18 H18A 109.5
C16 C18 H18B 109.5
H18A C18 H18B 109.5
C16 C18 H18C 109.5
H18A C18 H18C 109.5
H18B C18 H18C 109.5
C16 C19 H19A 109.5
C16 C19 H19B 109.5
H19A C19 H19B 109.5
C16 C19 H19C 109.5
H19A C19 H19C 109.5
H19B C19 H19C 109.5
C23 C20 C21 109.1(2)
C23 C20 C22 109.8(2)
C21 C20 C22 107.7(2)
C23 C20 P2 113.56(18)
C21 C20 P2 105.99(19)
C22 C20 P2 110.50(19)
C20 C21 H21A 109.5
C20 C21 H21B 109.5
H21A C21 H21B 109.5
C20 C21 H21C 109.5
H21A C21 H21C 109.5
H21B C21 H21C 109.5
C20 C22 H22A 109.5
C20 C22 H22B 109.5
H22A C22 H22B 109.5
C20 C22 H22C 109.5
H22A C22 H22C 109.5
H22B C22 H22C 109.5
C20 C23 H23A 109.5
C20 C23 H23B 109.5
H23A C23 H23B 109.5
C20 C23 H23C 109.5
H23A C23 H23C 109.5
H23B C23 H23C 109.5
Co1 C24 H24A 109.5
Co1 C24 H24B 109.5
H24A C24 H24B 109.5
Co1 C24 H24C 109.5
H24A C24 H24C 109.5
H24B C24 H24C 109.5
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
Co1 C24 2.008(3)
Co1 N1 2.008(2)
Co1 P1 2.2274(8)
Co1 P2 2.2349(7)
N1 C1 1.355(3)
N1 C5 1.359(3)
P1 C6 1.838(3)
P1 C8 1.874(3)
P1 C12 1.879(3)
P2 C7 1.836(2)
P2 C16 1.869(3)
P2 C20 1.874(3)
C1 C2 1.391(4)
C1 C6 1.503(4)
C2 C3 1.377(4)
C2 H2 0.9500
C3 C4 1.378(4)
C3 H3 0.9500
C4 C5 1.390(4)
C4 H4 0.9500
C5 C7 1.499(4)
C6 H6A 0.9900
C6 H6B 0.9900
C7 H7A 0.9900
C7 H7B 0.9900
C8 C9 1.529(4)
C8 C10 1.529(4)
C8 C11 1.536(4)
C9 H9A 0.9800
C9 H9B 0.9800
C9 H9C 0.9800
C10 H10A 0.9800
C10 H10B 0.9800
C10 H10C 0.9800
C11 H11A 0.9800
C11 H11B 0.9800
C11 H11C 0.9800
C12 C13 1.530(4)
C12 C14 1.530(4)
C12 C15 1.541(4)
C13 H13A 0.9800
C13 H13B 0.9800
C13 H13C 0.9800
C14 H14A 0.9800
C14 H14B 0.9800
C14 H14C 0.9800
C15 H15A 0.9800
C15 H15B 0.9800
C15 H15C 0.9800
C16 C19 1.531(4)
C16 C18 1.538(4)
C16 C17 1.539(4)
C17 H17A 0.9800
C17 H17B 0.9800
C17 H17C 0.9800
C18 H18A 0.9800
C18 H18B 0.9800
C18 H18C 0.9800
C19 H19A 0.9800
C19 H19B 0.9800
C19 H19C 0.9800
C20 C23 1.530(4)
C20 C21 1.539(4)
C20 C22 1.543(4)
C21 H21A 0.9800
C21 H21B 0.9800
C21 H21C 0.9800
C22 H22A 0.9800
C22 H22B 0.9800
C22 H22C 0.9800
C23 H23A 0.9800
C23 H23B 0.9800
C23 H23C 0.9800
C24 H24A 0.9800
C24 H24B 0.9800
C24 H24C 0.9800
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
P1 Co1 N1 C1 3.28(18)
P2 Co1 N1 C1 -170.77(18)
P1 Co1 N1 C5 172.01(18)
P2 Co1 N1 C5 -2.04(17)
C24 Co1 P1 C6 -166.70(12)
N1 Co1 P1 C6 11.89(11)
P2 Co1 P1 C6 46.54(19)
C24 Co1 P1 C8 83.15(13)
N1 Co1 P1 C8 -98.26(11)
P2 Co1 P1 C8 -63.61(19)
C24 Co1 P1 C12 -54.27(13)
N1 Co1 P1 C12 124.32(11)
P2 Co1 P1 C12 158.96(16)
C24 Co1 P2 C7 166.87(12)
N1 Co1 P2 C7 -11.73(10)
P1 Co1 P2 C7 -46.37(18)
C24 Co1 P2 C16 55.40(13)
N1 Co1 P2 C16 -123.19(11)
P1 Co1 P2 C16 -157.83(17)
C24 Co1 P2 C20 -82.88(13)
N1 Co1 P2 C20 98.53(11)
P1 Co1 P2 C20 63.89(19)
C5 N1 C1 C2 -8.0(3)
Co1 N1 C1 C2 161.00(19)
C5 N1 C1 C6 168.8(2)
Co1 N1 C1 C6 -22.3(3)
N1 C1 C2 C3 3.2(4)
C6 C1 C2 C3 -173.4(2)
C1 C2 C3 C4 3.3(4)
C2 C3 C4 C5 -4.7(4)
C1 N1 C5 C4 6.5(3)
Co1 N1 C5 C4 -162.49(18)
C1 N1 C5 C7 -171.2(2)
Co1 N1 C5 C7 19.8(3)
C3 C4 C5 N1 -0.2(4)
C3 C4 C5 C7 177.4(2)
N1 C1 C6 P1 31.7(3)
C2 C1 C6 P1 -151.6(2)
C8 P1 C6 C1 91.7(2)
C12 P1 C6 C1 -150.33(18)
Co1 P1 C6 C1 -25.13(18)
N1 C5 C7 P2 -29.4(3)
C4 C5 C7 P2 152.9(2)
C16 P2 C7 C5 148.68(18)
C20 P2 C7 C5 -94.17(19)
Co1 P2 C7 C5 23.90(18)
C6 P1 C8 C9 -50.3(2)
C12 P1 C8 C9 -162.0(2)
Co1 P1 C8 C9 57.1(2)
C6 P1 C8 C10 69.5(2)
C12 P1 C8 C10 -42.1(3)
Co1 P1 C8 C10 177.0(2)
C6 P1 C8 C11 -166.7(2)
C12 P1 C8 C11 81.7(2)
Co1 P1 C8 C11 -59.2(2)
C6 P1 C12 C13 83.5(2)
C8 P1 C12 C13 -164.49(18)
Co1 P1 C12 C13 -27.0(2)
C6 P1 C12 C14 -34.4(2)
C8 P1 C12 C14 77.6(2)
Co1 P1 C12 C14 -144.86(17)
C6 P1 C12 C15 -158.5(2)
C8 P1 C12 C15 -46.5(2)
Co1 P1 C12 C15 91.1(2)
C7 P2 C16 C19 164.01(19)
C20 P2 C16 C19 52.8(2)
Co1 P2 C16 C19 -86.2(2)
C7 P2 C16 C18 -78.18(19)
C20 P2 C16 C18 170.63(17)
Co1 P2 C16 C18 31.6(2)
C7 P2 C16 C17 40.6(2)
C20 P2 C16 C17 -70.6(2)
Co1 P2 C16 C17 150.39(16)
C7 P2 C20 C23 -66.2(2)
C16 P2 C20 C23 44.3(2)
Co1 P2 C20 C23 -173.89(18)
C7 P2 C20 C21 53.5(2)
C16 P2 C20 C21 164.00(18)
Co1 P2 C20 C21 -54.18(19)
C7 P2 C20 C22 169.8(2)
C16 P2 C20 C22 -79.6(2)
Co1 P2 C20 C22 62.2(2)
